Multilayer optical coatings typically consist of alternating layers of materials having high and low indices of refraction. In general it is advantageous to form a multilayer coating from high and low index material where the ratio of the high index to the low index is as large as possible. A multilayer coating formed from materials having a larger index ratio may be formed with fewer layers to achieve the same optical performance as a coating formed from materials having a lower index ratio. Additionally, a multilayer coating having superior optical performance can be achieved using an equal, or fewer, number of layers by replacing one high index material with another high index material having a larger index. The economics of an optical coating process will be determined by the number of layers required to provide a desired optical result, the rate at which such layers can be deposited, and the surface area over which those deposition rates can be achieved. Fewer layers, and therefore a thinner coating, will also be beneficial due to such characteristics as lower stress and/or scatter compared to thicker coatings.
Metal oxides have found wide use in optical coating applications because they are durable and generally have good transmission in the visible spectrum. Titanium dioxide (TiO2) has long been recognized as a potentially valuable high index material for optical coating applications because it is durable, visually transparent, and has a higher index than any other suitable metal oxide. However, the use of titanium dioxide has been severely limited due to several manufacturing difficulties. The foremost difficulty results from the fact that titanium dioxide has three naturally occurring crystalline phases: rutile, anatase, and brookite. Under certain conditions it can also be deposited in a non-crystalline, amorphous form. Of these various phases, the rutile phase has the highest, and therefore most desirable, refractive index. Rutile titanium dioxide is birefringent, with an average index of 2.75 at 550 nm and is the most thermodynamically stable phase. A further problem exists in that even when rutile titanium dioxide is deposited, it is often absorbing due to difficulties in oxidizing the film unless the deposition rate is so slow as to be economically impractical.
Although the rutile phase is the most thermodynamically stable, it requires very high energies to form rutile titanium dioxide directly during growth of the thin film. The energy required can be supplied by the deposition process, by heating of the substrate, or both. The phase diagram of deposited titanium dioxide as a function of substrate temperature and deposition process has been published and is shown in
Previous attempts to deposit rutile titanium dioxide have utilized techniques such as heating the substrates to high temperatures, use of ion beam sputtering, or RF sputtering. Heating the substrates to the temperature required to form rutile titanium dioxide is often impractical in manufacturing, and in many cases the heat will physically damage the substrates. RF sputtering and ion beam sputtering allow the formation of films composed substantially of rutile titanium dioxide at temperatures less than 200° C., however, the deposition rate is slow and thus economically impractical and, in the case of ion beam sputtering, the area coated is small and thus economically impractical.
For these reasons use of titanium dioxide in optical coatings has been mostly limited to deposition of the lower index anatase phase and applications where the temperature at which the film must perform is low.
The present invention in one aspect provides for the deposition of thin films of titanium dioxide that are substantially composed of rutile titanium dioxide on one or more substrates at higher rates, lower absorption, and lower temperatures than have been heretofore possible. The coating process and system may provides for the deposition of titanium dioxide in successive monolayers from a target operating primarily in the metallic mode. The term “monolayer” as used herein means a layer of material that is no more than one atom in thickness. Depositing a monolayer does not mean that the entire surface on which the monolayer is deposited are covered by atoms of the deposited material, but only that the material deposited is no more than one atom in thickness. Each newly deposited monolayer is fully oxidized under conditions resulting in the formation of rutile titanium dioxide before the next monolayer is deposited over the previous layer. The deposition process is performed at moderate temperatures and at rates that are significantly faster than those of other coating techniques.
Accordingly, it is an object of the present invention to obviate many of the above problems in the prior art and to provide a novel apparatus and process for high rate deposition of thin films of rutile titanium dioxide. These and many other objects and advantages of the present invention will be readily apparent to one skilled in the art to which the invention pertains from a perusal of the claims, the appended drawings, and the following detailed description of various embodiments.
With reference to the drawings, like numerals represent like components throughout the several drawings.
The present invention is directed to systems and processes for forming thin films of titanium dioxide formed in substantially all rutile phase. In one aspect, the invention is directed to reactive sputter coating systems and processes for forming thin films of rutile titanium dioxide. The system includes a sputtering chamber having one or more coating stations and a means for mounting and moving one or more substrates through the coating stations. The system and process may include a batch coating process wherein the mounting and moving means comprises a rotatable drum, table, disk, or other transporting device of suitable geometry. A reactive coating system and process suitable for forming thin films of rutile titanium dioxide is disclosed in U.S. Pat. No. 5,849,162 to Bartolomei et.al., the content of which is incorporated herein by reference.
The sputtering chamber includes one or more coating stations. At least one sputtering target is positioned in the coating station. In one aspect, the target comprises a magnetron sputtering device. The target is operated at a power sufficient to create a reactive atmosphere in the coating station and to plasma sputter titanium or an oxide of titanium onto the substrates that are moved through the coating station on the mounting and moving means.
A plasma generating device is also positioned in the coating station adjacent the target. In one aspect, the plasma generating device comprises a microwave generator. The plasma generator is operated at a power level for generating a plasma in the coating station that interdiffuses with the plasma generated by the target to increase the area, density, and reactivity of the reactive atmosphere in the coating station.
In one aspect, the present invention provides direct deposition of rutile titanium dioxide films at relatively low substrate temperatures by providing energy to the growing film in several forms. The energy is provided by a combination of the magnetron target plasma and the plasma generated by the plasma generating device. The present invention forms thin films of rutile titanium dioxide films that are essentially stochiometric as formed. This is accomplished by introduction of oxygen into the adjacent plasma, and by relatively rapid translation of the substrates into and out of close proximity to the target surface in the coating station. On each successive pass by the target a monolayer of titanium is deposited and then completely oxidized at energies sufficient to form rutile titanium dioxide. This oxidation of the film is accomplished before the substrate passes by the target once again and acquires a fresh layer of titanium metal.
In one embodiment, the adjacent plasma is of sufficient intensity to provide significant quantities of monatomic oxygen. Exposing the deposited titanium to monatomic oxygen permits the complete oxidation of the titanium being deposited without having to operate the target(s) in a poisoned mode and suffer the resulting large decrease in deposition rate. Previous attempts to deposit titanium dioxide at high rates suffered from this inability to completely oxidize the film, with the result that the deposited films were unacceptably absorbing. Without the adjacent plasma, the oxygen available to react with the freshly deposited titanium metal on the substrate surface is mainly diatomic in nature. To form titanium dioxide by reacting diatomic oxygen and titanium requires a high activation energy. Due to the high activation energy, the titanium is not completely oxidized.
In one aspect of the present invention, the plasma generating device provides a plasma containing monatomic oxygen which reacts much more easily with the titanium metal. Thus it is possible to completely oxidize the film and obviate the disadvantages of forming absorbing films.
The provision of monatomic oxygen to the growing film is important for the rapid and complete oxidation of the titanium atoms on the substrate surface, but it also has another benefit because it provides more energy to the growing film. This increased energy is provided by the heat of reaction of the monatomic oxygen with the titanium atoms, as compared to the lower heat of reaction that would be provided by reaction of the titanium atom with diatomic, molecular oxygen. Reaction of a diatomic oxygen molecule with a titanium atom requires at least formally that the oxygen molecule first be split into monatomic oxygen. This is a highly endothermic reaction, and the necessary energy for splitting the oxygen molecule is subtracted from the energy released by reaction of the oxygen atom and the titanium atom, giving a lower net energy release for the reaction of diatomic oxygen with titanium as compared to the reaction of monatomic oxygen atoms with titanium.
It is often desirable to operate the titanium target(s) in a substantially metallic mode so that material sputtered from the target consists primarily of titanium atoms. The oxygen is introduced into the adjacent plasma to provide activated oxygen species that fully oxidize the deposited titanium atoms. The energy released on oxidation of the titanium atoms contributes to the energy necessary to from the titanium dioxide in the rutile phase. Methods for control of the target oxidation state while maintaining a high sputtering rate are disclosed in U.S. Pat. No. 5,849,162.
In many situations it may be desirable to provide at least one additional coating station equipped with targets that permit sputtering of materials other than titanium. By alternating use of the coating stations, the present invention provides for the formation of multilayer coatings in which at least one of the layers is composed of substantially rutile titanium dioxide. It may also be desirable to provide more than one coating station capable of sputtering titanium in order to increase the overall deposition rate of rutile titanium dioxide on the substrates.
In one aspect of the present invention, balanced magnetrons are operated from an a.c. power supply. The use of an a.c. power supply aids in the formation of rutile titanium dioxide. In an a.c. sputtering system the power switches back and forth between the two targets, with each target alternately acting as the cathode and then the anode in the course of one cycle of power. At the frequencies used, the plasma decays significantly when the power is switched between the two targets (a time on the order of a few tens of microseconds), meaning that the plasma must be restruck over the target that is operating as the cathode. This higher energy needed to restrike the plasma over the target results in a higher electron temperature for the sputtering plasma, resulting in a higher sheath voltage around the substrate as it passes through the plasma. This in turn causes a higher energy ion bombardment of the substrate. This higher energy bombardment facilitates both the oxidation of the titanium atoms deposited on the substrate and the formation of the rutile titanium dioxide.
Other a.c. powered configurations and other power supplies may also be used to provide the higher electron temperature in the plasma to aid the formation of rutile titanium dioxide. Unbalanced a.c. magnetrons, as well as a pulsed d.c. magnetron, also require restriking of the plasma over the target and thus provide the benefit of higher electron temperatures in the plasma. The a.c. configurations also have the advantage that each target functions alternately as the anode and then the cathode so that the targets are kept clean of oxide buildup on their surface and the anode is never lost. In pulsed d.c. systems, only one target is present and it is always the cathode, making it easier for wandering anode problems to occur in the chamber. Other power supplies and target configurations may be used, although with some loss of rate and film quality.
It will often be advantageous, in order to provide coating of many substrates within one operation, to provide a system with relatively long sputtering targets, an elongated plasma generator, and a substrate holder capable of holding a large number of substrates.
It may also be desirable to provide a method for secondary movement of the substrate(s) with respect to the transporting device to improve uniformity of deposition on the substrate(s). For example, the substrate could be rotated about its center point, translated across some aspect of the transporting device, or some combination of these without departing from the current invention. U.S. Pat. No. 6,485,646 discloses a coating system wherein a secondary movement is provided to the substrates to improve uniformity of the coating on the substrates and among an array of substrates.
The present invention provides a system and process for forming thin films of rutile titanium dioxide with low absorption, at high rates, and low temperatures, the combination of which has heretofore been unrealized using reactive sputtering systems. Unlike ion beam sputtering, this process can be carried out on a relatively large throughput of substrates. The combination of high deposition rates and multiple substrates makes the current invention of great economic advantage in the manufacture of articles with rutile titanium dioxide coatings, such as multilayer optical coatings. It also makes titanium dioxide a usable coating material in applications where it would previously have not been feasible.
Oxygen is inlet into the chamber at the same port as the plasma generating devices 110, 112. This configuration may also provide for the secondary rotation of the substrates, which rotation rate is independent of the drum rotation rate.
A coating system configured as shown in
While preferred embodiments of the present invention have been described, it is to be understood that the embodiments described are illustrative only and that the scope of the invention is to be defined solely by the appended claims when accorded a full range of equivalence, many variations and modifications naturally occurring to those of skill in the art from a perusal hereof.
The present application claims the benefit of the filing date of U.S. Patent Application No. 60/508,871 filed Oct. 7, 2003, U.S. Patent Application No. 60/508,877 filed Oct. 7, 2003, and U.S. Patent Application No. 60/512,002 filed Oct. 17, 2003. Each of the above-identified applications is incorporated herein by reference.
Number | Date | Country | |
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60508871 | Oct 2003 | US | |
60508877 | Oct 2003 | US | |
60512002 | Oct 2003 | US |