Claims
- 1. A process for producing aromatic hydrocarbons, said process comprising contacting a feedstock comprising one or more non-aromatic compounds selected from the group consisting of C.sub.2 -C.sub.12 alkanes and C.sub.2 -C.sub.12 alkenes with a catalyst comprising a crystalline zeolite material having the structure of ZSM-5 or ZSM-11, said contacting taking place under aromatization conditions including a temperature of from about 200.degree. C. to about 700.degree. C., a pressure of from about 0.1 atmosphere to about 60 atmospheres, a weight hourly space velocity (WHSV) of from about 0.1 to about 400 and a hydrogen/hydrocarbon mole ratio of from about 0 to about 20, said catalyst further comprising an oxide of phosphorus which has been incorporated into said catalyst by a process comprising the steps of:
- (i) impregnating said zeolite with a source of phosphate ions; and
- (ii) calcining the impregnated zeolite of step (i) at a temperature of at least 649.degree. C. under conditions sufficient to convert said impregnated phosphate ions to said oxide of phosphorus.
- 2. According to claim 1, wherein said source of phosphate ions is an aqueous solution of an ammonium phosphate.
- 3. A process according to claim 2, wherein said ammonium phosphate is selected from the group consisting of (NH.sub.4).sub.2 HPO.sub.4 and NH.sub.4 H.sub.2 PO.sub.4.
- 4. A process according to claim 3, wherein essentially all of the cationic exchange sites of said zeolites are occupied by ammonium ions prior to and during the impregnation of said zeolite with said ammonium phosphate.
- 5. A process according to claim 1, wherein said zeolite material is an aluminosilicate zeolite having a silica/alumina mole ratio of at least 12.
- 6. A process according to claim 2, wherein said zeolitc material has the structure of ZSM-5.
- 7. A process according to claim 1 wherein said catalyst further comprises a binder.
- 8. A process according to claim 1, wherein said feedstock comprises from about 1 to about 30 weight percent of ethylehe, from about 1 to about 30 weight percent of propylene and from about 1 to about 30 weight percent of propane.
- 9. A process according to claim 1, wherein said feedstock comprises a refinery off gas.
- 10. A process according to claim 1, wherein said feedstock comprises ethylene, propane or propylene.
CROSS-REFERENCE TO RELATED APPLICATION
This application is a continuation-in-part of copending U.S. application Ser. No. 744,072, filed June 12, 1985, now U.S. Pat. No. 4,590,321, the entire disclosure of which is expressly incorporated herein by reference.
US Referenced Citations (21)
Continuation in Parts (1)
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Number |
Date |
Country |
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744072 |
Jun 1985 |
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