1. Technical Field
The subject matter of this disclosure relates to energy conversion and, in particular, to embodiments of an apparatus that convert thermal energy to electrical signals.
2. Description of Related Art
Thermophotovoltaic (TPV) devices convert thermal energy to electric power in accordance with the principles of operation common to solar cells. In particular, an emitter (or “radiator”) emits energy in response to thermal energy that heats the emitter. The thermal energy can arise from a direct source (e.g., through combustion, solar, atomic decay, etc.) or from an indirect source (e.g., industrial waste heat processes). In each case, thermal energy impinges on photoelectric conversion elements, e.g., TPV cells, which convert the energy into electric signals.
Elements of TPV devices include an absorber/emitter material, an energy filtering media, TPV cells for energy conversion, and a cooling mechanism. To successfully commercialize TPV devices (and systems incorporating TPV devices), proposed designs utilize cost-effective TPV cells that can convert as much of the energy the emitter radiates into electrical signals. Energy emitted at less than the TPV cell semiconductor bandgap cannot be converted to electrical energy. This unused energy is often parasitically absorbed by the TPV device as heat, which decreases efficiency of the TPV cell and, ultimately, reduce cost-effective operation.
The present disclosure describes embodiments of an apparatus that can convert energy across a broad spectrum of wavelengths. These embodiments utilize concentrating optics in combination with one or more of an integrated filter, a cooling mechanism, and a high-efficiency low current cell architecture to form efficient and cost-effective TPV devices. These components reduce the ratio of cell area to emitter area by concentrating the energy the emitter emit, thereby reducing the total cost of materials and promoting efficiency through integrating the filter and cooling mechanism into the device design.
During operation, embodiments of the proposed apparatus concentrate a large area of energy onto a small TPV cell area via unique construction that enables cost-effective application of the concentrating thermophotovoltaic cells. These embodiments can deploy in high-temperature environments (e.g., a fire, a boiler, an oven, a turbine, a generator, etc.). To harness energy, one or more embodiments can utilize an outer housing made of an absorber/emitter material (AEM), which can be contoured to various shapes, sizes, and form factors (e.g., an elongated, rod design) to fit the environment and/or contour and configuration of the thermal energy source.
Reference is now made briefly to the accompanying drawings in which:
Where applicable like reference characters designate identical or corresponding components and units throughout the several views, which are not to scale unless otherwise indicated.
Embodiments of the apparatus 100 can harness waste energy, e.g., in the form of heat that results from combustion of fuel. These embodiments find use in various applications, e.g., boilers, furnaces, ovens, and other applications where elevated temperatures prevail and/or where thermal energy is abundant. For example, the apparatus 100 can survive fluids (e.g., gas) at temperatures in excess of 500° C., which may exhaust from a combustion chamber that burns fuel (e.g., wood, coal, natural gas, etc). These heated fluids heat the emitter element 102, which in turn generates electromagnetic radiation that the energy conversion device 104 converts to electrical signals.
Designs for the apparatus 100 utilize components that comport with the environment and/or application in which the apparatus 100 is found. These designs leverage features and aspects of one or more of the elements (e.g., emitter element 102, energy conversion element 104, condenser element 106, and cooling element 108) to convert the thermal energy in the heated fluid to electrical signals. As set forth more below, this disclosure describes features of the apparatus 100 in terms of form factors that may coincide with one or more particular applications. For the combustion applications discussed above, the form factor may conform to the shape of the combustion chamber and/or to the size (e.g., diameter) of pipes, tubes, and conduits that receive exhaust gases from the combustion chamber. However, while indicative of one or more embodiments of the apparatus 100, these form factors can vary in respect to any number of features to attain an output (e.g., electrical signals) that satisfies potential design criteria and/or output thresholds. Such design criteria may require, for example, electrical signals that exhibit certain current levels to re-charge a battery and/or to operate a specified device (e.g., a radio).
The emitter element 102 withstands conditions (e.g., temperature, pressure, humidity, etc.) consistent with the designated application. The emitter element 102 also maximizes the spectrum of electromagnetic radiation generated in response to the thermal energy the emitter element 102 absorbs. Examples of the emitter element 102 act as grey-body and/or black-body emitters, comprising one or more materials that absorb thermal energy and emit electromagnetic radiation. These materials allow implementation of the emitters at temperatures of at least 500° C. or more and, in one particular implementation, at around 1200° C. Emitters of this type can generate electromagnetic radiation having wavelengths, for example, of 900 nm and greater. In one example, the emitter element 102 comprises one or more types of metals (e.g., tungsten, steel, tantalum, etc.), ceramics (e.g., aluminum oxide, silicon carbide, etc.), and composites, as well as compositions, derivations, and combinations thereof. The emitter element 102 may further utilize coatings, paints, and like surface treatments (e.g. erbium oxide, yttrium oxide, silicon carbide) that may improve absorption of heat and/or optimize properties of the emitter element 102 for radiating and dispersing the electromagnetic radiation. In one example, the selection of materials and construction for the emitter element 102 tune the electromagnetic radiation that emanates from the emitter element 102. Such construction may incorporate materials (e.g., tungsten photonic crystals (PhC)) throughout the emitter element 102 to tailor the electromagnetic radiation, e.g., with a cut-off wavelength of 2.3 μm.
Examples of the energy conversion device 104 include integrated circuit and semiconductor devices with structure that generate electricity from electromagnetic radiation. Such devices include thermophotovoltaic cells and/or combination of discrete photovoltaic elements (e.g, diodes) and photovoltaic materials to generate electricity from electromagnetic radiation. These types of devices can comprise a substrate and various layers of materials, the combination of which may cause the device to operate for the purposes herein. This layered structure operates (e.g., to generate electrical signals) in response to electromagnetic radiation over a wide spectrum of wavelengths that are consistent with black-body and grey-body emitter, as discussed above and further below.
Construction of the apparatus 100 positions the concentrator element 106 to receive electromagnetic energy that radiates from the emitter element 102. The construction also directs the electromagnetic energy towards, and in one example, onto the energy conversion device 104. Effective configurations for the concentrator element 106 gather and/or collect the electromagnetic radiation from a large area (e.g., proximate the emitter element 102) and direct the radiation onto a smaller area (e.g., onto the surface of the energy conversion device 102). The ratio of the large area to the smaller area can define a concentration factor for the concentrator element 106. In exemplary devices for use as the concentrator element 106, the concentration factor can be about 2 or greater and, in one example, in a range from about 2 to about 5.
The concentrator element 106 exhibits properties that concentrate the electromagnetic radiation from the emitter element 102, e.g., onto the surface of the energy conversion device 104. These properties can include optical properties and reflective properties, both of which can change the direction and/or focus of the electromagnetic radiation that passes through the concentrator element 106. For optical properties, the concentrator element 106 can form optical components (e.g., lenses) that comprise materials that can transmit electromagnetic radiation of wavelengths contemplated herein. These optical components can have various shapes (e.g., concave, convex, oblate, spheroid, etc.) to match operation of apparatus 100 and/or the constituent components. In one example, the optical components comprise magnesium fluoride, fused quartz, fused silica, and like materials, derivations, combinations, and compositions thereof. For reflective properties, the concentrator element 106 can embody structures with an input opening and an output opening that has an output area that is smaller than an input area of the input opening. The structures can further incorporate wall members with reflective materials and/or coatings to direct the electromagnetic radiation from the input opening to the output opening and, ultimately, onto the surface of the energy conversion device 104. For example, the concentrator element 106 may comprise metals of various types, which form reflective surfaces.
Examples of the filter element 110 form a barrier that allows electromagnetic radiation of a first wavelength (and/or a first range of wavelengths) to pass and that does not allow other electromagnetic radiation of a second wavelength (and/or a second range of wavelengths) to reach the energy conversion device 104. This barrier helps minimize the operating temperature of the apparatus 100 and, in particular, the operating temperature of the energy conversion device 104. Construction of the barrier can be tuned to pass only electromagnetic radiation of wavelengths that will stimulate the energy conversion device 104 to generate electrical signals. In one example, the barrier can reflect other electromagnetic radiation away from the energy conversion device 104. The reflected electromagnetic radiation may be of wavelengths that the energy conversion device 104 can not convert to electrical signals. Exemplary devices for the filter element 110 can embody a plasma filter or like components, that reflects electromagnetic radiation in a direction, e.g., back toward the emitter element 102. Suitable materials for use in the filter element 110 comprise transparent material (e.g. sapphire, fused silica, and magnesium fluoride) with properties that transmit electromagnetic radiation of wavelengths emitted by the emitter element of 102. Such materials may be arranged in one or more layers that reflect radiation of certain wavelengths and allows radiation of certain wavelengths to pass to the energy conversion device 104. For example, the plasma filter may reflect electromagnetic radiation with wavelengths of 1.8 microns to about 10 microns, of 2.3 microns or greater, and/or at least about 1.8 microns or greater.
The cooling element 108 can reduce and maintain the operating temperature of the energy conversion device 104 at levels that permit operation, e.g., at or below about 100° C. In one embodiment, the cooling element 108 is in thermal contact with the energy conversion device 100 to promote the most direct path for heat to dissipate. Examples of the heat transfer medium include water, ethylene glycol, as well as like refrigerants and materials. These materials can circulate through the cooling element 108. For active circulation, the apparatus 100 may couple with a flow generator (e.g., a pump) or other device that can pressurize the material to cause the exchange of material through the cooling element 108. In some applications, the cooling element 108 may employ passive circulation, e.g., when the cooling element 108 incorporates a heat pipe with multiple chambers and integrated construction that can help to rapidly dissipate heat away from the energy conversion device 104.
The apparatus 200 may be constructed as a monolithic device, wherein the emitter body 212 and the end cap 226 are formed as a single unitary structure. Such construction may leave the second end 216 open to allow for assembly and installation of components therein. A cover can be placed over the open second end 216 to secure and seal the apparatus 200. In other examples, the apparatus 200 may be assembled from various pieces that fasten together using adhesives, welds, fasteners (e.g., screws and bolts), and like techniques.
The support elements 220 can form fins having an aerodynamic shape (e.g., an airfoil). The fins can form integrally with the emitter body 212 or, in other constructions, the fins can fasten to the outer surface of the emitter body 212 using known fastening techniques. In one embodiment, the fins are sized and configured to fit within the pipe 224. The fit can be loose, i.e., wherein the fins limit movement of the apparatus 200 but the fins do not offer resistance against the inner surface 222 to allow the apparatus 200 to slide through the pipe 224. In other embodiments, the fins can engage the inner surface 222, e.g., via a surface that causes friction and/or exerts a force (e.g., a spring force) against the inner surface 222. Examples of the fins limit conduction, e.g., via embodiments wherein the shape is minimized to limit conduction from the emitter body 212 to the pipe 224.
The emitter body 212 is amenable to various form factors (e.g., shapes and sizes) as might be dictated by the application (e.g., the size and shape of the pipe 224). Examples of the form factor include the elongated cylindrical structure that is shown in
External connections 228, 230 allow ingress and egress of cooling fluid (e.g., via cooling connection 228) and electrical signals (e.g., via power connection 230). Examples of the cooling connection 228 can include tubes and conduits that mate with one or more corresponding fittings on the apparatus 200. Examples of the fittings include threaded connectors as well as threaded features (e.g., bores) to receive connectors therein. In the same respect, the power connection 230 can comprise electrical cables (e.g., coaxial cables, multi-wire cables, copper cables, etc.) with one or more electrical connections that couple with an electrical connection on the apparatus 200. For purposes of example, in one implementation the cables can couple with a load (e.g., a motor) and/or a storage unit (e.g., a battery) that the apparatus 200 is to supply with electrical signals. Collectively, the external connections 228, 230 can form a single cable and/or conduit, which can function as one or more of the external connections 228, 230.
As best shown in
In one embodiment, the emitter body 212 forms a housing to surround, protect, and maintain the components disposed therein. The housing is resistant to high temperatures (e.g., in excess of 500° C.). As set forth above, the housing absorbs heat and/or thermal energy on the outer surface 232, transmits the energy towards the inner surface 234, and disperses the energy as electromagnetic radiation that radiates into the interior volume 236. In other embodiments, construction of the apparatus 200 forms a hermetically-sealed chamber and/or maintains the interior volume 236 at a desired pressure. In one example, the hermetically-sealed chamber is evacuated, e.g., to form a vacuum. The vacuum helps limit interference, often by air or moisture, of electromagnetic radiation in the desired geometric direction. This configuration may improve output, e.g., by reducing energy loss due to conduction or convection. The hermetically-sealed chamber can also can retain various fluids including liquids and gases (e.g., nitrogen, hydrogen, and helium) that afford a desirable environment for energy conversion to occur. Construction of the emitter body 212 can further entail the use of multiple pieces and/or laminated layers of material. For example, this disclosure contemplates structures for the emitter body 212 in which a first inner surface 234 is part of a first material layer and the outer surface 232 is part of a second material layer disposed on the first materials layer.
Examples of the tubular structure 248 may contain a fixed amount of the cooling fluid 252. This fixed amount may not circulate out of the apparatus 200. However, in other examples, the cooling fluid 252 can circulate through the tubular structure 248, e.g., under pressure from a cooling fluid supply that is external to the apparatus 200.
Examples of the material ring 246 can form a cylinder that extends at least partially along the longitudinal axis 218. The cylinder permits electromagnetic energy to pass to the concentrator features 240, but may limit transfer of thermal energy, e.g., via conduction and convention between the emitter body 212 and the concentrator features 240 (and other elements and components of the apparatus 200). In one embodiment, the material ring 246 secures directly, by coating or other means, to the inner surface 234. In other examples, the material ring 246 can be supported at various positions by supports that couple the material ring 246 with the cooling element 210 and/or provide mechanical fastening with the emitter body 212. As set forth in more detail below, the material ring 246 can be disposed onto the surface of the cells 238 using known deposition techniques.
While various processes are contemplated, in one example, the material ring 246 can be constructed using various techniques, including via epitaxial lift-off, and incorporated into the apparatus 200. The material ring 246 can be positioned between the emitter body 212 and the concentrator feature 240 and/or disposed on the cells 238. For purposes of positions on the cells 238, the material ring 248 can be grown and/or deposited thereon directly. In one example, bonding material (e.g., a low absorbing yet highly thermally conductive interface material) might be used to secure the material ring 246 to the concentrator features 240 and the cells 238. In one embodiment, the filter component comprises a layer of InPAs nominally doped to 5E19. The InPAs layer can be grown by MOCVD on an InP substrate.
The material ring 246 may help concentrate the electromagnetic radiation onto the cells 238. For example, the material ring 246 may incorporate geometric shapes (e.g. concave lenses, convex lenses, linear lenses, etc.) that reflect and/or transmit electromagnetic radiation to the concentrator features 240. Such enhancements may reduce the size and shapes of certain components (e.g., the concentrator element 206), thus resulting in lower costs and reducing absorption of electromagnetic radiation that may increase thermal loading of the concentrator component 206. It may be desirable to maintain the components (e.g., the concentrator component 112) inside the housing at lower temperatures (e.g., at or below 100° C.). This feature can be accomplished by limiting the absorption of radiation by the filter component and, where applicable, by any bonding material that secures the filter component to portions of the apparatus 100 such as to the intermediary member 110.
The panels of the apparatus 300 may be affixed together into a single device, e.g., using clamps, frames, and similar fixtures. The types of fixtures may secure to the periphery of the panels, as desired. In other constructions, the individuals panels may be flexible, e.g., if constructed using materials that exhibit physical properties consistent with resilient and/or pliable materials. Embodiments of the apparatus that are constructed in this manner may conform to surfaces that are in and/or susceptible to thermal energy on the order disclosed above. These embodiments may comprise an adhesive or other bonding agent and/or material layer that can withstand the temperatures. Such materials may simplify implementation by providing a simple way to position and secure (e.g., adhere) the apparatus 200 into position.
Examples of the array 400 can be constructed using traditional semiconductor high-volume assembly technologies. The lead frame 402 can comprise various materials (e.g., metals, ceramics, etc.), which can receive solder, adhesive, and like bonding agents to mechanically secure and interconnect the cells 238 with the lead frame 402 and to one another, e.g., in series. Construction of the array 400 may incorporate one or more carriers comprising, for example, ceramics (e.g., ALN-DBC) onto which the cells 238 mount. The cell areas 402 can be sized to receive the carriers, which may be larger in size as compared to the cells 238. Exemplary construction may require the cells 238 to be soldered to the carriers, which mount to the lead frame 402. Interconnecting leads (e.g., wirebonds) can be added that extend from a first end that couples with interconnects on the cells 238 to a second end that couples with corresponding pads and interconnects on the lead frame 402. In this configuration, the interconnecting leads conduct electrical signals from the cells 238 to the interconnect 406, which can then conduct the electrical signals to the terminal end 408.
At the terminal end 408, embodiments of the array 400 may be outfit with terminals and/or other connective elements that electrically connect the leads (and/or the cells 116) to the exterior of the apparatus. This configuration will permit the electrical signals to couple, e.g., with a load, a plug, an extension cord, and the like. The leads may be electrically isolated from the components of the apparatus including the heat transfer mechanism 108. In one embodiment, the connector 410 may further comprise interface circuitry that can accept a plug or can otherwise permit a peripheral device to be coupled with the array 400.
It may also be desirable to maintain a low level of current in the cells 700, while still enabling the cell 70 to convert radiation energy to electrical energy at a high conversion efficiency (e.g., of about 30% or more and, in one example, between about 15% and about 50%). The level of current can be reduced by interconnecting PN junctions on the cell 700 and, more particularly, by connection of the PN junctions in series. In one embodiment, this feature can be achieved by dividing the area of the cell 700 into smaller cell areas and using metallic interconnections to connect adjacent, smaller cells. In another example, as shown in
In one example, the first junction 706 and the second junction 708 can generate electrical signals in response to, respectively, a first wavelength range and a second wavelength range. The first wavelength range and the second wavelength range can include one or more wavelengths not found in the other. For example, the first wavelength range may include wavelengths from about 900 μm to about 1.6 μm and the second wavelength range may include wavelength from about 1.6 μm to about 2 μm. The extend of the ranges can also be clarified in terms of bandgap, e.g., where the ranges cover 0.52 eV, 0.64 eV, and 0.74 eV.
In the example of
The concentrator feature 900 can be made, e.g., of metal, that is formed in the various shapes, and generally reflective and or coated with a reflective coating material at least on the surfaces of the wall members 908 that bound the interior passage 910. The shape of the concentrator feature 900 is selected to direct electromagnetic radiation through the interior passage 910, with the dimensional difference between the first opening 912 and the second opening 914 in the present example useful to collect large amounts of electromagnetic radiation at the top 904 and concentrate the electromagnetic radiation at the bottom 906.
In view of the foregoing, embodiments of the apparatus discussed herein can convert heat and thermal energy to electrical signals, e.g., for re-charging a battery. These embodiments arrange cells (e.g., thermophotovoltaic cells) in combination with concentrator features to provide the cells with electromagnetic radiation in sufficient amounts to generate electrical signals. One or more embodiments can be combined to form a plurality of the apparatus, which can effectively increase output of electrical signals. These systems may be found in various operating environments and used in various applications. These operating environments include one embodiment comprising a singular apparatus in an outdoor fire application, one embodiment comprising a plurality of apparatus aligned linearly within a home or commercial boiler application, one embodiment comprising a circular array of apparatus aligned at an appropriate angle to take advantage of a singular burner as in a cookstove environment, and one embodiment comprising a linear array of apparatus within an industrial heat application such as a smelting furnace, reflow oven.
As used herein, an element or function recited in the singular and proceeded with the word “a” or “an” should be understood as not excluding plural said elements or functions, unless such exclusion is explicitly recited. Furthermore, references to “one embodiment” of the claimed invention should not be interpreted as excluding the existence of additional embodiments that also incorporate the recited features.
This written description uses examples to disclose embodiments of the invention, including the best mode, and also to enable any person skilled in the art to practice the invention, including making and using any devices or systems and performing any incorporated methods. The patentable scope of the invention is defined by the claims, and may include other examples that occur to those skilled in the art. Such other examples are intended to be within the scope of the claims if they have structural elements that do not differ from the literal language of the claims, or if they include equivalent structural elements with insubstantial differences from the literal language of the claims.
This application claims the benefit of priority under 35 U.S.C. §119(e) to U.S. Provisional Patent Application Ser. No. 61/536,863, entitled “APPARATUS FOR CONVERTING THERMAL ENERGY TO ELECTRICAL ENERGY,” the contents of which is incorporated by reference it its entirety.
Number | Date | Country | |
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61536863 | Sep 2011 | US |