This disclosure relates in general to the field of solar photovoltaics, and more particularly to the field of repeatedly fabricating thin film solar substrates from a semiconductor template.
In the field of photovoltaics, this disclosure enables low cost fabrication of thin film substrates to be used for solar cell manufacturing by means of a template which can be used repeatedly to fabricate said thin film substrates. The field of this disclosure covers several apparatuses and methods for generating thin film substrates and for treating the templates which are used to produce the thin film substrates, with the goal of recovering the templates to enable an extended number of re-uses.
Crystalline silicon (including multi- and mono-crystalline silicon) is the most dominant absorber material for commercial photovoltaic applications. The relatively high efficiencies associated with mass-produced crystalline silicon solar cells, combined with the abundance of material, garner appeal for continued use and advancement. But the relatively high cost of crystalline silicon material itself limits the widespread use of these solar modules. At present, the cost of “wafering”, or crystallizing silicon and cutting a wafer, accounts for about 40% to 60% of the finished solar module manufacturing cost. If a more direct way of making wafers were possible, great headway could be made in lowering the cost of solar cells.
There are different known methods of growing monocrystalline silicon and releasing or transferring the grown wafer. Regardless of the methods, a low cost epitaxial silicon deposition process accompanied by a high-volume, production-worthy, low cost method of forming a release layer are prerequisites for wider use of silicon solar cells.
Another prerequisite is the availability of a re-usable template to repeatedly perform the sequence of release layer formation, thin film deposition, on-template processing, thin film layer release, recovery/reconditioning of template.
The microelectronics industry achieves economy of scale through obtaining greater yield by increasing the number of die (or chips) per wafer, scaling the wafer size, and enhancing the chip functionality (or integration density) with each successive new product generation. In the solar industry, economy is achieved through the industrialization of solar cell and module manufacturing processes with low cost high productivity equipment. Further economies are achieved through price reduction in raw materials through reduction of materials used per watt output of solar cells.
In order to achieve the necessary economy for the solar photovoltaics industry, process cost modeling is studied to identify and optimize equipment performance. Several categories of cost make up the total cost picture: Fixed Cost (FC), Recurring Cost (RC) and Yield Cost (YC). FC is made up of items such as equipment purchase price, installation cost and robotics or automation cost. RC is largely made up of electricity, gases, chemicals, operator salaries and maintenance technician support. YC may be interpreted as the total value of parts lost during production.
To achieve Cost of Ownership (CoO) numbers required by the solar field, all aspects of the cost picture must be optimized. The qualities of a low cost process are (in order of priority): 1) High productivity, 2) High yield, 3) Low RC, and 4) Low FC.
Designing highly productive and economical methods and process equipment requires a good understanding of the process requirements and reflecting those requirements into the equipment architecture. High yield requires a robust process and reliable equipment and as equipment productivity increases, so too does yield cost. Low RC is also a prerequisite for overall low CoO. RC can impact plant site selection based on, for example, cost of local power or availability of bulk chemicals. FC, although important, is diluted by equipment productivity.
With the above said, in summary, a high productivity, reliable, efficient manufacturing process flow and equipment is a prerequisite for low cost solar cells.
The use of a reusable semiconductor template for the production of thin film semiconductor substrates (TFSSs) allows significant cost reduction in the field of solar photovoltaics. A sacrificial release layer is produced on the template, and then a TFSS is deposited on the sacrificial layer. However, when the TFSS is released from the template, residual film may be left behind. This disclosure deals primarily with ways of removing that residuum and preparing the template for reuse.
The features, nature, and advantages of the disclosed subject matter will become more apparent from the detailed description set forth below when taken in conjunction with the drawings, in which like reference numerals indicate like features and wherein:
Although the present disclosure is described with reference to specific embodiments, one skilled in the art could apply the principles discussed herein to other areas and/or embodiments without undue experimentation.
This disclosure includes process flows, unit processes, and apparatuses, and variations thereof which enable the repeated use of a template that is used in the fabrication of thin film layers which subsequently are processed to become solar cells.
This disclosure includes a starting semiconductor wafer (called a template) with correct resistivity to enable anodization to form porous semiconductor material on one or both sides. The semiconductors used may include silicon, and in particular monocrystalline silicon. The template outline can be of any suitable shape, including round (with or without notches or flats), square, or pseudo-square with rounded or chamfered corners. The porous semiconductor material may consist of several layers with discrete or graded porosity. At least one section of the porous semiconductor layer system serves as a designated weakened layer that facilitates separation of the TFSS from the template.
This disclosure covers the use of a template for repeatedly fabricating thin crystalline solar cell substrates from the template; the solar cell substrates can be fabricated on one side of the template or on both sides of the template. Even though the figures in this disclosure specifically address the single sided processing, it is envisioned that all embodiments of the current disclosure hold essentially for the case of single sided substrate processing as well as for double side substrate processing.
Regarding the starting wafer, several structural architecture options exist which are described in the following. In the simplest embodiment, the template can be essentially flat, i.e. the surface can be of any chosen surface quality, such as for example as-sawn with saw damage removed, lapped or ground, etched or even mirror polished. In another embodiment, the wafer can be textured, using for instance alkaline random texturing before the formation of the above-described porous semiconductor layer system. By this means, a textured surface is then transferred directly onto the thin film solar cell substrate. As a third alternative, the template can receive a patterned three-dimensional structure. This three-dimensional structure may be achieved through the use of patterning technology, such as, but not exclusively, photolithography.
An example process is described in
In
A three-dimensional template patterning is depicted in most figures of this disclosure as it encompasses a larger realm of embodiments. However, unless otherwise noted, the figures, process flows, methods and apparatuses of this disclosure are equally applicable to flat or randomly textured templates.
With either a patterned or an un-patterned template prepared, the subsequent process step is porous semiconductor formation, followed by rinsing and drying where necessary. Porous semiconductor is to be formed on at least one side of the template. For the case that the semiconductor is silicon, the process of forming porous silicon has been described in previous disclosures, for example U.S. Patent Publication No. 2011/0030610, which is hereby incorporated by reference. Fundamentally, the porous semiconductor formation entails the fabrication of at least one lower porosity region 112 at the surface and at least one higher porosity layer 114 closer to the template.
The template with the porous semiconductor layers formed is then transferred to an epitaxial deposition reactor, in which an epitaxial layer is deposited at least on one side of the template.
Before the deposition, either during the ramp-up phase or during a separate pre-deposition time, the template is kept in a hydrogen ambient which serves several purposes: the top layer of the porous semiconductor is reflowed to re-form a quasi-monocrystalline growth surface of semiconductor (QMS). Also, the hydrogen bake serves to reduce any oxidized surface semiconductor back to its elemental form. In addition, the high porosity semiconductor layer coalesces to form a weak layer which can later serve as the release boundary between the grown layer and the template.
If the semiconductor is silicon, then in the initial stages of the deposition or during the bake, the reflow can be assisted by small amounts of a non-chlorine-containing species such as silane or using very low flow quantities of other silicon-containing gases such as trichlorosilane (TCS). This is one option for a process component that serves to safely prevent a failure mechanism that may occur during imperfect reflow and which is described below.
There are potential failure mechanisms that can occur during reflow. Several mitigations to such failure mechanisms are part of this disclosure: as the template is heated up in the semiconductor deposition reactor, which can for example be an epitaxial reactor, the template touches the susceptor typically in a plurality of locations. These contact points can contribute to a non-ideality in the above-described reflow of the porous semiconductor layer. These contact points can also contribute to a local abrasion of the porous semiconductor layer. As a consequence, the porous semiconductor layer may contain local areas where it is not hermetic.
An example of a failure mechanism is illustrated in
As for the epitaxial deposition process, the TFSS that is deposited epitaxially may contain an in-situ emitter, deposited in the semiconductor deposition chamber. The emitter may also be added later as an ex-situ emitter outside of the epitaxy chamber. The structure on the template may be with the emitter up or down. The epitaxial or non-epitaxial deposition may or may not contain a suitable dopant gradient designed to aid the desired flow of generated carriers through the device.
This so fabricated layer structure of deposited semiconductor on a weakened layer on a high temperature capable template is extremely valuable. It allows for carrying a thin film on a solid template and allows much flexibility for what is in the following called on-template processing.
In such on-template processing, the template serves as a carrier to move and support the thin and fragile TFSS throughout several on-template process steps, including but not limited to the following: thermal processes such as oxidation or film deposition, including but not limited to thermal oxidation; nanosecond (ns), picoseconds (ps) or other laser processes, such as scribing, doping, or ablation; chemical vapor deposition (CVD) and physical vapor deposition (PVD) processes; lithography, screen printing, ink jet printing, spray coating or etching, immersion clean, etch or deposition (such as plating), lamination, die attach or bonding, releasing, wet chemical texturing or dry texturing of the surface, rinsing, cleaning and drying of the surface. A unique quality here is that the template is clean and solar-cell-compatible, rigid and sturdy, high-temperature-capable, and reworkable.
After suitable on-template processing, the TFSS can be released from the template carrier. A conceptual diagram of the release of TFSS 116 from template 100 is shown in
This border cutting can be performed before or after the release of the TFSS. It may be advantageous to do cutting both before and after the release, depending on reinforcement process and materials. The border cutting also serves to weaken the thin TFSS and thus facilitate easier release. Another potential method for facilitating easier release is the use of a grinding or otherwise abrasive method, preferably applied to the edge of the template. By doing so, the TFSS epitaxial layer region at the edge of the template can serve as the weak point, from which release can be initiated. Such pre-release grinding can also facilitate the flow of air into the weakened area between TFSS 116 and template 100, thereby allowing pressure equalization and removing pressure-differential-induced resistance to the release motion. The release itself can be carried out by exploiting the presence of local weak areas which serve as initiation locations for the release.
Optionally, a pulsed force, for instance by pulsating the vacuum on either side of the template and substrate sandwich, can be applied. In this way, the release process can be extended across location and time (not unlike opening a zipper), rather than having to overcome the whole area bond force plus the atmospheric pressure holding force on the template. Alternatively, the release can be initiated at an edge or a corner of a substrate and then proceed from there, while in the process keeping the template and the partially released TFSS essentially parallel, in order to avoid small curvature radii, which can contribute to excessive stresses and potential cracking of the active TFSS layer.
After release of the active TFSS there may be residual deposited thin film that is remaining outside of the active area, especially if the template is somewhat oversized with respect to the active TFSS.
However, a typical CVD deposition process can deposit material not just on the front side, but depending on the design, also on the edges and the back side of the template. The extent of the film coverage is illustrated in template 210. Thick deposition of semiconductor layer in the bevel area can be undesirable. Depending on the process, deposition on the backside can be detrimental for subsequent processing, or desired, if the backside deposition yields a comparable film to the front side deposition in the case of double side processing. Several precautions may be taken in order to wind up with a template like template 200 instead of template 210. One mode for avoiding or minimizing backside and bevel deposition is to use a neutral gas, such as hydrogen, as a purge gas in the vicinity of the edge and the backside of the template during the deposition step. Another mode for avoiding or minimizing backside and bevel deposition is to use a shadow mask that shadows the area where deposition is not desired from the deposition gas. A third mode for reducing backside and bevel deposition is to use susceptor designs with large surface area or otherwise optimized geometries which can serve to preferentially deposit material from the gas phase, thereby depleting the deposition gas in areas where deposition is not desired. Deposition processes may have preferred locations and directions where more or less material is deposited in undesirable areas. It may be advantageous to symmetrize the deposition of the undesired material across several re-uses of the same template. For that purpose, the template orientation can be tracked where needed, and dedicated changes of orientation or location can be programmed as part of a production flow.
In template 210, porous silicon layer 212 wraps partially around the edge of the template, but TFSS 214 wraps around even farther. Under circumstances where the TFSS extends beyond the edge of the porous semiconductor, other methods may be employed to remove the section of the TFSS that directly contacts the template.
The removal of the residual deposited thin film can be accomplished on a single wafer basis or in a batch mode. The removal processes described so far are designed to remove material at least in the flat part of the template outside of the active area and extending onto the bevel of the template at the bevel edge. Other methods may be used to remove the remainder 220 of the TFSS that is bonded directly to template 210 due to local lacking or imperfect quality of the porous semiconductor layer.
Independent of the precautions mentioned above, it may be advantageous to remove excess deposited material in the bevel or the backside area. This removal of excess deposited material may be carried out after each re-use cycle or after several re-use cycles and may be repeated throughout the lifetime of the template.
In
Another alternative process to the tape, sheet or precision bevel grind/polish step is the use of a laser, either direct or water-jet-guided, to remove excess deposition at the bevel and the underside of the template and reshape the bevel. The effect of a laser based bevel material removal process is shown in
In some cases, the processes described above in conjunction with
After the removal of the undesired TFSS material by whatever method, a typical flow may include re-use cleaning, which serves several purposes: first, to bring the template into a re-usable condition, capable of withstanding repeated re-uses; second, to remove remnants of the sacrificial release layer; next, to remove metallic contaminants that would be detrimental to the lifetimes of the subsequent TFSSs to be deposited on the same template; and finally, to remove detrimental remnants of any on-template processes, such as organic or metal-containing residues. Typically, after the re-use cleaning, the template is subjected again to the porous semiconductor formation process, thereby forming another sacrificial release layer. This is then again followed by the deposition of the thin film to be released. Subsequent processing continues as described above.
Residual deposition extending onto the backside of the template may be detrimental to further processing and may accumulate as the template is subjected repeatedly to the sacrificial layer formation/deposition/further processing/release/post-release treatment processing. Residual deposition on the backside can cause local stress points and unsmooth template surfaces which are detrimental to handling and which may increase the propensity of the template to break. Therefore, the avoidance (described above) or removal of backside deposited material may be advantageous. This may be carried out after each re-use cycle or after several re-use cycles and may be repeated throughout the lifetime of the template. These methods can be done either by removing material from the complete backside area or by removing only locally at the wafer edge the material deposited mainly at the edge of the backside.
The template is a highly valuable commodity in the overall process. Therefore, any process that serves to extend the potential number of deposition cycles that the template can sustain adds substantially to the value proposition. Therefore, in the case of defective processing on the template or incomplete release or removal of the TFSS film, the template can be subjected to a reconditioning process. This reconditioning process may consist of grinding and/or polishing of the full area of the template or of only the problematic portions of the template. After successful reconditioning, the templates can be re-entered into the process loop and re-use can be resumed.
Grinding and/or polishing can be accomplished using a single side or double side grinder/polisher. The grinding/polishing process is chosen according to the necessity of surface finish. The TFSS described above which later forms the substrate for the solar cell does not rely on a mirror polished surface finish of the substrate. It is therefore important to point out that the porous semiconductor sacrificial layer can be formed on a template surface that does not have to start out as a mirror polished semiconductor surface. As it is not known beforehand at what stage an imperfect processing of the substrate occurs and as an HVM-compatible grind/polish process uses up the least amount of material from the starting template if the thickness is known, it is advantageous to inspect the templates at one stage subsequent to the release process, and sort them into thickness ranges, such that a multitude of templates can be processed in a grinder/polisher at the same time, to the same target thickness. The above sorting for thickness and for local residue from the deposition can be done concurrently with suitable equipment, such as optical, capacitive or gas back pressure based sensing.
The TFSS that was released from the template carrier and which may already have several processes applied to it while on the template can be processed further after the release. There are several possible embodiments for the TFSS and its further handling: for sufficient layer thickness, the TFSS can be self-supporting and handled through further processes as is. If the template that was used to deposit the TFSS material onto was structured to form a three-dimensional structure, such as an array of pyramids, prisms or other three-dimensional geometries, then the TFSS may be self-supporting even if the amount of deposited TFSS material is very small. This structural feature is a potential advantage of the three-dimensional template and TFSS. If the layer thickness is not sufficient for the TFSS to be self-supporting, then the TFSS can be supported during further processing via a suitable support plate.
Those with ordinary skill in the art will recognize that the disclosed embodiments have relevance to a wide variety of areas in addition to those specific examples described above.
The foregoing description of the exemplary embodiments is provided to enable any person skilled in the art to make or use the claimed subject matter. Various modifications to these embodiments will be readily apparent to those skilled in the art, and the generic principles defined herein may be applied to other embodiments without the use of the innovative faculty. Thus, the claimed subject matter is not intended to be limited to the embodiments shown herein but is to be accorded the widest scope consistent with the principles and novel features disclosed herein.
It is intended that all such additional systems, methods, features, and advantages that are included within this description be within the scope of the claims.
This application claims priority to U.S. Provisional Patent Application Ser. No. 61/373,793 filed Aug. 13, 2010, which is hereby incorporated by reference in its entirety. This application is also a continuation-in-part of U.S. patent application Ser. No. 11/868,493 (published as U.S. Pub. No. 2008/0289684), filed Oct. 6, 2007, which is hereby incorporated by reference in its entirety.
Number | Date | Country | |
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61373793 | Aug 2010 | US |
Number | Date | Country | |
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Parent | 11868493 | Oct 2007 | US |
Child | 13209390 | US |