Patent Application
20220339700
The present invention relates to an apparatus of manufacturing an inorganic material and a method of manufacturing an inorganic material.
Recently, as a solid electrolyte material of a lithium battery, a sulfide solid electrolyte material may be used.
Patent Document 1 describes a method of manufacturing a sulfide solid electrolyte material. In this method, lithium sulfide (Li2S) powder, diphosphorus pentasulfide (P2S5) powder, and red phosphorus (P) powder are mixed with each other in a glove box in an argon atmosphere to obtain a raw material composition. Next, using a planetary ball mill machine, mechanical milling is conducted on the raw material composition to obtain an amorphous ion conductive material. Next, this ion conductive material is heated to obtain a sulfide solid electrolyte material.
In the manufacturing of the inorganic material such as a sulfide solid electrolyte material, mechanical milling is conducted on plural kinds of inorganic compounds using a crusher such as a planetary ball mill machine. The mechanical milling may be required to reduce contact between the inorganic compound and air.
One example of the objects of the present invention is to reduce contact between an inorganic compound and air during mechanical milling. Another object of the present invention will be clarified from the description of the present specification.
According to one aspect of the present invention,
there is provided an apparatus of manufacturing an inorganic material, the apparatus including:
a blower blowing inert gas;
a crusher repeating vitrifying plural kinds of inorganic compounds to be the inorganic material by mechanical energy and blowing up the plural kinds of vitrified inorganic compounds by the inert gas blown from the blower;
a first collector into which at least some of the plural kinds of inorganic compounds blown up by the inert gas enters, the first collector returning the at least some of the plural kinds of inorganic compounds to the crusher; and
a system circulating the inert gas from the blower through the crusher and the first collector to the blower.
According to another aspect of the present invention,
there is provided a method of manufacturing an inorganic material, the method including:
by a blower, blowing inert gas;
by a crusher, repeating vitrifying plural kinds of inorganic compounds to be the inorganic material by mechanical energy and blowing up the plural kinds of vitrified inorganic compounds by the inert gas blown from the blower;
returning from a first collector to the crusher at least some of the plural kinds of inorganic compounds blown up by the inert gas and entering into the first collector; and
circulating the inert gas from the blower through the crusher and the first collector to the blower.
In the above-described aspects of the present invention, contact between an inorganic compound and air during mechanical milling can be reduced.
Hereinafter, an embodiment of the present invention will be described using the drawings. In all of the drawings, the same components will be represented by the same reference numerals, and the description thereof will not be repeated.
The summary of the apparatus 10 will be described using
A structure of the apparatus 10 will be described using
The apparatus 10 includes the blower 100, the buffer tank 110, the crusher 200, the first collector 300, a first container 310, a second collector 400, a second container 410, a decompressor 500, the pipe Pa, a plurality of pipes Pb, the pipe Pc (second pipe), a pipe Pd, a pipe Pe (first pipe), a pipe Pf (third pipe), a pipe Pg, a pipe Ph (fourth pipe), the pipe Pi, a pipe Pj, a pipe Pk, a pipe Pl, a pipe Pm, a pipe Pn, a pipe Po, a valve Va1, a plurality of valves Vb1, a valve Vc1, a valve Vc2 (second valve), a valve Vc3, a valve Vd1, a valve Ve1 (first valve), a valve Ve2, a valve Vf1 (third valve), a valve Vg1, a valve Vh1, a valve Vh2, a valve Vi1, a valve Vi2, a valve Vj1, a valve Vk1, a valve Vl1, a valve Vm1, a valve Vn1, a valve vo1, a line Le (first line), a line Lh (second line), and an exhaust duct D.
The pipe Pa communicates to a gas outlet 104 of the blower 100 and a gas inlet 112 of the buffer tank 110. The valve Va1 is provided in the pipe Pa.
Each of the plurality of pipes Pb communicates to each of a plurality of gas outlets 114 of the buffer tank 110 and each of a plurality of gas inlets 202 of the crusher 200. Each of the plurality of valves Vb1 are provided in each of the plurality of pipes Pb. For example, when seen from the top of the rotating table 212 (the details will be described below) of the crusher 200, the plurality of pipes Pb are disposed around the rotating table 212. Specifically, the plurality of pipes Pb are arranged in rotational symmetry about the center (rotation axis R described below) of the rotating table 212.
The pipe Pc communicates to a material discharge pipe 206 of the crusher 200 and a suction port 302 of the first collector 300. The valve Vc1, the valve Vc2, and the valve Vc3 are provided in the pipe Pc and are arranged in this order from the material discharge pipe 206 of the crusher 200 to the suction port 302 of the first collector 300.
The pipe Pd communicates to a material supply pipe 204 of the crusher 200 and a material discharge port 304 of the first collector 300. The valve Vd1 is provided in the pipe Pd.
The pipe Pe communicates to the first container 310 and a material supply port 308 of the first collector 300. The valve Ve1 and the valve Ve2 are provided in the pipe Pe and are arranged in this order from the first container 310 to the material supply port 308 of the first collector 300. The valve Ve1 is detachably attached to the pipe Pe together with the first container 310. In other words, when the valve Ve1 is detached from the pipe Pe, the first container 310 and the valve Ve1 can be integrated. Further, the pipe Pe is connected to the line Le between the valve Ve1 and the valve Ve2. The inside of the pipe Pe can be replaced with a vacuum or inert gas through the line Le. That is, the line Le can reduce the internal pressure of the pipe Pe and can introduce inert gas into the pipe Pe.
The pipe Pf communicates to a portion of the pipe Pc positioned between the valve Vc1 and the valve Vc2 (that is, between the crusher 200 and the valve Vc2), and a suction port 402 of the second collector 400. The valve Vf1 is provided in the pipe Pf.
The pipe Pg communicates to a portion of the pipe Pc positioned between the valve Vc2 and the valve Vc3, and a gas discharge pipe 406 of the second collector 400. The valve Vg1 is provided in the pipe Pg.
The pipe Ph communicates to the second container 410 and a material discharge port 404 of the second collector 400. The valve Vh1 and the valve Vh2 are provided in the pipe Ph and are arranged in this order from the second container 410 to the material discharge port 404 of the second collector 400. Further, the pipe Ph is connected to the line Lh between the valve Vh1 and the valve Vh2. The inside of the pipe Ph can be replaced with a vacuum or inert gas through the line Lh. That is, the line Lh can reduce the internal pressure of the pipe Ph and can introduce inert gas into the pipe Ph.
The pipe Pi communicates to a gas discharge port 306 of the first collector 300 and a gas inlet 102 of the blower 100. The valve Vi1 and the valve Vi2 are provided in the pipe Pi, and are arranged in this order from the gas discharge port 306 of the first collector 300 to the gas inlet 102 of the blower 100.
The pipe Pj is connected to a portion of the pipe Pi positioned between the gas discharge port 306 of the first collector 300 and the valve Vi1 and a portion of the pipe Pi positioned between the gas inlet 102 of the blower 100 and the valve Vi2. The valve Vj1 is provided in the pipe Pj.
The pipe Pk communicates to an adjustment port 116 of the buffer tank 110 and an exhaust duct D. The valve Vk1 is provided in the pipe Pk.
The pipe Pl communicates to a gas discharge port 208 of the crusher 200 and the decompressor 500. The valve Vl1 is provided in the pipe Pl.
The pipe Pm communicates to the decompressor 500 and the exhaust duct D. The valve Vm1 is provided in the pipe Pm.
The pipe Pn communicates a portion of the pipe Pl positioned between the gas discharge port 208 of the crusher 200 and the valve Vl1, and the exhaust duct D. The valve Vn1 is provided in the pipe Pn.
The pipe Po is branched from the pipe Pi and communicates to the exhaust duct D. Specifically, the pipe Pi includes an end portion of the pipe Pj positioned between the valve Vi2 and the gas inlet 102 of the blower 100. The pipe Po communicates to a portion of the pipe Pi positioned between the above-described portion and the gas inlet 102 of the blower 100, and the exhaust duct D. The valve Vo1 is provided in the pipe Po.
The blower 100 sucks gas in the pipe Pj through the gas inlet 102 of the blower 100. The blower 100 discharges, through the gas outlet 104 of the blower 100, the gas sucked through the gas inlet 102 of the blower 100. Thus, the blower 100 sends the gas to the buffer tank 110 through the pipe Pa. The rotation speed of a motor of the blower 100 is changeable by an inverter 106, and the flow rate of the gas sent from the blower 100 is freely changeable depending on the rotation speed of the motor.
The gas sent from the blower 100 through the pipe Pa enters into the gas inlet 112 of the buffer tank 110. The gas in the buffer tank 110 passes through the plurality of gas outlets 114 of the buffer tank 110 and is sent to the crusher 200 through the plurality of pipes Pb. The pressure of the gas in the buffer tank 110 is adjusted by the valve Vk1.
The gas sent from the buffer tank 110 through the plurality of pipes Pb enters into the plurality of gas inlets 202 of the crusher 200. A material sent from the first container 310 through the pipe Pe, the first collector 300, and the pipe Pd enters into the material supply pipe 204 of the crusher 200. At least some of the material and at least some of the gas in the crusher 200 are discharged through the material discharge pipe 206 of the crusher 200. The internal pressure of the crusher 200 can be reduced by the decompressor 500. The gas in the crusher 200 can be discharged to the exhaust duct D through the pipe Pn.
The first collector 300 sucks the material and the gas in the pipe Pc through the suction port 302 of the first collector 300. The first collector 300 discharges the material sucked through the suction port 302 of the first collector 300 through the material discharge port 304 of the first collector 300. Thus, the first collector 300 sends the material to the crusher 200 through the pipe Pd. The first collector 300 discharges the gas sucked through the suction port 302 of the first collector 300 through the gas discharge port 306 of the first collector 300. Thus, the first collector 300 sends the gas to the blower 100 through the pipe Pi. The first collector 300 is, for example, a dust collector.
The second collector 400 sucks the material and the gas in the pipe Pc and the pipe Pf through the suction port 402 of the second collector 400. The second collector 400 discharges the material sucked through the suction port 402 of the second collector 400 through the material discharge port 404 of the second collector 400. Thus, the second collector 400 sends the material to the second container 410 through the pipe Ph. The second collector 400 discharges the gas sucked through the suction port 402 of the second collector 400 through the gas discharge pipe 406 of the second collector 400. The second collector 400 is, for example, a cyclone dust collector.
Next, a structure of the crusher 200 will be described using
The crusher 200 includes the rotating table 212, the plurality of balls 214, and the presser 216. In the example shown in
The rotating table 212 is rotatable about the rotation axis R. The rotation axis R of the rotating table 212 passes through the center of the rotating table 212 in a height direction (thickness direction) of the rotating table 212. The height direction (thickness direction) of the rotating table 212 is along the vertical direction. The plurality of balls 214 are arranged around the rotation axis R of the rotating table 212. Specifically, the plurality of balls 214 are arranged in rotational symmetry about the rotation axis R. The plurality of balls 214 rotate together with the rotation of the rotating table 212. Each of the plurality of balls 214 is individually rotatable about rotation axis R1 rotating together with the rotation of the rotating table 212. The rotation axis R1 of each ball 214 passes through the center of the ball 214 in the height direction (thickness direction) of the ball 214. The height direction (thickness direction) of the ball 214 is along the vertical direction. The presser 216 presses the plurality of balls 214 to the rotating table 212 from a side opposite to the rotating table 212.
Next, an example of a method of manufacturing the inorganic material (A) from the plural kinds of inorganic compounds (A1) using the apparatus 10 will be described using
The valve Ve1 and the valve Ve2 are closed, and the plural kinds of inorganic compounds (A1) are contained in the first container 310. Specifically, first, the first container 310 is detached from the pipe Pe together with the valve Ve1. Next, the plural kinds of inorganic compounds (A1) are contained in the first container 310. The containing of the plural kinds of inorganic compounds (A1) is implemented in an atmosphere (for example, in a glove box) controlled by the inert gas. Next, the first container 310 and the valve Ve1 are attached to the pipe Pe with the valve Ve1 being closed. In this case, even if the first container 310 and the valve Ve1 are exposed to the atmosphere, the closed valve Ve1 can prevent the plural kinds of inorganic compounds (A1) in the first container 310 from being exposed to the atmosphere (air). When the first container 310 is attached, the atmosphere in the pipe Pe can be replaced with the inert gas through the line Le connected to the pipe Pe.
Thus, when the inorganic compounds (A1) pass through the pipe Pe, the inorganic compounds (A1) can be prevented from being exposed to the atmosphere (air). Next, the valve Ve1, the valve Ve2, and the valve Vd1 are opened, and the plural kinds of inorganic compounds (A1) are sent from the first container 310 to the crusher 200 through the pipe Pe, the first collector 300, and the pipe Pd. That is, the first container 310 contains the plural kinds of inorganic compounds (A1) supplied to the crusher 200.
Further, the valve Ve1, the valve Ve2, the valve Vf1, the valve Vg1, the valve Vh1, the valve Vh2, the valve Vj1, the valve Vl1, the valve Vm1, the valve Vn1, and the valve vo1 are closed, and the valve Va1, the valves Vb1, the valve Vc1, the valve Vc2, the valve Vc3, the valve Vd1, the valve Vi1, and the valve Vi2 are opened, and the inert gas is supplied to a portion of the pipe Pi positioned between the valve Vi1 and the valve Vi2. Next, the blower 100 is operated while adjusting the internal pressure of the buffer tank 110 using the valve Vk1. Thus, the system S, that is, the system from the blower 100 through the pipe Pa, the buffer tank 110, the pipe Pb, the crusher 200, the pipe Pc, the first collector 300, and the pipe Pi to the blower 100 circulates the inert gas and is closed from the outside (that is, the system S is not exposed to the atmosphere (air)).
The supply of the inert gas to the portion of the pipe Pi positioned between the valve Vi1 and the valve Vi2 may be conducted before or after supplying the plural kinds of inorganic compounds (A1) from the first container 310 to the crusher 200 or may be conducted while supplying the plural kinds of inorganic compounds (A1) from the first container 310 to the crusher 200. The position where the inert gas is supplied does not need to be the portion of the pipe Pi positioned between the valve Vi1 and the valve Vi2 and may be any portion in the system S. The inert gas may be supplied to a plurality of portions in the system S (including the portion of the pipe Pi positioned between the valve Vi1 and the valve Vi2).
In the present embodiment, the inert gas is nitrogen gas. The nitrogen gas is supplied, for example, from a nitrogen gas container through a nitrogen purifier. In this example, the impurity concentration (for example, the water concentration or the oxygen concentration) in the nitrogen gas can be reduced. For example, the water concentration in the nitrogen gas may be 400 ppm or less, preferably 40 ppm or less, and more preferably 2 ppm or less, and the oxygen concentration in the nitrogen gas may be 400 ppm or less, preferably 40 ppm or less, and more preferably 2 ppm or less. The inert gas may be, however, gas other than nitrogen gas, such as argon gas.
Further, the crusher 200 is operated. Specifically, the rotating table 212 is rotated about the rotation axis R, each of the balls 214 is rotated about the rotation axis R1, and the plurality of balls 214 are pressed to the rotating table 212 by the presser 216. The operation of the crusher 200 may start before or after supplying the plural kinds of inorganic compounds (A1) from the first container 310 to the crusher 200 or may start while supplying the plural kinds of inorganic compounds (A1) from the first container 310 to the crusher 200. The crusher 200 repeats vitrifying the plural kinds of inorganic compounds (A1) using mechanical energy and blowing up the plural kinds of vitrified inorganic compounds (A1) by the inert gas blown from the blower 100, as below.
First, as indicated by the black arrow extending from the material supply pipe 204 to the rotating table 212 in
Next, as indicated by two black arrows extending from the periphery of the center (rotation axis R) of the rotating table 212 to both sides in
As indicated by two white arrows positioned on both sides of the rotating table 212, the plurality of balls 214, and the presser 216 in
As indicated by two black arrows extending from the outside of the rotating table 212 to the center of the rotating table 212 on the presser 216 in
As indicated by two black arrows extending to the upper side of the presser 216 above the presser 216 in
While conducting mechanical milling of the crusher 200, as described above, the system S, that is the system from the blower 100 through the pipe Pa, the buffer tank 110, the pipe Pb, the crusher 200, the pipe Pc, the first collector 300, and the pipe Pi to the blower 100 circulates the inert gas and is closed from the outside. Accordingly, contact between the plural kinds of inorganic compounds (A1) and air can be reduced.
By conducting mechanical milling on the plural kinds of inorganic compounds (A1) by the crusher 200, the plural kinds of inorganic compounds (A1) are vitrified, and the inorganic material (A) is manufactured from the plural kinds of inorganic compounds (A1).
Next, an example of a method of removing the inorganic material (A) from the apparatus 10 will be described.
The valve Vc2 is closed, the valve Vf1 and the valve Vg1 are opened, and the inverter 106 connected to the motor of the blower 100 is controlled to increase the rotation speed of the motor of the blower 100, and the flow rate of the inert gas sent to the gas inlets 202 of the crusher 200 increases (at this stage, the valve Vh1 and the valve Vh2 are closed). By increasing the flow rate of the inert gas sent to the gas inlets 202 of the crusher 200, the inorganic material (A) blown up by the inert gas in the crusher 200 is sent into the material discharge pipe 206 without substantially or completely returning to the rotating table 212. The inorganic material (A) sent into the material discharge pipe 206 enters into the suction port 402 of the second collector 400 through the pipe Pc and the pipe Pf. Thus, the inorganic material (A) is collected by the second collector 400. Next, the valve Vh1 and the valve Vh2 are opened. Thus, the inorganic material (A) collected by the second collector 400 enters into the second container 410 through the pipe Ph. Next, the valve Vh1 and the valve Vh2 are closed. Next, the second container 410 is detached from the pipe Ph. In this case, the inside of the pipe Ph can be prevented from being exposed to the atmosphere (air) by the closed valve Vh1 and valve Vh2. When the second container 410 is attached to the pipe Ph again, the atmosphere in the pipe Ph can be replaced with the inert gas through the line Lh connected to the pipe Ph. Thus, when the inorganic material (A) passes through the pipe Ph, the inorganic material (A) can be prevented from being exposed to the atmosphere (air).
Next, an example of the operation of the decompressor 500 will be described.
The inside of the crusher 200 may be exposed to the atmosphere (air), for example, when an internal component (for example, the rotating table 212, the balls 214, or the presser 216) of the crusher 200 is cleaned. In this case, the air in the crusher 200 can be removed by reducing the internal pressure of the crusher 200 using the decompressor 500. For example, the decompressor 500 can be operated with the plurality of valves Vb1, the valve Vc1, the valve Vd1, and the valve Vn1 closed, and with the valve Vl1 and the valve Vm1 opened.
By heating the inorganic material (A), an inorganic material (B) having improved crystallinity can be formed. The inorganic material (B) is not particularly limited, and examples thereof include an inorganic solid electrolyte material, a positive electrode active material, a negative electrode active material, and the like.
The inorganic solid electrolyte material is not particularly limited, and examples thereof include a sulfide-based inorganic solid electrolyte material, an oxide-based inorganic solid electrolyte material, and other lithium-based inorganic solid electrolyte materials. Among these, a sulfide-based inorganic solid electrolyte material is preferable. The inorganic solid electrolyte material is not particularly limited, and examples thereof include an inorganic solid electrolyte material used for a solid electrolyte layer forming an all-solid-state lithium ion battery.
Examples of the sulfide-based inorganic solid electrolyte material include a Li2S—P2S5 material, a Li2S—SiS2 material, a Li2S—GeS2 material, a Li2S—Al2S3 material, a Li2S—SiS2—Li3PO4 material, a Li2S—P2S5—GeS2 material, a Li2S—Li2O—P2S5—SiS2 material, a Li2S—GeS2—P2S5—SiS2 material, a Li2S—SnS2—P2S5—SiS2 material, a Li2S—P2S5—Li3N material, a Li2S2+x—P4S3 material, a Li2S—P2S5—P4S3 material, and the like. Among these, the Li2S—P2S5 material and the Li2S—P2S5—Li3N material are preferable from the viewpoint that they have excellent lithium ionic conductivity and has stability to the extent that decomposition or the like does not occur in a wide voltage range. Here, for example, the Li2S—P2S5 material refers to an inorganic material obtained by a chemical reaction of an inorganic composition including at least Li2S (lithium sulfide) and P2S5 by mechanical energy, and the Li2S—P2S5—Li3N material refers to an inorganic material obtained by a chemical reaction of an inorganic composition including at least Li2S (lithium sulfide), P2Ss, and Li3N by mechanical energy. Here, in the present embodiment, examples of the lithium sulfide include lithium polysulfide.
Examples of the oxide-based inorganic solid electrolyte material include: a NASICON type such as LiTi2(PO4)3, LiZr2(PO4)3, or LiGe2 (PO4)3, a perovskite type such as (La0.5+xLi0.5+3x)TiO3; a Li2O—P2O5 material; a Li2O—P2O5—Li3N material; and the like.
Examples of the other lithium-based inorganic solid electrolyte material include LiPON, LiNbO3, LiTaO3, Li3PO4, LiPO4-x Nx (x satisfies 0<x≤1), LiN, LiI, LISICON, and the like. A glass ceramic obtained by precipitating crystal of the inorganic solid electrolytes may also be used as the inorganic solid electrolyte material.
The sulfide-based inorganic solid electrolyte material includes Li, P, and S as constituent elements. From the viewpoint of further improving the lithium ionic conductivity, the electrochemical stability, the stability and the handling properties in water or air, and the like, a molar ratio (Li/P) of the content of Li to the content of P in the solid electrolyte material is preferably 1.0 or higher and 10.0 or lower, more preferably 2.0 or higher and 5.0 or lower, still more preferably 2.5 or higher and 4.0 or lower, still more preferably 2.8 or higher and 3.6 or lower, still more preferably 3.0 or higher and 3.5 or lower, still more preferably 3.1 or higher and 3.4 or lower, and still more preferably 3.1 or higher and 3.3 or lower. A molar ratio (S/P) of the content of S to the content of P is preferably 1.0 or higher and 10.0 or lower, more preferably 2.0 or higher and 6.0 or lower, more preferably 3.0 or higher and 5.0 or lower, still more preferably 3.5 or higher and 4.5 or lower, still more preferably 3.8 or higher and 4.2 or lower, still more preferably 3.9 or higher and 4.1 or lower, and still more preferably 4.0. Here, the contents of Li, P, and S in the solid electrolyte material can be obtained, for example, by ICP optical emission spectroscopy or X-ray photoelectron spectroscopy.
Examples of the shape of the sulfide-based inorganic solid electrolyte material include a particle shape. The inorganic solid electrolyte material having a particle shape is not particularly limited, and an average particle size d50 in a weight-based particle size distribution measured using a laser-diffraction scattering method particle size distribution measurement is preferably 1 μm or more and 100 μm or less, more preferably 3 μm or more and 80 μm or less, still more preferably 5 μm or more and 60 μm or less. When the average particle size d50 of the inorganic solid electrolyte material is in the above-described range, the lithium ionic conductivity of the obtained solid electrolyte membrane can be further improved while maintaining excellent handling properties.
The positive electrode active material is not particularly limited, and examples thereof include a positive electrode active material that can be used for a positive electrode layer of a lithium ion battery. Examples of the positive electrode active material include a composite oxide such as a lithium cobalt oxide (LiCoO2), a lithium nickel oxide (LiNiO2), a lithium manganese oxide (LiMn2O4), a solid solution oxide (Li2MnO3-LiMO2 (M=Co, Ni, or the like)), lithium-manganese-nickel oxide (LiNi1/3Mn1/3Co1/3O2), or an olivine-type lithium phosphorus oxide (LiFePO4); a sulfide-based positive electrode active material such as CuS, a Li—Cu—S compound, TiS2, FeS, MoS2, V2S5, a Li—Mo—S compound, a Li—Ti—S compound, a Li-V-S compound, or a Li—Fe—S compound; and the like. Among these, from the viewpoints of higher discharge capacity density and higher cycle characteristics, a sulfide-based positive electrode active material is preferable, and a Li—Mo—S compound, a Li—Ti—S compound, or a Li-V-S compound is more preferable. Here, the Li—Mo—S compound includes Li, Mo, and S as constituent elements and can be typically obtained by a chemical reaction of an inorganic composition including molybdenum sulfide and lithium sulfide as raw materials by mechanical energy. The Li—Ti—S compound includes Li, Ti, and S as constituent elements and can be typically obtained by a chemical reaction of an inorganic composition including titanium sulfide and lithium sulfide as raw materials by mechanical energy. The Li-V-S compound includes Li, V, and S as constituent elements and can be typically obtained by a chemical reaction of an inorganic composition including vanadium sulfide and lithium sulfide as raw materials by mechanical energy.
The negative electrode active material is not particularly limited, and examples thereof include a negative electrode active material that can be used for a negative electrode layer of a lithium ion battery. Examples of the negative electrode active material include: a metal material mainly formed of a lithium alloy, a tin alloy, a silicon alloy, a gallium alloy, an indium alloy, or an aluminum alloy; a lithium titanium composite oxide (for example, Li4Ti5O12), a graphite material, and the like.
Examples of the plural kinds of inorganic compounds (A1) include a material to be the inorganic material (B) by mechanical milling and heating. For example, the plural kinds of inorganic compounds (A1) include Li.
The crusher 200 further includes a cover portion 220. The cover portion 220 is positioned above the presser 216. As indicated by white arrows extending along the cover portion 220 in
Hereinafter, the embodiment of the present invention has been described with reference to the drawings. However, the embodiment is merely an example of the present invention, and various configurations other than the above-described configurations may also be adopted.
For example, in the present embodiment, the crusher 200 presses the balls 214 against the rotating table 212 with the presser 216. The presser 216, however, may press rollers against the rotating table 212 instead of the balls 214. Even in this case, the crusher 200 can conduct mechanical milling on the plural kinds of inorganic compounds (A1).
The present application claims priority based on Japanese Patent Application No. 2019-181878 filed on Oct. 2, 2019, the entire content of which is incorporated herein by reference.
| Number | Date | Country | Kind |
|---|---|---|---|
| 2019-181878 | Oct 2019 | JP | national |
| Filing Document | Filing Date | Country | Kind |
|---|---|---|---|
| PCT/JP2020/031130 | 8/18/2020 | WO |
