Fluids, e.g. heated fluids, are often impinged upon substrates for a variety of purposes. For example, a heated fluid may be impinged upon a substrate for purposes of annealing, drying of a surface coating, promoting a chemical reaction or a physical change, and the like. Often, an impinged fluid is allowed to escape into the surrounding atmosphere, where it may be allowed to disperse or may be at least partially removed by a duct, hood, or the like.
Herein are disclosed apparatus and methods for impinging a heated fluid onto the surface of a substrate and then locally removing the impinged fluid. The apparatus and methods may be used to heat a surface of a substrate e.g. so that the substrate can be melt-bonded to another substrate.
Thus in one aspect, herein is disclosed a method of impinging a heated first fluid onto a first surface of a first moving substrate, and locally removing at least a portion of the impinged heated first fluid, and bonding the first surface of the first moving substrate to a first surface of a second moving substrate, the method comprising: providing at least one first fluid delivery outlet and at least one first fluid capture inlet that is locally positioned relative to the first fluid delivery outlet; passing the first moving substrate by the first fluid delivery outlet and impinging a heated first fluid from the first fluid delivery outlet onto the first surface of the first moving substrate so that the first surface of the first substrate is a heated surface; locally capturing at least 60% of the volumetric flow of impinged first fluid by way of the at least one first fluid capture inlet and removing the locally captured first fluid through at least one first fluid removal channel that is fluidly connected to the first fluid capture inlet; contacting a first surface of a second moving substrate with a second fluid that is at least 100 degrees C. lower in temperature than the temperature of the heated first fluid; and, contacting the heated first surface of the first substrate with the first surface of the second substrate so that the first surface of the first substrate and the first surface of the second substrate melt-bond to each other.
Thus in another aspect, herein is disclosed an apparatus for impinging a heated first fluid onto a first surface of a first moving substrate, and locally removing at least a portion of the impinged heated first fluid, and bonding the first surface of the first moving substrate to a first surface of a second moving substrate, the apparatus comprising: at least one first fluid delivery outlet and at least one first fluid capture inlet that is locally positioned relative to the first fluid delivery outlet; a first backing surface configured to support the first moving substrate and to carry the first moving substrate by the first fluid delivery outlet so that a heated first fluid that is delivered from the first fluid delivery outlet is impinged upon the first surface of the first moving substrate so that it is a heated first surface; and, a second backing surface configured to support the second moving substrate and to carry the second moving substrate along a converging path which brings the first major surface of the second moving substrate into contact with the heated first surface of the first moving substrate.
Like reference numbers in the various figures indicate like elements. Some elements may be present in similar or identical multiples; in such cases the elements may comprise the same reference number, with one or more of the elements designated by a prime (′) for convenience of description. Unless otherwise indicated, all figures and drawings in this document are not to scale and are chosen for the purpose of illustrating different embodiments of the invention. In particular the dimensions of the various components are depicted in illustrative terms only, and no relationship between the dimensions of the various components should be inferred from the drawings, unless so indicated. Although terms such as “top”, bottom”, “upper”, lower”, “under”, “over”, “front”, “back”, “outward”, “inward”, “up” and “down”, and “first” and “second” may be used in this disclosure, it should be understood that those terms are used in their relative sense only unless otherwise noted.
The apparatus and methods described herein are directed to the impinging of a heated first fluid (i.e., a heated gaseous fluid) onto a first (major) surface of a first moving substrate so that the first surface becomes a heated first surface, and the local removal of at least a portion (e.g., at least about 60 volume percent, at least about 80 volume percent, or substantially all) of the impinged heated first fluid. The apparatus and methods described herein are further directed to the contacting of a first surface of a second moving substrate with a second fluid that is at least 100 degrees C. lower in temperature than the temperature of the heated first fluid (such second fluid that is at least 100 degrees C. lower in temperature than the temperature of the heated first fluid will be referred to herein for convenience as “lower-temperature” second fluid). By at least 100 degrees C. lower in temperature is meant that the temperature of the second fluid is lower than that of the heated first fluid by a difference of at least 100 degrees C. For example, if the temperature of the heated first fluid is 150° C., the temperature of the second fluid is 50° C. or lower.
In some embodiments, the second fluid may be a heated fluid (although remaining at least 100 degrees C. lower in temperature than that of the first heated fluid, as defined above) that is impinged on the first surface of the second substrate e.g. by way of a conventional blower, duct, hot air delivery system, or the like. In some embodiments, the second fluid may be an ambient-temperature fluid (meaning it is generally at the temperature of the ambient surrounding air in which the apparatus is located). In such case, the ambient-temperature fluid may be a moving fluid (e.g., forced air) that is actively impinged onto the first surface of the second substrate, e.g. by a conventional blower, etc. Alternatively, the ambient-temperature fluid may be quiescent (unforced) air, with the contacting of the air with the first surface of the second substrate occurring by virtue of motion of the second substrate through the quiescent air. In some embodiments, the second fluid may be a cooled fluid, meaning fluid which has been cooled (e.g., through the use of refrigeration equipment, cooling water, or the like) to a temperature that is colder than the ambient temperature of the surrounding air, and that is contacted with (e.g., impinged upon) the first surface of the second substrate.
In some embodiments in which the second fluid is impinged upon the first surface of the second substrate, no mechanism for actively removing the impinged second fluid may be employed. In other embodiments, a conventional hood, shroud, duct, etc., may be used to (non-locally) actively remove at least a portion of the impinged second fluid. In some embodiments, the second fluid (whether heated, cooled, or ambient-temperature) may be impinged onto the first surface of the second substrate by way of a fluid delivery outlet, with at least a portion (e.g., at least about 60 volume percent, at least about 80 volume percent, or substantially all) of the impinged second fluid being locally removed by at least one second fluid capture inlet, as discussed in detail elsewhere herein.
In various embodiments, the temperature of the heated first fluid may be at least about 150° C., at least about 200° C., at least about 250° C., or at least about 300° C. In various embodiments, the temperature of the lower-temperature second fluid may be at most about 200° C., at most about 100° C., or at most about 50° C. In some embodiments, the lower-temperature second fluid may be at ambient temperatures (which, depending on the particular environment in which the apparatus is located, may range from e.g. 15° C. to 35° C.). In some embodiments, the lower-temperature second fluid may be cooled to below the ambient temperature, as mentioned above.
The heated first surface of the first moving substrate (upon which the heated first fluid was impinged), and the first surface of the second moving substrate (with which the second fluid was contacted), may then be contacted with each other to facilitate melt-bonding (e.g. surface-bonding) of the surfaces to each other. That is, after the heating of the first surface of the first substrate by the impinged heated first fluid, the first surfaces of the first and second substrate can be brought into contact with each other while the first surface of the first substrate remains in a heated condition which will, upon contact with the first surface of the second substrate, cause the temperature of the first surface of the second substrate to momentarily increase so that melt-bonding can be achieved. Those of ordinary skill in the art will recognize such melt-bonding as a process in which molecules of the first substrate and of the second substrate at least slightly intermix while in a heated state and then remain intermixed upon cooling and solidification so that a bond is achieved.
As disclosed herein, the impinging of the heated first fluid onto the first surface of a moving substrate can raise the temperature of the first surface of the first substrate sufficiently for melt-bonding to be achieved, without necessarily raising the temperature of the remaining portions of the first substrate (e.g., the interior of the substrate and/or the second, opposing major surface of the substrate) to a point sufficient to cause unacceptable physical changes or damage to the first substrate. Moreover, the contacting of the second substrate with a lower-temperature second fluid may ensure that the second substrate is not unacceptably physically changed or damaged by the process of being melt-bonded to the first substrate.
Shown in
Backing surfaces 231 and 221 may comprise any suitable surface. If a moving substrate is discontinuous or porous (e.g., if the substrate is a fibrous web) such a backing surface may be a solid surface that serves to occlude the second major surface of the substrate such that the impinging fluid does not penetrate through the thickness of the substrate and exit through the second major surface of the substrate. Thus in these embodiments, the heating of a major surface of a moving substrate by the impinging of heated fluid as described herein, does not encompass methods in which a heated fluid is impinged upon a major surface of a substrate and passed through the substrate so as to exit through the oppositely-facing major surface of the substrate.
In some embodiments, a backing surface may be provided by a backing roll, e.g., a temperature-controlled roll. Thus, in the exemplary illustration of
In the illustrated embodiment of
Upon exiting nip 222, laminate 150 may be cooled if desired, e.g. by contacting one or both major surfaces of laminate 150 with a cooling roll, by the impinging of a cooling fluid upon one or both surfaces of laminate 150, and the like. Laminate 150 may thereafter be processed through any suitable web-handling process, rolled up, stored, etc. For example, additional layers may be coated or laminated on laminate 150, individual pieces may be cut therefrom as described previously, and so on.
In some embodiments, the impinging of a heated first fluid onto first surface 112 of substrate 110, and the impinging of a lower-temperature second fluid onto the first surface 121 of substrate 120, may be achieved by the use of nozzle 400 as illustrated in exemplary manner in
As shown in side view in
Portions of the interior of nozzle 400 may be divided (e.g., by interior partition 422 shown in
While the exemplary nozzle 400 of
Typically, nozzle 400 will comprise solid (i.e., impermeable) partitions 442 and 442′ that collectively define fluid delivery channels 421 and 431. The terminal ends of partitions 442 and 442′ that are closest to substrate 110 may collectively define fluid delivery outlet 420 (and may be the only elements that define fluid delivery outlet 420 if outlet 420 does not comprise a fluid-permeable sheet (described later in detail) at its working face. Similarly, the terminal ends of partitions 442 and 442′ that are closest to substrate 120 may collectively define fluid delivery outlet 430.
Partitions 442 and 442′ may be positioned generally parallel to each other (e.g., in similar manner as shown in
For convenience of description, first fluid delivery outlet 420 is characterized as comprising working face 424, which can be most conveniently considered to be the surface through which the heated fluid passes as it exits outlet 420. Working face 424 may be an imaginary surface, such as an imaginary arcuate surface (e.g., a section of a cylindrical surface) defined by terminal ends of partitions 442 and 442′. Or, working face 424 may comprise a physical layer, e.g. a fluid-permeable sheet, as discussed later herein in detail. Second fluid delivery outlet 430 is likewise characterized as comprising working face 434.
Each outlet and working face thereof may have a circumferential length, and a lateral width (extending in a direction transverse to the direction of motion of the adjacent substrate, i.e. extending in a direction aligned with the long axes of the adjacent backing roll). In some embodiments, the circumferential length may be longer than the lateral width, so that the outlet is circumferentially elongated. While in the exemplary illustration of
In the exemplary embodiment of
Those of ordinary skill in the art will realize that in embodiments with arcuate fluid delivery outlets (described below in more detail), the relative orientation of normal axes 423 and 433 may vary with the circumferential location along each outlet at which the normal axis is positioned. In such cases, the denoting that two fluid delivery outlets are in diverging relation means that at least the portions of the two outlets that are in closest proximity to each other (e.g., the portions of outlets 420 and 430 that are proximal to salient 435) are in diverging relation. In some cases, e.g. in which at least one of the fluid delivery outlets is circumferentially extended so as to form e.g. a nearly-semicylindrical shape, a portion of that fluid delivery outlet that is distal to the other fluid delivery outlet (e.g., distal to salient 435) may not be in diverging relation with any or all portions of the other fluid delivery outlet. However, in such cases, as long as the above-described condition is met in which at least portions of the two outlets that are in closest proximity to each other are in diverging relation, the fluid delivery outlets are still considered to be in diverging relation as defined herein.
First and second fluid delivery outlets 420 and 430 arranged in diverging relation as disclosed herein may be particularly advantageous for the directing of first and second fluids onto two converging substrates. In particular, such fluid delivery outlets in diverging relation allow nozzle 400 to be placed closely adjacent to a nip (e.g., a lamination nip) established by backing rolls, e.g., in the manner depicted in
In the exemplary illustration of
In particular embodiments, first fluid delivery outlet 420 is arcuate with a working face 424 that is generally congruent with the adjacent surface of backing roll 230, and second fluid delivery outlet 430 is arcuate with a working face 434 that is generally congruent with the adjacent surface of backing roll 220. This may allow nozzle 400 to be positioned such that each working face of each fluid delivery outlet is very close to the first major surface of its respective substrates.
In embodiments in which outlets 420 and 430 are desired to be closely mated to the adjacent surface of (cylindrical) backing rolls, the working face of each outlet may comprise an arcuate shape that is a section of a generally cylindrical surface with a radius of curvature matching that of the surface of the backing roll to which the outlet is to be mated. In situations in which backing roll 220 and backing roll 230 are the same diameter, the two fluid delivery outlets thus may be symmetric with the same radius of curvature. However, if backing roll 220 and backing roll 230 differ in diameter, as in the embodiment shown in
The circumferential length of each arcuate outlet may differ as desired. For example, in
Fluid delivery outlet 420 and fluid delivery outlet 430 may be chosen to have any suitable lateral width. As used herein, lateral means in the direction transverse to the direction of motion of a substrate to be heated and in a direction parallel to the long axis of the backing roll (i.e., the direction in and out of plane in
A circumferential end of first fluid delivery outlet 420, and a circumferential end of second fluid delivery outlet 430, may be positioned adjacent to each other so as to form protruding salient 435, as shown in exemplary manner in
In some embodiments, the working surface of a fluid delivery outlet may not be congruent with the backing roll to which it is mated. For example, either or both of outlets 420 and 430 could be generally planar (flat) rather than arcuate as shown in
As mentioned, the working face of a fluid delivery outlet may be open; or, it may comprise a fluid-permeable sheet through which the fluid may be passed. Such a fluid-permeable sheet may render the flow of fluid through the outlet more uniform, e.g. over the circumferential length of the outlet. Additionally, depending on the characteristics of the sheet, the sheet may redirect the fluid somewhat away from its original direction of flow through the fluid delivery channel. For example, with reference to
In various embodiments, the fluid-permeable sheet may comprise through-openings that collectively provide the sheet with a percent open area of at least about 20, at least about 30, or at least about 40. In further embodiments, the fluid-permeable sheet may comprise a percent open area of at most about 90, at most about 80, or at most about 70. In specific embodiments, the fluid-permeable sheet may comprise a perforated screen with through-holes of a diameter of at least about 0.2 mm, at least about 0.4 mm, or at least about 0.6 mm. The fluid-permeable sheet may comprise e.g. a perforated screen with through-holes of a diameter of at most about 4 mm, at most about 2 mm, or at most about 1.4 mm. The through-holes may be in the form of elongated, e.g. laterally-elongated, slots or the like. The combination of percent open area and through-hole size may be chosen to enhance the uniform heating of the substrate. The screen may be comprised of any material with durability and temperature resistance sufficient for the uses outlined herein. Metal screen, e.g. steel, may be suitable.
A fluid (e.g., a heated first fluid) may exit a working face of a fluid delivery outlet at any suitable nominal linear velocity (volumetric flowrate divided by the open area of the outlet). The velocity of such a fluid may be affected and/or determined by the volumetric flowrate of fluid supplied to first fluid delivery channel 421 by supply line 410, by the size of fluid delivery outlet 420, by the percent open area and/or diameter of the through-holes in a fluid-permeable sheet (if present) at the working face of the outlet, etc. The linear velocity may often be in the low subsonic range, e.g., less than Mach 0.5, typically less than Mach 0.2. Often, the linear velocity will be in the range of a few meters per second; e.g., less than 50, less than 25, or less than 15 meters per second. As such, the fluid impingement apparatus and methods used herein can be distinguished from the use of e.g. hot air knives, which often rely on a linear velocity approaching or exceeding sonic velocity.
As mentioned, during operation of apparatus 1 the linear velocity of the lower-temperature second fluid exiting nozzle 400 through outlet 430 can be controlled independently of that the heated first fluid exiting through outlet 420. The area of working faces 424 and 434 of outlets 420 and 430, respectively, may be chosen so as to impinge fluid on an area of desired size, and may be chosen in consideration of the characteristics of the substrates to be heated (e.g., their width, thickness, density, heat capacity, etc.). Often, outlets with working faces in the range of from e.g. about 5 to 500 square centimeters may be used. The volumetric flowrate of the heated first fluid and of the lower-temperature second fluid, and the temperature thereof, may each be chosen as desired. For melt-bonding applications, the temperature of the heated first fluid may be chosen to be at least equal to, or somewhat above, the softening point or melting point of a component of the first substrate.
Any suitable heated gaseous fluid may be used as the heated first fluid, with ambient air being a convenient choice. However, dehumidified air, nitrogen, an inert gas, or a gas mixture chosen to have a specific effect (e.g. the promotion of bondability, hydrophobicity, etc.) may be used as desired. The fluid may be heated by an external heater (not shown in any figure) prior to being delivered to nozzle 400 through supply line 410. In addition, or instead, heating elements may be supplied within nozzle 400; or additional heating (e.g., resistance heating, infrared heating, etc.) of nozzle 400 may be applied. Similarly, the temperature of the lower-temperature second fluid may be controlled (via heating or cooling) by any suitable method.
As disclosed herein, the heated first fluid, after having been impinged on the first substrate, is locally removed. By local removal is meant that heated first fluid that has been impinged on the surface of the first substrate by a nozzle is actively removed from the local vicinity of the fluid impingement nozzle. This is to be contrasted with processes in which an impinged heated fluid is passively allowed to escape from the local vicinity of the nozzle, either to dissipate into the surrounding atmosphere or to be removed by a device (e.g., a hood, shroud, duct, etc.) that is positioned some distance (e.g., at least a decimeter) away from the fluid impingement nozzle. Such local removal can be achieved by the use of a nozzle of the general type described earlier herein, comprising a fluid delivery channel with a fluid delivery outlet, with the addition of at least one fluid capture inlet that is locally positioned relative to the fluid delivery outlet. By locally positioned it is meant that at their point of closest approach to each other, the fluid capture inlet is located less than 10 mm from the fluid delivery outlet. In various embodiments, at their point of closest approach, the fluid capture inlet is located less than about 5 mm, or less than about 2 mm, from the fluid delivery outlet. The fluid capture inlet is fluidly connected to a fluid removal channel, through which fluid that has been captured by the fluid capture inlet can be actively removed (e.g., by way of an exhaust line fluidly connected to an external suction blower, not shown in any figure). The fluid capture inlet can locally remove a substantial volume percent of the impinged fluid from the local vicinity of the nozzle before the impinged fluid is able to exit the local vicinity of the substrate and irreversibly disperse into the surrounding atmosphere so as to no longer be locally removable. In various embodiments, at least about 60%, at least about 80%, or substantially all, of the volumetric flow of the impinged heated first fluid is locally removed by the apparatus and methods disclosed herein.
Exemplary nozzle 500 with a locally positioned fluid capture inlet is shown in representative manner in
While in the exemplary embodiment of
In similar manner to nozzle 400, nozzle 500 comprises fluid delivery outlet 520 comprising working face 524 (which in this case comprises perforated screen 525), with fluid delivery outlet 520 being fluidly connected to fluid delivery channel 521 (of which only the portion proximate to fluid delivery outlet 520 is shown in
Referring again to the simplified, representative one delivery outlet, one-substrate illustration of
Working faces 544 and 544′ of fluid capture inlets 540 may be positioned approximately even with working face 524 of fluid delivery outlet 520, so that working faces 544, 544′ and 524 are generally equidistant from surface 101 of substrate 100, as represented by distance 545 in
Those of ordinary skill in the art will appreciate that by the methods disclosed herein, impinged fluid may be circulated at least slightly laterally beyond the boundaries of the fluid capture inlets and yet still locally captured by the fluid capture inlets and removed. It has been found that adjustment of the design of nozzle 500 and of the operating parameters of the system (e.g., flowrate of fluid, suction applied through the fluid removal channels, etc.) can alter the extent to which the impinged fluid is able to penetrate laterally beyond the boundaries of the fluid capture inlets before being captured by the capture inlets, and/or can alter the extent to which ambient air is captured in addition to the impinged fluid, either of both of which can advantageously enhance the uniformity of the heating experienced by substrate 100.
In considering
As mentioned, in some embodiments a nozzle that is configured to impinge a fluid on a substrate and also to locally capture and remove at least a portion of the impinged fluid may be a single-sided nozzle (described in further detail later herein with regard to
A nozzle corresponding to such a dual-sided embodiment is described in further detail with reference to
Nozzle 500 additionally comprises second fluid delivery outlet 550 with working face 554, outlet 550 being fluidly connected to second fluid delivery channel 551, and being laterally flanked by second fluid capture inlets 560 and 560′ with working faces 564 and 564′ respectively and which are fluidly connected to second fluid removal channels 561 and 561′ respectively. All of these features are analogous to nozzle 400 of
In nozzle 500 of
At least one fluid exhaust line is used to exhaust the locally captured fluid from the fluid removal channels of nozzle 500. In some embodiments, fluid removal channels 541 and 561 may comprise portions of a single fluid removal channel, there being no dividing partition in between. Thus in this embodiment a single fluid exhaust line may be used to exhaust fluid from removal channels 541 and 561. If a partition (e.g., a portion of partition 522) is provided between fluid removal channels 541 and 561, separate fluid exhaust lines 571 and 572 can be provided for each fluid removal channel, as shown in
First fluid delivery outlet 520 may be used to impinge heated first fluid onto first major surface 101 of first moving substrate 100, while substrate 100 is in contact with backing surface 201 (e.g., of backing roll 200). Likewise, fluid delivery outlet 550 may be used to impinge lower-temperature second fluid onto first major surface 106 of second moving substrate 105, while substrate 105 is in contact with backing surface 206 (e.g., of backing roll 205). These operations may be conducted in similar manner as described for nozzle 400, except that fluid capture inlets 540, 540′, and 560 and 560′ and associated fluid removal channels, etc. are used as described above, to locally capture and remove at least a portion of the impinged fluids.
In some cases it may be desirable to provide multiple, laterally spaced fluid delivery outlets each fluidly connected to a fluid delivery channel. As elsewhere herein, laterally signifies a direction transverse to the direction of motion of the substrate upon which the fluid is to be impinged, e.g. along the long axis of a backing roll.
The descriptions of the various fluid delivery and removal channels, fluid delivery outlets and fluid capture inlets provided earlier herein with regard to nozzles 400 and 500, are applicable to the various channels, outlets and inlets of nozzle 600. And, of course, while shown (for convenience of description) in
As illustrated in
The basic design of nozzle 600, in which multiple, laterally spaced fluid delivery outlets are used, in which fluid capture inlets are positioned outwardly laterally flanking the fluid delivery outlets, and in which an additional fluid capture inlet is positioned laterally in between the fluid delivery outlets, can be extended as desired. That is, a nozzle may be produced with any number of fluid delivery outlets (with their long axis aligned generally in the direction of motion of the web), laterally interspersed in an alternating manner with fluid capture inlets. As mentioned previously, multiple, physically separate fluid delivery outlets and fluid capture inlets can be provided, to a similar end. Any such design may allow wide-width substrates to be heated by the methods disclosed herein.
Further details concerning the impinging of one or more fluids onto one or more substrates may be found in U.S. patent application Ser. No. 12/974,329, filed Dec. 21, 2010, entitled Apparatus and Methods for Impinging Fluids on Substrates, which is incorporated by reference in its entirety herein.
A fluid delivery outlet may be positioned at any suitable orientation (e.g., angular orientation) relative to the path of a moving substrate which it is used to impinge a fluid upon. Such orientations may be discussed with reference to the view of
In some embodiments, a fluid delivery outlet 820 may comprise a long axis, as is evident in
It will be noted that
Further details concerning the orientation of fluid delivery outlets relative to the long axis and/or pathway of a substrate upon which a fluid is impinged, may be found in U.S. patent application Ser. No. 13/029,155, filed Feb. 17, 2011, entitled Apparatus and Methods for Impinging Fluids on Substrates, which is incorporated by reference in its entirety for this purpose herein.
Those of ordinary skill will appreciate that many variations of the above-discussed arrangements and conditions may be employed. For example, in some embodiments a dual-sided nozzle may be used, of the general type illustrated in
In other embodiments, a nozzle capable of dual-sided use may be employed, but the impingement of lower-temperature second fluid onto the second substrate may be restricted or even completely eliminated. This may be performed e.g. by closing a shutter on the working face of the second fluid delivery outlet(s) as mentioned earlier herein, by closing a valve anywhere along the second fluid delivery channel(s), by not supplying any second fluid to the nozzle through a second fluid supply line, or by any suitable method of blocking or eliminating the flow of the second fluid. If the delivery of lower-temperature second fluid from such a nozzle is completely eliminated, the contacting of a second substrate with a lower temperature fluid may occur via use of a conventional blower or the like, or simply by way of the motion of the second substrate through the ambient atmosphere within which the apparatus is located. In various embodiments, a conventionally-delivered (i.e., without local removal) lower-temperature second fluid may be a heated fluid (although remaining more than 100 degrees C. lower than the temperature of the heated first fluid, as disclosed herein), may be an ambient-temperature fluid (e.g., air), or may be a cooled fluid.
In other embodiments, a nozzle may be used which is a “single-sided nozzle”, as shown in generic representation as nozzle 401 of
The apparatus and methods disclosed herein may be used e.g. to facilitate the melt-bonding of the surfaces of two substrates to each other. In particular, they may be used to surface-bond a first, fibrous substrate to another, second substrate to make a surface-bonded laminate. By this is meant that the fibrous substrate may be attached to the second substrate by way of some the fibers of a first surface of the fibrous substrate being surface-bonded to a first surface of the second substrate. The designation that fibers of the first substrate are surface-bonded to the first major surface of the second substrate means that parts of the surfaces of at least some fiber portions are melt-bonded to the first surface of the second substrate, in such a manner as to substantially preserve the original (pre-bonded) shape of the first major surface of the second substrate, and to substantially preserve at least some portions of the first major surface of the second substrate in an exposed condition, in the surface-bonded area.
The requirement that surface bonding substantially preserves the original shape of the first major surface means that surface-bonded fibers may be distinguished from fibers that are bonded to a substrate in a manner that results in fiber portions being embedded (e.g., partially or completely encapsulated) within the substrate by way of at least partial penetration of the fibers into the substrate, deformation of the substrate, and the like. The requirement that surface bonding substantially preserves at least some portions of the first major surface of the second substrate in an exposed condition means that surface-bonded fibers may be distinguished from fibers that are bonded to a second substrate in a manner that results in the fibers being sufficiently melted, densified, compacted, commingled etc., so as to form a continuous bond. By continuous bond is meant that fibers immediately adjacent to the first major surface of the second substrate have commingled and/or densified sufficiently (e.g., melted together so as to partially or completely lose their identity as individual fibers) to form a continuous layer of material atop, and in contact with, the first major surface. Those of ordinary skill in the art will appreciate that fibrous webs that are bonded to substrates that are still in a molten, semi-molten, soft, etc. state, (such as extruded materials that have not yet cooled e.g. to a solid condition), may not comprise surface bonding, since bonding to a substrate that is still at such a high temperature and/or is still considerably deformable, may cause the fibers to become embedded, may cause the formation of a continuous bond, or both.
Although particularly useful in the bonding of a fibrous substrate to a film substrate (e.g., in order to form a surface-bonded laminate as described above), the apparatus and methods disclosed herein can be used to melt-bond any two suitable substrates to each other. It should also be understood that, although discussions herein have focused primarily on the representative configuration in which a first substrate (upon whose first surface a heated first fluid is impinged) is a fibrous substrate, and a second substrate (whose first surface is contacted with a lower-temperature second fluid) is a film substrate, the substrate roles may be swapped if desired. Suitable substrates may be made of any suitable thermoplastic polymeric material (e.g., a material that is melt-bondable). Such materials may include e.g. polyolefins, polyesters, polyamides, and various other materials. Examples of suitable polyolefins include polyethylene, polypropylene, polybutylene, ethylene copolymers, propylene copolymers, butylene copolymers, and copolymers and blends of these materials. The substrate may comprise various additives and the like, as are well known in the art, as long as such additives do not unacceptably reduce the ability of the substrate to be melt bonded. If the substrate comprises a film substrate, it may be a multilayer substrate, e.g. a coextruded multilayer film, as long as a first major surface of an outermost layer of the multilayer substrate is able to be melt-bonded to another substrate. In some embodiments, one or both of the substrates to be bonded may comprise a preformed substrate, by which is meant that it is a pre-existing, previously-made substrate (e.g., film, nonwoven web, etc.) whose physical properties have generally fully developed. This should be contrasted e.g. with a case in which a substrate is made (e.g., extruded) and taken generally directly into the herein-described bonding process in a condition in which it is still generally molten, semi-molten, soft, or the like.
Suitable substrates may be any desired thickness. In various embodiments, the thickness of a substrate (not including the height of any protrusions) may be less than about 400 microns, less than about 200 microns, less than about 100 microns, or less than about 50 microns. In some embodiments, a substrate to be bonded does not comprise any adhesive (i.e., hot melt adhesive, pressure sensitive adhesive, and the like) e.g. in the form of coatings on a major surface of the web. In some embodiments, a substrate may be continuous, i.e. without any through-penetrating holes. In other embodiments, a substrate may be discontinuous, e.g. comprising through-penetrating perforations and the like. In some embodiments, a substrate may be comprised of a dense, nonporous material. In some embodiments, a substrate may be comprised of a porous material. In particular embodiments, a substrate may comprise a fibrous web, e.g. a nonwoven fibrous web.
In some embodiments, a first major surface and a second, oppositely-facing major surface of a substrate may be free of protrusions. In other embodiments, optional protrusions may protrude from a second major surface of the substrate, e.g., the surface opposite the surface which is to be melt-bonded to another substrate by the apparatus and methods disclosed herein. Such protrusions can be of any desired type, shape or design, present at any desired density per area of substrate, as desired for any suitable purpose. Such protrusions may be integral with (that is, of the same composition, and formed at the same time with as a unit) the substrate. In some embodiments, such protrusions may comprise male fastening elements, e.g. hooks, of the type that are capable of engaging with a fibrous material and which can serve as the hook component of a so-called hook and loop fastening system. Any such male fastening elements can be used. In particular embodiments, fastening elements may be used that each comprise a stem and a relatively large head (that may be e.g. generally mushroom-shaped, a flattened disc, and the like), of the general type described in U.S. Pat. Nos. 6,558,602, 5,077,870, and 4,894,060. Suitable substrates with protrusions comprising male fastening elements include e.g. those products available from 3M Company, St. Paul, Minn., under the trade designation CS200 and CS 600. Other suitable substrates include e.g. those described in U.S. Pat. Nos. 7,067,185 and 7,048,984.
If a substrate to be bonded is a fibrous substrate, it may be any suitable fibrous web with sufficient mechanical strength to be handled as a self-supporting web and to be subjected to the bonding processes described herein. In some embodiments, such a fibrous web may comprise interlaced fibers such as achieved by weaving, knitting, stitching and the like. As such, a fibrous web may be comprised of a suitable fabric or textile, as long as the materials comprising the fibers are suitable for the herein-described bonding. In some embodiments, the fibrous web comprises a nonwoven fibrous web. Any suitable self-supporting nonwoven fibrous web may be used, made of any material as desired, as long as the herein-described bonding can be performed. Such a nonwoven fibrous web may be e.g. a carded web, spunbonded web, a spunlaced web, an airlaid web, or a meltblown web (i.e., as long as such a web has undergone sufficient processing as to render it self-supporting). Such a nonwoven fibrous web may be a multilayer material with, for example, at least one layer of a meltblown web and at least one layer of a spunbonded web, or any other suitable combination of nonwoven webs. For instance, it may be a spunbond-meltbond-spunbond, spunbond-spunbond, or spunbond-spunbond-spunbond multilayer material. Or, the web may be a composite web comprising a nonwoven layer and a dense film layer, as exemplified by webs comprising nonwoven fibers bonded in arcuately protruding loops to a dense film backing and available from 3M Company, St. Paul, Minn., under the trade designation Extrusion Bonded Loop.
Such a fibrous web may be made of any suitable thermoplastic polymeric material (e.g., a material that is melt-bondable). Such materials may include e.g. polyolefins, polyesters, polyamides, and various other materials. Examples of suitable polyolefins include polyethylene, polypropylene, polybutylene, ethylene copolymers, propylene copolymers, butylene copolymers, and copolymers and blends of these materials. In some embodiments, some or all of the fibers of the web may comprise monocomponent fibers. In some embodiments, the fibrous web may also or instead comprise bicomponent fibers, e.g., that comprise a sheath of lower-melting material surrounding a core of higher melting material. If desired, the sheath material may be chosen so as to enhance its ability to melt-bond to another substrate. Other fibers (e.g., staple fibers and the like) may be present. In some embodiments, the fibrous web does not comprise any adhesive (i.e., hot melt adhesive, pressure sensitive adhesive, and the like) as might be present in the form of adhesive particles, binder or the like, distributed throughout the web or on a major surface of the web.
Further details concerning surface bonding of substrates and properties of surface-bonded substrates may be found in U.S. patent application Ser. No. 12/974,536, filed Dec. 21, 2010, entitled Bonded Substrates and Methods for Bonding Substrates, which is incorporated by reference in its entirety for this purpose herein.
A method of impinging a heated first fluid onto a first surface of a first moving substrate, and locally removing at least a portion of the impinged heated first fluid, and bonding the first surface of the first moving substrate to a first surface of a second moving substrate, the method comprising: providing at least one first fluid delivery outlet and at least one first fluid capture inlet that is locally positioned relative to the first fluid delivery outlet; passing the first moving substrate by the first fluid delivery outlet and impinging a heated first fluid from the first fluid delivery outlet onto the first surface of the first moving substrate so that the first surface of the first substrate is a heated surface; locally capturing at least 60% of the volumetric flow of impinged first fluid by way of the at least one first fluid capture inlet and removing the locally captured first fluid through at least one first fluid removal channel that is fluidly connected to the first fluid capture inlet; contacting a first surface of a second moving substrate with a second fluid that is at least 100 degrees C. lower in temperature than the temperature of the heated first fluid; and, contacting the heated first surface of the first substrate with the first surface of the second substrate so that the first surface of the first substrate and the first surface of the second substrate melt-bond to each other.
The method of embodiment 1 wherein the second fluid is ambient-temperature, quiescent air that is contacted with the first surface of the second substrate by way of the second moving substrate being moved through the ambient-temperature quiescent air.
The method of embodiment 1 wherein the second fluid is an ambient-temperature fluid that is impinged onto the first surface of the second substrate.
The method of embodiment 1 wherein the second fluid is a heated fluid that is impinged onto the first surface of the second substrate.
The method of embodiment 1 wherein the second fluid is a cooled fluid that is impinged onto the first surface of the second substrate.
The method of any of embodiments 1-5 comprising locally capturing at least 80% of the volumetric flow of the impinged first fluid.
The method of any of embodiments 1-6 comprising locally capturing substantially all of the volumetric flow of the impinged first fluid.
The method of any of embodiments 1-7 wherein the nominal velocity of the heated first fluid passing through the at least one first fluid delivery outlet is less than 0.2 Mach.
The method of any of embodiments 1-8 wherein the at least one first fluid delivery outlet and the at least one first fluid capture inlet are each positioned less than 5 mm from the first surface of the first moving substrate.
The method of any of embodiments 1-9 wherein the at least one first fluid delivery outlet comprises an elongated shape with a long axis, and wherein a pair of first fluid capture inlets, each with an elongated shape with a long axis, are positioned in a laterally outwardly flanking relationship with the first fluid delivery outlet, with the long axis of the first fluid capture inlets being generally parallel to the long axis of the first fluid delivery outlet, and wherein the long axis of the first fluid capture inlets and of the first fluid delivery outlet are generally aligned with the direction of motion of the first substrate.
The method of embodiment 10 wherein the at least one first fluid delivery outlet is one of a pair of laterally-spaced first fluid delivery outlets, with the pair of first fluid capture inlets laterally outwardly flanking the pair of first fluid delivery outlets and with an additional first fluid capture inlet laterally sandwiched between the pair of first fluid delivery outlets.
The method of any of embodiments 1-11 wherein the first moving substrate comprises a long axis, wherein the at least one first fluid delivery outlet comprises an elongated shape with a long axis, and wherein the long axis of the at least one first fluid delivery outlet is generally aligned with the long axis of the first substrate.
The method of any of embodiments 1-12 wherein the first moving substrate comprises a long axis, wherein the at least one first fluid delivery outlet comprises an elongated shape with a long axis, and wherein the long axis of the at least one first fluid delivery outlet is oriented transversely to the long axis of the first substrate.
The method of any of embodiments 1-13 wherein the first moving substrate is in contact with the surface of a first backing roll and the second moving substrate is in contact with the surface of a second backing roll, and wherein the first fluid delivery outlet comprises an arcuate shape generally congruent with the surface of the first backing roll, and wherein the surface of the first backing roll, and the surface of the second backing roll, respectively carry the first and second substrates along converging paths toward each other and into contact with each other so that the melt-bonding can be performed.
The method of any of embodiments 1-14 wherein the first substrate comprises a polymer film and wherein the second substrate comprises a nonwoven fibrous web.
The method of any of embodiments 1-15 wherein the first substrate comprises a nonwoven fibrous web and wherein the second substrate comprises a polymer film.
The method of any of embodiments 1 and 3-16 wherein the method further comprises providing at least one second fluid delivery outlet and at least one second fluid capture inlet that is locally positioned relative to the second fluid delivery outlet; passing the second moving substrate by the second fluid delivery outlet and impinging a lower-temperature second fluid, that is at least 100 degrees C. lower in temperature than the temperature of the heated first fluid, from the second fluid delivery outlet onto the first surface of the second moving substrate; locally capturing at least 60% of the total volumetric flow of impinged second fluid by way of the at least one second fluid capture inlet and removing the locally captured second fluid through a least one second fluid removal channel that is fluidly connected to the second fluid capture inlet.
The method of embodiment 17 wherein the at least one first fluid delivery outlet and the at least one second fluid delivery outlet are in diverging relation.
An apparatus for impinging a heated first fluid onto a first surface of a first moving substrate, and locally removing at least a portion of the impinged heated first fluid, and bonding the first surface of the first moving substrate to a first surface of a second moving substrate, the apparatus comprising: at least one first fluid delivery outlet and at least one first fluid capture inlet that is locally positioned relative to the first fluid delivery outlet; a first backing surface configured to support the first moving substrate and to carry the first moving substrate by the first fluid delivery outlet so that a heated first fluid that is delivered from the first fluid delivery outlet is impinged upon the first surface of the first moving substrate so that it is a heated first surface; and, a second backing surface configured to support the second moving substrate and to carry the second moving substrate along a converging path which brings the first major surface of the second moving substrate into contact with the heated first surface of the first moving substrate.
The apparatus of embodiment 19 wherein the first fluid delivery outlet comprises a circumferentially elongated arcuate shape and wherein the first fluid capture inlet comprises a circumferentially elongated arcuate shape that is congruent with that of the heated first fluid capture inlet.
The apparatus of any of embodiments 19-20 wherein the first fluid delivery outlet is laterally outwardly flanked by a pair of first fluid capture inlets that are both congruent with the first fluid delivery outlet.
The apparatus of any of embodiments 19-21 wherein the apparatus comprises a laterally-spaced pair of first fluid delivery outlets, with a pair of first fluid capture inlets laterally outwardly flanking the pair of first fluid delivery outlets and with an additional first fluid capture inlet laterally sandwiched between the pair of first fluid delivery outlets.
The apparatus of any of embodiments 19-22 wherein the apparatus comprises at least three laterally-spaced first fluid delivery outlets, with a first fluid capture inlet laterally sandwiched in between each two first fluid delivery outlets, and with a set of first fluid capture inlets laterally outwardly flanking the laterally outwardmost first fluid delivery outlets.
The apparatus of any of embodiments 19-23 wherein each of the at least one fluid delivery outlets comprises a working face comprising a fluid-permeable sheet comprising a discontinuous screen with through-openings providing the sheet with a percent open area of between 20% and 80%.
The apparatus of any of embodiments 19-24 wherein the first backing surface comprises the surface of a first backing roll and wherein the second backing surface comprises the surface of a second backing roll, the first and second backing rolls collectively comprising a nip-roll pair that establishes a converging pathway for the first and second substrates, and wherein the first fluid delivery outlet comprises an arcuate shape generally congruent with the surface of the first backing roll.
A first substrate was obtained from 3M Company, St. Paul, Minn. under the trade designation CS600 (of the general type described in U.S. Pat. No. 6,000,106). The first surface of the first substrate was generally smooth and the second surface of the first substrate bore protrusions at a density of approximately 2300 per square inch, (with the protrusions being male fastening elements each with an enlarged, generally disc-shaped head). The thickness of the substrate was approximately 100 microns (not counting the height of the protrusions) and the height of the protrusions was approximately 380 microns. The backing and protrusions were of integral construction and were both comprised of polypropylene/polyethylene copolymer. The first substrate was obtained as elongated strips each of 15 mm width. A second substrate was obtained that was a spunbond nonwoven web available from First Quality Nonwovens under the trade designation Spunbond 64.4 gsm (Pillow Bond). The web was 64.4 gsm with a point bonded pattern believed to be in the range of approximately 15% bonded area and a width of 110 mm, and was comprised of polypropylene.
A web handling apparatus with lamination nip was setup in similar manner to that that shown in
In using the apparatus, the first substrates were guided onto a 10.2 cm radius chrome preheat roll (analogous to roll 210 of
From the preheat roll the first substrates traversed a distance of approximately 5.1 cm to a first backing roll (analogous to roll 220 of
In using the apparatus, the nonwoven web second substrate was guided onto a second backing roll, of 10.2 cm radius (analogous to roll 230 of
The backing rolls were positioned in a horizontal stack, similar to the arrangement shown in
As viewed from a direction aligned with the movement of the two substrate strips, the first diverging face of the nozzle comprised two air delivery outlets, each of lateral width approximately 16 mm. The two air delivery outlets were laterally outwardly flanked by two air capture inlets, each of lateral width approximately 26 mm. Sandwiched laterally in between the two air delivery outlets was an additional air capture inlet, of lateral width approximately 4 mm. No perforated metal outlet plate used in this configuration. Thus, the first face of the nozzle comprised a configuration analogous to that shown in
When viewed from a direction aligned with the movement of the nonwoven web, the second diverging face of the nozzle comprised a similar arrangement of two air delivery outlets, two laterally flanking air capture inlets, and one laterally sandwiched air capture inlet. The lateral widths of the outlets and inlets were the same as for the first diverging surface. The second diverging surface comprised an adjustable shutter that extended laterally so as to laterally cover the width of both air delivery outlets, and that could be moved circumferentially along the working surfaces of the air delivery outlets so as to control the circumferential length of the air delivery outlets. The shutter also extended across the lateral width of all three fluid capture inlets. As mentioned above, the shutter was positioned so that the circumferential length of the air delivery outlets of the second diverging face was effectively approximately 0 mm, with the outlets of the second face thus being essentially completely blocked to prevent flow of heated air. (The fluid capture inlets of this face were likewise blocked by the shutter).
All of the air delivery outlets and inlets of the first and second diverging faces were fluidly connected to air delivery channels and air removal channels, respectively. The air delivery outlets were all fed by the same air delivery conduit attached to the nozzle, so that the first and second substrates would have received air at generally similar temperatures, except that the air flow onto the second substrate was essentially completely eliminated by the above-mentioned shutter. The temperature and volumetric flowrate of the heated air supplied to the nozzle could be controlled as desired (by use of a heater available from Leister, of Kaegiswil, Switzerland, under the trade designation Lufterhitzer 5000). The volumetric rate of removal of captured air (through a removal conduit attached to the nozzle) could be controlled as desired.
The nozzle was positioned close to the first and second backing rolls in a manner analogous to the position of nozzle 400 in
The heated air supply temperature was measured at 680° F. (360° C.), by use of several thermocouples and associated hardware. The volumetric flow rate of heated air and captured air was determined using a hot wire anemometer and associated hardware. The volumetric flow of heated air was approximately 1.0 cubic meters per minute. With the total area of the air delivery outlets of the first face of the nozzle being approximately 24 cm2, the linear velocity of the heated air at the working face of the outlets was estimated to be approximately 7 meters per second. The return supply volume was approximately 1.14 cubic meters per minute, thus corresponding to capture of ambient air at a volumetric flowrate of approximately 14% of that of the captured impinged air.
The above-described apparatus and methods were used to guide the elongated strip first substrates, and the nonwoven web second substrate, in an arcuate path along the surface of the first and second backing rolls respectively, during which they passed closely by the first and second diverging surfaces (respectively) of the nozzle, with only the first surface of the first substrates being impinged with heated air (with local capture of impinged air). The strip substrates and the nonwoven web then entered the nip between the two backing rolls wherein the (heated) first surfaces of the strip substrates and the first surface of the nonwoven web were brought into contact with each other. The nip between the two backing rolls was set at low pressure, with the pressure estimated to be 15 pli (pounds per linear inch), or approximately 27 N per linear cm. The line speed of the two substrates and of the nonwoven web was set to nominal 40 meters per minute.
After being contacted together, the substrates and the nonwoven web together circumferentially followed the surface of the second backing roll over an arc of approximately 180 degrees before being removed from contact with the backing roll.
This process resulted in the bonding of two parallel strips of the substrate to the first surface of the nonwoven web, with a strip of the first surface of the nonwoven web being exposed between the near edges of the substrate strips, and with strips of the first surface of the nonwoven web exposed beyond the far edges of the strips.
Upon inspection, it was found that the bond between the substrate strips and the nonwoven web was excellent, and that it was difficult to impossible to remove the substrate from the nonwoven web without significantly damaging or destroying one or both. The bonded area extended completely over the area of contact between the substrate and the nonwoven web, including the very edges of the substrate. It was also noted that the second surface of the nonwoven web (the surface opposite the surface to which the substrate was bonded) in areas where the substrate was bonded did not differ significantly from areas without the substrate. That is, it did not appear that the bonding process significantly altered the loft, density, or appearance of the nonwoven web. It was also noted that the bonding process did not appear to affect or alter the protruding male fastening elements. That is, no physical damage or deformation of the elements was noted. Qualitatively, no difference was observed in the loft of the fibrous web as a result of having undergone the bonding process. Qualitatively, no difference was observed in engagement performance of the fastening elements with fibrous materials as a result of having undergone the bonding process. Upon close inspection, the nonwoven web and the substrate were observed to be surface-bonded together, as described herein.
The tests and test results described above are intended solely to be illustrative, rather than predictive, and variations in the testing procedure can be expected to yield different results. All quantitative values in the Examples section are understood to be approximate in view of the commonly known tolerances involved in the procedures used. The foregoing detailed description and examples have been given for clarity of understanding only. No unnecessary limitations are to be understood therefrom.
It will be apparent to those skilled in the art that the specific exemplary structures, features, details, configurations, etc., that are disclosed herein can be modified and/or combined in numerous embodiments. All such variations and combinations are contemplated by the inventor as being within the bounds of the conceived invention. Thus, the scope of the present invention should not be limited to the specific illustrative structures described herein, but rather by the structures described by the language of the claims, and the equivalents of those structures. To the extent that there is a conflict or discrepancy between this specification and the disclosure in any document incorporated by reference herein, this specification will control.
This application is a divisional of U.S. application Ser. No. 13/160,036, filed on Jun. 14, 2011, U.S. Pat. No. 8,956,496, the disclosure of which is incorporated by reference in its entirety herein.
Number | Name | Date | Kind |
---|---|---|---|
3210227 | Shichman | Oct 1965 | A |
3297513 | Robinson | Jan 1967 | A |
3843480 | Dreher | Oct 1974 | A |
4021287 | Martin | May 1977 | A |
4225376 | Berg | Sep 1980 | A |
4450038 | Ishii | May 1984 | A |
5147690 | Faust | Sep 1992 | A |
5384341 | Itagaki et al. | Jan 1995 | A |
5916413 | Johnson et al. | Jun 1999 | A |
5976249 | Stahl | Nov 1999 | A |
6019152 | Haynes | Feb 2000 | A |
6066221 | Marmon | May 2000 | A |
6238767 | McCormack | May 2001 | B1 |
6256903 | Rudd | Jul 2001 | B1 |
6375776 | Buoni | Apr 2002 | B1 |
7416627 | Day | Aug 2008 | B2 |
8956496 | Biegler | Feb 2015 | B2 |
9096960 | Biegler | Aug 2015 | B2 |
9126224 | Biegler | Sep 2015 | B2 |
20030056925 | Beck | Mar 2003 | A1 |
20040068848 | Ausen | Apr 2004 | A1 |
20060065357 | Sikorski | Mar 2006 | A1 |
20060248745 | Viswanath | Nov 2006 | A1 |
20110147475 | Biegler et al. | Jun 2011 | A1 |
20110151171 | Biegler et al. | Jun 2011 | A1 |
Number | Date | Country |
---|---|---|
296 17 525 | Dec 1996 | DE |
11-170791 | Jun 1999 | JP |
10-2000-0057141 | Sep 2000 | KR |
Entry |
---|
International Search Report, PCT/US2012/040682, dated Dec. 10, 2012, 4 pages. |
“STP—Standard Temperature and Pressure & NTP—Normal Temperature and Pressure” engineeringtoolbox.com as captured by archive.org on Apr. 21, 2006. |
U.S. Appl. No. 12/974,536, filed Dec. 21, 2010. |
U.S. Appl. No. 12/974,329, filed Dec. 21, 2010. |
U.S. Appl. No. 13/029,155, filed Feb. 17, 2011. |
Number | Date | Country | |
---|---|---|---|
20150158279 A1 | Jun 2015 | US |
Number | Date | Country | |
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Parent | 13160036 | Jun 2011 | US |
Child | 14623226 | US |