Apparatus and method for reducing slippage between structures in an interferometric modulator

Information

  • Patent Grant
  • 7630119
  • Patent Number
    7,630,119
  • Date Filed
    Friday, August 12, 2005
    19 years ago
  • Date Issued
    Tuesday, December 8, 2009
    15 years ago
Abstract
A support structure within an interferometric modulator device may contact various other structures within the device. Increased bond strengths between the support structure and the other structures may be achieved in various ways, such as by providing roughened surfaces and/or adhesive materials at the interfaces between the support structures and the other structures. In an embodiment, increased adhesion is achieved between a support structure and a substrate layer. In another embodiment, increased adhesion is achieved between a support structure and a moveable layer. Increased adhesion may reduce undesirable slippage between the support structures and the other structures to which they are attached within the interferometric modulator.
Description
BACKGROUND

1. Field of the Invention


This invention relates to microelectromechanical systems for use as interferometric modulators. More particularly, this invention relates to systems and methods for improving the micro-electromechanical operation of interferometric modulators.


2. Description of the Related Technology


Microelectromechanical systems (MEMS) include micro mechanical elements, actuators, and electronics. Micromechanical elements may be created using deposition, etching, and or other micromachining processes that etch away parts of substrates and/or deposited material layers or that add layers to form electrical and electromechanical devices. One type of MEMS device is called an interferometric modulator. As used herein, the term interferometric modulator or interferometric light modulator refers to a device that selectively absorbs and/or reflects light using the principles of optical interference. In certain embodiments, an interferometric modulator may comprise a pair of conductive plates, one or both of which may be transparent and/or reflective in whole or part and capable of relative motion upon application of an appropriate electrical signal. In a particular embodiment, one plate may comprise a stationary layer deposited on a substrate and the other plate may comprise a metallic membrane separated from the stationary layer by an air gap. As described herein in more detail, the position of one plate in relation to another can change the optical interference of light incident on the interferometric modulator. Such devices have a wide range of applications, and it would be beneficial in the art to utilize and/or modify the characteristics of these types of devices so that their features can be exploited in improving existing products and creating new products that have not yet been developed.


SUMMARY

The system, method, and devices of the invention each have several aspects, no single one of which is solely responsible for its desirable attributes. Without limiting the scope of this invention, its more prominent features will now be discussed briefly. After considering this discussion, and particularly after reading the section entitled “Detailed Description of Certain Embodiments” one will understand how the features of this invention provide advantages over other display devices.


An embodiment provides an interferometric modulator that includes a substrate layer and a moveable layer. The substrate layer includes a first reflective surface and the movable layer includes a second reflective surface. The second reflective surface is spaced from the first reflective surface to thereby define a cavity. The interferometric modulator further includes a support structure positioned at a side of the cavity between the substrate layer and the moveable layer, and a bond between the support structure and at least one of the substrate layer and the moveable layer. The bond may be configured to increase adhesion between the support structure and at least one of the substrate layer and the moveable layer. Another embodiment provides a display device that includes such an interferometric modulator.


Another embodiment provides an interferometric modulator that includes a means for supporting a moveable layer over a fixed layer, and a means for bonding the support means to at least one of the fixed layer and the moveable layer. The bonding means may be configured to provide improved adhesion between the support means and at least one of the fixed layer and the moveable layer. The bonding means may include, for example, an adhesive and/or a roughened interface between the support means and at least one of the fixed layer and the moveable layer.


Another embodiment provides a method of making an interferometric modulator that includes forming a substrate layer, the substrate layer comprising a first reflective surface, and treating at least a portion of a support region of the substrate layer to form a treated support region. The method further includes forming a support structure on the treated support region. The treated support region may be configured to increase adhesion between the substrate layer and the support structure. Another embodiment provides an interferometric modulator made by such a method.


Another embodiment provides a method of making an interferometric modulator that includes forming a substrate layer and forming a support structure on the substrate layer. The method further includes treating the support structure to form a treated support structure and forming a moveable layer on the treated support structure. Another embodiment provides an interferometric modulator made by such a method.


These and other embodiments are described in greater detail below.





BRIEF DESCRIPTION OF THE DRAWINGS


FIG. 1 is an isometric view depicting a portion of one embodiment of an interferometric modulator display in which a movable reflective layer of a first interferometric modulator is in a relaxed position and a movable reflective layer of a second interferometric modulator is in an actuated position.



FIG. 2 is a system block diagram illustrating one embodiment of an electronic device incorporating a 3×3 interferometric modulator display.



FIG. 3 is a diagram of movable mirror position versus applied voltage for one exemplary embodiment of an interferometric modulator of FIG. 1.



FIG. 4 is an illustration of a set of row and column voltages that may be used to drive an interferometric modulator display.



FIGS. 5A and 5B illustrate one exemplary timing diagram for row and column signals that may be used to write a frame of display data to the 3×3 interferometric modulator display of FIG. 2.



FIGS. 6A and 6B are system block diagrams illustrating an embodiment of a visual display device comprising a plurality of interferometric modulators.



FIG. 7A is a cross section of the device of FIG. 1.



FIG. 7B is a cross section of an alternative embodiment of an interferometric modulator.



FIG. 7C is a cross section of another alternative embodiment of an interferometric modulator.



FIG. 7D is a cross section of yet another alternative embodiment of an interferometric modulator.



FIG. 7E is a cross section of an additional alternative embodiment of an interferometric modulator.



FIG. 8 is a flow diagram illustrating certain steps in an embodiment of a method of making an interferometric modulator.



FIG. 9 is a cross section of an embodiment of an interferometric modulator.



FIGS. 10A-10E are partial cross sections of an embodiment of an interferometric modulator illustrating bonds to a post structure.



FIG. 11 is a flow diagram illustrating certain steps in an embodiment of a method of making an interferometric modulator.



FIG. 12 is a flow diagram illustrating certain steps in an embodiment of a method of making an interferometric modulator.





DETAILED DESCRIPTION OF PREFERRED EMBODIMENTS

The following detailed description is directed to certain specific embodiments of the invention. However, the invention can be embodied in a multitude of different ways. In this description, reference is made to the drawings wherein like parts are designated with like numerals throughout. As will be apparent from the following description, the embodiments may be implemented in any device that is configured to display an image, whether in motion (e.g., video) or stationary (e.g., still image), and whether textual or pictorial. More particularly, it is contemplated that the embodiments may be implemented in or associated with a variety of electronic devices such as, but not limited to, mobile telephones, wireless devices, personal data assistants (PDAs), hand-held or portable computers, GPS receivers/navigators, cameras, MP3 players, camcorders, game consoles, wrist watches, clocks, calculators, television monitors, flat panel displays, computer monitors, auto displays (e.g., odometer display, etc.), cockpit controls and/or displays, display of camera views (e.g., display of a rear view camera in a vehicle), electronic photographs, electronic billboards or signs, projectors, architectural structures, packaging, and aesthetic structures (e.g., display of images on a piece of jewelry). MEMS devices of similar structure to those described herein can also be used in non-display applications such as in electronic switching devices.


An embodiment provides increased bond strengths between post structures and other structures (such as the substrate and/or the moveable layer) in an interferometric modulator. In certain embodiments, the increased bond strengths are achieved by providing a roughened surface and/or an adhesive layer at the interface between the post structure and the structures to which it is attached (such as the substrate and/or the moveable layer).


One interferometric modulator display embodiment comprising an interferometric MEMS display element is illustrated in FIG. 1. In these devices, the pixels are in either a bright or dark state. In the bright (“on” or “open”) state, the display element reflects a large portion of incident visible light to a user. When in the dark (“off” or “closed”) state, the display element reflects little incident visible light to the user. Depending on the embodiment, the light reflectance properties of the “on” and “off” states may be reversed. MEMS pixels can be configured to reflect predominantly at selected colors, allowing for a color display in addition to black and white.



FIG. 1 is an isometric view depicting two adjacent pixels in a series of pixels of a visual display, wherein each pixel comprises a MEMS interferometric modulator. In some embodiments, an interferometric modulator display comprises a row/column array of these interferometric modulators. Each interferometric modulator includes a pair of reflective layers positioned at a variable and controllable distance from each other to form a resonant optical cavity with at least one variable dimension. In one embodiment, one of the reflective layers may be moved between two positions. In the first position, referred to herein as the relaxed position, the movable reflective layer is positioned at a relatively large distance from a fixed partially reflective layer. In the second position, referred to herein as the actuated position, the movable reflective layer is positioned more closely adjacent to the partially reflective layer. Incident light that reflects from the two layers interferes constructively or destructively depending on the position of the movable reflective layer, producing either an overall reflective or non-reflective state for each pixel.


The depicted portion of the pixel array in FIG. 1 includes two adjacent interferometric modulators 12a and 12b. In the interferometric modulator 12a on the left, a movable reflective layer 14a is illustrated in a relaxed position at a predetermined distance from an optical stack 16a, which includes a partially reflective layer. In the interferometric modulator 12b on the right, the movable reflective layer 14b is illustrated in an actuated position adjacent to the optical stack 16b.


The optical stacks 16a and 16b (collectively referred to as optical stack 16), as referenced herein, typically comprise of several fused layers, which can include an electrode layer, such as indium tin oxide (ITO), a partially reflective layer, such as chromium, and a transparent dielectric. The optical stack 16 is thus electrically conductive, partially transparent and partially reflective, and may be fabricated, for example, by depositing one or more of the above layers onto a transparent substrate 20. In some embodiments, the layers are patterned into parallel strips, and may form row electrodes in a display device as described further below. The movable reflective layers 14a, 14b may be formed as a series of parallel strips of a deposited metal layer or layers (orthogonal to the row electrodes of 16a, 16b) deposited on top of posts 18 and an intervening sacrificial material deposited between the posts 18. When the sacrificial material is etched away, the movable reflective layers 14a, 14b are separated from the optical stacks 16a, 16b by a defined gap 19. A highly conductive and reflective material such as aluminum may be used for the reflective layers 14, and these strips may form column electrodes in a display device.


With no applied voltage, the cavity 19 remains between the movable reflective layer 14a and optical stack 16a, with the movable reflective layer 14a in a mechanically relaxed state, as illustrated by the pixel 12a in FIG. 1. However, when a potential difference is applied to a selected row and column, the capacitor formed at the intersection of the row and column electrodes at the corresponding pixel becomes charged, and electrostatic forces pull the electrodes together. If the voltage is high enough, the movable reflective layer 14 is deformed and is forced against the optical stack 16. A dielectric layer (not illustrated in this Figure) within the optical stack 16 may prevent shorting and control the separation distance between layers 14 and 16, as illustrated by pixel 12b on the right in FIG. 1. The behavior is the same regardless of the polarity of the applied potential difference. In this way, row/column actuation that can control the reflective vs. non-reflective pixel states is analogous in many ways to that used in conventional LCD and other display technologies.



FIGS. 2 through 5 illustrate one exemplary process and system for using an array of interferometric modulators in a display application.



FIG. 2 is a system block diagram illustrating one embodiment of an electronic device that may incorporate aspects of the invention. In the exemplary embodiment, the electronic device includes a processor 21 which may be any general purpose single- or multi-chip microprocessor such as an ARM, Pentium®, Pentium II®, Pentium III®, Pentium IV®, Pentium® Pro, an 8051, a MIPS®, a Power PC®, an ALPHA®, or any special purpose microprocessor such as a digital signal processor, microcontroller, or a programmable gate array. As is conventional in the art, the processor 21 may be configured to execute one or more software modules. In addition to executing an operating system, the processor may be configured to execute one or more software applications, including a web browser, a telephone application, an email program, or any other software application.


In one embodiment, the processor 21 is also configured to communicate with an array driver 22. In one embodiment, the array driver 22 includes a row driver circuit 24 and a column driver circuit 26 that provide signals to a panel or display array (display) 30. The cross section of the array illustrated in FIG. 1 is shown by the lines 1-1 in FIG. 2. For MEMS interferometric modulators, the row/column actuation protocol may take advantage of a hysteresis property of these devices illustrated in FIG. 3. It may require, for example, a 10 volt potential difference to cause a movable layer to deform from the relaxed state to the actuated state. However, when the voltage is reduced from that value, the movable layer maintains its state as the voltage drops back below 10 volts. In the exemplary embodiment of FIG. 3, the movable layer does not relax completely until the voltage drops below 2 volts. There is thus a range of voltage, about 3 to 7 V in the example illustrated in FIG. 3, where there exists a window of applied voltage within which the device is stable in either the relaxed or actuated state. This is referred to herein as the “hysteresis window” or “stability window.” For a display array having the hysteresis characteristics of FIG. 3, the row/column actuation protocol can be designed such that during row strobing, pixels in the strobed row that are to be actuated are exposed to a voltage difference of about 10 volts, and pixels that are to be relaxed are exposed to a voltage difference of close to zero volts. After the strobe, the pixels are exposed to a steady state voltage difference of about 5 volts such that they remain in whatever state the row strobe put them in. After being written, each pixel sees a potential difference within the “stability window” of 3-7 volts in this example. This feature makes the pixel design illustrated in FIG. 1 stable under the same applied voltage conditions in either an actuated or relaxed pre-existing state. Since each pixel of the interferometric modulator, whether in the actuated or relaxed state, is essentially a capacitor formed by the fixed and moving reflective layers, this stable state can be held at a voltage within the hysteresis window with almost no power dissipation. Essentially no current flows into the pixel if the applied potential is fixed.


In typical applications, a display frame may be created by asserting the set of column electrodes in accordance with the desired set of actuated pixels in the first row. A row pulse is then applied to the row 1 electrode, actuating the pixels corresponding to the asserted column lines. The asserted set of column electrodes is then changed to correspond to the desired set of actuated pixels in the second row. A pulse is then applied to the row 2 electrode, actuating the appropriate pixels in row 2 in accordance with the asserted column electrodes. The row 1 pixels are unaffected by the row 2 pulse, and remain in the state they were set to during the row 1 pulse. This may be repeated for the entire series of rows in a sequential fashion to produce the frame. Generally, the frames are refreshed and/or updated with new display data by continually repeating this process at some desired number of frames per second. A wide variety of protocols for driving row and column electrodes of pixel arrays to produce display frames are also well known and may be used in conjunction with the present invention.



FIGS. 4 and 5 illustrate one possible actuation protocol for creating a display frame on the 3×3 array of FIG. 2. FIG. 4 illustrates a possible set of column and row voltage levels that may be used for pixels exhibiting the hysteresis curves of FIG. 3. In the FIG. 4 embodiment, actuating a pixel involves setting the appropriate column to −Vbias, and the appropriate row to +ΔV, which may correspond to −5 volts and +5 volts respectively. Relaxing the pixel is accomplished by setting the appropriate column to +Vbias, and the appropriate row to the same +ΔV, producing a zero volt potential difference across the pixel. In those rows where the row voltage is held at zero volts, the pixels are stable in whatever state they were originally in, regardless of whether the column is at +Vbias, or −Vbias. As is also illustrated in FIG. 4, it will be appreciated that voltages of opposite polarity than those described above can be used, e.g., actuating a pixel can involve setting the appropriate column to +Vbias, and the appropriate row to −ΔV. In this embodiment, releasing the pixel is accomplished by setting the appropriate column to −Vbias, and the appropriate row to the same −ΔV, producing a zero volt potential difference across the pixel.



FIG. 5B is a timing diagram showing a series of row and column signals applied to the 3×3 array of FIG. 2 which will result in the display arrangement illustrated in FIG. 5A, where actuated pixels are non-reflective. Prior to writing the frame illustrated in FIG. 5A, the pixels can be in any state, and in this example, all the rows are at 0 volts, and all the columns are at +5 volts. With these applied voltages, all pixels are stable in their existing actuated or relaxed states.


In the FIG. 5A frame, pixels (1,1), (1,2), (2,2), (3,2) and (3,3) are actuated. To accomplish this, during a “line time” for row 1, columns 1 and 2 are set to −5 volts, and column 3 is set to +5 volts. This does not change the state of any pixels, because all the pixels remain in the 3-7 volt stability window. Row 1 is then strobed with a pulse that goes from 0, up to 5 volts, and back to zero. This actuates the (1,1) and (1,2) pixels and relaxes the (1,3) pixel. No other pixels in the array are affected. To set row 2 as desired, column 2 is set to −5 volts, and columns 1 and 3 are set to +5 volts. The same strobe applied to row 2 will then actuate pixel (2,2) and relax pixels (2,1) and (2,3). Again, no other pixels of the array are affected. Row 3 is similarly set by setting columns 2 and 3 to −5 volts, and column 1 to +5 volts. The row 3 strobe sets the row 3 pixels as shown in FIG. 5A. After writing the frame, the row potentials are zero, and the column potentials can remain at either +5 or −5 volts, and the display is then stable in the arrangement of FIG. 5A. It will be appreciated that the same procedure can be employed for arrays of dozens or hundreds of rows and columns. It will also be appreciated that the timing, sequence, and levels of voltages used to perform row and column actuation can be varied widely within the general principles outlined above, and the above example is exemplary only, and any actuation voltage method can be used with the systems and methods described herein.



FIGS. 6A and 6B are system block diagrams illustrating an embodiment of a display device 40. The display device 40 can be, for example, a cellular or mobile telephone. However, the same components of display device 40 or slight variations thereof are also illustrative of various types of display devices such as televisions and portable media players.


The display device 40 includes a housing 41, a display 30, an antenna 43, a speaker 45, an input device 48, and a microphone 46. The housing 41 is generally formed from any of a variety of manufacturing processes as are well known to those of skill in the art, including injection molding, and vacuum forming. In addition, the housing 41 may be made from any of a variety of materials, including but not limited to plastic, metal, glass, rubber, and ceramic, or a combination thereof. In one embodiment the housing 41 includes removable portions (not shown) that may be interchanged with other removable portions of different color, or containing different logos, pictures, or symbols.


The display 30 of exemplary display device 40 may be any of a variety of displays, including a bi-stable display, as described herein. In other embodiments, the display 30 includes a flat-panel display, such as plasma, EL, OLED, STN LCD, or TFT LCD as described above, or a non-flat-panel display, such as a CRT or other tube device, as is well known to those of skill in the art. However, for purposes of describing the present embodiment, the display 30 includes an interferometric modulator display, as described herein.


The components of one embodiment of exemplary display device 40 are schematically illustrated in FIG. 6B. The illustrated exemplary display device 40 includes a housing 41 and can include additional components at least partially enclosed therein. For example, in one embodiment, the exemplary display device 40 includes a network interface 27 that includes an antenna 43 which is coupled to a transceiver 47. The transceiver 47 is connected to the processor 21, which is connected to conditioning hardware 52. The conditioning hardware 52 may be configured to condition a signal (e.g. filter a signal). The conditioning hardware 52 is connected to a speaker 45 and a microphone 46. The processor 21 is also connected to an input device 48 and a driver controller 29. The driver controller 29 is coupled to a frame buffer 28 and to the array driver 22, which in turn is coupled to a display array 30. A power supply 50 provides power to all components as required by the particular exemplary display device 40 design.


The network interface 27 includes the antenna 43 and the transceiver 47 so that the exemplary display device 40 can communicate with one ore more devices over a network. In one embodiment the network interface 27 may also have some processing capabilities to relieve requirements of the processor 21. The antenna 43 is any antenna known to those of skill in the art for transmitting and receiving signals. In one embodiment, the antenna transmits and receives RF signals according to the IEEE 802.11 standard, including IEEE 802.11(a), (b), or (g). In another embodiment, the antenna transmits and receives RF signals according to the BLUETOOTH standard. In the case of a cellular telephone, the antenna is designed to receive CDMA, GSM, AMPS or other known signals that are used to communicate within a wireless cell phone network. The transceiver 47 pre-processes the signals received from the antenna 43 so that they may be received by and further manipulated by the processor 21. The transceiver 47 also processes signals received from the processor 21 so that they may be transmitted from the exemplary display device 40 via the antenna 43.


In an alternative embodiment, the transceiver 47 can be replaced by a receiver. In yet another alternative embodiment, network interface 27 can be replaced by an image source, which can store or generate image data to be sent to the processor 21. For example, the image source can be a digital video disc (DVD) or a hard-disc drive that contains image data, or a software module that generates image data.


Processor 21 generally controls the overall operation of the exemplary display device 40. The processor 21 receives data, such as compressed image data from the network interface 27 or an image source, and processes the data into raw image data or into a format that is readily processed into raw image data. The processor 21 then sends the processed data to the driver controller 29 or to frame buffer 28 for storage. Raw data typically refers to the information that identifies the image characteristics at each location within an image. For example, such image characteristics can include color, saturation, and gray-scale level.


In one embodiment, the processor 21 includes a microcontroller, CPU, or logic unit to control operation of the exemplary display device 40. Conditioning hardware 52 generally includes amplifiers and filters for transmitting signals to the speaker 45, and for receiving signals from the microphone 46. Conditioning hardware 52 may be discrete components within the exemplary display device 40, or may be incorporated within the processor 21 or other components.


The driver controller 29 takes the raw image data generated by the processor 21 either directly from the processor 21 or from the frame buffer 28 and reformats the raw image data appropriately for high speed transmission to the array driver 22. Specifically, the driver controller 29 reformats the raw image data into a data flow having a raster-like format, such that it has a time order suitable for scanning across the display array 30. Then the driver controller 29 sends the formatted information to the array driver 22. Although a driver controller 29, such as a LCD controller, is often associated with the system processor 21 as a stand-alone Integrated Circuit (IC), such controllers may be implemented in many ways. They may be embedded in the processor 21 as hardware, embedded in the processor 21 as software, or fully integrated in hardware with the array driver 22.


Typically, the array driver 22 receives the formatted information from the driver controller 29 and reformats the video data into a parallel set of waveforms that are applied many times per second to the hundreds and sometimes thousands of leads coming from the display's x-y matrix of pixels.


In one embodiment, the driver controller 29, array driver 22, and display array 30 are appropriate for any of the types of displays described herein. For example, in one embodiment, driver controller 29 is a conventional display controller or a bi-stable display controller (e.g., an interferometric modulator controller). In another embodiment, array driver 22 is a conventional driver or a bi-stable display driver (e.g., an interferometric modulator display). In one embodiment, a driver controller 29 is integrated with the array driver 22. Such an embodiment is common in highly integrated systems such as cellular phones, watches, and other small area displays. In yet another embodiment, display array 30 is a typical display array or a bi-stable display array (e.g., a display including an array of interferometric modulators).


The input device 48 allows a user to control the operation of the exemplary display device 40. In one embodiment, input device 48 includes a keypad, such as a QWERTY keyboard or a telephone keypad, a button, a switch, a touch-sensitive screen, a pressure- or heat-sensitive membrane. In one embodiment, the microphone 46 is an input device for the exemplary display device 40. When the microphone 46 is used to input data to the device, voice commands may be provided by a user for controlling operations of the exemplary display device 40.


Power supply 50 can include a variety of energy storage devices as are well known in the art. For example, in one embodiment, power supply 50 is a rechargeable battery, such as a nickel-cadmium battery or a lithium ion battery. In another embodiment, power supply 50 is a renewable energy source, a capacitor, or a solar cell, including a plastic solar cell, and solar-cell paint. In another embodiment, power supply 50 is configured to receive power from a wall outlet.


In some implementations control programmability resides, as described above, in a driver controller which can be located in several places in the electronic display system. In some cases control programmability resides in the array driver 22. Those of skill in the art will recognize that the above-described optimization may be implemented in any number of hardware and/or software components and in various configurations.


The details of the structure of interferometric modulators that operate in accordance with the principles set forth above may vary widely. For example, FIGS. 7A-7E illustrate five different embodiments of the movable reflective layer 14 and its supporting structures. FIG. 7A is a cross section of the embodiment of FIG. 1, where a strip of metal material 14 is deposited on orthogonally extending supports 18. In FIG. 7B, the moveable reflective layer 14 is attached to supports at the corners only, on tethers 32. In FIG. 7C, the moveable reflective layer 14 is suspended from a deformable layer 34, which may comprise a flexible metal. The deformable layer 34 connects, directly or indirectly, to the substrate 20 around the perimeter of the deformable layer 34. These connections are herein referred to as support posts. The embodiment illustrated in FIG. 7D has support post plugs 42 upon which the deformable layer 34 rests. The movable reflective layer 14 remains suspended over the cavity, as in FIGS. 7A-7C, but the deformable layer 34 does not form the support posts by filling holes between the deformable layer 34 and the optical stack 16. Rather, the support posts are formed of a planarization material, which is used to form support post plugs 42. The embodiment illustrated in FIG. 7E is based on the embodiment shown in FIG. 7D, but may also be adapted to work with any of the embodiments illustrated in FIGS. 7A-7C as well as additional embodiments not shown. In the embodiment shown in FIG. 7E, an extra layer of metal or other conductive material has been used to form a bus structure 44. This allows signal routing along the back of the interferometric modulators, eliminating a number of electrodes that may otherwise have had to be formed on the substrate 20.


In embodiments such as those shown in FIG. 7, the interferometric modulators function as direct-view devices, in which images are viewed from the front side of the transparent substrate 20, the side opposite to that upon which the modulator is arranged. In these embodiments, the reflective layer 14 optically shields some portions of the interferometric modulator on the side of the reflective layer opposite the substrate 20, including the deformable layer 34 and the bus structure 44. This allows the shielded areas to be configured and operated upon without negatively affecting the image quality. This separable modulator architecture allows the structural design and materials used for the electromechanical aspects and the optical aspects of the modulator to be selected and to function independently of each other. Moreover, the embodiments shown in FIGS. 7C-7E have additional benefits deriving from the decoupling of the optical properties of the reflective layer 14 from its mechanical properties, which are carried out by the deformable layer 34. This allows the structural design and materials used for the reflective layer 14 to be optimized with respect to the optical properties, and the structural design and materials used for the deformable layer 34 to be optimized with respect to desired mechanical properties.



FIG. 8 illustrates certain steps in an embodiment of a manufacturing process 800 for a MEMS, e.g., an interferometric modulator. Such steps may be present in a process for manufacturing, e.g., interferometric modulators of the general type illustrated in FIGS. 1 and 7, along with other steps not shown in FIG. 8. With reference to FIGS. 1, 7 and 8, the process 800 begins at step 805 with the formation of the optical stack 16 over the substrate 20. The substrate 20 may be a transparent substrate such as glass or plastic and may have been subjected to prior preparation step(s), e.g., cleaning, to facilitate efficient formation of the optical stack 16. The optical stack 16 may be formed by employing one or more deposition steps, e.g., conductive layer (e.g., indium tin oxide) deposition, reflective layer (e.g., chromium) deposition, and dielectric layer deposition, along with one or more patterning, masking, and/or etching steps.


The process 800 illustrated in FIG. 8 continues at step 810 with the formation of a sacrificial layer over the optical stack 16. The sacrificial layer is later removed (e.g., at step 825) to form the cavity 19 as discussed below and thus the sacrificial layer is not shown in the resulting interferometric modulator 12 illustrated in FIGS. 1 and 7. The formation of the sacrificial layer over the optical stack 16 may include deposition of a material such as molybdenum or amorphous silicon, in a thickness selected to provide, after subsequent removal, a cavity 19 having the desired size. Deposition of the sacrificial material may be carried out using deposition techniques such as physical vapor deposition (PVD, e.g., sputtering), plasma-enhanced chemical vapor deposition (PECVD), thermal chemical vapor deposition (thermal CVD), or spin-coating.


The process 800 illustrated in FIG. 8 continues at step 815 with the formation of a support structure e.g., a post 18 as illustrated in FIGS. 1 and 7. The formation of the post 18 may include the steps of patterning the sacrificial layer to form an aperture, then depositing a material (e.g., a polymer, metal or oxide) into the aperture to form the post 18, using a deposition method such as PECVD, thermal CVD, or spin-coating. In some embodiments, the aperture formed in the sacrificial layer extends through both the sacrificial layer and the optical stack 16 to the underlying substrate 20, so that the lower end of the post 18 contacts the substrate 20 as illustrated in FIG. 7A. In other embodiments, the aperture formed in the sacrificial layer extends through the sacrificial layer, but not through the optical stack 16. For example, FIG. 7C illustrates the lower end of the support post plugs 42 in contact with the optical stack 16.


The process 800 illustrated in FIG. 8 continues at step 820 with the formation of a moveable reflective layer such as the moveable reflective layer 14 illustrated in FIGS. 1 and 7. The moveable reflective layer 14 may be formed by employing one or more deposition steps, e.g., reflective layer (e.g., aluminum, aluminum alloy) deposition, along with one or more patterning, masking, and/or etching steps.


The process 800 illustrated in FIG. 8 continues at step 825 with the formation of a cavity, e.g., a cavity 19 as illustrated in FIGS. 1 and 7. The cavity 19 may be formed by exposing the sacrificial material (deposited at step 810) to a selective etchant. For example, a sacrificial material such as molybdenum or amorphous silicon may be removed by dry chemical etching, e.g., by exposing the sacrificial layer to a gaseous or vaporous etchant such as xenon difluoride (XeF2) for a period of time that is effective to remove the desired amount of material. Other etching methods, e.g. wet etching and/or plasma etching, may be also be used.


Interferometric modulators may be manufactured in accordance with various sets of processing parameters, and thus it will be understood that FIG. 8 shows only a few of the more common steps for the purposes of illustration. It will be also be understood that not all processes for manufacturing interferometric modulators include all the steps illustrated in FIG. 8; that the steps illustrated in FIG. 8 need not necessarily be carried out in the order shown, and that various additional manufacturing steps may be carried out, e.g., testing, back-end processing, and incorporating the interferometric modulator into a display device 40 as illustrated in FIG. 6.



FIG. 9 illustrates a cross-sectional view of an embodiment of an interferometric modulator. In this embodiment, the support structure 18 interacts with the moveable reflective layer 14 at an interface 905 between the upper end of the support structure 18 and the lower surface of the layer 14. Likewise, the support structure 18 interacts with the substrate 20 at an interface 910 between the lower end of the support 18 and the upper surface of the substrate 20. In certain situations, sliding or slippage between the support 18 and one or both of the moveable reflective layer 14 and the substrate 20 may occur. It has now been found that this movement may be decreased or eliminated in a number of ways. For example, in one embodiment, the movement is decreased by forming a bond at one or both of the interfaces 905, 910. The bond is preferably configured to increase adhesion between the support structure 18 and at least one of the substrate layer 20 and the moveable layer 14. The increased adhesion may provide other benefits, instead of or in addition to decreasing and/or preventing relative movement between the support structure 18 and the layer(s) with which it is in contact.



FIG. 10A illustrates an embodiment of a bond 1005 formed at the interface between the upper end of the support structure 18 and the lower surface of the moveable layer 14, and a bond 1010 at the interface between the lower end of the support structure 18 and the upper surface of a transparent substrate layer 20. In the illustrated embodiment, the bonds 1005, 1010 both comprise a roughened interface between the support structure 18 and each of the moveable layer 14 and the substrate layer 20, respectively. This invention is not bound by theory, but it is believed that roughening increases the surface area at the interface and/or provides mechanical interlocking between the two surfaces, thereby increasing adhesion between the support structure 18 and each of the layers 14, 20. Adhesion tends to increase as the degree of roughness increases, and thus the degree of roughness for each of the bonds 1005, 1010 is preferably selected to provide the desired degree of adhesion, as determined by routine experimentation. The bond 1010 at the interface between the lower end of the support structure 18 and the upper surface of a transparent substrate layer 20 may be formed during fabrication of the interferometric modulator, preferably by roughening a region 1040 of the surface of the substrate 20 prior to formation of the support structure, as described in greater detail below. The bond 1005 at the interface between the upper end of the support structure 18 and the lower surface of the moveable layer 14 may also be formed during fabrication of the interferometric modulator, preferably by roughening the support structure prior to formation of the moveable layer 14, as described in greater detail below. Roughening of the substrate and/or support structure may be carried out in various ways, e.g., by etching techniques known to those skilled in the art. For example, the substrate may be etched by oxygen plasma burn down and/or by sputter etching. The degree of roughening for each of the bonds 1005, 1010, may be the same or different. In some embodiments (not shown in FIG. 10A), only one of the interfaces 905, 910 is treated to increase adhesion between the support structure 18 and the layers 14, 20, respectively.



FIG. 10B illustrates an embodiment of a bond 1015 formed at the interface between the upper end of the support structure 18 and the lower surface of the moveable layer 14, and a bond 1020 at the interface between the lower end of the support structure 18 and the upper surface of a transparent substrate layer 20. In the illustrated embodiment, the bonds 1015, 1020 both comprise an adhesive layer between the support structure 18 and each of the moveable layer 14 and the substrate layer 20, respectively. The adhesive layer preferably comprises a material that adheres more strongly to both of the surfaces at the interface than either of the interfacial surfaces adhere to one another in the absence of the adhesive material. For example, the bond 1015 preferably comprises a material that adheres better to both the support structure 18 and the moveable layer 14, than the support structure 18 adheres to the moveable layer 14 in the absence of the bond 1015. Likewise, the bond 1020 preferably comprises a material that adheres better to both the support structure 18 and the substrate layer 20, than the support structure 18 adheres to the substrate layer 20 in the absence of the bond 1020. Adhesive materials may be selected by routine experimentation. Preferably, one or both of the adhesive bond 1015 and the adhesive bond 1020 comprise aluminum, e.g., the bonds 1015, 1020 contain aluminum or an aluminum alloy. The bond 1020 at the interface between the lower end of the support structure 18 and the upper surface of a transparent substrate layer 20 may be formed during fabrication of the interferometric modulator, preferably by depositing an adhesive material onto the substrate 20 prior to formation of the support structure, as described in greater detail below. Likewise, the bond 1015 at the interface between the upper end of the support structure 18 and the lower surface of the moveable layer 14 may also be formed during fabrication of the interferometric modulator, preferably by depositing an adhesive material onto the support structure prior to formation of the moveable layer 14, as described in greater detail below.



FIG. 10C illustrates that a bond between the support structure and at least one of the substrate layer and the moveable layer may comprise both a roughened interface and an adhesive layer. The bond 1035 between the upper end of the support structure 18 and the lower surface of the moveable layer 14 shown in FIG. 10C comprises a bond 1005 that comprises a roughened surface on the upper end of the support structure 18, and an adhesive layer 1015 between the roughened interface and the lower surface of the moveable layer 14. This invention is not bound by theory, but it is believed that the surface roughening increases the surface area of the upper end of the support structure 18 that is available for bonding, thus increasing adhesion between the upper end of the support structure 18 and the adhesive layer in the bond 1015. FIG. 10C also illustrates an interferometric modulator in which the upper end of the support structure 18 is bonded to the lower surface of the moveable layer 14 in a different manner (via the bond 1035) than the lower end of the support structure 18 is bonded to the upper surface of the substrate layer 20 (via a bond 1010 that comprises a roughened interface, without an adhesive layer).



FIG. 10D illustrates an embodiment of a bond 1025 formed at the interface between the lower end of the support structure 18 and the upper surface of a transparent substrate layer 20, where the upper surface of the substrate 20 comprises an optical stack 16. In the illustrated embodiment, the bond 1015 is formed by roughening the optical stack 16, rather than the transparent substrate 20 as illustrated in FIG. 10A. Likewise, FIG. 10E illustrates an embodiment of a bond 1030 formed at the interface between the lower end of the support structure 18 and the upper surface of a transparent substrate layer 20, where the upper surface of the substrate 20 comprises an optical stack 16. In the illustrated embodiment, the bond 1030 is formed by depositing an adhesive layer onto the optical stack 16, rather than onto the transparent substrate 20 as illustrated in FIG. 10B.


The various bonds 1005, 1010, 1015, 1020, 1025, 1030 are illustrated in FIG. 10 for an interferometric modulator of the general type shown in FIG. 7A. It will be understood that similar bonds may be formed between the support structures and the layers to which the support structures are attached in other types of interferometric modulators, including but not limited to the interferometric modulators illustrated in FIGS. 7B-E. For example, in an embodiment (not illustrated in FIG. 10), a bond is formed between a support structure and a moveable layer, and a reflective surface is suspended from the moveable layer, e.g., in the general manner illustrated in FIG. 7C. It will also be appreciated that the support structure 18 (e.g., a post) is an example of a means for supporting a moveable layer (e.g., the moveable layer 14) over a fixed layer (e.g., the substrate layer 20 comprising the optical stack 16). It will also be appreciated that the bonds formed by surface roughening (e.g., the bonds 1005, 1010) and by the use of an adhesive layer (e.g., the bonds 1015, 1020) are examples of means for bonding the support means to at least one of the fixed layer and the moveable layer.



FIG. 11 is a flow chart illustrating an embodiment of a method of making an interferometric modulator. The method 1100 begins at step 1105 by forming a substrate layer. Preferably, the substrate layer comprises a first reflective surface. The substrate layer may include a transparent substrate 20 and the first reflective surface may include an optical stack 16 as illustrated in FIGS. 1 and 7. The optical stack 16 may be formed on the substrate 20 by employing one or more deposition steps, e.g., reflective layer (e.g., chromium) deposition, conductive layer (e.g., indium tin oxide) deposition, and dielectric layer deposition, along with one or more patterning, masking, and/or etching steps.


The method 1100 continues at step 1110 by treating at least a portion of a support region of the substrate layer to form a treated support region. The support region of the substrate layer is typically the area that will underlie a support structure that will be formed in a subsequent step. The substrate layer may comprise the first reflective surface, and thus treatment of the support region of the substrate layer may include treatment of the support region of the substrate, e.g., treatment of the support region 1040 of the substrate 20 as illustrated in FIG. 10A, and/or treatment of the first reflective surface, e.g., the support region 1045 of the optical stack 16 as illustrated in FIG. 10. Treating the support region to form a treated support region may include, for example, roughening the support region and/or applying an adhesive layer. Thus, the resulting treated support region may include, for example, a roughened surface (such as the roughened surfaces included in the bonds 1010, 1025 illustrated in FIGS. 10A and 10D, respectively) and/or a adhesive layer such as the adhesive layers included in the bonds 1020, 1030 illustrated in FIGS. 10B and 10E, respectively. Treating the support region may include exposing the support region to a roughening treatment such as a wet chemical etch, a dry chemical etch, and/or a plasma etch. Examples of roughening treatments include oxygen plasma burn down and sputter etching. In addition to or instead of roughening, treating the support region may include depositing an adhesive layer by a deposition process such as, e.g., spin-on, PECVD, thermal CVD, and/or PVD (e.g., sputtering). In an embodiment, deposition of an adhesive layer comprises depositing a metal, wherein the metal comprises aluminum (e.g., an aluminum alloy). Treatment is preferably carried out to an extent that is effective to provide increased adhesion between the substrate layer and the subsequently-formed support structure, e.g., between the substrate 20 and the support structure 18 as illustrated in FIG. 10.


The method 1100 continues at step 1115 by forming a support structure on the treated support region. The support structure may be formed in various ways. For example, in an embodiment, a configuration such as that illustrated in FIGS. 10A and 10B may be fabricated by depositing a first reflective layer (e.g., the optical stack 16) and a sacrificial layer on a substrate (e.g., the substrate 20), forming an aperture (e.g., a hole) through the sacrificial layer and the first reflective layer to expose a portion of the underlying substrate (e.g., to expose the underlying substrate 20), treating the exposed substrate to form a treated support region (e.g., the treated support region 1040) as described above, and depositing a support structure material into the aperture to form a support structure (e.g., the support structure 18) in contact with the treated support region. In another embodiment, a configuration such as that illustrated in FIGS. 10D and 10E may be fabricated by depositing a first reflective layer (e.g., the optical stack 16) and a sacrificial layer on a substrate (e.g., the substrate 20), forming an aperture (e.g., a hole) through the sacrificial layer to expose a portion of the underlying first reflective layer (e.g., to expose the optical stack 16), treating the exposed optical stack 16 to form a treated support region (e.g., the treated support region 1045) as described above, and depositing a support structure material into the aperture to form a support structure (e.g., the support structure 18) in contact with the treated support region. The support structure may be formed in various ways, e.g., by spin-in deposition of a polymer or by chemical vapor deposition (e.g., PECVD or thermal CVD) of an oxide such as a silicon oxide.


It will be understood that additional steps (not illustrated in FIG. 11) in the fabrication of the interferometric modulator may also be conducted in accordance with the method 1100, e.g., deposition of the sacrificial layer over the substrate layer, deposition of a moveable layer over the sacrificial layer, deposition of a second reflective layer over the sacrificial layer, removal of the sacrificial layer to form a cavity positioned between the first reflective layer and the second reflective layer, and/or removal of the sacrificial layer to form a cavity positioned between the first reflective layer and the moveable layer.



FIG. 12 is a flow chart illustrating another embodiment of a method of making an interferometric modulator. The method 1200 begins at step 1205 by forming a substrate layer. Preferably, the substrate layer comprises a first reflective surface. The substrate layer may include a transparent substrate 20 and the first reflective surface may include an optical stack 16 as illustrated in FIGS. 1 and 7. The optical stack 16 may be formed on the substrate 20 by employing one or more deposition steps, e.g., reflective layer (e.g., chromium) deposition, conductive layer (e.g., indium tin oxide) deposition, and dielectric layer deposition, along with one or more patterning, masking, and/or etching steps.


The method 1200 continues at step 1210 by forming a support structure on the substrate layer. The support structure may be formed in various ways. For example, in an embodiment, a configuration such as that illustrated in FIGS. 10A and 10B may be fabricated by depositing a first reflective layer (e.g., the optical stack 16) and a sacrificial layer on a substrate (e.g., the substrate 20), forming an aperture (e.g., a hole) through the sacrificial layer and the first reflective layer to expose a portion of the underlying substrate (e.g., to expose the underlying substrate 20), and depositing a support structure material into the aperture to form a support structure (e.g., the support structure 18) in contact with the substrate (e.g., the substrate 20). Optionally, the exposed substrate may be treated to form a treated support region (e.g., the treated support region 1040) as described above. In another embodiment, a configuration such as that illustrated in FIGS. 10D and 10E may be fabricated by depositing a first reflective layer (e.g., the optical stack 16) and a sacrificial layer on a substrate (e.g., the substrate 20), forming an aperture (e.g., a hole) through the sacrificial layer to expose a portion of the underlying first reflective layer (e.g., to expose the optical stack 16), and depositing a support structure material into the aperture to form a support structure (e.g., the support structure 18) in contact with the first reflective layer (e.g., the optical stack 16). Optionally, the exposed optical stack 16 may be treated to form a treated support region (e.g., the treated support region 1045) as described above. The support structure may be formed in various ways as described above, e.g., by spin-in deposition of a polymer or by chemical vapor deposition (e.g., PECVD or thermal CVD) of an oxide such as a silicon oxide.


The method 1200 continues at step 1215 by treating the support structure to form a treated support structure. Preferably, the upper end of the support structure is treated to increase adhesion to a subsequently-formed moveable layer. Treating the support structure to form a treated support structure may include, for example, roughening the upper end of the support structure and/or applying an adhesive layer over the upper end of the support structure. Thus, the resulting treated support structure may include, for example, a roughened surface (such as the roughened surface included in the bond 1005 illustrated in FIG. 10A) and/or a adhesive layer such as the adhesive layer included in the bond 1015 illustrated in FIG. 10B. Treating the support structure may include exposing the support structure to a roughening treatment such as a wet chemical etch, a dry chemical etch, and/or a plasma etch. Examples of roughening treatments include oxygen plasma burn down and sputter etching. In addition to or instead of roughening, treating the support structure may include depositing an adhesive layer by a deposition process such as, e.g., spin-on, plasma-enhanced chemical vapor deposition (PECVD), thermal chemical vapor deposition (thermal CVD), and/or PVD. In an embodiment, deposition of an adhesive layer comprises depositing a metal, wherein the metal comprises aluminum (e.g., an aluminum alloy). Treatment is preferably carried out to an extent that is effective to provide increased adhesion between the support structure and the subsequently-formed moveable layer, e.g., between the support structure 18 and the moveable layer 14 as illustrated in FIG. 10.


The method 1200 continues at step 1220 by forming a moveable layer on the treated support structure. The moveable reflective layer (e.g., the layer 14 as illustrated in FIGS. 1 and 7) may be formed by employing one or more deposition steps, e.g., reflective layer (e.g., aluminum, aluminum alloy) deposition, along with one or more patterning, masking, and/or etching steps. In an embodiment, formation of the moveable layer on a roughened surface at the upper end of the support structure forms a bond, e.g., the bond 1005 as illustrated in FIG. 10. In another embodiment, formation of the moveable layer on an adhesive layer at the upper end of the support structure forms a bond, e.g., the bonds 1015, 1035 as illustrated in FIG. 10.


It will be understood that additional steps (not illustrated in FIG. 12) in the fabrication of the interferometric modulator may also be conducted in accordance with the method 1200, e.g., deposition of a first reflective layer over the substrate, deposition of a sacrificial layer over the substrate and/or over the first reflective layer, deposition of a second reflective layer over the sacrificial layer, removal of the sacrificial layer to form a cavity positioned between the first reflective layer and the second reflective layer, and/or removal of the sacrificial layer to form a cavity positioned between the first reflective layer and the moveable layer.


The methods 1100, 1200 discussed above make reference in certain embodiments to forming bonds to the support structure 18 of an interferometric modulator of the general type shown in FIG. 7A. It will be understood that the illustrated methods may also be employed to form similar bonds between the support structures and the layers to which the support structures are attached in other types of interferometric modulators, including but not limited to the interferometric modulators illustrated in FIGS. 7B-E. For example, in an embodiment (not illustrated in FIG. 10), the method 1200 is employed to form a bond between a support structure and a moveable layer, and a reflective surface is formed that is suspended from the moveable layer, e.g., in the general manner illustrated in FIG. 7C. It will be appreciated that the methods 1100, 1200 may each be carried out individually, or combined into a single method. For example, the method 1100 may be conducted to form a bond between the substrate layer (e.g., the substrate 20 or the optical stack 16) and the support structure 18; the method 1200 may be conducted to form a bond between the support structure 18 and the moveable layer 14; and/or the methods 1100 and 1200 may be carried out together, e.g., to form bonds between the support structure 18 and both of the substrate layer (e.g., the substrate 20 or the optical stack 16) and the moveable layer 14.


While the above detailed description has shown, described, and pointed out novel features of the invention as applied to various embodiments, it will be understood that various omissions, substitutions, and changes in the form and details of the device or process illustrated may be made by those skilled in the art without departing from the spirit of the invention. As will be recognized, the present invention may be embodied within a form that does not provide all of the features and benefits set forth herein, as some features may be used or practiced separately from others.

Claims
  • 1. A microelectromechanical systems (MEMS) device, comprising: a substrate layer comprising a first reflective surface and a transparent substrate underlying the first reflective surface, the first reflective surface being partially transmissive, the first reflective surface formed on the transparent substrate;a movable layer comprising a second reflective surface, the second reflective surface being spaced from the first reflective surface to thereby define an interferometric cavity;a support structure positioned at a side of the cavity and configured to separate at least a portion of the substrate layer from at least a portion of the moveable layer; anda roughened interface between a surface of the support structure and a surface of the substrate layer connected to the surface of the support structure, the roughened interface being configured to increase adhesion between the support structure and the substrate layer.
  • 2. The MEMS device of claim 1, comprising an interferometric modulator.
  • 3. The MEMS device of claim 1, wherein the roughened interface comprises a roughened surface of the support structure.
  • 4. The MEMS device of claim 1, wherein the roughened interface comprises a roughened surface of the first reflective surface.
  • 5. The MEMS device of claim 1, wherein the second reflective surface is suspended from the moveable layer.
  • 6. The MEMS device of claim 1, further comprising an adhesive layer disposed at the roughened interface and connected to the support structure and the substrate layer.
  • 7. The MEMS device of claim 6, wherein the adhesive layer comprises aluminum.
  • 8. The MEMS device of claim 6, wherein the adhesive layer is connected to the support structure and the transparent substrate.
  • 9. The MEMS device of claim 6, wherein the adhesive layer is connected to the support structure and the first reflective surface.
  • 10. An interferometric modulator comprising: means for interferometrically modulating light, the modulating means comprising a fixed layer and a movable layer spaced apart from the fixed layer, the fixed layer comprising a first reflective surface formed on a transparent substrate, the first reflective surface being partially transmissive, the movable layer comprising a second reflective surface;means for supporting the moveable layer over the fixed layer; andmeans for bonding the support means to the fixed layer, the bonding means being formed on the fixed layer and comprising a roughened interface configured to increase adhesion between the supporting means and the fixed layer.
  • 11. The interferometric modulator of claim 10, wherein the bonding means further comprises an adhesive.
  • 12. The interferometric modulator of claim 10, wherein the support means comprises a post.
  • 13. A display device comprising the interferometric modulator of claim 2.
  • 14. The display device of claim 13, further comprising: a display;a processor that is in electrical communication with the display, the processor being configured to process image data;a memory device in electrical communication with the processor.
  • 15. The display device of claim 14, further comprising: a driver circuit configured to send at least one signal to the display.
  • 16. The display device of claim 15, further comprising: a controller configured to send at least a portion of the image data to the driver circuit.
  • 17. The display device of claim 14, further comprising: an image source module configured to send the image data to the processor.
  • 18. The display device of claim 17, wherein the image source module comprises at least one of a receiver, transceiver, and transmitter.
  • 19. The display device of claim 14, further comprising: an input device configured to receive input data and to communicate the input data to the processor.
  • 20. The MEMS device of claim 1, wherein the roughened interface comprises an etched surface of the support structure.
  • 21. The MEMS device of claim 1, wherein the roughened interface comprises an etched surface of the substrate layer.
  • 22. The MEMS device of claim 10, wherein the roughened interface comprises an etched surface of the support means.
  • 23. The MEMS device of claim 10, wherein the roughened interface comprises an etched surface of the fixed layer.
  • 24. The device of claim 1, wherein the roughened interface comprises a roughened surface of the transparent substrate.
  • 25. The device of claim 1, wherein the roughened interface comprises a roughened surface of the transparent substrate and a roughened surface of the support structure.
  • 26. The device of claim 1, wherein the roughened interface comprises a roughened surface of the support structure and a roughened surface of the first reflective surface.
CROSS-REFERENCE TO RELATED APPLICATIONS

This application claims priority to U.S. Provisional Application No. 60/613,499, filed Sep. 27, 2004, which is hereby incorporated by reference in its entirety.

US Referenced Citations (477)
Number Name Date Kind
2534846 Ambrose et al. Dec 1950 A
3439973 Paul et al. Apr 1969 A
3443854 Weiss May 1969 A
3653741 Marks Apr 1972 A
3656836 de Cremoux et al. Apr 1972 A
3725868 Malmer, Jr. et al. Apr 1973 A
3728030 Hawes Apr 1973 A
3813265 Marks May 1974 A
3955880 Lierke May 1976 A
3955190 Teraishi Jun 1976 A
4099854 Decker et al. Jul 1978 A
4196396 Smith Apr 1980 A
4228437 Shelton Oct 1980 A
4377324 Durand et al. Mar 1983 A
4389096 Hori et al. Jun 1983 A
4392711 Moraw et al. Jul 1983 A
4403248 te Velde Sep 1983 A
4441791 Hornbeck Apr 1984 A
4445050 Marks Apr 1984 A
4459182 te Velde Jul 1984 A
4482213 Piliavin et al. Nov 1984 A
4500171 Penz et al. Feb 1985 A
4519676 te Velde May 1985 A
4531126 Sadones Jul 1985 A
4566935 Hornbeck Jan 1986 A
4571603 Hornbeck et al. Feb 1986 A
4596992 Hornbeck Jun 1986 A
4615595 Hornbeck Oct 1986 A
4662746 Hornbeck May 1987 A
4663083 Marks May 1987 A
4666254 Itoh et al. May 1987 A
4681403 te Velde et al. Jul 1987 A
4710732 Hornbeck Dec 1987 A
4748366 Taylor May 1988 A
4786128 Birnbach Nov 1988 A
4790635 Apsley Dec 1988 A
4856863 Sampsell et al. Aug 1989 A
4857978 Goldburt et al. Aug 1989 A
4859060 Katagiri et al. Aug 1989 A
4900136 Goldburt et al. Feb 1990 A
4900395 Syverson et al. Feb 1990 A
4937496 Neiger et al. Jun 1990 A
4954789 Sampsell Sep 1990 A
4956619 Hornbeck Sep 1990 A
4965562 Verhulst Oct 1990 A
4982184 Kirkwood Jan 1991 A
5018256 Hornbeck May 1991 A
5022745 Zahowski et al. Jun 1991 A
5028939 Hornbeck et al. Jul 1991 A
5037173 Sampsell et al. Aug 1991 A
5044736 Jaskie et al. Sep 1991 A
5061049 Hornbeck Oct 1991 A
5075796 Schildkraut et al. Dec 1991 A
5078479 Vuilleumier Jan 1992 A
5079544 DeMond et al. Jan 1992 A
5083857 Hornbeck Jan 1992 A
5091983 Lukosz Feb 1992 A
5096279 Hornbeck et al. Mar 1992 A
5099353 Hornbeck Mar 1992 A
5124834 Cusano et al. Jun 1992 A
5136669 Gerdt Aug 1992 A
5142405 Hornbeck Aug 1992 A
5142414 Koehler Aug 1992 A
5153771 Link et al. Oct 1992 A
5162787 Thompson et al. Nov 1992 A
5168406 Nelson Dec 1992 A
5170156 DeMond et al. Dec 1992 A
5170283 O'Brien et al. Dec 1992 A
5172262 Hornbeck Dec 1992 A
5179274 Sampsell Jan 1993 A
5192395 Boysel et al. Mar 1993 A
5192946 Thompson et al. Mar 1993 A
5206629 DeMond et al. Apr 1993 A
5212582 Nelson May 1993 A
5214419 DeMond et al. May 1993 A
5214420 Thompson et al. May 1993 A
5216537 Hornbeck Jun 1993 A
5226099 Mignardi et al. Jul 1993 A
5228013 Bik Jul 1993 A
5231532 Magel et al. Jul 1993 A
5233385 Sampsell Aug 1993 A
5233456 Nelson Aug 1993 A
5233459 Bozler et al. Aug 1993 A
5254980 Hendrix et al. Oct 1993 A
5272473 Thompson et al. Dec 1993 A
5278652 Urbanus et al. Jan 1994 A
5280277 Hornbeck Jan 1994 A
5287096 Thompson et al. Feb 1994 A
5293272 Jannson et al. Mar 1994 A
5296950 Lin et al. Mar 1994 A
5305640 Boysel et al. Apr 1994 A
5311360 Bloom et al. May 1994 A
5312513 Florence et al. May 1994 A
5315370 Bulow May 1994 A
5323002 Sampsell et al. Jun 1994 A
5324683 Fitch et al. Jun 1994 A
5325116 Sampsell Jun 1994 A
5326430 Cronin et al. Jul 1994 A
5327286 Sampsell et al. Jul 1994 A
5331454 Hornbeck Jul 1994 A
5339116 Urbanus et al. Aug 1994 A
5345328 Fritz et al. Sep 1994 A
5353170 Fung et al. Oct 1994 A
5355357 Yamamori et al. Oct 1994 A
5358601 Cathey Oct 1994 A
5365283 Doherty et al. Nov 1994 A
5381232 Van Wijk Jan 1995 A
5381253 Sharp et al. Jan 1995 A
5401983 Jokerst et al. Mar 1995 A
5411769 Hornbeck May 1995 A
5444566 Gale et al. Aug 1995 A
5446479 Thompson et al. Aug 1995 A
5448314 Heimbuch et al. Sep 1995 A
5452024 Sampsell Sep 1995 A
5454906 Baker et al. Oct 1995 A
5457493 Leddy et al. Oct 1995 A
5457566 Sampsell et al. Oct 1995 A
5459602 Sampsell Oct 1995 A
5459610 Bloom et al. Oct 1995 A
5461411 Florence et al. Oct 1995 A
5471341 Warde et al. Nov 1995 A
5474865 Vasudev Dec 1995 A
5489952 Gove et al. Feb 1996 A
5497172 Doherty et al. Mar 1996 A
5497197 Gove et al. Mar 1996 A
5499037 Nakagawa et al. Mar 1996 A
5499062 Urbanus Mar 1996 A
5500635 Mott Mar 1996 A
5500761 Goossen et al. Mar 1996 A
5506597 Thompson et al. Apr 1996 A
5515076 Thompson et al. May 1996 A
5517347 Sampsell May 1996 A
5523803 Urbanus et al. Jun 1996 A
5526051 Gove et al. Jun 1996 A
5526172 Kanack Jun 1996 A
5526327 Cordova, Jr. Jun 1996 A
5526688 Boysel et al. Jun 1996 A
5535047 Hornbeck Jul 1996 A
5535526 White Jul 1996 A
5548301 Kornher et al. Aug 1996 A
5551293 Boysel et al. Sep 1996 A
5552924 Tregilgas Sep 1996 A
5552925 Worley Sep 1996 A
5559358 Burns et al. Sep 1996 A
5563398 Sampsell Oct 1996 A
5567334 Baker et al. Oct 1996 A
5570135 Gove et al. Oct 1996 A
5579149 Moret et al. Nov 1996 A
5581272 Conner et al. Dec 1996 A
5583688 Hornbeck Dec 1996 A
5589852 Thompson et al. Dec 1996 A
5597736 Sampsell Jan 1997 A
5600383 Hornbeck Feb 1997 A
5602671 Hornbeck Feb 1997 A
5606441 Florence et al. Feb 1997 A
5608468 Gove et al. Mar 1997 A
5610438 Wallace et al. Mar 1997 A
5610624 Bhuva Mar 1997 A
5610625 Sampsell Mar 1997 A
5614937 Nelson Mar 1997 A
5619059 Li et al. Apr 1997 A
5619365 Rhoades et al. Apr 1997 A
5619366 Rhoads et al. Apr 1997 A
5629790 Neukermans et al. May 1997 A
5633652 Kanbe et al. May 1997 A
5636052 Arney et al. Jun 1997 A
5636185 Brewer et al. Jun 1997 A
5638084 Kalt Jun 1997 A
5638946 Zavracky Jun 1997 A
5641391 Hunter et al. Jun 1997 A
5646729 Koskinen et al. Jul 1997 A
5646768 Kaeriyama Jul 1997 A
5650881 Hornbeck Jul 1997 A
5654741 Sampsell et al. Aug 1997 A
5657099 Doherty et al. Aug 1997 A
5659374 Gale, Jr. et al. Aug 1997 A
5661591 Lin et al. Aug 1997 A
5661592 Bornstein et al. Aug 1997 A
5665997 Weaver et al. Sep 1997 A
5673139 Johnson Sep 1997 A
5683591 Offenberg Nov 1997 A
5703710 Brinkman et al. Dec 1997 A
5710656 Goosen Jan 1998 A
5726480 Pister Mar 1998 A
5739945 Tayebati Apr 1998 A
5740150 Uchimaru et al. Apr 1998 A
5745193 Urbanus et al. Apr 1998 A
5745281 Yi et al. Apr 1998 A
5751469 Arney et al. May 1998 A
5771116 Miller et al. Jun 1998 A
5784190 Worley Jul 1998 A
5784212 Hornbeck Jul 1998 A
5786927 Greywall et al. Jul 1998 A
5793504 Stoll Aug 1998 A
5808780 McDonald Sep 1998 A
5808781 Arney et al. Sep 1998 A
5818095 Sampsell Oct 1998 A
5825528 Goosen Oct 1998 A
5835255 Miles Nov 1998 A
5838484 Goossen et al. Nov 1998 A
5842088 Thompson Nov 1998 A
5867302 Fleming Feb 1999 A
5905482 Hughes et al. May 1999 A
5912758 Knipe et al. Jun 1999 A
5943158 Ford et al. Aug 1999 A
5959763 Bozler et al. Sep 1999 A
5986796 Miles Nov 1999 A
5994174 Carey et al. Nov 1999 A
6028689 Michalicek et al. Feb 2000 A
6028690 Carter et al. Feb 2000 A
6038056 Florence et al. Mar 2000 A
6040937 Miles Mar 2000 A
6046840 Huibers Apr 2000 A
6049317 Thompson et al. Apr 2000 A
6055090 Miles Apr 2000 A
6056406 Park et al. May 2000 A
6061075 Nelson et al. May 2000 A
6097145 Kastalsky et al. Aug 2000 A
6099132 Kaeriyama Aug 2000 A
6100872 Aratani et al. Aug 2000 A
6113239 Sampsell et al. Sep 2000 A
6147790 Meier et al. Nov 2000 A
6158156 Patrick Dec 2000 A
6160833 Floyd et al. Dec 2000 A
6171945 Mandal et al. Jan 2001 B1
6172797 Huibers Jan 2001 B1
6180428 Peeters et al. Jan 2001 B1
6201633 Peeters et al. Mar 2001 B1
6215221 Cabuz et al. Apr 2001 B1
6232936 Gove et al. May 2001 B1
6239777 Atsushi et al. May 2001 B1
6243149 Swanson et al. Jun 2001 B1
6262697 Stephenson Jul 2001 B1
6282010 Sulzbach et al. Aug 2001 B1
6288472 Cabuz et al. Sep 2001 B1
6288824 Kastalsky Sep 2001 B1
6295154 Laor et al. Sep 2001 B1
6297072 Tilmans et al. Oct 2001 B1
6323982 Hornbeck Nov 2001 B1
6327071 Kimura Dec 2001 B1
6331909 Dunfield Dec 2001 B1
6335831 Kowarz et al. Jan 2002 B2
6356254 Kimura Mar 2002 B1
6356378 Huibers Mar 2002 B1
6358021 Cabuz Mar 2002 B1
6376787 Martin et al. Apr 2002 B1
6384952 Clark et al. May 2002 B1
6407851 Islam et al. Jun 2002 B1
6417868 Reinhart et al. Jul 2002 B1
6433917 Mei et al. Aug 2002 B1
6438282 Takeda et al. Aug 2002 B1
6447126 Hornbeck Sep 2002 B1
6449084 Guo Sep 2002 B1
6452712 Atobe et al. Sep 2002 B2
6456420 Goodwin-Johansson Sep 2002 B1
6465355 Horsley Oct 2002 B1
6466190 Evoy Oct 2002 B1
6466354 Gudeman Oct 2002 B1
6466358 Tew Oct 2002 B2
6473072 Comiskey et al. Oct 2002 B1
6473274 Maimone et al. Oct 2002 B1
6480177 Doherty et al. Nov 2002 B2
6496122 Sampsell Dec 2002 B2
6545335 Chua et al. Apr 2003 B1
6548908 Chua et al. Apr 2003 B2
6549338 Wolverton et al. Apr 2003 B1
6552840 Knipe Apr 2003 B2
6556338 Han et al. Apr 2003 B2
6574033 Chui et al. Jun 2003 B1
6589625 Kothari et al. Jul 2003 B1
6597490 Tayebati Jul 2003 B2
6600201 Hartwell et al. Jul 2003 B2
6606175 Sampsell et al. Aug 2003 B1
6608268 Goldsmith Aug 2003 B1
6624944 Wallace et al. Sep 2003 B1
6625047 Coleman, Jr. Sep 2003 B2
6630786 Cummings et al. Oct 2003 B2
6632698 Ives Oct 2003 B2
6635919 Melendez et al. Oct 2003 B1
6643069 Dewald Nov 2003 B2
6650455 Miles Nov 2003 B2
6657832 Williams et al. Dec 2003 B2
6660656 Cheung et al. Dec 2003 B2
6661561 Fitzpatrick et al. Dec 2003 B2
6666561 Blakley Dec 2003 B1
6674033 Chui et al. Jan 2004 B1
6674090 Chua et al. Jan 2004 B1
6674562 Miles et al. Jan 2004 B1
6680792 Miles Jan 2004 B2
6698295 Sherrer Mar 2004 B1
6710908 Miles et al. Mar 2004 B2
6741377 Miles May 2004 B2
6741383 Huibers et al. May 2004 B2
6741384 Martin et al. May 2004 B1
6741503 Farris et al. May 2004 B1
6747785 Chen et al. Jun 2004 B2
6747800 Lin Jun 2004 B1
6775174 Huffman et al. Aug 2004 B2
6778155 Doherty et al. Aug 2004 B2
6794119 Miles Sep 2004 B2
6809788 Yamada et al. Oct 2004 B2
6811267 Allen et al. Nov 2004 B1
6813059 Hunter et al. Nov 2004 B2
6819469 Koba Nov 2004 B1
6822628 Dunphy et al. Nov 2004 B2
6829132 Martin et al. Dec 2004 B2
6841081 Chang et al. Jan 2005 B2
6844959 Huibers et al. Jan 2005 B2
6853129 Cummings et al. Feb 2005 B1
6855610 Tung et al. Feb 2005 B2
6859218 Luman et al. Feb 2005 B1
6861277 Monroe et al. Mar 2005 B1
6862022 Slupe Mar 2005 B2
6862029 D'Souza et al. Mar 2005 B1
6867896 Miles Mar 2005 B2
6870581 Li et al. Mar 2005 B2
6870654 Lin et al. Mar 2005 B2
6882458 Lin et al. Apr 2005 B2
6882461 Tsai et al. Apr 2005 B1
6891658 Whitehead et al. May 2005 B2
6912022 Lin et al. Jun 2005 B2
6940630 Xie Sep 2005 B2
6947200 Huibers Sep 2005 B2
6952303 Lin et al. Oct 2005 B2
6958847 Lin Oct 2005 B2
6959990 Penn Nov 2005 B2
6980350 Hung et al. Dec 2005 B2
7008812 Carley Mar 2006 B1
7053737 Schwartz et al. May 2006 B2
7075700 Muenter Jul 2006 B2
7123216 Miles Oct 2006 B1
7236284 Miles Jun 2007 B2
20010003487 Miles Jun 2001 A1
20010028503 Flanders et al. Oct 2001 A1
20010043171 Van Gorkom et al. Nov 2001 A1
20020014579 Dunfield Feb 2002 A1
20020015215 Miles Feb 2002 A1
20020021485 Pilossof Feb 2002 A1
20020024711 Miles Feb 2002 A1
20020027636 Yamada Mar 2002 A1
20020054422 Carr et al. May 2002 A1
20020054424 Miles May 2002 A1
20020070931 Ishikawa Jun 2002 A1
20020075555 Miles Jun 2002 A1
20020114558 Nemirovsky Aug 2002 A1
20020126364 Miles Sep 2002 A1
20020139981 Young Oct 2002 A1
20020146200 Kurdle et al. Oct 2002 A1
20020149828 Miles Oct 2002 A1
20020149850 Heffner et al. Oct 2002 A1
20020167072 Andosca Nov 2002 A1
20020167730 Needham et al. Nov 2002 A1
20020186483 Hagelin et al. Dec 2002 A1
20030015936 Yoon et al. Jan 2003 A1
20030016428 Kato et al. Jan 2003 A1
20030021004 Cunningham et al. Jan 2003 A1
20030029705 Qiu et al. Feb 2003 A1
20030035196 Walker Feb 2003 A1
20030043157 Miles Mar 2003 A1
20030053078 Missey et al. Mar 2003 A1
20030053233 Felton Mar 2003 A1
20030072070 Miles Apr 2003 A1
20030156315 Li et al. Aug 2003 A1
20030202264 Weber et al. Oct 2003 A1
20030202265 Reboa et al. Oct 2003 A1
20030202266 Ring et al. Oct 2003 A1
20030210851 Fu et al. Nov 2003 A1
20040008396 Stappaerts Jan 2004 A1
20040008438 Sato Jan 2004 A1
20040027671 Wu et al. Feb 2004 A1
20040027701 Ishikawa Feb 2004 A1
20040043552 Strumpell et al. Mar 2004 A1
20040051929 Sampsell et al. Mar 2004 A1
20040056742 Dabbaj Mar 2004 A1
20040058532 Miles et al. Mar 2004 A1
20040075967 Lynch et al. Apr 2004 A1
20040080035 Delapierre Apr 2004 A1
20040080807 Chen et al. Apr 2004 A1
20040100594 Huibers et al. May 2004 A1
20040100677 Huibers et al. May 2004 A1
20040100680 Huibers et al. May 2004 A1
20040107775 Kim Jun 2004 A1
20040124483 Partridge et al. Jul 2004 A1
20040125281 Lin Jul 2004 A1
20040125282 Lin et al. Jul 2004 A1
20040125347 Patel et al. Jul 2004 A1
20040136045 Tran Jul 2004 A1
20040140557 Sun et al. Jul 2004 A1
20040145049 McKinnell et al. Jul 2004 A1
20040145811 Lin et al. Jul 2004 A1
20040147056 McKinnell et al. Jul 2004 A1
20040147198 Lin et al. Jul 2004 A1
20040148009 Buzzard et al. Jul 2004 A1
20040150939 Huff Aug 2004 A1
20040160143 Shreeve et al. Aug 2004 A1
20040174583 Chen et al. Sep 2004 A1
20040175577 Lin et al. Sep 2004 A1
20040179281 Reboa Sep 2004 A1
20040179445 Park et al. Sep 2004 A1
20040184766 Kim et al. Sep 2004 A1
20040201908 Kaneko Oct 2004 A1
20040207897 Lin Oct 2004 A1
20040209192 Lin et al. Oct 2004 A1
20040209195 Lin Oct 2004 A1
20040212026 Van Brocklin et al. Oct 2004 A1
20040217378 Martin et al. Nov 2004 A1
20040217919 Pichl et al. Nov 2004 A1
20040218251 Piehl et al. Nov 2004 A1
20040218334 Martin et al. Nov 2004 A1
20040218341 Martin et al. Nov 2004 A1
20040227493 Van Brocklin et al. Nov 2004 A1
20040233503 Kimura Nov 2004 A1
20040240032 Miles Dec 2004 A1
20040240138 Martin et al. Dec 2004 A1
20040245588 Nikkel et al. Dec 2004 A1
20040263944 Miles et al. Dec 2004 A1
20050001828 Martin et al. Jan 2005 A1
20050002082 Miles Jan 2005 A1
20050003667 Lin et al. Jan 2005 A1
20050014374 Partridge et al. Jan 2005 A1
20050024557 Lin Feb 2005 A1
20050035699 Tsai Feb 2005 A1
20050036095 Yeh et al. Feb 2005 A1
20050036192 Lin et al. Feb 2005 A1
20050038950 Adelmann Feb 2005 A1
20050042117 Lin Feb 2005 A1
20050046919 Taguchi et al. Mar 2005 A1
20050046922 Lin et al. Mar 2005 A1
20050046948 Lin Mar 2005 A1
20050057442 Way Mar 2005 A1
20050068583 Gutkowski et al. Mar 2005 A1
20050068605 Tsai Mar 2005 A1
20050068606 Tsai Mar 2005 A1
20050069209 Damera-Venkata et al. Mar 2005 A1
20050078348 Lin Apr 2005 A1
20050157364 Lin Jul 2005 A1
20050168849 Lin Aug 2005 A1
20050195462 Lin Sep 2005 A1
20050195467 Kothari et al. Sep 2005 A1
20050202649 Hung et al. Sep 2005 A1
20050206991 Chui et al. Sep 2005 A1
20050249966 Tung et al. Nov 2005 A1
20060007517 Tsai Jan 2006 A1
20060024880 Chui et al. Feb 2006 A1
20060044654 Vandorpe et al. Mar 2006 A1
20060056000 Mignard Mar 2006 A1
20060065940 Kothari et al. Mar 2006 A1
20060066599 Chui et al. Mar 2006 A1
20060066640 Kothari et al. Mar 2006 A1
20060066935 Cummings et al. Mar 2006 A1
20060067643 Kothari et al. Mar 2006 A1
20060067651 Chui Mar 2006 A1
20060077152 Chui et al. Apr 2006 A1
20060077155 Chui et al. Apr 2006 A1
20060077156 Chui et al. Apr 2006 A1
20060077507 Chui et al. Apr 2006 A1
20060077508 Chui et al. Apr 2006 A1
20060077515 Cummings et al. Apr 2006 A1
20060077516 Kothari Apr 2006 A1
20060077527 Kothari et al. Apr 2006 A1
20060077533 Miles et al. Apr 2006 A1
20060079048 Sampsell Apr 2006 A1
20060139723 Miles Jun 2006 A9
20060220160 Miles Oct 2006 A1
20060262126 Miles Nov 2006 A1
20060262380 Miles Nov 2006 A1
20060268388 Miles Nov 2006 A1
20060274074 Miles Dec 2006 A1
20070177247 Miles Aug 2007 A1
20080037093 Miles Feb 2008 A1
20080088904 Miles Apr 2008 A1
20080088910 Miles Apr 2008 A1
20080088911 Miles Apr 2008 A1
20080088912 Miles Apr 2008 A1
20080106782 Miles May 2008 A1
20090068781 Tung et al. Mar 2009 A1
20090080060 Sampsell et al. Mar 2009 A1
Foreign Referenced Citations (55)
Number Date Country
157313 May 1991 CN
4108966 Aug 1992 DE
10228946 Jan 2004 DE
0 310 176 Apr 1989 EP
0 361 981 Apr 1990 EP
0 667 548 Aug 1995 EP
0 788 005 Aug 1997 EP
1 122 577 Aug 2001 EP
1275997 Jan 2003 EP
1 435 336 Jul 2004 EP
1 473 691 Nov 2004 EP
1473581 Nov 2004 EP
1484635 Dec 2004 EP
2 824 643 Nov 2002 FR
62 082454 Apr 1987 JP
05275401 Oct 1993 JP
9-127439 May 1997 JP
11211999 Aug 1999 JP
11211999 Nov 1999 JP
2000306515 Nov 2000 JP
2001-221913 Aug 2001 JP
2002-062490 Feb 2002 JP
2002-221678 Aug 2002 JP
2002277771 Sep 2002 JP
2003-340795 Feb 2003 JP
2003-195201 Jul 2003 JP
2003195201 Jul 2003 JP
2004157527 Jun 2004 JP
2004-212638 Jul 2004 JP
2004-212680 Jul 2004 JP
2004235465 Aug 2004 JP
2004286825 Oct 2004 JP
WO9530924 Nov 1995 WO
WO9717628 May 1997 WO
WO9952006 Oct 1999 WO
WO9952006 Oct 1999 WO
WO 02079853 Oct 2002 WO
WO03007049 Jan 2003 WO
WO 03014789 Feb 2003 WO
WO 03054925 Jul 2003 WO
WO 03054925 Jul 2003 WO
WO 03069404 Aug 2003 WO
WO 03069413 Aug 2003 WO
WO03069413 Aug 2003 WO
WO03073151 Sep 2003 WO
WO 03085728 Oct 2003 WO
WO 2004006003 Jan 2004 WO
WO2004006003 Jan 2004 WO
WO04026757 Apr 2004 WO
WO 2005006364 Jan 2005 WO
PCTUS2005026448 Jul 2005 WO
PCTUS2005030962 Aug 2005 WO
PCTUS2005034465 Sep 2005 WO
PCTUS2005029850 Dec 2005 WO
WO 2006014929 Feb 2006 WO
Related Publications (1)
Number Date Country
20060067649 A1 Mar 2006 US
Provisional Applications (1)
Number Date Country
60613499 Sep 2004 US