Patent Application
20210112855
The present invention relates to an aroma cartridge which is mounted in a chamber provided with an electrically controlled heating element in a heating-type smoking appliance, the aroma cartridge being mounted so as to be in contact with the heating element, whereby an aerosol smoke and a fragrance component generated due to heating of the heating element can be satisfyingly experienced.
In recent years, as separation of smoking and non-smoking areas and prohibition of cigarettes have become more widespread in workplaces, restaurants, and other spaces where people congregate, the number of enthusiasts of smoking tobacco that is burned by a flame, such as in cigarettes, has declined, whereas there has been a sharp increase in the number of smoking enthusiasts who use an electronic-cigarette heating-type smoking appliance, by aspirating smoke generated by heat that is transmitted by a heater or other electrically controlled heating element. This is because, in contrast with conventional flame-type smoking in which the smoker and non-smokers in the vicinity of the smoker aspirate harmful substances generated by combustion (600° C. or higher) and thermal decomposition of tobacco material and paper, a smoker of an electronic cigarette can enjoy smoking by aspirating an aroma or smoke of a tobacco material or harmless glycerin or the like made from an aerosol former, at a low temperature (200-350° C.) that does not lead to combustion or thermal decomposition of the tobacco material, and effects on non-smokers in the vicinity can also be reduced.
Electronic cigarettes are roughly classified into two types (Non-Patent Documents 1 and 2). One type includes a capsule-type electronic cigarette and a stick-type electronic cigarette in which a capsule or stick containing tobacco leaves or the like is heated, and smoke or the like is aspirated. The other type is a liquid-type electronic cigarette in which a vapor generated by heating a scented or flavored liquid is inhaled.
Stick-type electronic cigarettes in particular have a large number of enthusiasts, due to a high degree of similarity thereof in form, smoking method, taste, and other characteristics to conventional cigarettes, as well as a small aspiration quantity of harmful substances, and various developments in stick-type electronic cigarettes have been made (e.g., Patent Documents 1 through 3). A specific example thereof is an electronic cigarette in which a stick (electronic cigarette cartridge), comprising a mouthpiece provided to an aerosol-forming body obtained by processing an aerosol former for generating a smoke-forming aerosol, a perfume, a binder, and other components together with a tobacco component into a cigarette-form stick shape, is mounted to a heating-type smoking appliance and smoked. A mechanism of this smoking is that when the aerosol-forming body is mounted so as to be in contact with a heat source of the heating-type smoking appliance, and the aerosol-forming body is heated, a volatile substance including an aerosol former is released from the aerosol-forming body, while at the same time, the volatile substance is drawn in toward the mouthpiece at another end together with air by suction by the smoker, and in a process of conveyance of the volatile substance, the volatile substance of the aerosol former cools and condenses, and forms an aerosol resembling smoke, and another volatile substance imparts an aroma to the mouth and nose of the smoker, thereby enabling the smoker to enjoy smoking (Patent Document 2). Through this mechanism, in the case of heating-type smoking such as in a stick-type electronic cigarette, smoking can be performed at a temperature of 200-250° C. sufficient to volatilize the glycerin, propylene glycol, or other aerosol former included in the aerosol-forming body, i.e., at a temperature at which thermal decomposition of tobacco leaves begins. Therefore, compared with flame-type smoking in which burning occurs at the minimum temperature of 600° C. necessary for combustion, and also at a temperature exceeding 900° C. during smoking, generation of harmful substances, which are said to be generated in larger amounts as the temperature is increased, is suppressed, and adverse effects on health are low.
Unlike a stick-type electronic cigarette, a liquid-type electronic cigarette does not include a tobacco component, and is a novel smoking appliance whereby it is possible to enjoy various tastes such as coffee, cola, Red Bull, and other beverages; chocolate, vanilla, cream, and other desserts; orange, lemon, melon, and other fruits; and menthol, mint, herbs, and other algefacients (Non-Patent Document 2). A specific example thereof is an electronic cigarette whereby a liquid in which a perfume is mixed with propylene glycol and vegetable glycerin is heated, and a volatilized volatile substance is aspirated. The most significant features of this electronic cigarette are that no harmful substances are included therein, tar or nicotine are also not generated, and a wide variety of tastes can be enjoyed. A wide variety of liquids are actually sold for this electronic cigarette.
A fusion of features of these two types of electronic cigarettes has also been attempted in recent years (Patent Document 4). As described above, the aerosol-forming body processed into a stick shape which is heated in the conventional stick-type electronic cigarette includes a tobacco component, and therefore generates nonetheless small quantities of harmful substances, as well as tar or nicotine. The invention of Patent Document 4 is therefore a stick-type electronic cigarette that does not include a tobacco component, which was a problem in a stick-type electronic cigarette. Specifically, the invention of Patent Document 4 is a stick-type electronic cigarette in which, instead of a tobacco component, a non-tobacco material is employed for generating only a fragrance which has the effect of smoking for calming mind and body and helping to promote health and beauty, and an aerosol-forming body in which an aerosol former, a binder, and other components are blended is used.
However, in this stick-type electronic cigarette which uses only a non-tobacco material, a tobacco material including a large quantity of fibers cannot be used in the aerosol-forming body, and the stick-type electronic cigarette also has problems that arise as a consequence of using a wide variety of non-tobacco materials to release various flavors.
In an aerosol-forming body that includes a tobacco material, fibers of the tobacco material maintain an aggregated state in the aerosol-forming body and hinder fusion and falling out of the tobacco material. However, when a non-tobacco material not including a large quantity of fibers is used, a large amount of a binder or the like for performing the function of fibers is used to stably maintain an aggregated state in an aroma-generating sheet to be heated or an aroma-generating filler to be heated (referred to hereinbelow as “aroma-generating base material to be heated.”). When the amount of the binder is increased, the density of the aroma-generating base material to be heated is therefore increased, flow passages (“gas flow passages” hereinbelow) for volatile components (“gas” hereinbelow) from within the aroma-generating base material to be heated of the non-tobacco material and the aerosol former released by heating are blocked, and aspiration of aerosol smoke or a fragrance component of the non-tobacco material (“aspirated components” hereinbelow) becomes difficult, resulting in a reduced aspiration quantity.
Because the aerosol former is glycerin, propylene glycol, or the like, which is liquid at normal temperature, bleed-out of the aerosol former over time from the aroma-generating base material to be heated increases the larger the amount of the binder is, and aroma-generating base materials to be heated fuse together. Gas flow passages are therefore blocked, and aspiration of aspirated components becomes difficult, resulting in a reduced aspiration quantity. When the fusion described above occurs, not only does it become difficult to insert a heating element into the aroma-generating base material to be heated, but the heating element can also be damaged. Specifically, the aroma-generating base materials to be heated can become stuck together and hardened during transport or storage/keeping at a storefront, leading to difficulty in penetration thereof by a heating element, damage to a cartridge, or damage to the heating element.
Conversely, when the added amount of the binder or the like is reduced to keep gas flow passages clear, the non-tobacco material falls out or forms dust or the like, it is difficult to maintain the cartridge in a rigid form, and the cartridge sometimes breaks when inserted on the heating element. Pieces thereof may also be aspirated into the mouth.
Specifically, because of the need to maintain generation of a smoke-forming aerosol or generation of the fragrance component released from the non-tobacco material, the problems described above are not readily solved by significantly changing a blending ratio or a composition for forming the aroma-generating base material to be heated. Therefore, there is a need for a means of solving the above problems that focuses on, inter alia, a mouthpiece structure, which has a marked effect on the aspiration quantity, and on a method for producing the aroma-generating base material to be heated and a filling state thereof.
An object of the present invention is to provide an aroma cartridge whereby it is possible to overcome a problem of decreased aspiration force that characteristically arises from using only a non-tobacco material and not using any tobacco component, i.e., a problem of decreased aspiration quantity of an aspirated component due to blockage of gas flow passages within an aroma-generating base material to be heated and between aroma-generating base materials to be heated, and whereby there is also no dust generation or dislodgement of the non-tobacco material and other materials.
The present invention is referred to herein as an “aroma cartridge,” but may also be called a “smoking cartridge” or an “electronic-cigarette-compatible cartridge.”
The above terms are applied also to a source of a scent in which a non-tobacco material that is free of tobacco components is used.
The term “aroma” herein means “pleasant scent,” and includes a scent that wafts from a raw material itself (a fragrance), a scent that drifts in space when heated (an aroma), a scent that plays about the mouth when aspirated (a flavor), or the like.
The term “smoking” usually means smoking tobacco, but in the present invention, “smoking” simply means “enjoying smoke,” “tasting smoke,” or “satisfyingly experiencing smoke,” and is not limited to referring to tobacco as the source of the smoke, and can also be applied to a source in which a non-tobacco material is used. The term “smoke” herein also includes a substance “resembling smoke” or a “smoke-like” substance, such as an aerosol or other droplets dispersed in air, for example.
An “electronic-cigarette-compatible cartridge” is also defined simply as an “(interchangeable) cartridge that can be used interchangeably as a replacement for an electronic cigarette cartridge that includes a tobacco component,” regardless of whether the compatible cartridge includes a tobacco component.
More specifically, an object of the present invention is to provide a cylindrical aroma cartridge which can be mounted so as to contact a heating element of a heating-type smoking appliance in which an electrically controlled heating element is provided in a chamber, and whereby an aerosol smoke and a fragrance component generated due to heating by the heating element can be satisfyingly experienced, wherein: a mouthpiece comprising at least a filter for filtering smoke and a fragrance component, and an aroma generator to be heated in which is wound at least an aroma-generating base material to be heated which is in contact with the heating element are adjacent to each other and wound by a cartridge exterior body; the mouthpiece is provided with a mechanism having a function for enhancing the aspiration quantity of a gas and a function for capturing dislodged material or dust of a non-tobacco material or the like; and the aroma generator to be heated is provided with a material having a structure that eliminates dust or dislodgement of non-tobacco material or the like without reducing the aspiration quantity of a gas.
Specifically, the aroma cartridge of the present invention comprises: an aroma generator to be heated, in which is wound an aroma-generating base material to be heated which is in contact with a heating element; a mouthpiece comprising a filter for filtering an aerosol smoke and a fragrance component generated due to heating by the heating element; and a cartridge exterior body surrounding an external periphery so as to connect the aroma generator to be heated and the mouthpiece, at least one of the aroma generator to be heated and the mouthpiece having at least one of means for optimizing aspiration of the smoke and the fragrance component and a gas-generation-maintaining material for maintaining generation of the smoke and the fragrance component.
The aspiration quantity optimization means and the gas-generation-maintaining material are a structure and a material, respectively, described below. The aspiration quantity optimization means is a mouthpiece structure for enhancing the aspiration quantity, and is a structure for preventing and capturing dislodged material or dust of a non-tobacco material or the like of the aroma generator to be heated. More specifically, what is meant by aspiration quantity optimization means is: a cavity for enhancing the aspiration quantity by enlarging a gas flow passage provided in the filter constituting the mouthpiece; a shape reinforcement member for preventing a decrease in aspiration quantity due to deformation, provided to a support body for preventing the aroma generator to be heated constituting the mouthpiece from moving toward the mouthpiece; a heat insulation material for preventing a joined part from being damaged by heat diffusion, provided to the mouthpiece; and a cover material and a capturing partition wall material for preventing the occurrence of dust or dislodged material of the non-tobacco material, etc. The gas-generation-maintaining material is a material whereby a flow channel for gas released from the aroma generator to be heated is not blocked. More specifically, the gas-generation-maintaining material is: an aroma-generating base material to be heated in which an internal structure thereof is improved by a production method; an aroma-generating base material to be heated which constitutes the aroma generator to be heated, in which a blended amount thereof is optimized; inorganic particles present within and/or on a surface of the aroma-generating base material to be heated which constitutes the aroma generator to be heated; and an aroma-generating base material to be heated in which a filling ratio thereof is improved. These structures and materials of the present invention will be described below in detail.
First, in the aroma cartridge of the present invention, the filter is obtained by molding fibers into a cylindrical shape, and the filter constitutes all or a portion of the mouthpiece, and the aspiration optimization means includes a cavity provided in the filter in a longitudinal direction so as not to penetrate through the filter. The filter is formed from commonly used cellulose acetate (CA) fibers or polyethylene terephthalate (PET) or other polyester fibers or the like, and because the flow rate of gas aspirated by a typical smoker is not adequate in the case of an aroma cartridge of an aroma generator to be heated which uses a non-tobacco material, the aspiration quantity is enhanced by a cavity in the filter.
A shape or quantity of the cavity is not particularly limited and may be determined as appropriate for the type of aroma generator to be heated, but in consideration of the effect of increasing the quantity of gas aspirated by a typical smoker, and the degree of difficulty of a method for producing the cavity, at least one cavity is preferably arranged in both longitudinal end parts or in either one longitudinal end part of the filter.
A position in which the cavity is formed is arranged so that when a smoker aspirates, the aspirated gas enters the entire mouth uniformly. When there is one cavity, the cavity is preferably formed on a center axis of a cylinder existing in the longitudinal direction of the filter. When there are two cavities, the cavities are preferably formed symmetrically about the center axis of a cylinder existing in the longitudinal direction of the filter. Furthermore, when there are three or more filters, the cavities are preferably arranged in rotationally symmetrical positions about the center axis of a cylinder existing in the longitudinal direction of the filter and on the center axis of a cylinder existing in the longitudinal direction of the filter.
The shape of the cavity is preferably columnar or conical, from the perspective of the effect of increasing the quantity of gas aspirated by a typical smoker, and the degree of difficulty of a method for producing the cavity, but the cavity is not limited to a columnar or conical bottom surface shape. However, the cavities described above are efficiently formed by ordinary mechanical drilling, electrical discharge machining, or laser machining, and are therefore preferably cylindrical or circular conical for the sake of workability.
The filter alone may constitute the entire mouthpiece, or the filter may be a portion of the mouthpiece. When a portion of the mouthpiece is the filter, a remainder thereof is preferably a void formed by the cartridge exterior body. An arrangement of the filter and the void is not particularly limited, and an aroma generator to be heated and the filter may be adjacent, or the aroma generator to be heated and the void may be adjacent. The cartridge exterior body is usually formed using a thin film of PE, PP, or other polyolefin resin, PET resin, CA resin, polylactic acid (PLA), or the like, or thin paper or the like, but when a void is formed by the cartridge exterior body, the thickness thereof, which will vary according to the material, must be sufficient to maintain strength of the mouthpiece.
The mouthpiece can be further equipped with a member having a preferred function other than the filter, to enhance functioning of the mouthpiece. Typical examples of such a member generally include a support member for preventing the aroma generator to be heated from moving toward the mouthpiece, and a cooling member whereby the aerosol former of the aroma generator to be heated is cooled after being volatilized, generation of smoke is promoted, and the temperature of a gas is reduced, and the support member and the cooling member may constitute the mouthpiece together with the filter. Any one or both of the above members may be applied. When one of the members is applied, the member is disposed between the aroma generator to be heated and the filter. When both members are applied, the support member and the cooling member are arranged in this order or in reverse order between the aroma generator to be heated and the filter.
It is necessary to reduce the gas temperature through use of a cooling member not only for the purpose of cooling and condensing the volatilized aerosol former to generate smoke, but also to lower the temperature of the gas itself in an extremely short interval compared to cigarettes between the mouthpiece and a heated part of the aroma cartridge, and make it possible to enjoy a pleasant smoking sensation in the mouth. Consequently, the cooling member preferably serves as a heat exchanger, and a cylindrical porous body having high porosity and continuous holes, or a cylindrical tube or the like provided with numerous through holes is used as the cooling member. The porosity thereof must be at least 50% or greater, and is preferably 70-90%. As the material of the cooling member, PE, PP, and other polyolefin resins, PET resin, CA resin, polylactic acid (PLA), and the like have been used, but a cooling member formed by winding a metal foil of aluminum or the like having high thermal conductivity on the above materials, or a cooling member formed from such a metal is more preferred.
The mouthpiece thus has, as an essential constituent member, a filter for making the aroma cartridge easy for the smoker to hold in the mouth, and for filtering the gas and smoothing the taste of the gas, and a support member and/or a cooling member can be arranged as needed in the mouthpiece. When this structure is used, the filter is what hinders aspiration of gas, and the aspiration quantity can therefore be increased by reducing a length of the filter. A mouthpiece structure for increasing the aspiration quantity by shortening the filter, instead of by providing a cavity as described above, was therefore investigated.
The length of the aroma cartridge and the length of the aroma generator to be heated are determined in accordance with the structure of the heating-type smoking appliance, and therefore, when the filter of the mouthpiece is shortened, the structure is such that a portion of the filter is replaced by the support member. In the past, since the support member could not hinder passage of gas while preventing the aroma generator to be heated from moving toward the mouthpiece, the support member was a hollow cylindrical structure having a thin side surface, formed using inexpensive polyethylene (PE), polypropylene (PP), or another polyolefin resin, CA resin or another plastic, or paper or the like as the material thereof. The support member is also hollow and preferably has a thin a side surface as possible so as not to hinder passage of gas. However, when the filter is shortened to increase the length of such a support member, a problem arises that the mouthpiece is easily deformed.
To address this problem, the present invention provides an aroma cartridge comprising a mouthpiece constituted from at least a filter and a support member, the support member having a structure whereby the mouthpiece does not deform and the aspiration quantity is not reduced, even when the length of the support member is increased and the thickness of the side surface thereof is decreased.
Specifically, in this aroma cartridge, the mouthpiece has a support member including a through hole, for preventing the aroma generator to be heated from moving toward the mouthpiece, center axes of the support member and a cylinder of the through hole substantially coincide, and the aspiration optimization means includes a shape reinforcement member fixedly or movably arranged in the through hole. More specifically, the shape reinforcement member has axes of the support member and the through hole in a plane thereof, and comprises at least one or more plate-shaped members in contact with an inner wall of the through hole. Arranging such a plate-shaped member in the cylindrical through hole of the support member obviates the need to change a material and makes it possible to prevent deformation of the support member, even when the length of the cylindrical support member is increased and the thickness of the side surface thereof is decreased. A shape of the plate-shaped member is preferably a cross section of a cylinder cut in an axial direction thereof, i.e., a rectangle. From the perspective of aspiration quantity, the plate-shaped member is preferably as thin as possible, and the number thereof is as small as possible, but when prevention of deformation is also considered, it is preferred to have 2-4 plate-shaped members having a thickness of 0.1-0.5 mm formed from a polyolefin resin.
Furthermore, in order to prevent deformation of the support member, the shape reinforcement member more preferably comprises a concentric cylinder having substantially the same center axis as the center axis of a cylinder of the support member and the through hole and having a radius smaller than a radius of the through hole, and a plate-shaped member arranged on an external peripheral side of the concentric cylinder so as to contact an inner wall of the through hole in a radial direction of the concentric cylinder, and from the perspective of gas aspiration, the concentric cylinder is even more preferably hollow.
Aspiration of gas can thus be optimized without deformation of the support member in an aroma cartridge in which is applied a mouthpiece comprising a support member which is adjacent to the aroma generator to be heated and in which is arranged a shape reinforcement member for preventing the aroma generator to be heated from moving toward the mouthpiece, and a filter adjacent to the support member. However, a filter having a cavity is more preferably applied as the filter in order to provide a wider range of control of gas aspiration. A cooling member whereby the volatilized aerosol former can be efficiently converted to an aerosol smoke can also be arranged between the filter and the support member. In both of these cases, a filter having a cavity is preferably applied as the filter in order to further optimize the aspiration quantity.
As the aspiration quantity is increased by improvement of the filter and the support member, heat of a gas is more readily transmitted by convection from the heating element to the filter. Adhesion between members constituting the aroma cartridge may therefore decrease. Locations of joining surfaces at which adhesion is decreased vary according to the configuration of the aroma cartridge, but examples thereof include interfaces of the aroma generator to be heated with the support member, the cooling member, and the cartridge exterior body, interfaces of the filter with the support member, the cooling member, and the cartridge exterior body, interfaces of the support member with the cooling member and the cartridge exterior body, and an interface of the cooling member and the cartridge exterior body.
When adhesion decreases at the interfaces described above, gas leakage occurs which adversely affects the aspiration quantity, and a heat insulation member is therefore preferably provided between the aroma generator to be heated and the mouthpiece. The heat insulation member does not allow a general spread of high-temperature gas, unlike the support member adjacent to the aroma generator to be heated, and is preferably constituted from a heat-insulating porous body made of plastic, such as a sponge having continuous holes with long flow passages, and may also function to retain the high-temperature gas to some degree and cool the gas. Consequently, the heat insulation member has an extremely small length and need not have the degree of cooling functionality of a cooling member, and is preferably applied instead of a support member for preventing the aroma generator to be heated from moving toward the mouthpiece.
In a heating-type smoking appliance (
Furthermore, since the aroma-generating base material to be heated releases various aromas, the quantity of a fiber component thereof is sometimes extremely small. A blended amount of a binder, etc., is adjusted in such cases, but in order to maintain aroma, the blending ratio of the non-tobacco material cannot be significantly reduced, and dislodged material or dust of the non-tobacco material, etc., occurs more readily than usual. The dust and dislodged material are carried toward the mouthpiece by smoking, and cause blockage of voids in the cooling member and the filter, and cause an extreme decrease in aspiration quantity. An aroma-generating base material to be heated that is obtained from such blending is also prone to form dislodged material, dust, and the like when impaled on the needle-shaped heating element of the aroma cartridge.
Therefore, the present invention also provides an aroma cartridge in which a cover material arranged on an end part on the mouthpiece side of the aroma generator to be heated, and a partition wall material arranged on an end part on an opposite side to said mouthpiece are arranged as the aspiration optimization means. Either one or both of the cover material and the partition wall material may be provided, in accordance with the state of the aroma-generating base material to be heated and the aroma generator to be heated in which aroma-generating base materials to be heated are bundled. The cover material and/or the partition wall material prevent clogging of the filter and/or the cooling member by dislodged material or dust, and ensure a stable aspiration quantity.
A solution means for structural improvement of gas aspiration optimization in the aroma cartridge is described above. However, the aroma generator to be heated, which is heated to release gas, must also be improved in order to optimize aspiration. A quantity of gas released by the aroma generator to be heated is closely related to the aspiration quantity described above, and this point is described below. In the present invention, a material for stabilizing the quantity of gas released is referred to as a gas-generation-maintaining material.
The reason that the improvement in the quantity of gas released by heating of the aroma generator to be heated is not maintained has already been explained, but due to the importance of this point in the present invention, the reason will be described again. In an aerosol-forming body that includes a tobacco material, fibers of the tobacco material maintain an aggregated state in the aerosol-forming body and hinder fusion and falling out of the tobacco material. However, when a non-tobacco material not including a large quantity of fibers is used, a large amount of a binder or the like for performing the function of fibers is used to stably maintain an aggregated state in an aroma-generating base material to be heated. When the amount of the binder is increased, the density of the aroma-generating base material to be heated is therefore increased, gas flow passages are blocked, and aspiration of aspirated components becomes difficult.
Because the aerosol former is glycerin, propylene glycol, or the like, which is liquid at normal temperature, bleed-out of the aerosol former over time from the aroma-generating base material to be heated increases the larger the amount of the binder is, and aroma-generating base materials to be heated fuse together. Flow passages between aroma-generating base materials to be heated are therefore blocked, and aspiration of aspirated components becomes difficult. When the fusion described above occurs, not only does it become difficult to insert a heating element into the aroma-generating base material to be heated, but the heating element can also be damaged. Conversely, when the added amount of the binder or the like is reduced to keep gas flow passages clear, the non-tobacco material falls out or forms dust or the like, it is difficult to maintain the cartridge in a rigid form, and the cartridge sometimes breaks when inserted on the heating element. Pieces thereof may also be aspirated into the mouth.
Therefore, in the present invention, it was discovered that the problems described above can be solved firstly by a method (device) for producing the aroma-generating base material to be heated. The description below will primarily follow a production method comprising steps, but it is apparent that a producing device exists that is capable of implementing the production method as a whole, by comprising means for executing the steps. Therefore, a production method and a producing device will be described simultaneously (in stacked fashion) using the terms “step (means)” and “method (device)” so that there is no duplication of description thereof.
The reason that the abovementioned problems are solved by a method (device) for producing an aroma-generating base material to be heated is thought to be that the aroma-generating base material to be heated is produced by drying and subsequent cutting of a sheet molded by a paper-making method, roll-pressing, pressing, or another compression molding method, and casting or another method from a composition in which a material selected from a non-tobacco material, an aerosol former, a binder, an adhesion prevention agent, a perfume, a non-tobacco-material extract, an antimicrobial preservative, and the like is dispersed or dissolved as a medium in pure water, alcohol, or another medium, and an internal structure of the aroma-generating base material to be heated is altered in various ways by the production method (device) in molding and drying steps (means).
This is based on the fact that in a blend of different polymers, for example, a phase-separated structure of a blend is affected by the production method (device) or a producing condition, and on the fact that in the case of an emulsion, suspension, or the like in which an oil is dispersed in water, whether the emulsion, suspension, or the like becomes a water-in-oil or oil-in-water-type emulsion, suspension, or the like is affected by the type of oil, the blending ratio of the oil and water, the type of a surfactant, and various other factors. Analysis of clear differences in the structure of aroma-generating base materials to be heated that arise from such differences in the production method (device) is nearly impossible, due to the complexity of material systems included therein, and a method for analyzing these differences would require considerable labor to discover. Reasons for using polymer blend, an emulsion, or the like as the basis for asserting that differences in internal structure arise from the production method (device) is that the substances blended in a polymer blend, an emulsion, or the like are limited, there is a long history of research thereof, and methods for analysis thereof are established, and that the differences in structure that arise from producing conditions are distinct.
Various methods [devices] for producing an aroma-generating base material to be heated have been investigated, but the following method is included as an example. This example is a method (device) for producing an aroma-generating base material to be heated, by cutting an aroma-generating sheet to be heated that is produced by: a step (means) for drying/pulverizing and then dry-mixing a non-tobacco material to prepare a non-tobacco material; a step (means) for preparing raw materials selected from an aerosol former, a binder, an adhesion inhibitor, a perfume, a non-tobacco material extract, an antimicrobial preservative, etc.; a step (means) for preparing pure water and an alcohol; a wet mixing step (means) for mixing the prepared ingredients at once; a paper-making step (means) for producing a water-containing sheet from a slurry produced by wet mixing; a molding step (means) for roll-pressing the resultant water-containing sheet to obtain a sheet; and a step (means) for drying the sheet produced by the molding step (means).
However, the aroma-generating base material to be heated that is produced by this method (device) has problems in that an aggregated state is difficult to maintain therein, a large quantity of binder is required, and fusion of the aroma-generating base material to be heated due to bleed-out of the aerosol former is prone to occur. Consequently, the quantity of gas released by an aroma generator to be heated that uses this aroma-generating base material as a filler changes significantly over time, and a smoker cannot obtain stable aspiration of gas.
The material for stabilizing the quantity of gas released by the aroma generator to be heated in the aroma cartridge of the present invention, i.e., the gas-generation-maintaining material, is firstly an aroma-generating base material to be heated that is produced by: a dry mixing step (means) for mixing a dried and pulverized non-tobacco material; a first wet mixing step (means) for mixing, in an alcohol and pure water mixture, the non-tobacco material produced by the dry mixing step (means), and a material selected from an aerosol former, a binder or thickener, crosslinked polyvinylpyrrolidone (PVP), a perfume, a non-tobacco extract, β-cyclodextrin, microcrystalline cellulose, and an antimicrobial preservative; a second wet mixing step (means) for producing a slurry including the non-tobacco material, etc., by adding additional pure water and/or alcohol to the alcohol and pure water mixture including the non-tobacco material, etc., produced by the first wet mixing step (means); a paper-making step (means) for producing a water-containing sheet from the slurry produced by the second wet mixing step (means); a sheet molding step (means) for compressing the water-containing sheet to obtain a sheet; a drying step (means) for drying the sheet produced by the sheet molding step (means) to produce an aroma-generating sheet to be heated; and a sheet processing step (means) for cutting or folding the aroma-generating sheet to be heated.
A feature of producing in this method (device) is a second wet mixing. Through this second wet mixing in which pure water and alcohol are added, a dispersion state of the non-tobacco material and the polypropylene glycol, glycerin, or other aerosol former is improved, and the aggregated state of the aroma-generating base material to be heated can therefore be stabilized, and bleed-out of the aerosol former can be reduced without increasing the added quantity of the binder. In particular, ethanol, propanol, or another lower monoalcohol is effective and preferred as the alcohol, and the added quantity thereof is preferably 0.1-10 parts by mass with respect to 100 parts by mass of the non-tobacco material.
A gas-generation-maintaining material in a second aroma cartridge of the present invention is an aroma-generating base material to be heated that is produced by: a dry mixing step (means) for mixing a dried and pulverized non-tobacco material; a first wet mixing step (means) for mixing, in an alcohol and pure water mixture, the non-tobacco material produced by the dry mixing step (means), and a material selected from an aerosol former, a binder or thickener, crosslinked PVP, a perfume, a non-tobacco extract, β-cyclodextrin, microcrystalline cellulose, and an antimicrobial preservative; a second wet mixing step (means) for producing a slurry including the non-tobacco material, etc., by adding additional pure water and/or alcohol to the alcohol and pure water mixture including the non-tobacco material, etc., produced by the first wet mixing step (means); a paper-making step (means) for producing a water-containing sheet from the slurry produced by the second wet mixing step (means); a sheet molding step (means) for compressing or casting the water-containing sheet to obtain a sheet; an aerosol former absorption step (means) for coating the water-containing sheet with, or dipping the sheet into, the aerosol former, a moisture content of the water-containing sheet being reduced to less than 50% by mass by the sheet molding step (means); a drying step (means) for drying the sheet produced by the aerosol former absorption step (means) and producing an aroma-generating sheet to be heated; and a sheet processing step (means) for cutting or folding the aroma-generating sheet to be heated.
A second wet mixing is also a feature of producing by this method (device), and like the first production method (device), the alcohol is preferably ethanol, propanol, or another lower monoalcohol, and the added quantity thereof is preferably 0.1-10 parts by mass with respect to 100 parts by mass of the non-tobacco material. However, an additional feature of the production method (device) of the second aspect is the addition of an aerosol former absorption step (means) for coating the water-containing sheet with, or dipping the sheet into, the aerosol former, a moisture content of the water-containing sheet being reduced to less than 50% by mass. In the conventional production method (device), the aerosol former and the non-tobacco material were separated in an undried sheet of an aroma-generating base material to be heated, in which the dispersion state of the aerosol former and the non-tobacco material was poor and the moisture content was less than 50% by mass, and absorption of the aerosol former was therefore difficult. However, since the dispersion state is improved by the second wet step (means), the aerosol former is absorbed into the sheet in the aerosol former absorption step (means). Therefore, even when the added quantities of the aerosol former and the binder are the same as in the first production method (device), the aggregated state of the aroma-generating base material to be heated can be stabilized, bleed-out of the aerosol former can be reduced, and the aerosol former is also more readily volatilized by heating.
A gas-generation-maintaining material in a third aroma cartridge of the present invention is an aroma-generating base material to be heated that is produced by: a wet mixing step (means) for producing a slurry of a non-tobacco material by mixing a dried and pulverized non-tobacco material with pure water; a paper-making step (means) for producing a water-containing sheet from the slurry produced by the wet mixing step (means); a sheet molding step (means) for compressing or casting the water-containing sheet to obtain a sheet; a drying step (means) for reducing the moisture content of the sheet produced by the sheet molding step (means) to less than 50% by mass; an absorption and adsorption step (means) for coating the sheet produced by the drying step (means) with, or dipping the sheet into, an alcohol and pure water mixture of a material selected from an aerosol former, a binder or thickener, crosslinked PVP, a perfume, a non-tobacco material extract, β-cyclodextrin, microcrystalline cellulose, a concentrate of water discharged in the sheet molding step (means), and an antimicrobial preservative; a drying step (means) for drying the sheet produced by the absorption and adsorption step (means) to produce an aroma-generating sheet to be heated; and a sheet processing step (means) for cutting or folding the aroma-generating sheet to be heated.
In the first and second production methods [devices], a water-containing sheet is formed by making a paper from a slurry obtained by wet-mixing the non-tobacco material and all other materials with pure water and alcohol; however, a feature of the third production method (device) is that a water-containing sheet is produced from a slurry of the non-tobacco material alone, and the aerosol former and other materials are absorbed into and adsorbed on a sheet obtained by drying the water-containing sheet. In the first and second production methods [devices], dispersion of the non-tobacco material and the aerosol former is improved with the object of wet-dispersing all of the materials. As a result of investigating a production method (device) that does not have a step (means) for mixing and dispersing the non-tobacco material and the aerosol former, the inventors discovered that a pure water and alcohol mixture of an aerosol former and other materials rapidly permeates, and is absorbed into and adsorbed on, a dried sheet of a non-tobacco material, as in the third production method (device), and thus arrived at the present invention. The aroma-generating base material to be heated that is produced by this method (device) has a stable aggregated state and reduced occurrence of bleed-out of the aerosol former.
A gas-generation-maintaining material in a fourth aroma cartridge of the present invention is an aroma-generating base material to be heated that is produced by: a non-tobacco-material preparation step (means) for drying and pulverizing a non-tobacco material; a perfume and/or non-tobacco extract mixing step (means) for mixing at least a perfume and/or a non-tobacco material extract and crosslinked PVP and/or β-cyclodextrin in alcohol to cause the perfume and/or non-tobacco extract to reside in the crosslinked PVP and/or β-cyclodextrin; an aerosol former dissolving step (means) for mixing at least an aerosol former and a binder or thickener with pure water; a wet mixing step (means) for mixing a material produced by the non-tobacco material preparation step (means), a material produced by the perfume and/or non-tobacco extract dissolving step (means), and a material produced by the aerosol former dissolving step (means); a sheet molding step (means) for producing an aroma-generating sheet to be heated, by compression from a material produced by the wet mixing step (means); and a sheet processing step (means) for cutting or folding the aroma-generating sheet to be heated.
The previous production methods [devices] had the feature of molding a sheet obtained by a step (means) for making a paper from a slurry of the non-tobacco material and other components. However, in view of the results of the third production method (device), because casting a sheet from a slurry of the non-tobacco material and other materials having various different properties is itself problematic, rather than using a slurry including large quantities of pure water and alcohol in the above method, a sheet of the aroma-generating base material to be heated is molded from a highly viscous mixture of the non-tobacco material, etc., in which there is little pure water and alcohol, using a roll press such as a three-roll mill. It is thought that all of the materials are uniformly kneaded and dispersed in this method (device) because a large shear force and compression force are applied to the mixture of the non-tobacco material, etc.
Here, it is important that a mixing step (means) for mixing at least a perfume and/or a non-tobacco material extract and crosslinked PVP and/or β-cyclodextrin in alcohol to cause the perfume and/or non-tobacco extract to reside in the crosslinked PVP and/or β-cyclodextrin, and an aerosol former dissolving step (means) for mixing at least an aerosol former and a binder or thickener with pure water are provided, and that the perfume, the non-tobacco-material extract, the aerosol former, the binder or thickener, and other materials that can be dissolved in pure water and alcohol are dissolved in advance. In particular, when menthol and/or xylitol is used as the perfume, the menthol and/or xylitol is sorbed by the crosslinked PVP and/or β-cyclodextrin, and exists stably in the aroma-generating base material to be heated, and has the effect of suppressing bleed-out of the aerosol former. Therefore, the mixing step (means) for mixing at least a perfume and/or a non-tobacco material extract and crosslinked PVP and/or β-cyclodextrin in alcohol to cause the perfume and/or non-tobacco extract to reside in the crosslinked PVP and/or β-cyclodextrin plays an extremely important role.
By adopting this production method (device), a stable aggregated state of the aroma-generating base material to be heated is obtained, bleed-out of the aerosol former can be markedly reduced, volatilization of gas by heating of the aroma generator to be heated is promoted without fusion of the aroma-generating base material to be heated, and a decrease in the aspiration quantity over time can be prevented.
Furthermore, in the sheet molding step (means) of this production method (device), a step (means) for adding a material selected from a non-tobacco material, an aerosol former, a binder or thickener, crosslinked PVP, a perfume, a non-tobacco extract, β-cyclodextrin, microcrystalline cellulose, an antimicrobial preservative, and pure water is preferably added. This step (means) can promote kneading by a shear force and compression force and control the moisture content in the sheet molding step (means), and increase volatility of the aerosol former.
A gas-generation-maintaining material in a fifth aroma cartridge of the present invention is an aroma-generating base material to be heated that is produced by: a first wet mixing step (means) for mixing a dried and pulverized non-tobacco material, a first binder aqueous solution in which a first binder is dissolved in pure water, and a material selected from an aerosol former, crosslinked PVP, a perfume, a non-tobacco extract, β-cyclodextrin, microcrystalline cellulose, and an antimicrobial preservative; an aging step (means) for stabilizing a mixture produced by the first wet mixing step (means); a second wet mixing step (means) for mixing an aged mixture produced by the aging step (means) and a second binder aqueous solution in which a second binder is dissolved in pure water; a sheet molding step (means) for producing an aroma-generating sheet to be heated, by compression from a material produced by the second wet mixing step (means); and a sheet processing step (means) for cutting or folding the aroma-generating sheet to be heated. In this production method (device) as well, a step (means) for adding a material selected from a non-tobacco material, an aerosol former, a binder or thickener, crosslinked PVP, a perfume, a non-tobacco extract, β-cyclodextrin, microcrystalline cellulose, an antimicrobial preservative, and pure water is preferably added in the sheet molding step (means), the same as in the fourth production method (device).
A feature of this production method (device) in particular is that a step (means) for aging the mixture is provided, and a step (means) for adding a binder in two additions before and after the aging step (means) is provided. The binder of the first addition is preferably a modified cellulose polymer, and the binder of the second addition is preferably a polysaccharide-based polymer other than cellulose.
The aging step (means) is meant as a step in which the dispersion state of the mixture of the non-tobacco material, etc., changes over time, and is estimated to lead to a dispersion state of lowest energy and stable uniformity, because the above state change can form an aggregated state in the aroma-generating base material to be heated.
Dividing addition of a binder into two additions makes it possible to adequately disperse the mixture without reducing the added quantity of the binder, and is for facilitating adjustment of viscosity. This effect is closely related to the aging step (means). Because a stable dispersion state is created by performing the first addition of a binder and then aging, the second addition of a binder is facilitated, the amount of binder added can be reduced, and viscosity adjustment is facilitated. Therefore, a modified cellulose polymer having excellent dispersing ability is preferred for the first addition, and a polysaccharide-based polymer other than cellulose, having ability as a thickener for adjusting viscosity, is preferred for the second addition.
Any one or more of methyl cellulose, ethyl cellulose, carboxymethyl cellulose, carboxyethyl cellulose, hydroxymethyl cellulose, hydroxyethyl cellulose, hydroxypropyl cellulose, and a sodium salt, a potassium salt, or a calcium salt of carboxymethyl cellulose or carboxyethyl cellulose is preferred for use as the modified cellulose polymer, and any one or more of konjac mannan (glucomannan), guar gum, pectin, carrageenan, tamarind seed gum, gum arabic, soybean polysaccharide, locust bean gum, karaya gum, xanthan gum, and agar is preferred for use as the polysaccharide-based polymer.
Blended amounts of the binders are preferably 5-20 parts by mass of the first binder and 0.1-5 parts by mass of the second binder with respect to 100 parts by mass of the non-tobacco material.
There are also appropriate conditions for the aging step (means) that lead to a stable dispersion state, and the aging step is preferably performed at 15-30° C. for 72-336 hours. Since the binder is a polymer having a hydroxyl group or a carboxyl group, the presence/absence of hydrogen bond formation brings about a difference in the state of molecules dissolved in the pure water and alcohol, and the appropriate temperature conditions are thought to be due to the fact that this effect is temperature-dependent. The optimum temperature range was derived as a result of experimentation. There is a minimum amount of time required for the dispersion state to change over time and stabilize, but taking more time than is needed does not produce a significant change, and reduces productivity.
Described above is a material for causing a gas to be stably released from the aroma generator to be heated, i.e., a solution means for optimizing an aroma-generating base material to be heated as a gas-generation-maintaining material by way of the method (device) for producing the same. However, a material that more actively stabilizes gas release has been proposed.
This gas-generation-maintaining material consists of inorganic particles. The inorganic particles have two effects, dependent upon the location in which the inorganic particles are present. The inorganic particles have one effect when present within an aroma filler to be heated. By addition of inorganic particles to the aroma generator to be heated, the density of the aroma-generating base material to be heated decreases, closure of gas flow passages is eliminated, and there is no difficulty in aspiration of gas. The inorganic particles have another effect when on a surface of an aroma-generating sheet to be heated or the aroma-generating base material to be heated. Even when the aerosol former bleeds out over time from the aroma-generating base material to be heated, the inorganic particles can prevent aroma-generating base materials to be heated from fusing together, flow passages between aroma-generating sheets to be heated or aroma-generating base materials to be heated are not closed, and the problem of difficulty in aspirating aspirated components is overcome. Because fusion of aroma-generating sheets to be heated or aroma-generating base materials to be heated is eliminated, the problem of difficulty inserting the heating element into the aroma-generating base material to be heated is also overcome. Introducing inorganic particles to the aroma generator to be heated also has the effect that regardless of whether the inorganic particles are within or on the surface of the aroma-generating base material to be heated, an area of contact between the heating element and an organic component of the aroma-generating base material to be heated is reduced, and fouling of the heating element of a heating-type smoking appliance can therefore be mitigated.
In order to cause the inorganic particles to be present as a gas-generation-maintaining material within the aroma-generating base material to be heated, the inorganic particles may be added in a composition of the aroma-generating base material to be heated, as a raw material in the process for producing the aroma-generating base material to be heated described above. The step (means) for adding the inorganic particles is not particularly limited, but the inorganic particles are preferably added before wet mixing of a tobacco material and other materials.
In order to cause inorganic particles to be present on the surface of the aroma-generating base material to be heated, in the five production methods [devices] described above, there is a step (means) for spraying inorganic particles on the aroma-generating sheet to be heated, after the step (means) whereby the aroma-generating sheet to be heated is produced, and a step (means) for spraying inorganic particles on the aroma-generating base material to be heated, after the sheet processing step (means) whereby the aroma-generating base material to be heated is produced.
The inorganic particles are preferably magnesium oxide, calcium oxide, titanium oxide, iron oxide, alumina, or another metal oxide; magnesium carbonate, calcium carbonate, or another metal carbonate; calcium phosphate or another metal phosphate; potassium titanate, magnesium titanate, or another titanate; zeolite, colloidal silica, fumed silica, or another silicon oxide, or the like, and an average particle diameter thereof is more preferably 1-100 μm. In order for the inorganic particles to function effectively, 0.1-10 parts by mass of the inorganic particles are preferably added with respect to 100 parts by mass of the non-tobacco material.
As described above, the aroma cartridge of the present invention comprises: an aroma generator to be heated, in which is wound an aroma-generating base material to be heated which is in contact with a heating element; a mouthpiece comprising a filter for filtering an aerosol smoke and a fragrance component generated due to heating by the heating element; and a cartridge exterior body surrounding an external periphery so as to connect the aroma generator to be heated and the mouthpiece, at least one of the aroma generator to be heated and the mouthpiece having at least one of means for optimizing aspiration of the smoke and the fragrance component and a gas-generation-maintaining material for maintaining generation of the smoke and the fragrance component. The aspiration optimization means and the gas-generation-maintaining material in the aroma cartridge of the present invention are described above, and aspects of the invention that complement these features are further described below.
The filling ratio of the aroma-generating base material to be heated that constitutes the aroma generator to be heated is preferably 60-90% in order to obtain stable aspiration of gas. Aspiration of gas is difficult when the filling ratio exceeds the above range, and the quantity of gas released is inadequate when the filling ratio is less than the above range. A filling ratio of 60-73% in particular is preferred in order to prevent fusion over time of the aroma-generating base material to be heated. Fusion over time of the aroma-generating base material to be heated becomes noticeable when the filling ratio exceeds 73%. However, the filling ratio is not thus limited in the case of the aroma-generating base material to be heated that is produced from the improved production methods [devices] described above, and the aroma-generating base material to be heated in which inorganic particles are present within and on the surface thereof, and in these materials, severe fusion over time does not occur even when the filling ratio exceeds 73%.
The aerosol former included in the aroma-generating base material to be heated is preferably 50-80 parts by mass with respect to 100 parts by mass of the non-tobacco material. A volatilized amount of the aerosol former for forming an aerosol is inadequate when the blended amount thereof is less than the above range, and when the blended amount is greater than the above range, bleed-out of the aerosol former from the aroma-generating base material to be heated is severe, and severe fusion of the aroma-generating base material to be heated occurs.
The crosslinked PVP serves to stabilize the aggregated state of the aroma-generating base material to be heated, and to cause temporary residence of the menthol, xylitol, or other fragrance component, and is preferably 7-25 parts by mass with respect to 100 parts by mass of the non-tobacco material. The function of the crosslinked PVP cannot be expressed when the blended amount thereof is less than the above range, and the fragrance component from the non-tobacco material, etc., is insufficient when the blended amount exceeds the above range.
The microcrystalline cellulose is preferably 7-25 parts by mass with respect to 100 parts by mass of the non-tobacco material. This microcrystalline cellulose is a powder having fluid properties that does not dissolve in water, ethanol, or another organic solvent, and is used as an excipient for forming tablets of a medicine. This is because microcrystalline cellulose is effective at preventing adhesion to a die, preventing cohesive failure, etc., in formation of a tablet by direct compression, due to the fluidity thereof and high compressibility with a large volume change thereof. Microcrystalline cellulose has the same effects in the aroma-generating base material to be heated, and the function of the microcrystalline cellulose cannot be expressed when the blended amount thereof is less than 7-25 parts by mass. Conversely, then the blended amount exceeds the above range, the blending ratios of other materials become in adequate relative to the microcrystalline cellulose, and functioning of the aroma-generating base material to be heated is adversely affected.
Lastly, the β-cyclodextrin is preferably 0.2-1.0 part by mass with respect to 100 parts by mass of the non-tobacco material. The β-cyclodextrin serves to cause temporary residence of the menthol, xylitol, or other fragrance component, and must therefore be blended in at least the above quantity. However, functioning of the aroma-generating base material to be heated is inhibited when an excessive quantity of β-cyclodextrin is added. Inclusion of menthol in particular by β-cyclodextrin is known, and β-cyclodextrin is preferably added when menthol is used as a fragrance component.
Constituent materials that are particularly suitable for the aroma-generating base material to be heated of the present invention are listed below.
Parts that can be used as the non-tobacco material include roots (including scaly roots (bulbs), tuberous roots (potatoes), corms, etc.), stems, tubers, bark (including stem bark, tree bark, etc.), leaves, flowers (including petals, pistils, stamens, etc.), seeds and fruits, tree trunks or branches, and the like.
In particular, bulbs include onion, cluster amaryllis, tulip, hyacinth, garlic, scallion, and lily, corms include crocus, gladiolus, freesia, iris, taro, and konjac, tubers include konjac, cyclamen, anemone, begonia, Chinese artichoke, potato, and Apios (potato bean), rhizomes include canna, lotus (lotus root), and ginger, and tuberous roots include dahlia, sweet potato, and cassava, and Jerusalem artichoke rhizophores include genus Dioscorea (yam, Japanese yam, Chinese yam, and other yams). In addition, turnip, burdock, carrot, radish, kudzu, asparagus, bamboo shoots, udo, daikon, yacon, and the like are preferred for use.
Tuberous roots (potatoes) and the plants cited below contain carbohydrates, and are preferred for use as an aroma filling sheet or filler to be heated. Corn starch (maize), potato starch (potato), sweet potato starch (sweet potato), tapioca starch (tapioca), and the like are cited as starches, and function also as thickeners, stabilizers, or the like. These starches can also be crosslinked to enhance acid resistance, enhance heat resistance, enhance shear resistance, etc., or esterified or etherified to enhance storage stability, promote gelatinization, etc., or oxidized to enhance transparency, enhance film properties, enhance storage stability, etc.
Seeds and fruits that are preferred for use include peach, blueberry, lemon, orange, apple, banana, pineapple, mango, grape, kinkan, melon, plum, almond, cacao, coffee bean, peanut, sunflower, olive, walnut, and other nuts and edible fruits (flesh portion) or seeds.
Seaweeds that are preferred for use include sea lettuce, green laver, devil weed, laver, arame, seaweed (Collema nigrescense), egonori, gracilaria, Kagome konbu, Ecklonia cava, ganiashi, sea grapes, Ecklonia kurome, konbu, Porphyra yezoensis, dulse, Pyropia kurogii, Ecklonia stolonifera, tengusa, shredded konbu, Arthrothamnus, nori (seaweed), Petalonia binghamiae, hijiki, hitoegusa, hirome, funori, gutweed, Japanese kelp, mekabu, mozuku, and wakame.
A plant used as an herb or spice can also be preferred for use as the non-tobacco material, and dried gardenia fruit, kaffir lime leaves, Japanese ginger, mugwort, wasabi, ajowan seed, anise, alfalfa, echinacea, shallot, tarragon, everlasting flower, elder, allspice, orris root, oregano, orange peel, orange flower, orange leaf, Cayenne chili pepper (Cayenne chili pepper), German chamomile, Roman chamomile, cardamom, curry leaf, garlic (garlic), catnip, caraway, caraway seed, fragrant olive, cumin, cumin seed, clove, green cardamom, green pepper, cornflower, saffron, cedar, cinnamon, jasmine, juniper berry, jolokia, ginger (ginger), star anise, spearmint, sumac, sage, savory (savory), celery, celery seed, turmeric (Curcuma), thyme, tamarind, tarragon, chervil (cerfeuil), chives, dill, dill seed, tomato (dried tomato), tonka bean, dried coriander, nutmeg, hibiscus, habanero, jalapeno, bird's eye chili, basil, vanilla, phakchi (coriander), parsley, paprika, hyssop, Piment d'Espelette, pink peppercorn, fenugreek seed, fennel, brown mustard, black cardamom, black cumin, black pepper, vetiver, pennyroyal, peppermint (Japanese mint), horseradish, white pepper, white mustard, poppy seed, porcini, marjoram, mustard seed, Maniguette pepper, marigold, Malva flower, mace, yarrow flower, eucalyptus, lavender, licorice, linden, red clover, red pepper, lemongrass, lemon verbena, lemon balm, lemon peel, rose (rose), rose bud (purple), rose hip, rose petal, rosemary, rose red, laurel (bay leaf), long pepper, sesame (raw sesame, roasted sesame), golden chili pepper, szechuan pepper (hoa jao), Mitaka pepper, Japanese pepper, chili pepper, yuzu, and the like can be used. Mixed spices (e.g., five-spice powder, garam masala, ras el hanout, baligoule, chicken curry masala, tandoori masala, quatre epices, herbes de Provence), or a mixture of various plants used as potpourri or the like can also be used.
Teas can also be preferred for use. Teas not only differ according to the plant used to form the tea, but different teas can be formed from the same plant depending on the processing method (device) that is used, and teas are therefore preferred as non-tobacco materials each having different aroma components. Specific examples thereof include Japanese tea, black tea, ashitaba tea, sweet tea, jiaogulan tea, aloe tea, ginkgo leaf tea, oolong tea, curcuma tea, urajirogashi tea, Siberian ginseng tea, plantain tea, kakiodoshi tea, persimmon leaf tea, German chamomile tea, chamomile tea, Chamaecrista nomame tea, Chinese quince tea, chrysanthemum tea, gymnema tea, guava tea, Lycium tea, mulberry leaf tea, black soybean tea, geranium tea, brown rice tea, burdock tea, comfrey tea, kelp tea, sakura tea, saffron tea, shiitake tea, perilla tea, jasmine tea, ginger tea, horsetail tea, Japanese sweet flag tea, Swertia tea, buckwheat tea, Aralia elata tea, dandelion tea, sweet tea, Houttuynia cordata tea, tochu tea, natamame tea, elder tea, privet tea, adlay tea, habu Tea, loquat leaf tea, pu-erh tea, safflower tea, pine needle tea, mate tea, barley tea, Acer maximowiczianum tea, mugwort tea, eucalyptus tea, luo han guo tea, rooibos tea, bitter gourd tea, and the like. In the case of teas, used tea leaves after drinking may be used. A merit of using used tea leaves is that an expensive tea can be reused for effective utilization.
Rice varieties that are preferred for use include indica varieties (Indica type, continent-type, long-grain type), glaberrima varieties (African rice), sativa varieties (Asian rice), Javanica varieties (Javanica type, tropical island type, large-grain varieties), Japonica varieties (Japonica type, temperate island type, short-grain varieties), and NERICA (interspecies hybrid of Asian rice and African rice), and the rice can also be used in the form of flour or bran.
Wheat varieties that are preferred for use include Setaria italica, oats (cultivated varieties of wild oat, oats), barley (barley), wild oats, millet, kodra (kodon millet), wheat (wheat), finger millet, teff, pearl millet, naked barley (barley variant), adlay (fruit, not seed), barnyard millet, fonio, wild rice, Mochi Mugi (mochi variety of barley), Sorghum bicolor (Indian millet, kaoliang, sorghum), corn, rye (rye), buckwheat, amaranth (amaranth, Amaranthus caudatus), quinoa, and Fagopyrum tataricum.
Legume grains (Fabaceae) that are preferred for use include adzuki, carob, common bean, garden pea, pigeon pea, cluster bean, grass pea (Lathyrus sativus), black lentil, cowpea, winged bean, Macrotyloma geocarpum, fava bean, soybean, ricebean, jack bean, tamarind, tepary bean, sword bean, velvet beam (Mucuna pruriens), Vigna subterranea, chickpea, hyacinth bean, scarlet runner bean, horse gram (Macrotyloma uniflorum), moth bean, lima bean, peanut, mung bean, lupine, lentil, and lentil (almond).
Mushrooms that are preferred for use include matsutake, shiitake, Lactarius hatsudake, Lyophyllum shimeji, truffle, mushroom, and Agaricus campestris.
In addition, trunks, branches, bark, leaves, and roots of sugar cane (which may be syrup of molasses), sugar beet (beet), cypress, pine, cedar, hiba, camellia, sandalwood, and other aromatic trees are also preferred for use.
Ferns, mosses, and the like can also be used as the non-tobacco material.
A byproduct, strained lees (sake lees or strained grape lees (comprising skin, seeds, stems, etc., of grapes)), or the like from production of sake, wine, or other fermented liquor can also be used.
Known herbal medicines are also preferred for use. Specific examples thereof include indigo (aisou), Rubia cordifolia root (akanekon), Mallotus bark (akamekashiwa), gambir (asenyaku), benzoin (ansokukou), Clematis root (ireisen), Artemisiae capillaris (inchinkou), fennel (uigyou), curcuma (turmeric), Prunus mume (ubai), Lindera root (uyaku), Quercus salicina (urajirogashi), bearberry leaf, rosae fructus (eijitsu), Corydalis tuber (engosaku), herba rabdosiae (enmeisou), Astragalus root (uogi), Scutellaria root (uogon), phellodendron bark (uobaku), Coptis rhizome (uoren), Pruni cortex (ouhi), Hypericum erectum (otogirisou), Polygala root (onji), Sophora japonica flower (kaika), Long-stamen onion bulb (gaihaku), Prunella spike (kagosou), chebulic myrobalan (kashi), Polygonum tuber (kashuu), Curcuma rhizome (gajutsu), Pogostemon herb (kakkou), kudzu vine root (kakkon), German chamomile flower, Trichosanthes root (karokon), Trichosanthes kirilowii (karonin), dried ginger (kankyou), licorice root (kanzou), common coltsfoot flower (kantouka), Artemisia leaf (gaiyou), Platycodon root (kikyou), Hovenia dulcis (kugishi), orange fruit (kikoku), immature orange fruit (kijitsu), Chrysanthemum flower (kikuka), dried tangerine peel (kippi), Angelicae koreanae radix (kyoukatsu), apricot kernel (kyounin), kumquat (kinkan), Japanese honeysuckle (kinginka), Desmodium styracifolium (kinsensou), barbary wolfberry fruit (kukoshi), Lycium leaf (kukoyou), Sophora root (kujin), walnut (kurumi), Melia azedarach (kurenpi), Lindera umbellata (kuromoji), Dianthus superbus (kubaku), Schizonepeta herb (keigai), Cassia bark (keihi), Cassia seed (ketsumeishi), Pharbitis seed (kengoshi), figwort root (genjin), Saccharum granorum (koui), safflower (kouka), Albizia julibrissin bark (goukanpi), Dalbergia odorifera (koukou), Glycine max (koushi), crested latesummer mint (kouju), red ginseng (koujin), Cyperus rhizome (koubushi), non-glutinous rice (koubei), magnolia bark (kouboku), Ligusticum sinense root (kouhon), Acanthopanax gracilis (gokahi), Achyranthes root (goshitsu), Euodia fruit (goshuyu), Japanese knotweed (gojoukon), great burdock achene (goboushi), Schisandra fruit (gomishi), Bupleurum root (saiko), Asiasari radix (saishin), saffron, Smilax rhizome (sankirai), hawthorn fruit (sanzashi), Gardenia fruit (sanshishi), Cornus fruit (sanshuyu), Vietnamese Sophora root (sanzukon), jujube seed (sansounin), Japanese pepper (sanshou), Scirpus fluviatilis (sanryou), Dioscorea rhizome (sanyaku), Rehmannia root (jiou), aster (shion), Lycium bark (jikoppi), Lithospermum root (shikon), Perilla fruit (shisoshi), Perilla herb (shisoyou), Tribulus fruit (shitsurishi), persimmon calyx (shitei), belvedere fruit (jifushi), peony root (shakuyaku), Cnidium monnieri fruit (jashoushi), Codonopsis root (shajin), plantain seed (shazenshi), plantain herb (shazensou), Amomum seed (shukusha), Houttuynia herb (juuyaku), ginger (shoukyou), hemp palm fruit (shurojitsu), hemp palm leaf (shuroyou), Cimicifuga rhizome (shouma), Tritici fructus (shoubaku), Acorus calamus (shoubukon), magnolia flower (shin'i), Ligustrum fruit (joteishi), Fraxini bark (shinpi), malted rice (shinkiku), Gentiana macrophylla root (jingyou), motherwort fruit (juuishi), Zanthoxylum seed (shokumoku), green tangerine peel (seihi), Acorus tatarinowii (sekishoukon), pomegranate fruit peel (sekiryuujitsuhi), Dendrobium herb (sekkoku), Szechwan lovage rhizome (senkyuu), Peucedanum praeruptorum root (zenko), Nuphar rhizome (senkotsu), Inula japonica (senpukuka), Sambucus williamsii stem (sekkotsuboku), black cardamom (souka), Gleditsia sinensis (soukakushi), Viscum stem (soukisei), Xanthium strumarium (soujishi), Atractylodes rhizome (soujutsu), Thuja orientalis (sokuhakuyou), dipsaci root (zokudan), mulberry bark (souhakuhi), sappan wood (soboku), Perilla leaf (soyou), Gleditsia sinensis (soukyou), rhubarb (daiou), jujube (taisou), Areca peel (daifukuhi), Alisma rhizome (takusha), danshen herb (tanjin), bamboo culm (chikujo), Panax rhizome (chikusetsuninjin), Phyllostachys nigra leaf (chikuyou), Anemarrhena rhizome (chimo), garden burnet root (chiyu), clove (choujji), gambir plant (choutoukou), dried tangerine peel (chinpi), Arisaematis rhizoma (tennanshou), Gastrodia tuber (tenma), Asparagi radix (tenmontou), Benincasa seed (tougashi), Japanese Angelica root (touki), castor oil plant (tougoma), Codonopsis root (toujin), common rush (toushinsou), peach seed (tounin), bitter orange peel (touhi), dodder seed (toshishi), Aesculus turbinata fruit (tochinomi), Eucommia bark (tochuu), Aralia rhizome (dokkatsu), Trichosanthes cucumeroides (dokakon), Cistanche herb (nikujuyou), nutmeg, Lonicera japonica (nindou), ginseng (ninjin), Fritillaria bulb (baimo), germinated barley (bakuga), Platycladus orientalis (hakushonin), white hyacinth bean (hakuhenzu), Ophiopogonis tuber (bakumontou), Psoralea corylifoli (hakoshi), mentha herb (hakka), peppermint (hakka), guava fruit (banka), Pinellia tuber (hange), Agkistrodon (hanbi), Isatidis root (banrankon), Scutellaria barbata (hanshiren), lily root (yurine), Angelica dahurica (byakushi), Hedyotis diffusa (byakukajazetsusou), Japanese stemona root (hyakubukon), Atractylodes macrocephala (byakujutsu), Areca seed (binrouji), Sinomenium stem (boui), Imperata rhizome (boukon), Saposhnikovia root (boufuu), Typha angustifolia pollen (houou), Taraxacum root (houeikon), Moutan bark (botanpi), Ephedra herb (maou), hemp fruit (mashinin), Vitex rotundifola fruit (mankeishi), pine resin (matsuyani), Akebia stem (mokutsuu), Chaenomeles fruit (mokka), Saussurea root (mokkou), myrrh (motsuyaku), Equisetum hyemale (mokuzoku), Belamcanda chinensis (yakan), bitter cardamom (yakuchi), Fallopia multiflora (yakoutou), Siraitia grosvenorii (rakanka), Eupatorium fortunei (ransou), longan aril (ryuuganniku), Japanese gentian (ryuutan), Alpinia offcinarum rhizome (ryoukyou), Ganoderma lucidum (reishi), Forsythia fruit (rengyou), Glechoma hederacea (rensensou), Nelumbo seed (renniku), and Phragmitis rhizome (rokon).
Lastly, an extract or so-called essence of a non-tobacco material can be used, and the extract may be in the form of a liquid, a starch syrup, a powder, granules, a solution, or the like.
Glycerin, propylene glycol, sorbitol, triethylene glycol, lactic acid, diacetin (glycerin diacetal), triacetin (glycerin triacetate), triethylene glycol diacetate, triethyl citrate, isopropyl myristate, methyl stearate, dimethyl dodecane dioate, dimethyl tetradecanedioate, or the like can be used as the aerosol former, but glycerin and propylene glycol are particularly preferred for use.
A commercially available product, such as Divergan (registered trademark) produced by BASF SE or Polyclar (registered trademark) produced by ISP Inc., can be used without modification as the crosslinked PVP.
Through the aroma cartridge of the present invention provided with an aspiration optimization means, it is possible to overcome the problem of decreased aspiration quantity of a gas by a smoker due to blockage of gas flow passages within and between aroma-generating base materials to be heated, which is a problem that characteristically arises in an aroma cartridge that uses a non-tobacco material and does not use any tobacco component. Meanwhile, in the aroma cartridge provided with a gas-generation-maintaining material, a decrease in the released quantity of gas due to blockage of gas flow passages can be remedied, and it is possible to provide an aroma cartridge in which there is no dust generation or dislodgement of the non-tobacco material and other materials.
Through the aroma generator to be heated of the present invention, in which inorganic particles are provided as the gas-generation-maintaining material, fusion of aroma-generating base materials to be heated is prevented, and it is possible to overcome the problem of inability to mount an aroma cartridge on the heating element of a heating-type smoking appliance when the aroma cartridge has been stored for a long time, as well as the problem of the heating element becoming damaged or contaminated.
The present invention will be described in further detail below using embodiments and the accompanying drawings, but the present invention is not limited thereby, various modifications thereof are possible without departing from the scope of the present invention, and the present invention is limited only by the technical ideas recited in the claims.
In
In this smoking, an advantage of an aroma cartridge constituted solely from non-tobacco materials is that substances harmful to the human body, tar, and nicotine are not generated, and it is possible to enjoy various tastes such as coffee, cola, Red Bull, and other beverages; chocolate, vanilla, cream, and other desserts; orange, lemon, melon, and other fruits; and menthol, mint, herbs, and other algefacients. However, such an aroma cartridge has problems that arise as a consequence of using a wide variety of non-tobacco materials for releasing various flavors as substitutes for a tobacco material, which includes a large quantity of fibers.
In an aerosol-forming body that includes a tobacco material, fibers of the tobacco material maintain an aggregated state thereof and hinder fusion and falling out of the tobacco material. However, in the aroma-generating base material to be heated, which includes a non-tobacco material that does not include a large quantity of fibers, a large amount of a binder or the like for performing the function of fibers must be blended therein to stably maintain an aggregated state. The density of the aroma-generating base material to be heated is therefore increased, gas flow passages are blocked, and aspiration of aspirated components becomes difficult, resulting in a reduced aspiration quantity.
Because the aerosol former is glycerin, propylene glycol, or the like, which is liquid at normal temperature, bleed-out of the aerosol former over time from the aroma-generating base material to be heated increases the larger the amount of the binder is, and aroma-generating base materials to be heated fuse together. Gas flow passages are therefore blocked, and aspiration of the fragrance component becomes difficult, resulting in a reduced aspiration quantity. When the fusion described above occurs, not only does it become difficult to insert the heating element into the aroma-generating base material to be heated, but the heating element can also be damaged.
Meanwhile, when the added amount of the binder or the like is reduced to keep gas flow passages clear, the non-tobacco material falls out or forms dust or the like, it is difficult to maintain the aroma cartridge in a rigid form, and the aroma cartridge sometimes breaks when inserted on the heating element. Pieces thereof may also be aspirated into the mouth.
An object of the present invention is to provide a means for solving the aforementioned problems. Specifically, the present invention provides a means for keeping gas flow passages clear and preventing a decrease in aspiration quantity. A solution method that significantly changes blending ratios or a composition used to form the aroma-generating base material to be heated cannot be employed, due to the need to maintain generation of a smoke-forming aerosol or generation of the fragrance component released from the non-tobacco material. Therefore, the present invention provides a means for solving the aforementioned problems by two different approaches.
The first approach is a physical means for solving the aforementioned problems that focuses on, inter alia, configuring the aroma cartridge, and on the mouthpiece structure, which has a marked effect on the aspiration quantity. Another approach is a chemical means for solving the aforementioned problems that focuses on, inter alia, the method (device) for producing the aroma-generating base material to be heated, and on a filling state thereof.
The physical means for solving the aforementioned problems is to provide an aroma cartridge comprising an aspiration optimization means for enhancing the aspiration quantity of the mouthpiece, and provides an aroma cartridge comprising an aspiration optimization means for preventing a decrease in the aspiration quantity by capturing dislodged material or dust of the non-tobacco material and other materials of the aroma generator to be heated. More specifically, the physical means provides a filter constituting the mouthpiece, a support body which constitutes the mouthpiece and prevents the aroma generator to be heated from moving toward the mouthpiece, and an aroma cartridge in which a cavity for enhancing the aspiration quantity by enlarging a gas flow passage, a shape reinforcement member for preventing a decrease in aspiration quantity due to deformation, and a heat insulation material for preventing a joined part from being damaged by heat diffusion are each provided as aspiration optimization means in the mouthpiece. The physical means also provides an aroma cartridge in which a cover material and/or a partition wall material for preventing and capturing dislodged material or dust of the non-tobacco material are provided as aspiration optimization means in the aroma generator to be heated.
The chemical means for solving the aforementioned problems is to provide an aroma cartridge comprising a gas-generation-maintaining material that does not reduce the aspiration quantity of the aroma generator to be heated. More specifically, the chemical means provides an aroma cartridge in which the aroma generator to be heated is provided with, as gas-generation-maintaining materials, an aroma-generating base material to be heated in which an internal structure thereof is improved by the method (device) used to produce the same, an aroma-generating base material to be heated in which a blended amount thereof is optimized, inorganic particles present within and/or on a surface of the aroma-generating base material to be heated, and an aroma-generating base material to be heated in which a filling ratio thereof is improved.
The aspiration optimization means and the gas-generation-maintaining materials can produce an adequate effect alone, and therefore,
The aspiration optimization means will first be described in detail using the accompanying drawings.
The longer and thicker the dimensions of the cavity are, the more the aspiration quantity can be increased, but to avoid problems related to the strength of the mouthpiece, a length c1, an inside diameter b1, and a surface area of the cavity are preferably 10-25 mm, 1-4 mm, and 34.54-326.54 mm2, respectively. In the example illustrated in
The cavity in
Such a filter provided with a cavity is extremely effective also as an aspiration optimization means for solving the problem of reduced aspiration quantity in the conventional mouthpiece provided with a support member and/or cooling member.
Following is a specific description of a means in the present invention for addressing deformation of the mouthpiece when a filter and a support member and/or a cooling member are arranged in the mouthpiece, as described using
The reinforcing support members in
The cavity 2252-5-c1 is arranged in the filter 2252-5 in a longitudinal end part of the filter 2252-5 on the aroma-generator 21 to-be-heated side thereof so that center axes of straight cylinders of the filter 2252-5 and the cavity 2252-5-c1 substantially coincide. The aspiration optimization means herein is a shape-reinforcing material having: a tubular reinforcing material 2251-5-s4 as a hollow concentric circular tube in a through hole 2251-5-h of a support member 2251-5 which is formed so that the center axis of a straight cylinder thereof is substantially the same as the center axis of the support member 2251-5, and which has substantially the same axis as the through hole 2251-5-h and has a radius smaller than a radius of the through hole 2251-5-h; and four plate-shaped reinforcing materials 2252-5-s3 provided on an external peripheral side of the tubular reinforcing material 2251-5-s4 in a shape so as to contact an inner wall of the through hole 2251-5-h in a radial direction of the tubular reinforcing material 2251-5-s4; the aspiration optimization means being fixedly or movably arranged as the reinforcing support member 2251-5. This configuration is not limiting, and various reinforcing support members and various filters in which a cavity is formed can be combined.
The cavity 2263-c1 is disposed in a longitudinal end part of the filter 2263 on the aroma-generator 21 to-be-heated side thereof so that center axes of straight cylinders of the filter 2263 and the cavity 2263-c1 substantially coincide. The aspiration optimization means herein is a shape-reinforcing material having: a tubular reinforcing material 2261-s4 as a hollow concentric circular tube in a through hole 2261-h of a support member 2261 which is formed so that the center axis of a straight cylinder thereof is substantially the same as the center axis of the support member 2261, and which has substantially the same axis as the through hole 2261-h and has a radius smaller than a radius of the through hole 2261-h; and four plate-shaped reinforcing materials 2261-s3 provided on an external peripheral side of the tubular reinforcing material 2261-s4 in a shape so as to contact an inner wall of the through hole 2261-h in a radial direction of the tubular reinforcing material 2261-s4; the aspiration optimization means being fixedly or movably arranged as the reinforcing support member 2261. This configuration is also not limiting in this case, and various reinforcing support members and various filters in which a cavity is formed can be combined with a cooling member interposed therebetween.
As the aspiration quantity is increased by improvement of the filter and support member as described above, heat of a gas is more readily transmitted by convection from the heating element to the filter. Adhesion between members constituting the aroma cartridge therefore decreases, and gas leaks from between members, which may adversely affect the aspiration quantity. Described below is an aroma cartridge capable of solving this problem, in which the aroma cartridge is provided with a heat insulation member between the mouthpiece and the aroma generator to be heated.
The heat insulation members described above do not allow a general spread of high-temperature gas, unlike the support member adjacent to the aroma generator to be heated, and are preferably constituted from a heat-insulating porous body made of plastic, such as a sponge having continuous holes with long flow passages. The heat insulation members also function to retain the high-temperature gas to some degree and cool the gas, and need not have the degree of cooling functionality of a cooling member, and are preferably applied instead of a support member for preventing the aroma generator to be heated from moving toward the mouthpiece. Consequently, a length s of the heat insulation member depends upon the material used therein, but a length of about 1-5 mm is adequate.
A cover material and/or a partition wall material, which function as an aspiration optimization means for preventing an extreme decrease in aspiration quantity due to blockage of voids in the cooling member and the filter by dislodged material or dust of the non-tobacco material, will next be described using the accompanying drawings.
Either one or both of the cover material and the partition wall material may be provided, in accordance with the state of the aroma-generating base material to be heated aroma generator to be heated in which aroma-generating base materials to be heated are bundled. The cover material and/or the partition wall material prevent clogging of the filter and/or the cooling member by dislodged material or dust, and ensure a stable aspiration quantity. The cover material and/or the partition wall material can also prevent dislodged material, dust, or the like from being generated when the aroma cartridge is impaled on the needle-shaped heating element.
Physical solution means for structural improvement to ensure the gas aspiration quantity when smoking the aroma cartridge were described in detail above using the accompanying drawings. A gas-generation-maintaining material provided to the aroma generator to be heated, in order to solve the problem of a decrease in the aspiration quantity of gas, is described below using the accompanying drawings. The conventional aroma generator to be heated has the drawback that the released quantity of gas decreases over time, which brings about a reduction in the aspiration quantity of gas during smoking. The aroma cartridge of the present invention is provided with an aroma-generating base material to be heated which constitutes an aroma generator to be heated, to which is applied a chemical solution means, as a gas-generation-maintaining material for preventing a decrease in the aspiration quantity of gas.
First,
The aroma-generating base material to be heated is produced by various producing steps (means), but is ultimately wound as a sheet or a filler to become an aroma-generating substrate to be heated. As indicated in
Following is a specific description, using the accompanying drawings, of a gas-generation-maintaining material having a function for preventing a decrease in the quantity of gas released by the aroma generator to be heated, which is closely related to a decrease in the aspiration quantity of gas during smoking, and ensuring the aspiration quantity of gas; i.e., a specific description of an aroma-generating base material to be heated to which a chemical solution means is applied. In the aroma cartridge of the present invention, the aroma generator to be heated is provided with an aroma-generating base material to be heated, to which the chemical solution means is applied, as a gas-generation-maintaining material.
Methods [devices] for producing the conventional aroma-generating base material to be heated include various methods [devices], but an example thereof is illustrated in
(Production Example 1) is presented as a specific example.
The pulverized products below were loaded into a dry mixer as non-tobacco materials and dry-mixed for 5 minutes.
The dry mixture above and the ingredients below were loaded into a wet mixer and wet-mixed for 15 minutes.
In the step (means) for molding a sheet from a slurry obtained as described above, a water-containing sheet was created by loading a specified amount of the slurry on a frame provided with an appropriate drainboard. At this time in the present Production Example, assuming the moisture content of 100 in the slurry, the moisture content in the water-containing sheet was about 95.
The water-containing sheet was then passed three times through a press roll set to a predetermined clearance to mold the water-containing sheet, an amount of pure water corresponding to 7 parts by mass with respect to 100 parts by mass in the water-containing sheet passed three times through the press roll was then added to the water-containing sheet, and the water-containing sheet was passed five more times through the press roll.
The molded water-containing sheet obtained as described above was then dried for 300 minutes in a 35° C. environment to create an aroma-generating sheet to be heated having a moisture content of 20% by mass. The drying temperature is preferably less than 50° C. to maintain flavor. The drying temperature is more preferably less than 45° C., and even more preferably less than 40° C. The thickness of the sheet is adjusted as appropriate, but was set to 0.5 mm in the present Production Example. The sheet was cut, and a rectangular aroma-generating sheet to be heated having a length of 240 mm and a width of 75 mm, and an aroma-generating filler to be heated having a length of 240 mm and a width of 1.5 mm were obtained. The length direction of the filler and the sheet cut from the aroma-generating sheet to be heated was parallel to a rotational axis direction of the roll, and the width direction of the filler and the sheet was the rotation direction of the roll.
A single sheet of the aroma-generating sheet to be heated and 50 units of the aroma-generating filler to be heated, fabricated as described above, were wound and then cut to a length of 12 mm to produce an aroma generator to be heated, such as illustrated in
The aroma generator to be heated and the aroma cartridge fabricated as described above were evaluated in the manner indicated below.
<<Evaluation 1>>
Fabricated aroma cartridges were packed into a paper box 70 mm on a long side thereof, 14 mm on a short side thereof, and having a height of 45 mm, so that the aroma generators to be heated were facing the bottom of the box. A box containing aroma cartridges thus prepared was placed in a plastic bag and left to stand for two weeks in a 40° C. environment. The box was then retrieved and left to stand for one day in a normal-temperature and normal-humidity environment, and the evaluation described below was performed. Packing material was taken from the aroma generators to be heated, and it was confirmed whether the aroma cartridges were packed together. The aroma cartridges were also smoked by five test subjects, and sensory evaluation of the aspiration quantity and flavor was performed.
For aroma cartridges in Rank C, difficulty of insertion on the heating element of the heating-type smoking took is made highly likely by prolonged storage and other factors.
The aroma cartridge fabricated in (Production Example 1) was evaluated as Rank C, the aroma-generating sheet to be heated and the aroma filler to be heated fused over time, the quantity of gas released during smoking, i.e., the gas aspiration quantity, was decreased and flavor also deteriorated, and the aroma-generating sheet to be heated and the aroma filler to be heated did not function as gas-generation-maintaining materials for the aroma generator to be heated.
This problem was solved by improving the production method (device). A feature of the improved production method (device) is that a second wet mixing step (means) is introduced as a producing step (means), as indicated in
(Production Example 2) is presented as a specific example.
Black tea leaves were dried at 70° C. to give a moisture content of 2 by mass, and then pulverized. Licorice, lotus leaves, and Korean ginseng were also dried and pulverized in the same manner. The drying temperature is preferably 60° C.-80° C. When the drying temperature is in this range, it is easy to reach the desired moisture content while avoiding dissipation of necessary flavor components. The desired moisture content is even easier to reach when the drying temperature is 65° C. or above, and dissipation of necessary flavor components can be further prevented when the drying temperature is 75° C. or below.
The moisture content after pulverization is preferably 5% by mass or less. Slurry formation in the subsequent step (means) is thereby facilitated. A moisture content after pulverization of 3% by mass or less is more preferred. A moisture content of 0.1% by mass or greater is preferred to enable good compatibility with water or the like.
The dried and pulverized materials described above, passed through an 80 mesh sieve, were used as non-tobacco materials, which the non-tobacco materials were loaded into a dry mixer in the blending quantities shown below and dry-mixed for 5 minutes.
The dry mixture above and the ingredients below were loaded into a wet mixer, and a first wet mixing was performed for 15 minutes.
Then, 180 parts by mass of pure water and 10 parts by mass of ethanol were additionally loaded in the wet mixer including the above slurry, and a second wet mixing was performed for 10 minutes. Ethanol was added in this case because the dispersion state of the dry pulverized products with respect to polypropylene glycol and glycerin can be markedly improved thereby. The alcohol is not limited to ethanol, insofar as the alcohol is a lower monoalcohol. The added amount of such a lower monoalcohol is preferably 0.1-10 parts by mass with respect to 100 parts by mass of the dry pulverized products. An improved dispersion state is observed when the aforementioned added amount is 0.1 part by mass or greater, and keeping the added amount to 10 parts by mass or less makes it possible to suppress persistence of the lower monoalcohol. The effect is more pronounced when the added amount is 0.5-5 parts by mass.
The reason for loading the pure water first to form the mixture is that a slurry having better dispersion can be obtained by advancing dispersion of the mixture beforehand, and then diluting/mixing with additional water. It is also preferred to divide loading of the water into multiple additions. When the water is loaded in multiple additions, a combination of additions is preferred in which small amounts of water are loaded at first, and the amount of water loaded is subsequently increased. This is because dispersion is enhanced to a high degree during loading of water at first, and the slurry becomes uniform as the amount of water loaded is subsequently increased.
In the step (means) for molding a sheet from a slurry obtained as described above, a water-containing sheet was created by loading a specified amount of the slurry on a frame provided with an appropriate drainboard. At this time in the present Production Example, assuming the moisture content of 100 in the slurry, the moisture content in the water-containing sheet was about 95.
The water-containing sheet was then passed three times through a press roll set to a predetermined clearance to mold the water-containing sheet, an amount of pure water corresponding to 7 parts by mass with respect to 100 parts by mass in the water-containing sheet passed three times through the press roll was then added to the water-containing sheet, and the water-containing sheet was passed five more times through the press roll. Preferably, 2 parts by mass to 15 parts by mass of water are added with respect to 100 parts by mass of the water-containing sheet. Adding water over the course of molding the water-containing sheet a plurality of times in this manner has the effect that the water included in the water-containing sheet is readily made uniform in a certain range, and has the effect that conditions in a subsequent drying step (means) can be made uniform, and that the quality of the final product can be made uniform.
The molded water-containing sheet obtained as described above was then dried for 300 minutes in a 35° C. environment to create a molded sheet for an electronic cigarette filler, having a moisture content of 20% by mass. The drying temperature is preferably less than 50° C. to maintain flavor. The drying temperature is more preferably less than 45° C., and even more preferably less than 40° C. The thickness of the sheet was set to 0.5 mm. In order to be wound as an aroma generator to be heated, the sheet was cut into an aroma-generating sheet to be heated having a length z of 240 mm and a width x of 75 mm, and an aroma-generating filler to be heated having a length z of 240 mm and a width x of 1.5 mm.
A single sheet of the aroma-generating sheet to be heated and 50 units of the aroma-generating filler to be heated, produced by the above method (device), were wound and then cut to a length z of 12 mm to produce an aroma generator to be heated, such as illustrated in
The aroma cartridge was subjected to <<Evaluation 1>> in the same manner as the aroma cartridge fabricated in (Production Example 1), and a result of Rank A was obtained. This reason for this result was considered to be that the aroma-generating base material to be heated which was produced by this method (device) had minimal fusion over time within or between the aroma-generating base materials to be heated, and little change in the amount of gas released by heating, and that the gas aspiration quantity being maintained during smoking. Specifically, the aroma-generating base material to be heated which was produced by this method (device) functions as a gas-generation-maintaining material for the aroma-generating substrate to be heated.
The production method (device) illustrated in
The dispersion state in the second wet mixing was good, and absorption of propylene glycol in this step (means) therefore proceeded rapidly. The aroma-generating base material to be heated having a thickness of 0.5 mm, which was produced by this method (device), was also cut to the same size as in (Production Example 2) to produce an aroma cartridge. When the aroma cartridge was subjected to <<Evaluation 1>>, a result of Rank A was obtained, and it was clear that the aroma-generating sheet produced by this method (device) also functions as a gas-generation-maintaining material for the aroma-generating substrate to be heated.
The improvements shared by the production methods [devices] of
Specifically, an aroma-generating base material to be heated is produced by: a wet mixing step (means) M1 for mixing, with pure water, a dried and pulverized non-tobacco material for producing a gas-generation-maintaining material, and producing a slurry of the non-tobacco material; a paper-making step (means) S1 for producing a water-containing sheet from the slurry produced by the wet mixing step (means); a sheet molding step (means) S2 for compressing or casting the water-containing sheet to obtain a sheet; a drying step (means) S3 reducing the moisture content of the sheet produced by the sheet molding step (means) to less than 50% by mass; an absorption and adsorption step (means) S4 for coating the sheet produced by the drying step (means) with, or dipping the sheet into, an alcohol and pure water mixture of a material selected from an aerosol former, a binder or thickener, crosslinked PVP, a perfume, a non-tobacco material extract, β-cyclodextrin, microcrystalline cellulose, a concentrate of water discharged in the sheet molding step (means), and an antimicrobial preservative; a drying step (means) for producing an aroma-generating sheet to be heated, by drying the sheet produced by the absorption and adsorption step (means); and a sheet processing step (means) H1 for cutting or folding the aroma-generating sheet to be heated.
(Production Example 3) is presented as a specific example of this production method (device).
The above ingredients were mixed to obtain a slurry.
The slurry was cast to obtain a sheet having at thickness of 0.5 mm. Residual water from casting was concentrated and stored, and used for the next step (means).
The sheet was dried, the ingredients below were added per 100 parts by mass of the sheet, and the product was dried to produce a sheet.
The resultant sheet was used to fabricate an aroma generator to be heated and an aroma cartridge which uses the same, in the same manner as in (Production Example 2), and when <<Evaluation 1>> thereof was performed, a result of Rank A was obtained. It was clear that the aroma-generating sheet to be heated that was produced by this method (device) also functions as a gas-generation-maintaining material for the aroma-generating substrate to be heated.
The production methods [devices] heretofore described feature fabricating an aroma-generating sheet to be heated by producing a slurry of a non-tobacco material, etc., and making a paper thereof. However, since good results have been obtained from a method (device) in which an aerosol former, a perfume, a binder, and other components are absorbed into a water-containing sheet produced by making a paper of a slurry of only a non-tobacco material, as illustrated in
Specifically, this method is a method (device) for producing an aroma-generating base material to be heated, by: non-tobacco material preparation steps (means) Z1 and 2 for drying an pulverizing a non-tobacco material; a perfume and/or non-tobacco extract dissolving step (means) M1 for mixing at least a perfume and/or a non-tobacco material extract and crosslinked PVP and/or β-cyclodextrin in alcohol to cause the perfume and/or non-tobacco extract to reside in the crosslinked PVP and/or β-cyclodextrin; an aerosol former dissolving step (means) M2 for mixing at least an aerosol former and a binder or thickener with pure water; a wet mixing step (means) M3 for mixing the material produced by the non-tobacco material preparation step (means), the material produced by the perfume and/or non-tobacco extract dissolving step (means), and the material produced by the aerosol former dissolving step (means); a sheet molding step (means) S1 for producing an aroma-generating sheet to be heated, by compression from the material produced by the wet mixing step (means); and a sheet processing step (means) H1 for cutting or folding the aroma-generating sheet to be heated.
(Production Example 4) is presented as a specific example of this production method (device).
In the non-tobacco material preparation steps (means) Z1 and 2 for drying and pulverizing a non-tobacco material, a non-tobacco material having a moisture content of 20% by mass was prepared using black tea leaves as the non-tobacco material, by drying the non-tobacco material in an oven at 70° C., then pulverizing the material using an agitation mill and passing the material through an 80 mesh sieve.
In the step (means) M1 for dissolving menthol, menthol is dissolved by weighing out and mixing menthol, a lower alcohol, and a water-insoluble crosslinked polymer. The water-insoluble crosslinked polymer is preferably added and mixed after the menthol is dissolved in the lower alcohol. An effect whereby dissipation of the menthol is suppressed is obtained when menthol, a lower alcohol, and a water-insoluble crosslinked polymer are mixed.
Here, the menthol is not limited to being obtained from a natural product, and a synthetic product can also be used. Peppermint, mint, peppermint oil, and other materials that include menthol may also be used.
The lower alcohol is a solvent for dissolving the menthol, and ethyl alcohol is especially preferred for use.
The water-insoluble crosslinked polymer is intended as a polymer which is obtained by crosslinking a polymer that is water-soluble in the non-crosslinked form thereof, which then becomes insoluble in water and swells. It is, of course, preferred that the water-insoluble crosslinked polymer swell and not dissolve in the lower alcohol, and such a polymer is selected. Such a water-insoluble crosslinked polymer has a hydrophilic component and a hydrophobic component, and it is thought that the hydrophilic component contributes to swelling, and that dissipation of the menthol is suppressed by orienting of the hydrophilic component toward the menthol. Preferred examples of the hydrophilic crosslinked polymer include crosslinked PVP, and crosslinked polysaccharides obtained by subjecting a water-soluble polysaccharide to epoxy crosslinking, ester crosslinking, and ether crosslinking. An effect in which menthol dissipation is markedly suppressed is observed particularly when ethanol and crosslinked PVP are used together with menthol.
It is sufficient to add enough menthol to achieve a target amount of a desired flavor, but the menthol content in the aroma-generating base material to be heated is preferably 0.1-10% by mass, and more preferably 0.2-5% by mass.
When forming the aroma-generating base material to be heated, the added amount of the hydrophilic crosslinked polymer is preferably 10-2000 parts by mass, more preferably 50-600 parts by mass, with respect to 100 parts by mass of menthol.
In order for the effect of inhibiting dissipation of the menthol to be obtained, the hydrophilic crosslinked polymer is preferably present in a ratio of 2% by mass or more, more preferably 4% by mass or more, in the aroma-generating base material to be heated. Including the hydrophilic crosslinked polymer in such an amount makes long-term storage possible while suppressing dissipation of the menthol, and makes it possible for the cooling sensation of menthol to be enjoyed even after long-term storage. The content of the hydrophilic crosslinked polymer in the aroma-generating base material to be heated is preferably 20% by mass or less, and more preferably 10% by mass or less. Flavors caused by non-plant-derived polyphenols and the like can be maintained when the content of the hydrophilic crosslinked polymer is 10% by mass or less.
The lower alcohol used is preferably included in the amount of 50 parts by mass or more with respect to 100 parts by mass of menthol. When the amount of the lower alcohol is 100 parts by mass or more, adequate mixing of the hydrophilic crosslinked polymer is possible while the menthol is dissolved. When the amount of the lower alcohol is 2000 parts by mass or less, persistence of the lower alcohol in subsequent steps (means) can be reduced, and an efficient production process (means) can be obtained.
Based on the above, as an example,
were weighed, the menthol was dissolved in ethyl alcohol to obtain a menthol ethyl alcohol solution, crosslinked PVP was then added to the menthol ethyl alcohol solution and agitation-mixed, and a menthol/ethyl alcohol/crosslinked PVP mixture was obtained.
Then, in the step (means) M2 for dissolving an aerosol former and other materials, an aerosol former, a flavor additive, a preservative, a binder or thickener, and other ingredients are dissolved in pure water.
Here, glycerin, propylene glycol, sorbitol, triethylene glycol, lactic acid, diacetin (glycerin diacetal), triacetin (glycerin triacetate), triethylene glycol diacetate, triethyl citrate, isopropyl myristate, methyl stearate, dimethyl dodecane dioate, dimethyl tetradecanedioate, or the like can be used as the aerosol former. Glycerin and propylene glycol are particularly preferred for use. These aerosol formers are preferably used in an amount of 1-80% by mass, more preferably 10-40% by mass, with respect to the aroma-generating base material to be heated.
A perfume for adding flavor is used as needed, and examples thereof include essences of peppermint, cocoa, coffee, black tea, and the like.
An antimicrobial preservative for food can also be added as needed. Sorbic acid, potassium sorbate, benzoic acid, sodium benzoate, or the like can be used as the antimicrobial preservative.
Guar gum, xanthan gum, gum arabic, locust bean gum, and other gums; hydroxypropyl cellulose, carboxymethyl cellulose, hydroxyethyl cellulose, methyl cellulose, ethyl cellulose, and other modified cellulose polymers; a starch, alginic acid and other organic acids; sodium alginate, sodium carboxymethyl cellulose, carrageenan, agar, and pectin or another polysaccharide of a conjugate base salt or the like of an organic acid can be used as the binder or thickener or the like. The above substances may be used in combination.
A 20% aqueous solution of glycerin, propylene glycol, sodium carboxymethyl cellulose, methyl cellulose, glucomannan, and xylitol from among the above substances was prepared.
Then, in the step (means) M3 for wet mixing the materials of the non-tobacco material preparation steps (means) Z1 and 2, the perfume dissolving step (means) M1, and the aerosol former dissolving step (means) M2, a non-tobacco plant composition for an aroma-generating base material to be heated was then fabricated by stirring the materials in the blending ratios below for 15 minutes while applying shear force through use of an impeller, using an ordinary wet mixer.
A three-roll mill was used in the step (means) for molding a sheet. A step for loading the above composition into a three-roll mill, adding 20 parts by mass of pure water while observing the state of the sheet, and collecting a sheet-shaped product by pressing a doctor blade against a roll was repeated 8 times, and a final sheet-shaped non-tobacco plant composition was obtained. When a three-roll mill is used, while kneading, dispersion, and the like are performed by a compression force from pressing between close rolls and a shear force from the roll speed difference, the desired sheet thickness can be obtained using the doctor blade, and it is possible to produce a sheet that is more uniform than a sheet fabricated by a slurry paper-making step (means). Besides a three-roll mill, a press roller or press machine can also be suitably used.
In the sheet molding step (means) S1, a non-tobacco plant, an aerosol former, a perfume, an antimicrobial preservative, a binder or thickener, water, or the like may be added as needed.
The pure water used in the present invention is preferably pure water which has been sterilized or from which microbes have been removed, but the pure water may also be obtained using a reverse osmosis membrane, ion exchange, or the like.
A sheet having a thickness of approximately 0.5 mm was molded in the sheet molding step (means) S1. The thickness of the sheet may be in the range of 0.1-1.0 mm or 0.1-0.5 mm.
This aroma-generating sheet to be heated having a thickness of 0.5 mm was then cut into an aroma-generating sheet to be heated and an aroma-generating filler to be heated, in the same manner as in (Production Example 2), and was then processed into an aroma generator to be heated, and assembled into an aroma cartridge. When <<Evaluation 1>> thereof was performed, a result of Rank A was obtained, and it was clear that the aroma-generating sheet to be heated that was produced by this method (device) also functions as a gas-generation-maintaining material for the aroma-generating substrate to be heated.
In an aroma-generating base material to be heated that uses a non-tobacco material, the component compositions and the properties thereof are diverse, and it has become clear that nonuniformity of mixing, dispersal, and solution state thereof results in changes over time such as bleed-out of the aerosol former from the aroma-generating base material to be heated, and causes the quantity of gas released from the aroma-generating base material to be heated to decrease and the gas aspiration quantity during smoking to decrease. Consequently, the problem of a change in the gas aspiration quantity over time is solved by improving the nonuniformity.
Furthermore, the binder or thickener, which is one of the constituent materials of an aroma-generating base material to be heated that uses a non-tobacco material, was discovered to be a cause of problems that are specific to an aroma cartridge that uses a non-tobacco material. The binder or thickener is added to prevent fusion within the aroma-generating base material to be heated or between aroma-generating base materials to be heated and to prevent the aggregated state thereof from being disrupted due to the inability to include a large quantity of fibers. However, it was learned that the density of the aroma-generating base material to be heated increases when the added amount of the binder or thickener is increased, and although the aggregated state thereof can be maintained, the aroma-generating base material to be heated shrinks over time, and bleed-out of the aerosol former becomes severe. As a result of investigating the added amount of the binder, the addition method (device), and the type of the binder, it was discovered that the problems described above can be solved by an aroma-generating base material to be heated that is produced by the method (device) illustrated in
Specifically, an aggregated state can be stably maintained, and there is no blockage of gas flow passages in an aroma-generating base material to be heated that is produced by: steps (means) Z1 and 2 for preparing a dried and pulverized non-tobacco material; a step (means) M1 for producing a first binder aqueous solution in which a first binder is dissolved in pure water; a first wet mixing step (means) M1 for mixing a material prepared by steps (means) Z4 and 5 for preparing a material selected from an aerosol former, crosslinked PVP, a perfume, a non-tobacco material extract, β-cyclodextrin, microcrystalline cellulose, and an antimicrobial preservative; an aging step (means) Y1 for stabilizing a mixture produced by the first wet mixing step (means); a second wet mixing step (means) M2 for mixing an aged mixture produced by the aging step (means) and a second binder aqueous solution produced by a step (means) Z6 for dissolving a second binder in pure water; a sheet molding step (means) S1 for producing an aroma-generating sheet to be heated, by compression from the material produced by the second wet mixing step (means); and a sheet processing step (means) H1 for cutting or folding the aroma-generating sheet to be heated. Fusion over time between the aroma-generating base materials to be heated was also not observed.
(Production Example 5) is presented as a specific example of this production method (device).
In the step (means) Z1 for drying and pulverizing the raw material non-tobacco plant, the moisture content is preferably adjusted to facilitate absorption or support of the aerosol former, pure water, and other components, and the drying temperature is preferably 60-80° C. or lower. When the drying temperature is in this range, it is easy to reach the desired moisture content while avoiding dissipation of necessary flavor components. The desired moisture content is even easier to reach when the drying temperature is 65° C. or above, and dissipation of necessary flavor components can be further prevented when the drying temperature is 75° C. or below. The moisture content after drying/pulverization is preferably 5% by mass or less, and slurry formation in the subsequent step (means) is thereby facilitated. A moisture content after drying/pulverization of 3% by mass or less is more preferred. However, compatibility with water, etc., decreases when the moisture content is 0.1% by mass or greater. By further providing a sieving step (means) for sieving the dried pulverized product, a non-tobacco plant having the desired particle size can be supplied to the first wet mixing step (means) M3, and slurry formation is facilitated.
Celluloses, konjac mannan (glucomannan), guar gum, pectin, carrageenan, tamarind seed gum, gum arabic, soybean polysaccharide, locust bean gum, karaya gum, xanthan gum, agar, corn starch, and the like can be cited as examples of the first binder used in the preparation step (means) Z3 for dissolving a first binder in pure water, but celluloses are preferred. Regarding viscosity, mixing with the non-tobacco plant is favorable when the solution viscosity is 300 mPa·s or greater. A solution viscosity of 5000 mPa·s or greater is appropriate for binding of a non-tobacco plant. The solution viscosity is a value measured using a Brookfield viscometer at 10-30 rpm in a 25° C. environment, by preparing a 1% aqueous solution, starting rotation of the rotor, and taking the measurement value when the display value stabilizes. Here, although the upper limit of measurement by the Brookfield viscometer is 100,000 mPa·s, a viscosity exceeding this upper limit is within the viscosity range described above.
Celluloses that are preferred as the first binder generally include cellulose, cellulose derivatives, and metal salts thereof, but a water-soluble cellulose is particularly preferred in the present invention from the perspective of binding a non-tobacco plant. Examples of such celluloses can include methyl cellulose, ethyl cellulose, carboxymethyl cellulose, carboxyethyl cellulose, hydroxymethyl cellulose, hydroxyethyl cellulose, hydroxypropyl cellulose, and sodium salts, potassium salts, calcium salts, and other metal salts of these celluloses. Among the above examples, metal salts of celluloses are more preferred, and sodium carboxymethyl cellulose is even more preferred.
Glycerin, propylene glycol, sorbitol, triethylene glycol, lactic acid, diacetin (glycerin diacetal), triacetin (glycerin triacetate), triethylene glycol diacetate, triethyl citrate, isopropyl myristate, methyl stearate, dimethyl dodecane dioate, dimethyl tetradecanedioate, or the like can be used as the aerosol former used in the step (means) Z4 for preparing the aerosol former, but glycerin and propylene glycol are particularly preferred. These aerosol formers are used in a range of 1-80% by mass, particularly preferably 10-40% by mass, with respect to the composition of the aroma-generating base material to be heated.
In a step (means) Z5 for preparing a component used in addition to the above components, menthol, peppermint, cocoa, coffee, black tea essence, or another flavoring agent for adding flavor as needed, crosslinked PVP or β-cyclodextrin having a function for causing temporary residence of the flavoring agent, microcrystalline cellulose having moldability and ease of release from a die or the like, sorbic acid, potassium sorbate, benzoic acid, sodium benzoate, or another food antimicrobial preservative for storage stability, or the like can be added.
The materials prepared as described above are mixed in the first wet mixing step (means) M1. The mixer need not be specialized, and may be a mixer in which materials in a mixing tank are mixed while a shear force is applied thereto by an impeller, for example, and it is also possible to knead and further intensify mixing using a roll mill, a kneader, or an extruder. The mixing temperature in this step (means) is preferably 40° C. or lower, and more preferably 30° C. or lower, and maintaining the temperature at about 25° C. is even more preferred. The reason for this is that there is a risk of dissipation of fragrance components when excessive heat is applied during mixing. The temperature of the mixing tank must therefore be controlled.
A first mixture produced by the first wet mixing step (means) M1 preferably undergoes an aging step (means) Y1 for leaving the first mixture to stand for a predetermined time at a predetermined temperature, but this step (means) is not essential. However, addition of the binder must be divided into a first mixing step (means) and a second mixing step (means). When a non-tobacco material mixture in which the binder is dividedly added and which is not subjected to an aging step (means) Y1, and an aged mixture subjected to the aging step (means) Y1 are processed into an aroma cartridge as the aroma-generating base material to be heated, and smoking evaluation thereof is performed using the heating-type smoking appliance illustrated in
The temperature in the aging step (means) Y1 is preferably 15-30° C., and more preferably 18-24° C. The reason for this is that the flavor improvement described above is increased when the temperature is 15° C. or higher, and change in flavor and change in aspiration quantity over time are suppressed and improvement of flavor change over time is maintained when the temperature is 30° C. or below. These effects are more pronounced when the temperature is 18-24° C. The time for the aging step (means) Y1 is preferably 72-336 hours, and more preferably 96-192 hours. The reason for this is that an improvement of flavor is observed when the time is 72 hours or more, and change in flavor and change in aspiration quantity over time are suppressed and improvement of flavor change over time is maintained when the time is 336 hours or less. These effects are more pronounced when the time is 96-192 hours. Aging is preferably performed with the mixture from the first wet mixing in a sealed condition. This is to prevent dissipation of flavor.
The mixture immediately after the first wet mixing and the mixture aged after the first wet step (means) are inputted to the second wet mixing step (means) M2. The second wet mixing step (means) M2 has the feature of adding a second binder and mixing. The effect of divided addition of the first binder and the second binder is that, in addition to the effect of improving initial aspiration quantity and flavor and reducing a change in aspiration quantity and flavor over time, molding into a desired form is facilitated in the sheet molding step (means) H1. The reason for this is that mixing is easier than during addition in the first step (means), the time until the viscosity of the mixture becomes even can be shortened, and viscosity adjustment is facilitated.
As in the case of the first binder, celluloses, konjac mannan (glucomannan), guar gum, pectin, carrageenan, tamarind seed gum, gum arabic, soybean polysaccharide, locust bean gum, karaya gum, xanthan gum, agar, starch, corn starch, and the like can be used as the second binder, but polysaccharides other than cellulose are preferred. Regarding viscosity, mixing with the non-tobacco plant is favorable when the solution viscosity is 300 mPa·s or greater, as in the case of the first binder. A solution viscosity of 5000 mPa-s or greater is appropriate for binding of a non-tobacco plant. This viscosity is also measured by the method (device) described above. Here, although the upper limit of measurement by the Brookfield viscometer is 100,000 mPa·s, a viscosity exceeding this upper limit is within the viscosity range described above.
A polysaccharide is preferred for use as the second binder. Among polysaccharides, a polysaccharide that is water soluble or that includes water and swells or forms a gel is particularly preferred for use. Through use of such a polysaccharide, the molded aroma-generating base material to be heated maintains an aggregated state, molding workability thereof is increased, and the occurrence of sheet breakage, dislodgement of the non-tobacco material, and other problems in the sheet molding step (means) H1 is reduced. Glucomannan, guar gum, pectin, carrageenan, locust bean gum, and agar are cited as examples of such a polysaccharide. When these polysaccharides are added for use, the solution viscosity thereof is preferably increased so as to be greater than the solution viscosity of the first binder. Use of the binder in this manner further enhances the suitability thereof in the sheet molding step (means) H1. Among the above polysaccharides, glucomannan is most preferred.
It is sometimes preferred to adopt a production method (device) in which the second wet mixing step (means) M2 is also configured so that menthol, peppermint, cocoa, coffee, black tea essence, or another flavoring agent, crosslinked PVP or β-cyclodextrin having a function for causing temporary residence of the flavoring agent, microcrystalline cellulose having moldability and ease of release from a die or the like, sorbic acid, potassium sorbate, benzoic acid, sodium benzoate, or another food antimicrobial preservative for storage stability, or the like is prepared in the same manner as in step (means) Z5 and added as needed.
An ordinary wet mixer can also be used when materials prepared as described above are mixed in the second wet mixing step (means) M2, the same as in the first wet mixing step (means) M1. For example, the mixer may be a mixer in which materials in a mixing tank are mixed while a shear force is applied thereto by an impeller, and it is also possible to knead and further intensify mixing using a roll mill, a kneader, or an extruder. The mixing temperature in this step (means) is preferably 40° C. or lower, and more preferably 30° C. or lower, and maintaining the temperature at about 25° C. is even more preferred. The reason for this is that there is a risk of dissipation of fragrance components when excessive heat is applied during mixing. The temperature of the mixing tank must therefore be controlled.
The composition for an aroma-generating base material to be heated including a non-tobacco material produced in the second wet mixing M2 is then inputted to the sheet molding step (means) H1 and molded to the desired form. In order for the composition to be used as an aroma-generating base material to be heated, roll molding, press molding, or another sheet molding process is preferably applied thereto, but these processes are not limiting. A method (device) whereby the composition is passed through an orifice and molded by compression, or a method (device) whereby the composition is dried and then pulverized into granular form may be employed.
Sheet molding that is suitable for producing the aroma-generating base material to be heated is described below. In one method (device), a sheet is molded using a three-roll mill. When a three-roll mill is used, while kneading, dispersion, and the like are performed by a compression force from pressing between close rolls and a shear force from the roll speed difference, the desired sheet thickness can be obtained using a doctor blade, and a three-roll mill is particularly preferred for molding a sheet of the composition of the present invention, in which various materials having different properties are mixed. A press roller or press machine may also be jointly used in fabricating a sheet. The three-roll mill works the composition into a sheet shape while kneading and dispersing the composition, and therefore complements the first and second wet mixing steps, and a more preferred state of mixing and dispersion can be obtained. Consequently, when a three-roll mill is used in the second wet mixing step (means) M2, this means that there is no device distinction between the second wet mixing step (means) M2 and the sheet molding step (means) H1, and mixing and molding are performed in the same process.
Mixing and dispersion can thus be performed in sheet molding which uses a three-roll mill, and it is therefore possible to configure the production method (device) so that a non-tobacco material, an aerosol former, a binder or thickener, a perfume, crosslinked PVP, β-cyclodextrin, microcrystalline cellulose, an antimicrobial preservative, pure water, or the like is also added as needed.
In order to clarify the feature wherein a first binder and a second binder such as are described above are dividedly added in the method (device) for producing an aroma-generating base material to be heated, the method (device) was evaluated in comparison with the conventional production method (device) using the same materials across both methods and limiting the form of the aroma-generating base material to be heated to a filler. The evaluation is described using Production Examples and working examples of the present invention.
The materials below were agitation-mixed, and a xylitol/aqueous solution was obtained.
Black tea leaves dried at 70° C., pulverized, and passed through an 80 mesh sieve were used. The moisture content thereof was 2% by mass. A dried jiaogulan product pulverized and passed through an 80 mesh sieve was likewise used.
The above materials were loaded into a mixer and mixed for 15 minutes (first wet mixing step (means) M1), and a first mixture was obtained.
The resultant first mixture was inputted to the second wet mixing step (means) M2. While 100 parts by mass of the first mixture was loaded in a three-roll mill, 0.5 part by mass of glucomannan and 20 parts by mass of water were added. A step (means) for collecting a sheet-shaped product by pressing a doctor blade against a roll was repeated 8 times. In this step (means), the second wet mixing step (means) M2 and the sheet molding step (means) H1 are performed by the same device, in which the first half of mixing can be regarded as the second mixing step (means) M2, and the second half of mixing can be regarded as the sheet molding step (means) H1. A sheet having the desired thickness was produced while kneading and dispersion were accomplished at the same time in the three-roll mill.
The aroma-generating sheet to be heated which was produced by these steps (means) was molded so as to have a thickness of 0.3 mm. The sheet was cut into a rectangle 150 mm in length×240 mm in width, which was supplied to a rotary cutter and processed to a shape having a width of 1.5 mm, a length of 240 mm, and a thickness of 0.3 mm, and an aroma-generating filler to be heated was obtained. Fifty units of the filler were bundled and arranged lengthwise, and paper having a basis weight of 34 g/m2 was wound thereon and sized to produce a cylindrical aroma-generating processing object to be heated. The inside diameter of the processing object was 6.9 mm. The processing object was furthermore cut to a length of 12.0 mm to form an aroma generator to be heated. The mass of the aroma generator to be heated was 0.29 g, and the volume filling ratio of the filler with respect to the volume of the aroma generator to be heated was 0.60. The longitudinal direction of the rectangle into which the aroma-generating sheet to be heated was cut was parallel to the rotational axis of the roll, and the transverse direction thereof was the rotation direction of the roll (the same hereinbelow).
The aqueous solution viscosity of the sodium carboxymethyl cellulose used in the present Production Example was 650 mPa·s (Brookfield viscometer, 1% aqueous solution, 25° C.), and the aqueous solution viscosity of the glucomannan polysaccharide was 44000 mPa-s (Brookfield viscometer, 1% aqueous solution, 25° C.).
Until the first wet mixing step (means) M1, a first mixture was produced in the same manner as in (Production Example A). The first mixture was sealed in a polyethylene bag and aged for 6 days (144 hours) at a temperature of 20° C. to produce an aged mixture. The apparent volume after the aging step (means) Y1 was approximately 1.5 times larger. When a second aged mixture was confirmed after the aging step (means) Y1, separation of brown pulverized material appeared to have decreased relative to before aging, and the aging was considered to have led to a stable and uniform dispersion state. The mixture produced by the aging step (means) Y1 was inputted to the second wet mixing step (means) M2, and an aroma generator to be heated was produced.
In the same manner as in (Production Example B), an aged mixture was inputted to the second wet mixing step (means) M2, and an aroma-generating sheet to be heated was fabricated by the sheet molding step (means) H1. However, in the present Production Example, processing conditions in the second wet mixing step (means) and the sheet molding step (means) H1 were changed, and an aroma-generating sheet to be heated was fabricated by molding so that the thickness thereof was 0.1 mm. The sheet was cut into a rectangle 150 mm in length×240 mm in width, which was supplied to a rotary cutter and processed to a shape having a width of 1.0 mm, a length of 240 mm, and a thickness of 0.1 mm, and an aroma-generating filler to be heated was obtained. Two hundred twenty five units of the filler were bundled and arranged lengthwise, and paper having a basis weight of 34 g/m2 was wound thereon and sized to produce a cylindrical aroma-generating processing object to be heated. The inside diameter of the processing object was 6.9 mm. The processing object was furthermore cut to a length of 12.0 mm to form an aroma generator to be heated. The mass of the aroma generator to be heated was 0.29 g, and the volume filling ratio of the filler with respect to the volume of the aroma generator to be heated was 0.60.
In the same manner as in (Production Example B), an aged mixture was inputted to the second wet mixing step (means) M2, and an aroma-generating sheet to be heated was fabricated by the sheet molding step (means) H1. However, in the present Production Example, processing conditions in the second wet mixing step (means) and the sheet molding step (means) H1 were changed, and an aroma-generating sheet to be heated was fabricated by molding so that the thickness thereof was 0.5 mm. The aroma-generating sheet to be heated was cut into a rectangle 150 mm in length×240 mm in width, which was supplied to a rotary cutter and processed to a shape having a width of 1.0 mm, a length of 240 mm, and a thickness of 0.5 mm, and an aroma-generating filler to be heated was obtained. Two hundred twenty five units of the filler were bundled and arranged lengthwise, and paper having a basis weight of 34 g/m2 was wound thereon and sized to produce a cylindrical aroma-generating processing object to be heated. The inside diameter of the processing object was 6.9 mm. The processing object was furthermore cut to a length of 12.0 mm to form an aroma generator to be heated. The mass of the aroma generator to be heated was 0.29 g, and the volume filling ratio of the filler with respect to the volume of the aroma generator to be heated was 0.60.
An aroma generator to be heated was fabricated for comparison, in which methyl cellulose and carboxymethyl cellulose as first binders and glucomannan as a second binder were added en bloc.
The materials below were agitation-mixed, and a xylitol/aqueous solution was obtained.
Black tea leaves dried at 70° C., pulverized, and passed through an 80 mesh sieve were used. The moisture content thereof was 2% by mass. A dried jiaogulan product pulverized and passed through an 80 mesh sieve was likewise used.
The above materials were loaded into a mixer and mixed for 15 minutes, and a mixture including glucomannan and all the other materials above was obtained.
The mixture produced as described above was mixed in a three-roll mill, and an aroma-generating sheet to be heated having a thickness of 0.3 mm was fabricated while a step (means) for collecting a sheet-shaped product by pressing a doctor blade against a roll was repeated 8 times to accomplish kneading and dispersion of the mixture at the same time. There was difficulty in forming a sheet during molding using the three-roll mill. Although a sheet was formed, measurement thereof according to Evaluation A was not possible.
The resultant aroma-generating sheet to be heated was cut into a rectangle 150 mm in length×240 mm in width, which was supplied to a rotary cutter and processed to a shape having a width of 1.5 mm, a length of 240 mm, and a thickness of 0.3 mm, and an aroma-generating filler to be heated was obtained. Fifty units of the filler were bundled and arranged lengthwise, and paper having a basis weight of 34 g/m2 was wound thereon and sized to produce a cylindrical aroma-generating processing object to be heated. The inside diameter of the processing object was 6.9 mm. The processing object was furthermore cut to a length of 12.0 mm to form an aroma generator to be heated. The mass of the aroma generator to be heated was 0.29 g, and the volume filling ratio of the filler with respect to the volume of the aroma generator to be heated was 0.60.
Using the aroma generator to be heated that was fabricated in (Production Example A), an aroma cartridge of the type illustrated in
An aroma cartridge was fabricated in the same manner as in (Example A), except that the aroma generator to be heated that was fabricated in (Production Example B) was used.
An aroma cartridge was fabricated in the same manner as in (Example A), except that the aroma generator to be heated that was fabricated in (Production Example C) was used.
An aroma cartridge was fabricated in the same manner as in (Example A), except that the aroma generator to be heated that was fabricated in (Production Example D) was used.
An aroma cartridge was fabricated in the same manner as in (Example A), except that the aroma generator to be heated that was fabricated in (Comparative Production Example) was used. However, in fabrication of the aroma cartridge, the aroma-generating filler to be heated was too soft, and fabrication was difficult.
The evaluations described below were performed for the aroma-generating sheets to be heated and the aroma cartridges fabricated as described above. <<Evaluation 1>> was also performed in addition to the evaluations below.
<<Evaluation A>>
A tensile strength of the aroma-generating sheet to be heated was tested. A commonly used tensile strength tester was used for tensile strength testing. A sample having a width of 10.0 cm and a length of 22.0 cm cut from the aroma-generating sheet to be heated was used as a sample, and tensile strength was measured at a cross head speed of 10 cm/min and a distance of 20.0 cm between clamps of the tensile tester. The testing environment was a room temperature of 20° C. and a humidity of 50%. An aroma-generating sheet to be heated fabricated by each production method (device) was evaluated by comparing a breaking strength thereof, and it was learned that a breaking strength of 3.9 N/mm2 or greater, preferably 5.0 N/mm2 or greater, was preferred comprehensively in terms of such characteristics as molding, aroma cartridge fabrication, initial aspiration quantity, initial flavor, and change over time in aspiration quantity and flavor.
The heating-type smoking appliance used was an IQOS (registered trademark) heating-type electronic tobacco device, produced by Philip Morris, of the type illustrated in
<<Evaluation C>>
Dislodgement of smoked filler was evaluated. The evaluation method (device) comprises directing the aroma-generator-to-be-heated side of the smoked aroma cartridge vertically downward and observing whether the aroma-generating filler to be heated falls out. The evaluation criteria are as described below.
Rank A: No falling material observed.
Rank B: Part of the filler falls out.
Test results are shown in Table 1. As is clear from Table 1, divided addition of binders is recognized as having an effect on each of molding, aroma cartridge fabrication, initial aspiration quantity and flavor, change in aspiration quantity and flavor over time, and fusion over time of the aroma-generating filler to be heated, and this effect can be further increased by aging. Consequently, it is obvious that the aroma-generating base material to be heated in which binders are dividedly added, as well as the aroma-generating base material to be heated in which an aging step (means) is applied in the fabrication thereof, function as gas-generation-maintaining materials in the aroma cartridge.
Based on the above, it was recognized that the production method (device) has an effect on the internal structure of the aroma-generating base material to be heated, and that the aroma-generating base material to be heated fabricated by the appropriate production method (device) functions as a gas-generation-maintaining material for the aroma cartridge that is fabricated using the aroma-generating base material to be heated. In the present invention, another material that functions as a gas-generation-maintaining material was discovered. This material consists of inorganic particles.
The effect of the inorganic particles will be described in specific examples. (Production Example 1) was employed as the conventionally used production method (device), and the effect of various inorganic particles on the gas generation maintenance ability of the aroma-generating base material to be heated, which was fabricated by this production method (device), was evaluated as described below.
An aroma generator to be heated was fabricated and an aroma cartridge was assembled in accordance with (Production Example 1), but in the present example, after the aroma-generating sheet to be heated which was fabricated in (Production Example 1) was cut to a length of 12 mm and a width of 1.5 mm (and a thickness of 0.5 mm) to fabricate an aroma-generating filler to be heated, a step (means) for adding predetermined amounts of various inorganic particles and spraying and coating with the inorganic particles so as to evenly adhere the inorganic particles to the surface of the aroma-generating filler to be heated was added, as indicated by the spraying step (means) H2 in
<<Evaluation 2>>
The evaluation described below was performed after confirming the presence of fouling adhering to the heating element 113 after use of the aroma cartridge in the manner illustrated in
Calcium carbonate powder having an average particle diameter of 15 μm, in the amount of 1 part by mass with respect to 100 parts by mass of an aroma-generating filler to be heated which was cut as described above from the aroma-generating sheet to be heated fabricated in (Production Example 1), was sprayed so as to adhere to the entire surface of the aroma-generating filler to be heated, and said entire surface was coated with the calcium carbonate powder. After confirming by microscopy that calcium carbonate particles having a diameter of 10-50 μm were adhering to the aroma-generating filler to be heated, an aroma generator to be heated was fabricated using 0.29 g of the aroma-generating filler to be heated having calcium carbonate particles on the surface thereof. An aroma cartridge was assembled from a mouthpiece and the aroma generator to be heated. The measured filling ratio of the filler in this case was 81%.
Magnesium carbonate powder having an average particle diameter of 10 μm, in the amount of 1 part by mass with respect to 100 parts by mass of an aroma-generating filler to be heated which was cut as described above from the aroma-generating sheet to be heated fabricated in (Production Example 1), was sprayed so as to adhere to the entire surface of the aroma-generating filler to be heated, and said entire surface was coated with the calcium carbonate powder. After confirming by microscopy that magnesium carbonate particles having a diameter of 10-50 μm were adhering to the aroma-generating filler to be heated, an aroma generator to be heated was fabricated using 0.29 g of the aroma-generating filler to be heated having magnesium carbonate particles on the surface thereof. An aroma cartridge was assembled from a mouthpiece and the aroma generator to be heated. The measured filling ratio of the filler in this case was 80%.
Silicon oxide powder having an average particle diameter of 20 μm, in the amount of 1 part by mass with respect to 100 parts by mass of an aroma-generating filler to be heated which was cut as described above from the aroma-generating sheet to be heated fabricated in (Production Example 1), was sprayed so as to adhere to the entire surface of the aroma-generating filler to be heated, and said entire surface was coated with the silicon oxide powder. After confirming by microscopy that silicon oxide particles having a diameter of 10-50 μm were adhering to the aroma-generating filler to be heated, an aroma generator to be heated was fabricated using 0.29 g of the aroma-generating filler to be heated having silicon oxide particles on the surface thereof. An aroma cartridge was assembled from a mouthpiece and the aroma generator to be heated. The measured filling ratio of the filler in this case was 80%.
Alumina particles having an average particle diameter of 5 μm, in the amount of 1 part by mass with respect to 100 parts by mass of an aroma-generating filler to be heated which was cut as described above from the aroma-generating sheet to be heated fabricated in (Production Example 1), were sprayed so as to adhere to the entire surface of the aroma-generating filler to be heated, and said entire surface was coated with the alumina particles. After confirming by microscopy that alumina particles having a diameter of 10-50 μm were adhering to the aroma-generating filler to be heated, an aroma generator to be heated was fabricated using 0.29 g of the aroma-generating filler to be heated having alumina particles on the surface thereof. An aroma cartridge was assembled from a mouthpiece and the aroma generator to be heated. The measured filling ratio of the filler in this case was 81%.
Alumina particles having an average particle diameter of 2 μm, in the amount of 1 part by mass with respect to 100 parts by mass of an aroma-generating filler to be heated which was cut as described above from the aroma-generating sheet to be heated fabricated in (Production Example 1), were sprayed so as to adhere to the entire surface of the aroma-generating filler to be heated, and said entire surface was coated with the alumina particles. Although it could not be confirmed by microscopy in this case that alumina particles having a diameter of 10-50 μm were adhering to the aroma-generating filler to be heated, an aroma generator to be heated was fabricated using 0.29 g of the aroma-generating filler to be heated which was coated with alumina particles. An aroma cartridge was assembled from a mouthpiece and the aroma generator to be heated. The measured filling ratio of the filler in this case was 81%.
Silicon oxide particles having an average particle diameter of 0.5 μm, in the amount of 1 part by mass with respect to 100 parts by mass of an aroma-generating filler to be heated which was cut as described above from the aroma-generating sheet to be heated fabricated in (Production Example 1), were sprayed so as to adhere to the entire surface of the aroma-generating filler to be heated, and said entire surface was coated with the silicon oxide particles. Although it could also not be confirmed by microscopy in this case that silicon oxide particles having a diameter of 10-50 μm were adhering to the aroma-generating filler to be heated, an aroma generator to be heated was fabricated using 0.29 g of the aroma-generating filler to be heated which was coated with silicon oxide particles. An aroma cartridge was assembled from a mouthpiece and the aroma generator to be heated. The measured filling ratio of the filler in this case was 81′.
Silicon oxide particles having an average particle diameter of 47 μm, in the amount of 1 part by mass with respect to 100 parts by mass of an aroma-generating filler to be heated which was cut as described above from the aroma-generating sheet to be heated fabricated in (Production Example 1), were sprayed so as to adhere to the entire surface of the aroma-generating filler to be heated, and said entire surface was coated with the silicon oxide particles. After confirming by microscopy that silicon oxide particles having a diameter of 10-50 μm were adhering to the aroma-generating filler to be heated, an aroma generator to be heated was fabricated using 0.29 g of the aroma-generating filler to be heated which was coated with silicon oxide particles. An aroma cartridge was assembled from a mouthpiece and the aroma generator to be heated. The measured filling ratio of the filler in this case was 65%.
An aroma generator to be heated was fabricated using, without modification thereof, 0.29 g of the aroma-generating filler to be heated which was cut as described above from the aroma-generating sheet to be heated fabricated in (Production Example 1). An aroma cartridge was assembled from a mouthpiece and the aroma generator to be heated. The measured filling ratio of the filler in this case was 81%.
Results of the evaluations described above are shown in Table 2. As is clear from Table 2, inorganic particles having a wide range of particle diameters function as gas-generation-maintaining materials, regardless of the material properties thereof. As is clear from the results of <<Evaluation 1>>, there was no fusion over time of the aroma-generating filler to be heated, and there was little change over time in the released quantity of gas, i.e., in both gas aspiration quantity and flavor. The reason for such a result is not known for certain, but may be as follows. It is possible that when inorganic particles are present on the surface of the filler, the inorganic particles act as spacers to reduce the contact area between fillers, and have the effect of inhibiting fusion of the fillers due to bleed-out of the aerosol former even when placed in a high-temperature state for a long time, and the inorganic particles have such effects as suppressing bleed-out of the aerosol former.
As is clear from <<Evaluation 2>>, the inorganic particles also have the effects of preventing contamination of the heating element. In particular, a good effect is obtained when the average particle diameter of an added inorganic powder is 1-50 μm, and prevention of contamination is further increased when the average particle diameter is 5 μm or greater. A good effect is obtained when the added quantity an added inorganic powder is 0.01-5 parts by mass, and prevention of contamination is further increased when the added quantity is 0.1 part by mass or greater. The reason that the inorganic particles have the effect of preventing contamination of the heating element is not known for certain, but such reasons as the following can be conjectured. An inorganic material is not readily decomposed by heating, the inorganic particles polish the surface of the heating element and remove contaminating matter when the aroma cartridge is installed on and removed from the heating element, and the inorganic particles reduce the area of contact between the heating element surface and the aroma-generating filler to be heated.
In order to obtain the above results, the inorganic particles preferably have an average particle diameter of 1-100 μm. The effect of the inorganic particles decreases when the average particle diameter thereof is less than 1 μm. An average particle diameter of 5 μm or greater is preferred, because the effect of the inorganic particles is thereby increased. For the same reason, an average particle diameter of 10 μm or greater is more preferred. The filling ratio of the filler decreases the larger the average particle diameter is, but when the average particle diameter is 50 μm or less, the inorganic particles have a large effect, and the minimum necessary filling ratio can be ensured.
The minimum necessary filling ratio herein is closely related to the aspiration quantity of gas generated by heating. When the filling ratio is less than 60%, an adequate quantity of gas is not released by heating, the quantity of gas aspirated by the smoker is inadequate, and the sensation of inhalation is unsatisfactory. Consequently, the necessary filling ratio is more preferably 65% or greater, and even more preferably 70% or greater. Conversely, when the filling ratio exceeds 90%, problems arise in that gaps between fillers are decreased, smoking is difficult, and insertion on the heating element also becomes difficult.
This filling ratio can be evaluated by a method for calculating the area ratio of the aroma-generating base material to be heated with respect to a cross section of the aroma generator to be heated. The filling ratio was determined by evaluating a filler and a gap portion including no filler, using a digital microscope. An image was projected on a display at a magnification of 100 using a digital microscope (VHX-2000, produced by KEYENCE CORPORATION). A range of the image to be analyzed was set to a region in which only the filler and the gap portion including no filler appeared. In this case, for an observation sample having a diameter of 7.0 mm, the range was set to 3.5 mm horizontally and 2.6 mm vertically. For image analysis in the range described above, an “extraction mode” was set to “luminance” in an “automatic measurement mode” using included software. In measurement, “standard” was selected, an “extraction parameter” was set to “bright,” and a “threshold value” was selected so that the observed filler and gap were separated. The filling ratio was determined as the ratio of the entire measurement region that was occupied by the filler.
The average particle diameter of the inorganic particles in the present invention was determined by a wet method using a laser diffraction/scattering-type particle diameter distribution measuring device. In the present invention, a Microtrac MT3300III produced by MICROTRACBEL CORPORATION was used. The average particle diameter in the present invention indicates the median diameter D50 at 50% of a volume-based distribution accumulated for a range of 0.02 μm to 2000 μm.
The presence of inorganic particles in the present invention was confirmed not only by microscope observation in the producing steps (means), but also by observation of the filler surface using an optical microscope or an electron microscope. The presence of inorganic particles was also confirmed by microscope or electron microscope observation of residue from thermal decomposition of the filler, from results of about 10 observations in a visual field of 100 μm×100 μm at an appropriate magnification. Confirmation that inorganic particles in a residue were the added inorganic particles was obtained using a scanning electron microscope capable of X-ray microanalysis (XMA).
The added quantity of inorganic particles must be at least 0.001 part by mass with respect to 100 parts by mass of the filler in order for the effect of the inorganic particles to manifest, and is more preferably 0.01 part by mass or greater, and even more preferably 0.05 part by mass or greater. Conversely, when the added quantity exceeds 10 parts by mass with respect to 100 parts by mass of the filler, the filling ratio of the filler decreases, which affects gas aspiration quantity or flavor. From this perspective, an added quantity of 5 parts by mass or less is more preferred, and an added quantity of 2 parts by mass or less is even more preferred.
Inorganic substances that can be used as the inorganic particles of the present invention are not particularly limited, but sodium chloride, potassium chloride, and other metal chlorides, magnesium oxide, calcium oxide, titanium oxide, iron oxide, alumina, and other metal oxides, magnesium carbonate, calcium carbonate, and other metal carbonates, magnesium sulfate, calcium sulfate, and other metal sulfates, calcium phosphate and other metal phosphates, and potassium titanate, magnesium titanate, and other titanates can be used singly, or two or more of the above substances can be selected for use. Zeolite, colloidal silica, fumed silica, and other silicon oxides, and natural materials such as diatomaceous earth and vermiculite can also be used. Magnesium carbonate, calcium carbonate, silicon oxide, and alumina are particularly preferred.
The inorganic particles can be attached to the aroma-generating base material to be heated in the spraying step (means) H2 in
Through the present invention described above, by improving a production method (device), it is possible to provide an aroma generator to be heated in which an aroma-generating base material to be heated functions as a gas-generation-maintaining material, and an aroma generator to be heated in which inorganic particles function as a gas-generation-maintaining material. Consequently, it is also possible to provide an aroma cartridge in which there is no need to provide a gas aspiration optimization means to a mouthpiece, as illustrated in
The present invention can provide an aroma cartridge of tobacco of genus Nicotiana of the family Solanaceae and a plant of the same genus, and of a harmless aroma which is derived from a plant or the like not including a tobacco component, whereby smoking can be enjoyed with a cigarette sensation not only by an experienced flame-type smoker but also by a first-time smoker. The present invention is therefore a novel smoking appliance whereby smoking that is devoid of adverse health effects on the smoker as well as on surrounding non-smokers can be enjoyed, and which induces a waves in the brain, has a soothing effect, and helps to promote health and beauty. The aroma cartridge of the present invention is also provided with a gas aspiration optimization means and a gas-generation-maintaining material, and therefore has the feature that no change in flavor or aspiration quantity of smoke and a fragrance component occurs even when the aroma cartridge is stored for a long time. Consequently, technology relating to the aroma cartridge of the present invention has broad applicability in incense sticks, incense burning, incense powder, rubbing incense, and the like, or in aromatherapy and the like.
| Number | Date | Country | Kind |
|---|---|---|---|
| 2018-095473 | May 2018 | JP | national |
| 2018-095478 | May 2018 | JP | national |
| Filing Document | Filing Date | Country | Kind |
|---|---|---|---|
| PCT/JP2019/017530 | 4/24/2019 | WO | 00 |
