The present invention relates to the manufacture of conglomerate stone slabs obtained from mixtures consisting of granules of stone and/or stone-like material and a bonding agent, and more specifically to the manufacture of slabs of this type which have particular colouring effects, such as so-called veining, intended to imitate as closely as possible natural stone materials.
More specifically the invention relates to a method and an apparatus for producing the slabs in question. In the description which follows reference will be made to the production of slabs with a veined effect, it being understood that reference thereto is made solely by way of a non-limiting example.
For many years so-called Bretonstone slabs have been known, this name referring to a particular manufacturing technology which essentially envisages the preparation of one or more starting mixtures comprising granules of stone and/or stone-like material with a specific particle size distribution and a bonding agent which made be of an inorganic nature (such as cement) or a synthetic resin which can be hardened (by the action of heat and/or a catalyst).
The starting mixture is distributed in the form of a layer of predetermined thickness on a temporary moulding support (such as a conveyor belt or a tray mould) and then subjected, for a predefined period of time and under a vacuum of given intensity, to the action of a press while a vibratory movement of prechosen frequency is applied to the press ram.
The resultant rough-formed slab is then transferred to the hardening stage using procedures which depend on the nature of the bonding agent.
In the continuation of the present description reference to Bretonstone slabs and/or the Bretonstone method is understood as meaning slabs obtained with the method described above.
According to an already known method for manufacturing Bretonstone slabs with a veined effect, after the step involving deposition of the starting mixture on the temporary support, colouring agent is distributed in an irregular manner on the surface of the layer of mixture and then the colouring agent is mixed up with the mixture using a spiked tool so that the colouring agent penetrates into the thickness of the mixture to a depth such that the finished slab, after the usual sizing and polishing operations, has veining similar to that of the natural stone from which the granules used in the mixture are obtained.
For further details regarding this method and the associated apparatus reference should be made to the patent IT-A-1,328,246 (corresponding to WO-A-03/027042) in the name of the same applicant, herein incorporated by reference.
This method is useful solely in the case where the finished slab must not be used such that its side edges are visible.
In fact, it has been found that, no matter how effectively mixing up of the colouring agent may be performed by means of the spiked tool, the colouring agent penetrates into the thickness of the mixture—and can therefore be seen in the finished slab—only over a section of a few millimetres, corresponding to not more than half the thickness of the finished slab.
There exist, however, certain uses of the finished slabs where the edge or side of the slab also remains visible (as, for example, in the case of so-called kitchen or bathroom tops) and, after polishing, the veining can be noted only in a thickness of a few millimetres from the top surface, while it is absent in the remainder of the edge or side to the detriment of the aesthetic characteristics of the slab laid.
According to an alternative solution, also known, for obtaining Bretonstone slabs with a veined effect, the mixture is distributed on the moulding support by means of a weighing type distributor unit with the characteristic features described in the patent IT-A-1,335,533 (corresponding to WO-A-2004/039547), herein incorporated by reference.
In this case, the starting mixture, before being loaded into the metering unit, is made to pass underneath devices which apply liquid or powder colouring or pigments agents onto its surface.
Since the mixture is loaded into the metering unit, falling freely, and then conveyed to the outlet for discharging onto the moulding support, it undergoes a certain degree of remixing which in turn results, on the one hand, in a substantial shortening of the veining and, on the other hand, in a not insignificant diffusion of the pigment in the mass of the mixture which is therefore at least partly coloured throughout the mass.
Another technology known for many years and aimed at the manufacture of slabs designed for internal and external cladding of buildings as well as the manufacture of articles similar to ceramic articles is one where granules of stone, stone-like or ceramic material, preferably in the form of sand, with a suitable particle size distribution, are mixed with the components normally used for the manufacture of ceramic materials, usually in powder form, and consisting mainly of clay or kaolin.
The resultant mixture is wetted with a bonding agent, which may be sodium silicate in aqueous form or a mixture of silicasol and polyvinyl alcohol.
With this starting mixture a layer of predetermined thickness is formed on a temporary support which is then subject to a vibrocompression step, resulting in a rough-formed slab.
The slab, after a drying step, in order to remove the water present in the mixture, undergoes a baking step at a high temperature (in the region of 1200° C.).
Below this technology, the associated method and the resultant slabs will be referred to by the generic name of “Lapitech”.
This type of slab and technology is also affected by the same problem already mentioned with regard to the Bretonstone slabs.
It is therefore desirable to provide a method and a corresponding apparatus for manufacturing slabs of the Bretonstone or Lapitech type in which the slabs have coloured veining with a length comparable to that of standard natural stone and this veining is visible throughout the thickness and therefore along the entire edge of the finished slabs.
This object is achieved with a method for manufacturing slabs in which:
at least one starting mixture comprising at least one granular product comprising stone or stone-like or ceramic material with a specific particle size distribution and a hardening bonding agent is prepared;
said at least one mixture is loaded into a metering/distributor unit comprising:
a hopper with a top mouth for loading the mixture and a bottom opening for discharging the said mixture;
an extractor belt which forms the bottom wall of said hopper;
the mixture discharged from the bottom opening of said hopper is transferred by means of said extractor belt so that, falling freely from said belt, it is distributed in the form of a layer of predetermined thickness on a temporary moulding support positioned at a lower level than said extractor belt;
the layer of mixed formed on said temporary support is subjected to vibrocompression so as to obtain a rough-formed slab;
after a drying step, where applicable, said rough-formed slab is transferred into a hardening station,
the method being characterized in that at least one colouring or pigmenting agent is distributed on the surface of the mixture being transferred by means of said extractor belt before the mixture is distributed, falling freely, onto said temporary moulding support.
Advantageously, the metering/distributor unit used in said method is that described and illustrated in Italian patent application No. TV 2004A000118 (corresponding to WO-A-2006/045728), herein incorporated by reference.
In the case where Bretonstone slabs are manufactured, the method according to the present invention envisages that: the bonding agent contained in the at least one starting mixture may be of an inorganic nature (such as cement) or a synthetic resin which can be hardened (by the action of heat and/or a catalyst); the layer formed on said temporary moulding support is subjected, for a predefined period of time and under a vacuum of given intensity, to the action of a press, while a vibratory movement of prechosen frequency is applied to the press ram; the resultant rough-formed slab is subjected to the hardening step using procedures which depend on the nature of the bonding agent.
In the case where Lapitech slabs are manufactured, where said starting mixture (as already mentioned) comprises, in addition to the granules of stone, stone-like or ceramic material with a prechosen particle size, in particular in the form of sand, also materials known per se for the manufacture of ceramic materials, such as clay and kaolin in powder form and an agent chosen from sodium silicate and silicasol together with polyvinyl alcohol, the rough-formed slab resulting from the vibrocompression step is subjected to a drying step and then a high-temperature baking step such that the clay or kaolin forms a bonding matrix for the abovementioned granules.
In the preferred embodiment of the invention said at least one colouring agent is distributed on the surface of the mixture in a non-uniform manner.
In turn the apparatus according to the invention is that described in the already cited Italian patent application No. TV2004A000118, except that it comprises as a characterizing aspect at least one device for dispensing colouring or pigmenting agent positioned at the downstream end of the extractor belt forming the bottom of the already mentioned hopper so as to dispense said colouring agent onto the surface of the layer of mixture transported by means of said extractor belt towards the position where it falls freely onto the said temporary moulding support.
It has been established that with the method and the apparatus according to the present invention the colouring agent is distributed randomly and not uniformly within the mass mixture, which falls into the temporary support producing the aforementioned veining which affects the entire thickness of the finished slab.
The colouring or pigmenting agent may be in solid form (preferably a dry powder) or liquid form and may be supplemented with or replaced by colouring or reflective granules which result in very attractive special effects in the finished product and throughout its thickness.
Considering now specifically the colouring agent dispensing device associated with the abovementioned apparatus, it may comprise a plurality of devices, namely one for each colouring agent, which are controlled independently of each other as regards the start and end of the dispensing operation, which may take place continuously or intermittently.
In the case where there is a plurality of dispensing devices, they may be mounted transversely with respect to the direction of feeding of the extractor belt which transports the layer of mixture discharged by the metering/distributor unit, so as to cover the entire width of the mixture layer.
Alternatively, it is possible to envisage a smaller number of dispensing devices mounted on a cross-member fixed at the top and transversely with respect to the extractor belt for the layer of mixture and movable along the said cross-member.
The invention will now be described with regard to the accompanying drawings which show, by way of a non-limiting example, two variations of embodiment of the apparatus according to the invention.
More specifically:
In brief, the apparatus comprises a frame 10 which supports a surface 12 on which a temporary moulding support 14 is placed for each operating cycle, on which support a layer of mixture 18, supplied by a metering/distributor device denoted overall by the referenced above 20, is deposited in a free-falling manner.
The mixture distributor 20 in turn comprises a hopper 22 with a top mouth 24 for loading fresh mixture, a shaped or conveying wall 26 with a profile curved towards the inside of the hopper 22 and a mixture discharge opening 28 at the end of said shaped wall 26.
An extractor belt 30, positioned underneath said hopper 22, forms with its upper surface 30 the bottom of said hopper.
The belt 30 is used to convey and deposit a uniform layer of said mixture, after it has flowed inside the hopper 22 and passed out through said discharge opening 28, on said temporary support 14 which is positioned at a lower level than said extractor belt. At the same time a relative movement of said hopper 22 and said support 14 is maintained so that the layer of mixture distributed on said support is uniform.
In order to ensure the relative movement of hopper 22 and temporary support 14, the metering/distributor device 20 is mounted on a carriage denoted overall by the reference number 34 and movable by means of roller wheels parallel to the surface 12 of the apparatus.
From
For further details regarding this apparatus reference should be made to the already mentioned Italian patent application No. TV2004A000118.
According to the invention, at least one device for dispensing colouring agent, denoted by the general reference number 40, is positioned at the downstream end of the extractor belt 30, preferably downstream of the discharge opening 28 of the hopper 22.
In this connection it should be noted that the colouring agent may be dispensed at any point on the upper surface 32 of the extractor belt 30, except for the zone immediately underneath the hopper 22.
In particular, in accordance with the embodiment shown in
As regards the structure of the colouring agent dispensers, it is preferably that described in the aforementioned Italian patent application TV2004A000118 and illustrated in
The surface of the mixture, before leaving the extractor belt 30, is therefore sprinkled with colouring material in a manner which depends on the operating mode of the dispensing nozzle. In fact, if the dispensing nozzle is operated intermittently and at irregular time intervals, it is evident that the distribution of colouring agent on the surface of the mixture will not be homogeneous and pre-ordered.
Since the mixture with colouring agent is then transferred by means of a free-falling action onto the temporary moulding support and since the mixture when falling produces coloured lumps on the surface, the colouring agent, without uniformly colouring the mixture, is able to produce during the subsequent vibrocompression step colouring effects which affect the entire thickness of the manufactured article, similar to the veining of natural stones.
If, on the other hand, the mixture were to be uniformly coloured, the desired object would not be achieved, namely the formation of veining imitating that of standard natural stone.
At the same time, as demonstrated by experimental tests, the coloured zones affect the entire thickness of the mixture, so that the predefined object of the invention is fully achieved.
The variant shown in
It is evident that a solution midway between those described above is possible, namely one where a smaller number of dispensing devices 40 are mounted on the cross-member 36, with the each of them designed so that it is movable along the cross-member over a limited distance, so as to ensure more correct distribution of colouring agent on the surface of the mixture which is transported by the upper surface 32 of the extractor belt 30 towards the temporary support 14.
The product obtained fully satisfies the aforementioned requirements and has the appearance shown in
Finally, it should be noted that with the present invention a further advantage is achieved, mainly that of avoiding the need for any further operation on the mixture already deposited on the temporary support (for example using spiked tools) in order to ensure greater distribution of the colouring agent, with the obvious advantage in terms of simplification of the apparatus and the operating cycle.
It is understood that conceptually and mechanically equivalent modifications and variations are possible and may be envisaged without departing from the scope of the present invention as defined in the accompanying claims.
Number | Date | Country | Kind |
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TV2007A000126 | Jul 2007 | IT | national |
This is a continuation of application Ser. No. 12/669,121 filed Jan. 14, 2010, which is a 35 U.S.C. 371 national stage filing from International Application No.PCT/EP2008/058682, filed Jul. 4, 2008, which claims priority to Italian Application No. TV2007A000126, filed Jul. 16, 2007, the teachings of which are incorporated herein by reference.
Number | Name | Date | Kind |
---|---|---|---|
1448203 | Cumfer et al. | Mar 1923 | A |
1829187 | Piessevaux | Oct 1931 | A |
2098246 | Jarrier | Nov 1937 | A |
2200773 | Finne | May 1940 | A |
2323864 | Weyandt | Jul 1943 | A |
3426730 | Lawson et al. | Feb 1969 | A |
3663137 | Haas et al. | May 1972 | A |
3809516 | Komaki | May 1974 | A |
3953623 | Das | Apr 1976 | A |
4204820 | Toncelli | May 1980 | A |
4557882 | Arnold | Dec 1985 | A |
4569920 | Smith-Johannsen | Feb 1986 | A |
4617060 | Dreibelbis | Oct 1986 | A |
4698010 | Toncelli | Oct 1987 | A |
4783435 | Dreibelbis | Nov 1988 | A |
4937394 | Dreibelbis | Jun 1990 | A |
5013523 | Hata et al. | May 1991 | A |
5031546 | Amos et al. | Jul 1991 | A |
5174823 | Dario | Dec 1992 | A |
5264168 | Toncelli et al. | Nov 1993 | A |
5314090 | Alexander | May 1994 | A |
5469971 | Chilton et al. | Nov 1995 | A |
5477307 | Bergen et al. | Dec 1995 | A |
5514399 | Cordera et al. | May 1996 | A |
5820802 | Oberoi | Oct 1998 | A |
5914187 | Naruse et al. | Jun 1999 | A |
5922254 | Ebert et al. | Jul 1999 | A |
5942205 | Murata et al. | Aug 1999 | A |
6355191 | Toncelli | Mar 2002 | B1 |
6387307 | Bossetti | May 2002 | B1 |
6461552 | Geiger | Oct 2002 | B1 |
6713015 | Toncelli | Mar 2004 | B1 |
7487892 | Hirsch | Feb 2009 | B1 |
7550026 | Hayakawa | Jun 2009 | B2 |
7550106 | Toncelli | Jun 2009 | B2 |
7819346 | Perkes | Oct 2010 | B2 |
20040032044 | Toncelli | Feb 2004 | A1 |
20040121082 | Dunnous | Jun 2004 | A1 |
20050122833 | Bailey | Jun 2005 | A1 |
20050147806 | Toncelli | Jul 2005 | A1 |
20050238752 | Toncelli | Oct 2005 | A1 |
20080079185 | Jamrussamee et al. | Apr 2008 | A1 |
20080187742 | Toncelli | Aug 2008 | A1 |
20080280750 | Liu | Nov 2008 | A1 |
20080315448 | Cruz | Dec 2008 | A1 |
20090101790 | Toncelli | Apr 2009 | A1 |
20100052225 | Toncelli | Mar 2010 | A1 |
20100119722 | Tarozzi | May 2010 | A1 |
20100197005 | Belouski et al. | Aug 2010 | A1 |
20110003366 | Zeikus | Jan 2011 | A1 |
20110318483 | Toncelli | Dec 2011 | A1 |
Number | Date | Country |
---|---|---|
1522987 | Aug 2004 | CN |
2784164 | May 2006 | CN |
378275 | Jul 1990 | EP |
0962294 | Dec 1999 | EP |
1510314 | Mar 2005 | EP |
1787779 | May 2007 | EP |
2485067 | Dec 1981 | FR |
2310161 | Aug 1997 | GB |
1242777 | May 1994 | IT |
TV940091 | Jan 1996 | IT |
1293176 | Feb 1999 | IT |
S57194034 | Nov 1982 | JP |
S6443336 | Feb 1989 | JP |
2002348722 | Dec 2002 | JP |
2283818 | Jul 2006 | RU |
9615888 | May 1996 | WO |
9846543 | Oct 1998 | WO |
0117741 | Mar 2001 | WO |
2003027042 | Apr 2003 | WO |
2004022295 | Mar 2004 | WO |
2004039547 | May 2004 | WO |
2006045728 | May 2006 | WO |
2006048438 | May 2006 | WO |
2006122892 | Nov 2006 | WO |
2007009860 | Jan 2007 | WO |
2009010406 | Jan 2009 | WO |
Entry |
---|
Abdullah, Mohd Mustafa Al Bakri, et al. “Concrete Ceramic Waste Slab (CCWS).” Journal of Engineering Research and Ed Journal of Engineering Research and Education, (2006) vol. 3, pp. 139-145; available at http://dspace.unimap.edu.my/dspace/handle/123456789/2032. |
International Preliminary Report on Patentability dated Sep. 16, 2009 for PCT/EP2008/058682, 11 pages. |
International Search Report dated Feb. 3, 2009 for PCT/EP2008/058682, 4 pages. |
International Search Report dated Mar. 17, 2009 for PCT/IB2008/050966, 3 pages. |
International Search Report dated Jun. 11, 2010 for PCT/IB2008/050998, 4 pages. |
Written Opinion dated Feb. 3, 2009 for PCT/EP2008/058682, 8 pages. |
Written Opinion dated Mar. 17, 2009 for PCT/IB2008/050966, 4 pages. |
Written Opinion dated Jun. 11, 2010 for PCT/IB2008/050998, 7 pages. |
Number | Date | Country | |
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20160016328 A1 | Jan 2016 | US |
Number | Date | Country | |
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Parent | 12669121 | US | |
Child | 14868920 | US |