Currently claimed embodiments of this invention relate to systems and methods for focusing sunlight at high power and high concentration, and more particularly for commercial use of solar energy as an economically viable form of renewable energy.
High concentration of sunlight at a receiver is advantageous because it provides for high temperature at the receiver. This in turn allows for both higher efficiency conversion of solar thermal energy into electricity, and for a broad range of solar industrial process heat (SIPH).
Solar thermal production of hydrogen from water—for example, by the redox reaction of cerium oxide at 1,500 C.—requires concentration of ˜3,500× to avoid significant energy loss by thermal radiation escaping back out of the reactor window (Brendelberger 2021).
Very high solar concentration, for example >10,000 suns, may be obtained using a paraboloidal reflector which is turned to point at the sun through the day, but the cost per unit area for large steerable paraboloids is too high to make them commercially viable. Lower cost may be achieved using a large, fixed paraboloid together with a field of flat heliostats to direct sunlight into the reflector along the paraboloid axis. A heliostat is a device generally in a fixed location, with a mirrored surface to reflect solar energy toward a fixed target. Heliostats typically have one or more back-silvered glass mirrors attached to a rigid steel frame. A heliostat includes a tracking mechanism which turns the reflecting surface to maintain the reflected sunlight on the target as the sun moves through the sky. The largest high power system with very high concentration was built as shown schematically in
The mirror area per unit area of collection is reduced in the system described in U.S. Pat. No. 4,000,733 to Pauly, 1977, Solar Furnace, in which sunlight concentrated by multiple flat heliostats onto a paraboloidal dish is further concentrated by additional mirrors and lenses, but the description gives no quantitative specifics.
At lower concentration, <1,000 suns, very large heliostat installations have been used to collect very high solar power for thermal generation of electric power (CSP). Typically, in such systems, the receiver is sized to subtend an angle of ¾ to 1 degree, as seen from a heliostat, and the heliostats, which are essentially flat, are sized to be smaller than the size of the sunlight illumination formed at the receiver. Heliostats with size approximately ⅓ the solar disc size are typical in the largest CSP installations. A disadvantage of using such small, flat heliostats is that to obtain high sunlight concentration, a very large number must be used; for example, some 50,000 heliostats are needed around a tower-mounted cylindrical receiver to obtain a ratio of receiver-to-mirror area ˜800, in the best cases. The resulting complexity is high, and concentration at the target allowing for cosine and other losses is low at around 500×.
Very high concentrations are in principle achievable with the high powers available at the focus of a heliostat field, provided each individual heliostat realizes the highest concentration set by thermodynamics of sunlight on a distant target—this is achieved if the heliostat reflector is shaped to form a disc image of the sun at the receiver, of angular diameter equal to 0.55° (9.2 milliradians). The heliostat reflector shape needed to form an image of the sun depends on the angle at which sunlight strikes the reflector, and this angle changes as the position of the sun in the sky moves throughout the day. In general, the different shapes are toroids, i.e. surfaces with concave curvature that varies according to angle around the mirror.
U.S. Pat. No. 4,459,972 to Moore discloses such a concave focusing reflector formed as a section of a toroid of fixed shape, chosen to produce a disc image of the sun at midday. To minimize the image degradation at other times of day, a heliostat reflector with fixed toroidal curvature may be oriented by a mount constructed with a first rotation axis along the line to the target, as shown in
To form a disc image of the sun throughout the day, whatever the angle of incidence of the sun on the reflector, requires not only that the toroid axis have the correct rotation angle, but also that the toroidal radii of curvature be set according to the changing angle of incidence (AOI). These changes are given by the Coddington equations and are shown in
Heliostats built for a target-axis mount that also have the capability to change the two toroidal radii of curvature (and thus the potential to extend solar disc imaging over more of the day) have been described in three publications. In U.S. 2015 0323772A1 Mixed Heliostat Field, L. Gallar describes a reflecting surface assembled from many small reflecting segments which are oriented by a system of cams and two drive motors. A similar mechanism is described by Chong, referenced above. A different, passive approach to changing the tangential and sagittal toroid curvature of a heliostat on a target axis mount is described by Lehmann and Allenspach in PCT/AU2012/000382, Toroidal heliostat, where the support of the reflecting surface is configured to bend by passive means, including changing orientation to gravity.
In practice, neither of the above two approaches have been adopted for commercial use because of complexity and cost. A further difficulty of both is that the provisions for curvature adjustment reduce stiffness and strength, whereas commercial heliostats must maintain accurate pointing in wind and survive wind gusts of up to 90 mph.
In a third prior art invention PCT/US2020/053130, 2021, Actively Focused Lightweight Heliostat, the entire content of which is incorporated herein by reference, Angel et al describe a heliostat on an alt-azimuth mount whose reflecting surface is 1) mounted on a stiff spaceframe structure, 2) has a toroidal shape which is made adjustable by the inclusion of many back struts that form part of the spaceframe structure, and 3) is positioned by three or more electrically driven actuators driven under computer control. A prototype using a hexagonal mirror on an alt-az mount and three independent actuators was demonstrated to give sharp disc images of the sun with 1/10 the area of the reflector over a wide range of angles of incidence. But while this invention combines stiffness and accurate changes in toroidal shape, it is complex and may not be cost effective. It is also not equipped to track the sun, as needed to exploit sharp solar disc images for the highest time-averaged concentration at the receiver.
In order to realize the full potential for very high concentration from a field of heliostats focusing disc images, the heliostat must be equipped for orientation to very high accuracy. If, for example, the overall error of the reflector surface relative to the ideal toroid for disc imaging is 1 mrad rms, then the reflector should be oriented to better than 1 mrad rms, averaged over time, to avoid significant additional blurring of the time-averaged concentration.
In prior art, systems have been described targeting such high accuracy tracking by using fisheye cameras in closed loop control. In such systems, the camera is fixed to the reflector with known relative orientation, and one or more images are taken that include the sun and another separate object. Given accurate knowledge of the position of both these sources, the camera orientation (and hence that of the reflector) may be accurately computed. Systems have been described that use solar-illuminated objects as the second source. In one previous implementation, U.S. Pat. No. 8,153,945 B2, Hickerson and Reznik, 2012, the second source is the solar illuminated receiver, but its position is not accurately known: its optical center of gravity depends on the orientations of all the heliostats providing illumination. If some are off in position, the others will follow like sheep. In another implementation, Reduced to minimum cost: Lay-down heliostat with monolithic mirror-panel and closed loop control, 2018, Pfahl et al, sunlight reflected from different parts of the tower supporting the receiver is used as a second source; however, reliable orientation data is difficult to obtain, because the tower image is much fainter and much more complex than the solar disc image, and therefore it requires separate much longer exposure.
The challenges to achieving high concentration and high power, along with the long-felt needs to lower the cost of increased sunlight concentration and reduce losses at the receiver obtaining energy from many heliostats, continue to leave room for improvement over the prior art.
A heliostat according to some embodiments of the current invention includes a reflector that has at least one segment arranged in a segment assembly and that defines a reflecting surface; a rigid spaceframe structure that includes a plurality of struts joined at nodes, the plurality of struts supporting the segment assembly so as to hold the reflecting surface in a concave toroidal shape; a dual-axis mount constructed and arranged to support and orient the rigid spaceframe structure and the segment assembly so as to reflect sunlight incident on the reflecting surface toward a distant receiving surface, the dual-axis mount including at least two drives; at least one mechanical linkage coupled to at least one drive of the dual-axis mount and configured to change a relative position of at least two nodes of the rigid spaceframe structure in synchronization with motion of the at least one drive, and thereby changing a shape of the rigid spaceframe structure and the reflector. Wherein the change of the relative position of the at least two nodes alters the shape of the reflector in such a way as to change a toroidal reflector shape so as to form and maintain a focused disc image of the sun on the distant receiver as the dual-axis mount is turned to follow the sun's motion throughout the day.
A system for tracking a plurality of heliostats according to some embodiments of the current invention includes a plurality of heliostats arranged in a heliostat field; a plurality of wide-field digital fisheye cameras, one attached rigidly to the reflector or support frame of each of the heliostats; one or more light sources located on towers, within or adjacent to the heliostat field, with at least one of the light sources arranged to be visible to each of the plurality of wide-field digital fisheye cameras; an image processor configured to communicate with each camera of the plurality of wide-field digital fisheye cameras to record image data for a continuous sequence of images, each image of the sequence of images capturing the sun and at least one of the one or more light sources; and a computer configured to receive the image data from the image processor. The computer is configured to process the image data, in conjunction with the known position of the light source and position of the sun at each instant of imaging, to compute an orientation of each heliostat reflector of the plurality of heliostats, and to control and correct future tracking motions of each heliostat so as to direct reflected sunlight accurately to a receiver of the plurality of heliostats.
A system for focusing sunlight at high power and concentration according to some embodiments of the current invention includes a tower; one or a plurality of compound parabolic concentrators (CPCs) mounted atop the tower; a plurality of heliostats arranged in an array on the ground, each heliostat of the plurality of heliostats includes an active reflector, each active reflector defining a reflector shape that is changed while in operation so that reflected sunlight is focused to form and maintain a disc image of the sun centered on one of the CPCs over a period of time while in operation. The plurality of heliostats are arranged within one or more ellipses formed by an intersection of an acceptance cone angle of each CPC and the ground, in a close packed configuration within each ellipse, out to distances not larger than that which yields a disc image of the sun equal in size to the CPC entrance diameter. The sunlight from the plurality of heliostats is efficiently coupled into the CPC, which outputs high power solar energy at high concentration, up to 4,000 suns.
An apparatus for focusing sunlight at high power and concentration according to some embodiments of the current invention includes a tower; a cylindrical receiver mounted on the tower; and a plurality of heliostats, each heliostat of the plurality of heliostats including an active reflector, each active reflector defining a reflector shape that is changeable while in operation so that reflected sunlight is focused to form and maintain a disc image of the sun over a period of time while in operation. The plurality of heliostats are arranged in a 360-degree array surrounding the tower and oriented to reflect and focus the solar disc images onto the cylindrical receiver. The receiver presents an area to any one of the plurality of heliostats of no more than twice that of an accurately imaged solar disc from the distance of the most distant heliostat. The solar concentration averaging over the full cylinder surface of >1000 suns is achieved for solar elevations >20 degrees.
Some embodiments of the current invention are discussed in detail below. In describing embodiments, specific terminology is employed for the sake of clarity. However, the invention is not intended to be limited to the specific terminology so selected. A person skilled in the relevant art will recognize that other equivalent components can be employed, and other methods developed, without departing from the broad concepts of the present invention. All references cited anywhere in this specification are incorporated by reference as if each had been individually incorporated.
Accordingly, some embodiments of this invention relate to apparatuses and methods for focusing sunlight at high power and high concentration, for example, as high as 4,000 suns. The apparatus includes heliostats with active adjustment of surface shape and provision for accurate sun-tracking, and optical configurations to receive and further concentrate sunlight onto a receiver. The application can be for commercial use of solar energy as an economically viable form of renewable energy.
Accordingly, an embodiment of the current invention is directed to systems. apparatuses and methods for focusing sunlight at high power and high concentration, for example, >1,000 suns. Such an apparatus includes heliostats with unique active adjustment of surface shape, provision for high accuracy sun-tracking, and optical configurations to receive and further concentrate sunlight onto a receiver. Applications of some embodiments of the current invention can include commercial use of solar thermal energy as an economically viable form of renewable energy.
A heliostat design according to some embodiments of the current invention is one in which the concave reflector shape is continuously and automatically altered through the day. Some embodiments of the current invention include methods of using configurations of fields of such heliostats so as to deliver sunlight at high concentration and high power to a receiver. The individual heliostats each maintain a sharply focused disc image of the sun at the receiver. The receiver reflector shape is a toroid, with curvatures and orientation adapted according to the changing angle of incidence of the sun. In some embodiments of this invention, the shape changes are accomplished by a simple mechanical coupling to the tracking motion of the mount that changes the strut lengths of a stiff supporting mechanical truss or spaceframe, according to heliostat orientation.
The heliostat reflectors of this embodiment are oriented by and are mechanically coupled to a target-oriented dual-axis mount. The mount turns the heliostat about a first (target) axis, which is aimed at a distant surface that receives the reflected sunlight, and about a second (cross) axis perpendicular to both the first axis and to the reflector surface. The rotation angles of both axes are adjusted to orient the reflector so as to reflect sunlight toward the receiving surface; i.e., along the direction of the first axis. The rotation motion of the second axis then tracks the angle of incidence (AOI) of sunlight on the reflector, and is mechanically linked to change the toroidal shape of a rectangular reflector as needed to focus a sharp disc image of the sun. Struts extending out from a back central node of the speceframe are moved to raise or lower the corners of the reflector as required. To obtain high concentration by a field of many such heliostats, all directing sunlight to form disc images of the sun on a single tower-mounted receiver, the heliostats are set close together in the field but spaced far enough apart to prevent collisions, to minimize shadowing of incoming sunlight by adjacent heliostats, and to minimize blocking of reflected light by adjacent heliostats. We show that such dense packing may be obtained by an embodiment of this invention which uses rectangular reflectors with spaceframe struts extending to each of their four corners.
Some embodiments of this invention overcome the limitations from complexity or stiffness, or both, of previous approaches which provided for shape change in heliostats. Thus in recent prior art, Angel et al demonstrated a prototype that focused solar disc images through the day, but at the cost of bending requiring three motor driven actuators and an electronic system for control and power. Some embodiments of the current invention are simpler and less expensive, requiring no added motors or control system.
In several embodiments of the current invention, the concave reflecting surface and its supporting frame are rectangular, with the sides of the rectangle oriented at 45degrees to the second, cross-axis of the target-oriented mount, as shown in
In an embodiment of this invention, these required changes in reflector and spaceframe shape are made using a reflector spaceframe support constructed as shown schematically in
The two out-of-plane back struts 12 and 13 have first ends at the frame corners 121 and 131 and second ends at the back central node 10, and a further two out-of-plane back struts 22 and 23 that have first ends at the frame corners 221 and 231 and second ends at the node 20.
The shape of the spaceframe structure 100 and the attached reflector 2 is altered by extending or retracting the positions of the nodes 10 and 20 in the direction of the node 4, using mechanical links to the cross-axis motion, as described below. As indicated by the short arrows in
In some embodiments of the invention, the shape of the reflector when no forces are applied will be chosen to be that which minimizes the force magnitude (positive or negative) acting on nodes 10 and 20 when covering the full range of shape change. This shape will be the toroid for which the sagittal curvature change (as shown in
Two different embodiments integrate the spaceframe of
1. Embodiment 1, in which the target and cross-axis drives are attached directly to each other in an integrated structure below the reflector spaceframe, and the cam system to move the neighboring nodes 10 and 20 employs curved slots through which drive-rollers are rotated directly by the cross-axis motion.
2. Embodiment 2, in which the target axis remains outside the spaceframe structure, separate from the cross-axis drive, which is located within the spaceframe, near node 4 and directly behind the reflector. The cam system is linear, using a rack and pinion driven by the cross-axis motor. Two struts that move parallel to the surface normal 51 carry the motions down to the nodes 10 and 20.
This embodiment is for a heliostat on a target-oriented mount, with the cross-axis motion mechanically linked to provide the required changes in toroidal shape. As shown in
A mechanical linkage 25 to change the shape of the reflector 2 in synchronization with the cross-axis rotation is attached also to the cross-axis drive. Its operation is best understood with reference to the detailed drawing in
Motion of the cam rollers 65 and 66 relative to the nodes 10 and 20 in directions other than that of the normal 51 is prevented by additional rollers 69 and 70 on common shafts 71 and 72 attached in forks to the concentric drive cylinders 67 and constrained to move in straight slots in pairs of plates 57 attached to the L structure 60, on either side of the fixed cam wheel 61.
The cam rollers 65 and 66 shown in
This embodiment is, as is the previous embodiment, for a heliostat on a target-oriented mount, with the cross-axis motion mechanically linked to provide the required changes in toroidal shape. But here, as shown in
Finite Element Model of a Steel Spaceframe with Single Glass Sheet Reflector
In this embodiment of the invention, the reflector 2 is made from a single, flat, back-silvered sheet of low-iron float glass of specific dimensions. The accuracy of setting initial mid-range toroidal surfaces (for 60° angle of incidence) is explored for two different focal lengths. In addition, the accuracy is modeled over the range of toroidal shapes (for angles of incidence of 0 and 70 degrees) that can be obtained using an adjustable shape steel spaceframe. The spaceframe is of the type shown in
The modeled rectangular reflector 2 attached to the front frame 3 measures 2.4 m×3.3 m, giving 8 m2 in area, consistent with the largest size float glass sheets commonly available, conveniently shipped by container. The sheet is 3.2 mm thick and weighs 65 kg. We model the shaped reflectors for two cases: the shorter for slant range distance (focal length), the shortest envisaged, 64 m, and the longer of 130 m. The supporting steel frame was modeled with a spaceframe structure of struts as in
The capability of the dimensioned spaceframe reflector first to induce in the originally flat sheet of glass the base toroidal shape for 60° AOI, and then to change it over the range of angles of incidence from 0° to 70°, is shown in
As can be seen, the contours of the induced shapes and their changes are close to the ideal. The base toroids for 60° AOI show errors relative to the ideal toroidal shapes, of 0.23 mrad rms for focal length 130 m and 0.44 mrad rms for 64 m. Then with the support frame actuated for 0° AOI, the errors are 0.35 and 0.71 mrad respectively. At the most extreme bending, for 70° AOI, they are 0.58 and 1.13 mrad respectively.
The model shows that the largest tensile stresses induced by the bending of the originally flat glass sheet can be as high as 1600 psi in small areas under the modeled support pads. In mass production, the bending forces will be applied by adhesive along the full length of the frame struts, for less localized and lower stresses. Effective stress over whole mirror area is ˜650 psi, a safe level.
In order to calculate the solar concentration that may be achieved in practice using heliostat with a reflector according to some embodiments of this invention, the broadening of the solar disc image it forms must be accounted for. This is done for a surface with given slope errors by calculating first the image that would be formed by rays reflected from a point source (such as a star). This image is then convolved with the known distribution of light across the disc of the sun.
The result of the errors in reflector shape to cause spillage at the receiver is estimated for quantitatively the case in which the entrance to the receiver is circular, with diameter equal to that of the ideal solar disc image at the chosen focal distance. This diameter is shown by the white circles in all of
In an embodiment of this invention with closed loop tracking to maintain accurate orientation of a field of heliostats, each heliostat reflector is equipped to measure its orientation using a rigidly attached camera with a fisheye lens. The camera records images including the sun and one or more tower-mounted light sources. The sources are located within or adjacent to the heliostat field, positioned so that each heliostat sees at least one light source at all times, in addition to the sun. Any error in orientation is computed from images showing both sources and used to make pointing correction.
The light sources 90 of this invention are made bright enough relative to the sun so that a single camera exposure short enough to capture a non-saturated solar disc image will also record a source image with good signal to noise ratio, and resolved over several camera image pixels, so that its centroid may be computed to sub-pixel level. The relative brightness of the sources to the sun is increased by a factor of 10 or more compared to a source with the same emission spectrum as the sun, such as reflected sunlight, by use of LEDs 92 that emit light in a narrow spectral range and using a narrow band filter 56 that transmits light only in the same narrow spectral range as the LED.
In an embodiment, the glass filter is Hoya type U340A that absorbs visible light except for a 40 nm wide band centered at 720 nm wavelength. The LED is chosen to have matching wavelength and spectral width. In a further step to obtain maximum brightness, the LEDs may be operated at higher-than-normal power in pulsed mode with low duty cycle, with a short camera exposure synchronized with the emission pulse.
The camera 53 may view the sun through the thin reflective silver film deposited on the back of the glass 55, which remains a continuous sheet, with no aperture cut through it. The usual protective copper and paint layers will in this case be removed, or not deposited in the first place. The transmission of the 100 nm thick silver film is in the range 0.1-1% for visible light, sufficient for the camera to image the sun. Alternatively, the silver may be removed from the camera viewing region, and a neutral density filter be used in addition to the glass filter 56.
Solar Concentrator of High Power and High Concentration with Heliostats Forming Solar Disc Images at the Entrances of CPCs
In this embodiment of the invention, sunlight from heliostats that reflect sunlight to form disc images of the sun is further concentrated by use of a compound parabolic concentrator (CPC) as illustrated in
In some embodiments of this invention, one or a multiplicity of CPCs powering a reactor receiver are set atop a tower and are aimed toward heliostats located on the ground within the elliptical section of the CPC cone.
As a specific quantitative example, an analysis of the efficiency of delivery of concentrated sunlight is made here for the case of heliostats of the size analyzed above, each using a single 8.05 m2 glass sheet. The CPC, with entrance cone of 23 degrees and entrance diameter 70 equal to 1 m, is placed on a 40 m high tower and aimed down at 30° below horizontal. Heliostats are located at radial distance 89 no larger than 100 m, for a maximum slant range (and heliostat focal length) of 108 m. At this distance, a perfectly formed disc image of the sun (9.2 mrad diameter) is 0.99 m, matched to the CPC entrance aperture 70.
The efficiency of delivery of sunlight to the receiver depends in part on geometric losses incurred by: shadowing by neighbor heliostats; reduction of the projected mirror area in proportion to the cosine of the angle of incidence; and blocking of the reflected light by neighbors. To estimate these losses, a 3-dimensional geometric model of the field was made, and views such as those shown in
A practical embodiment of this invention will use not just one such elliptical field of heliostats powering one CPC on a tower, but a number of CPCs on a single tower, oriented to face out in different directions to view adjacent elliptical fields.
The geometric shadowing, cosine loss and blocking losses depend on latitude and time of day and year. Table 1 gives the area of sunlight reflected to each CPC, with the above geometric losses taken into account. The calculation is for this embodiment at a specific latitude, 32°, and a specific representative day, namely the equinox. The hour (relative to solar noon) is given in column 1, while the remaining columns give the area of sunlight receiver by each CPC, starting with CPC 1 powered by field 161 in
To estimate the power delivered to such a reactor, losses other than geometric are included. The reflectivity of the heliostat and CPC mirrors are both taken to be 90%. The spillage loss at the CPC entrance apertures, averaged over heliostats at all radii, is taken to be 10%, which includes the effect of both disc image blurring and heliostat orientation errors, based on the analysis in paragraph 77 above. Losses at the CPC vacuum windows are taken to be also 10%. On this basis, the effective area of sunlight delivered into the reactor will be reduced by a factor 0.66. The concentration at the entrance to the 5 CPCs, with total area 3.93 m2, thus averages 516 suns at noon, and remains above 433 suns over 8 hours, from 8 am until 4 pm. With these estimates, and assuming a minimum direct solar flux at normal incidence of 700W/m2 at 8 am and 4 pm, when the solar elevation is 25 degrees, the power delivered will remain above 1.3 MW for eight hours.
Given CPCs designed for 10 times concentration, i.e. with exit apertures of 316 mm diameter, the concentration of sunlight entering the reactor will remain above 4,330 suns for the 8-hour interval. This exceeds the >3,500 suns target projected for hydrogen generation by the cerium oxide redox reaction (Brendelberger reference). Thus, efficient thermal production of hydrogen should be possible.
High power solar concentrator with disc-imaging heliostats in a circular field, for high concentration at a central cylindrical receiver. (From provisional application)
The potential for the heliostats according to some embodiments of this invention to obtain very high concentration when implemented in a concentrating solar power array is further illustrated in this embodiment, in which a circular field of disc-imaging heliostats is set about a central cylindrical receiver.
Taking the heliostats to be oriented to reflect sunlight to a central cylindrical receiver at 50 m elevation,
The ideally focused disc images, from the outer heliostats at 130 m slant range, are 1.20 m in diameter. The cylindrical receiver is sized with height and diameter of 1.4 m, with a surface area of 6.2 m2. This is sufficient to reduce spillage such that over 90% of the reflected light averaged over the full field is received. With spillage loss from imperfect disc imaging thus at 10%, and heliostat reflectivity at 90%, the average concentration of sunlight for solar elevations of 60 degrees and 40 degrees will be 1,840× and 1,750× respectively. At a solar elevation of 20 degrees, the total area of sunlight available to the annular field is 13,750 m2. Analysis similar to that of
Through the day, while the sun is over 20° elevation, this concentrating field will maintain a concentration at over 1000 suns. The delivered power, including the losses from spillage and reflectivity, referenced to a solar DNI flux of 1000 W/m2, will range up to 11.4 MW for 60° elevation.
An embodiment of this invention further increases the concentration at a cylindrical receiver. A novel and simple flat circular reflector “beams down” the half of the light that, for a conventional cylindrical receiver, would illuminate the upper half of the cylinder. The height of the cylinder is then halved and the flux, now all on what was the lower half is doubled, as is the concentration.
While various embodiments of the present invention have been described above, it should be understood that they have been presented by way of example only, and not limitation. Thus, the breadth and scope of the present invention should not be limited by any of the above-described illustrative embodiments, but should instead be defined only in accordance with the following claims and their equivalents.
The embodiments illustrated and discussed in this specification are intended only to teach those skilled in the art how to make and use the invention. In describing embodiments of the disclosure, specific terminology is employed for the sake of clarity. However, the disclosure is not intended to be limited to the specific terminology so selected. The above-described embodiments of the disclosure may be modified or varied, without departing from the invention, as appreciated by those skilled in the art in light of the above teachings. It is therefore to be understood that, within the scope of the claims and their equivalents, the invention may be practiced otherwise than as specifically described. For example, it is to be understood that the present disclosure contemplates that, to the extent possible, one or more features of any embodiment can be combined with one or more features of any other embodiment.
This application claims priority to U.S. Provisional Application No. 63/321,527 filed Mar. 18, 2022; the entire content of which is hereby incorporated by reference.
This invention was made with government support under Grant No. DE-EE0010246 awarded by Department of Energy. The government has certain rights in the invention.
Filing Document | Filing Date | Country | Kind |
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PCT/US2023/015674 | 3/20/2023 | WO |
Number | Date | Country | |
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63321527 | Mar 2022 | US |