The disclosed technology relates to thermodynamic cycles, and in particular relates to improved power collection schemes from the collapse of magnetic fluxes in a sample for certain types of thermodynamic cycles.
It has previously been proposed to use a sample having temporary magnetic remanence to perform a thermodynamic cycle in which a varying magnetic field is used to produce a magnetic flux in the sample during a first part of the cycle, with the field being removed during a second part of the cycle, leading to collapse of the magnetic domains in the sample and the creation of an independent magnetic flux. It has been proposed to use this principle to convert heat energy into electricity, and also for refrigeration.
An example of a system of this type is described in International Publication No. WO 00/64038 entitled “Thermodynamic Cycles and Method for Generating Electricity” and filed Apr. 19, 2000. Described in WO 00/64038, energy is recovered from the sample once per cycle of the excitation field. In a first step of the cycle, the sample is magnetized, with very little corresponding temperature rise, as the sample is far from the ferromagnetic phase transition point of the sample. The sample is then demagenetized by the removal of the field from the sample, after which the temperature of the sample falls as thermal energy within the sample is expended in working to re-randomize the domains in the sample against the field arising from the remnant magnetism of the sample. After a short time, heat from the surroundings warms the sample, and the magnetic domains within the sample become randomly oriented, and this leads to the generation of an independent magnetic flux as the magnetic field arising from the alignment of the magnetic domains collapses. This independent magnetic flux delivers power to the field generation apparatus.
Disclosed below are representative embodiments of methods, apparatus, and systems that should not be construed as limiting in any way. Instead, the present disclosure is directed toward all novel and non-obvious features and aspects of the various disclosed methods, apparatus, systems, and equivalents thereof, alone and in various combinations and sub-combinations with one another. The present disclosure is not limited to any specific aspect or feature, or combination thereof, nor do the disclosed methods, apparatus, and systems require that any one or more specific advantages be present or problems be solved.
In one exemplary embodiment of the disclosed technology, an apparatus for performing a thermodynamic cycle is disclosed. The exemplary apparatus comprises: a sample that exhibits temporary magnetic remanence; and a magnetization apparatus for magnetizing the sample, wherein the magnetization apparatus is operable, during a first part of the thermodynamic cycle, to produce a cyclically-varying magnetizing field comprising a wavetrain of a single or plurality of consecutive cycles, and to remove the magnetizing field from the sample during a second part of the thermodynamic cycle, wherein demagnetization of the sample during the second part of the thermodynamic cycle causes the generation of an independent magnetic flux.
In another exemplary embodiment of the disclosed technology, an apparatus for performing a thermodynamic cycle is disclosed. The exemplary apparatus comprises: a sample that exhibits temporary electrical remanence; and a polarizing apparatus for polarizing the sample, wherein the polarizing apparatus is operable, during a first part of the thermodynamic cycle, to produce a cyclically-varying electrical field comprising a wavetrain of a single or plurality of consecutive cycles, and to remove the electrical field from the sample during a second part of the thermodynamic cycle, wherein depolarization of the sample during the second part of the thermodynamic cycle causes the generation of an independent electric flux and a transient independent magnetic flux associated with the changing independent electric flux.
In certain desirable embodiments, the periodically-varying magnetizing field is a substantially unipolar or bipolar sinusoidal or half sawtoothed or pulse varying magnetizing field. Preferably, the magnetizing field produces a substantially exponentially-decaying remnant magnetic flux in the sample. The sample can be, for example, a ferrofluid, a ferroset slurry or a ferroset with heat conduction channels therethrough. In some embodiments, the wavetrain comprises at least five consecutive cycles of the magnetizing field (e.g., at least ten consecutive cycles of the magnetizing field). In certain embodiments, the magnetization apparatus also comprises a power collection apparatus, in which power is generated during the second part of the thermodynamic cycle by the independent magnetic flux.
In other certain desirable embodiments, the periodically-varying electric field is a substantially unipolar or bipolar sinusoidal or half sawtoothed or pulse varying polarizing field. Preferably, the polarizing field produces a substantially exponentially-decaying remnant electric flux in the sample. The sample can be, for example, an electret with heat conduction channels therethrough. In some embodiments, the wavetrain comprises at least five consecutive cycles of the polarizing field (e.g., at least ten consecutive cycles of the polarizing field). In certain embodiments, the polarizing apparatus also comprises a power collection apparatus, in which power is generated during the second part of the thermodynamic cycle by the independent electric flux or a transient magnetic field resulting from the independent electric flux.
In another exemplary embodiment, a method of converting energy is disclosed. The exemplary comprises: providing a sample that exhibits temporary magnetic remanence; magnetizing the sample, during a first part of a thermodynamic cycle, by producing a cyclically-varying magnetizing field comprising a wavetrain of a plurality of consecutive cycles; and removing the magnetizing field from the sample during a second part of the thermodynamic cycle, thereby allowing the sample to demagnetize, the demagnetization of the sample causing the generation of an independent magnetic flux. In certain embodiments, the method further comprises the step of converting at least some of the independent magnetic flux into an electric current.
In another exemplary embodiment, a method of converting energy is disclosed. The exemplary comprises: providing a sample that exhibits temporary electrical remanence; polarizing the sample, during a first part of a thermodynamic cycle, by producing a cyclically-varying polarizing field comprising a wavetrain of a plurality of consecutive cycles; and removing the polarizing field from the sample during a second part of the thermodynamic cycle, thereby allowing the sample to depolarize, the depolarizing of the sample causing the generation of an independent electric field. In certain embodiments, the method further comprises the step of converting at least some of the independent electric flux into an electric current.
In another exemplary embodiment, a method of converting energy is disclosed. The exemplary comprises: providing a sample that exhibits temporary electrical remanence; polarizing the sample, during a first part of a thermodynamic cycle, by producing a cyclically-varying polarizing field comprising a wavetrain of a plurality of consecutive cycles; and removing the polarizing field from the sample during a second part of the thermodynamic cycle, thereby allowing the sample to depolarize, the depolarizing of the sample causing the generation of an independent electric field and by Maxwell's equations, a magnetic field. In certain embodiments, the method further comprises the step of converting at least some of the transient independent magnetic flux into an electric current.
In another exemplary embodiment, an apparatus for performing a thermodynamic cycle is disclosed comprising: a sample that exhibits temporary magnetic remanence; and a magnetization apparatus for magnetizing the sample, wherein the magnetization apparatus is operable, during a first part of the thermodynamic cycle, to produce a substantially periodically-varying magnetizing field that is substantially unipolar or bipolar sinusoidal or half sawtoothed or pulse varying, thus producing a substantially unipolar or bipolar sinusoidal or half sawtoothed magnetic flux in the sample with a decaying exponential element at the discontinuities, and to remove the magnetizing field from the sample during a second part of the thermodynamic cycle, wherein demagnetization of the sample during the second part of the thermodynamic cycle causes the generation of an independent magnetic flux. The sample can be, for example, a ferrofluid or a ferro set with heat conduction channels therethrough.
In a further exemplary embodiment, another method for converting energy is disclosed. The exemplary method comprises: providing a sample that exhibits temporary magnetic remanence; magnetizing the sample, during a first part of a thermodynamic cycle, by producing a substantially unipolar or bipolar sinusoidal or half sawtoothed or pulse varying field, thus producing a substantially unipolar or bipolar sinusoidal or half sawtoothed magnetic flux in the sample with a decaying exponential element at the discontinuities; and removing the magnetizing field from the sample during a second part of the thermodynamic cycle, thereby allowing the sample to demagnetize, the demagnetization of the sample causing the generation of an independent magnetic flux. In certain embodiments, the method further comprises the step of converting at least some of the independent magnetic flux into an electric current.
In another exemplary embodiment, an apparatus for performing a thermodynamic cycle is disclosed comprising: a sample that exhibits temporary electric remanence; and a polarizing apparatus for polarizing the sample, wherein the polarization apparatus is operable, during a first part of the thermodynamic cycle, to produce a substantially periodically-varying polarizing field that is a substantially unipolar or bipolar sinusoidal or half sawtoothed or pulse varying field, thus producing a substantially unipolar or bipolar sinusoidal or half sawtoothed electric flux in the sample with a decaying exponential element at the discontinuities, and to remove the polarizing field from the sample during a second part of the thermodynamic cycle, wherein depolarization of the sample during the second part of the thermodynamic cycle causes the generation of an independent electric flux. The sample can be, for example, a ferro set with heat conduction channels therethrough or a plurality of ferrosets suspended in a non-conductive fluid.
In a further exemplary embodiment, another method for converting energy is disclosed. The exemplary method comprises: providing a sample that exhibits temporary electric remanence; polarizing the sample, during a first part of a thermodynamic cycle, by producing a substantially unipolar or bipolar sinusoidal or half sawtoothed or pulse varying field, thus producing a substantially unipolar or bipolar sinusoidal or half sawtoothed electric flux in the sample with a decaying exponential element at the discontinuities; and removing the polarizing field from the sample during a second part of the thermodynamic cycle, thereby allowing the sample to depolarize, the depolarization of the sample causing the generation of an independent electric flux or transient magnetic flux resulting from the changing electric flux. In certain embodiments, the method further comprises the step of converting at least some of the independent electric flux or transient magnetic flux resulting from the changing electric flux into an electric current.
In a further exemplary embodiment, another method for converting energy is disclosed. The exemplary method comprises: providing a sample that exhibits temporary magnetic remanence; magnetizing the sample, during a first part of a thermodynamic cycle, by producing a substantially unipolar or bipolar sinusoidal or half sawtoothed or pulse varying field, thus producing a substantially unipolar or bipolar sinusoidal or half sawtoothed magnetic flux in the sample with a decaying exponential element at the discontinuities; and removing the magnetizing field from the sample during a second part of the thermodynamic cycle, thereby allowing the sample to demagnetize, the demagnetization of the sample causing the generation of an independent magnetic flux. In certain embodiments, the method further comprises the step of converting at least some of the independent magnetic flux into an electric current by superimposing a chopped, inverted copy of the induced current, at a frequency higher than the relaxation rate of the flux remanence, to cancel the re-magnetizing field from the induced current to achieve higher output power.
In a further exemplary embodiment, another method for converting energy is disclosed. The exemplary method comprises: providing a sample that exhibits temporary magnetic remanence; magnetizing the sample, during a first part of a thermodynamic cycle, by producing a substantially unipolar orbipolar sinusoidal or half sawtoothed or pulse varying field, thus producing a substantially unipolar or bipolar sinusoidal or half sawtoothed magnetic flux in the sample with a decaying exponential element at the discontinuities; and removing the magnetizing field from the sample during a second part of the thermodynamic cycle, thereby allowing the sample to demagnetize, the demagnetization of the sample causing the generation of an independent magnetic flux. In certain embodiments, the method further comprises the step of converting at least some of the independent magnetic flux into an electric current by varying the turns-ratio of the output coil and/or the load resistance as the flux decays.
In a further exemplary embodiment, another method for converting energy is disclosed. The exemplary method comprises: providing a sample that exhibits temporary electric remanence; polarizing the sample, during a first part of a thermodynamic cycle, by producing a substantially unipolar or bipolar sinusoidal or half sawtoothed or pulse varying field, thus producing a substantially unipolar or bipolar sinusoidal or half sawtoothed electric flux in the sample with a decaying exponential element at the discontinuities; and removing the polarizing field from the sample during a second part of the thermodynamic cycle, thereby allowing the sample to depolarize, the depolarization of the sample causing the generation of an independent electric flux. In certain embodiments, the method further comprises the step of converting at least some of the independent electric flux into an electric current by causing the generation of a transitory independent magnetic flux from the change in the electric flux. In certain embodiments, the method further comprises the step of converting at least some of the independent magnetic flux into an electric current by superimposing a chopped, inverted copy of the induced current, at a frequency higher than the relaxation rate of the flux remanence, to cancel the re-magnetizing field from the induced current to achieve higher output power.
In a further exemplary embodiment, another method for converting energy is disclosed. The exemplary method comprises: providing a sample that exhibits temporary electric remanence; polarizing the sample, during a first part of a thermodynamic cycle, by producing a substantially unipolar or bipolar sinusoidal or half sawtoothed or pulse varying field, thus producing a substantially unipolar or bipolar sinusoidal or half sawtoothed electric flux in the sample with a decaying exponential element at the discontinuities; and removing the polarizing field from the sample during a second part of the thermodynamic cycle, thereby allowing the sample to depolarize, the depolarization of the sample causing the generation of an independent electric flux. In certain embodiments, the method further comprises the step of converting at least some of the independent electric flux into an electric current by varying the load resistance as the flux decays.
The foregoing and other objects, features, and advantages of the invention will become more apparent from the following detailed description, which proceeds with reference to the accompanying figures.
Appendix 1 contains the MatLab computer simulation code for the magnetic temporary remanence device state equations.
This document concerns improvements to a method of generating electricity given by the plant diagram 1 in
The power extraction area has the working substance 3 in a typical configuration given in
With reference to
With reference to
With reference to
In this section we explain a temporal phenomenon that seems to limit the dipole-work to being under the supplied magnetization energy if the load resistance is only linear; the implication being that a non-linear impedance will allow the dipole-work to exceed the magnetization energy input or by some other method (the Field Cancellation Method).
The Electrical State Equations for the Magnetic Temporary Remanence Cycle
A mathematical model can be constructed for the working substance and electrical output circuit. Let us first consider the ferrofluid flux decaying into a linear resistor.
Reference
The flux linkage is given by (μ, is the relative permeability):
λ−NAB⇒NAμ0μr(H+M) eqn. 1
The magnetic field is given by:
(reference is also made
Where i is the current through the coil, N is the number of turns and D is the length. The ferrofluid or super-paramagnetic material in general obeys a 1st order equation and implicit in this is the convolution of the H field 10 with magnetization M 11, 12. Advantageously, the H field 10 is switched on slowly relative to the relaxation rate of the working substance 3 so that dissipative processes are minimised:
That is, the rate of change of the magnetization is negatively proportional to the existing magnetization minus the driving contribution of the magnetic field (boosted by the susceptibility x and permeability of the co-material 6 μ,l), thus when H is substituted, the following is obtained:
The LR circuit 9, 16, 18, on analysis considering the voltages yields the following, another state space equation:
Or substituting
from eqn. 4,
With reference to
A simple electrical load only returns part of the magnetization energy 23 and that dipole work plateaus 22. We shall investigate this with the following theory:
With reference to
The integrand has been resolved with the relative permeability of the co-material 6 in close proximity to the working substance subsumed into M′. We can further write the integrand by M′=μXH as (dropping the primes):
With reference to the lower figures in
The dominant pole near the origin sets the dynamics, and a binomial series expansion of the roots of the denominator gives:
The dominant pole gives the response:
Thus
the 2nd term is a purely electrical circuit effect (inductor-resistor circuit) which dominates at high loading (R→0). The current 25 induced into the power output coils 9 is then:
The electrical work delivered to the load is:
by which we can calculate the work as the time constant stretches to infinity (the plateau 22 of the dipole-work on
This expression for the ultimate simple dipole-work, eqn. 12 is seen to be less than the magnetization energy eqn. 8.
The “H-Field Cancellation” Method
Reference
In the previous section it was shown that a resistive electrical load 16 on its own only returned part of the input magnetization work. What was manifest was a slowing in the time constant (
The technique is to provide a cancelling magnetic field that has no effect on the ferrofluid or the power extraction circuit and this is depicted in
Essentially what occurs is that the current 25 in the output power coil 9 re-magnetizes the working substance 3 and co-material 6 and slows the current waveform (
It is not a simple matter of just supplying an opposite field as a null-transformer will result. We shall discuss this shortly in the next section looking at the electrical analysis. Essentially, a superimposed field around the working substance needs to be created, that is of such high frequency, that it is averaged to substantially zero by the slow relaxation rate of the working substance 3.
Comparing the current and magnetization vs. time traces in the lower figures of
With reference to
sin A·sin B=½ cos(A−B)−½ cos(A+B) eqn. 13
The lowest legend represents the superposition of the field from the current 25 and the field from the cancellation current 26. It can be seen that the low frequency component, that the working substance 3 would respond to, is obliterated. In
The Electrical Circuit and Electrical Analysis of the Work Required by the H-Field Cancellation Circuit
With reference to
We proceed to analyse the energetics of the scheme by the equivalent circuit of a null transformer (
The sense of the currents and voltages from the self and mutual inductances and the decaying ferrofluid (working substance 3 and co-material 6) flux,
is shown. It is quite clear that the LHS current mirror does work against the decaying ferrofluid flux and this is of course at least equal to the work that is supposed to be delivered onto the RHS into the load. It is obvious that no power is delivered to the load. Another way of putting this is, of course, that it is a null transformer with changes in magnetic field excluded from the coils' interior. Another way, still, is to note that the current in the LHS circuit is equal and opposite to the RHS and that this is induced into the RHS circuit nullifying all current.
Next we note the addition of the filtering circuit elements, the high pass (and storage capacitor) on the LHS and the high frequency inductor (hf choke) on the RHS in
This can be understood by a simple potential divider effect (
The current 26 in the LHS circuit is set-up by the current mirror 32 (
Further to the argument, the current source mainly performs electrical work establishing the cancellation magnetic field on the LHS. This can be recouped with high efficiency by a “flyback” circuit 30, 31 (
Considering now the work of the chopping circuit on the right-hand power output circuit (
This time we note that, the high frequency chopping field results in an high impedance from the choke 34; very little electrical work is thus expended by the chopping circuit on the power output circuit.
1.1.1. Dynamic Analysis of the H-Field Cancellation Method and the Ultimate Electrical Work
We now follow the same procedure with the state equations of eqn. 3, eqn. 4 and eqn. 6 but with the re-magnetizing H-field removed from equation 3, to yield the transform of the induced current 25:
Whereupon the current in the time domain by the dominant pole is:
The dipole-work by the cancellation method in the limit is obtained, once again, by
This is seen to be the magnetic field energy of the ferrofluid flux (the plateau 24,
The cancellation method has been proven in experiment and simulation (appendix 1) in the first instance by the simple expedient of zeroing the re-magnetization term:
The results are displayed in
A more physical simulation, other than the “trick” of zeroing the H-field is implemented at the end of appendix 1 by a high frequency cancellation H-field:
Though this code is much slower to run due to the fine time-scale needed to simulate the cancellation field and the potentially long time scale of the electrical circuit.
With reference to
with variation of the parameter Xμ, which is the effective susceptibility of the ferrofluid/working substance 3 with the high permeability co-material 6 present and this is plotted in
The power produced by the device is then:
P−(Wdw.cancel−Emag−Wlosses)Fcycle eqn. 18
Method of Excess Power by Non-Linear Impedances
Reference is made to
The first problem we shall address is the electrical time constant dominating and swamping the quicker time constant of the ferrofluid. As has been seen in the linear case, we aim for low output impedances (which can always be matched to a load or the load is just used as a heating element for a conventional Carnot cycle) as these obtain the most energy on each cycle, however they are the slowest (
The first method is, under computer control for the computer to vary the turns ratio of the output coil and the output resistance. This method is able to achieve the highest energy returned from the decaying ferrofluid in a finite time scale.
The inductance has been expanded into a well-known form for the inductance of a long solenoid.
Another constraint can be found from adjusting the rate of non-linear power output (just EMF2/R) to be greater than the linear case magnetizing the ferrofluid as a baseline.
Where the constants K2 is a multiple of the magnetizing energy and K3 is the time scale of linear magnetization (the ferrofluid is switched on slower than its 3-dB point so that needless dissipation doesn't occur. K3 works out about 3).
Into eqn. 20 is substituted eqn. 3 and we solve this for R(i,t) which is then substituted into inequality eqn. 19 leading to eventually:
Overall the solutions for N(i,t) and R(i,t) are constrained (physically) as:
With the conditions:
Device Based on Electrical Remanence
Reference is made to
In constructing the electrostatic dual of the temporary remanence cycle, there are subtle similarities and differences. Both involve a charging and discharging phase: one with magnetic flux and an energy cost of the magnetizing energy, the other electric or polarization flux and the energy cost of polarization energy. Both too would seem to have a “lossy” tank where this input energy is converted to internal energy (“heat”) at the rate a function of:
However, as we saw with the magnetic system:
The re-magnetizing field is in the same sense (if one can imagine the entry and exit wires of the solenoid as parallel to the axial field) as the current and original magnetizing field; furthermore, this re-magnetizing field can be cancelled by the field cancellation method to leave, via eqn. 5, a means of getting dipole work that exceeds the input energy cost; the difference in the two is the thermal energy converted (see Cornwall's thesis).
Eqn. 5 comes directly from the 2nd Maxwell/Faraday's Law equation in integral form, which is then equated to the potential drop across the resistor. No such law exists in the electrostatic case regarding the flux and discharge and this always leads to the return of the electrostatic field energy ½ϵoEdE·dV and polarization energy EdP·dV (from EdD·dV):
From the 1st Maxwell equation/Gauss' Law:
And hence,
This represents a combination of the electric field at the plates of the capacitor and the electric field from the polarization. The movement of the free charges is the circuit current, thus:
Multiplying both sides the voltage across the plates, i.e.
yields,
Which upon integration w·r·t. time,
⇒(ϵ0EdE+EdP)V vi eqn. 25
This is just seen to be the differential electrostatic work EdD and the instantaneous electrical power.
We also note in this case too, that the first state equation becomes:
No de-polarization cancelling method can be made to strike out the term Xϵoϵ,E, when we realize that the potential across the load resistor is negative and acts to increase the rate of decay further. This only reflects energy leaving the capacitor “tank” (in competition to that being converted to heat), as it should.
The power extraction area 5 can be implemented with the electrical dual of magnetism, electrostatics. By the 4th Maxwell equation, the changing electrical field from the temporary polarization creates a temporary magnetic field. This then amounts immediately to an analogous situation with the magnetic device and a further embodiment (
Where P is the polarization and E is the electric field strength. The electrically polarizable working substance 3 can have its electrical susceptibility x increased with electrically polarizable co-material 35 (
From the definition of electrical polarization by the first Maxwell equation as being the electric field (E-field) produced by bound charges, we can write:
Note that the electric field has two components: The E-field from the polarization and the E-field which results from the displacement current, Etemp.
Let us consider Etemp first. The fourth Maxwell equation includes the displacement current term. We are considering a dielectric so the current density term is left out:
The electric field results from the polarization along the x-axis, which is the axis of the capacitor, so we can write:
Thus the curl operator can only have components in the yz plane:
For simplicity we shall consider cylindrical symmetry and we know that the B-field will circulate around the changing Px vector. Using Stoke's Identity to relate the line integral of the curl of B to the surface integral of the flux from P, we find:
Thus the temporary independent magnetic flux is:
This B-field is itself changing and will lead to Etemp and so on, as a series in powers of 1/c2, so we safely truncate it to first order in 1/c2. The E-field is given by Maxwell's 2nd equation:
Which we know from Stoke's Identity will lead to an E-field perpendicular to the plane yz, that is, in the anti-x axis direction (
is negative), increasing with magnitude with the radius (that is, our line integral path is an axially aligned loop through the centre of the capacitor, see
The path at the centre contributes nothing, so we can write (V is the volume, n is the turns per unit length):
A further embodiment of this device is thus apparent and shown in
Much the same argument as regards the magnetization field (
The non-linear approach can be applied too to this embodiment of the device by varying the load resistance (
The following claims include dependent claims which are not repeated for all of the independent claims. However, unless wherein it would be inconsistent, it should be understood that the features of any of the dependent claims may be combined with any of the independent claims.
When used in this specification and claims, the terms “comprises” and “comprising” and variations thereof mean that the specified features, steps or integers are included. The terms are not to be interpreted to exclude the presence of other features, steps or components.
The features disclosed in the foregoing description, or the following claims, or the accompanying drawings, expressed in their specific forms or in terms of a means for performing the disclosed function, or a method or process for attaining the disclosed result, as appropriate, may, separately, or in any combination of such features, be utilized for realizing the invention in diverse forms thereof.
Number | Date | Country | Kind |
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1308877.8 | May 2013 | GB | national |
1312644.6 | Jul 2013 | GB | national |
1312753.5 | Jul 2013 | GB | national |
1314507.3 | Aug 2013 | GB | national |
Filing Document | Filing Date | Country | Kind |
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PCT/GB2014/051504 | 5/16/2014 | WO | 00 |
Publishing Document | Publishing Date | Country | Kind |
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WO2014/184572 | 11/20/2014 | WO | A |
Number | Name | Date | Kind |
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6725668 | Cornwall | Apr 2004 | B1 |
7746203 | Cornwall | Jun 2010 | B2 |
Number | Date | Country | |
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20160094159 A1 | Mar 2016 | US |