1. Field of the Invention
The present invention generally relates to electrochemical systems, and more particularly, to an apparatus and method for managing fluids in a fuel cell stack.
2. Description of the Related Art
Electrochemical fuel cells convert reactants, namely fuel and oxidant fluid streams, to generate electric power and reaction products. Electrochemical fuel cells generally employ an electrolyte disposed between two electrodes, namely a cathode and an anode. An electrocatalyst, disposed at the interfaces between the electrolyte and the electrodes, typically promotes the desired electrochemical reactions at the electrodes. The location of the electrocatalyst generally defines the electrochemically active area.
One type of electrochemical fuel cell is a proton exchange membrane (PEM) fuel cell 10 shown in
As shown in
Fluid reactant streams are supplied to and exhausted from internal manifolds and passages in the system 60 via inlet and outlet ports 76 in the end plate assemblies 62, 64. Aligned internal reactant manifold openings 78, 80 in the MEAs 68 and flow field plates 70, respectively, form internal reactant manifolds extending through the system 60. As one of ordinary skill in the art will appreciate, in other representative electrochemical fuel cell stacks, reactant manifold openings may instead be positioned to form edge or external reactant manifolds.
A perimeter seal 82 can be provided around an outer edge of both sides of the MEA 68. Furthermore manifold seals 84 can circumscribe the internal reactant manifold openings 78 on both sides of the MEA 68. When the system 60 is secured in its assembled, compressed state, the seals 82, 84 cooperate with the adjacent pair of plates 70 to fluidly isolate fuel and oxidant reactant streams in internal reactant manifolds and passages, thereby isolating one reactant stream from the other and preventing the streams from leaking from the system 60.
As illustrated in
Instead of two plates 70a, 70b, one plate 70 unitarily formed or alternatively fabricated from two half plates 70a, 70b can be positioned between the cells 66, forming bipolar plates as discussed above.
The flow field plates 70 also have a plurality of typically parallel flow field channels 96 formed in the non-active surface thereof. The channels 96 on adjoining pairs of plates 70 cooperate to form coolant flow fields 98 extending laterally between the opposing non-active surfaces of the adjacent fuel cells 66 of the system 60 (generally perpendicular to the stacking direction). A coolant stream, such as air or other cooling media may flow through these flow fields 98 to remove heat generated by exothermic electrochemical reactions, which are induced inside the fuel cell system 60.
In the conventional fuel cell system 60, water typically accumulates in the flow field channels 86, back-feed channels 90 and back-feed ports 92. As gas, such as reactants and/or oxidants, is injected into the flow field channels 86, the gas pressure and movement may flush some of the accumulated water through the above-described outlets.
If a relatively large amount of water collects in a localized region of the flow field channels 86, back-feed channels 90 and/or back-feed port 92, the water may block the channels 86, 90 or port 92. If the accumulated water blocks the channels 86, 90 or port 92, gas flow can be adversely affected, and in extreme cases, cease. Consequently, as the reactants and/or oxidants in the gas residing in the blocked channels 86, 90 or port 92 are depleted, electrical output and fuel efficiency of the fuel cell decreases.
Such water accumulation can also lead to ice formation before and during freeze startups. Although purging the water from the system is one option for preventing water accumulation, regions of low purge velocity tend to retain water during a purge. Furthermore, due to the large ratio of capillary forces from the back-feed ports 92 to the reactant manifold openings 78, water tends to wick back into the exit of the back-feed port 92 after the purge. Therefore, after the purge, regions of low purge velocity in the reactant manifold openings 78 typically store relatively large amounts of water, which may wick or otherwise move back into the back-feed channels 90 and/or back-feed port 92. This water freezes under appropriate environmental conditions, resulting in ice blockage. These blockages typically prevent efficient reactant access and flow to the flow field channels 86 and may cause uneven flow sharing and fuel starvation in the fuel cell system 60.
In addition to purging the water from the system 60, other methods of mitigating ice blockages include operating the fuel cell system 60 extremely dry; however, even then, some ice blockage occurs because it is nearly impossible to completely prevent water from exiting the fuel cells 66. Furthermore, operating fuel cell systems in extremely dry conditions typically impedes performance and reduces the fatigue life of the system 60.
Those of ordinary skill in the art will appreciate that other configurations for the reactant supply manifolds and back-feed channels and ports exist, nearly all of which suffer from the above obstacles. For example,
Accordingly, there is a need for an apparatus and method for managing fluid flow in a fuel cell stack that substantially prevents water retention and ice-blockage formation in the fuel cell stack and that is inexpensive, space conserving and easy to implement.
According to one embodiment, a flow field plate assembly for use in a fuel cell stack having a plurality of fuel cells comprising a membrane electrode assembly (MEA), comprises a first flow field plate positionable on an anode side of the MEA of a first fuel cell, at least a portion of a first side of the first flow field plate having a reactant manifold opening and at least one reactant flow field channel adapted to direct a fuel to at least a portion of an anode electrode layer of the MEA, a second flow field plate positionable on a cathode side of the MEA of a second fuel cell, adjacent the first fuel cell, at least a portion of a first side of the second flow field plate having a reactant manifold opening and at least one reactant flow field channel adapted to direct an oxygen-containing gas to at least a portion of the cathode electrode layer, and at least one body comprising a porous medium positioned at least partially adjacent at least one of the first and second flow field plates, the porous medium being operable to allow passage of the fuel and the oxygen-containing gas therethrough, and block from passage therethrough, a flow of liquids, when the flow field plate is installed in the fuel cell stack and the fuel cell stack is in operation.
According to another embodiment, a fuel cell stack comprises a plurality of fuel cells, each fuel cell having a membrane electrode assembly (MEA) having an ion-exchange membrane interposed between anode and cathode electrode layers, a first flow field plate positioned on an anode side of the MEA, at least a portion of a first side of the first flow field plate having a reactant manifold opening, at least one reactant flow field channel adapted to direct a fuel toward at least a portion of the anode electrode layer, and means for directing the fuel interposed between the reactant manifold opening and the reactant flow field channel, a second flow field plate positioned on a cathode side of the MEA, at least a portion of a first side of the second flow field plate having a reactant manifold opening, at least one reactant flow field channel adapted to direct an oxygen-containing gas toward at least a portion of the cathode electrode layer, and means for directing the oxygen-containing gas interposed between the reactant manifold opening and the reactant flow field channel, and at least one body comprising a porous medium positioned at least partially adjacent at least one of the first and second flow field plates, the porous medium being operable to allow passage of the fuel and the oxygen-containing gas therethrough, and block from passage therethrough, a flow of liquids.
According to yet another embodiment, a method for managing fluids in a fuel cell stack to prevent liquid collection and ice formation, comprises providing at least one body having a porous medium adjacent a flow field plate of at least one fuel cell of the fuel cell stack between a reactant manifold opening and a reactant flow field channel of the flow field plate to allow passage of at least one of a fuel and an oxygen-containing gas therethrough, and block from passage therethrough, a flow of liquids.
Reference throughout this specification to “one embodiment” or “an embodiment” means that a particular feature, structure or characteristic described in connection with the embodiment is included in at least one embodiment. Thus, the appearances of the phrases “in one embodiment” or “in an embodiment” in various places throughout this specification are not necessarily all referring to the same embodiment. Furthermore, the particular features, structures, or characteristics may be combined in any suitable manner in one or more embodiments.
In another embodiment as shown in
As better shown in
In some embodiments, the porous media 302 may comprise material that in addition to allowing reactant gases through also allows water vapor through, while blocking liquid water and other liquids. In other embodiments, the porous media 302 may comprise material that also blocks water vapor and only allows reactant gases to pass through. Furthermore, the porous media 302 may comprise material that is hydrophobic, such as TEFLON® to further repel water and prevent water collection and ice blockage formation in regions proximate the porous media 302. As one example, the porous media 302 may comprise carbon fiber paper (CFP), such as those available from Toray, for example, TGP-30 (Toray Graphite Paper) CFP material coated with TEFLON®.
As illustrated in
Alternatively, where the coolant is a liquid and the porous medium 302 needs to be installed for manufacturing purposes, the porous medium 302 may be positioned with respect to the coolant manifold opening 320 such that openings 321 are provided between the limbs 310 coincident with the coolant manifold opening 320. Further, the opposing end of the porous medium 302, toward the transition region 322, can comprise open channels (i.e. not include the base 308) so that liquid coolant can reach the coolant flow channels (not shown).
One of ordinary skill in the art having reviewed this disclosure will appreciate that an embodiment of the present invention can be used with any flow field plate, on either the active or the inactive sides of the flow field plates, and/or on an oxidant or a fuel reactant side of the flow field plates to create a gaseous and/or vapor exclusive pathway and ensure continuous reactant and/or coolant flow in a fuel cell stack.
For example,
At least one of the reactant manifold openings 406 may comprise back-feed channels 412 on the inactive side 416, which are in fluid communication with a back-feed port 414, which in turn is in fluid communication with the active side 418 to deliver reactants thereto. When the reactants arrive through the back-feed port 414 to the active side 418, they enter a reactant transition region 424, which guides the reactants to the reactant flow channels 426 to support proper electrochemical reactions. Further, the coolant manifold opening 420 may lead to feed channels 428, directing the coolant to the coolant transition region 422, which leads to coolant flow field channels 430.
The active side 418 and inactive side 416 of the flow field plate 404 may be fitted and/or manufactured with porous media 402. In plates 404 where the porous media 402 are fitted, the porous media 402 can be an insert and extend to at least partially, and in some embodiments fully, occupy a volume of the back-feed channels 412 and or the coolant feed channels 428. Alternatively, when the flow field plates 404 are manufactured with the porous media 402, the porous media 402 may replace the back-feed channels 412 and/or the coolant feed channels 428. The porous media 402 may include a height and/or depth dimension that is substantially equivalent to a height and/or depth dimension of the back-feed channels 412 and/or the coolant feed channels 428.
Another example of a location on the flow field plates 404 in which the porous media 402 may be placed can be adjacent the back-feed port 414 in the reactant transition region 424 of the active side 418 as shown in
The porous media 402 can comprise any shape, for example the porous media 402 may comprise a solid shape such as a rectangle similar to the porous media 402 positioned adjacent the back-feed port 414 on the active side 418. Another example is an irregular shape having linear and curvilinear portions conforming to a direction of flow of fluids adjacent the flow field plate 404. An example of such a porous media 402 is illustrated in
In one embodiment, a thin porous media 502 can be positioned to partially occupy the back-feed channel 512 through which reactants travel to be exhausted from or fed to the corresponding membrane electrode assembly, as illustrated in
It is understood that the porous media 502 need not be centered in the back-feed channel 512; it can be positioned anywhere in the back-feed channel 512. The thin porous media 502 can include a thickness that does not significantly affect a pressure differential between an entry and an exit of the back-feed channels 512; for example, the porous media 502 can comprise a thickness of approximately 100 microns.
In another embodiment as shown in
Those of ordinary skill in the art having reviewed this disclosure will appreciate that the porous media 506, 507 can also be incorporated in bipolar plates in similar fashion as that described herein in conjunction with any of the embodiments.
All of the above U.S. patents, U.S. patent application publications, U.S. patent applications, foreign patents, foreign patent applications and non-patent publications referred to in this specification and/or listed in the Application Data Sheet, are incorporated herein by reference, in their entirety.
From the foregoing it will be appreciated that, although specific embodiments of the invention have been described herein for purposes of illustration, various modifications may be made without deviating from the spirit and scope of the invention. Accordingly, the invention is not limited except as by the appended claims and equivalents thereof.
This application claims the benefit under 35 U.S.C. § 119(e) of U.S. Provisional Patent Application No. 60/824,803 filed Sep. 7, 2006 where this provisional application is incorporated herein by reference in its entirety.
Number | Date | Country | |
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60824803 | Sep 2006 | US |