Apparatus and method for fabricating glass bodies using an aerosol delivery system

Abstract

A method of fabricating a glass body that includes a multiplicity of constituents, at least one of which is a dopant (e.g., a rare-earth element) having a low vapor pressure (LVP) precursor comprises the steps of: (a) generating an aerosol from the LVP precursor; (b) separately generating vapors of the other constituents; (c) convecting the aerosol and vapors to deposition system including a substrate; and (d) forming at least one doped layer on a surface of the substrate. In one embodiment, the method also includes filtering the aerosol so as to remove aerosol particles outside of a particular range of sizes. Also described is a unique aerosol generator that is particularly useful in generating aerosols of rare-earth dopants. Particular embodiments directed to the fabrication of Yb-doped optical fibers are described.

Description

BRIEF DESCRIPTION OF THE SEVERAL VIEWS OF THE DRAWING

Our invention, together with its various features and advantages, can be readily understood from the following more detailed description taken in conjunction with the accompanying drawing, in which:

FIG. 1 is a schematic, partially isometric view of apparatus for fabricating RE-doped optical fibers, in accordance with one embodiment of our invention;

FIG. 2 shows two side views [Parts (A) and (B)] and an end view [Part (C)] of an aerosol generator, in accordance with another embodiment of our invention. Part (A) is a side view looking along arrow A of Part (C), whereas Part (B) is a side view looking along arrow B of Part (C). Note, the heaters 12.4a and 12.4b of Part (A) are shown schematically;

FIG. 3 is a schematic, partially isometric view of a feedstock tube with a concentric inner tube positioned therein for vaporizing the aerosol before it enters an MCVD preform tube, in accordance with still another embodiment of our invention; and

FIG. 4 is a graph showing how the transmission of light in Yb-doped silica fibers degrades with time (photodarkening) for two different cases.

Claims

1. A method of fabricating a glass body that includes a multiplicity of constituents, at least one constituent being a first dopant having a first LVP precursor comprising the steps of: (a) generating a first aerosol comprising first particles of the first LVP precursor, each first particle including only the first LVP precursor of the first dopant;(b) separately generating vapors of the other constituents; generating steps (a) and (b) taking place at a location remote from a deposition system used to form the glass body;(c) convecting the aerosol of step (a) and the vapors of step (b) from the remote location to the deposition system, which includes a substrate; and(d) forming on a surface of the substrate at least one doped layer comprising the dopants contained in the aerosol and vapors convected in step (c).

2. The method of claim 1, further including the additional step of filtering the first aerosol so as to remove aerosol particles outside of a particular range of sizes and transmit those within the same range, said filtering step being performed by at least one component that does not include any generator used in aerosol generating step (a) or any tubing used in convecting step (c).

3. The method of claim 2, wherein the filtering step removes particles having sizes outside the range of approximately 0.01 to 10 μm and transmits particles within the same range.

4. The method of claim 1, wherein generating step (a) includes heating the LVP precursor at a first temperature high relative to room temperature and convecting step (c) convects the aerosols through tubing maintained at a temperature lower than the first temperature.

5. The method of claim 1, wherein generating step (a) includes the additional steps of (a1) providing the LVP precursor to a first chamber of a vessel, (a2) heating the LVP precursor to provide a vapor thereof, (a3) flowing a carrier gas into the first chamber, thereby to generate in a second chamber of the vessel a gas mixture that contains the precursor, (a4) flowing a cooler carrier gas into the second chamber, thereby to condense the vapor and form an aerosol of the precursor, and (a5) extracting the aerosol from the vessel.

6. The method of claim 5, wherein the carrier gas is saturated with the precursor.

7. The method of claim 1, wherein said glass body is fabricated as a planar waveguide.

8. The method of claim 1, wherein said waveguide is fabricated as a silica optical fiber.

9. The method of claim 8, wherein said deposition system comprises an MCVD system and the substrate comprises a substrate tube, the MCVD system including a feedstock tube axially coupled to the substrate tube and a concentric, inner tube positioned within the feedstock tube, and wherein convecting step (c) includes convecting the aerosols into one of the inner tube and the feedstock tube and heating the aerosols to a vapor state before they enter the substrate tube.

10. The method of claim 1, wherein another constituent is a second dopant having a second LVP precursor, and further including the additional step of separately generating a second aerosol comprises second particles of the second LVP precursor, each second particle including only the second LVP precursor of the second dopant.

11. The method of claim 10, further including the step of maintaining the first and second aerosols in parallel fluid-flow communication with one another.

12. The method of claim 10, further including the step of mixing the aerosols of step (a) with one another before convecting them to the deposition system.

13. The method of claim 1, further including the step of mixing the aerosols of step (a) with the vapors of step (b) before convecting them to the deposition system.

14. The method of claim 8, further including the additional steps of forming a preform comprising the at least one doped layer and drawing an optical fiber from the preform.

15. The method of claim 1, wherein said first LVP particles and carrier gas are free of any organic compounds.

16. The method of claim 1, wherein said first LVP precursor is a chloride.

17. The method of claim 16, wherein said first particles are suspended in a carrier gas of He.

18. The method of claim 16 wherein the glass body is a Yb-doped optical fiber.

19. The method of claim 18, wherein the fiber includes a Yb-doped region and the fiber exhibits reduced photodarkening when optical radiation propagates along at least the Yb-doped region.

20. The method of claim 1, wherein the first dopant is selected from the group consisting of Er, Yb, Nd, Tm, Ho, and La.

21. The method of claim 1, wherein the deposition system oxidizes and vaporizes precursors delivered thereto, and most of the LVP precursor vaporizes in the deposition system before oxidizing.

22. The method of claim 1, wherein most of the aerosol particles are oxidized before being delivered to the deposition system.

23. The method of claim 1, wherein generating steps (a) and (b) are allowed to reach equilibrium before performing convecting step (c).

24. The method of claim 1, further including the steps of monitoring the size and/or number of first particles generated in step (a) and controlling an operating parameter of step (a) in response to the monitoring step.

25. The method of claim 1, wherein the glass body is fabricated as glass soot.

26. An MCVD method of fabricating a silica optical fiber that includes a multiplicity of constituents, at least one constituent being a first rare-earth dopant having a first LVP precursor comprising the steps of: (a) generating a first aerosol comprising first particles of the first LVP precursor, the first particles including only the first LVP precursor of the first dopant, wherein generating step (a) includes the additional steps of (a1) providing the first LVP precursor to a first chamber of a vessel, (a2) heating the first LVP precursor to a temperature high relative to room temperature to provide a vapor thereof, (a3) flowing a carrier gas into the first chamber, thereby to generate in a second chamber of the vessel a vapor of carrier gas containing the first precursor, (a4) flowing a cooler carrier gas into the second chamber, thereby to condense the vapor and form the first aerosol of the first LVP precursor, and (a5) extracting the first aerosol from the vessel;(b) separately generating a vapor of a silica precursor; generating steps (a) and (b) taking place at a location remote from a deposition system used to form the optical fiber;(c) convecting the first aerosol and the silica vapor from the remote location through tubing to an MCVD system, which includes a substrate tube, the tubing being maintained at or slightly above room temperature;(d) forming on an inside wall of the substrate tube doped silica layers from the particles and vapors convected by step (c); and(e) collapsing the substrate tube to form a fiber preform.

27. The method of claim 26, further including, after step (b), the additional step of filtering the first aerosol so as to remove aerosol particles having sizes outside of a predetermined range and transmit those within the same range; said filtering step being performed by at least one component that does not include any generator used in aerosol generating step (a) or any tubing used in convecting step (c)

28. The method of claim 26, wherein said MCVD system includes a feedstock tube axially coupled to the substrate tube and a concentric, inner tube positioned within the feedstock tube, and wherein convecting step (d) includes convecting the first aerosol into the inner tube and heating the aerosol to a vapor state before they enter the substrate tube.

29. The method of claim 26, wherein said first LVP precursor is a chloride.

30. The method of claim 29, wherein said first particles are suspended in a carrier gas of He.

31. The method of claim 29, wherein the fiber is a Yb-doped optical fiber.

32. The method of claim 31, wherein the fiber includes a Yb-doped region and the fiber exhibits reduced photodarkening when optical radiation propagates along the Yb-doped region.

33. The method of claim 26, wherein said first LVP particles and carrier gas are free of any organic compounds

34. A method of fabricating a glass body that includes a multiplicity of constituents, at least one constituent being a first dopant having a first LVP precursor comprising the steps of: (a) generating a first aerosol comprising first particles that include the first LVP precursor; generating step (a) including the steps of (a1) providing a vapor of the LVP precursor and (a2) supersaturating the LVP vapor to form the aerosol;(b) separately generating vapors of the other constituents;(c) convecting the aerosol of step (a) and the vapors of step (b) to a deposition system including a substrate; and(d) forming on a surface of the substrate at least one doped layer from the dopants contained in the aerosol and vapors convected in step (c).

35. The method of claim 34, wherein step (a2) includes the steps of flowing a primary carrier gas through the LVP vapor to entrain the LVP vapor and condensing the entrained vapor to form the aerosol.

36. The method of claim 35, wherein the condensing step includes flowing a cooler, secondary carrier gas through the entrained vapor.

37. The method of claim 34, wherein step (a1) includes flowing a reactive gas over a sub-precursor of the LVP precursor to cause a chemical reaction that generates the LVP precursor vapor.

38. The method of claim 37, wherein the sub-precursor comprises a metal body and the metal comprises the first dopant.

39. The method of claim 34, wherein step (a2) comprises rapidly cooling the LVP vapor.

40. The method of claim 34, wherein step (a2) comprises adiabatically expanding the primary carrier gas and LVP vapor to condense the LVP vapor.

41. The method of claim 34, wherein said first LVP particles and carrier gas are free of any organic compounds

42. The method of claim 34, wherein in step (a2) the first LVP precursor is condensed onto a seed aerosol.

43. The method of claim 42, wherein the seed aerosol comprises a LVP substance.

44. The method of claim 43, wherein the seed aerosol is selected from the group consisting of RE precursor aerosols and alumina aerosol.

45. The method of claim 42, wherein the seed aerosol comprises an aerosol of an oxidized HVP compound.

46. The method of claim 45, wherein the HVP compound is selected from the group consisting of dopants and host material.

47. The method of claim 46, wherein the seed aerosol comprises a homogeneous multi-component oxide comprising two or more HVP compounds.

48. The method of claim 34, wherein generating steps (a) and (b) taking place at a location remote from a deposition system used to form the glass body; and wherein the convecting step (c) transports the aerosol of step (a) and the vapors of step (b) from the remote location to the deposition system.

49. The method of claim 34, further including the additional step of filtering the first aerosol so as to remove aerosol particles outside of a particular range of sizes and transmit those within the same range, said filtering step being performed by at least one component that does not include any generator used in aerosol generating step (a) or any tubing used in convecting step (c)

50. The method of claim 46, wherein the filtering step removes particles having sizes outside the range of approximately 0.01 to 10 μm and transmits particles within the same range.

51. The method of claim 34, further including the steps of monitoring the size and/or number of first particles generated in step (a) and controlling an operating parameter of step (a) in response to the monitoring step.

52. An aerosol generator comprising a vessel having first and second chambers in fluid-flow communication with one another,said first chamber configured to contain a LVP substance,a heater configured to heat said substance,a first input port configured to flow a primary gas into said first chamber, thereby to generate in said second chamber a vapor compound that includes at least one element of said substance,a second input port configured to flow a cooler carrier gas into said second chamber, thereby to condense said vapor and form an aerosol therefrom, andan output port configured to extract said aerosol from the vessel.