The present invention relates to an apparatus for isochoric gas compression, in particular to a gas for industrial use, which uses as driving energy the thermal energy deriving from waste thermal flows preferably from the same industrial plant. The apparatus according to the invention substantially does not therefore require the need for mechanical and/or electrical energy in order to carry out the compression of the gas and consequently of a thermodynamic cycle which, starting from a thermal source, in this case waste thermal flows, makes the aforementioned mechanical and/or electric energy available for carrying out the compression.
Many industries in which gas compression plants are used, have at their disposal large waste thermal flows the thermal energy of which generally can be exploited for the production of electrical or mechanical energy. For this purpose, as is known, recovery organic Rankine cycle (ORC) or Rankine cycle with water vapor, are used.
Compression plants need at the same time a driving energy and a substantial portion of their energy needs is represented by the compression of air or other gases.
According to the known art it is therefore possible to install a recovery cycle (with water vapor, gas or organic fluid), in order to produce with it electric energy for actuating the compressors.
Another known technique is to couple the turbine of the recovery cycle directly to the compressor by using the mechanical energy processed in the turbine for the actuation of the compressor.
These solutions, although having high yields, require high installation costs and involve the presence of rotating machines (turbines and compressors) that require maintenance and can reduce the reliability of the system.
The Applicant has therefore recognized the need for developing an apparatus able to directly use the thermal energy for compressing a gas, without going through a thermodynamic cycle which turns the thermal energy into mechanical and/or electric energy. In this way, an apparatus is obtained which, having a reasonable efficiency, requires low installation and maintenance costs, thanks to its simplicity of construction.
Purpose of the present invention is to provide an apparatus for isochoric compressing of gas, in particular of gas for industrial use, which uses almost exclusively thermal energy as driving energy deriving from waste thermal flows of the same industrial plant.
Traditionally, for compressing a gas using a thermal source, it is necessary to install a recovery cycle, with which electrical or mechanical energy can be produced in order to actuate the compressors, as represented in a simplified way in
Instead, the apparatus according to the present invention, although having a limited efficiency, does not require the use of the rotary machines, if not for some auxiliary functions as will be seen below for some embodiments, and therefore it allows low installation and maintenance costs, thanks to its simplicity of construction.
According to the present invention, it is possible to compress the gas and return it up to a temperature close to the suction one, by exploiting a hot thermal source, a cold thermal source and a gas permeable means, hereinafter also called regenerator, which is capable of accumulating and giving its heat to the gas.
According to the present invention an apparatus is described for the isochoric compression of gas, the characteristics of which are set out in the appended independent claim.
Further embodiments of the aforesaid preferred and/or particularly advantageous apparatus, are described according to the characteristics set forth in the attached dependent claims.
The invention will now be described with reference to the accompanying drawings, which illustrate some non-limiting embodiments thereof, in which:
Referring now to the aforesaid Figures and in particular to
The apparatus 1 for isochoric gas compression comprises a container 2 within which are positioned a first heat exchanger 3, preferably placed at the top, and a second heat exchanger 4, preferably placed at the bottom, respectively, in order to introduce heat into the system and to extract it. By way of example, the “hot” heat exchanger 3 could be crossed by a diathermal oil, whereas the “cold” heat exchanger 4 could use water cooled by a suitable circuit able to exchange heat with the environment. In the lower section 2b of the container an inlet gas duct 5 is present, which must be compressed and an outlet duct 6 for the compressed gas, both being equipped with a corresponding supply valve V1 and the discharge valve V2. The container 2 is traversed by a gas permeable means, called regenerator 7, movable between a lower and an upper position and able to accumulate and transfer heat to the gas (for instance, made with various overlapping metal mesh layers, which exchange heat with the gas during the crossing of the same and accumulate it within their mass). The regenerator 7 divides the container 2 into two sections, an upper section 2a, at a higher temperature, and a lower section 2b, at a lower temperature. The volumes of the two sections 2a and 2b are obviously variable according to the position of the regenerator 7. The pressures in the two sections are instead approximately the same, being the gas permeable septum.
Referring to the positions of the regenerator 1A to 1E, to the configurations of the valves V1, V2 (0=closed, 1=open) and to the corresponding graphs which, according to the aforementioned positions of the regenerator, respectively represent the regenerator stroke and the gas pressure, the apparatus) works according to the following logic:
It must be considered that in the hypothesis of a perfect gas, the maximum obtainable pressure is derived from the law of gases P*V=M*R*T which, once applied to the specific case (To and T1, V constant, R constant, M constant) permits to obtain Poutmax=Pin*T1/T0. The valve V2 is actuated at a pressure lower than this maximum pressure, as by this Poutmax a useful outlet flow rate would not be associated (in fact, in the applied gas relation, the volume must be constant). The closer is Pout with respect to Pin (that is, the lower is the required compression ratio), the greater the extractable flow rate for each cycle of the system (at the expense of an obviously moderate Pout/Pin compression ratio).
The system delivers a pressurized gas until the regenerator has reached the lower dead point (position 1C). The supplied gas has approximately the temperature T0, due to the fact that it passes through the regenerator before passing through V2 and in the presence of the “cold” heat exchanger 4 placed in the lower portion of the container;
The beginning or the end of some phases may not coincide with the upper and lower dead points, as the pressure inside the apparatus, in a certain instant, also depends on the heat input supplied by the exchangers 3 and 4, and not only on the position of the regenerator 7.
In this way it is therefore possible to return the compressed gas to a temperature close to the suction one, by simply exploiting a hot thermal source, a cold thermal source and a gas regenerator, without the need for the addition of other energy as well as a thermal energy, apart from the small fraction needed to cyclically actuate the regenerator inside the container. Preferably, the regenerator 7 performs a complete cycle in a time ranging from 1 to 10 seconds, for example in relation to a container volume 2 of about 1000 liters and a height of about 1 m.
An alternative embodiment of the invention is shown in
The configuration 3B is similar to the previous one, but instead of moving the disc with a mechanical actuator, the gas is moved by one or more fans 9 capable of generating a reversible flow. The disc is made as light as possible and moves accordingly in order to equalize the pressures between the two sections 2a and 2b of the container.
In the configuration 3C also the first heat exchanger 3 and the second heat exchanger 4 are placed outside the container. Obviously, in
A third embodiment of the invention is shown in
In particular, in
The configuration in
The operating logic of the configuration of
When the disc 8 moves downwards, that is towards the cold source (
During the movement downwards of the disc 8, the gas passes through the regenerator, heating up and then through the fan 9a and the “hot” heat exchanger 3″. In the heat exchanger 3 passes a flow rate equal to m1+m3, thanks to the flow rate provided by the fan. The flow rate m1 which has left the section 2b of the container is equal to the flow rate that enters the upper section 2a of the container (subtracted the amounts cumulated in the volumes of the respective components), whereas the remaining flow rate m3 cannot but be recycled upstream of the fan for the recirculation duct R2.
When the disc moves upwards towards the hot source (
The gas then passes through the regenerator, cooling down and then through the fan 9b and the “cold” heat exchanger 4. In the heat exchanger 4 passes a flow rate equal to m1+m2, thanks to the flow rate provided by the fan. The flow rate m1 which has left the section 2a of the container is equal to the flow rate entering the lower section 2b of the container, whereas the remaining flow rate m2 cannot help but be recycled upstream of the fan for the recirculation duct R1.
The flow rates involved are established by the prevalence of the fan with respect to the load losses of the respective branches. More in detail, it is sufficient to increase the rotation speed of the fan 9a of the hot branch with respect to the rotation speed of the fan 9b of the cold branch, in order to obtain a lowering of the pressure at the node K with respect to the node H and therefore a flow from H to K and vice versa. In this way an alternating flow is obtained without using valves.
The gas enters or leaves the system through the valves V1 and V2 when, respectively, the pressure in the lower portion of the exchanger drops below the inlet pressure or rises above the outlet pressure, with the logic already described for the configuration in
In previous solutions, the regenerator 7, 7a supplies a great portion of the heat required to bring the gas to a higher temperature, and the “hot” heat exchanger 3 supplies the remaining heat portion. Therefore, in the heat exchanger 3, the heat exchange occurs with the gas being already at high temperature, as the gas has been already heated by the regenerator. Therefore also the heat carrier, for example diathermic oil, which flows into the heat exchanger 3 works with relatively low temperature differences. This phenomenon may adversely affect the ability to perform an effective heat recovery from a gaseous effluent as a low temperature difference of oil affects the ability to effectively cool down the gaseous source, just because the oil remains at relatively high temperatures.
In the configuration of
In fact, when the flow is directed downwards it would be counterproductive to let the hot gas flow through the exchanger 3 which has the function of giving heat and not of absorbing it. On the other hand, the giving of heat from the heat exchanger 3 to the gas is not continuous, but takes place only for a half-cycle of operation, or in any case in an uneven manner.
In
Another possible configuration with regenerators in parallel with the heat exchangers is shown in
For the lower values of average peripheral velocity, a law of motion will be chosen which foresees the length of angular acceleration and deceleration concentrated towards the beginning and the end of the displacement (in order to minimize the load losses).
For higher average speeds, the motion will preferably be close to a sinusoidal motion, in order to minimize the forces of inertia generated by the motion. The hot source is distributed in the exchange pipes (or is collected by them) through suitable collectors 11; the cold source is either distributed or collected by the collectors 12. Duct 5 and duct 6 are respectively the inlet and outlet ducts of the gas to be compressed.
The configuration of
In
In a further version of the proposed scheme, the mobile septum 8 is also made by an exchange matrix adapted to constitute a regenerator. In this case the flow rate passing through the exchangers 3 and 4 respectively and the matrices of the adjacent regenerators is pushed through said components as a consequence of the load loss which is generated during the motion of the septum. For better clarification, the flow rates are divided between the rotating septum and the fixed exchange components in relation to the pressure loss generated by the flow passing through them.
In
In a further embodiment of the present invention, as shown in
This embodiment has peculiar characteristics and consequent advantages. The helical arrangement releases the frontal area of the exchangers from the sectional surface of the container. For example, in the rotating configuration with flat heat exchangers/regenerators, the section of the latter can only equal to that of the cylinder. The advantage of the helical arrangement is to permit to greatly increase the frontal area of the exchange matrices, substantially by disengaging it from the area of the axial section of the container.
Moreover, the conical shape gives the system a certain elasticity in order to cope with differential thermal expansions and with the internal pressure.
This solution makes it possible to vary, during the project, the passage surface by varying the number of threads (in the direction of windings) or the angle α.
Further advantages consist in that the masses are roughly balanced around the axis and that the cone resists to the pressure better than a flat surface.
In all the embodiments of the invention, the regenerator must be able to accumulate a relatively large portion of the heat exchanged in the different phases, therefore it must have an adequate overall mass. In order to limit the overall dimensions and optimize the heat exchange, the regenerator for example can be realized as follows:
The present invention, in every one of its possible configurations, can in theory operate with any difference in temperature between the hot and cold source; obviously, the higher the temperature of the hot source and the greater the difference in temperature with the cold source, the better are the performances, in terms of efficiency and compression ratio. Regarding the cold source, this could be made of a water-cooled circuit with air cooler, therefore with water temperatures typically ranging from 10° C. to 50° C. depending on the year season and its location. The hot source could be made of waste fumes coming from an industrial process or from the exhaust of an internal combustion engine or gas turbine, therefore with temperatures typically ranging between 200° C. and 800° C.; however, as the gas/gas heat exchangers need large exchange surfaces, it is more convenient to realize the present apparatus in such a way, that an intermediate heat exchange circuit is formed between waste fumes and gas to be compressed (that is, diathermic oil or molten salt). The Author considers therefore convenient to realize the present invention so that the “hot” exchanger 3 receives at its inlet a carrier fluid at a temperature ranging between 200° C. and 450° C., as such temperatures are sufficiently high to obtain good compression ratios, but, at the same time, remain below the limits of use of the common diathermic oils present on the market.
Within these limits of temperature, the highest compression ratios attainable (Pout/Pin) are roughly comprised between 1.1 and 2.5. These are maximum values being achieved in a closed system, that is without entry or exit of gas (therefore with zero efficiency); the extraction of compressed gas leads to the achievement of lower pressures with respect to the limits set out above: the greater the required flow rate, the lower the pressure reached. According to the Author, a good compromise between discharge pressure and flow rate is obtained for compression ratios ranging between 1, 1 and 2.
The present invention therefore allows to have relatively low compression ratios, for example close to 1.3.
It is therefore particularly useful that the inlet pressure is already high, for example equal to 3 MPa, as with a ratio of 1.3, pressures close to 4 MPa can be achieved.
It is also evident that higher values of compression ratio can be achieved by arranging in series a greater number of apparatuses according to the present invention.
Due to the fact that the apparatus outputs compressed gas in a non-continuous way, the energy is related to the speed of displacement of the separation septum or regenerator (depending on the configuration considered). The Author believes that the system can preferably operate with a cycle time of between 1 and 10 seconds, for example in relation to a volume of container 2 of about 1000 liters and with a height of about 1 m. These time values consider inertias of the separation septum, thermal energies reasonably achievable from the exchangers and the regenerator, energies of fans and therefore load losses.
In addition to the embodiment of the invention, as described above, it is to be understood that numerous further variants exist. It must also be understood that such embodiments are only exemplary and limit neither the scope of the invention, nor its applications, nor its possible configurations. On the contrary, although the above description makes it possible for the skilled technician to implement the present invention at least according to an exemplary embodiment thereof, it must be understood that many variations of the described components are conceivable, without thereby departing from the scope of the invention, as defined in the attached claims, which are interpreted literally and/or according to their legal equivalents.
Number | Date | Country | Kind |
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102017000119044 | Oct 2017 | IT | national |
Filing Document | Filing Date | Country | Kind |
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PCT/IB2018/058044 | 10/17/2018 | WO | 00 |