Patent Application
20080017591
This application is a utility application and claims the benefit under 35 USC § 119(a) of India Application No. 734/DEL/2006 filed Mar. 20, 2006. This disclosure of the prior application is considered part of and is incorporated by reference in the disclosure of this application.
The present invention relates to an apparatus for filtration and disinfection of sea water/ship's ballast water and a method thereof. The present invention particularly relates to an apparatus and method for simultaneous filtration and disinfection of ship's ballast water, such as sea water, based on centrifugation and hydrodynamic cavitation created using vortex diodes. This apparatus and method of the present invention for sea water treatment have particular utility in a ship to treat ship's ballast water that is being transported from one region to another. The apparatus and method of the present invention may find other uses, such as making potable drinking water from contaminated water.
This apparatus and method of the present invention for sea water treatment have particular utility in a ship to treat ship's ballast water that is being transported from one region to another. The apparatus and method of the present invention may find other uses, such as making potable drinking water from contaminated water.
When a ship leaves a port empty, or partially loaded, it takes seawater into ballast tanks to maintain stability and adjust buoyancy. In virtually every case, this ballast water will contain living organisms. When the ship reaches its destination and prepares to load its cargo, it discharges this ballast water, thus introducing potentially invasive species to the aquatic environment of the destination port. Approximately 70,000 cargo vessels carry billions of tons of ballast water around the world annually. This introduces hundreds of marine invasive species to non-native environments. This form of environmental pollution brings about ecological imbalance and causes indeterminate damages, estimated to be in billions of dollars.
To address this issue, many countries have passed regulations governing ballast water treatment and management. The International Maritime Organization (IMO) has adopted a convention for the control and management of ship's ballast water and sediments. The IMO convention has set guidelines, pending ratification, for the quality of ballast water that can be discharged at any location. A variety of options are under consideration for the treatment/disinfection of ballast water in maritime vessels. The present invention specifically uses, simultaneously, centrifugation and hydrodynamic cavitation for ballast water treatment.
Cavitation is a phenomenon of formation, growth and collapse of micro bubbles within a liquid. In hydrodynamic cavitation, the pressure variation in the flowing liquid causes cavitation. If the pressure falls below a critical value, usually below the vapor pressure of the medium at operating temperature, then small bubbles or vapor cavities are formed in the fluid. The condition at which these fine bubbles can be produced is termed as cavitation inception. An increase in the velocity will result in a further drop in pressure and an increase in the cavitation intensity. Generally, pressure recovery takes place further downstream where these cavities collapse generating a high magnitude pressure pulse. If the gas content inside the cavity is small enough, the pressure impulse could be very high, of the order of several hundreds of bars, which is enough to rupture microbial cells causing its destruction. Asymmetric collapse of cavities also results in very high speed liquid jets. Shear rates around such jets is adequate to kill micro-organisms. The present invention harnesses the phenomena of hydrodynamic cavitation using a novel apparatus and method to treat ballast water. This novel apparatus allows filtration and disinfection in single equipment. Such treatment limits the environmentally hazardous effects that may result from current practices.
The use of water treatment apparatuses and methods are known in the prior art. For example, U.S. Pat. No. 6,840,983 to McNulty describes a system and method of water treatment using a venturi injector for removal of dissolved oxygen from water. However, the focus is more on oxygen removal for corrosion inhibition and less on removing micro-organisms. The disclosed system is not effective for killing the micro-organisms in the ballast water to the desired level.
Reference may be made to U.S. Pat. No. 6,835,307 and Australian patent no. 6497400, which describe thermal treatment for ballast water. The treatment does not use cavitation or chemicals for treating ballast water. The system is not effective for killing the micro-organisms in the ballast water to the desired level. Another reference may be made to U.S. Pat. No. 6,773,607, wherein is described systems and methods for annihilating non-indigenous marine species and pathogenic bacteria in ship ballast water. These methods rely on adding a killing agent which needs to be stored on board. However, chemical disinfection techniques suffer from disadvantages like formation of possibly carcinogenic byproducts.
Reference may be made to a similar U.S. Pat. No. 6,773,611, in which apparatuses and methods of a ballast water treatment system are disclosed which includes a control system and a ballast tank system. This method is also based on adding biocides for treating ballast water and therefore requires production and storage of hazardous chemicals on board besides generating undesirable byproducts.
A ballast water treatment based on ultra sound cavitation is disclosed in the U.S. Pat. No. 6,770,248. The treatment requires piezoelectric rings immersed in pressurized transmission medium. Besides these requirements, the penetration of ultrasonic cavitation is small and its performance deteriorates with the scale-up. The method fails to use more effective hydrodynamic cavitation.
Reference may also be made to U.S. Pat. No. 6,761,123, which discloses a method for killing of aquatic nuisance species (ANS) in ship's ballast water by permeating to equilibrium a gaseous mixture. The method is time consuming and requires a vacuum over a long period (few days). This severely limits its utility for treating ballast water on ships.
A further reference may be drawn to U.S. Pat. Nos. 6,516,738, 6,125,778, 20020066399 A1 and 20030015481 A1 and PCT patent no. WO0210076, which describe methods for ballast water treatment using Ozone. The systems require generation and storage of Ozone on board. The systems do not use cavitation. The methods do not allow ballast water treatment without the occurrence of chemical reactions.
In U.S. Pat. No. 6,500,345, 2003029811 and 20050016933; PCT patent nos.: WO2004002895 A2, WO02072478 A2 and WO0244089 A2, are described apparatuses and methods for treating ballast water using UV or chemical biocides or killing agents. Efficiency of UV based system degrades with scale of operation. The use of chemical biocides is undesirable due to hazards in storage and formation of by-products. The method does not allow ballast water treatment without the occurrence of chemical reaction.
A European patent EP1517860 and an US patent 2004055966 describe methods that involve filtration of water through membrane filter followed by UV radiation, which has certain limitations in achieving the required efficiency in eliminating organisms as well as filtration rate.
In U.S. Pat. Nos. 6,284,793, 2004129645, 2004099608 and 2005016933 A1 and a PCT patent no. WO2005061388, are described methods, that are based on chemical treatment. In this method, the organisms are destroyed by the addition of per carboxylic acid, hydrogen peroxide, ionization gases, chlorine dioxide and cyanide. The method relies on several toxic and hazardous chemicals. The method does not allow ballast water treatment without the occurrence of chemical reaction.
Reference may be made to U.S. Pat. No. 6,171,508, which describes a method and apparatus for treating ship ballast water based on oxygenations and de-oxygenation. Oxygenation and de-oxygenation steps are based on mass transfer equipment and are significantly more time consuming and expensive.
In U.S. Pat. No. 5,816,181 ballast water treatment using heating is disclosed. The method is based on use of multiple heat exchangers. Such heat exchangers require significant space and the disinfection using heating is rather expensive. The efficacy of the heat treatment is not as high as other methods of disinfection based on chemical biocides or hydrodynamic cavitation.
U.S. Pat. No. 5,192,451 discloses a method for controlling zebra mussels in ship ballast tanks by adding a water-soluble dialkyl diallyl quaternary ammonium polymer. However, the method does not allow ballast water treatment without the occurrence of chemical reaction and does not use hydrodynamic cavitation.
A reference may be made to a Japanese patent Publication number, 2005, 246198, which describes a method of sterilizing harmful planktons. It works on the principle of cavitation jet. The flow is directed towards a V-shaped surface using a nozzle, wherein it hits the surface with great force, causing physical impact. However, the method does not involve filtration and cavitation simultaneously and has a drawback. The metallic surface on which the water jet hits will be subjected to erosion corrosion due to physical impact.
Reference may also be made to a Japanese patent Publication number, 2005, 271648, which involves a treatment device comprised of a high speed pump, that forces water through an annular passage causing cavitation. However, the method does not involve filtration and cavitation simultaneously.
Besides the abovementioned patents, several studies on ultrasonic and hydrodynamic cavitation have been published in scientific journals, such as for example, Moholkar and Pandit, 1997; Gogate and Pandit, 2001 and references cited therein. The focus of these studies was mainly on developing basic understanding of cavitation phenomena and to explore new applications of cavitation. None of these studies however dealt with use of hydrodynamic cavitation for disinfection of ballast water.
Most of the prior art on hydrodynamic cavitation based on realization of cavitation by passing a fluid through a constriction. As fluid passes through a constriction, the static pressure downstream drops due to an increase in liquid velocity, which leads to hydrodynamic cavitation. None of the prior studies have used principle of conservation of angular momentum for realizing cavitation.
While the above described hitherto known prior art inventions and studies fulfill their particular objectives and requirements, these do not describe a system and method for ballast water treatment which allows a vessel to disinfect ballast water that is being transported from one port to another without using chemicals, UV or ultrasound. Therefore, there is a definite need for developing a novel and more efficient disinfection technology, which could eliminate or reduce the use of disinfecting chemicals and also is not based on the use of UV or ultrasound.
In our co-pending patent application, Indian reference no.: 2988/DEL/2005 and PCT reference no.: PCT/IN2005/000444, we have described and claimed an apparatus for disinfection of sea water/ship's ballast water, which comprises a water intake means connected in series through a pressure gauge and check valve(s) to an inlet port of a cavitation chamber, optionally through an heat exchanger, characterized in that the cavitation chamber essentially being provided with single or multiple cavitating elements placed perpendicular to the direction of flow of fluid, said cavitating elements being spaced at uniform or non-uniform spacing and each said cavitating element having a fractional open area in the form of single or multiple orifices, the output of the said cavitation chamber being passed through a quality check point and check valve(s) to a ballast tank, the output of the said ballast tank being connected to a discharge pump through check valve(s) to a discharge outlet.
The main object of the present invention is to provide an apparatus for filtration and disinfection of sea water/ship's ballast water and a method thereof, which obviates the drawbacks of the hitherto known prior art, and not only has the advantages of the hitherto known prior art water treatment apparatuses and methods, but also provides additional advantages.
Another object of the present invention is to provide an apparatus for filtration and disinfection of sea water/ship's ballast water and a method thereof, which is based on the principle of hydrodynamic cavitation and is based on the principle of conservation of angular momentum. It comprised of a cavitation chamber with tangential entry, thus enabling more efficient cavitation and more suitable disinfection method for ballast water. Besides realizing cavitation, the apparatus described in present invention also allows possibility of filtration using the same cavitation chamber. This will make available an economically favorable and efficient manner by which to limit the environmentally adverse effects that may result when untreated ballast water is released into an environment that is ecologically different from that in which the water was originally obtained.
Yet another object of the present invention is to provide an apparatus for filtration and disinfection of sea water/ship's ballast water and a method thereof, wherein ballast water preferably but optionally, is passed through a cavitation chamber (diode chamber) having one or more bleed holes to realize effective filtration, wherein the size and the number of bleed holes are in the range of 0.01 to 0.25 times the depth of diode chamber.
Still another object of the present invention is to provide a system and method of water treatment by circulating the ballast water preferably but optionally, through a single cavitating chamber or a series of cavitating chambers for multiple times. The number of re-circulations needs to be optimized following the procedure discussed later. This makes it possible to efficiently treat water, preferably but optionally ballast water.
Still yet another object of the present invention is to provide an apparatus for filtration and disinfection of sea water/ship's ballast water and a method thereof, wherein the ballast water preferably but optionally, is circulated for multiple times through a cavitation chamber having a single or a series of bleed holes.
A further object of the present invention is to provide an apparatus for filtration and disinfection of sea water/ship's ballast water and a method thereof, wherein the ballast water is pre-heated using the exhaust gases of the ship's engine, prior to feeding it to the cavitation chamber.
A still further object of the present invention is to provide an apparatus for filtration and disinfection of sea water/ship's ballast water and a method thereof, preferably for but not limited to the purposes of killing aquatic organisms.
A yet further object of the present invention is to provide an apparatus for filtration and disinfection of sea water/ship's ballast water and a method thereof, which is new, improved and eco-friendly and may be easily and efficiently manufactured, marketed and can be retrofitted with minor modifications in the ships, which are in service.
Another object of the present invention is to provide an apparatus for filtration and disinfection of sea water/ship's ballast water and a method thereof, that requires minimum installation area on board and has relatively low cost of manufacture with regard to both materials and labor, and which then can be made available to the user industries at relatively low prices.
The present invention provides an apparatus for filtration and disinfection of sea water/ship's ballast water and a method thereof. To achieve this, the present invention comprises a system for ballast water treatment having a vortex diode with single or multiple bleed holes. The vortex diode having an inlet port that is adapted to receive ballast water and an outlet port that is adapted to expel the treated ballast water. Water to be treated, optionally pre-heated, enters the inlet port and passes through the vortex diode, comprising bleed holes, wherein hydrodynamic cavitation occurs at the downstream of vortex diode which effectively disinfects the ballast water. The disinfected ballast water is expelled through the outlet port to a receptacle, which is preferably but optionally a ballast tank. The water rejected through the bleed holes can be released in the sea. The method for ballast water treatment may further comprise re-circulating said water through the cavitation chamber to provide further disinfection and may also include re-treating the water before releasing the water to the surrounding waterways from the receptacle, which is preferably but optionally a ballast tank, or alternatively, but not exclusively, a closed tank or a water conduit connecting to surrounding waterways.
As such, the general purpose of the present invention, which will be described subsequently in greater detail, is to provide an apparatus for filtration and disinfection of sea water/ship's ballast water and a method thereof which has all the advantages of the prior art mentioned heretofore and many novel features that result in a system and method for ballast water treatment which is not anticipated, rendered obvious, suggested, or even implied by the prior art, either alone or in any combination thereof.
The ballast water is passed through a novel vortex diode comprising bleed holes. This may be achieved while ballasting and de-ballasting. Preferably but optionally, the vortex diodes are connected in series to a transfer piping through which ballast tanks receive or expel water. A pump means, preferably but optionally a ballast pump as found on many ships is adapted to receive water from an external water source and may pump water through the vortex diode.
The system may also include a re-circulation means that takes water in the receptacle and re-circulates the water from the receptacle via a re-circulation piping means and re-pumps the water through the vortex diode back into the receptacle. This re-circulation means, optionally but preferably, is monitored for the level of micro-organisms present in the treated water. There are, of course, additional features of the invention that will be described hereinafter.
The numerous objects and advantages of the present invention will be readily apparent to those of ordinary skill in the art upon a reading of the following detailed description of presently preferred, but nonetheless illustrative, embodiments of the present invention when taken in conjunction with the accompanying drawings. It is to be understood that the invention is not limited in its application to the details of construction and to the arrangements of the components set forth in the following description or illustrated in the drawings. The invention is capable of other embodiments and of being practiced and carried out in various ways. Also, it is to be understood that the phraseology and terminology employed herein are for the purpose of description and should not be regarded as limiting.
There thus has been outlined broadly the more important features of the invention in order that the detailed description thereof that follows may be better understood and in order that the present contribution to the art may be better appreciated.
The objects of the invention as outlined herein above, along with the various features of novelty that characterize the invention, are pointed out with particularity in the claims annexed to and forming a part of this disclosure. For a better understanding of the invention, its operating advantages and the specific objects attained by its uses, reference should be made to the accompanying drawings and descriptive matter in which there are illustrated current embodiments of the invention.
The apparatus for filtration and disinfection of sea water/ship's ballast water and a method thereof of the present invention have been illustrated in FIGS. 1 to 6 of the drawings accompanying the specification.
In
In
In
The methodology used for identification of the optimum operating parameters involves identification of type of organisms and estimating required intensity/number of cavitation events. The Rayleigh-Plesset equation is used to simulate cavity dynamics and to quantify collapse of cavities and resulting disinfection performance. Cavitation number (Cv) is an important parameter in hydrodynamic cavitation which decides the conditions for the onset of cavitation in a particular system. It can be expressed as:
where p2 is recovery pressure, pv is the vapor pressure of liquid, vo is average velocity of liquid at the orifice and ρ1 is the density of liquid. Under ideal conditions, cavitation preferably occurs for Cv<1 though under some conditions e.g. presence of gases/solid particles, cavitation may occur at Cv>1. Computational fluid dynamics (CFD) based models are used to simulate flow and to predict the instantaneous pressure field around the traveling cavity at any downstream location.
The CFD models involve solution of conservation equations of mass, momentum and energy on a digital computer for a specific design/configuration. The more detailed flow chart of 4th box in
The next step is to select appropriate governing equations for solving the flow in cavitation chamber/elements. The flows relevant to cavitation are invariably turbulent. Several different models have been developed to simulate turbulent flows (see for example Ranade, 2002 and references cited therein). For simulating the flow through the cavitation chamber/elements relevant to the present invention, we used the standard k−□ model to simulate turbulence.
The basic governing equations listed below were solved using finite volume method and SIMPLE algorithm (Patankar, 1972) using a commercial CFD solver, FLUENT (of Fluent Inc., USA). The geometry modeling was done using commercial software called GAMBIT (of Fluent Inc., USA). The computational model was evaluated to quantify errors associated with the numerical solution. After establishing that these numerical errors are within acceptable limits, the model was used to simulate flow and pressure field in different configurations of vortex diode/elements. The simulated trajectories of cavities and pressure/velocity history along such trajectories were stored for subsequent calculations of Rayleigh-Plesset equation. The fluctuating pressure field predicted by the CFD models is incorporated into a bubble dynamics equation to obtain the cavity radius history and the collapse pressures for a cavity of certain size, traveling with the fluid (see Pandit and Gogte, 2001; Ranade, 2002). Once the parameters for generating desired cavitation events are identified, CFD models are then used to optimize the overall configuration of cavitation chamber. The methodology is useful to optimize the overall system to meet the IMO guidelines on ballast water treatment.
The basic governing equations are as follows:
The present invention provides an apparatus and method for filtration and disinfection of ship's ballast water, such as sea water, based on centrifugation and hydrodynamic cavitation. The apparatus comprises a vortex diode of circular cross section with single or multiple bleeding holes; tangential inlet ports and axial outlet ports. The chamber depth can be considered as a reference length scale. Typically the chamber diameter is in the range of 2 to 12 times the chamber depth, preferentially in the range of 4 to 8 times the chamber depth.
Accordingly the present invention provides an apparatus for filtration and disinfection of sea water/ship's ballast water, which comprises a water intake means (17 & 18) consisting of a ballast water intake source (17) and pump means (18) connected in series through a pressure gauge (3) and check valve(s) to an inlet port of a cavitation chamber of the form of vortex diode (5), optionally through an heat exchanger (4), characterized in that the said vortex diode cavitation chamber (5) essentially being provided on the periphery with single or multiple bleed holes of diameter(s) being in the range of 0.04 to 0.25 times the chamber depth, the output of the said vortex diode cavitation chamber (5) being passed through a quality check point (6) and check valve(s) (7) to a ballast tank (8), the output of the said ballast tank (8) being connected to a discharge pump (9) through check valve(s) to a discharge outlet and the bleed holes output from the said vortex diode cavitation chamber (5) being connected to the said intake source (17).
In an embodiment of the present invention, the vortex diode (5) has water intake means (17 & 18) through which seawater enters from outside a vessel.
In another embodiment of the present invention, the pump means (18) is one or a series of pumps such as, but not limited to a ballast pump.
In yet another embodiment of the present invention, the heat exchanger (4) is connected to an energy source such as a standard source or method known in the art, or steam or engine exhaust gases from the ships engine.
In still another embodiment of the present invention, the ratio of diameter of the vortex diode cavitation chamber to the depth of the chamber is in the range of 2 to 12 and the said chamber being provided with tangential inlet port having a taper with angle ranging from 2 to 10 degrees and axial outlet port having a taper with angle ranging from 1 to 7 degrees and a smoothened expansion to a straight portion with expansion ratio on the range of 2 to 30. The inlet port ensures the smooth tangential entry of the fed water. The shortest diameter of the tangential inlet port is same as the depth of diode chamber. The diameter of the inlet port near the diode chamber is same as that of chamber depth.
In yet another embodiment of the present invention, the vortex diode (5) comprises of single or multiple bleeding holes; wherein the number of bleeding holes is in the range of 1 to 60, having a fractional open area in the form of single or multiple holes which are either circular or non-circular with or without sharp edges and each hole is having diameter in the range of 500 micrometers to few millimeters. The water coming out of the bleed holes is recycled to the water intake means (17). The diameter of the bleeding holes is in the range of 4 to 25% of the chamber depth.
In still yet another embodiment of the present invention, the vortex diode (5) comprises a slot shaped bleeding outlet covering the entire periphery of the diode chamber.
In a further embodiment of the present invention, (i) the diameter of vortex diode; (ii) the number of bleed holes; (iii) the location and spacing between bleed holes; (iv) the chamber depth (v) configuration of inlet and outlet ports; (vi) the operating temperature; (vii) the operating flow rate/flow velocity; (viii) the number of re-circulations through vortex diode; are estimated and configured using computational fluid dynamics (CFD) based models and Rayleigh-Plesset equation for cavitation collapse, such as herein described.
In a yet further embodiment of the present invention, the quality check point (6) is provided with known devices capable of monitoring the quality of treated water.
In a still further embodiment of the present invention, to enable re-circulation of the treated water or a portion thereof if required by the quality check point (6), the discharge outlet of the said discharge pump (9) being connected through a pressure gauge (10) and check valve(s), optionally through an heat exchanger (11), to an inlet port of a vortex diode (12) having single or multiple cavitating elements and back to the said ballast tank (8) through a quality check point (13) and check valves (14, 7).
Accordingly the present invention provides a method for filtration and disinfection of sea water/ship's ballast water using the apparatus as herein above described, which comprises subjecting the ballast water to be treated to hydrodynamic cavitation by pumping the water intake of sea water, optionally pre-heated, into an inlet port of a vortex diode having single or multiple bleeding holes, the treated ballast water being passed through a quality check point to a ballast tank, re-circulating the treated water or a portion thereof if required by the quality check, for further hydrodynamic cavitation.
In an embodiment of the present invention, the ballast water to be treated is optionally pre-heated to a temperature in the range of 10 to 70° C.
In another embodiment of the present invention, the water flow rate through the vortex diode is such that the liquid velocities at the inlet are in the range of 1 to 15 m/s.
In still another embodiment of the present invention, the water pressure is in the range of 0.5 to 150 kg/cm2.
In another embodiment of the present invention, the method for filtration and disinfection treatment of water using centrifugation and hydrodynamic cavitation is also suitable for a wide variety of water treatment applications including but not limited to wastewater management, agricultural applications, pool and space applications, oil and gas applications, and various disinfectant applications.
The ballast water disinfection treatment herein described preferably though not exclusively occurs such that as the ship pumps sea water through a vortex diode, which has preferably but not limited to single or multiple bleeding holes. Generally, the pump means, which may be one or a series of pumps, draws seawater from waterways surrounding the ship into the transfer piping means. The pumped seawater is passed through preferably but not limited to a heat exchanger. The energy source to heat this water may be a standard source or method known in the art, such as steam or engine exhaust gas or other. Control of the vortex diode may be through a regulator connected in series with the water intake line means that is connected to the cavitation chamber. The treated water expelled from the vortex diode is connected to a receptacle or optionally receptacles, which is preferably but optionally a ballast tank(s). The water collected from the bleed holes can be recycled back to water intake means or discarded to sea.
The water treatment start-up and shut down will coincide with the vessel's water intake. A re-circulation mechanism may be employed to further treat water and the need for such may be determined by an appropriate quality check system. Though at present, no in-line monitoring sensors are available by which organisms could be counted. However, elsewhere efforts are underway to devise sensors for detecting presence of specific pathogens. If a re-circulation mechanism needs to be activated, the shutdown operation, preferably although optionally, may be controlled by a control panel means. In use, it can now be understood the apparatus and method of water treatment may be used for a non-chemical, efficient treatment of water.
While an embodiment of the apparatus and method of water treatment of the present invention has been described in detail it should be apparent that modifications and variations thereto are possible, all of which fall within the true spirit and scope of the invention. With respect to the above description then, it is to be realized that the optimum dimensional relationships for the parts of the invention, the following procedure may be used.
The water pumping through the vortex diode gets disinfected due to hydrodynamic cavitation. Whenever water passes through the cavitation chamber, cavities are generated due to the pressure fluctuations resulting from the strong vertical flow within a chamber. The generated cavities undergo various stages of the cavitation phenomena before violently collapsing, resulting in the release of large magnitudes of energy and highly reactive oxidizing species. The oxidizing species and conditions of high temperature and pressure are considered responsible for the disinfection of the micro-organisms. The quantum of the oxidizing species and the magnitude of temperature/pressure, hence the disinfection efficiency, is dependent on the geometric and operating conditions.
It should be noted that, the optimum dimensional relationships for the parts of the invention to include variations in size, materials, shape, form, function and manner of operation, assembly and use, are deemed readily apparent and obvious to one skilled in the art, and all equivalent relationships to those illustrated in the drawings and described in the specification are intended to be encompassed by the present invention.
For example, any suitable cylindrical conduit made of a wide variety of metals, plastic, or other sturdy material may be used for the transfer piping means and/or re-circulation piping means described. And, although the disinfection treatment of water using hydrodynamic cavitation preferably but optionally on vessels, has been described, it should be appreciated that the method and the apparatus of water treatment herein described may also be suitable for a wide variety of water treatment applications including but not limited to wastewater management, agricultural applications, pool and space applications, oil and gas applications, and various disinfectant applications. Additionally, a wide variety of holds or tanks of many shapes and sizes, as well as an open body of water, also may be used instead of the basic receptacle or ballast tank described. Furthermore, the method, configuration, size, shape and pressure and volume requirements may be adapted to conform to a wide variety of ships of a variety of shapes and sizes, and a closed recirculation system and method described may be transferable from one receptacle to another. The invention may also be adapted for use with a wide variety of pumps, receptacles, cavitation elements or sources, pressure valves and other components that are required by the invention but already present in a vessel or other treatment location.
The novel apparatus and method of the present invention is capable of sterilizing hazardous organisms contained in ballast water stored in a ballast tank to effectively provide treatment of ballast water. The foregoing is considered as illustrative only of the principles of the invention. Further, since numerous modifications and changes will readily occur to those skilled in the art, it is not desired to limit the invention to the exact construction and operation shown and described, and accordingly, all suitable modifications and equivalents may be resorted to, falling within the scope of the invention.
The novelty of the present invention resides in the capability to provide a relatively low cost and eco-friendly apparatus and method based on hydrodynamic cavitation for efficient and economical disinfection of sea water/ship's ballast water by simply passing the organism infested water through single or multiple vortex diode, without use of any chemicals or any chemical reaction.
The non-obvious inventive step of providing one or more cavitation chamber(s) without using flow constrictions. The present invention harnesses the principle of conservation of angular momentum to generate low pressure regions within the chamber where cavitation occurs. Use of such a chamber with specially configured tangential inlet port and axial outlet port enables realization of the novelty of the apparatus of the present invention. Further, the non-obvious inventive step of combining the filtration and cavitation in a single equipment by providing single or multiple bleeding holes to the vortex diode enables realization of the novelty of the method of the present invention for filtration and disinfection of sea water/ship's ballast water.
In order to demonstrate the performance characteristics of the apparatus for disinfection of sea water/ship's ballast water and a method thereof of the present invention, an experimental set-up was constructed as shown in
The evaluation for the destruction level of the organisms is carried out as per the following procedure:
The biological count with regard to free living zooplanktons is assessed in the intake and discharge waters. Aliquot of water sample (50 liters) after serial dilutions is plated on Zobell marine agar and incubated for 24 hours at ambient temperature. The colonies are enumerated thereafter and expressed as number per milliliter. The bacterial count in discharge water (post-cavitation) is compared with the intake water (pre-cavitation) and the percentage reduction in bacterial number is calculated using the following formula:
Where, I=Cell count in intake water (pre-cavitation)
The biological count with regard to viable bacteria, associated with zooplankton, is assessed in the intake and discharge waters using spread plate method. Zooplankton cells are collected by passing known quantity of intake (pre-cavitation) and discharge (post-cavitation) waters through a sieve made up of bolting silk with 50μ mesh and suspended in a known quantity of filtered seawater. The zooplankton cells are then homogenized and an aliquot of this homogenate (0.1 ml) after serial dilutions is plated on Zobell marine agar and incubated for 24 hours at ambient temperature. The colonies are enumerated thereafter and expressed as number per milliliter. The bacterial count in discharge water (post-cavitation) is compared with the intake water (pre-cavitation) and the percentage reduction in bacterial number is calculated as above.
The biological count with regard to phytoplankton of cell size greater than 10μ is assessed in the intake (pre-cavitation condition) and discharge (post-cavitation condition) waters. For this purpose a known volume of intake water and discharge water is filtered through a sieve made up of bolting silk with 10μ mesh. The phytoplankton cells retained on the 10μ bolting silk are then immediately transferred into a known volume of filtered seawater. A sub sample of known volume is taken after thorough mixing and only pigmented cells with red chlorophyll fluorescence under UV light are enumerated using an inverted epifluorescence microscope and expressed as numbers per milliliter. The phytoplankton count in discharge water is compared with intake water and the percentage reduction in number is calculated as above.
The biological count with regard to Zooplankton of size greater than 50μ is assessed in the intake (pre-cavitation condition) and discharge (post-cavitation condition) waters. For this purpose a known volume of intake water and discharge water is filtered through a sieve made up of bolting silk with 50μ mesh. The Zooplankton cells retained on the sieve are then immediately transferred into a known volume of filtered seawater. A sub sample of known volume is taken after thorough mixing and only live zooplanktons (with mobility) are enumerated using a binocular microscope and expressed as numbers per cubic meter. The zooplankton count in discharge water is compared with intake water and the percentage reduction in number is calculated using the following formula:
Where, I=Cell count in intake water (pre-cavitation)
The following examples are given by way of illustration of the apparatus for filtration and disinfection of sea water/ship's ballast water and a method thereof of the present invention in actual practice and therefore should not be construed to limit the scope of the present invention in any manner.
The decomposition of aqueous solution of Potassium Iodide to form Iodine was used to identify occurrence and to evaluate the extent of cavitation. The decomposition of Potassium iodide (KI) was carried out using the vortex diode with chamber diameter, 35 mm; depth 6 mm and nozzle angle 7 degree, to estimate the extent of cavitation taking place in the same.
The experimental setup used is shown in
Appropriate calibration of UV-VIS Spectrophotometer by measuring the absorbance at 354 nm of known Iodine Concentration was carried out. 14 liter of 1% Potassium Iodide solution in distilled water was charged in the system. The bypass line valve was then adjusted to obtain the desired inlet pressure to the vortex diode. Cooling water was circulated through the jacket to control temperature at 40° C. Samples were collected at the interval of 10 minutes for one hour. These samples were kept in dark and their absorbance was immediately measured in the UV-VIS Spectrophotometer at 354 nm. From the absorbance values for the samples collected at interval of 10 minutes for different inlet pressures, the Iodine concentration and the percentage degradation of KI values at different time intervals were calculated which are listed in the below.
The observed degradation of KI clearly indicates that hydrodynamic cavitation occurs in a system comprised of vortex diode.
Flow through cavitation chamber of 90 mm diameter, 15 mm depth with tangential nozzle expansion angle of 7 degree and flow rate=0.42 lps corresponding to the liquid velocity at the entry of vortex diode as 0.86 m/s and pressure=3 kg/cm2. The seawater was passed through the vortex diode once. The % destruction as indicated in the following table is with reference to the inlet water.
Flow through cavitation chamber of 90 mm diameter, 15 mm depth with tangential nozzle expansion angle of 7 degree and flow rate=0.42 lps corresponding to the liquid velocity at the entry of vortex diode as 0.86 m/s and pressure=3 kg/cm2. The seawater was passed through the vortex diode thrice. The % destruction as indicated in the following table is with reference to the inlet water.
Flow through cavitation chamber of 90 mm diameter, 15 mm depth with tangential nozzle expansion angle of 7 degree and flow rate=0.42 lps corresponding to the liquid velocity at the entry of vortex diode as 0.86 m/s and pressure=3 kg/cm2. The seawater was passed through the vortex diode five times. The % destruction as indicated in the following table is with reference to the inlet water.
Flow through cavitation chamber of 90 mm diameter, 15 mm depth with tangential nozzle expansion angle of 7 degree and flow rate=0.67 lps corresponding to the liquid velocity at the entry of vortex diode as 1.37 m/s and pressure=5 kg/cm2. The seawater was passed through the vortex diode once. The % destruction as indicated in the following table is with reference to the inlet water.
Flow through cavitation chamber of 90 mm diameter, 15 mm depth with tangential nozzle expansion angle of 7 degree and flow rate=0.67 lps corresponding to the liquid velocity at the entry of vortex diode as 1.37 m/s and pressure=5 kg/cm2. The seawater was passed through the vortex diode twice. The % destruction as indicated in the following table is with reference to the inlet water.
Flow through cavitation chamber of 90 mm diameter, 15 mm depth with tangential nozzle expansion angle of 7 degree and flow rate=0.67 lps corresponding to the liquid velocity at the entry of vortex diode as 1.37 m/s and pressure=5 kg/cm2. The seawater was passed through the vortex diode five times. The % destruction as indicated in the following table is with reference to the inlet water.
Flow through cavitation chamber of 90 mm diameter, 15 mm depth with tangential nozzle expansion angle of 7 degree and flow rate=0.82 lps corresponding to the liquid velocity at the entry of vortex diode as 1.67 m/s and pressure=7 kg/cm2. The seawater was passed through the vortex diode thrice. The % destruction as indicated in the following table is with reference to the inlet water.
Flow through cavitation chamber of 90 mm diameter, 15 mm depth with tangential nozzle expansion angle of 7 degree and flow rate=0.82 lps corresponding to the liquid velocity at the entry of vortex diode as 1.67 m/s and pressure=7 kg/cm2. The seawater was passed through the vortex diode five times. The % destruction as indicated in the following table is with reference to the inlet water.
Flow through cavitation chamber of 90 mm diameter, 15 mm depth with tangential nozzle expansion angle of 7 degree and flow rate=0.82 lps corresponding to the liquid velocity at the entry of vortex diode as 1.67 m/s and pressure=7 kg/cm2. The seawater was passed through the vortex diode ten times. The % destruction as indicated in the following table is with reference to the inlet water.
From the results of biological counts obtained using the vortex diode as given in the illustrative examples herein above it is clear that there is a substantial destruction of organisms. This observed destruction occurred without requiring any chemicals or heat treatment or the use of UV or ultrasound treatment. The disinfection performance can be significantly enhanced by employing the optimization methodology based on CFD and Rayleigh-Plesset equations. By employing such a methodology the apparatus of ballast water disinfection can be tailored to destruction of specific organisms as well.
The aforementioned patents and other water treatment systems and methods currently known in the art make no provisions as in the present invention for the disinfection/treatment of ballast water using hydrodynamic cavitation wherein the apparatus is essentially a vortex diode with tangential inlet ports and axial outlet port. In view of the foregoing disadvantages inherent in the known types of ballast water treatment systems and methods now present in the prior art, the present invention provides an apparatus and method to treat ballast water using hydrodynamic cavitation in which ballast water is passed through a vortex diode with bleeding holes to realize simultaneous filtration and cavitation and overcomes the disadvantages and drawbacks noted in the prior art. Further, the present invention provides an apparatus for isolation by centrifugation and disinfection of sea water/ship's ballast water and a method thereof, which has all the advantages of the prior art mentioned heretofore and many novel features that result in a system and method for ballast water treatment which is not anticipated, rendered obvious, suggested, or even implied by the prior art, either alone or in any combination thereof.
The Main Advantages of the Present Invention are:
As such, those skilled in the art will appreciate that the concept, upon which this disclosure is based, may readily be utilized as a basis for the designing of other structures, methods and systems for carrying out the several purposes of the present invention. It is important, therefore, that the claims be regarded as including such equivalent constructions insofar as they do not depart from the spirit and scope of the present invention.
| Number | Date | Country | Kind |
|---|---|---|---|
| 734/DEL/2006 | Mar 2006 | IN | national |
