The present invention relates generally to carbon fiber. More specifically, the present invention relates to an apparatus and method for splitting a tow of carbon fiber from a high filament count into lower filament counts.
Carbon fibers are fibers composed mostly of carbon ranging from 5 to 10 micrometers (0.00020-0.00039 in) in diameter. Carbon fibers offer many advantages including high stiffness, high tensile strength, low weight to strength ratio, high chemical resistance, high-temperature tolerance, and low thermal expansion. These properties have made carbon fiber very popular in aerospace, civil engineering, military, automotive, and motorsports applications.
Carbon fiber is created by converting a precursor fiber into carbon. These precursor fibers are a significant cost of manufacturing carbon fiber. As a means of reducing costs, research is being done to utilize less expensive precursor fibers. These less expensive precursor fibers can reduce the final cost of carbon fibers by roughly a third or more. Production using these economical precursor fibers currently results in thick tows with filament counts as high as 300,000 (300K, where âKâ means 1,000) or higher.
While these thick tows are economical to produce, most applications require tows of a much lower filament count. As an example, some automotive parts utilize 50K filament count tows, while some aerospace applications require thin tows of 3K filament count. This creates a need for a method and apparatus for converting these thick economical tows down to the thinner tows used by most applications. Current methods and systems for splitting tows have known issues, such as filament tangling, fiber tearing or breakage, and fiber fuzz. Further, these known issues like tearing or breakage can lead to inconsistent tows, where the mass is not uniform over their length or varies from tow to tow. This can lead to weak spots when the tow is manufactured into a final product.
Therefore, there is a need for improved methods and systems for splitting carbon fiber tows that overcome the above-mentioned issues.
According to some embodiments, an apparatus and method of splitting carbon fiber filament tows is disclosed. The present invention is capable of being utilized in line with the initial production of the carbon fiber as well as being able to split carbon fiber from a previous production. The simplicity of the design also allows for easy setup and troubleshooting.
The present invention is comprised of a splitting assembly which utilizes Polytetrafluoroethylene (PTFE) or equivalent material blades to split the carbon fiber tow. This splitting process is performed within or at the exit of the electrolyte bath assembly.
The combination of the design and location of the splitting assembly within the electrolyte bath assembly has significant advantages. Some advantages being that the electrolyte fluid provides a lubricating effect, the static charge built up on the blades help to split the fiber, and the electrical current in the electrolyte bath helps consolidate and bond the split tows.
All illustrations of the drawings are for the purpose of describing selected versions of the present invention and are not intended to limit the scope of the present invention.
The present invention is an apparatus and method for splitting or dividing a carbon fiber tow from a heavy tow 1 (a high filament count tow) into a number of split tows 16 (lower filament count tows).
Lower cost textile grade precursor fibers are starting to be used to manufacture carbon fiber, significantly decreasing the cost of carbon fiber. The fiber tows (or bundles) created by these methods are thick having filament counts of 300,000 (300K, K meaning 1,000) or higher. While these large or heavy tows are good for cost, they are too high of a filament count for most applications. Examples of typical tows for some applications would be a 50K tow for an automotive part, or a 3K tows for an aerospace part. The present invention allows for the splitting of these heavy tows 1 down into the desired sized tow. The present invention can be used in-line with the manufacture of new carbon fiber. Alternately, the present invention may also be used with carbon fiber that has been previously manufactured, by first stripping off any sizing agent or coating, then processing through the invention.
The preferred embodiment of the present invention is comprised of an electrolyte bath assembly 2, and a splitting assembly 9. The electrolyte bath assembly 2 is further comprised of a bath basin 3, an electrolyte fluid 4, an upper entry roller 5, a lower entry roller 6, a lower exit roller 7, an upper exit roller 8, an anode 18 and a cathode 19.
The bath basin 3 is a basin which contains the electrolyte fluid 4 of which there are several types but in the preferred embodiment, the electrolyte fluid 4 is comprised of an ammonia solution commonly used for carbon fiber manufacturing.
The bath basin 3 has an entry end 30 and an exit end 31. The entry end 30 of the bath basin 3 is the side where a heavy tow 1 enters the electrolyte bath assembly 2. The exit end 31 is the side where the fiber tow would exit the electrolyte bath assembly 2.
The function of the entry rollers is to guide a heavy tow 1 into the bath basin 3, and there are many possible of designs for the entry rollers of the present invention. Some designs are as simple as a single roller which guides the heavy tow 1 into the bath basin 3. The preferred embodiment is designed with two entry rollers. The upper entry roller 5 is positioned adjacent to the entry end 30 with the top of the upper entry roller 5 positioned above the top lip of the bath basin 3. The lower entry roller 6 is positioned adjacent to the entry end 30 with the bottom of the roller positioned below the surface of the electrolyte fluid 4 within the bath basin 3.
The function of the exit rollers is to guide the fiber tow out of the bath basin 3, and there are many possible of designs for the exit rollers of the present invention. Some designs are as simple as a simple as a single roller which guides the fiber tow out of the bath basin 3. The preferred embodiment is designed with two exit rollers. The upper exit roller 8 is positioned adjacent to the exit end 31 with the top of the upper exit roller 8 positioned above the top lip of the bath basin 3. The lower exit roller 7 is positioned adjacent to the exit end 31 with the bottom of the roller positioned below the surface of the electrolyte fluid 4 within the bath basin 3.
An anode is a device that is positively charged by an electrical source, whereas a cathode is a device that is negatively charged by an electrical source. In the preferred embodiment, the upper entry roller 5 also serves the function of being an anode 18. The upper entry roller 5 is positively charged using an electrical power source. The heavy tow 1, being an electrically conductive material picks up and carries this positive charge created by the anode 18. The cathode 19 in the preferred embodiment takes the form of a plate that is submerged in the electrolyte fluid 4 within the bath basin 3.
The preferred embodiment of the present invention is further comprised of the splitting assembly 9 which is comprised of at least one blade 10, blade pins 11, a base plate 12, a set of base plate supports 14, and a set of locking hinges 15.
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In the present invention, blades 10 may be created in a variety of shapes and sizes based the application and the equipment used. Blade 10 height can vary but needs to be tall enough to engage the heavy tow 1 and keep the split tows 16 separated. The leading edge of each blade 10 is beveled to a knife-edge, this knife-edge being used to split the heavy tow 1.
Further embodiments of the blade 10 can take varied shapes, such a disc blade 32. The blade 10 shape is not limited by the preferred embodiment as many shapes can be created with a knife-edge and similar properties to the preferred embodiment.
The present invention uses a blade 10 that is constructed of a smooth material that is capable of splitting the tow without cutting or tearing the filaments. In the preferred embodiment, the blade 10 is created from Polytetrafluoroethylene or PTFE. PTFE is used because of its low surface roughness and smooth surface. PTFE is also an electrical insulator which allows it to build up and hold a static charge. This static charge repeals the filaments and improves the splitting of the heavy tow 1 into split tows 16.
Other embodiments may be created from other smooth materials such as porcelain or other materials with equivalent smoothness. In some embodiments the blades 10 may be made of a base material that is coating with PTFE, porcelain, or equivalent material.
PTFE has a further advantage of not reacting with the elements of the electrolyte bath assembly 2. If the blades 10 were made of metal, it may react with the electrolyte bath causing pits or build ups that could lead to tearing and destroying filaments.
In some embodiments, after the split tows 16 exit the splitting assembly 9, the split tows 16 are feed into an array of tension sensors 17. The array being positioned after the exit end 31 of the bath basin 3. The array of tension sensors 17 having a corresponding tension sensor that is mounted in line with the towpath of each split tow 16. Each split tow 16 would be feed into a tension sensor 17 that would then detect the tension on each split tow 16. This tension data would then be correlated to a filament count for each split tow 16. Further, if any tension changes are detected, the operator may be alerted of a possible process change.
In further embodiments, a vision system or an array of vision systems can be used in place of the array of tension sensors 17. The vision system would be capable of visually measure the size of the split tow 16 and correlating the visual size measurement of the split tow 16 to a filament count.
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The base plate actuator 20 being pivotally mounted to an adjacent solid surface and being pivotally attached to the base plate 12, so that as the base plate actuator 20 extends it pushes the base plate 12 upward and forwards, and when the base plate actuator 20 is contracted it pulls the base plate 12 backwards and downward.
The blade actuators 21 being mounted to the base plate 12 and the blade 10 being fixed to the blade actuator 21, so that when the actuator is extended in a first direction, the blade 10 is moved in the first direction, and when the blade actuator 21 is retracted in a second direction, the blade 10 is moved in the second direction.
The communication device 22 is configured for receiving a signal from at least one user device associated with at least one user. Said signal may be associated with a positioning command for the desired position for the blade 10 and splitting assembly 9. The communication device 22 transmits the signal corresponding to the desired position to the base plate actuator 20 and the blade actuators 21. The actuators then adjust the position the splitting assembly 9 and blades 10 to the desired position as indicated by the signal.
The system may further include a processing device communicatively coupled with the communication device 22. The processing device may be configured for analyzing the signal and generating the signal transmitted to the base plate actuator 20 and the blade actuators 21.
The present invention is further comprised of a method for splitting a carbon fiber tow. After obtaining a heavy tow 1 of carbon fiber with a high filament count, the heavy tow 1 is fed into the electrolyte bath assembly 2.
In the preferred method the heavy tow 1 is feed under tension into the entry end 30 of the bath basin 3. The heavy tow 1 first wrapping over the top of the upper entry roller 5 making a 90-degree bend downward into the electrolyte fluid 4 inside the bath basin 3. The heavy tow 1 next wraps under the lower entry roller 6 making a 90-degree bend and feeds horizontally beneath the surface of the electrolyte fluid 4.
The fiber tow feeds through the bath basin 3 until it reaches the exit end 31, where the fiber tow wraps underneath the lower exit roller 7 and makes a 90-degree bend upward. The fiber tow then feeds upward and wraps over top of the upper exit roller 8, making a 90-degree bend and feeding horizontally away from the exit end 31 of the bath basin 3.
With the heavy tow 1 being feed through the electrolyte bath assembly 2 under tension, a first splitting assembly 9 is positioned and oriented to engage the towpath of the heavy tow 1. The heavy tow 1 is split using the blade 10 so that a split tow 16 is produced on either side of the blade 10 containing a reduced filament count. If the first splitting assembly 9 contains more than one blade 10, the heavy tow 1 is split by each blade 10 so that more split tows 16 are created as more blades 10 are added.
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While the fiber tow is within the bath basin 3 and under the surface of the electrolyte fluid 4, an electrolysis treatment is performed on the fiber tow. In the preferred method the electrolysis treatment is performed by having the upper entry roller 5 function as an anode 18 having a positive charge that is applied to the heavy tow 1. Due to the electrical conductivity of carbon fiber, the heavy tow 1 carries the positive charge, which makes the heavy tow act as an anode. The cathode 19 applies a negative charge to the electrolyte fluid 4 within the bath basin 3.
As the positively charged heavy tow 1 is feed through the negatively charged electrolyte fluid 4, the charge difference between the anode 18 and the cathode 19 ionizes carbon atoms within the electrolyte fluid 4. These carbon ions bond to the fiber tow and create bonds between the carbon fiber filaments, creating a stronger tow that resists breaks. This process of forming creating bonds is the electrolysis treatment.
One advantage of the present invention is that since the split tow 16 are either inside the bath basin 3, or still coated in electrolyte fluid 4 at the exit of the bath basin 3, bonds are still being created. Therefore, any loose fibers created during splitting are bonded to the split tow 16, creating a consolidated, bonded split tow 16.
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The position of the blades 10 can also be moved using blade actuators 21. The blades 10 are attached to the end of the blade actuators 21 so as the blade actuators 21 extend and retract the blades 10 move horizontally across the base plate, similar to moving hole positions. The blade actuators 21 are now able to position the blades 10 using the extension of the blade actuators 21 and position the blades 10 in the correct location on the cross section of the heavy tow 1 to split it into split tows 16 of the desired filament count.
The addition of actuators allows the splitting assembly 9 to be lowered, to disengage the heavy tow 1. Then the blade 10 position can be adjusted to the desired position to achieve the desired filament count. Then the splitting assembly 9 can be raised to engage and split the heavy tow 1 into split tows 16 of the desired filament count. In this fashion positioning of the splitting assemblies are electronically controlled or automated.
Further methods include a communication device 22 being configured to receive a signal from at least one user device associated with at least one user. The signal being associated with the desired position for the splitting assembly 9 and blades 10. The communication device 22 being communicatively linked to the base plate actuator 20 and the blade actuators 21, transmits the signal according to the desired position of splitting assembly 9 to the base plate actuator 20, and the desired position of the blades 10 to the blade actuator 21. The base plate actuator 20 then extends or retracts in order to position the splitting assembly 9 into the desired position. Further, the blade actuators 21 extend to position the blades 10 into the desired position.
The splitting process of the present invention contains advantages including but not limited to the examples disclosed below. One advantage being that the electrolyte liquid 4 acts as a lubricant, helping the fibers to split and separate with minimal tearing and damage, thereby maintaining a uniform split tow 16 with a consistent filament count over its length.
Another advantage is that the charge difference between the anode 18 and cathode 19 helps the fiber tow attract loose fibers and helps to consolidate the split tow 16 after the splitting process.
A further advantage of splitting inside the bath basin 3 is that any loose filaments are pulled toward the split tow 16 by drag cause by the tow moving through fluid. If the splitting occurs outside of the bath basin 3, then the surface tension of the electrolyte fluid 4 remaining on the split tow 16, helps pull loose filaments towards the split tow 16.
Further embodiments of the present invention may be comprised without any base plates 12, instead the blade 10 is positioned and oriented by an alternate means such as welding or bolting directly to the bath basin 3.
Further embodiments may have multiple heavy tows 1 that are feed through the electrolyte bath assembly 2 at the same time. These multiple tows may be split using a single splitting assembly 9 or separate splitting assemblies 9, arranged are need. Some further embodiments may have one or more splitting assemblies 9 mounted inside the bath basin 3 along with one or more splitting assemblies mounted adjacent to the exit end 31 of the bath basin 3.
Although the invention has been explained in relation to its preferred embodiment, it is to be understood that many other possible modifications and variations can be made without departing from the spirit and scope of the invention.
Further the present invention is capable of being used during other stages in the manufacture of carbon fiber. In one embodiment, a sizing agent treatment is applied to the carbon fiber tow using a sizing treatment assembly comprised of an entrance roller, an exiting roller, and a sizing tub. The sizing tub having an entrance end and an exiting end. The entrance roller being mounted inside the sizing tub adjacent to the entrance end. The exiting roller being mounted inside the sizing tub adjacent to the exiting end.
The sizing treatment assembly is further comprised of a splitting assembly or assemblies. The splitting assembly are positioned either inside of the sizing tub between the entrance and exiting rollers or outside of the sizing tub adjacent to the exiting end.
The sizing agent treatment embodiment would have a first method of use where the splitting assembly or assemblies are positioned inside of the sizing tub between the entrance and exiting rollers. The carbon fiber tow would enter the sizing treatment assembly being guided into the sizing tub using the entrance roller. The splitting assembly would split the carbon fiber tow from a high filament count into tows with a reduced filament count. The tows with a reduced filament count would then be guided out of the sizing tub using the exiting roller.
The sizing agent treatment embodiment would have a second method of use where the splitting assembly or assemblies are positioned outside of the sizing tub adjacent to the exiting end. The carbon fiber tow would enter the sizing treatment assembly being guided into the sizing tub using the entrance roller. The tow would then be guided out of the sizing tub using the exiting roller. Then the splitting assembly would split the carbon fiber tow from a high filament count into tows with a reduced filament count.
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Number | Date | Country | |
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20230211974 A1 | Jul 2023 | US |
Number | Date | Country | |
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63296329 | Jan 2022 | US |