The present invention is generally related to apparatus and methods for producing foamed materials.
Single component fluid materials, such as polymeric materials like thermoplastic hot melt adhesives and polymeric coatings, may be foamed before being dispensed. To that end, conventional dispensing systems may inject a gas, such as nitrogen, into solution with a single component polymeric material to transform the polymeric material into a foamed version of the material. Compressed volumes of the compressible gas are entrained in the incompressible polymeric material. When the polymeric material is dispensed and the constraint on expansion is removed, the entrained volumes of gas rapidly expand and are trapped within the polymeric material to generate a foamed fluid material. These trapped cells comprise small bubbles of gas distributed throughout the polymeric material. The resulting foamed polymeric material may then be dispensed onto a target application area.
A benefit of foaming polymeric materials is the reduced weight at equal volume with the same thickness. This benefit is advantageous in several applications, such as the manufacture of motor vehicles like automobiles and the manufacture of aircraft.
Other types of foamed materials may be formed from two or more components that may, for example, chemically react when combined. Materials of this type may, for example, include two-component and three-component adhesives. Foamed multi-component materials may be produced by conventional techniques that rely on a chemical reaction to produce entrained volumes of gas.
Apparatus and methods capable of foaming multi-component materials without the need for a chemical reaction would be desirable.
In one embodiment, a method is provided for producing a foamed material from a catalyst-containing component, a crosslinker-containing component, and a gas. The method includes mixing the catalyst-containing component and the crosslinker-containing component to form a mixture, mechanically mixing the gas with the mixture, and dispensing the mixture as the foamed material. The gas is entrained in the mixture and, when dispensed, expands to form the foamed material. The purely mechanical approach for foaming the catalyst-containing component and the crosslinker-containing component by introducing a gas overcomes various disadvantages of conventional approaches that rely on a chemical reaction to form the entrained gas. Generally, foamed multi-component materials may, for example, be desirable in aircraft manufacturing as their use as a replacement for identical non-foamed materials reduces the weight of material used for bonding aircraft components.
In another embodiment, an apparatus is provided for producing a foamed material from first and second fluid components and a gas. The apparatus includes a mixing device having a mixing chamber, a first inlet communicating with the mixing chamber, a second inlet communicating with the mixing chamber, a gas port communicating with the mixing chamber, and a mixing element inside the mixing chamber. The first and second inlets are configured for respectively admitting the first and second fluid components into the mixing chamber. The apparatus further includes a gas flow control valve coupled to the gas port and configured for introducing the gas through the gas port into the mixing chamber. The mixing element is configured to mix the first and second fluid components with the gas inside the mixing chamber to form a mixture that, when dispensed, produces the foamed material. The mixing device mechanically mixes the gas with the first and second fluid components, which eliminates the need to rely on a chemical reaction to provide the entrained gas.
In yet another embodiment, an apparatus is provided for producing a foamed material from first and second fluid components and a gas. The apparatus includes a first mixing device having a first mixing chamber and a first mixing element inside the first mixing chamber. The first mixing element is configured to mix the first and second fluid components. The apparatus further includes second mixing device having a second mixing chamber coupled in fluid communication with the first mixing device for receiving the first and second fluid components from the first mixing device, a second mixing element inside the second mixing chamber, and a port configured to provide access into the mixing chamber. A gas flow control valve is coupled with the port and is configured for introducing the gas into the first and second fluid components in the second mixing chamber. The second mixing element is configured to mix the first and second fluid components with the gas inside the second mixing chamber to form a mixture that, when dispensed, produces the foamed material.
With reference to
As used herein, the first fluid component is referred to as a catalyst-containing component and the second fluid component is referred to as the crosslinker-containing component. With regard to the catalyst-containing component, it is understood that the component may contain an accelerator, an initiator, or another reactive species instead or, or in addition to, a catalyst. The isolation of the catalyst in the catalyst-containing component from the crosslinker in the crosslinker-containing component prevents curing.
The first and second fluid components are stored in isolation from each other to preclude chemical reaction leading to crosslinking and are only combined shortly before the time of use. When combined together, a chemical reaction initiates and curing occurs to form a cured product. Specifically, the crosslinker in the crosslinker-containing component reacts with the catalyst in the catalyst-containing component to form a polymer network via one or more of numerous reactions depending on the specific catalyst and reactant structure. However, the combination of the catalyst-containing component with the crosslinker-containing component either does not result in a chemical reaction that produces gas or chemically reacts to produce only a negligible amount of gas that is insufficient in and of itself to result in a measurable change in the dispensed weight.
The dispensing system 10 of the representative embodiment includes a first mixing device in the form of a static mixer 24 that is operatively coupled to first and second feeding devices 30, 32. For example, the feeding devices 30, 32 may include respective conduits or lines 30a, 32a and respective pumps 30b, 32b that withdraw amounts of the first and second fluid components from respective supplies 13, 15 and direct the withdrawn the respective first and second fluid components through the lines 30a, 32a, through the static mixer 24. The pressurization supplied by the pumps 30b, 32b forces the mixture of the first and second fluid components from the static mixer 24 toward a second mixing device in the form of a dynamic mixer 40. Specifically, the feeding devices 30, 32 respectively feed the first and second fluid components from the respective supplies 13, 15 into a mixing chamber 37 of the static mixer 24 through respective ports 13a, 15a of the static mixer 24.
In the representative embodiment, a control system 42 regulates the rate and/or amounts of the first and second fluid components that are fed through feeding devices 30, 32 and may include, without limitation, master and slave components 42a, 42b that cooperate in this regard to maintain an appropriate mixture. Check valves 43a, 43b are respectively disposed in lines 30a, 32a to selectively permit or restrict flow of the first and second fluid components into the static mixer 24.
The static mixer 24 includes a mixing element 35, which is located inside the mixing chamber 37, that is operative to mix the first and second fluid components with one another to form a mixture. Conventional static mixers, which have no moving parts, are devices having a series of internal baffles or elements, such as a series of alternating right- and left-hand helical elements oriented at right angles to one another. Representative static mixers are disclosed in commonly-assigned U.S. Pat. No. 5,480,589, the disclosure of which is incorporated by reference herein in its entirety. For example, and without limitation, the dynamic mixer 40 may be of a type commercially known under the name Ultra FoamMix and available from Nordson Corporation of Westlake, Ohio. The mixing chamber 37 of the static mixer 24 is connected through a line 46 with an inlet 35a of a mixing chamber 40a of the dynamic mixer 40. The mixture is routed from the mixing chamber 37 of the static mixer 24 to the mixing chamber 40a of the dynamic mixer 40.
A pressurized gas, such as nitrogen, dry air, or an inert gas, is fed from a supply 48 into the mixing chamber 40a through a gas infeed device 50. The gas from the supply 48 is supplied into the mixing chamber 40a of the dynamic mixer 40 through a port 40b, which provides fluid access into the mixing chamber 40a. The flow of the gas through port 40b into the mixing chamber 40a of the dynamic mixer 40 may be regulated by a gas flow control valve 49 of the gas infeed device 50. Typically, the pressure of the gas being introduced into the mixing chamber 40a is maintained higher than the fluid pressure of the mixture inside the mixing chamber 40a so that the gas flows into the mixing chamber 40a. Generally, the specific gas pressure will depend on the viscosity and flow rate of the mixture. As used herein, the process of mechanically injecting the gas into the mixture refers to the use of a mechanism to inject the gas into the mixture, in contrast to a chemical process that generates the gas from a chemical reaction.
The dynamic mixer 40 includes a mixing element 51 inside the mixing chamber 40a that combines the gas with the first and second fluid components of the multiple-component material. Representative dynamic mixers are disclosed in commonly-assigned U.S. Pat. No. 4,778,631, the disclosure of which is incorporated by reference herein in its entirety. As used herein, the process of mechanically mixing the gas with the mixture refers to the use of a either a static or moving mixing element to accomplish the requisite mixing to form a mixture that can be ultimately dispensed as a foamed material.
The material mixture containing the entrained gas exits an outlet of the dynamic mixer 40 through an outlet line 54 and is directed to a dispensing device 60. The dispensing device 60 dispenses the foamed material 11 directly onto an application target, such as a substrate or another structural component (not shown). For example, the foamed material 11 may be applied to a first structural component of an aircraft and used to bond the first component with a second structural component of the aircraft. As specific examples, the foamed material 11 may be used as a fuel tank sealant, a windshield sealant, a firewall sealant, an electric potting compound, a conductive sealant, or as an aerodynamic and corrosion inhibitive sealant.
Dispensing device 60 is configured in a manner understood by a person having ordinary skill in the art to dispense the foamed material in discrete volumes, such as beads or dots, to provide an interrupted, non-continuous pattern on a moving substrate, or to dispense the foamed material as continuous beads or stripes. The dispensing device 60 may comprise a gun, a module, a hand gun, etc. For example, and without limitation, dispensing device 60 may take the form of a dispensing gun known under model AG900, which is available from the Nordson Corporation of Westlake, Ohio. In one specific embodiment, the dispensing device 60 may be any conventional hot melt dispenser, including but not limited to needle valve-type dispensers, capable of selectively actuating a needle tip relative to a sealing seat for intermittently discharging amounts of the mixture the multi-component material and entrained gas from a discharge orifice and providing a positive flow cutoff. The dispensing device 60 may be pneumatically actuated by the operation of a solenoid valve that supplies air pressure to an air cylinder for moving the valve stem away from the sealing seat, thereby allowing the mixture the multi-component material and entrained gas to flow to the discharge orifice. Alternatively, the dispensing device 60 may be electrically operated and include a coil that generates an electromagnetic field for moving an armature relative to a stationary pole, in which the stem is physically coupled with the armature for moving the valve stem relative to the sealing seat. The discharge orifice of the dispensing device 60 may be defined in a nozzle that may be readily removed and exchanged with other similar nozzles for varying the configuration of discharge orifice to dispense amounts, streams, dots or beads of the multi-component material and entrained gas characterized by a different size and/or a different shape for the foamed material 11 on the substrate. The dispensing device 60 may also include a trigger that is manually actuated to initiate dispensing.
A foam control system 58 controls the operation of the dynamic mixer 40 and may control, for example and without limitation, the flow of gas from supply 48 into the dynamic mixer 40 via the gas flow control valve 49 and/or the flow of the material out of the dynamic mixer 40. The foam control system 58 is electrically coupled with the gas flow control valve 49 for this purpose.
When the mixture of multi-component material and entrained gas is dispensed from the dispensing device 60, the discrete volumes of gas rapidly expand and are trapped, following expansion, within the volume of the multi-component material to generate the foamed material 11. The trapped closed cells comprise small bubbles of gas distributed throughout the bulk of the foamed material 11 and provide a structure of closed cells in the cured material. The bubble distribution may be homogeneous or inhomogeneous depending upon, among other variables, the type of base resin, the desired density reduction, the residence time in the mixing chamber 40a of dynamic mixer 40, and the flow rate of the mixture of the first and second fluid components. The gas bubbles displace a percentage of the multi-component material to define cells and yield a weight reduction of the cured product, as well as to alter/improve the mechanical properties of the cured product.
In an alternative embodiment, the dispensing device 60 may dispense the foamed material 11 into a temporary holding container, such as a cartridge 62, for storage and subsequent dispensing. The foamed material 11 dispensed into the cartridge 62 may be frozen (as schematically illustrated by box 64) to permit storage in the cartridge 62 and subsequently heated to thaw the frozen foamed material to a dispensable condition and permit dispensing of the foamed material 11 from the cartridge 62. The curing of the material is suspended at the temperatures characteristic of the frozen condition. While frozen, the gas may be retained within the mixture of the first and second fluid components such that the foamed condition is maintained during storage and survives until the material is unfrozen and dispensed.
After or during use, it may be necessary to clean one or more of the components of system 10. System 10 may be cleaned using a schematically illustrated flushing system 70, which may be coupled to one or more of the components of system 10. In particular, flushing system 70 may dispense a cleaning agent such as a solvent 72 having a suitably chosen density to facilitate purging of residual portions of the first and second fluid components through and out of system 10. While the exemplary embodiment of
The mix control system 42 and the foam control system 58 may each have a processor (not shown), which may be any suitable conventional microprocessor, microcontroller or digital signal processor, configured to execute software that implements control algorithms to permit the operation. The control systems 42, 58 may also have a memory (not shown) used to store programmed instructions for the processor, as well as user input/output devices. The control systems 42, 58 may be integrated into a single control system.
With reference to
With continued reference to
The first module 122 is fluidly coupled to the supply 13 of the first component through an elbow fitting 141. Elbow fitting 141 may be of a quick-release type to facilitate coupling with the supply 13 of the first fluid component or it may alternatively be of any other type such as one including a threaded coupling. Air fittings 142a, 142b fluidly couple the first module 122 with a source of process air to pressurize the interior of the first module 122 and thereby facilitate supplying the first component to the mixing module 126. The second module 124 similarly includes an elbow fitting 143 and air fittings 144a, 144b respectively similar in structure and/or function to the elbow fitting 141 and air fittings 142a, 142b associated with the first module 122. Second module 124 is fluidly coupled to the supply 15 of the second fluid component.
With specific reference to
A mixing element 166 extends within the mixing chamber 160 and rotates to mix the first and second fluid components and the pressurized gas with one another to thereby form the gas-entrained multiple-component material. To this end, the mixing element 166 includes a central shaft 168 coupled for rotation to a motor (not shown) and a generally cylindrical body 170 attached to the shaft 168. The cylindrical body 170 includes fins 174 that are helically arranged such that, during continuous rotation of the mixing element 166, the fins 174 tend to force the components 13, 15 toward the inlet ports 152a, 154a, thereby retarding the flow of the gas-entrained material toward an outlet port (not shown) coupled to the dispenser 135. The fluid components flowing through the mixing chamber 160 and the incoming pressurized gas are therefore repeatedly divided by the fins 174 into minor streams and then recombined, thus creating a substantially homogeneous blend or mixture in the mixing chamber 160.
The inlet ports 152a, 154a intersect the mixing chamber 160 near the upstream end of the mixing element 166. In one embodiment, the inlet port 152a is used to introduce the first fluid component and is located upstream of the inlet port 154a used to introduce the second fluid component. This provides a purging or flushing action of the second fluid component through the mixing chamber 160.
As discussed above, the gas injection module 132 injects the pressurized gas through a gas port 175 into the mixing chamber 160. The gas is mixed or blended with the first and second fluid components in the mixing chamber 160. In this regard, and with reference to
With continued reference to
The plunger 202 is movable relative to the seat 204 to provide the first condition when a fluid pressure between the plunger 202 and the inlet 188 exceeds a sum of the biasing force provided by the spring 206 and a fluid pressure between the plunger 202 and the outlet 190. The plunger 202 is further movable to provide the second condition described above when the fluid pressure between the plunger 202 and the outlet 190 exceeds the sum of the biasing force provided by the spring 206 and the fluid pressure between the plunger 202 and the inlet 188.
With continued reference to
Other structural and functional details of the exemplary gas injection module 132a and mixing module 126 are disclosed in commonly-assigned U.S. patent application Ser. No. 11/939,150, filed Sep. 17, 2008, and the disclosure of which is hereby incorporated by reference herein in its entirety. The systems and methods of the various embodiments may use the foamed material, for example foamed polysulfide, to produce sheets, blocks and molded parts, which may be of particular benefit in aircraft manufacturing.
While the invention has been illustrated by a description of various embodiments and while these embodiments have been described in considerable detail, it is not the intention of the applicants to restrict or in any way limit the scope of the appended claims to such detail. Additional advantages and modifications will readily appear to those skilled in the art. Thus, the invention in its broader aspects is therefore not limited to the specific details, and representative apparatus and method shown and described. Accordingly, departures may be made from such details without departing from the spirit or scope of applicants' general inventive concept.
This application claims the benefit of U.S. Provisional Application No. 61/038,873, filed Mar. 24, 2008, the disclosure of which is hereby incorporated by reference herein in its entirety.
Number | Date | Country | |
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61038873 | Mar 2008 | US |