1. Technical Field
Embodiments of the present invention relate generally to solar thermal energy absorber tubes used in the collection and use of solar thermal energy by solar concentrators and solar collector systems. More particularly, the various embodiments provide an inner tube of an absorber tube that comprises a metallic coating layer, which minimizes permeation of hydrogen from a fluid within the inner tube and into an evacuated cavity formed between the inner tube and an outer surrounding tube. Various embodiments further provide an interface assembly, which permits the use of differing materials between an absorption portion and a mounting portion of the inner tube.
2. Description of Related Art
Solar concentrators and solar collector systems work by collecting solar thermal energy (e.g., sunlight) from a large area and concentrating it into a smaller area. Various types of solar concentrators and solar collector systems exist and include at least parabolic solar concentrators. Parabolic solar concentrators use mirrored surfaces curved in a parabolic shape to focus sunlight onto the mathematical focal point of their inherent parabola. Trough-shaped parabolic solar concentrators (e.g., parabolic troughs), like various other types of solar collector systems, typically comprise elongated absorber tubes, or heat collection elements (HCE), which run the length of the trough. A longitudinal axis of the absorber tube generally corresponds to the focal region. In this manner, the parabolic trough focuses sunlight directly onto the absorber tube.
Parabolic trough solar concentrators are generally positioned in solar collector system fields, often containing hundreds, if not thousands, of adjacently positioned parabolic trough solar concentrators. Together, the multiple adjacently positioned parabolic trough solar concentrators may form a parabolic trough power plant. In such parabolic trough power plants, a fluid, typically oil, runs through each of the absorber tubes positioned in the focal region of each of the parabolic troughs. The focused sunlight upon each of the absorber tubes heats the fluid to high temperatures before the fluid passes through a heat exchanger, which generates steam. The steam may then be used to run a conventional power plant.
Many absorber tubes, as commonly known and understood in the art, comprise an inner tube formed from a single piece of material. Generally speaking, the inner tube is formed from a stainless steel material, as such provides the anti-corrosive properties necessary to withstand various external environmental conditions encountered during use. However, stainless steel material is relatively heavy, weak, and exhibits properties that result in a relatively slow heat transfer rate, all of which contribute to various degrees of inefficiencies within solar concentrators and solar collector systems. As such, a need exists for an inner tube configuration that provides improved characteristics relative to those generally viewed as lacking in stainless steel, while also not sacrificing those advantageous characteristics of stainless steel (e.g., weather resistance).
Many absorber tubes, as commonly known and understood in the art, comprise an absorbing layer or coating that is configured to facilitate, or at best not impede, the transmittal of thermal energy (e.g., sunlight) through the inner tube of the absorber tube and thus into the fluid contained therein. Such inner tubes, however, generally remain susceptible to migration and/or permeation of hydrogen molecules (e.g., from the heated fluid) into a space between the inner and outer tubes of the absorber tube. Various techniques have been employed to minimize such migration and/or permeation, with at least some conventional absorber tubes incorporating a plurality of getters in the space configured to absorb the hydrogen molecules. However, getters may require additional maintenance, may block at least a portion of thermal energy transmission to the fluid, and/or may not fully prevent migration and/or permeation. As such, a need exists for an absorber tube configuration that provides an improved degree of migration and/or permeation prevention, while also minimizing the need for the plurality of getters, as previously described herein.
Various embodiments of the present invention provide an absorber tube that comprises an inner tube having an exterior surface, at least a portion of which contains a plurality of coating layers. Various embodiments of the present invention still further provide an inner tube having a connecting member located between central and end portions of the tube, wherein the central portion may be formed from carbon steel and/or coated with at least a reflective layer.
More specifically, according to various embodiments, an absorber tube configured for the collection of solar thermal energy in a solar concentrator system is provided. The absorber tube comprises an inner tube comprising an interior surface and an exterior surface, at least a portion of the exterior surface comprising a plurality of coating layers; and an outer tube substantially surrounding the inner tube and being spaced apart from and concentric with the inner tube so as to define a cavity between the inner tube and the outer tube, wherein at least one of the plurality of coating layers is configured to substantially impede migration of gaseous molecular particles from the interior surface of the inner tube and into the cavity.
In certain embodiments, the plurality of coating layers comprise a copper coating, the copper coating being operatively adhered to the exterior surface of the inner tube by generating an electrical charge between the copper coating and the exterior surface, the copper coating further being configured to deflect a substantial portion of the gaseous molecular particles toward an interior volume of the inner tube so as to substantially impede migration of gaseous molecular particles from the interior volume and into the cavity between the inner tube and the outer tube.
According to various embodiments, an absorber tube configured for the collection of solar thermal energy in a solar concentrator system is also provided. The absorber tube comprises an inner tube comprising: (A) a central portion; (B) at least one end portion, the at least one end portion being configured to facilitate mounting the absorber tube relative to the solar concentrator system; and (C) at least one connecting member, the at least one connecting member being located intermediate the central portion and the at least one end portion. The central portion of the inner tube is formed from a steel-based material having a structural composition substantially different from a material of the at least one end portion.
In certain embodiments, the connecting member comprises an annular ring portion and a protrusion portion. A diameter of the annular ring portion is substantially the same as a diameter of an interior surface of the inner tube, such that at least a portion of the annular ring portion is configured to form a seal between the interior surface of the inner tube and the connecting member; and a diameter of the protrusion portion is substantially the same as a diameter of an exterior surface of the inner tube, such that at least a portion of the protrusion portion is configured to form a seal between a passage through the inner tube and the connecting member.
In certain embodiments, the at least one end portion comprises a first end portion and a second end portion; the at least one connecting member comprises a first connecting member and a second connecting member, the first connecting member being located intermediate the central portion and the first end portion, the second connecting member being located intermediate the central portion and the second end portion; the first connecting member comprises a first annular ring portion and a first protrusion portion, a diameter of the first annular ring portion being substantially the same as a diameter of an interior surface of the inner tube, such that at least a portion of the first annular ring portion is configured to form a seal between the interior surface of the inner tube and the first connecting member, a diameter of the first protrusion portion being substantially the same as a diameter of an exterior surface of the inner tube, such that at least a portion of the first protrusion portion is configured to form a seal between a passage through the inner tube and the first connecting member; and the second connecting member comprises a second annular ring portion and a second protrusion portion, a diameter of the second annular ring portion being substantially the same as a diameter of an interior surface of the inner tube, such that at least a portion of the second annular ring portion is configured to form a seal between the interior surface of the inner tube and the second connecting member, a diameter of the second protrusion portion being substantially the same as a diameter of an exterior surface of the inner tube, such that at least a portion of the second protrusion portion is configured to form a seal between a passage through the inner tube and the second connecting member.
Still further, according to various embodiments, a method is provided for manufacturing an absorber tube configured for the collection of solar thermal energy in a solar concentrator system. The method comprises the steps of: (A) providing an absorber tube comprising: (1) an inner tube comprising an interior surface and an exterior surface; and (2) an outer tube substantially surrounding the inner tube and being spaced apart from and concentric with the inner tube so as to define a cavity between the inner tube and the outer tube; (B) inserting a reflective coating material into the cavity between the inner tube and the outer tube; and (C) creating an electrically charged vacuum within the cavity, such that the reflective coating material is electrically attracted to and thus adhered to the exterior surface of the inner tube.
In certain embodiments, the method further involves the reflective layer comprising a copper coating; the copper coating being negatively charged; and the vacuum being positively charged so as to cause the copper coating to be forced into contact with the exterior surface of the inner tube.
The accompanying drawings incorporated herein and forming a part of the disclosure illustrate several aspects of the present invention and together with the detailed description serve to explain certain principles of the present invention. In the drawings, which are not necessarily drawn to scale:
Various embodiments of the present invention will now be described more fully hereinafter with reference to the accompanying drawings, in which some, but not all embodiments of the invention are shown. Indeed, embodiments of the invention may be embodied in many different forms and should not be construed as limited to the embodiments set forth herein. Rather, these embodiments are provided so that this disclosure will satisfy applicable legal requirements. Unless otherwise defined, all technical and scientific terms used herein have the same meaning as commonly known and understood by one of ordinary skill in the art to which the invention relates. The term “or” is used herein in both the alternative and conjunctive sense, unless otherwise indicated. Like numbers refer to like elements throughout.
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Still further, as commonly known and understood in the art, additional parabolic trough 10 and absorber tubes 14 may be physically positioned adjacent one another so as to provide for additional solar energy collection capabilities. In various embodiments, the parabolic mirrors 12 and/or absorber tubes 14 may also be made mobile such that their orientation may be adjusted in accordance with movement of the sun so as to achieve maximum solar collection. Such and still other possible configurations, as commonly known and understood in the art, are described in further detail in at least U.S. Patent Application Publication No. 2010/0126499 filed by Wei David Lu of Greer, S.C. and incorporated herein by reference in its entirety.
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According to various embodiments, at least a portion of the inner tube 22 may be formed from a material substantially different from that of the remainder of the inner tube 22 and/or the outer tube 16. In certain embodiments, at least the absorption portion 24 of the inner tube 22 is formed from carbon steel material, while the mounting portion 30 and the outer tube 16 are formed from a commonly known stainless steel material (e.g., the non-limiting examples of a Series 300—304, 310, or 316—rated stainless steel). In this manner, the absorption portion 24 of the inner tube 22 provides in various embodiments improved performance characteristics relative to commonly known inner tubes 22 fully formed from stainless steel.
As non-limiting examples, the formation of at least the absorption portion 24 from a carbon steel material results in an overall lighter weight of the absorber tube 14, a harder and stronger surface to withstand operational conditions, and/or a heightened rate of heat transfer of thermal energy to the fluid 15 within the absorber tube. Still further, in certain embodiments, the formation of at least the absorption portion 24 from a carbon steel material results in an expansion of the absorption portion 24 (e.g., along its longitudinal length) of approximately one inch (1″), for absorber tubes 14 having a total length of approximately four meters (4 m). Such is in comparison to an expansion (along the same longitudinal length) of approximately six inches (6″) for absorber tubes 14 formed entirely from stainless rather than carbon steel. As such, in these and still other embodiments, an additional non-limiting advantage exists in that less complex and smaller expansion elements 40 may be incorporated within the absorber 14, thereby reducing costs and inefficiencies otherwise oftentimes encountered.
According to various embodiments, the inner tube 22 of the absorber tube 14 may contain a fluid 15 that is generally heated as a result of the passage of thermal energy (e.g., sunlight) into the inner tube, as has been previously described herein. In certain embodiments, the fluid 15 may comprise a hydrocarbon (CxHy), such as the non-limiting example of crude oil. As commonly known and understood in the art, and as has been described in at least U.S. Patent Application Publication No. 2010/0126499 filed by Wei David Lu of Greer, S.C. and incorporated herein by reference in its entirety, gas molecules (e.g., hydrogen in oils) separate when heated, causing them to oftentimes permeate from within the inner tube 22 and into the space 60 adjacent the outer tube 16, thus creating concerns and inefficiencies as previously described herein. Various types of permeating gas molecules, also commonly known and understood in the art, include the non-limiting examples of air, carbon dioxide, carbon monoxide, nitrogen, oxygen, and/or water.
Various configurations of absorber tubes 14 have sought to mitigate problems associated with gas permeation by incorporating a plurality of getters 50 (see
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As a non-limiting example, the copper layer 36 may be adhered to at least a portion of the inner tube 22 by electrically charging the copper layer upon it being placed within the space 60 between the inner tube and the outer tube 16. In certain embodiments, a vacuum created within the space 60 may be initially positively charged. Upon insertion, the copper layer 36 may be negatively charged, thus causing the copper layer to be forced into contact (e.g., via electromagnetic forces) with the outer wall 24 of the inner tube 22. It should be understood that, in other embodiments, the copper layer 36 may be adhered to at least a portion of the inner tube 22 in any of a variety of commonly known and understood methods, as may be desirable or perhaps advantageous for a particular application.
It should be understood that the physical characteristics of copper provide a unique combination of heat loss and reflectivity. In particular, according to various embodiments wherein gas molecules are subject to permeation from within the inner tube 22 and out into the space 60 adjacent the outer tube 16, the copper layer 36 provides a reflective surface that not only impedes the gas molecules (e.g., hydrogen) from escaping the inner tube 22, but also reflects such back into the fluid 15 contained therein, thereby improving the overall efficiency of a solar concentrator or solar collection system upon which the absorber tube 14 according to various embodiments is installed. It should be understood that in certain embodiments, provision of the copper layer 36 impedes migration and/or permeation of gas molecules, while in other embodiments, the copper layer 36 may be configured so as to substantially prevent the same. In still other embodiments, the copper layer 36 may be configured so as to impede migration and/or permeation of gas molecules to a particular degree sufficient to reduce by ¼ the number of getters 50 required within the space 60, while in further envisioned embodiments, the copper layer 36 may enable a greater degree of reduction in the number of getters 50, as may be desirable for a particular application.
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In various embodiments, the absorber layer 38 and the copper layer 36 are adhered relative to one another via a bonding layer 37. In certain embodiments, the bonding layer is an aluminum nitride—stainless steel coating that provides adhesive characteristics between the absorber and copper layers 36, 38. In other embodiments, the bonding layer may be any of a variety of commonly known and used adhesive materials sufficient to bond two respective coating layers relative to one another. It should be understood, however, that in these and still other embodiments, the bonding layer 37, like the absorber layer 38 must likewise be configured so as to not substantially impede the absorption of thermal energy into the inner tube 22 and the fluid 15 contained therein.
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Indeed, many modifications and other embodiments of the invention set forth herein will come to mind to one skilled in the art to which this invention pertains having the benefit of the teachings presented in the foregoing descriptions and the associated drawings. Therefore, it is to be understood that the invention is not to be limited to the specific embodiments disclosed and that modifications and other embodiments are intended to be included within the scope of the appended claims. Although specific terms are employed herein, they are used in a generic and descriptive sense only and not for purposes of limitation.
This application claims priority to and the benefit of U.S. Application No. 61/585,868 entitled, “Apparatuses and Methods for Providing a Solar Thermal Energy Absorber Tube for a Solar Collector System” that was filed on Jan. 12, 2012, the entirety which is hereby incorporated by reference herein.
Number | Date | Country | |
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61585868 | Jan 2012 | US |