Patent Grant
9457294
This invention generally relates to an apparatus and process for contacting and separating liquids.
Generally, liquid extraction and reaction processes have been widely employed using liquid-liquid mixing in refining and chemical technologies. Such mixing technologies can be utilized for the desulfurization of liquid hydrocarbons, hydrogen fluoride alkylation for producing gasoline blends, and any other suitable process requiring the blending of liquids. Often, the mixing of two immiscible liquids may facilitate a chemical reaction, or extract a substance, such as sulfur, from one liquid phase into the other. Typically, intimate mixing and contacting between immiscible phases followed by an efficient liquid-liquid phase separation is desired for accomplishing the desired reaction and/or separation.
Usually, the liquid-liquid extractors may only perform the extraction function. As an example, static mixers may provide efficient mixing, but often a settling vessel is required downstream in the mixture to separate the two liquid phases. Mixing in a stirred tank can also be very efficient, but the impeller action may result in emulsification slowing separation of the two liquids afterwards. A further mechanism for extraction can be packed bed columns. Another alternative is a vertical tray column used for liquid-liquid extraction that can offer suitable efficiency due to minimum back mixing. However, sufficient space between each tray is typically required for immediate phase separation and to prevent bypassing of a tray by a solvent. Also, the tray column may have limited turndown capability and require some settling volume after the last trays for producing a fine phase separation. Additionally, overflow weirs and downcomers can take up additional space inside the column and reduce the effective tray area. As such, the tray column height can be quite long and diameter is larger than theoretical to accommodate the internals. The height of the column can make it unsuitable for modulation and substantial resources may be required to erect the column in the field and to make the required connections.
As described above, it is desired to find a liquid-liquid mixing and separation apparatus that can be compact and provide robust performance, and a process corresponding thereto.
One exemplary embodiment can be an apparatus for contacting a first liquid and a second liquid. The apparatus can include a vessel. The vessel can include a wall and a funnical frustum. The wall may form a perimeter about an interior space and include a first side and a second side forming a passageway communicating at least one of the first and second liquids to the interior space. The funnical frustum may be positioned proximate to the passageway and abut the wall for facilitating contacting of the first and second liquids.
Another exemplary embodiment may be an apparatus for contacting liquids. The apparatus can include the vessel having a wall forming a perimeter about an interior space therein, a top coupled to the wall, and a bottom coupled to the wall. The wall can form a first side and a second side to provide a passageway for at least one liquid. The first side may form a first vane and a second vane. Generally, the second vane tapers the passageway for forming a slot providing at least one liquid into the vessel.
A further exemplary embodiment can be a process for separating immiscible liquids. The process may include providing at least one of the liquids via a slot of a passageway formed by a first side tapering towards a second side above a funnical frustum to impart a swirling motion at an acceleration of about 1-about 60 g, alternatively about 10-about 60 g, to the at least one liquid exiting the slot.
A liquid-liquid vortex contactor can produce a highly dispersed liquid-liquid mixture in a field of centrifugal forces inside a vortex zone to provide intimate contact between two liquid phases for facilitating a liquid-liquid reaction or extraction. The turbulence in the vortex can result in a very large interfacial area for chemical reaction or mass transfer, typically an attractive characteristic for liquid-liquid extraction. In one exemplary embodiment, an almost 100% of a theoretical extraction may be achieved.
Generally, the operation of a liquid-liquid vortex contactor can be based on the rotation of two liquids. In general, the tangential motion of mode of a first liquid (continuous phase) can be used to swirl and break up a second liquid (dispersed phase). As a consequence, it is possible to approach one theoretical stage in a vortex contactor.
Desirably, the vortex contactor provides sufficient yet not excessive shear to reduce the volume required for subsequent phase separation. The proposed liquid-liquid mixer and contactor design can utilize vortex contacting technology. As such, this suitable design is typically desired to reduce the size and cost of liquid-liquid extractors and/or reactors.
As used herein, the term “stream” can include various hydrocarbon molecules, such as straight-chain, branched, or cyclic alkanes, alkenes, alkadienes, and alkynes, and optionally other substances, such as gases, e.g., hydrogen, or impurities, such as heavy metals, and sulfur and nitrogen compounds. The stream can also include aromatic and non-aromatic hydrocarbons. Moreover, the hydrocarbon molecules may be abbreviated C1, C2, C3 . . . Cn where “n” represents the number of carbon atoms in the one or more hydrocarbon molecules. Furthermore, a superscript “+” or “−” may be used with an abbreviated one or more hydrocarbons notation, e.g., C3+ or C3−, which is inclusive of the abbreviated one or more hydrocarbons. As an example, the abbreviation “C3+” means one or more hydrocarbon molecules of three carbon atoms and/or more. The stream may include substances in addition to or other than one or more hydrocarbons, such as an alkaline, an acid and/or water.
As used herein, the term “zone” can refer to an area including one or more equipment items and/or one or more sub-zones. Equipment items can include one or more reactors or reactor vessels, heaters, exchangers, pipes, pumps, compressors, and controllers. Additionally, an equipment item, such as a reactor, dryer, or vessel, can further include one or more zones or sub-zones.
As used herein, the term “rich” can mean an amount of generally at least about 50%, and preferably about 70%, by mole, of a compound or class of compounds in a stream. If referring to a solute in solution, e.g., one or more thiol compounds in an alkaline solution, the term “rich” may be referenced to the equilibrium concentration of the solute. As an example, about 5%, by mole, of a solute in a solvent may be considered rich if the concentration of solute at equilibrium is 10%, by mole.
As used herein, the term “substantially” can mean an amount of generally at least about 80%, preferably about 90%, and optimally about 99%, by mole, of a compound or class of compounds in a stream. If referring to a solute in solution, e.g., one or more thiol compounds in an alkaline solution, the term “substantially” may be referenced to the equilibrium concentration of the solute. As an example, about 8%, by mole, of a solute in a solvent may be considered substantial if the concentration of solute at equilibrium is 10%, by mole.
As used herein, the term “frustum” can mean a solid figure formed when a plane, which is substantially parallel to a base or a top of a cone, a pyramid, and a funnel, sections the shape. With respect to the term “funnical frustum”, the sectioning plane can pass through a conical portion of the funnel and substantially parallel to another plane perpendicular to the mouth of the funnel.
As used herein, the term “coupled” can mean two items, directly or indirectly, joined, fastened, associated, connected, or formed integrally together either by chemical or mechanical means, by processes including stamping, molding, or welding. What is more, two items can be coupled by the use of a third component such as a mechanical fastener, e.g., a screw, a nail, a staple, or a rivet; an adhesive; or a solder.
As described herein, the term “coalescer” can be a device containing at least one of a metal mesh, one or more vanes, one or more glass fibers, sand, and anthracite coal to facilitate separation of immiscible liquids of similar density. These components may be constructed of or coated with materials that exhibit hydrophobic-oleophilic characteristics.
As used herein, the term “g-force” can be abbreviated “g” and mean the angular acceleration imparted to a liquid and can be in units of meter per second squared (abbreviated m/s2). One “g” can equal 9.8 m/s2.
As used herein, the term “kilopascal” may be abbreviated “KPa” and all pressures disclosed herein are absolute.
As used herein, the term “cross-sectional” may refer to a view of only a slice or portion of a component or apparatus without depicting underlying elements.
As used herein, the term “immiscible” can describe substances of the same phase or state of matter that cannot be uniformly mixed or blended. As an example, such immiscible mixtures can include liquids such as oil and water, or caustic, such as a water solution of sodium or potassium hydroxide, and hydrocarbon.
Generally, two methods can be used to introduce liquid into a liquid-liquid vortex contactor. In one exemplary case, the two liquids may be mixed upstream introduced simultaneously into the liquid-liquid vortex contactor. Then the mixture can enter the body via a swirler located at the periphery of the liquid-liquid vortex contactor. The swirler can be incorporated into a wall of the vortex contactor or a component consisting of a thin ring with multiple slots and tangential guiding sides or vanes designed to produce a smooth transition from pressure energy to rotational momentum. In the second case, the continuous phase liquid can enter the liquid-liquid vortex contactor through a swirler, as described above. The dispersed phase may be introduced separately inside the liquid-liquid vortex contactor, preferably directed towards a perimeter, such that the dispersed phase can travel by centrifugal forces through the continuous phase.
The apparatus as disclosed herein can facilitate the extraction of a component from two immiscible liquids. Although densities may be similar, one liquid is typically heavier than the other. Usually, the first liquid can be lighter and less dense and the second liquid may be heavier and denser. Often, the first liquid can be at least one hydrocarbon, such as naphtha, hexane, dodecane, and a liquefied petroleum gas; and the second liquid can be water or an acidic or an alkaline solution thereof, such as a sodium and/or potassium hydroxide solution. Generally, the first liquid contains a substance to be extracted and/or reacted, such as one or more sulfur compounds. Extracted substances can include one or more sulfur compounds. Often, the substance is extracted from the hydrocarbon liquid into an alkaline solution. Examples can include contacting a liquefied petroleum gas containing one or more sulfur compounds and a solution of sodium hydroxide, a liquefied petroleum gas containing one or more sulfur compounds and water, or hexane containing one or more sulfur compounds and water.
Also, the apparatus as disclosed herein can be utilized for contacting two immiscible liquids for facilitating reaction, such as alkylation, with an acid catalyst, such as hydrofluoric acid or sulfuric acid. Although two liquids are described as being utilized in the apparatus, it does not exclude the inclusion of a third or additional liquids for facilitating the reactions and/or extractions.
At preferred operating conditions, the mixture of the two liquids can form a highly dispersed liquid-liquid vortex layer. As a consequence, this can ensure the highest mass transfer and/or reaction rates.
The spinning vortex may be conveyed downstream by hydraulics. Although not wanting to be bound by theory, the rotational movement of the mixed fluid is accelerated by means of a frustum, preferably a curved internal structure, which may enable the heavier phase to move rapidly toward the vortex contactor walls. Moreover, the frustum can maintain the stability of the vortex and smoothing of pressure and flow. The curved internal structure may include a frustum, preferably parabolic, that may abut the internal wall and taper the inner radius of the liquid-liquid vortex contactor body.
Referring to
Referring to
Additionally, the vessel 140 can also provide first outlets 304 positioned within the coalescing zone 300 and second outlets 308 positioned in the coalescing zone 300 as well as below the first outlets 304. In other embodiments, the outlets 304 and 308 can be in the vortex zone 180, or one set of outlets 304 or 308 may be in the vortex zone 180 and the other set of outlets 304 or 308 can be in the coalescing zone 300. Although two outlets are depicted for each set, it should be understood that each set, independently, may include only a single outlet 304 or 308.
Referring to the vortex zone 180, the vortex zone 180 can be contained by the at least one wall 200 forming a substantially circular cross-section, as viewed from a top, plan view as in
Turning to
Turning back to
The sprayer 150 can form a first inlet 164 for receiving a first liquid and a second inlet 168 for receiving a second liquid. Both the first inlet 164 and second inlet 168 can communicate with at least one opening 162, which can be a common inlet and communicate with both inlets 164 and 168, formed in the side of the vessel 140. Generally, the sprayer 150 can form a sleeve 160 surrounding a shaft 172. Particularly, the sleeve 160 can form a void 166 in
Referring to
Generally, the at least one opening 162 communicates with the passageway 270 defined by the first side 240 spaced apart from the second side 260. The first side 240 can form vanes, namely a first vane 244 and a second vane 248. The second vane 248 may be at an angle of about 90-about 180° with respect to the first vane 244 and taper the passageway 270 for forming a slot 274 for the exiting liquids. So, the first side 240 can taper the passageway 270 by being angled away from the second side 260 while moving inwardly in the passageway 270. As an aside, each side 240 and 260 can, independently, be considered a vane, as well as the vanes 244 and 248 being components, parts, or sub-vanes of the vane 240. Additionally, the second vane 248 can form another angle of about 10-about 20° with the second side 260. Alternatively, the another angle or slot can be less than about 7° as the diameter of the vessel 140 increases. The tapering of the passageway 270 can facilitate acceleration and impart a circular motion to the first and second liquids. Although the vanes 244 and 248 are depicted as being integrally formed with the at least one wall 200, it should be understood that the vanes 244 and 248 can be separate components coupled or integrally formed together. What is more, the vanes 244 and 248 and the sides 240 and 260 may be a part of the at least one wall 200 or formed into a separate component, such as a swirler as discussed above.
The vanes 244 and 248 may define an obtuse angle with each other. In an aspect, the first vane 244 may diverge away from the second side 260 while moving inwardly in the passageway 270. The second vane 248 may converge toward the second side 260 while moving inwardly in the passageway 270.
In operation and referring to
Afterwards, the liquids may travel through the passageway 270 and exit the slot 274 with an imparted swirling motion. The sides 240 and 260 can provide a smooth transition from pressure to rotational energy and form a vortex layer above the funnical frustum 280 contacting the liquids. The second liquid forming a disperse phase can migrate to the perimeter 212 through the continuous phase of the first liquid. At the perimeter 212, the droplets of the second phase can coalesce creating stratification between the phases. Hence, the bulk of the separation may occur within the vortex zone 180.
Subsequently, the liquids can fall into the coalescing zone 300 where the second liquid can further separate from the first liquid. Coalesced droplets can settle via gravity. The first liquid may rise passing through a coalescer 290, typically a stainless steel mesh, optionally coated, to permit the first liquid to rise into an annulus-shaped chamber 294 within the coalescing zone 300 and exit through the first outlet 304 perhaps after passing though apertures. Alternatively, the annulus-shaped chamber 294 may form multiple orifices. The second liquid can progress to the bottom 190 of the vessel 140 and exit the second outlet 308 perhaps after passing under a suspended edge of an internal wall. The second liquid can be drained via the second outlet 308 to maintain the second liquid at a predetermined level. As an example, a sensor can measure the position of an interface between the first and second liquids, which may send signals to a valve regulating the flow of the second liquid from the second outlet 308. The phase separation in the vortex zone 180 can be controlled by the level of liquid, the pressure drop of the liquids injected, and the pressure at the outlets 304 and 308 to control the amount of phase separation in the vortex zone 180.
Generally, any suitable pressure can be utilized with the swirler formed by the at least one wall 200 to impart a g-force. Such a g-force can be about 1-about 60 g, or greater than about 10 g in the vortex zone 180. Typically, the g-force can vary depending on the location, and may exceed 60 g at other locations, such as the passageway 270. A pressure drop the opening 162 to the slot 274 can be about 5-about 350 KPa, preferably about 5-about 170 KPa. In other suitable embodiments, the g-force can be less than about 1 g.
Referring to
Referring to
Referring to
The first liquid can fall towards the bottom 190 and exit the tube 220 via the first outlet 306. The second liquid may form larger droplets at the perimeter 212 and exit the second outlet 324 formed in the at least one wall 200.
The first liquid can exit as a hydrocarbon product that generally includes about 1-about 10 ppm, preferably no more than about 1 ppm, by weight, of, independently, a cation such as sodium associated with, e.g., an alkaline liquid, and one or more sulfur compounds. However, it should be understood that several vessels can be used in series so the hydrocarbon effluent exiting the last vessel can ensure that no more than about 1 ppm, by weight, of, independently, the cation and one or more sulfur compounds can be present in the hydrocarbon product.
Without further elaboration, it is believed that one skilled in the art can, using the preceding description, utilize the present invention to its fullest extent. The preceding preferred specific embodiments are, therefore, to be construed as merely illustrative, and not limitative of the remainder of the disclosure in any way whatsoever.
In the foregoing, all temperatures are set forth in degrees Celsius and, all parts and percentages are by weight, unless otherwise indicated.
From the foregoing description, one skilled in the art can easily ascertain the essential characteristics of this invention and, without departing from the spirit and scope thereof, can make various changes and modifications of the invention to adapt it to various usages and conditions.
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| Number | Date | Country | |
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| 20140160879 A1 | Jun 2014 | US |
