The present invention relates to a coating method based on cathodic arc vaporization.
Cathodic arc vaporization is a known method for depositing nitrides such as AlxCr1-xN layers at high coating rates. This method can be used to produce coatings that are dense and adhere well to the surface. But during the coating process, macro-particles (droplets) form, which become incorporated into the layers and impair the layer quality. Droplet formation occurs particularly when a target contains at least two metals that have very different melting points, as is the case with aluminum and chromium. In this connection, the size and number of these droplets can be reduced by increasing the flow of nitrogen.
The object of the present invention, however, is to further reduce the number and size of the droplets.
According to the invention, the arc vaporization is operated using targets produced by means of powder metallurgy in which the components are in the form of intermetallic compounds, i.e. the target has been produced using a powder that contains an intermetallic compound. An example of such an intermetallic compound is Al8Cr5. This makes it possible, for example in a nitrogen-containing atmosphere, to produce an Al—Cr—N layer that essentially contains a composition of metallic components of 60 at % Al and 40 at % Cr. For example if a layer with a concentration ratio of 70 at % Al and 30 at % Cr is produced, then it is possible to use a target with the intermetallic compound Al9Cr4.
If other concentration ratios are to be produced, then according to another embodiment of the present invention, it is possible for arc vaporization to be carried out using a target produced by means of powder metallurgy in which the powder of one intermetallic compound has been mixed with the powder of another intermetallic compound. The atomic concentration of the metallic components then depends on the mixture ratio of the two powders.
According, to another embodiment, it is possible to use targets that contain the ceramic compounds AlN and CrN.
The present invention has disclosed the following:
According to the present invention, in order to produce some layers, it can also be advantageous to use a method as described above, but in which the powder used for producing the target contains both an intermetallic compound and a ceramic compound.
Number | Date | Country | Kind |
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10 2013 006 633.6 | Apr 2013 | DE | national |
Filing Document | Filing Date | Country | Kind |
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PCT/EP2014/000989 | 4/14/2014 | WO | 00 |