Patent Application
20200386473
Embodiments of the invention described herein pertain to the field of liquefaction of natural gas. More particularly, but not by way of limitation, one or more embodiments of the invention enable an apparatus, system and method for reliquefaction of previously regasified LNG.
Natural gas is often transported by seagoing vessel from the location where it is produced to the location where it is consumed. Liquefaction of natural gas facilitates more efficient storage and transportation of the natural gas, since liquefied natural gas (“LNG”) takes up only about 1/600 of the volume that the same amount of natural gas does in its gaseous state. LNG is produced by cooling natural gas below its boiling point, which is about −160° C. at atmospheric pressure depending upon composition. LNG may be stored slightly above atmospheric pressure in cryogenic containment onboard the seagoing vessels. Upon reaching the location of intended use, the LNG may be offloaded directly to onshore storage tanks, or where the vessel features the required equipment—such as a floating storage and regasification unit (FSRU), converted back to its gaseous form by adding heat and thereby raising the temperature above its boiling point.
In this manner, natural gas produced in locations where it is abundant, may be liquefied and shipped overseas to locations where it is most needed. Marine vessels designed for transporting LNG are conventionally large carrier vessels known as LNG carriers. A typical LNG carrier may have a capacity in the range of 138,000 m3 to 266,000 m3. Once the LNG carrier loaded with LNG cargo docks at the delivery terminal it is either offloaded directly to onshore storage tanks, or in the case of an FSRU, the LNG is regasified and delivered into high pressure gas pipelines typically between a pressure of about 45 barg and about 100 barg. The pipelines carry the gas to its destination, which may for example be a power plant or other end user or gas distributer. As the gas travels through the pipeline to its ultimate destination, gas from various sources is comingled within the gas network.
The LNG carried by the LNGC is typically discharged into shore side storage tanks or an FSRU for later regasification by either a vaporizer located onshore or onboard the FSRU. Unfortunately, many delivery terminals do not possess onshore storage tanks, making the FSRU a better delivery choice since these units provide onboard storage. In the case of an FSRU the natural gas is sent out in gaseous form into the high pressure pipeline through a gas arm on a dock or through an offshore subsea buoy.
A problem that arises is that some energy consumers do not have an existing natural gas pipeline or natural gas distribution system into which the FSRU can connect. These off-grid facilities often have low volume demand for natural gas and may be hundreds of kilometers away from a gas grid, which does not justify the cost of building a new pipeline. Typically, such low demand consumers rely on alternative and often costly liquid fuels, like diesel oil or kerosene. In order to reduce operating costs and emissions, many such facilities would benefit from the use of LNG delivered via tanker trucks. These locations then use small air-based regasification systems to convert the trucked LNG to useable natural gas at their facilities. Examples of these low demand facilities are locations such as hospitals in need of a source of reliable off-grid power to fuel backup generators, mines, remote power generation facilities, residential areas or other installations that need reliable energy but for whom the quantity of demand does not justify the cost of connecting into a sparse or nonexistent gas grid.
In some instances it could be possible to load these trucks from an FSRU provided the vessel was located in a suitable port with sufficient road access. However, there is a gross mismatch between the typical high capacity and unloading rate of an FSRU (up to 10,000 m3/hr), since these trucks typically have below 60 m3 gross volume (less than 57 m3 useable net volume) and load at a much more sedate 50 m3/hr. To transfer LNG from the FSRU to the LNG tanker truck, it has been proposed to use ship-to-ship (STS) transfer equipment and protocol to transfer LNG off the FSRU, and down to the jetty where the LNG tanker trucks would arrive and be loaded. However, in some locations using STS transfer protocol is not feasible because the FSRU is not accessible by truck. The FSRU may be inaccessible by truck when the FSRU is docked at an offshore buoy, a sea island, or at the end of a trestle with no truck access. Where the FSRU is inaccessible by truck, loading the LNG tanker truck with LNG requires running a cryogenic liquid pipe as well as a gas return line to shore, which is expensive and oftentimes infeasible since ambient conditions are warm compared to the LNG, and the warm temperatures cause the LNG to boil. If for example, the FSRU is three kilometers or more off shore, a cryogenic pipeline of such length is prohibitively expensive. The stainless steel piping needed to carry cryogenic fluid is twice as expensive as the mild steel used for pipelines that carry gas, and in addition, cryogenic pipes require significant quantities of costly insulation.
It has also been proposed to supply LNG tanker trucks by siphoning gaseous natural gas from an existing gas network, and then liquefying the gas so it can be loaded onto the LNG tanker truck in liquefied form. However, current liquefaction processes require sophisticated pretreatment of typical pipeline quality natural gas before it can be liquefied. Typically, natural gas in a gas grid is comingled from various sources. The comingled gas contains contaminants that will freeze at the low temperatures required to liquefy natural gas. These contaminants include water, carbon dioxide and mercury. All these and other impurities must be removed prior to liquefaction in order for the liquefaction process to be successful and so as not to damage the liquefaction equipment with ice and other solids. Pretreatment of pipeline gas to obtain LNG quality gas is expensive and requires complex pretreatment facilities, which are undesirable when it comes to supplying small tanker trucks in remote locations.
A number of commercially-licensed processes are available for producing LNG from pretreated natural gas. These range from single and dual-mixed refrigerant (SMR/DMR), to propane-precooled (C3MR) and cascade-based processes. However, these processes are only feasible on a large scale. A typical baseload liquefaction plant of this type typically features multiple LNG trains, each with a capacity in excess of 4.0 Million Tonnes Per Annum (MTPA). Liquefaction on this scale is not appropriate for small LNG tanker trucks in comparison.
To date, smaller scale reliquefaction of natural gas, in the form of boil off gas (BOG), has been accomplished onboard large LNG carriers, such as Q Flex and Q Max carriers, by means of a nitrogen expansion system. Nitrogen expansion systems provide refrigeration by first compressing nitrogen to high pressure, cooling it to ambient temperature and then expanding the nitrogen over an expander. As a result of the Joule-Thompson effect, as well as the removal of work in the expander, the nitrogen temperature drops below −160° C. The cryogenic gaseous nitrogen is then fed to a heat exchanger where it reliquefies the BOG, without the requirement for pretreatment. The LNG produced from the BOG can then be returned to the cargo tanks. The power for the process is provided by generators onboard the LNG carrier.
The problem with aforementioned nitrogen expansion systems when applied to pipeline gas is that, not only is the quality insufficient, but the temperature of the pipeline gas is also ambient as compared to the cold (about −159° C.) natural gas entering the nitrogen refrigeration loop from the top of the vessel's cargo tanks. Additionally the cold vapor is also at a low pressure of between 5 and 15 kPag. When the reliquefied LNG leaves the nitrogen refrigeration loop, it is delivered to the storage tanks similarly at a pressure of approximately 15 kPag. In contrast, pipeline gas has a pressure of 45-100 barg and a temperature of 5-10° C. LNG tanker trucks accept LNG at a pressure of 5-6 barg. Thus, while nitrogen refrigeration without pretreatment loops are suitable for cold, low-pressure boil off gas, they are not conventionally able to accept, warm, high pressure pipeline gas as an input nor provide LNG at 5-6 barg as an output.
As is apparent from the abovementioned problems, current reliquefaction techniques are not suitable for reliquefaction of pipeline specification natural gas without significant pretreatment for the express purpose of loading comparatively small LNG carrying trucks. Therefore, there is a further need for an apparatus, system and method for reliquefaction of previously regasified LNG to supply LNG to LNG cargo trucks.
One or more embodiments of the invention enable an apparatus, system and method for reliquefaction of previously regasified LNG.
An apparatus, system and method for reliquefaction of previously-regasified LNG is described. An illustrative embodiment of a regasified LNG reliquefaction method includes diverting high pressure regasified LNG (HP RLNG) from a natural gas pipeline, wherein the HP RLNG is diverted through a lateral that connects to the natural gas pipeline prior to the natural gas pipeline converging with a natural gas grid, and wherein the natural gas pipeline receives the HP RLNG from an FSRU, expanding the natural gas from the lateral with an expander to obtain low pressure regasified LNG (LP RLNG), liquefying the LP RLNG in a cold box, wherein the cold box places the LP RLNG in heat exchange with nitrogen of a nitrogen expansion loop to produce low pressure LNG, and transmitting the low pressure LNG to a cryogenic cargo tank onboard an LNG tanker truck. In certain embodiments, the regasified LNG reliquefaction method further includes using energy extracted by the expander to drive a compressor that operates in the nitrogen expansion loop, the compressor providing compression of nitrogen in the nitrogen expansion loop. In some embodiments, the regasified LNG reliquefaction method further includes compressing the nitrogen in the nitrogen expansion loop using a compressor powered by a generator, the generator at least partially fueled by a portion of the HP RLNG diverted through the lateral. In certain embodiments, the generator is at least partially fueled by a portion of boil-offgas from one of the cryogenic cargo tank, a land-based LNG storage tank fluidly coupled to the cold box, or a combination thereof. In some embodiments, the portion of the HP RLNG and the portion of the boil-off gas are combined by an eductor, and the combined gas fuels the generator. In certain embodiments, the nitrogen expansion loop includes a second expander, and further comprising expanding nitrogen in the nitrogen expansion loop over the second expander. In some embodiments, the regasified LNG reliquefaction method further includes using the nitrogen to extract heat from the LP RLNG in the cold box to produce the low pressure LNG. In certain embodiments, the regasified LNG reliquefaction method further includes returning boil-off gas from one of the cryogenic cargo tank, an intermediate land-based LNG storage tank, or a combination thereof to the cold box. In some embodiments, the regasified LNG reliquefaction method further includes using the boil-off gas to at least partially extract heat from the LP RLNG in the cold box. In certain embodiments, the LP RLNG is in heat exchange with the nitrogen in the cold box to extract latent heat from the LP RLNG.
An illustrative embodiment of a regasified LNG reliquefaction apparatus includes a natural gas pipeline extending between a FSRU and a natural gas grid, a lateral pipeline fluidly coupled to the natural gas pipeline prior to a commingling of the natural gas pipeline with the natural gas grid, the lateral pipeline fluidly coupled to an inlet of a natural gas expander and delivering LNG-quality natural gas to the inlet, an outlet of the expander fluidly coupled to a cold box, the cold box coupled to a nitrogen expansion loop, and LNG exiting the cold box, the LNG formed from the LNG-quality natural gas. In some embodiments, the regasified LNG reliquefaction apparatus further includes a power generator fluidly coupled to a portion of the LNG-quality natural gas delivered by the lateral pipeline. In certain embodiments, the power generator is energetically coupled to a compressor of the nitrogen expansion loop. In certain embodiments, the regasified LNG reliquefaction apparatus further includes a LNG storage tank receiving the LNG exiting the cold box. In some embodiments, the regasified LNG reliquefaction apparatus further includes a boil-off gas (BOG) return line fluidly coupling the LNG storage tank and the cold box. In certain embodiments, the regasified LNG reliquefaction apparatus further includes a power generator, and a boil-off gas (BOG) return line fluidly coupling the LNG storage tank and the power generator. In some embodiments, the regasified LNG reliquefaction apparatus further includes a portion of the LNG-quality natural gas delivered by the lateral pipeline and BOG carried by the BOG return line mixedly coupled by an eductor prior to entering the power generator. In certain embodiments, the regasified LNG reliquefaction apparatus further includes an LNG tanker truck cryogenically coupled to the LNG storage tank. In some embodiments, the natural gas expander is drivingly coupled to a compressor of the nitrogen expansion loop. In certain embodiments, LNG-quality natural gas sendout from the FSRU is liquefied in the cold box without pretreatment.
An illustrative embodiment of a regasified LNG reliquefaction system includes a FSRU fluidly coupled to a natural gas pipeline, the natural gas pipeline including high pressure regasified LNG (HP RLNG) produced from LNG-quality natural gas regasified by the FSRU, the natural gas pipeline transmitting the HP RLNG at a first pressure of 70-100 barg and a first temperature of 5-20° C., a lateral pipeline that couples the natural gas pipeline to an expander, the expander including an inlet that receives the HP RLNG from the lateral pipeline at the first pressure and the first temperature, wherein the expander converts the HP RLNG having the first pressure and the first temperature to low pressure regasified LNG (LP RLNG) having a second pressure of less than 10 barg and a second temperature of about −100° C., a cold box fluidly coupled to the LP RLNG and a nitrogen expansion loop, and LNG exiting the cold box at a third pressure of 5-6 barg. In some embodiments, the expander drives a compressor in the nitrogen expansion loop. In certain embodiments, the regasified LNG reliquefaction system further includes a compressor providing compression of nitrogen in the nitrogen expansion loop, the compressor powered by a generator fueled by a portion of the HP RLNG. In some embodiments, the nitrogen expansion loop further includes a second expander that expands the nitrogen. In certain embodiments, the nitrogen extracts heat from the LP RLNG in the cold box causing the LP RLNG to condense in the cold box at the second pressure. In some embodiments, the regasified LNG reliquefaction system further includes a storage tank fluidly coupled to the LNG exiting the cold box. In certain embodiments, the storage tank is fluidly coupled between the cold box and an LNG cargo tank onboard a truck. In some embodiments, a gas return line fluidly couples boil-offgas from the LNG cargo tank to the cold box. In certain embodiments, the boil-off gas cools the LP RLNG in the cold box and recondenses in the cold box. In some embodiments, a gas return line fluidly couples boil-off gas from the LNG cargo tanks to a power generator. In certain embodiments, the regasified LNG reliquefaction system further includes an eductor coupled to a fuel gas inlet of the power generator, wherein the eductor mixes the boil-off gas with a portion of the HP RLNG sent to the power generator. In some embodiments, the power generator provides make up power to the nitrogen expansion loop. In certain embodiments, the natural gas pipeline transmits the HP RLNG to downstream consumers via existing gas pipeline infrastructure.
An illustrative embodiment of a method of reliquefying previously regasified LNG includes diverting high pressure regasified LNG (HP RLNG) from a natural gas pipeline, wherein the HP RLNG is diverted through a lateral that connects to the natural gas pipeline prior to the natural gas pipeline converging with a natural gas grid, and wherein the natural gas pipeline receives the HP RLNG from an FSRU, expanding the natural gas from the lateral with an expander to obtain low pressure regasified LNG (LP RLNG), liquefying the LP RLNG in a cold box, wherein the cold box places the LP RLNG in heat exchange with nitrogen of a nitrogen expansion loop to produce low pressure LNG, and transmitting the low pressure LNG to a cryogenic cargo tank onboard an LNG tanker truck.
In further embodiments, features from specific embodiments may be combined with features from other embodiments. For example, features from one embodiment may be combined with features from any of the other embodiments. In further embodiments, additional features may be added to the specific embodiments described herein.
Advantages of the present invention may become apparent to those skilled in the art with the benefit of the following detailed description and upon reference to the accompanying drawings in which:
While the invention is susceptible to various modifications and alternative forms, specific embodiments thereof are shown by way of example in the drawings and may herein be described in detail. The drawings may not be to scale. It should be understood, however, that the embodiments described herein and shown in the drawings are not intended to limit the invention to the particular form disclosed, but on the contrary, the intention is to cover all modifications, equivalents and alternatives falling within the scope of the present invention as defined by the appended claims.
An apparatus, system and method for reliquefaction of previously regasified LNG will now be described. In the following exemplary description, numerous specific details are set forth in order to provide a more thorough understanding of embodiments of the invention. It will be apparent, however, to an artisan of ordinary skill that the present invention may be practiced without incorporating all aspects of the specific details described herein. In other instances, specific features, quantities, or measurements well known to those of ordinary skill in the art have not been described in detail so as not to obscure the invention. Readers should note that although examples of the invention are set forth herein, the claims, and the full scope of any equivalents, are what define the metes and bounds of the invention.
As used in this specification and the appended claims, the singular forms “a”, “an” and “the” include plural referents unless the context clearly dictates otherwise. Thus, for example, reference to a heat exchanger includes one or more heat exchangers.
“Coupled” refers to either a direct connection or an indirect connection (e.g., at least one intervening connection) between one or more objects or components. The phrase “directly attached” means a direct connection between objects or components.
As used in this specification and the appended claims “high pressure” means, with respect to gaseous natural gas, a pressure of between 45 barg and 100 barg. With respect to a conduit, pipe, hose and/or transfer member for transferring gaseous natural gas, “high pressure” means capable of maintaining, transferring and/or accommodating natural gas at one or more pressures falling in the range of between 45 barg and 100 barg.
As used in this specification and the appended claims “low pressure” with respect to gaseous natural gas or LNG, means a pressure of 10 barg or less.
As used in this specification and the appended claims, “FSRU” is used liberally to refer to any of a regasification vessel, a floating storage regasification unit and/or a floating regasification unit (FRU).
One or more embodiments of the invention provide a system and method for supplying low-demand off-grid facilities with liquefied natural gas (LNG) for local distribution. Illustrative embodiments may allow LNG tanker trucks to be supplied with LNG from a high pressure gas pipeline without the need for pretreatment of the gas, in a cost-effective and more efficient manner than conventional methods. Illustrative embodiments may provide a self-sufficient system that does not require a power source external from the system, for reliquefaction of LNG-quality, high pressure, warm natural gas that is economical on a low-demand scale.
Illustrative embodiments may include taking FSRU sendout through a lateral, before the gaseous natural gas comingles with other natural gas sources that may contain impurities. The high pressure, regasified LNG (HP RLNG) taken through the lateral may be at pipeline pressure and temperature of about 70-100 barg and 5-20° C. The lateral may deliver the high pressure regasified LNG (HP RLNG) to a self-sufficient reliquefaction system mounted on a skid. A expander of the reliquefaction system may expand the natural gas to form low pressure regasified LNG (LP RLNG) of less than 10 barg and about −100° C. Power obtained from the gas expansion may be used to power a compressor in a nitrogen expansion loop and/or may be used to power a generator for the nitrogen expansion loop. The generator providing any make up power may be a gas turbine or dual fuel diesel engine. Similarly if grid based electrical power is available a motor may be used. Some of the regasified LNG may be bled prior to the expander inlet and used to power the generator. The LP RLNG exiting the expander will continue to a cold box where the regasified LNG may be reliquefied. The cold box may employ nitrogen from the nitrogen expansion loop in heat exchange with the natural gas to extract latent heat from the LP RLNG. The reliquefied, low pressure LNG may then be sent to a fixed storage tank and/or an LNG truck for transportation to an off-grid, low demand facility (4547 m3 useable net volume). Boil-off gas (BOG) from the tanks in the LNG trucks may be returned to the cold box to assist in refrigerating the LP RLNG and/or may be sent to power the generator for fuel. Where the BOG is sent to the generator, an eductor may draw the boil-off gas from the storage tank using the high pressure gas supply to the generator as the motive fluid in the eductor. The mixing will increase the pressure of the BOG so that it can be employed by the generator at about 30 barg.
The absence of contaminants will allow HP RLNG 175 to be reliquefied without the need for pretreatment. Pretreatment facilities and ancillary equipment is prohibitively expensive and/or complicated for supply of tanker trucks 135, since there is no economy of scale. Pipeline gas typically includes sour gases such as sulfides and CO2, too much water and mercury, none of which can be present during liquefaction and therefore, if present, must be removed prior to liquefaction. Pretreatment facilities typically consist of amine sweetening units, dehydration units and mercury removal units, and their associated powers, pumps, separators, power facilities and other ancillary utilities. By using HP RLNG 175 as an input, illustrative embodiments provide a system and method that eliminates the need for pretreatment and is simple and cost effective.
Lateral 120 may supply reliquefaction system 125 with HP RLNG 175. Reliquefaction system 125 may provide reliquefaction of HP RLNG 175 taken through lateral 120. Reliquefaction system 125 may be a self-contained skid-mounted system. HP RLNG 175 transported through lateral 120 may enter skid 255 through control and Emergency Shut Down (ESD) valves. Once reliquefied using reliquefaction system 125, LNG 140 may be delivered into storage tank 130 and/or cryogenic mobile tanks 150 onboard LNG tanker truck 135 through cryogenic hoses 160 and/or cryogenic piping. Boil-off gas (BOG) 145 generated by the LNG transfer, generated within fixed cryogenic storage tank 130 and/or generated in mobile cryogenic storage tank 150 may be returned to reliquefaction system 125 via return line 165. Employing BOG 145 as coolant for reliquefaction system 125 may be beneficial to the environment (cleaner and safer) as opposed to the conventional procedure of venting BOG 145 into the atmosphere. Mobile cryogenic storage tanks 150 onboard LNG tanker truck 135 may carry about 45-47 m3 useable net volume of LNG 140, a volume suitable for “low demand,” off-grid, locations such as facility 155. LNG tanker truck 135 may then transport LNG 140 to low demand, off-grid facility 155, which may for example be a remotely-located hospital.
Turning to
Gas expander 200 may convert HP RLNG 175 to low pressure regasified LNG (LP RLNG) 225 having a pressure of less than 10 barg and a temperature of −100° C. and/or about −100° C. LP RLNG 225 may then flow into cold box 230. Cold box 230 may include a sensible and latent heat exchanger, and cold box drain pot. The sensible/latent heat exchanger of cold box 230 may be a PCHE or PFHE type heat exchanger that places LP RLNG 225 in heat exchange with nitrogen. A control and instrument box for reliquefaction system 125 may be coupled to cold box 230. LP RLNG 225 within cold box 230 may be at least partially cooled by nitrogen in nitrogen expansion loop 235. Nitrogen may be compressed by compressor 240 in loop 235. Compressor 240 may be powered by one of gas expander 200, generator 210 or partially by gas expander 200 and partially by generator 210. Additionally nitrogen loop expander 250 may also provide power to compressor 240. Nitrogen loop heat exchanger 245 may remove heat from nitrogen, and may for example be a compact heat exchanger. Nitrogen loop expander 250, along with nitrogen loop heat exchanger 245, may complete nitrogen loop 235 by lowering the pressure and temperature of nitrogen entering cold box 230.
Low pressure LNG 140 may exit cold box 230. Low pressure LNG 140 may be formed from LP RLNG 225 that has been reliquefied in cold box 230. LNG 140 may be sent at about 5-6 barg to fixed cryogenic storage tank 130 and/or to mobile cryogenic storage tank 150 onboard LNG tanker truck 135. In some embodiments, the outlet of reliquefaction system 125 may be LNG at 5-6 barg stored in a pressurized Type C tank 130 for direct filling from storage tank 130 into mobile cryogenic tanks 150 onboard LNG tanker truck 135. BOG 145 may be returned to cold box 230 to assist in cooling LP RLNG 225 and/or may be mixed in eductor 220 to provide gas to generator 210. BOG 145 may be at a low pressure, such as less than 5 barg and about −158 C, and when sent to eductor 220, BOG 145 may assist in lowering the pressure of stream 215 of HP RLNG 175 flowing to generator 210. HP RLNG 175 may serve as the motive fluid in eductor 220.
At reliquefaction step 325, LP RLNG 225 from expander 200 may be reliquefied using cold box 230 cooled by nitrogen and/or nitrogen expansion loop 235. Power generated from expansion step 315 may be used at powering step 320 to power generator 210, compressor 240 in nitrogen expansion loop 235 and/or other make-up power for reliquefaction system 125. Once reliquefied, LNG 140 obtained from cold box 230 may be transferred to LNG tanker truck 135 at storage step 330. Cryogenic transfer hoses 160 may transfer LNG to storage tank 130 and/or LNG cargo tanks 150 and gas return line 165 may transfer inert gas, BOG 145 and/or natural gas vapor to cold box 230 and/or to eductor 220. BOG 145 from LNG tanks 130, 150 may be returned to cold box 230 and/or sent to generator 210 for fuel at BOG handling step 335. BOG 145 may assist in cooling LP RLNG 225 in cold box 230, may be mixed with HP RLNG 175 in eductor 220 to provide fuel for generator 210 and/or may be utilized rather than vented into the atmosphere. At delivery step 340, tanker truck 135 may transport LNG 140 to facility 155 in need of natural gas. Facility 155 may be off-grid and may have a relatively low-demand that does not justify building a dedicated pipeline.
An apparatus, system and method for reliquefaction of previously regasified LNG has been described. Further modifications and alternative embodiments of various aspects of the invention may be apparent to those skilled in the art in view of this description. Accordingly, this description is to be construed as illustrative only and is for the purpose of teaching those skilled in the art the general manner of carrying out the invention. It is to be understood that the forms of the invention shown and described herein are to be taken as the presently preferred embodiments. Elements and materials may be substituted for those illustrated and described herein, parts and processes may be reversed, and certain features of the invention may be utilized independently, all as would be apparent to one skilled in the art after having the benefit of this description of the invention. Changes may be made in the elements described herein without departing from the scope and range of equivalents as described in the following claims. In addition, it is to be understood that features described herein independently may, in certain embodiments, be combined.
| Filing Document | Filing Date | Country | Kind |
|---|---|---|---|
| PCT/US2018/029425 | 4/25/2018 | WO | 00 |
| Number | Date | Country | |
|---|---|---|---|
| 62490451 | Apr 2017 | US |
