APPAREL AND METHOD OF MAKING THE SAME

Abstract
A garment includes a printed layer including a thermal regulation material located on a first side of a fabric defining a portion of the garment, where the printed layer includes a plurality of printed segments of the thermal regulation material. Hinges for the fabric are defined by non-printed segments of the fabric that are located between printed segments, and the hinges facilitate folding of the fabric along one or more of the hinges. A method of forming the garment is also described.
Description
FIELD

This application relates to the field of textiles, and particularly to garments and other articles of apparel designed for heat retention.


BACKGROUND

It is often desirable for a garment to include thermal regulation features. In some scenarios, it is desirable to provide articles of apparel that provide heat retention properties. For example, athletic performance apparel, including hunting jackets, boots, and other articles of apparel intended for outdoor use may include multiple layers and various materials designed to retain body heat in order to keep the wearer warm in cold weather. It is generally desirable for such garments and other articles of apparel to be relatively light in weight and capable of providing heat retention features without sacrificing other qualities, such as garment breathability and moisture wicking.


Ceramic materials have been used on garments in the past to provide heat retention qualities. Such ceramic materials are typically added as a thin layer to fabric and provide good heat retention features for the garment. Unfortunately, conventional ceramic materials and methods of applying such ceramic materials have diminished garment performance in other areas, including poor breathability and moisture management. In addition, many ceramic materials added to garments have resulted in an undesirable finish and have deteriorated quickly with repeated washing and wear. Furthermore, various alternative materials to ceramics which are capable of providing heat retaining qualities have result in garments with other undesirable qualities. For example, some alternative heat retaining materials provide an undesirable shiny finish on the garment with poor breathability and wash-fastness.


In other scenarios, it is desirable to provide thermal regulation in the form of a cooling effect to facilitate or enhance body cooling to the wearer of a garment or article of apparel. For example, an athlete generates heat as a result of physical activity, where skin and/or core body temperature rise during sustained physical exertion. Failure to properly move heat away from the body during exercise may lead to “overheating,” i.e., a rise in the core body temperature, potentially resulting in adverse health consequences, such as heat exhaustion or heat stroke. Accordingly, performance apparel may be configured to aid in the regulation of body temperature, with its aim being to keep the wearer cool. One approach configures a garment such that it draws moisture away from the skin. Other approaches equip the garment with tubes through which a cooling fluid flows, while still others provide the garment with pockets that receive cooling packs of various materials. These conventional approaches, however, suffer from disadvantages. Absorbent material, while increasing the comfort of the wearer, does not facilitate absorbing of heat. Cooling tubes and packs, while effective cooling mechanisms, add significant weight to the garment.


In view of the foregoing, it would be advantageous to provide garments and other articles of apparel incorporating material(s) for achieving a desired heat retention and/or thermal regulation effect for the wearer in particular scenarios. For example, in cold environment scenarios, it would be desirable to incorporate ceramic materials for heat retention without sacrificing other performance qualities. In warmer environments or scenarios in which the wearer's body temperature may increase due to physical activity (e.g., athletic performance), it would be desirable to provide a lightweight article of apparel effective to cool and/or temper the increase in temperature of the user. It would be advantageous if such garments provided excellent heat retention qualities while retaining good durability, breathability and moisture wicking qualities. Additionally, it would be advantageous if such garments provided a comfortable look and feel for the wearer.


SUMMARY

In accordance with at least one embodiment, a method of manufacturing a garment comprises printing a material onto a first side of a fabric to form a printed layer including a plurality of printed segments of the material. Hinges for the fabric are defined by non-printed segments of the fabric that are located between printed segments, and the hinges facilitate folding of the fabric along one or more of the hinges.


In at least another embodiment, a garment comprises a printed layer comprising a material located on a first side of a fabric defining a portion of the garment, the printed layer including a plurality of printed segments of the material. Hinges for the fabric are defined by non-printed segments of the fabric that are located between printed segments, and the hinges facilitate folding of the fabric along one or more of the hinges.


The printed segments can comprise a heat retention material and/or a thermal regulation material.


The above described features and advantages, as well as others, will become more readily apparent to those of ordinary skill in the art by reference to the following detailed description and accompanying drawings. While it would be desirable to provide a garment that provides one or more of these or other advantageous features, the teachings disclosed herein extend to those embodiments which fall within the scope of the appended claims, regardless of whether they accomplish one or more of the above-mentioned advantages.





BRIEF DESCRIPTION OF THE DRAWINGS


FIG. 1 is a front view of a shirt including a heat retention layer;



FIG. 2 is a cross-sectional view of fabric for the shirt of FIG. 1 including an outer layer, an inner layer, and a heat retention layer;



FIG. 3 is a bottom view of the fabric of FIG. 2 showing a pattern for the heat retention layer on the inner layer; and



FIG. 4 is a block diagram showing a method for making an article of apparel including with the heat retention layer of FIG. 3;



FIG. 5A depicts an example embodiment of a printed pattern that can be applied to surface portions of a fabric;



FIG. 5B is an enlarged view of a portion of the printed pattern of FIG. 5A; and



FIG. 6 is a chart illustrating the heat retention qualities of a fabric with the ceramic print described herein in comparison to the same fabric without the ceramic print described herein.



FIG. 7 is an example embodiment of a rotogravure apparatus used to imprint a material (e.g., a heat retention material and/or a thermal regulation material) in a pattern along a surface of a textile for a garment in a manner as described herein.





DETAILED DESCRIPTION

Example embodiments of garments or articles of apparel incorporating a material as a printed layer along a surface or side of fabric material forming the garment are now described with reference to the drawings. As described herein, the material can comprise a heat retaining or heat retention material (e.g., a ceramic, such as silica) and/or a thermal regulation material including one or more system reactive components so as to achieve heat retaining and/or thermal regulation properties for the garment.


With reference to FIG. 1, in at least one embodiment, an article of apparel with a heat retention layer is provided in the form of a garment, and particularly a shirt 10. The shirt 10 includes a torso portion 12, arms 14, and a neck opening 16. The shirt 10 is comprised of one or more sheets of material, and particularly fabric panels 20 connected together to form the garment. Each fabric panel 20 includes an outer side 22 and an inner side 24, as defined by the intended configuration of the item of apparel when worn by a user. A ceramic print 36 is provided as an additional layer on the inner side 24 of the fabric panel 20 in order to provide a heat retention layer for the wearer of the garment.


As shown in FIG. 2, in at least one embodiment, the fabric panel 20 is a multi-layer sheet of fabric including an outer layer 32 and an inner layer 34. The outer layer 32 and the inner layer 34 may be comprised of the same material or different materials. In at least one embodiment, the outer layer 32 and the inner layer 34 are both provided by a material comprised of polyester fibers. However, it will be recognized that the material may include any number of different fibers including cotton, nylon, or any of various other natural or synthetic fibers. In at least one embodiment, the material provided for the outer layer 32 and the inner layer 34 is a compression material that includes elastane or other elastic fibers. It will be recognized that the multi-layer fabric panel 20 disclosed herein is advantageous for providing heat retention qualities for the garment. However, in other embodiments the fabric panel 20 may be only a single layer rather than a multi-layer fabric. Additionally, in other embodiments, a sheet of material that is not fabric may be used instead of the fabric panel to form portions of the garment or other article of apparel.


With continued reference to FIG. 2, a ceramic print 36 is provided on the inner side 24 of the fabric panel 20. In at least one embodiment, the ceramic print 36 is provided by a layer of an aqueous solution or paste comprising a ceramic material. Such aqueous solutions or pastes comprising a ceramic material are referred to herein as “ceramic inks”. However, it will be recognized that such ceramic inks need not be applied to the fabric panel 20 in any particular manner or with any particular device.


In at least one embodiment, the ceramic ink comprises at least two percent ceramic by weight and less than fifty percent ceramic by weight. In at least one embodiment, the ceramic print is provided by an ink comprising between five percent and fifteen percent ceramic by weight, and particularly about ten percent ceramic by weight. The ceramic may be any of various ceramics appropriate for inclusion on a fabric including both oxide ceramics and non-oxide ceramics. In at least one embodiment, the ceramic material in the ceramic print is a high temperature molten silica. However, it will be recognized that the ceramic may be any of various other ceramic materials such as zirconium carbide, aluminum oxide, or any of various other ceramic materials.


As shown in FIG. 2, the ceramic print 36 does not completely cover the inner side 24 of the fabric panel 20. Accordingly, the ceramic ink may be provided on the fabric panel 20 in a pattern that provides ink covered portions 38 and non-ink portions 40 on the inner side 24 of the fabric panel 20. The non-ink portions are generally voids in the print pattern that expose the inner surface of the fabric panel 20. In this manner, the ink covered portions 38 and the non-ink portions define a discontinuous print on the fabric panel 20. In at least one embodiment, the ceramic print 36 covers between twenty percent and eighty percent of the inner side 24 of the fabric panel 20 (i.e., twenty to eighty percent of the surface area on the inner side 24 of the fabric portion 20 is covered by an ink covered portion 38). More particularly, in at least one embodiment, the ceramic print 36 covers between thirty and fifty percent of the inner side 24 of the fabric panel 20, and particularly about forty percent of the inner side 24 of the fabric panel 20.


With reference now to FIG. 3, an exemplary pattern for the ceramic print 36 is shown on the inner side 24 of the fabric panel 20. The pattern includes a plurality of linear members 50 provided by the ink covered portions 38 and a plurality of channels 70 provided by the non-ink portions. In the embodiment of FIG. 3, the plurality of linear members 50 include partial hexagon shapes. The plurality of partial hexagon shapes include four linear members 50 that are connected together to form a house shape 52 characterized by two parallel walls 54 connected to two angled roof portions 56 that meet at an apex 58. Additionally, in the embodiment of FIG. 3, most of the house shapes 52 include two additional linear members 50 provided by a short leg 60 positioned at the base of each parallel wall 54. Each short leg 60 is parallel to one of the roof sections 56.


The house shapes 52 are provided in a nested arrangement 64, as shown in FIG. 3, with successively smaller house shapes positioned to the inside of larger house shapes. In various embodiments, between three and twenty house shapes 52 are nested together. However, it will be recognized that any number of house shapes 52 may be utilized within the nested arrangement 64. A single linear member 66 is provided at a middle of the nested arrangement 64. Each successively smaller house shape is positioned slightly lower in the nested arrangement 64 than the immediately larger house shape. As a result, the ends of the short legs 60 provide a broken border 68 on the lower side of the nested arrangement 64. This broken border 68 includes two sides that angle toward one another at an angle that is equivalent to the angle of the roof portions 56. This broken border 68 on the lower side of the nested arrangement 64 also completes a hexagonal shape for the nested arrangement 64 defined by the largest house shape of the nested arrangement 64 on an upper portion of the hexagon and the broken border 68 on the lower portion of the hexagon.


As shown in FIG. 3, the pattern for the ceramic print 36 may include a plurality of nested arrangements 64 positioned adjacent to each other in a honeycomb-like manner. In particular, each side of the hexagon provided by one nested arrangement 64 is adjacent to another side of the hexagon provided by another nested arrangement 64. Thus, a given nested arrangement 64 may be surrounded by six immediately adjacent nested arrangements 64 on the ceramic print 36. In the embodiment of FIG. 3, at least some of the linear members 50 of different nested arrangements 64 contact one another. For example, two short legs 60 on the lateral sides of adjacent nested arrangement 64 may contact one another, as noted by contact point 69 in FIG. 3.


With continued reference to FIG. 3, the channels 70 positioned between the linear members 50 provide void areas that expose the inner side 24 of the fabric panel 20. Accordingly, the fabric panel 220 remains uncovered by the ceramic print 36 along the channels 70. A sufficient number of channels 70 are positioned between the linear members 50 such that between ten percent and ninety percent of the area on the inner side 24 of the fabric panel 20 remains uncovered by the ceramic print 36. It has been determined that advantages may be realized by covering less than the entire inner side 24 of the fabric panel 20, but at least a certain percentage of the inner side. In particular, desirable feel and heat retention qualities may be realized when the print coverage is within a certain range without sacrificing other fabric qualities such as breathability, moisture wicking and elasticity. Accordingly, in at least one embodiment that results in acceptable performance qualities, the ceramic print 36 covers between twenty percent and eighty percent of the area on the inner side 24 of the fabric panel 20. More specifically, in at least one embodiment, the ceramic print covers between thirty percent and fifty percent of the area on the inner side 24 of the fabric panel 20. Even more particularly, the ceramic print may cover about forty percent of the area on the inner side 24 of the fabric panel 20. In addition to overall print area effecting performance, it has been determined that the actual pattern of the ceramic print 36 may have an influence on performance. Thus, in addition to providing a desirable coverage for good fabric performance, the actual print pattern shown in FIG. 3 also provides excellent fabric performance characteristics with respect to heat retention, feel, breathability, and moisture wicking. For example, and as further noted herein, the print pattern can impart flex or hinge lines defined by non-printed areas located between linear printed segments for the fabric upon which the pattern is printed. This facilitates easy folding of fabric portions along such hinge lines that may be desirable for particular applications.


While the ceramic print 36 has been described herein as covering some percentage of the area on an inner side 24 of the fabric panel 20, it will be recognized that it is desirable to distribute the ceramic print evenly over the coverage area. For example, a ceramic print could cover fifty percent of a fabric panel by covering all of the left side of the panel, but none of the right side. However, it is generally more desirable for the ceramic print 36 to be provided in a pattern that extends over the entire fabric panel 20, while the ink portions 38 of the ceramic print 36 cover only some percentage of the overall fabric panel 20. Accordingly, a print pattern such as that shown in FIG. 3 is desirable. As discussed above, such a pattern may extend over a large area of the fabric panel 20 with the ink portions 38 only covering some percentage of the large area, and the remaining percentage being uncovered (i.e., a non-ink portion). Additionally, in some embodiments, it may be desirable for a single fabric panel to include the ceramic print on most of the panel but have some portion of the panel free of the ceramic print. For example, it may be desirable to leave the portion of a fabric panel that will be used in an underarm area free of the ceramic print in order to increase breathability in that area. Accordingly, it will be recognized that the term “fabric portion” as used herein refers to at least some part of at least one fabric panel. Accordingly, the ceramic print 36 may be provided on a “fabric portion” that includes all or only part of a given fabric panel. Additionally, the ceramic print 36 may be provided on a “fabric portion” that extends over all or parts of a plurality of fabric panels of a garment.


With reference now to FIG. 4, a method of manufacturing an article with the ceramic print 100 begins with step 102 where a printer is loaded or otherwise prepared with ceramic ink. As described above, the ceramic ink includes at least five percent ceramic by weight and less than fifty percent ceramic by weight. In at least one embodiment, the ceramic ink comprises about ten percent ceramic by weight. The ceramic ink may be formed by adding an appropriate quantity of ceramic powder to an existing quantity of ink. The ceramic powder may be provided by any of various ceramic powders including both oxide ceramics and non-oxide ceramics. The printer that uses the ceramic ink may be any of various types of printers capable of printing a ceramic ink on a surface, including screen printers, impression or foil printers, inkjet printers, or other types of printers as will be recognized by those of ordinary skill in the art. Moreover, it will be recognized that any of various methods may be used to adhere or otherwise bind the ceramic ink to the fabric including adhesion printing or other binding methods or materials such as a polyurethane binder.


With continued reference to FIG. 4, the method of manufacturing an article continues with step 104 where a sheet of fabric or other material is provided and prepared for engagement with a printer. As described previously, the sheet of fabric may be, for example, a fabric with elastic qualities, such as a compression fabric including elastane fibers. The sheet of fabric is generally prepared such that the sheet may be fed into the printer or otherwise placed on a printing surface.


At step 106, the printer prints the ceramic ink onto the sheet of fabric according to a predetermined pattern. As a result of the pattern, the printed sheet of fabric will include print covered portions where the ink has been printed on the surface of the fabric, and non-print portions where no ink is on the surface of the fabric. In at least one embodiment, the predetermined pattern is similar to that described above with reference to FIG. 3. In such embodiment, the pattern includes a plurality of linear members 50 that substantially form partial-hexagonal shapes 52, or house shapes, with channels 70 extending between the linear members.


Next, in step 108, the fabric with the printed pattern is cut into a shape that forms a fabric panel of a garment or other article of apparel. The fabric panel may be any of various fabric panels for use on the article of apparel, such as fabric panel for a torso portion of a shirt, a fabric panel for a sleeve, a fabric panel for a shoe upper, or any of various other fabric panels.


In step 110, the formed fabric panel is incorporated into a garment. The fabric panel is arranged on the garment such that the ceramic print on the fabric is exposed on the inside of the garment. Placement of the ceramic print on the inside of the garment can have particular advantages as improved heat retention is provided when the ceramic print is provided in direct contact with the skin of the wearer.


The garment 10 with the ceramic print 36 has been demonstrated to provide excellent performance characteristics with respect to heat retention, while also retaining good performance characteristics in other areas such as moisture retention and breathability. One example test illustrating these performance characteristics is provided below.


As previously noted, certain patterns of linear printed segments of ceramic print can be provided so as to impart flexure or hinge lines for the fabric along such printed segments, where the hinge lines are defined by exposed or non-printed areas or segments located between the printed segments.


In general, a printed ceramic pattern can be provided on a fabric panel that includes an arrangement of printed segments spaced apart by non-printed segments, called hinges. Each segment and hinge may possess any dimensions suitable for its intended purpose. In addition, the segments and hinges may be ordered in a manner as previously described herein in relation to FIG. 3. The segments and hinges can also be ordered into cells or units defining a repeating or random pattern across the textile surface (e.g., as shown in FIGS. 5A and 5B). By way of specific example, the ceramic composition printed pattern can include substantially linear segments arranged in a spaced apart and non-parallel manner in relation to each other to define selected angles (e.g., angles that are at 90° or greater, such as obtuse angles) between the linear segments. Additionally, the cells may include concentrically aligned or nested patterns of such linear segments. The nested patterns can include polygonal shapes (e.g., polygons having four or more sides, e.g., squares or rectangles, pentagons, hexagons, etc.) that are nested within the same or similar polygon shapes. The linear segments can be of the same or similar width and/or thickness or, alternatively, can have different widths and/or thicknesses. Each segment and hinge may possess any dimensions suitable for its intended purpose.


As depicted in FIGS. 5A and 5B, the discontinuous pattern 500 includes an array of cells 501, each cell generally including nested hexagons. Specifically, each cell 501 includes a first or outer hexagon 502 surrounding a second or inner hexagon 504, with the hexagons spaced from each other by a cell hinge 503. The outer hexagon 502 is formed by six linear segments 510A, 510B, 510C, 510D, 510E, 510F, with adjacent segments being separated from each other by a segment hinge 515. The inner hexagon 504 may be a series of individual segments or, as illustrated, one continuous segment. The inner hexagon 504 may optionally include a central space or dot 508 that is free of ceramic print. Each cell 501 is separated from adjacent cells by a border hinge 520. As shown, the segment hinge 515 and the border hinge 520 may be a narrower, minor (or micro) hinge, or a hinge that is smaller in width dimension, in comparison to the cell hinge 503, which is a wider, major (or macro) hinge. In other words, the hinges comprise elongated or linear segments of the textile that are exposed (i.e., no ceramic print has been applied) and have widths that can differ, where micro hinges have widths that are smaller in dimension in comparison to macro hinges. As shown in the examples of FIGS. 5A and 5B, the printed cells comprising printed patterns include micro hinges surrounding macro hinges. Further, the hinges (defined by linear non-printed segments) can intersect each other at varying angles (e.g., border hinges 520 as shown in FIG. 5B).


As noted above, the hinges 503, 515, 520 are areas to which no ceramic print has been applied, while the segments 510A-510F of the hexagons 502, 504 are printed areas. Areas that are printed are generally less flexible than non-printed areas. Accordingly, the textile structure (the base fabric) is free to flex along the hinge lines relative to the printed segments. With this configuration, the hinges 503, 515, 520 maintain the fold or drape of the base fabric, allowing it to flex/move along the hinges 503, 515, 520. This can be particularly useful, e.g., in bedding applications (where the fabric panel comprises a bedding component, such as a fitted sheet or a top sheet).


Example Testing

Experiments were conducted on fabrics with the ceramic print as described above in comparison to various commercially available fabrics with or without added heat retention features. These experiments utilized a hot plate to expose the test fabrics to a conductive heat source. First, the test fabrics were cut into appropriate samples sizes (e.g., 5×5 inch fabric swatches) to be tested and then were allowed to condition at 45 degrees Fahrenheit for 24 hours. Next, a copper plate was placed on a hot plate and allowed to heat up to 85 degrees Fahrenheit. After the copper plate was heated to 85 degrees Fahrenheit, the sample fabric was placed on the copper plate and observed with a thermal imaging camera. The samples were exposed to the copper plate for 10 minutes. After this 10 minute duration, the copper plate and fabric sample were moved to a cooling rack away from the heat source. The fabric sample was then observed while cooling for an additional 10 minutes with the thermal imaging camera.


The results of the testing showed that fabrics treated with the ceramic print provided excellent heat retention qualities as well as excellent breathability, wear and wash-fastness. One exemplary test performed according to the above procedure evaluated a standard commercially available fleece fabric in comparison to the same fleece fabric with the above-described ceramic print applied to the fabric. The results of this test are shown in FIG. 6. Line 610 of FIG. 6 represents the standard fleece fabric without the above-described ceramic print. Line 620 represents the same standard fleece fabric with the above-described ceramic print. As shown in FIG. 6, the fleece 620 with the ceramic print significantly outperformed fleece 610 that did not include the ceramic print with respect to heat retention over time. In particular, the fabric 620 with the ceramic print warmed up more quickly than the standard fabric 610 over a ten minute warm-up period and also retained more heat over a ten minute cool-down period.


As an alternative to a ceramic print for the fabric that provides heat retention properties to the fabric, the fabric can include a printed layer comprising a coating that includes system reactive components that are effective to delay/diminish the rise in skin temperature (compared to a garment lacking the coating) and/or improve the overall moisture management capacity of the fabric, either of which may improve wearer comfort. The system reactive components can be applied in a similar manner, e.g., via printing, as a ceramic print so as to form the same or similar types of printed patterns of segments and non-printed areas or segments located between printed segments that function as hinge lines in a similar manner as the ceramic print as described herein.


In an example embodiment, the printed layer comprises a thermal regulation material including one or more system reactive components, where the printed layer is disposed on an inner substrate or fabric surface (i.e., surface of the fabric which, when incorporated into an article of apparel or garment, faces the body of the wearer). The thermal regulation material is effective to alter the temperature regulation and/or moisture management properties of the substrate or fabric layer. By system reactive, it is intended to mean a compound that reacts to environmental conditions within a system. That is, the system reactive materials are selectively engaged in response to conditions of a wearer wearing the article of apparel. In particular, the compound absorbs, directs, and/or mitigates fluid (heat or water) depending on existing system conditions. For example, a component may initiate an endothermic reaction (e.g., when exposed to water). By way of further example, a component may be capable of selectively absorbing and releasing thermal energy (heat). By way of still further example, a component may be capable or conducting and/or directing heat from one location to another location within a system.


The system reactive components can include a cooling agent, a latent heat agent, and/or a heat dissipation agent. The cooling agent is an endothermic cooling agent, i.e., it creates a system that absorbs heat. Specifically, the cooling agent generates an endothermic reaction in aqueous solution, absorbing energy from its surroundings. Accordingly, the cooling agent possesses a negative heat of solution when dissolved in water. By way of example, the endothermic cooling agent possesses a heat of enthalpy in the range −10 cal/g to −50 cal/g. In particular, the endothermic cooling agent possesses a heat of enthalpy in the range −20 cal/g to −40 cal/g. With this configuration, when the cooling agent is contacted by water (i.e., the sweat of the wearer), the cooling agent is capable of cooling (i.e., lowering the temperature of) the water.


The cooling agent may be a polyol. By way of example, the cooling agent includes one or more of erythritol, lactitol, maltitol, mannitol, sorbitol, and xylitol. In an embodiment, the cooling agent is selected from one or more of sorbitol, xylitol and erythritol. Sorbitol is a hexavalent sugar alcohol and is derived from the catalytic reduction of glucose. Xylitol is produced by catalytic hydrogenation of the pentahydric alcohol xylose. Erythritol is produced from glucose by fermentation with yeast. Crystalline xylitol is preferred. The cooling agent may be present in an amount of about 15 wt % to about 35 wt % (e.g., about 25 wt %).


The latent heat agent is capable of absorbing and releasing thermal energy from a system while maintaining a generally constant temperature. In an embodiment, the latent heat agent is a phase change material (PCM). Phase change materials possess the ability to change state (solid, liquid, or vapor) within a specified temperature range. PCMs absorb heat energy from the environment when exposed to a temperature beyond a threshold value, and release heat to the environment once the temperature falls below the threshold value. For example, when the PCM is a solid-liquid PCM, the material begins as a solid. As the temperature rises, the PCM absorbs heat, storing this energy and becoming liquefied. Conversely, when temperature falls, the PCM releases the stored heat energy and crystallizes or solidifies. The overall temperature of the PCM during the storage and release of heat remains generally constant.


The phase change material should possess good thermal conductivity (enabling it to store or release heat in a short amount of time), a high storage density (enabling it to store a sufficient amount of heat), and the ability to oscillate between solid-liquid phases for a predetermined amount of time. Additionally, the phase change material should melt and solidify at a narrow temperature range to ensure rapid thermal response.


Linear chain hydrocarbons are suitable for use as the phase change materials. Linear chain hydrocarbons having a melting point and crystallization point falling within approximately 10° C. to 40° C. (e.g., 15° C. to 35° C.) and a latent heat of approximately 175 to 250 J/g (e.g., 185 to 240 J/g) may be utilized. In particular, a paraffin linear chain hydrocarbon having 15-20 carbon atoms may be utilized. The melting and crystallization temperatures of paraffin linear chain hydrocarbons having 15-20 carbon atoms fall in the range from 10° C. to 37° C. and 12° C.-30° C., respectively. The phase transition temperature of linear chain hydrocarbons, moreover, is dependent on the number of carbon atoms in the chain. By selecting a chain with a specified number of carbon atoms, a material can be selected such that its phase transition temperature liquefies and solidifies within a specified temperature window. For example, the phase change material may be selected to change phase at a temperature near (e.g., 1° C.-5° C. above or below) the average skin temperature of a user (i.e., a human wearer of the apparel, e.g., 33° C.-34° C.). With this configuration, the phase change material begins to regulate temperature either upon placement of the apparel on the wearer or shortly after the wearer begins physical activity.


In an embodiment, the paraffin is encapsulated in a polymer shell. Encapsulation prevents leakage of the phase change material in its liquid phase, as well as protects the material during processing (e.g., application to the substrate) and during consumer use. The resulting microcapsules may possess a diameter of about 1 to about 500 μm. In an embodiment, the paraffin PCM is present in an amount of about 25 wt % to about 45 wt % (e.g., about 35 wt %).


The heat dissipation agent is effective to conduct heat and/or direct heat from one location to another location within the system (e.g., within the thermal regulation printed layer and/or substrate/fabric material). In an embodiment, the heat dissipation agent possesses a high heat capacity, which determines how much the temperature of the agent will rise relative to the amount of heat applied. By way of example, the heat dissipation agent is a silicate mineral such as jade, e.g., nephrite, jadeite, or combinations thereof. The heat dissipation material may be present in an amount (dry formulation) of about 30 wt % to about 50 wt % (e.g., about 40 wt %).


The system reactive components are present with respect to each other in a ratio of approximately 1:1 to 1:2. By way of example, the ratio of temperature reactive components-cooling agent, latent heat agent, and heat dissipation agent—may be approximately 1:2:2, respectively. As indicated above, in system reactive component mixture, the cooling agent is present in an amount of from 15 wt % to 35 wt %; the latent heat agent is present in an amount of from 25 wt % to 45 wt %. Similarly, the heat dissipation agent is present in an amount of from 25 wt % to 45 wt %.


In addition to the temperature reactive components, the thermal regulation material forming the segments of the printed layer further includes a binder effective to disperse the temperature reactive components and/or to adhere the temperature reactive components to the substrate or fabric layer (e.g., to the yarns/fibers forming the fabric). The binder may be an elastomeric material possessing good elongation and tensile strength properties. Elastomeric materials typically have chains with high flexibility and low intermolecular interactions and either physical or chemical crosslinks to prevent flow of chains past one another when a material is stressed. In an embodiment, polyurethane (e.g., thermoplastic polyurethane such as polyester-based polyurethane) is utilized as the binder. In other embodiments, block copolymers with hard and soft segments may be utilized. For example, styrenic block copolymers such as a styrene-ethylene/butylene-styrene (SEBS) block copolymer may be utilized.


Thus, printed segments of the thermal regulation material including one or more system reactive components can be applied via any suitable form of printing process (e.g., via a rotogravure apparatus) so as to define linear printed segments of the thermal regulation material in any suitable shapes and patterns, including patterns as previously described herein and depicted, e.g., in FIGS. 3, 5A and 5B. Similar to ceramic printing, the printed segments of the thermal regulation material can comprise elongated or linear segments of the textile that are exposed (i.e., no ceramic print has been applied) and have widths that can differ, where micro hinges have widths that are smaller in dimension in comparison to macro hinges. As shown in the examples of FIGS. 5A and 5B, the printed cells comprising printed patterns include micro hinges surrounding macro hinges. Further, the hinges (defined by linear non-printed segments) can intersect each other at varying angles (e.g., border hinges 520 as shown in FIG. 5B).


The patterns of printed linear segments of the thermal regulation material can also impart flex or hinge lines/hinges (where the hinges are defined by the non-printed areas or segments located between the printed segments) for the fabric upon which the pattern is printed in the same or similar manner as described herein for ceramic printed patterns. This facilitates easy folding of fabric portions along such hinges that may be desirable for particular applications.


An example embodiment of a rotogravure apparatus that can be used to apply or imprint a ceramic and/or a thermal regulation material in any suitable patterns including linear printed segments (including patterns as depicted in FIGS. 3, 5A and 5B) is described with reference to FIG. 7. The rotogravure apparatus 700 includes a pair of cylinders 710 and 720 and a tank 740 that holds a liquid material 730 comprising a heat retaining material (ceramic or thermal regulation material) in a liquid binder. A textile 705 is processed by moving the textile between the two cylinders in the direction of the arrow while the cylinders rotate in opposing directions (also indicated by the dashed arrows along each cylinder 710, 720). Gravure cylinder 720 includes indentations or cells that capture liquid material 730 from the tank 740 within the cells and transfer such material 730 to the surface 706 of the textile 705 facing and in contact with the gravure cylinder 720 during operation of the gravure printing apparatus (in which cylinder 720 is rotating as shown). The indentations or cells are aligned on the surface of the cylinder 720 in the pattern in which thermal regulation material is to be applied to the textile surface (e.g., including linear segments and/or nested arrangements to produce patterns of the thermal regulation material on the textile surface such as is shown in FIGS. 3, 5A and 5B). Impression cylinder 710, which is in contact with the opposing surface 707 of the textile 705 (i.e., the textile surface that opposes the textile surface upon which the material 730 is applied) presses the textile 705 against the gravure cylinder 720 as the textile is moved or guided between the cylinders to achieve an impression printing of the thermal regulation material in the select pattern onto the textile surface.


The foregoing detailed description of one or more embodiments of garments with ceramics and/or other heat retaining material(s) and methods of making the same are presented herein by way of example only and not limitation. It will be recognized that there are advantages to certain individual features and functions described herein that may be obtained without incorporating other features and functions described herein. Moreover, it will be recognized that various alternatives, modifications, variations, or improvements of the above-disclosed embodiments and other features and functions, or alternatives thereof, may be desirably combined into many other different embodiments, systems or applications.


Furthermore, presently unforeseen or unanticipated alternatives, modifications, variations, or improvements therein may be subsequently made by those skilled in the art which are also intended to be encompassed by the appended claims. Therefore, the spirit and scope of any appended claims should not be limited to the description of the embodiments contained herein.

Claims
  • 1. A method of manufacturing a garment comprising: printing, via an impression printer, a material onto a first side of a fabric to form a printed layer in a pattern including a plurality of printed segments of the material;wherein hinges for the fabric are defined by non-printed segments of the fabric that are located between printed segments, and the hinges facilitate folding of the fabric along one or more of the hinges.
  • 2. The method of claim 1, wherein the hinges comprise elongated non-printed segments with varying width dimensions.
  • 3. The method of claim 2, wherein the hinges comprise micro hinges and macro hinges, the micro hinges having widths that are smaller than widths of the macro hinges.
  • 4. The method of claim 1, wherein the printing comprises forming the printed layer including cells, and each cell is defined by printed segments that enclose one or more non-printed segments.
  • 5. The method of claim 4, wherein the printing comprises forming the printed layer such that one or more cells includes nested patterns of printed segments enclosing non-printed segments.
  • 6. The method of claim 1, wherein the printing comprises printing a plurality of linear printed segments to define a cell that is enclosed by the linear printed segments and with hinges located between adjacent linear printed segments and forming a border around all the linear printed segments that define the cell.
  • 7. The method of claim 6, wherein the cell defined by the linear printed segments has a hexagonal shape.
  • 8. The method of claim 1, wherein the material comprises a heat retaining material and a binder, and the heat retaining material is present in an amount effective to provide heat retention properties to the fabric.
  • 9. The method of claim 8, wherein the heat retaining material comprises a ceramic, and the binder comprises polyurethane.
  • 10. The method of claim 1, wherein the material comprises a thermal regulation material including one or more system reactive components combined with a binder material, and the one or more system reactive components is selected from the group consisting of a cooling agent, a latent heat agent, and a heat dissipation agent.
  • 11. The method of claim 10, wherein: the cooling agent comprises a polyol selected from the group consisting of sorbitol, xylitol and erythritol;the latent heat agent comprises a phase change material comprising a paraffinic hydrocarbon; andthe heat dissipation agent comprises a silicate material.
  • 12. The method of claim 1, wherein the garment comprises a shirt or jacket, and the first side of the fabric is located on an inner surface of the garment that faces a wearer of the garment.
  • 13. A garment comprising: a printed layer comprising a thermal regulation material located on a first side of a fabric defining a portion of the garment, the printed layer including a plurality of printed segments of the thermal regulation material;wherein hinges for the fabric are defined by non-printed segments of the fabric that are located between printed segments, and the hinges facilitate folding of the fabric along one or more of the hinges.
  • 14. The garment of claim 13, wherein the hinges comprise elongated non-printed segments with varying width dimensions.
  • 15. The garment of claim 14, wherein the hinges comprise micro hinges and macro hinges, the micro hinges having widths that are smaller than widths of the macro hinges.
  • 16. The garment of claim 13, wherein the printed layer includes cells, and each cell is defined by printed segments that enclose one or more non-printed segments.
  • 17. The garment of claim 16, wherein each cell includes nested patterns of printed segments enclosing non-printed segments.
  • 18. The garment of claim 13, wherein the printed layer comprises a plurality of linear printed segments to define a cell that is enclosed by the linear printed segments and with hinges located between adjacent linear printed segments and forming a border around all the linear printed segments that define the cell.
  • 19. The garment of claim 13, wherein thermal regulation material comprises a heat retaining material and a binder, and the heat retaining material is present in an amount effective to provide heat retention properties to the fabric.
  • 20. The garment of claim 13, wherein the thermal regulation material comprises a thermal regulation material including one or more system reactive components combined with a binder material, and the one or more system reactive components is selected from the group consisting of a cooling agent, a latent heat agent, and a heat dissipation agent, wherein: the cooling agent comprises a polyol selected from the group consisting of sorbitol, xylitol and erythritol;the latent heat agent comprises a phase change material comprising a paraffinic hydrocarbon; andthe heat dissipation agent comprises a silicate material.
CROSS-REFERENCE TO RELATED APPLICATIONS

This application is a continuation-in-part of U.S. patent application Ser. No. 16/790,556, filed Feb. 13, 2020, which is a divisional of U.S. patent application Ser. No. 15/615,537, filed Jun. 6, 2017, which is a divisional of U.S. patent application Ser. No. 13/618,835, filed Sep. 14, 2012. This application is also a continuation-in-part of U.S. patent application Ser. No. 17/707,147, filed Mar. 29, 2022, which is a divisional of U.S. patent application Ser. No. 16/113,057, filed Aug. 27, 2018, which claims priority to U.S. Provisional Patent Application Ser. No. 62/550,678, filed Aug. 27, 2017. This application is further a continuation-in-part of U.S. patent application Ser. No. 18/340,948, filed Jun. 26, 2023, which is a continuation of U.S. patent application Ser. No. 17/356,824, filed Jun. 24, 2021, which is a continuation of U.S. patent application Ser. No. 16/038,241, filed Jul. 18, 2018, which is a divisional of U.S. patent application Ser. No. 14/507,270, filed Oct. 6, 2014, which claims priority to U.S. Provisional Patent Application Ser. No. 61/886,835, filed Oct. 4, 2013. The disclosures of the aforementioned applications are all incorporated herein by reference in their entireties.

Provisional Applications (2)
Number Date Country
62550678 Aug 2017 US
61886835 Oct 2013 US
Divisions (4)
Number Date Country
Parent 15615537 Jun 2017 US
Child 16790556 US
Parent 13618835 Sep 2012 US
Child 15615537 US
Parent 16113057 Aug 2018 US
Child 17707147 US
Parent 14507270 Oct 2014 US
Child 16038241 US
Continuations (2)
Number Date Country
Parent 17356824 Jun 2021 US
Child 18340948 US
Parent 16038241 Jul 2018 US
Child 17356824 US
Continuation in Parts (3)
Number Date Country
Parent 16790556 Feb 2020 US
Child 18740700 US
Parent 17707147 Mar 2022 US
Child 18740700 US
Parent 18340948 Jun 2023 US
Child 18740700 US