Apparatus and method for suppressing growth of oxide film on coil

Information

  • Patent Grant
  • 6495094
  • Patent Number
    6,495,094
  • Date Filed
    Thursday, November 9, 2000
    23 years ago
  • Date Issued
    Tuesday, December 17, 2002
    21 years ago
Abstract
An apparatus and a method for suppressing growth of an oxide film on a coil which is a spirally wound, rolled strip are disclosed. A rolled strip subjected to rolling by hot rolling equipment is wound spirally by a down-coiler to make a coil. Covers are disposed on the opposite sides of the coil such that heat resistant materials intimately contact the opposite sides of the coil. The covers are fixed by L-bolts and nuts to cover the opposite sides of the coil with the covers. In this state, the coil is naturally cooled for a predetermined time to suppress growth of an oxide film and increase productivity.
Description




BACKGROUND OF THE INVENTION




1. Field of the Invention




The present invention relates to an apparatus and a method for suppressing growth of an oxide film on a coil of a rolled strip which has been wound from hot rolling equipment onto a down-coiler and stored in a coil yard.




2. Description of the Related Art




FIGS.


13


(


a


) and


13


(


b


) schematically show a general state of storage of the coils.

FIG. 14

is a graph showing the thickness of an oxide film, in the width direction, on the coil in a conventional state of storage.




A rolled strip after rolling in hot rolling equipment is wound spirally by a down-coiler, carried to a coil yard, and stored there. The posture of the coil in storage is a vertical posture of a coil C as shown in

FIG. 13

(


a


), or a horizontal posture of the coil C as shown in FIG.


13


(


b


). In this posture of storage, the coils are placed in a layer, or stacked in layers, on a frame (not shown). The coils stored in that posture are cooled by natural ventilation or by forced cooling in a building for about 110 hours in summer, or about 80 hours in winter.




In the above posture of coil storage, the rolled strip is cooled in the coil yard while being left to stand for a long time at a high temperature in an oxidizing atmosphere of the air. Thus, an oxide film grows on the surface of the coil over a long time. In the case of the coil of the rolled strip spirally wound, both of its edges directly touch the air. From the edges, air penetrates the gap between the adjacent turns of the rolled strip. Consequently, the oxide film growing on the strip surface of the coil differs in thickness across its width direction.




The graph indicated in

FIG. 14

shows the thickness of the oxide film in the width direction of the coil. During rolling, the oxide film is formed uniformly to a thickness of 8 μm, and then the coil is cooled for a predetermined period of time in the coil yard. As shown in this graph, the oxide film on the strip surface of the coil grows to a thickness of 18 μm at the edge, 15 μm at a distance of 50 mm from the edge, 9 μm at a distance of 300 mm from the edge, and 8.5 μm at a distance of 470 mm from the edge (i.e., at a central position in the width direction). One will see that when the rolled strip in the coiled form is cooled, the oxide film grows to a thickness of 8.5 μm at the central position in the width direction, but to a thickness of 18 μm, a value more than two-fold, at the edge.




The rolled strip having the oxide file formed on the surface thereof is generally acid pickled to remove the oxide film. Then, the rolled strip is transported to a subsequent step such as a plating line. The acid pickling of the rolled strip is performed by guiding the rolled strip into an acid pickling tank holding an acidic liquid, and immersing the rolled strip therein for a predetermined time, thereby cleaning off the oxide film formed on the surface. That is, the duration of immersion of the rolled strip in the acid pickling tank is set in accordance with the thickness of the oxide film formed on the surface of the rolled strip. Hence, the rolled strip, which has the oxide film 8.5 μm thick at the central position and 18 μm at the edge, needs to be immersed in the acid pickling tank for a long time adapted for the oxide film which is 18 μm in thickness. As a result, the transport speed of the rolled strip in the acid pickling is slowed, decreasing the overall production efficiency. When the thickness of the oxide film formed on the surface of the rolled strip is great, moreover, the consumption of the acidic liquid used increases, raising the pickling cost.




SUMMARY OF THE INVENTION




The present invention has been accomplished to solve the above-described problems with the earlier technologies. It is an object of this invention to provide an apparatus and a method for suppressing growth of an oxide film on a coil of a rolled strip by properly storing and cooling the coil, while achieving an increase in productivity.




An aspect of the invention, as a means of attaining the above, object, is an apparatus for suppressing growth of an oxide film on a coil which is a spirally wound, rolled strip, wherein covers are provided for covering at least opposite sides of the coil.




Thus, the opposite sides of the coil are cooled while being shielded from the outside air. Penetration of air into the interior of the coil is inhibited, the growth of the oxide film on the rolled strip (coil), especially at its edge, is suppressed, and the formation of an extremely thick oxide film at the edge as compared with the center in the width direction can be prevented. As a result, the coil has a thin oxide film overall, and widthwise is leveled in thickness. The acid pickling time for cleaning off the oxide film can be markedly decreased, and the transport speed of the rolled strip during acid pickling can be increased, whereby the overall production efficiency can be raised. The consumption of the acidic liquid used can also be decreased to reduce the pickling cost.




In the apparatus for suppressing growth of an oxide film on a coil, a heat insulating material may be provided on a surface of each of the covers in intimate contact with the coil. By this measure, rapid local cooling of the coil is prevented, and penetration of air into the interior of the coil is reliably inhibited. Consequently, the formation of an extremely thick oxide film at the edge compared with the center in width direction can be prevented. The resulting oxide film is thin overall, and widthwise is leveled in thickness




In the apparatus for suppressing growth of an oxide film on a coil, each of the covers may be shaped like a ring having a through-hole at a center thereof, and eye rings formed to project toward the through-holes of the covers may be connected together and fixed by bolts and nuts. By these measures, the covers can be mounted easily on the coil.




In the apparatus for suppressing growth of an oxide film on a coil, a cooling water path may be provided in each of the covers. By this measure, the coil is forcibly cooled with cooling water, with its opposite sides being shielded from the outside air. Consequently, the cooling time can be shortened, and the storage time of the coil in the coil yard can be reduced.




In the apparatus for suppressing growth of an oxide film on a coil, each of the covers may be shaped like a disk having a flange portion in an outer peripheral area of the cover, and the cooling water path may be provided along a circumferential direction of the cover. Since the cooling water path becomes long, the cooling efficiency can be increased.




In the apparatus for suppressing growth of an oxide film on a coil, the covers may be provided with a supply path and a discharge path for supplying and discharging an inert gas into and from a hollow portion of the coil. By this measure, the opposite sides of the coil are shielded from the outside air, and the hollow portion of the coil is supplied with the inert gas. Thus, penetration of air into the interior of the coil is inhibited, and the oxidizing atmosphere inside the coil is purged with the inert gas. Consequently, growth of the oxide film on the rolled strip can be suppressed reliably.




In the apparatus for suppressing growth of an oxide film on a coil, each of the covers may be shaped like a disk having a flange portion in an outer peripheral area of the cover, and the supply path and the discharge path for the inert gas which communicate with the hollow portion of the coil may be provided in the center of the covers. By this measure, a simple constitution can increase the cooling efficiency.




In the apparatus for suppressing growth of an oxide film on a coil, the covers may be a cup for accommodating the coil and a cup for covering an opening of the cup. By so doing, the coil can be cooled, with its whole being shielded from the outside, so that the growth of the oxide film on the rolled strip can be suppressed reliably.




Another aspect of the invention is a method for suppressing growth of an oxide film on a coil which is a spirally wound, rolled strip, comprising cooling the coil while covering at least opposite sides of the coil with covers.




Thus, penetration of air into the interior of the coil can be inhibited, the growth of the oxide film on the rolled strip (coil), especially at its edge, can be suppressed, and the formation of an extremely thick oxide film at the edge compared with the center in the width direction can be prevented. As a result, the coil has a thin oxide film overall, and widthwise is leveled in thickness.




The method for suppressing growth of an oxide film on a coil may comprise cooling the coil while the heat insulating surfaces of the covers and the coil are in intimate contact with each other. By so doing, rapid local cooling of the coil is prevented, and penetration of air into the interior of the coil is reliably inhibited. Consequently, the formation of an extremely thick oxide film at the edge compared with the center in width direction can be prevented. The resulting oxide film becomes thin overall and widthwise is leveled in thickness.




The method for suppressing growth of an oxide film on a coil may comprise cooling the coil by flowing cooling water in a cooling water path provided in each of the covers. By so doing, the coil is forcibly cooled with cooling water, with its opposite sides being shielded from the outside sir. Consequently, the cooling time can be shortened, and the storage time of the coil in the coil yard can be reduced.




The method for suppressing growth of an oxide film on a coil may comprise cooling the coil while supplying and discharging an inert gas into and from a hollow portion of the coil. By so doing, the opposite sides of the coil are shielded from the outside air, and the hollow portion of the coil is supplied with the inert gas. Thus, penetration of air into the interior of the coil can be inhibited, and the oxidizing atmosphere inside the coil can be purged with the inert gas. Consequently, growth of the oxide film on the rolled strip can be suppressed reliably.




The method for suppressing growth of an oxide film on a coil may comprise cooling the coil in an accommodated state. By so doing, the coil can be cooled, with its whole being shielded from the outside, so that the growth of the oxide film on the rolled strip can be suppressed reliably.











BRIEF DESCRIPTION OF THE DRAWINGS




The above and other objects, features and advantages of the present invention will become more apparent from the following description taken in connection with the accompanying drawings, in which:





FIG. 1

is a partially cutaway front view of an apparatus for suppressing growth of an oxide film on a coil according to a first embodiment of the present invention, designed to carry out a method for suppressing growth of an oxide film on a coil;





FIG. 2

is a side view of the apparatus for suppressing growth of an oxide film on a coil;





FIG. 3

is an exploded perspective view of the apparatus for suppressing growth of an oxide film on a coil;





FIG. 4

is a graph showing the thickness of an oxide film in the width direction of a coil in the apparatus for suppressing growth of the oxide film on the coil according to the first embodiment;





FIG. 5

is a partially cutaway front view of an apparatus for suppressing growth of an oxide film on a coil according to a second embodiment of the invention;





FIG. 6

is a side view of the apparatus for suppressing growth of an oxide film on a coil;





FIG. 7

is a graph showing the thickness of an oxide film in the width direction of a coil in the apparatus for suppressing growth of the oxide film on the coil according to the second embodiment;





FIG. 8

is a graph showing the temperature of the coil versus the cooling time for the coil;





FIG. 9

is a partially cutaway front view of an apparatus for suppressing growth of an oxide film on a coil according to a third embodiment of the invention;





FIG. 10

is a side view of the apparatus for suppressing growth of an oxide film on a coil;





FIG. 11

is a partially cutaway front view of an apparatus for suppressing growth of an oxide film on a coil according to a fourth embodiment of the invention;





FIG. 12

is a side view of the apparatus for suppressing growth of an oxide film on a coil;




FIGS.


13


(


a


) and


13


(


b


) are each a schematic view showing a general storage state of the coils; and





FIG. 14

is a graph showing the thickness of an oxide film in a width direction of a coil in a conventional storage state.











DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS




Embodiments of the present invention will now be described in detail with reference to the accompanying drawings, which in no way limit the invention.




[First Embodiment]





FIG. 1

is a partially cutaway front view of an apparatus for suppressing growth of an oxide film on a coil according to a first embodiment of the invention, designed to carry out a method for suppressing growth of an oxide film on a coil.

FIG. 2

is a side view of the apparatus for suppressing growth of an oxide film on a coil.

FIG. 3

is an exploded perspective view of the apparatus for suppressing growth of an oxide film on a coil.

FIG. 4

is a graph showing the thickness of an oxide film in the width direction of a coil in the apparatus for suppressing growth of the oxide film on the coil according to the present embodiment.




As shown in

FIGS. 1

to


3


, a coil C is rolled by hot rolling equipment (not shown), and then spirally wound by a down-coiler. The resulting coil is transported to a coil yard, where it is stored by an apparatus


10


for suppressing growth of an oxide film on a coil according to the present embodiment. This apparatus


10


is composed of a pair of covers (right and left covers)


11


,


12


for covering opposite sides of the coil C, and two L-bolts


13


and two nuts


14


as connectors for fixing the covers


11


,


12


to the opposite sides of the coil C. The covers


11


,


12


are of the same structure, and have nearly the same diameter as (or a slightly larger diameter than) the diameter of the coil C. The covers


11


and


12


are shaped like rings having through-holes


15


and


16


, respectively, in the center. On the inner peripheral surface of the through-holes


15


and


16


, two eye rings


17


and two eye rings


18


are fixed. To the interior surface of each of the covers


11


and


12


, layers of heat resistant materials


19


and


20


having certain elasticity and heat insulating properties are attached which have a ring shape to be brought into intimate contact with the respective edges of the coil C. The reference numeral


21


denotes a coil storing frame for bearing the coil C.




A rolled strip subjected to rolling by the hot rolling equipment is wound spirally by the down-coiler to make a coil C. The coil C is transported to the coil yard, and is borne on the coil storing frame


21


. On the coil storing frame


21


, the covers


11


,


12


are disposed on the opposite sides of the coil C such that the heat resistant materials


19


,


20


intimately contact the opposite sides of the coil C. The L-bolts


13


are passed through the eye rings


17


of one cover


11


, the hollow core of the coil C, and the eye rings


18


of the other cover


12


, whereafter the nuts


14


are screwed on the front end portions of the L-bolts


13


. In this manner, the covers


11


,


12


are mounted on the coil C so as to cover its opposite sides.




When the covers


11


,


12


have been mounted on the opposite sides of the coil C via the heat resistant materials


19


,


20


, the coil C is naturally cooled in this condition for a predetermined period of time in the coil yard. During this cooling treatment, the covers


11


and


12


are mounted on the opposite sides of the coil C via the heat resistant materials


19


,


20


to close open ends of the gap between the adjacent spiral turns of the rolled strip in the coil C, thereby inhibiting penetration of air into the interior of the coil C. Thus, growth of an oxide film on the rolled strip (coil C), especially at its edge, is suppressed, and the formation of an oxide film which is extremely think at the edge compared with the center in the width direction can be prevented.




The graph as

FIG. 4

shows the thickness of the oxide film in the width direction of the coil C which has been cooled for a predetermined time in the coil yard after the oxide film was formed uniformly to a thickness of 8 μm during rolling. As shown in this graph, the thickness of the oxide film growing on the strip surface of the coil is 9.5 μm at the edge, and 8.5 μm at a distance of 470 mm from the edge (i.e., at the central position in the width direction). There is substantially no difference between the two thicknesses, indicating that the thickness of the oxide film is almost leveled in the width direction.




The above finding points to the prevention of the phenomenon that the oxide film becomes extremely thick only at the edge during cooling of the coil C after rolling. The overall thickness of the oxide film becomes small. The acid pickling time for cleaning off the oxide film can be markedly decreased, and the transport speed of the rolled strip during acid pickling can be increased, whereby the overall production efficiency can be raised. The consumption of the acidic liquid used can also be decreased to reduce the pickling cost. Furthermore, wasteful removal of the material other than the oxide film, namely, the base material, is decreased, and the quality of the product can be improved.




[Second Embodiment]





FIG. 5

is a partially cutaway front view of an apparatus for suppressing growth of an oxide film on a coil according to a second embodiment of the invention.

FIG. 6

is a side view of the apparatus for suppressing growth of an oxide film on a coil.

FIG. 7

is a graph showing the thickness of an oxide film in the width direction of a coil in the apparatus for suppressing growth of the oxide film on the coil according to the present embodiment.

FIG. 8

is a graph showing the temperature of the coil versus the cooling time for the coil. Members having the same functions as illustrated in the above-mentioned embodiment are assigned the same reference numerals, and their explanations will be omitted.




As shown in

FIGS. 5 and 6

, an apparatus


30


for suppressing growth of an oxide film on a coil has a pair of covers (right and left covers)


31


and


32


fitted on a coil C so as to cover its opposite sides. In each of the covers


31


and


32


, a cooling water path is provided, and a supply path and a discharge path are provided for supplying and discharging an inert gas into and from the hollow portion of the coil C. The covers


31


,


32


are of the same structure, and have a slightly larger diameter than the diameter of the coil C. The covers


31


and


32


are shaped like disks having flange portions


33


and


34


in the outer peripheral area of the cover, the flange portions


33


and


34


being fitted around the outer periphery at each end of the coil C. In the covers


31


and


2


, cooling water channels


35


and


36


are formed as the cooling water paths. One end of each of the cooling water channels


35


,


36


is connected to a cooling water source (not shown) via cooling water supply pipes


37


,


38


joined to upper parts of the covers


31


,


32


. The other end of each of the cooling water channels


35


,


36


is coupled to cooling water discharge pipes


39


,


40


joined to lower parts of the covers


31


,


32


. Cooling water from cooling equipment may be forcibly passed through the cooling water channels


35


,


36


by a pump. And after cooling, may be circulated to the cooling equipment. To one of the covers,


31


, a gas supply pipe


41


for supplying an inert gas into the hollow portion of the coil C is connected via a pipe joint


42


. To the other cover,


32


, a gas discharge pipe


43


for discharging the inert gas, which has been supplied into the hollow portion of the coil C, is connected via a pipe joint


44


. As the inert gas, a N


2


gas or a Ar gas is preferred in order to purge an oxidizing atmosphere from the coil. Such an inert gas may be forced into the hollow portion of the coil C at room temperature by a pump.




The coil C borne on a coil storing frame


21


is mounted by having its opposite sides fitted with the flange portions


33


and


34


of the covers


31


and


32


. By forcibly flowing cooling water from the cooling equipment into the cooling water channels


35


and


36


via the cooling water supply pipes


37


and


38


by means of the pump, the coil C is indirectly cooled. Also, by forcibly flowing the inert gas from the gas supply pipe


41


into the hollow portion of the coil C via the pipe joint


42


by means of the pump, the coil C is cooled, and the oxidizing atmosphere is purged. In this manner, the coil C is forcibly cooled for a predetermined time in the coil yard.




During this cooling treatment, the covers


31


and


32


are attached to the opposite sides of the coil C to close the open ends of the gap between the spiral turns of the rolled strip in the coil C. Thus, penetration of air into the interior of the coil C is inhibited. At the same time, the inert gas is supplied into the hollow portion of the coil C to purge the inside oxidizing atmosphere. Hence, growth of an oxide film on the rolled strip (coil C) is suppressed, and the formation of an oxide film which is extremely thick at the edge compared with the center in the width direction is prevented. That is, as shown in

FIG. 7

, the thickness of the oxide film growing on the strip surface of the coil C is smaller than 9 μm at the central position in the width direction, as well as the edge, indicating that the thickness of the oxide film is almost leveled in the width direction.




The graph as

FIG. 8

shows the temperature of the coil versus the cooling time for the coil, making a comparison between natural cooling of the coil C allowed to stand in the coil yard, and forced cooling of the coil C performed by flowing cooling water in the covers


31


and


32


and flowing the inert gas into the hollow portion of the coil C. As this graph shows, the cooling time to a predetermined temperature is shortened by about 20% in the forced cooling in comparison with the natural cooling.




The above findings point to the prevention of the phenomenon that the oxide film becomes extremely thick only at the edge during cooling of the coil C after rolling. The overall thickness of the oxide film becomes small. The acid pickling time for cleaning off the oxide film can be markedly decreased, and the transport speed of the rolled strip during acid pickling can be increased, whereby the overall production efficiency can be raised. The consumption of the acidic liquid used cal also be decreased to reduce the pickling cost. Furthermore, wasteful removal of the material other than the oxide film, namely, the base material, is decreased, and the quality of the product can be improved. Besides, the coil C is forcibly cooled to shorten the cooling time. Thus, the storage time of the coil C in the coil yard can be reduced.




In the present embodiment, the covers


31


,


32


have been mounted by fitting the flange portions


33


,


34


onto the opposite sides of the coil C. However, joints may be formed on the outer periphery of the covers


31


,


32


, and L-bolts and nuts may be used supplementally to fix the covers


31


,


32


, as in the aforementioned embodiment.




[Third Embodiment]





FIG. 9

is a partially cutaway front view of an apparatus for suppressing growth of an oxide film on a coil according to a third embodiment of the invention.

FIG. 10

is a side view of the apparatus for suppressing growth of an oxide film on a coil.




As shown in

FIGS. 9 and 10

, an apparatus


50


for suppressing growth of an oxide film on a coil is comprised of a cup (cover)


51


for accommodating a coil C so as to cover a side portion of the coil C, and a cap


52


fitted on the cup


51


so as to cover the other side portion of the coil C. The cup


51


is made of steel, takes a cylindrical shape, and has an inner peripheral portion slightly larger in diameter than the coil C. The cap


52


is also made of steel, takes a cylindrical shape, and has an inner peripheral portion which can be fitted around an outer peripheral portion of the cup


51


. The coil C is fitted within the cup


51


while being supported by an L-shaped fork. Then, the coil C is borne on a coil storing frame


21


, and the cap


52


is fitted on the cup


51


to accommodate the coil C. When the coil C has been accommodated in the cup


51


and the cap


52


in this manner, the coil C is naturally cooled for a predetermined time in this state in the coil yard. During the cooling treatment, therefore, the coil C is shielded from the outside air, so that the growth of an oxide film on the rolled strip (coil C) is suppressed. This results in the prevention of the phenomenon that the oxide film becomes extremely thick only at the edge during cooling of the coil C after rolling. The overall thickness of the oxide film becomes small. Furthermore, the coil C is accommodated in the cup


51


and the cap


52


and naturally cooled over a long time. Hence, the ductility of the rolled strip (steel plate) can be improved because of an annealing effect.




[Fourth Embodiment]





FIG. 11

is a partially cutaway front view of an apparatus for suppressing growth of an oxide film on a coil according to a fourth embodiment of the invention.

FIG. 12

is a side view of the apparatus for suppressing growth of an oxide film on a coil.




As shown in

FIGS. 11 and 12

, an apparatus


60


for suppressing growth of an oxide film on a coil is comprised of a cup (cover)


61


for accommodating a coil C so as to cover a side portion of the coil C, and a cap


62


fitted on the cup


61


so as to cover the other side portion of the coil C. The cup


61


is made of steel, takes a cylindrical shape, and has a laminated structure in which a heat insulating material


63


is mounted on an inner peripheral portion of the cup


61


. The cap


62


is also made of steel, takes a cylindrical shape, and has a laminated structure in which a heat insulating material


64


is mounted oh an inner peripheral portion of the cap


62


. The coil C is fitted within the cup


61


while being supported by an L-shaped fork. Then, the coil C is borne on a coil storing frame


21


, and the cap


62


is fitted on the cup


61


to accommodate the coil C. When the coil C has been accommodated in the cup


61


and the cap


62


in this manner, the coil C is naturally cooled in this state for a predetermined time in the coil yard. During the cooling treatment, therefore, the coil C is shielded from the outside air, so that the growth of an oxide film on the rolled strip (coil C) is suppressed. This results in the prevention of the phenomenon that the oxide film becomes extremely thick only at the edge during cooling of the coil C after rolling. The overall thickness of the oxide film becomes small. Furthermore, the coil C is accommodated in the cup


61


and the cap


62


, and shielded from the outside by the heat insulating materials


63


,


64


. In this condition, the coil C is naturally cooled over a long time. Hence, the ductility of the rolled strip (steel plate) can be improved because of an annealing effect.




In the foregoing respective embodiments, the cover has been formed in many shapes. However, the cover may be any one which can cover the opposite sides of the coil, and is not restricted to these shapes. Furthermore, bolts and nuts, and flange fitting have been used as fixing tools for fixing the cover to the coil, but they are not limitative of the invention.




The invention being thus described, it will be obvious that the same may be varied in many ways. Such variations are not to be regarded as a departure from the spirit and scope of the invention, and all such modifications as would be obvious to one skilled in the art are intended to be included within the scope of the following claims.



Claims
  • 1. An apparatus for suppressing growth of an oxide film on a coil which is a spirally wound, rolled strip, wherein:covers are provided for covering at least opposite sides of the coil, each of the covers being shaped like a ring having a through-hole at a center thereof, eye rings being formed to project toward the through-holes of the covers are connected together and fixed by bolts and nuts, and a cooling water path is provided in each of the covers.
  • 2. The apparatus for suppressing growth of an oxide film on a coil as claimed in claim 1, wherein:a heat insulating material is provided on a surface of each of the covers in intimate contact with the coil.
  • 3. The apparatus for suppressing growth of an oxide film on a coil as claimed in claim 1, wherein:each of the covers is shaped like a disk having a flange portion in an outer peripheral area of the cover, and the cooling water path is provided along a circumferential direction of the cover.
Priority Claims (1)
Number Date Country Kind
11-318012 Nov 1999 JP
US Referenced Citations (9)
Number Name Date Kind
1870577 Lamb Aug 1932 A
2495561 Wilson Jan 1950 A
2818170 Hogan Dec 1957 A
2880861 Sklar et al. Apr 1959 A
3443800 Kennedy May 1969 A
3580331 Wargo May 1971 A
3879167 De Luca et al. Apr 1975 A
4147506 Southern et al. Apr 1979 A
4165868 Southern Aug 1979 A