Aspects of the present disclosure relates to liquid and gas systems and methods that generate ultra-fine bubbles and mix them into a highly concentrated aqueous solution.
Bubbles contained in a liquid are visible to the eyes when the bubble sizes are range from 6 to 29 microns. We can see bubbles in carbonated drinks or those coming from the air diffuser in a water tank. Bubbles with the size of a few millimeters in diameter show visible surfacing action in a liquid, and the presence of fine bubbles of dozens of microns in diameter can be confirmed with white turbidity in a liquid, because these bubbles are scattering substances. Bubbles in diameter smaller than the wavelength of light are called ultra-fine bubbles, and they are too small to see. Ultra-fine bubbles have several unique properties including long lifetime in liquid owing to their negatively charged surface, and high gas solubility into the liquid owing to their high internal pressure. These special features of ultra-fine bubbles have attracted attention from many industries such as food, cosmetics, chemical, medical, semi-conductor, soil and water remediation, aquaculture and agriculture.
A mixing apparatus for generating and mixing gas bubbles, including for example, ultra-fine bubbles, into an aqueous solution includes a structure defining an interior fluid-flow chamber extending along a longitudinal axis between a liquid input end of the mixing apparatus and a liquid output end of the apparatus. The structure is characterized by a gas injection portion and a mixing vane portion. The gas injection portion, which is located downstream from the liquid input end and upstream from the liquid output end, defines a first region of the interior fluid-flow chamber and a gas injection lumen that is surrounded by the interior fluid-flow chamber. The first region of the interior fluid-flow chamber includes multiple fluid-flow lumens that guide fluid in the downstream direction toward the mixing vane portion. The gas injection lumen, which extends along a length of the gas injection portion, receives gas from a gas supply that is coupled to the gas injection portion and is configured to inject the received gas from the interior of the gas injection lumen into the surrounding interior fluid-flow chamber. The mixing vane portion extends in the downstream direction from the gas injection portion and defines a second region of the interior fluid-flow chamber that is contiguous with the first region of the fluid-flow chamber. The second region of the interior fluid-flow chamber includes multiple fluid-flow lumens, each twisting around the longitudinal axis to form a helical fluid-flow lumen that guides fluid in the downstream direction toward the liquid output end of the mixing apparatus.
The detailed description set forth below in connection with the appended drawings is intended as a description of various configurations and is not intended to represent the only configurations in which the concepts described herein may be practiced. The detailed description includes specific details for the purpose of providing a thorough understanding of various concepts. However, it will be apparent to those skilled in the art that these concepts may be practiced without these specific details.
With reference to
Moving from left to right in
Continuing in the downstream direction, the mixing vane component 102 includes: a) an upstream end 144 where the mixing vane component couples with the gas injection component 104, b) a helical region 146, and c) the liquid output end 138 through which liquid/gas mixture exist the mixing apparatus 100. The helical region 146 defines multiple fluid-flow lumens, each lumen twisting around the longitudinal axis 142 to form a helical fluid-flow lumen that guides fluid in the downstream direction toward the liquid output end 138 of the mixing apparatus 100. The helical fluid-path lumens form a second region of the interior fluid-flow chamber of the mixing apparatus 100. The helical fluid-path lumens of the second region of the fluid-flow chamber are equal in number with the C-shaped fluid path lumens of the first region of the fluid-flow chamber. For example, the mixing apparatus 100 of
In one configuration, each of the mixing vane component 102 and a gas injection component 104 may be separately manufactured as a single-piece, unitary component using 3D printing. The components 102, 104 may be 3D printed using a plastic or a metallic material. Regarding plastics, the components may be 3D printed, for example, in nylon or a polycarbonate material depending on which material better stands up to the type of gas that will be injected into the mixing apparatus 100. For example, polycarbonate is rated for ozone, while nylon is not. With respect to metallic materials, the components may be 3D printed, for example, in stainless steel.
Once the components 102, 104 are 3D printed, they are assembled with a gas inlet structure 114 and an O-ring 116 and secured together using various fastening components, e.g., nuts, bolts, washers, and a silicon sealant. The gas inlet structure 114 (also referred to herein as a muffler or a diffuser) provides a gas injection interface between gas received through the inlet portion 112 of the gas injection component 104 and the interior fluid-flow chamber of the mixing apparatus 100. The O-ring 116 fits within an annular groove 122 (visible in
In an alternative configuration, the mixing apparatus 100 may be 3D printed in its entirety as a single unitary piece by 3D printing, instead of separately 3D printing a mixing vane component 102 and a gas injection component 104 and assembling them. In this case, there is no O-ring 116 and manufacture of the gas inlet structure 114 is integrated with the 3D printing process. For example, as described further below, the gas inlet structure 114 may be formed as an internal structure of a gas injection portion of the mixing apparatus 100.
In other configurations, a mixing apparatus 100 may be manufactured using injection molding techniques. For example, separate molds may be used to form different portions of the mixing apparatus 100 relative to the longitudinal axis 142 of the apparatus. In one implementation, each molded portion corresponds one half of the mixing apparatus 100 along the longitudinal axis 142. Once molded, the two halves may be bonded together to form a single assembly of the mixing apparatus 100.
In any of the foregoing manufacturing configurations, after manufacture or manufacture and assembly, the mixing apparatus 100 may be encased in a sleeve. This may be accomplished by placing the mixing apparatus 100 in a heat-shrink tube; and then heating the tube to shrink into contact with the outer surface of the apparatus to thereby provide an impenetrable sleeve over the entire apparatus.
With reference to
The base 222 of the conical structure 202 transitions to the hollow cylinder 204. The interior of the hollow cylinder 204 defines a first portion 206 of the gas injection lumen that extends along the length of the cylinder. Extending from the outer surface of the hollow cylinder 204 are two wing structures 208a, 208b positioned on opposite sides of the cylinder. The wing structures 208a, 208b extend to and merge with an interior surface 210 (visible in
The space between the outer surfaces of the conical structure 202 and the hollow cylinder 204 and the interior surface 210 of the outer wall 224 of the gas injection component 104 define the first region of the interior fluid-flow chamber. With reference to
With reference to
A second section 604 of the first region of the interior fluid-flow chamber extends between point “b” and point “c” as shown in
With reference to
In one configuration, the gas inlet structure 114 comprises a threaded base that screws into the first portion 206 of the gas injection lumen and a cap structure (also referred to as a muffler or a diffuser) that couples with the threaded base. The hollow interior 214 of the gas inlet structure 114 defines a second portion of the gas injection lumen. The cap structure includes a cylindrical sidewall and an end cap, each having a porous structure that permits injected gas to pass through. Alternatively, the gas inlet structure 114 may be configured as a simple Pitot type tube with holes passing through its sidewall and end cap. Configured as such the porous cap or Pitot tube allows for the injection of gas in multiple directions relative to the longitudinal axis 142 of the mixing apparatus 100. For example, with reference to
In another configuration, where the mixing apparatus 100 is manufactured as a single unitary structure, a separate gas inlet structure 114 is not present. Instead, the gas inlet structure 114 is formed as part of the downstream region of the hollow cylinder 204. For example, the downstream region of the hollow cylinder 204 may comprise a reduced diameter portion that extends beyond the downstream end 124 of the gas injection component, which portion is formed to include a number of pores through which injected gas may pass in multiple directions relative to the longitudinal axis 142 of the mixing apparatus 100, as described above.
The gas injection lumen of the gas injection component 104 includes a third portion 216 that extends between the base of the inlet portion 112 to the first portion 216 of the gas injection lumen. Extending in this manner, the third portion 216 passes through the outer wall 224 of the gas injection component 104, through a wing structure 208a, and through the wall of the cylinder structure 204 before it merges with the first portion 206 of the gas injection lumen. The first, second and third portions 206, 214, 216 of the gas injection lumen may have any of a number of cross-section shapes. In one configuration, the first portion 206 and second portion 214 are cylindrical, while the third portion 216 is rectangular.
In operation, as shown in
A method of mixing gas and liquid may include passing liquid through a venturi to create a low-pressure zone, thereby exposing a supply of gas to the low-pressure zone adjacent the venturi. This may allow low pressure suction to extract gas from the gas supply and expose the gas to more liquid before entering the mixing vane component 102. With reference to
With reference to
As described above, the gas inlet structure 114 through which gas exits may be configured to allow for the injection of gas in multiple directions relative to the longitudinal axis 142 of the mixing apparatus 100, including radially outward relative to the longitudinal axis and downstream, in the direction of the longitudinal axis. Configured in this manner, the mixing apparatus 100 injects gas from a location close to the longitudinal axis 142, into fluid that surrounds the location, as the fluid flows past the location. In other words, the mixing apparatus is configured to inject gas into liquid from the inside out. This is distinct from other mixing apparatuses that are configured to inject gas into liquid from the outside in, for example, through an annular structure surrounding a fluid-flow path, such as disclosed in U.S. Pat. No. 5,935,490.
With reference to
In one configuration, the mixing vane component 102 may include a series of individual helical vane sections, of equal or different length, separated by a distance of “d” that is void of any helical structure.
With reference to
The structure may be formed of separately manufactured components that are assembled. For example, the gas injection portion may be in the form of a gas injection component 104 and the mixing vane portion may be in the form of a mixing vane component 102. Alternatively, the structure may be manufactured as a single component, portions of which respectively define a gas injection portion and a mixing vane portion.
The gas injection portion includes an outer wall 224 and a geometric structure 202, e.g., a cone, surrounded by the outer wall. The geometric structure has a tip 220 facing the liquid input end 134 and a base 222 facing the liquid output end 138. The gas injection portion also includes a hollow structure 204, e.g., a cylinder, that is also surrounded by the outer wall 224. The hollow structure 204 extends in the downstream direction from the base 222 of the geometric structure and has a hollow interior that defines a first portion 206 of the gas injection lumen. The outer wall 224 has an interior surface 210 and each of the geometric structure 202 and the hollow structure 204 has an outer surface spaced apart from the interior surface 210. The space between the interior surface 210 and the outer surfaces of the geometric structure 202 and the hollow structure 204 defines the first region of the interior fluid-flow chamber. The space between the interior surface and the outer surfaces changes in dimension along the length of the gas injection portion. The change in dimension creates a venturi that creates a low-pressure zone for liquid that may allow low pressure suction to extract gas from the gas injection lumen 206, 214, 216 and expose the gas to more liquid before entering the mixing vane component 102.
The hollow structure 204 has a gas inlet structure 114 that extends from a downstream region of the hollow structure. The gas inlet structure 114 has a hollow interior that defines a second portion 214 of the gas injection lumen. At least part of the second portion 214 of the gas injection lumen is configured to inject gas into the surrounding interior fluid-flow chamber in at least one of a plurality of directions relative to the longitudinal axis 142. For example, the gas inlet structure 114 may inject gas radially outward relative to the longitudinal axis 142 and/or downstream, in the direction of the longitudinal axis. In one configuration, the gas inlet structure 114 includes a hollow cap structure having at least one of a porous cylindrical sidewall and a porous end cap through which gas may injected into the surrounding interior fluid-flow chamber. In another configuration, the gas inlet structure is a reduced diameter portion of the downstream region of the hollow structure 204 that is formed to include a number of pores through which gas may injected into the surrounding interior fluid-flow chamber.
The first region of the interior fluid-flow chamber defined by the gas injection portion may include a plurality of separate fluid-path lumens 212a, 212b. In one configuration, the plurality of separate fluid-path lumens 212a, 212b are partially defined by a pair of wing structures 208a, 208b that extend between the outer surface of the hollow structure 204 and the interior surface 210 of the outer wall 224. One of the wing structures 208a, 208b may define a third portion 216 of the gas injection lumen. For example, the gas injection portion may include an inlet portion 112 having a base, and the third portion 216 of the gas injection lumen may extend from the base of the inlet portion 112 through one of the pair of wing structures 208a, 208b and into the first portion 206 of the gas injection lumen defined by the hollow structure 204.
The plurality of separate fluid-path lumens 212a, 212b of the first region of the interior fluid-flow chamber are non-helical lumens. For example, the gas injection portion may define a pair of fluid-path lumens 212a, 212b having a C-shaped cross section that extend linearly along part of the gas injection portion. At the junction of the gas injection portion and the mixing vane portion, each of the separate non-helical fluid-path lumens 212a, 212b transition to a helical lumen of the second region of the interior fluid-flow chamber defined by the mixing vane portion. The mixing vane portion may include one helical vane region 802 or a plurality of helical vane regions 802, 804 arranged adjacently along the length of the mixing vane portion. In configurations having multiple helical vane regions, adjacent helical vane regions are separated by void regions 806 that define a tubular lumen.
As previously mentioned, the mixing apparatus 100 thus described may be manufactured using 3D printing technology. In one configuration, each of the mixing vane component 102 and a gas injection component 104 may be separately manufactured as a single-piece, unitary component using 3D printing, and then assemble to form a mixing apparatus 100. In an alternative configuration, the mixing apparatus 100 may be manufactured in its entirety as a single unitary piece by 3D printing.
In either case, it has been shown that a 3D printed mixing vane component 102 results in much higher gas to liquid transfer efficiencies due to the exactness of 3D printing compared to heating and bending plastics (e.g., PVC plastics). The mixing vane component 102 and a gas injection component 104 can be printed using nylon, PVC, and/or other compatible filament with high tensile strength to withstand the force of water flowing at high speeds. The selected 3D print material should also be compatible with the chosen gas to be injected.
Also, as previously described, the mixing apparatus 100 may be manufacturing using techniques other than 3D printing. For example, the mixing apparatus 100 may be manufactured using a number of injection molds to form separate portions of the assembly, which portions are then joined together to form a mixing apparatus 100. The portions may be formed of plastic and bonded together, or metal, e.g., coarse cast iron or aluminum, and welded together.
The liquid/gas mixing apparatus may be manufactured in ½″, ¾″ and 1½″ sizes for use in varying systems, where the size corresponds to the interior diameter of the apparatus at the liquid input end 134 and the liquid output end 138. Larger liquid flows may be accommodated by an array of liquid/gas mixing apparatuses enclosed in a larger pipe. In this configuration, a portion of a large liquid flow is divided into separate portions, each of which passes through a liquid/gas mixing apparatus. Testing of a ½″ size ultra-fine bubble generating liquid/gas mixing apparatus configured as disclosed herein, has generated ultra-fine bubbles having a size ˜100 nanometers and concentration of 265,000,000 bubbles per ml, as measured using a NanoSight NS300 particle analyzer.
The foregoing description is provided to enable any person skilled in the art to practice the various aspects described herein. Various modifications to these aspects will be readily apparent to those skilled in the art, and the generic principles defined herein may be applied to other aspects. Thus, the claims are not intended to be limited to the aspects shown herein, but instead are to be accorded the full scope consistent with the claim language. All structural and functional equivalents to the elements of the various aspects described throughout this disclosure that are known or later come to be known to those of ordinary skill in the art are expressly incorporated herein by reference and are intended to be encompassed by the claims.
This application is a U.S. national phase application of and claims priority to International Application No. PCT/US2018/027187, entitled “Apparatus and Method for Generating and Mixing Ultra-Fine Gas Bubbles Into a High Gas Concentration Aqueous Solution” and filed on Apr. 11, 2018, which claims the benefit of U.S. Provisional Application Ser. No. 62/484,569, entitled “Apparatus and Method for Generating and Mixing Ultra-Fine Gas Bubbles into a High Gas Concentration Aqueous Solution” and filed on Apr. 12, 2017, the entire disclosures of which are expressly incorporated by reference herein.
Filing Document | Filing Date | Country | Kind |
---|---|---|---|
PCT/US2018/027187 | 4/11/2018 | WO | 00 |
Publishing Document | Publishing Date | Country | Kind |
---|---|---|---|
WO2018/191431 | 10/18/2018 | WO | A |
Number | Name | Date | Kind |
---|---|---|---|
2601018 | Heyl et al. | Jun 1952 | A |
3256802 | Karr | Jun 1966 | A |
3452966 | Smolski | Jul 1969 | A |
3545731 | Mcmanus | Dec 1970 | A |
3664638 | Grout et al. | May 1972 | A |
3761066 | Wheeler | Sep 1973 | A |
3852384 | Bearden | Dec 1974 | A |
3953002 | England, Jr. et al. | Apr 1976 | A |
4088449 | Smith | May 1978 | A |
4127332 | Thiruvengadam et al. | Nov 1978 | A |
4202635 | Hendrickson | May 1980 | A |
4408893 | Rice, III | Oct 1983 | A |
4466741 | Kojima | Aug 1984 | A |
4491551 | Johnson | Jan 1985 | A |
4674888 | Carlson | Jun 1987 | A |
4721562 | Barnscheidt et al. | Jan 1988 | A |
4749527 | Rasmusen | Jun 1988 | A |
4753535 | King | Jun 1988 | A |
4761077 | Werner | Aug 1988 | A |
4767026 | Keller et al. | Aug 1988 | A |
4840753 | Jungmann et al. | Jun 1989 | A |
4872833 | Kramer | Oct 1989 | A |
4911836 | Haggerty | Mar 1990 | A |
5073309 | Bousquet et al. | Dec 1991 | A |
5091118 | Burgher | Feb 1992 | A |
5498078 | Keller | Mar 1996 | A |
5814222 | Zelenak et al. | Sep 1998 | A |
5842600 | Singleterry et al. | Dec 1998 | A |
5885467 | Zelenak et al. | Mar 1999 | A |
5904851 | Taylor et al. | May 1999 | A |
5935490 | Archbold et al. | Aug 1999 | A |
6039884 | Burris et al. | Mar 2000 | A |
6142457 | Holtan et al. | Nov 2000 | A |
6322055 | Speece | Nov 2001 | B1 |
6467949 | Reeder et al. | Oct 2002 | B1 |
6474627 | Speece | Nov 2002 | B2 |
6485003 | Speece | Nov 2002 | B2 |
6623635 | Barnes | Sep 2003 | B2 |
6668556 | Speece | Dec 2003 | B2 |
6848258 | Speece | Feb 2005 | B1 |
6923568 | Wilmer et al. | Aug 2005 | B2 |
7103450 | Kubiak et al. | Sep 2006 | B2 |
7320749 | Speece et al. | Jan 2008 | B2 |
RE40407 | Natarius | Jul 2008 | E |
7534351 | Chiba | May 2009 | B2 |
7566397 | Speece | Jul 2009 | B2 |
7772376 | Payne et al. | Aug 2010 | B2 |
7814745 | Levin et al. | Oct 2010 | B2 |
7905653 | Wilmer et al. | Mar 2011 | B2 |
7975991 | Kojima | Jul 2011 | B2 |
8177197 | Ergican | May 2012 | B1 |
8196906 | Benton et al. | Jun 2012 | B2 |
8205541 | Barberio et al. | Jun 2012 | B2 |
8272777 | Kohrs et al. | Sep 2012 | B2 |
8286951 | Dart et al. | Oct 2012 | B2 |
8371114 | Hayashi et al. | Feb 2013 | B2 |
8567767 | Fantappie | Oct 2013 | B2 |
8580125 | Clidence et al. | Nov 2013 | B2 |
10052596 | Richardson | Aug 2018 | B2 |
10953375 | Blevins | Mar 2021 | B2 |
20010003291 | Uematsu | Jun 2001 | A1 |
20010033526 | Illy et al. | Oct 2001 | A1 |
20010042708 | Barnes | Nov 2001 | A1 |
20020066970 | Speece | Jun 2002 | A1 |
20030196437 | Speece | Oct 2003 | A1 |
20040112404 | Doke et al. | Jun 2004 | A1 |
20040124136 | Bak | Jul 2004 | A1 |
20050155922 | Tormaschy et al. | Jul 2005 | A1 |
20050173326 | Speece | Aug 2005 | A1 |
20050263914 | Kojima | Dec 2005 | A1 |
20060120214 | Raftis | Jun 2006 | A1 |
20060231500 | Speece et al. | Oct 2006 | A1 |
20080062813 | Wilmer et al. | Mar 2008 | A1 |
20080223782 | Chiba | Sep 2008 | A1 |
20080237140 | Liverud et al. | Oct 2008 | A1 |
20090034361 | Trang et al. | Feb 2009 | A1 |
20090308472 | Harman | Dec 2009 | A1 |
20100011967 | Barberio et al. | Jan 2010 | A1 |
20100025867 | Benton et al. | Feb 2010 | A1 |
20100031825 | Kemp | Feb 2010 | A1 |
20100208547 | Kiel et al. | Aug 2010 | A1 |
20110024362 | Clidence et al. | Feb 2011 | A1 |
20110153084 | Wilmer et al. | Jun 2011 | A1 |
20120032358 | Smith | Feb 2012 | A1 |
20120160333 | West | Jun 2012 | A1 |
20120195994 | El-Siblani et al. | Aug 2012 | A1 |
20130215710 | Hepperle et al. | Aug 2013 | A1 |
20150202579 | Richardson | Jul 2015 | A1 |
20150352503 | Lai | Dec 2015 | A1 |
20160136591 | Simmons | May 2016 | A1 |
20160339399 | Goi | Nov 2016 | A1 |
20160346758 | Kress et al. | Dec 2016 | A1 |
20170259219 | Russell et al. | Sep 2017 | A1 |
20170291151 | Berglund | Oct 2017 | A1 |
20200045997 | Blevins | Feb 2020 | A1 |
20200390127 | Giardino | Dec 2020 | A1 |
Number | Date | Country |
---|---|---|
87201156 | Dec 1987 | CN |
1254179 | Nov 1971 | GB |
2350069 | Nov 2000 | GB |
2350069 | Apr 2003 | GB |
205032089 | Feb 2016 | GN |
199512452 | May 1995 | WO |
2013050764 | Apr 2013 | WO |
2013050764 | Apr 2013 | WO |
2018191431 | Oct 2018 | WO |
Entry |
---|
European Patent Appln. No. 18783887. Extended Search Report (dated Dec. 10, 2020). |
CL201902890. Office Action (dated Aug. 10, 2020). |
PCT/US2014/070813. Int'l Search Report & Written Opinion (dated Apr. 28, 2015). |
PCT/US2018/027187. Int'l Search Report & Written Opinion (dated Aug. 9, 2018). |
PCT/US2019/034749. Int'l Search Report & Written Opinion (dated Aug. 15, 2019). |
CL201902890. Office Action—Search Report (dated Jan. 6, 2021). |
Number | Date | Country | |
---|---|---|---|
20200045997 A1 | Feb 2020 | US |
Number | Date | Country | |
---|---|---|---|
62484569 | Apr 2017 | US |