APPARATUS FOR SUPPLYING AIR TO FUEL CELL

BRIEF DESCRIPTION OF THE DRAWINGS

Referring now to the attached drawings which form a part of this original disclosure:

FIG. 1A is a schematic cross sectional view illustrating an air supplier in accordance with a first preferred embodiment of the present invention;

FIG. 1B is a schematic cross sectional view, taken alone a B-B line, of FIG. 1A;

FIG. 2 is a block diagram illustrating a fuel cell module that includes the air supplier of FIGS. 1A and 1B in accordance with the first preferred embodiment of the present invention;

FIG. 3 is a schematic view illustrating an air supplier in comparative example 1;

FIG. 4 is a schematic view illustrating an air supplier in comparative example 2;

FIG. 5 is a schematic view illustrating an air supplier in comparative example 3;

FIG. 6 is a diagram illustrating variations of sound pressure levels [dB] over octave band center frequency [Hz] for the air suppliers in the embodiment of the present invention and Comparative Examples 1, 2 and 3;

FIG. 7 is a diagram illustrating variation in temperature of motor over operating time for the air suppliers in the embodiment of the present invention and Comparative Example 3; and

FIG. 8 is a schematic cross sectional view illustrating a modified air supplier in accordance with a second preferred embodiment of the present invention.

DETAILED DESCRIPTION OF THE INVENTION

Selected embodiments of the present invention will now be described with reference to the drawings. It will be apparent to those skilled in the art from this disclosure that the following descriptions of the embodiments of the present invention are provided for illustration only and not for the purpose of limiting the invention as defined by the appended claims and their equivalents.

First Embodiment

FIG. 1A is a schematic cross sectional view illustrating an air supplier in accordance with a first preferred embodiment of the present invention. FIG. 1B is a schematic cross sectional view, taken alone a B-B line, of FIG. 1A. FIG. 2 is a block diagram illustrating a fuel cell module that includes the air supplier of FIGS. 1A and 1B in accordance with the first preferred embodiment of the present invention.

With reference to FIG. 2, a fuel cell module 10 may include, but is not limited to, a fuel cell 11, an air supplier 20, and a fuel supplier 50. The air supplier 20 is configured to supply an oxygen-containing air to the fuel cell 11. The fuel supplier 50 is configured to supply a fuel to the fuel cell 11.

In some cases, the fuel cell 11 can be realized by a direct methanol fuel cell (DMFC) which is configured to cause a reaction between methanol as a fuel and oxygen in the air, thereby generating power. In other cases, the fuel cell 11 can also be realized by a stack of plural direct methanol fuel cells (DMFCs).

The fuel cell 11 may include, but is not limited to, a fuel electrode 12 as an anode, an air electrode 13 as a cathode, and an electrolyte membrane 14. The electrolyte membrane 14 is interposed between the fuel electrode 12 and the air electrode 13. The fuel supplier 50 can be configured to supply a methanol solution as a fuel to a fuel electrode side in which the fuel electrode 12 as the anode is provided. The air supplier 20 can be configured to supply an oxygen-containing air to an air electrode in which the air electrode 13 as the cathode is provided. For convenience, the fuel electrode side will hereinafter be referred to as the fuel electrode side 12, and the air electrode side will hereinafter be referred to as the air electrode side 13.

The fuel electrode side 12 generates a reaction product of carbon dioxide. The air electrode side 13 generates another reaction product of waste water. Carbon dioxide is discharged from the fuel electrode side 12. Waste water is discharged from the air electrode side 13. The fuel electrode 12 and the air electrode 13 are connected to each other through a load 15.

The direct methanol fuel cell (DMFC) 11 is designed to cause the following reactions.

Fuel Electrode: CH₃OH+H₂O→CO₂+6H⁺+6e⁻

Air Electrode: O₂+4H⁺+4e⁻→2H₂O

DMFC: 2CH₃OH+3O₂→2CO₂+4H₂O

The air supplier 20 can be configured to take an oxygen containing air from the atmosphere and to supply the oxygen containing air onto the air electrode 13.

In some cases, the fuel supplier 50 may include, but is not limited to, a fuel tank 51, a fuel pump 52, and a first fuel supply path 53, and a second fuel supply path 54. The first fuel supply path 53 communicates between the fuel tank 51 and the fuel pump 52. The first fuel supply path 53 is configured to allow the fuel to be fed from the fuel tank 51 to the fuel pump 52. The second fuel supply path 54 communicates between the fuel pump 52 and the fuel electrode side 12. The second fuel supply path 54 is configured to allow the fuel to be fed from the fuel pump 52 to the fuel electrode side 12. The fuel pump 52 has an intake port which is connected through the first fuel supply path 53 to the fuel tank 51. The fuel pump 52 has a discharge port which is connected through the second fuel supply path 54 to the fuel electrode side 12. The fuel tank 51 stores the fuel such as the methanol solution. The fuel pump 52 can be driven to cause that the fuel is fed from the fuel tank 51 through the first and second fuel supply paths 53 and 54 to the fuel electrode side 12.

The air supplier 20 is connected through an air supply path 29 to the air electrode side 13. The air supply path 29 communicates between the air supplier 20 and the air electrode side 13. The air supply path 29 is configured to allow the oxygen containing air to be fed from the air supplier 20 to the air electrode side 13. As shown in FIG. 2, the air supplier 20 may include, but is not limited to, a housing 21, a motor 22, a pump 23, and an intake unit 40.

The configuration of the air supplier 20 is well illustrated in FIGS. 1A and 1B. In some cases, the housing 21 can be formed by a pair of outer and inner casings 24 and 25. The outer and inner casings 24 and 25 can also be realized by a metal such as stainless. The housing 21 can preferably be configured to provide sound insulation. The outer and inner casings 24 and 25 are separated by a gap from each other. In light of sound insulation, the gap between the outer and inner casings 24 and 25 may be kept in a vacuum. In other cases, the gap between the outer and inner casings 24 and 25 can be filled with a gas such as an air or an inert gas. In still other cases, the gap can be filled with a sound absorbing material such as glass wool, an open-cell foam, or an urethane foam. The housing 21 forms a chamber 26 which contains the motor 22 and the pump 23.

The motor 22 and the pump 23 are contained in the chamber 26 of the housing 21. In some cases, the motor 22 can be realized by a DC electric motor or an AC electric motor. The pump 23 is connected to the motor 22 so that the pump 23 is driven by the motor 22. The pump 23 has an intake port 27 and a discharge port 28. The intake port 27 is open to the chamber 26, thereby allowing the pump 23 to intake the air in the chamber 26. The pump 23 pressurizes the intake air. The discharge port 28 is connected to the air supply path 29. The air supply path 29 is further connected to the air electrode side 13 of the fuel cell 11. The air supply path 29 connects the discharge port 28 and the air electrode side 13. The pressured air is discharged from the discharge port 28 and then fed through the air supply path 29 to the air electrode side 13 of the fuel cell 11.

The intake unit 40 is coupled to the housing 21. In some case, the intake unit 40 can be disposed so that the center axis of the intake unit 40 crosses the center axis of the motor 22. As illustrated in FIGS. 1A and 1B, the intake unit 40 can be disposed over the motor 22, provided that the center axis of the intake unit 40 crosses the center axis of the motor 22. It is possible as modifications that the intake unit 40 can be disposed at other position as along as the center axis of the intake unit 40 crosses the center axis of the motor 22. The intake unit 40 can be disposed at a side position, where the center axis of the intake unit 40 crosses the center axis of the motor 22. Preferably, the motor 22 is positioned so that the center axis of the motor 22 is aligned to the center axis of the intake unit 40.

The intake unit 40 has opposing first and second sides. The intake unit 40 may further include, but is not limited to, an intake port 41, a connector 42, and a silencer 43. The intake port 41 is positioned in the first sides. The connector 42 is positioned in the second side. The silencer 43 is interposed between the intake port 41 and the connector 42. The intake port 41 has an air filter that removes foreign matter from the intake air. The intake port 41 has opposing first and second sides. The first side is open to the outside atmosphere. The second side is connected to the silencer 43.

The connector 42 connects the silencer 43 and the chamber 26. The connector 42 has an air passage 44 which is open to the inside atmosphere in the chamber 26. The intake unit 40 has the intake port 41 in the first side and the connector 42 in the second side. The intake port 41 is open to the outside atmosphere. The connector 42 has the air passage 44 which is open to the inside atmosphere in the chamber 26. The oxygen containing air is taken from the outside atmosphere and fed through the silencer 43 and the air passage 44 to the inside atmosphere in the chamber 26.

The connector 42 is aligned to the center axis of the intake unit 40. As described above, the intake unit 40 may preferably be disposed so that the motor 22 is positioned on the extended line that is aligned to the center axis of the intake unit 40. In this case, the motor 22 is positioned on the extended line of the connector 42. The oxygen containing air that is fed by the intake unit 40 is supplied to the chamber 26 while the oxygen containing air is also blown to the motor 22. The oxygen containing air is further flown through the chamber 26 toward the intake port 27 of the pump 23. The oxygen containing air is then suctioned by the pump 23 and fed through the air supply path 29 to the air electrode side 13 of the fuel cell 11.

The oxygen containing air is supplied by the intake unit 40 to the chamber 26, while the oxygen containing air is blown to the motor 22. The side wall of the motor 22 is likely to be heated. Blowing the oxygen containing air to the side wall of the motor 22 may effectively cool the pump 23.

It is possible as a modification that the center axis of the intake unit 40 is aligned to the center axis of the motor 22 so that the intake unit 40 supplies the oxygen containing air to the chamber 26, while the oxygen containing air is blown to the motor 22, thereby cooling the motor 22.

In some cases, the silencer 43 may be realized by a sound silencer or a sound absorbing silencer. The silencer 43 may have a tube member 45 and a sound absorbing material 46. The tube member 45 can be realized by a cylindrically shaped member that is made of a metal or a resin. The tube member 45 provides a sound absorbing air passage that allows the oxygen containing air to flow from the intake port 41 to the air passage 44. The sound absorbing air passage communicates with the air passage 44 of the connector 42. In some cases, the tube member 45 may have a cylindrically shaped side wall which has openings 47. The shape of the openings 47 may be, but is not limited to, a circle. The sound absorbing material 46 can be provided around the cylindrically shaped side wall of the tube member 45. The sound absorbing material 46 can plug or seal the openings 47. The sound absorbing material 46 can be realized by glass wool, or a porous member. In some cases, the porous material may be a fiber porous material such as a dust-proof bonded fabric. In other cases, the porous material may be a resin foam material. The sound absorbing material 46, which is disposed around the cylindrically shaped side wall with the openings 47 of the tube member 45, can absorb suction noise that is generated by the flow of the oxygen containing air in the sound absorbing air passage of the tube member 45.

The housing 21 can preferably be configured to perform another silencer, for example, an expansion silencer. The expansion silencer is a silencer that reduces the sound volume by a combination of an expanded passage with a narrow passage through which a sound wave propagates. The amount of sound volume reduction depends on a ratio in sectional area of the expanded passage to the narrow passage. The frequency of a sound that is to be reduced by the expansion silencer depends on the length of the expanded passage. The length of the expanded passage can be equal to the real number times of the specific frequency of a sound that is to be reduced. For example, the pump 23 may be designed to render the discharge port 28 discharge the air about 400 times per second. The pump 23 may generates a discharge sound of a frequency of 400 Hz. Assuming that the sound velocity is about 340 m/sec. at room temperature, the discharge sound generated from the pump 23 has a wavelength λ which is given by 340/400≈0.85 m. The total length L of the housing 21 can be set one quarter (¼) of the wavelength λ of the discharge sound that is generated by the pump 23. In this case, the housing 21 performs as an expansion silencer that reduces the discharge sound generated by the pump 23. For example, the total length L of the housing 21 can preferably be set 0.85/4≈0.21 m.

Performances of the air supplier 20 of this embodiment will be evaluated. For evaluation on the performances of the air supplier 20, the following three air suppliers were prepared.

COMPARATIVE EXAMPLE 1

FIG. 3 is a schematic view illustrating an air supplier in comparative example 1. An air supplier 60 includes a motor 62 and a pump 63, both of which are the same as the above-described motor 22 and pump 23 of the air supplier 20. The air supplier 60 also includes an intake unit that further includes an intake port 65 with an air filter, and a connector 66 that communicates the intake port 65 to the pump 63. The intake unit does not include any silencer such as the above-described silencer 43 of the intake unit 40. The air supplier 60 has no housing, so that the motor 62 and the pump 63 are exposed to the outside atmosphere. The motor 62 is connected to the pump 63 to drive the pump 63. The pump 63 is configured to feed an oxygen containing air from the outside atmosphere through the connector 66 to the air electrode side 13 of the fuel cell 11.

COMPARATIVE EXAMPLE 2

FIG. 4 is a schematic view illustrating an air supplier in comparative example 2. An air supplier 70 includes a housing 71, a motor 72, and a pump 73. The motor 72 and the pump 73 are the same as the above-described motor 22 and pump 23 of the air supplier 20. The air supplier 70 also includes an intake unit that further includes an intake port 75 with an air filter, and a connector 76 that communicates the intake port 75 to the pump 73. The intake unit does not include any silencer such as the above-described silencer 43 of the intake unit 40. The motor 72 is connected to the pump 73 to drive the pump 73. The pump 73 is configured to feed an oxygen containing air from the outside atmosphere through the connector 76 to the air electrode side 13 of the fuel cell 11. The motor 72 and the pump 73 are contained in the housing 71. The housing 71 is structurally the same as the above-describe housing 21 of the air supplier 20. Namely, the housing 71 can be formed by a pair of outer and inner casings. However, the housing 71 has the total length in the longitudinal direction that is not regulated in light of the wavelength of a sound noise that is to be reduced. In contrast, the above-described housing 21 is designed to have the total length in the longitudinal direction which corresponds to one quarter of the wavelength of a sound noise that is to be reduced.

COMPARATIVE EXAMPLE 3

FIG. 5 is a schematic view illustrating an air supplier in comparative example 3. An air supplier 80 includes a housing 81, a motor 82, and a pump 83. The motor 82 and the pump 83 are the same as the above-described motor 22 and pump 23 of the air supplier 20. The air supplier 80 also includes an intake unit that further includes an intake port 85 with an air filter, a silencer 88, and a connector 86 that communicates the intake port 85 to the pump 83. The silencer 88 is interposed between the intake port 85 and the connector 86. The silencer 88 of the intake unit is the same as the above-described silencer 43 of the intake unit 40. The motor 82 is connected to the pump 83 to drive the pump 83. The pump 83 is configured to feed an oxygen containing air from the outside atmosphere through the connector 86 to the air electrode side 13 of the fuel cell 11. The motor 82 and the pump 83 are contained in the housing 81. The housing 81 is structurally the same as the above-describe housing 21 of the air supplier 20. Namely, the housing 81 can be formed by a pair of outer and inner casings. However, the housing 81 has the total length in the longitudinal direction that is not regulated in light of the wavelength of a sound noise that is to be reduced. In contrast, the above-described housing 21 is designed to have the total length in the longitudinal direction which corresponds to one quarter of the wavelength of a sound noise that is to be reduced.

Evaluations on Sound insulation and Cooling:
(Sound Insulation Performance)

The air supplier 20 of the embodiment of the present invention is compared to each of the air suppliers 60, 70 and 80 in Comparative Examples 1, 2 and 3, in light of the sound insulation performance and the cooling performance.

Evaluation on the sound insulation performance was made as follow. An audio meter was used to compare in the sound insulation performance between the air supplier 20 and each of the air suppliers 60, 70 and 80. The audiometer was positioned to be distanced by 1 meter from each of the pumps 23, 63, 73, and 83 of the air suppliers 20, 60, 70 and 80. The audiometer was operated to measure the sound level. The measured sound level was then corrected by A-characteristics (see JIS: C-1505, C1502), thereby obtaining the corrected sound level. The correction with A-characteristics is such that the sound pressure level for each octave band is corrected with the A-characteristics over the entirety of an audible band. The corrected sound level of the air supplier 20 was 39 dB(A). The corrected sound level of the air supplier 60 was 70 dB(A). The corrected sound level of the air supplier 70 was 50 dB(A). The corrected sound level of the air supplier 80 was 45 dB(A). The air supplier 20 is most superior as compared to the other air suppliers 60, 70 and 80 in light of the sound insulation performance.

FIG. 6 is a diagram illustrating variations of sound pressure levels [dB] over octave band center frequency [Hz] for the air suppliers 20, 60, 70 and 80 in the embodiment of the present invention and Comparative Examples 1, 2, and 3. The sound insulation performance of the air supplier 20 in accordance with the embodiment of the present invention will be evaluated in detail with comparing the other air suppliers 60, 70 and 80 in Comparative Examples 1, 2, and 3. FIG. 6 demonstrates that the air supplier 20 of the embodiment of the present invention realizes remarkable reduction of the sound pressure level at 400 [Hz] as compared to the other air suppliers 60, 70 and 80 in Comparative Examples 1, 2, and 3. This demonstrates that the housing 21 performs the expansion silencer that effectively reduces the discharge sound noise that is generated by the pump 23.

The air supplier 20 of the embodiment of the present invention is also superior in the sound insulation performance in another frequency band higher than 1000 [Hz] as compared to the air suppliers 60 and 70 in Comparative Examples 1 and 2. The sound noise that is generated by the pump 23 has the frequency in the frequency band higher than 1000 [Hz]. The silencers 43 and 88 are effective to reduce the sound pressure level in the frequency band higher than 1000 [Hz]. Namely, the silencers 43 and 88 are effective to reduce the sound noises that are generated by the pumps 23 and 83. The air supplier 20 of the embodiment of the present invention is configured to effectively reduce the sound noise that is generated by the pump 23.

In addition, the air supplier 20 of the embodiment of the present invention is also superior in the sound insulation performance at 400 [Hz] as compared to the air suppliers 60, 70 and 80 in Comparative Examples 1, 2 and 3. Further, the air supplier 20 of the embodiment of the present invention is superior in the sound insulation performance in a frequency band higher than 400 [Hz] as compared to the air supplier 60 in Comparative Example 1.

(Cooling Performance)

Evaluation on the cooling performance was made as follow. The air supplier 20 in accordance with the embodiment of the present invention was evaluated on the cooling performance as compared to the air supplier 80 of Comparative Example 3. The air supplier 60 in Comparative Example 1 has no housing or silencer so that the motor 62 and the pump 63 are exposed to the outside atmosphere. The air supplier 60 free of any housing and any silencer in Comparative Example 1 is superior in the cooling performance, but is poor in the sound insulation performance. The air supplier 70 in Comparative Example 2 has the housing 71 and no silencer so that the motor 72 and the pump 73 are contained in the housing 71. However, the housing 71 is not designed to perform as the expansion silencer. The air supplier 70 free of any silencer in Comparative Example 2 is poor in the cooling performance and the sound insulation performance. The air supplier 80 in Comparative Example 3 has the housing 81 or the silencer 88 so that the motor 82 and the pump 83 are contained in the housing 81. However, the housing 81 is not designed to perform as the expansion silencer. The air supplier 80 with the housing 81 and the silencer 88 in Comparative Example 3 is poor in the cooling performance, but is not superior in the sound insulation performance. Thus, the air supplier 20 in accordance with the embodiment of the present invention was evaluated on the cooling performance as compared to the air supplier 80 of Comparative Example 3.

FIG. 7 is a diagram illustrating variation in temperature of motor over operating time for the air suppliers 20 and 80 in the embodiment of the present invention and Comparative Example 3. A temperature sensor was used to measure the temperature of the motor 22 or 82 of the air supplier 20 or 80. The temperature sensor was positioned under the motor 22 or 82. The oxygen containing air is supplied into the housing 21 or 81 from the air passage 44 or the connector 86. The temperature sensor does not receive the blow of the oxygen containing air from the air passage 44 or the connector 86. The temperature sensor is not illustrated in FIGS. 1A, 1B and 5.

As shown in FIG. 7, the pump 83 of the air supplier 80 of Comparative Example 3 started it operation and stopped after about 30 minutes by the stop of the motor 82 due to the overheat of the motor 82. As described above, the motor 82 is disposed in the housing 81. The cooling of the motor 82 is insufficient, thereby allowing the motor 82 to be overheated to stop its driving operation, resulting in the stop of the pumping operation of the pump 83.

As described above, the air supplier 20 of the embodiment of the present invention is configured such that the oxygen containing air is fed through the intake unit 40 and is blown directly to the motor 22 that drives the pump 23, thereby supplying the oxygen containing air to the chamber 26 of the housing 21, while blowing the oxygen containing air directly to the motor 22 to cool the motor 22. The motor 22 is cooled by the direct blow of the oxygen containing air from the intake unit 40 during the driving operation of the motor 22. Cooling the motor 22 keeps the temperature of the motor 22 at about 50° C., without overheating the motor 22, even the motor 22 is continued to drive the pump 23. As shown in FIG. 7, the pump 23 started its operation and forcibly stopped its operation after 130 minutes, so that the oxygen containing air is not blown to the motor 22 and the motor 22 is not cooled. As a result, the temperature of the motor 22 is slightly increased even after the motor 22 has been stopped. This means that blowing the oxygen containing air directly to the motor 22 cools the motor 22.

The air supplier 20 of the embodiment of the present application is configured such that the motor 22 is cooled by the direct blow of the oxygen containing air, while the oxygen containing air is supplied to the chamber 26 of the housing 21. The motor 22 and the pump 23 are disposed in the housing 21 in order to shield the sound noises that are generated by the motor 22 and the pump 23. The air supplier 20 of the embodiment of the present application is configured to cool the motor 22 and to shield the sound noises that have been generated by the motor 22 and the pump 23. Namely, the air supplier 20 is configured to prevent overheat of the motor 22 and also prevent the leakage of the sound noises that have been generated by the motor 22 and the pump 23.

The overall dimension L of the housing 21 in its longitudinal direction is decided based on the frequency of the sound noise such as discharge sound that is generated by the pump 23, so that the housing 21 performs as the expansion silencer. The housing 21 can reduce the sound of a specific frequency that is generated by the pump 23. Further, the silencer 43 is disposed on the intake unit 40 that introduces the air into the chamber 26 of the housing 21. The silencer 43 efficiently reduces the suction sound. Namely, the discharge sound noise of a particular frequency that is generated by the pump is reduced by the housing 21 that performs as the expansion silencer, while the suction sound noise as generated at the intake unit 40 is reduced by the silencer 43, thereby reducing the sound noises of the air supplier 20.

Modification:

In accordance with the above-described embodiment, the air supplier 20 is configured to cause that the air that is fed by the intake unit 40 is blown to the motor 22. For example, the intake unit 40 is disposed so that the center axis of the intake unit 40 crosses the center axis of the motor 22. It is, however, possible to modify the positional relation between the motor 22 and the intake unit 40 as long as the air that is fed by the intake unit 40 is blown to the motor 22. FIG. 8 is a schematic cross sectional view illustrating a modified air supplier in accordance with a second preferred embodiment of the present invention. The modified air supplier 20 of FIG. 8 is different from the air supplier 20 of FIGS. 1A and 1B as follows. The intake unit 40 has a pipe 31 which connects between the connector 42 and the silencer 43. The pipe 31 provides an air passage and communicates between the sound absorbing air passage of the tube member 45 and the air passage 44 of the connector 42 which is open to the inside atmosphere in the chamber 26. The pipe 31 allows that the air that is fed by the intake unit 40 is blown to the motor 22, even the center axis of the tube member 45 is displaced from the motor 22, and the center axis of the connector 42 extends toward the motor 22. In other words, the pipe 31 increases the flexibility in positioning the intake unit 40 relative to the housing 21, while the air that is fed by the intake unit 40 is blown to the motor 22. In some cases, the pipe 31 may be flexible. The motor 22 can be modified to have a heat radiator. A typical example of the heat radiator can include, but is not limited to, one or more radiator fins.

As used herein, the following directional terms “forward, rearward, above, downward, vertical, horizontal, below, and transverse” as well as any other similar directional terms refer to those directions of an apparatus equipped with the present invention. Accordingly, these terms, as utilized to describe the present invention should be interpreted relative to an apparatus equipped with the present invention.

The terms of degree such as “substantially,” “about,” and “approximately” as used herein mean a reasonable amount of deviation of the modified term such that the end result is not significantly changed. For example, these terms can be construed as including a deviation of at least ±5 percents of the modified term if this deviation would not negate the meaning of the word it modifies.

While preferred embodiments of the invention have been described and illustrated above, it should be understood that these are exemplary of the invention and are not to be considered as limiting. Additions, omissions, substitutions, and other modifications can be made without departing from the spirit or scope of the present invention. Accordingly, the invention is not to be considered as being limited by the foregoing description, and is only limited by the scope of the appended claims.

APPARATUS FOR SUPPLYING AIR TO FUEL CELL

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Priority Claims (1)