Patent Application
20150192050
The invention is directed to exhaust gas aftertreatment apparatuses for internal combustion engines and methods for their operation. More particularly, the invention is directed to an apparatus and method for preventing coke fouling of an aftertreatment injector nozzle of an aftertreatment system.
Exhaust gas aftertreatment apparatuses in automotive vehicles are used to convert or remove targeted substances from the exhaust gas. Aftertreatment devices include, for example, diesel oxidation catalysts (DOC), which can remove particulate matter and oxidize carbon monoxide and uncombusted hydrocarbons in the exhaust gas, diesel particulate filters (DPF), which remove particulate matter from the exhaust gas, and selective catalytic reduction (SCR) systems, that inject an ammonia-based reductant in the presence of a catalyst to convert oxides of nitrogen (NOx) to nitrogen gas and water. Certain aftertreatment devices operate only at or above a threshold temperature, for example, the SCR devices. Other devices, such as the DPF, require the regular removal of collected particulate matter from the filter body. One such process, known as regeneration, occurs by oxidation of the collected particulate matter, which requires the filter body to be at an elevated temperature, typically above 600° C.
At engine start up, aftertreatment components may be at or near ambient temperature, which is typically too low for operation of those devices. In addition, automotive exhaust, and diesel engine exhaust in particular, is not consistently at temperatures high enough for operation of certain exhaust aftertreatment systems on the vehicle, in particular, regeneration of DPFs. Accordingly, some device or method for increasing the temperature of the exhaust gas when necessary is provided. Exhaust heating methods and devices include engine management for control of exhaust gas temperature, resistive heating coils placed in the exhaust, and burners. One such device is a system for injecting hydrocarbon, typically diesel fuel, into the exhaust gas, including an injector with a nozzle positioned to inject fuel into the exhaust gas flow.
A problem with hydrocarbon injectors is fouling of the injector nozzle from decomposed liquid hydrocarbon, particulate matter, and other residue collecting on the nozzle, called “coking”.
The invention proposes an apparatus and method for solving these problems.
According to the invention, an exhaust gas aftertreatment apparatus having a hydrocarbon injector includes an injector nozzle coated with a catalytic material. The catalytic coating allows hydrocarbon that collects on the nozzle to oxidize at a temperature lower than non-catalyzed oxidation.
An apparatus according to the invention further includes a device for providing and controlling an air flow through the injector responsive to the exhaust gas temperature.
A method of the invention for operating the injector has three states: (1) fuel injection for heating the aftertreatment devices, (2) after fuel injection, air flow through the nozzle to purge residual fuel and/or cool the nozzle to prevent carbon deposits when exhaust gas temperature is low, and (3) no (or low) air flow to allow passive heating of the nozzle by the exhaust for oxidation of any accumulated carbon when exhaust temperature is high enough to support oxidation. Immediately following state (3) the method may include an additional air purge to remove ash.
A method of operating an injector for an exhaust gas aftertreatment apparatus to avoid coke deposits, the injector nozzle having a catalyst coating, includes the steps of injecting a hydrocarbon fluid into an exhaust gas flow over a selected duration, causing air to flow through the injector nozzle when an exhaust gas temperature is below a threshold temperature, and, substantially stopping the flow of air through the injector nozzle when the exhaust gas temperature is above the threshold temperature.
According to another aspect of the invention, the method includes the steps of monitoring a condition of the aftertreatment apparatus, monitoring an exhaust gas temperature, and, responsive to the condition of the aftertreatment apparatus and responsive to the exhaust gas temperature, controlling the injection of hydrocarbon in the exhaust gas flow.
According to another aspect of the invention, air flow is preferably pulsed, the air flow parameters, volume, frequency, and duration, being controlled responsive to exhaust gas temperature.
The invention will be better understood by reference to the following detailed description read in conjunction with the appended drawings, in which:
The DPF filters the exhaust gas and collects soot and other particulate matter, which must be removed at intervals or the DPF becomes clogged. One common method for removing particulate matter, which is mainly carbon based, is to raise the temperature of the DPF filter body to a temperature sufficient to oxidize the particulate matter. The temperature of the DPF filter body can be increased in various ways, as is known in the art. One way is to add hydrocarbon (or fuel) to the exhaust gas, which is oxidized, releasing heat energy. An injector 20 connected to a source of hydrocarbon 22 is shown in
Because the injector 20 is upstream of the aftertreatment device 16, it is exposed to exhaust gas carrying particulate matter. In addition, the injector nozzle 24 and the hydrocarbon liquid at and exiting the nozzle 24 of the injector are exposed to the heat of the exhaust. This can result in coking of the nozzle as hydrocarbon liquid and particulate matter deposits form on the nozzle.
Maintaining the nozzle at a relative low temperature can help avoid, although not eliminate, coking. Coke deposits may be removed by heating the nozzle to a sufficiently high temperature to oxidize the carbon, and devices for heating nozzles are known. However, these add expense and complexity to the injector system.
According to the invention, an injector nozzle 24 is provided with a coating of a catalytic material that allows coke deposits to oxidize at a relatively low temperature. Suitable catalytic materials include precious metal catalysts such as platinum and palladium. Referring to
A catalytic coating is preferably applied to surfaces exposed to exhaust gas heat and the fuel injected by the nozzle 24. Such surfaces include the exterior surface 46 of the nozzle body 24, the tip 44, and a surface 48 defining the flow channel 42.
The catalytic coating on these surfaces will reduce the temperature necessary to oxidize carbon deposits on those surfaces.
The method determines if the exhaust gas is above a temperature threshold at which the exhaust gas can heat the catalyst coated nozzle to a temperature sufficient for oxidization of deposited carbon (S104). Using a precious metal as a catalyst, heating the nozzle to about 240° C. or higher will promote oxidation.
Although described in a sequential manner, it should be understood that the method of the invention is not performed entirely sequentially; the steps of monitoring the AT device, monitoring the exhaust gas temperature, and determining if the exhaust gas temperature is above the threshold are performed continually or in a repeating sequence as the rest of the method is performed.
If the exhaust gas temperature is above the threshold of Step S104, the method at Step S106 stops air flow through the injector or substantially stops air flow to provide a minimal amount of air flow, for example, to prevent ingress of exhaust gas into the nozzle, but not effectively cool the nozzle. The lack of air flow or low amount of air flow allows the nozzle to heat to the temperature sufficient for oxidizing any carbon deposits. A timer may be started to measure an interval during which the nozzle is heated and oxidation occurs. Alternatively, according to the method, the air flow will remain off or at a minimum as long as the exhaust gas temperature is above the threshold as determined in Step S104.
When the heating/oxidizing time interval has elapsed (Step S108) or the exhaust gas temperature falls below the threshold temperature, the method increases air flow through the nozzle (S110), to provide cooling to inhibit coking.
Returning to Step S104, if the exhaust gas temperature is below the threshold temperature, the condition of the AT device is evaluated to determine if it is necessary to increase the exhaust gas temperature (Step S112). For example, a DPF device may require a regeneration procedure to remove collected particulate matter.
If the AT device does not require heating, the method causes air to flow through the nozzle (Step S114). Air flow will help cool the nozzle to prevent or inhibit coking fouling.
If the AT device requires heating, hydrocarbon is injected through the injector (Step S116) while the exhaust gas temperature is monitored. An amount of hydrocarbon and a frequency of injections are controlled to the exhaust gas temperature to heat the DPF device to a target temperature and maintain that temperature for a time interval sufficient for regenerating the DPF. Alternatively, the DPF may be heated until the exhaust gas pressure differential between the entry and exit drops below a threshold.
When the regeneration process is completed, the hydrocarbon injection is stopped and air is caused to flow through the nozzle (Step S114). The flow of air after hydrocarbon injection will help purge the nozzle of residual hydrocarbon and the continued flow of air helps cool the nozzle to help inhibit or prevent coke fouling.
It is noted that according to the invention, at low exhaust temperatures where the temperature is not sufficiently high to oxidize carbon, air flows continuously through the nozzle to maintain nozzle temperatures as low as possible to slow carbon deposition. At exhaust temperatures high enough to support oxidation of carbon deposited on the nozzle, air flow through the nozzle is completely or substantially completely shut off to avoid cooling the nozzle and allow oxidation of any coking.
In the present application, the use of terms such as “including” is open-ended and is intended to have the same meaning as terms such as “comprising” and not preclude the presence of other structure, material, or acts. Similarly, though the use of terms such as “can” or “may” is intended to be open-ended and to reflect that structure, material, or acts are not necessary, the failure to use such terms is not intended to reflect that structure, material, or acts are essential. To the extent that structure, material, or acts are presently considered to be essential, they are identified as such.
While this invention has been illustrated and described in accordance with a preferred embodiment, it is recognized that variations and changes may be made therein without departing from the invention as set forth in the claims.
| Filing Document | Filing Date | Country | Kind | 371c Date |
|---|---|---|---|---|
| PCT/US12/48277 | 7/26/2012 | WO | 00 | 1/13/2015 |
