Referring to the attached drawings, an apparatus and a method for producing a casting mold of the present invention are explained below in detail according to preferred embodiments.
As shown in
As a material for the mold 1, a metal material or a heat-resistant resin material is available. The structure and the shape of the mold are not specifically limited. For example, the mold may be formed with a plurality of segment patterns, which can be coupled to each other to obtain the cavity of a desired shape in the mold. The mold 1 shown in
The sand supply unit 3 is slidable on a rail 80, and can be connected to the steam supply passage 10. When the steam supply passage 10 is connected to the sand supply unit 3, it functions as a sand supply passage for injecting the resin-coated sand 2 into the cavity 40.
The steam supply unit 7 comprises a steam generator 70 for generating steam having, for example, a temperature of 110° C. to 180° C., and a heating device 72 for generating superheated steam by raising the steam temperature without considerably increasing the pressure of the steam supplied from the steam generator 70. To superheat the steam, it is preferred to use a microwave. The superheated steam is defined as a steam obtained by further heating a saturated steam at its saturation temperature or more. In the present invention, the superheated steam supplied into the cavity preferably has a steam pressure of 1.5˜10 kgf/cm2 and a temperature of 150° C. to 700° C., more preferably 200° C. to 600° C.
As shown in
An opening amount of each of the electromagnetic valves (31, 32, 33) used as flow regulators is controlled by the control unit 4 according to an output of a temperature sensor (50, 51, 52) located in the vicinity of an entrance of the corresponding steam discharge passage. That is, an amount of the steam sucked in the respective steam discharge passage changes with the opening amount of the corresponding electromagnetic valve. Therefore, when the steam discharge passage is formed at a region of the cavity of the complex shape where the steam is hard to reach, and the opening amount of the electromagnetic valve is controlled such that a temperature detected by the temperature sensor located in the steam discharge passage is within a desired temperature range, the steam can be uniformly supplied all over the cavity.
From the viewpoint of uniformly supplying the steam into the cavity, it is also preferred that the control parameter for the electromagnetic valve comprises a void fraction of the resin-coated sand 2 filled in the cavity. That is, as shown in
On the other hand, as shown in
In addition, when producing a thick-walled casing mold, there is a fear that heat is not sufficiently supplied into a core portion of the resin-coated sand filled in the cavity, so that only a part of the resin-coated sand which contacts an inner surface of the heated mold is cured. In the past, the metal mold has been heated at a high temperature to solve this problem. However, since a toxic gas occurs at the time of curing the binder material at the high temperature, a deterioration of working conditions was unavoidable. According to the present invention, since the steam is forcibly sucked into the steam discharge passages, it is possible to reliably achieve a uniform supply of heat into the core portion of the resin-coated sand filled in the cavity. Therefore, the casing mold can be produced under improved safe working conditions. In addition, it is not needed to heat the mold at the high temperature, as compared with the past. Furthermore, there is an advantage that a heat-resistant resin material other than the metal material can be used as the mold material. In this case, an increase in degree of freedom of designing the mold and a reduction in production cost can be achieved.
In addition, it is preferred to control the opening amounts of the electromagnetic valves in consideration of the void fraction by previously determining the void fraction of the resin-coated sand filled in the mold by a preliminary experiment, and inputting this void fraction through an input portion (not shown) formed in the control unit 4. For example, the void fraction is defined as a numerical value measured by the following method.
First, 100 ml of a mixture solution prepared such that a weight ratio of water:methanol is 7:3 is put in a measuring cylinder having a volume of 200 ml. Next, 100 ml of the resin-coated sand, which is measured by use of another measuring cylinder, is gradually added to the mixture solution, and then the measuring cylinder is sealed. After it is confirmed that the occurrence of air bubbles has stopped, a liquid level in the measuring cylinder is read off. The void fraction is provided by a difference between the liquid level (M ml) and the scale of 200 ml. Therefore, the void fraction (%) is defined as 200-M. As the solution, water including an interfacial active agent or another liquid may be used in place of the mixture of water and methanol.
A method for producing the casing mold with use of the apparatus described above is explained below in detail. First, the resin-coated sand 2 is injected into the heated mold 1 by the sand supply unit 3. The resin-coated sand can be prepared by coating a refractory aggregate with a binder material (binder resin) such as a thermosetting resin. As the thermosetting resin, for example, it is possible to use a phenol resin, furan resin, isocyanate resin, amine polyol resin or a polyether polyol resin. The mold is preferably heated at a curing temperature or more of the resin-coated sand, for example, 130° C. to 200° C.
Next, the superheated steam is supplied into the cavity 40 of the mold 1 by the steam supply unit 7 to cure the resin-coated sand The superheated steam preferably has the curing temperature or more of the resin-coated sand 2, for example, 200° C. to 600° C., and a steam pressure of 1.5˜10 kgf/cm2. After the superheated steam supplied in the cavity heats the resin-coated sand at the temperature needed for curing, it is discharged from the cavity through the steam discharge passages (20, 21, 22). At this time, the electromagnetic valves (30, 31, 32) and the suction pump 5 are controlled by the control unit 4 such that the cavity is uniformly filled with the superheated steam.
According to the present invention, since the steam discharge passages are formed at different locations to forcibly discharge the superheated steam from the cavity, the superheated steam can be uniformly supplied all over the cavity. Therefore, even when producing the casing mold of a complex shape, it is possible to remarkably reduce the treatment time needed to cure the casing mold, and prevent variations in quality to stably provide the casting mold with uniform quality. In addition, when the binder material of the thermosetting resin is cured by use of the superheated steam, the occurrence of a toxic gas such as ammonia, formaldehyde and phenol can be remarkably reduced. Furthermore, even when a small amount of the toxic gas is generated, it is absorbed by the steam, and then discharged to prevent that the working conditions are deteriorated by the occurrence of the toxic gas. Thus, it is possible to achieve improvements in yield ratio and production efficiency of the casing mold, while preventing the deterioration of working conditions.
After the supply of superheated steam is continued until the curing of the resin-coated sand is completed, the casing mold of the cured resin-coated sand is removed from the cavity. To prevent that the moisture remains in the produced casing mold, the casing mold may be dried by a drying device. By the way, according to the present invention, since the steam uniformly supplied all over the cavity of the complex shape is forcibly removed through the steam discharge passages, dew condensation of the steam is hard to happen in the interior of the casing mold. Therefore, the drying process described above may be omitted.
In the above explanation, a single supply passage is used to supply the resin-coated sand and the superheated steam into the cavity. However, a plurality of supply passages may be formed depending on the shape and size of the cavity. In addition, the apparatus described above has three steam discharge passages. According to the shape of the cavity, two or four or more of the steam discharge passages may be formed at suitable locations. Moreover, it is not essential in the present invention that each of the steam discharge passages has the electromagnetic valve. Further, the suction pump may be connected to only a predetermined one or more of the steam discharge passages.
The present invention is concretely explained below according to Examples.
A resin-coated sand used in the subject Examples was prepared, as described below. First, 680 parts by weight of phenol, 680 parts by weight of 37% formalin and 101 parts by weight of hexamethyltetramine were put in a reaction vessel. A resultant mixture was heated up to 70° C. by taking about 60 minutes, and then reacted by keeping as it is for 5 hours. The thus obtained reaction product was dewatered at 90° C. under a reduced pressure of 100 Torr, and then cooled to obtain a resol-type phenol resin having a softening point of 80° C.
Next, 30 kg of a Flattery sand heated at 145° C. and 450 g of the resol-type phenol resin were put in a Wahl mixer, and kneaded for 30 seconds. Subsequently, 450 g of water was added to the mixer, and a resultant mixture was further kneaded until sand particles are disrupted. After 30 g of calcium stearate was further added to the mixer, and a resultant mixture was kneaded for 30 seconds, aeration was performed to obtain a resin-coated sand having a resin amount of 1.5% by weight ratio. A void fraction of the resin-coated sand is 42%.
To produce the casting mold, the apparatus of
Temperatures measured at the vicinities of the entrances of the respective steam discharge passages (20, 21, 22) and evaluation results of the casting molds, each of which was removed from the metal mold, are shown in Table 1. As the evaluation standards, “◯” designates that the casting mold has good quality, “Δ” designates that the casting mold partially has an uncured portion, and “×” designates that the casting mold is unusable.
In Examples 1 to 3, the temperatures of the steam discharge passages are relatively uniform. In addition, even when the steam was supplied for a short time period, the inside of the cavity was uniformly heated. As a result, the casting molds with stable quality were obtained. On the other hand, in Comparative Examples 1 to 3, since the suction of the steam into the steam discharge passages was not controlled, the temperatures measured at the vicinities of the entrances of the steam discharge passages (21, 22) were relatively low. In addition, as the steam supply time was longer, the quality of the casing mold was slightly improved. However, when the steam supply time was short, a defective casing mold occurred due to nonuniform temperature distribution in the cavity.
Thus, the results of the subject Examples show that the casting mold having the complex shape can be stably produced by supplying the steam for the short time period.
A resin-coated sand used in the subject Examples was prepared according to the substantially same manner as the Examples 1 to 3 except for using Unimin 90 sand in place of the Flattery sand. A void fraction of this resin-coated sand is 37%. By using this resin-coated sand, casting molds were produced as in the cases of Examples 1 to 3 and Comparative Examples 1 to 3. Results are shown in Table 2.
According to the present invention, since the inside of the cavity was uniformly heated by controlling the temperatures of the steam discharge passages relatively uniform, the casing mold with stable quality could be produced irrespective of using the resin-coated sand with a lower void fraction. On the other hand, in the Comparative Examples 4 to 6, the temperature distribution in the cavity became nonuniform due to the decrease in void fraction of the resin-coated sand. In addition, even when the steam supply time was extended at the maximum, sufficiently high temperatures were obtained at the steam discharge passages (21, 22). Consequently, usable casing molds were not obtained by the steam supply times adopted in the subject Comparative Examples.
Thus, the results of the subject Examples show that even when using the resin-coated sand with a low void fraction, the casting mold having the complex shape can be efficiently produced by supplying the steam for the short time period.
As described above, in the case of producing the casing mold having a complex shape, the present invention can achieve a remarkable effect that the resin-coated sand can be uniformly cured in the mold by increasing a supply amount of superheated steam into intricate portions. In addition, it is possible to efficiently produce the casting mold with stable quality, and flexibly cope with the production of various shapes of the casing molds, without detracting the advantages brought by the conventional method for producing the casing mold by use of the superheated steam, which is disclosed in Japanese Patent Early Publication No. 2000-107835. Thus, according to the present invention, it is expected that the method of producing the casing mold by use of the superheated steam will become more widely utilized.
Filing Document | Filing Date | Country | Kind | 371c Date |
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PCT/JP04/17175 | 11/18/2004 | WO | 00 | 9/20/2007 |