The present invention relates to an apparatus and to a method for producing krypton and xenon by separating air by cryogenic distillation and in particular to a method for separating gasses from air using internal compression (in which the gaseous oxygen is produced by vaporization under pressure in the exchange line) where a krypton/xenon mixture is extracted.
In a unit for separating gasses from air comprising a double column and where the gaseous oxygen is produced by vaporization under pressure in the exchange line (internal compression apparatus) in which provision is made to extract a krypton/xenon mixture, it is observed that the efficiency of this extraction decreases significantly because the pumped oxygen extracted from the low pressure distillation column brings with it a non-negligible proportion of components to be valorized, such as krypton and xenon.
For this type of internal compression apparatus, in the case of the production of krypton/xenon associated with a production of argon, several methods making it possible to overcome this problem have been considered.
The invention can summarized as two essential steps:
According to a variant, the low pressure column is fed by the purge rich in krypton and in xenon produced by concentration. The purge rich in krypton and in xenon produced above will feed the low pressure column, at a distillation stage lower than the tapping of the liquid oxygen which is intended to be pumped in order to then be vaporized in the main exchanger. The final mixture, rich in krypton and in xenon, is extracted from the bottom of the low pressure column in order to be subsequently treated there.
Optionally, in the case where the krypton and xenon mixture is in liquid form, this return is injected at the intake of the pump in order to minimize the OL tapping from the column and thus to increase the extraction yield of the krypton and xenon.
Such a method makes it possible to extract about 90% of the xenon present in the air where a conventional method only allows a yield of about 70% at best. With regard to the extraction of the krypton, this reaches about 75% whereas the yield of a conventional apparatus at best only allows a yield of the order of 60%.
According to one purpose of the invention, there is provided a method for producing krypton and xenon by separation of air by cryogenic distillation in a double column comprising a medium pressure column and a low pressure column in which:
According to optional features:
According to another purpose of the invention, there is provided an apparatus for producing krypton and xenon by separation of air by cryogenic distillation comprising a double column constituted by a medium pressure column and a low pressure column and a vaporizer comprising:
The apparatus possibly comprises:
The invention will be described in more detail with reference to the FIGURE.
A stream of medium-pressure gaseous air 1 is sent to the medium pressure column 20 of a double air separation column. The double column also comprises a low pressure column 21 thermally coupled with the medium pressure column 20 by means of a vaporizer 24, which vaporizes the bottom liquid of the low pressure column by heat exchange with the gaseous nitrogen at the top of the medium pressure column.
A high-pressure liquid air stream is expanded in a valve and then divided into two. The stream 3 thus formed is sent to the medium pressure column 20 a few theoretical trays above the entry point of the stream 1. The rest of the liquid air 4 is cooled in the subcooler 26, expanded and then sent to the low pressure column 21.
A lower stream of rich liquid 5, enriched in oxygen, krypton and xenon, is tapped from the bottom of the medium pressure column 20, cooled in the subcooler 26 and then expanded and sent to a vaporizer 22 where it partially vaporizes by heat exchange with the nitrogen-enriched gaseous air 8 coming from the medium pressure column 20. The gaseous air is condensed in order to form a stream 9 which is then sent to the low pressure column 21. The vaporized rich liquid 16 is expanded as an intermediate gas and sent to the low pressure column whilst the remaining intermediate liquid 7 is sent to the low pressure column 21 a few trays above the bottom. A higher stream of rich liquid 6 is tapped between the air intake 1 and the air intake 3 and/or the tapping of the stream 8. This stream 6 is cooled in the subcooler 26, mixed with the vaporized rich liquid 16 and sent to the low pressure column 21. Impoverished liquid, enriched with nitrogen 15, is tapped at the top of the medium pressure column 20 and sent to the top of the low pressure column 21 after cooling and expansion.
Liquid oxygen 10 is tapped from the low pressure column 21 a few trays above the bottom and preferably above the liquid intake 7. This liquid is pumped by the pump 23 in order to serve as an oxygen-rich product.
Liquid oxygen 11, enriched with krypton and xenon, is tapped from the bottom of the low pressure column 21 and can be purified subsequently in order to produce a mixture of krypton and xenon. The intermediate liquid 7 can be mixed directly with this liquid oxygen stream instead of being sent to the low pressure column 21.
Low pressure nitrogen 13 is tapped at the top of the low pressure column 21, heated in the subcooler and heated against the air streams 1, 2 (heating not shown).
Items of equipment:
20 Medium pressure column, 21 Low pressure column, 22 Lower rich liquid vaporizer, 23 Liquid oxygen pump.
1 Medium pressure gaseous air, 2 High pressure liquid air, 3 Expanded liquid air feeding the medium pressure column, 4 Expanded liquid air feeding the low pressure column, 5 Lower rich liquid, enriched in krypton and xenon, 6 Vaporized lower rich liquid, impoverished in krypton and xenon, 7 Purge rich in krypton and xenon, 8 Impoverished air extracted from the medium pressure column, 9 Liquid impoverished air, 10 Liquid oxygen extracted from the low pressure column, 11 Liquid oxygen extracted from the low pressure column rich in krypton and xenon.
Number | Date | Country | Kind |
---|---|---|---|
0852727 | Apr 2008 | FR | national |
Filing Document | Filing Date | Country | Kind | 371c Date |
---|---|---|---|---|
PCT/FR09/50625 | 4/8/2009 | WO | 00 | 10/13/2010 |