Claims
- 1. A metal cleaner-anticorrosion composition comprising an alkaline metal salt, whereby the alkaline metal salt is not a borate, a surfactant, and an anticorrosion agent comprising a triazole compound in combination with an alkali metal borate, wherein a pH of the composition in aqueous solution is from 7.5 to less than 10.
- 2. The composition of claim 1, wherein the alkaline metal salt comprises a carbonate salt, a bicarbonate salt or mixtures thereof.
- 3. The composition of claim 1, wherein the alkali metal borate and the triazole compound each comprise from about 0.5 to about 1.5 wt. % of the composition.
- 4. The composition of claim 1, wherein a weight ratio of triazole compound to alkali metal borate is about 1:1.
- 5. The composition of claim 1, wherein the triazole compound is a water soluble 1,2,3-triazole compound.
- 6. The composition of claim 5, wherein the 1,2,3-triazole compound comprises 1,2,3-benzotriazole; 4-phenyl-1,2,3-triazole; 1,2-naphthotriazole; 4-nitrobenzotriazole; 1,2,3-tolytriazole; 4-methyl-1,2,3-triazole; 4-ethyl-1,2,3-triazole; 5-methyl-1,2,3-triazole; 5-ethyl-1,2,3-triazole; 5-propyl-1,2,3-triazole or 5-butyl-1,2,3-triazole.
- 7. The composition of claim 1, wherein the alkali metal borate comprises sodium tetraborate pentahydrate or sodium tetraborate decahydrate.
- 8. The composition of claim 1, wherein the surfactant is a nonionic surfactant.
- 9. The composition of claim 1, wherein the surfactant comprises an ethoxylated alkyl-thiol having from 7 to 20 carbon atoms and is ethoxylated with 3 to 15 ethylene oxide units.
- 10. The composition of claim 9, further including a nitrogen-containing surfactant.
- 11. The composition of claim 10, wherein the nitrogen-containing surfactant is an N-alkyl pyrrolidone.
- 12. The composition of claim 1, further comprising a hydrotrope.
- 13. The composition of claim 1, further comprising a water soluble salt of magnesium and a carboxylated polymer.
- 14. The composition of claim 1, wherein the composition is free of silicate.
- 15. An aqueous metal cleaning concentrate comprising a cleaning-anticorrosion composition wherein the composition comprises from about 5 to about 45 wt. % of the concentrate with the balance water, wherein the composition comprises an alkaline metal salt, whereby the alkaline metal salt is not a borate, a surfactant, and an anticorrosion agent comprising a triazole compound in combination with an alkali metal borate, wherein a pH of the concentrate ranges from about 7.5 to less than 10.
- 16. The aqueous concentrate of claim 15, wherein the alkaline metal salts comprise carbonate salts, bicarbonate salts or mixtures thereof.
- 17. The aqueous concentrate of claim 15, wherein the metal cleaning composition comprises from about 10 to about 60 wt. % of the alkaline metal salt, from about 5 wt. % to about 45 wt. % of the surfactant, from about 0.5 wt. % to about 1.5 wt. % of each of the triazole compound and the alkali metal borate and from 0 to about 45 wt. % of a hydrotrope.
- 18. The aqueous concentrate of claim 15, wherein the metal cleaning composition is free of silicates.
- 19. The aqueous concentrate of claim 15, wherein the triazole compound comprises a water soluble 1,2,3-triazole compound.
- 20. The aqueous concentrate of claim 19, wherein the water soluble 1,2,3-triazole compound comprises 1,2,3-benzotriazole; 4-phenyl-1,2,3-triazole; 1,2-naphthotriazole; 4-nitrobenzotriazole; 1,2,3-tolytriazole; 4-methyl-1,2,3-triazole; 4-ethyl-1,2,3-triazole; 5-methyl-1,2,3-triazole; 5-ethyl-1,2,3-triazole; 5-propyl-1,2,3-triazole; or 5-butyl-1,2,3-triazole.
- 21. The aqueous concentrate of claim 15, wherein the alkali metal borate comprises sodium tetraborate pentahydrate or sodium tetraborate decahydrate.
- 22. The aqueous concentrate of claim 15, wherein the surfactant is a nonionic surfactant.
- 23. The aqueous concentrate of claim 15, wherein the surfactant is an ethoxylated alkyl-thiol having from 7 to 20 carbons and is ethoxylated with 3 to 15 ethylene oxide units.
- 24. The aqueous concentrate of claim 23, further comprising a nitrogen-containing surfactant.
- 25. The aqueous concentrate of claim 24, wherein the nitrogen-containing surfactant is an N-alkyl pyrrolidone.
- 26. The aqueous concentrate of claim 15, wherein a weight ratio of the triazole compound to the alkali metal borate is about 1:1.
- 27. An aqueous metal cleaning-anticorrosion solution comprising a metal cleaning-anticorrosion composition wherein the composition comprises from about 1 to about 10 wt. % of the aqueous solution with the balance water, wherein the composition comprises an alkaline metal salt, whereby the alkaline metal salt is not a borate, a surfactant, and an anticorrosion agent comprising a triazole compound in combination with an alkali metal borate, wherein a pH of the solution ranges from about 7.5 to less than 10.
- 28. The aqueous solution of claim 27, wherein a weight ratio of triazole compound to alkali metal borate is about 1:1.
- 29. The aqueous solution of claim 27, wherein the triazole compound comprises a water soluble 1,2,3-triazole.
- 30. The aqueous solution of claim 29, wherein the 1,2,3-triazole comprises 1,2,3-benzotriazole; 4-phenyl-1,2,3-triazole; 1,2-naphthotriazole; 4-nitrobenzotriazole; 1,2,3-tolytriazole; 4-methyl-1,2,3-triazole; 4-ethyl-1,2,3-triazole; 5-methyl-1,2,3-triazole; 5-ethyl-1,2,3-triazole; 5-propyl-1,2,3-triazole; or 5-butyl-1,2,3-triazole.
- 31. The aqueous solution of claim 27, wherein the alkali metal borate comprises sodium tetraborate pentahydrate or sodium tetraborate decahydrate.
- 32. The aqueous solution of claim 27, wherein the metal cleaning composition is free of silicates.
- 33. The aqueous solution of claim 27, wherein the surfactant is a nonionic surfactant.
- 34. The aqueous solution of claim 27, wherein the surfactant is an ethoxylated alkyl-thiol having from 7 to 20 carbons and is ethoxylated with 3 to 15 ethylene oxide units.
- 35. The aqueous solution of claim 34, further comprising a nitrogen-containing surfactant.
- 36. The aqueous solution of claim 35, wherein the nitrogen-containing surfactant is an N-alkyl pyrrolidone.
- 37. The aqueous solution of claim 27, wherein the alkaline metal salts comprise carbonate salts, bicarbonate salts or mixtures thereof.
- 38. A method for cleaning and for preventing corrosion of metal comprising contacting a surface of a metal substrate with an aqueous solution for a sufficient amount of time to remove contaminants therefrom and to prevent corrosion, the aqueous solution containing a composition comprising an alkaline metal salt, whereby the alkaline metal salt is not a borate, a surfactant, and an anticorrosion inhibitor comprising a triazole compound in combination with an alkali metal borate, wherein a pH of the solution ranges from about 7.5 to less than 10.
- 39. The method of claim 38, wherein the alkaline metal salt comprises from about 10 to about 60 wt. % of the composition, the triazole compound and the alkali metal borate each comprise from about 0.5 to about 1.5 wt. % of the composition, the surfactant comprises from about 5 to about 45 wt. % of the composition, and a hydrotrope comprising from 0 to about 45 wt. % of the composition.
- 40. The method of claim 38, wherein the alkaline metal salt comprises a carbonate salt, a bicarbonate salt or mixtures thereof.
- 41. The method of claim 38, wherein the triazole comprises a water soluble 1,2,3-triazole.
- 42. The method of claim 41, wherein the water soluble 1,2,3-triazole comprises 1,2,3-benzotriazole; 4-phenyl-1,2,3-triazole; 1,2-naphthotriazole; 4-nitrobenzotriazole; 1,2,3-tolytriazole; 4-methyl-1,2,3-triazole; 4-ethyl-1,2,3-triazole; 5-methyl-1,2,3-triazole; 5-ethyl-1,2,3-triazole; 5-propyl-1,2,3-triazole; or 5-butyl-1,2,3-triazole.
- 43. The method of claim 38, wherein the alkali metal borate comprises sodium tetraborate pentahydrate or sodium tetraborate decahydrate.
- 44. The method of claim 38, wherein the surfactant comprises a nonionic surfactant.
- 45. The method of claim 38, wherein the surfactant is an ethoxylated-thiol having from 7 to 20 carbon atoms and is ethoxylated with 3 to 15 ethylene oxide units.
- 46. The method of claim 45, wherein the aqueous solution further comprises a nitrogen-containing surfactant.
- 47. The method of claim 46, wherein the nitrogen-containing surfactant is an N-alkyl pyrrolidone.
- 48. The method of claim 38, wherein a weight ratio of the triazole compound to the alkali metal borate is about 1:1.
- 49. The method of claim 38, wherein the metal substrate contains copper.
BACKGROUND OF THE INVENTION
The present application is a continuation-in-part of U.S. application Ser. No. 08/609,895, filed Mar. 4, 1996, now U.S. Pat. No. 5,650,385 which is a continuation of U.S. application Ser. No. 08/311,254, filed Sep. 23, 1994 and now abandoned.
US Referenced Citations (16)
Continuations (1)
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Date |
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Parent |
311254 |
Sep 1994 |
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Continuation in Parts (1)
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609895 |
Mar 1996 |
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