This application claims foreign priority benefits under 35 U.S.C. §119(a)-(d) to EP 10188558.0, filed Oct. 22, 2010, the disclosure of which is hereby incorporated by reference in its entirety.
The present invention relates to an exhaust gas treatment arrangement and method, such as but not necessarily limited to an arrangement and method for treating exhaust gases flowing along a flow path in an exhaust pipe system.
Combustion engines in vehicles produces exhaust gases when running. The exhaust gases produced may comprise particles or elements which may be harmful to humans, animals and/or nature. Over the years, different attempts have been made to reduce the amount of these harmful particles or elements coming from the exhaust gases. It has been found that a catalytic converter arranged in an exhaust pipe system for treatment of the exhaust gases may result in a reduced level of nitrogen oxides, NOx. A further improved reduction of NOx in the exhaust gases has been achieved by mixing a reductant into the exhaust gases prior to treatment of the exhaust gases in the catalytic converter. An even further improvement has been achieved when a reductant of e.g. urea, being converted into an ammonia gas, was introduced into the exhaust pipe system and mixed with the flowing exhaust gases.
US 2007/0048204 A1 discloses a technique having urea introduced into an exhaust pipe system to reduce emission of NOx in the exhaust gases upon treatment in a catalytic converter. Prior to entering into the exhaust pipe system, the urea in US 2007/0048204 A1 is pressurized and heated. Upon entering into the exhaust pipe system containing exhaust gases, upstream the catalytic converter, the pressurized and heated urea is converted into ammonia gas. The conversion and mixing of the ammonia gas takes place in a mixing part of the exhaust pipe system upstream the catalytic converter. The mixing part has a length which is primarily dedicated to the mixing of the reductant into the exhaust gases. After the mixing, the mixture of ammonia gas and exhaust gases enters into the catalytic converter. Inside the catalytic converter the ammonia gas reacts with the exhaust gases in a chemical process resulting in a reduction of the level of NOx in the exhaust gases.
A drawback with prior art technology is that the length of the mixing part may determine, or affect, how well the reductant is mixed with the exhaust gases inside the exhaust pipe system, hence, how effective the system is in reducing the emission of NOx. If the mixing part is too short then a low conversion of NOx may be achieved. If the mixing part is too short then not enough of urea will be able to converse into ammonia gas. The length of the mixing part in the prior art solution has to satisfy two conflicting requirements:
a) to be sufficiently long in order for the ammonia gas to be converted and mixed into the exhaust gases prior to entering into the catalytic converter. Being in liquid phase, the urea that hasn't been converted into ammonia gas may have a low probability of being mixed with the exhaust gases, hence to reduce their NOx level.
b) to be as short as possible to reduce the total length of the exhaust gas system and simultaneously be sufficiently long in order to fulfill requirement a).
An object of the invention is to provide a compact exhaust pipe system whose length is not dependent on the mixing length required to mix a reductant with exhaust gases prior to the exhaust gases entering into a catalytic converter.
Another object of the invention is to provide an exhaust gas treatment arrangement where a reductant does not need to go through a process of phase change upon being introduced into the exhaust pipe system may be used.
Another object of the invention is to reduce, or ameliorate, at least some of the drawbacks in known technology, or to provide useful alternatives thereto.
This and other objects are achieved by the exhaust gas treatment arrangement contemplated by the present invention.
As such, the present invention relates to an exhaust gas treatment arrangement for treating exhaust gases flowing along a flow path in an exhaust pipe system. The arrangement comprises a supply element being in communication with a source comprising ammonia gas. The supply element comprises at least two discharge apertures being adapted to communicate with the flow path such that the ammonia gas is dispersible from the discharge apertures into the exhaust gases in the flow path in at least two discharge directions.
An exhaust pipe system with the arrangement of the present invention may be constructed comprising a short, reduced or almost eliminated mixing length. The shortened exhaust pipe system thus provides as an advantage that the exhaust pipe system may be made using less material. This reduced use of material may further have a positive impact of the production cost, which thus may be decreased. Another advantage caused by the reduced mixing length is that a higher temperature of the exhaust gases entering into the catalytic converter may be achieved. This because the flow path for the exhaust gases from the combustion engine to the catalytic converter is shortened. A high temperature of the exhaust gases is desirable as they enter into the catalytic converter. A high temperature of the exhaust gases has proven to improve the chemical reaction between the reductant and the exhaust gases in the catalytic converter, and thus to reduce the level of NOx in the exhaust gases.
Another advantage in accordance with the invention is that no mixing device has to be present in the flow path to achieve sufficient mixing between of the reductant into the exhaust gases. Another further advantage is that the mixing and distribution of the reductant into the flow path may be achieved without backpressure losses.
According to the present invention, the supply element may be adapted to be arranged on an outside of said exhaust pipe system. Being arranged on the outside allows the supply element to communicate with e.g. the source comprising the reductant. A flow of reductant from the source may then be provided to the flow path in the exhaust pipe system.
According to the present invention, the supply element may be adapted to be arranged within said exhaust pipe system. The arrangement within said exhaust pipe may be achieved by including an internal element of the supply element within said exhaust pipe for dispersing, e.g. spraying, the reductant directly into the flow path of exhaust gases.
According to the present invention, the supply element may be ring-shaped. The ring-shaped element may be uniformly arranged in the flow path having a substantially circular cross-section. The ring-shaped element may comprise discharge apertures which are uniformly and symmetrically arranged along the ring shaped element. The reductant is uniformly dispersed into the flow path via the uniformly and symmetrically arranged discharge apertures.
According to the present invention, the supply element may be adapted to extend across said flow path. Such extension may be achieved by including a tube element in the supply element. The tube element may extend symmetrically partly, or in full, across the flow path. The tube element may comprise discharge apertures which are uniformly and symmetrically arranged along the tube element crossing the flow path. The reductant is arranged to be uniformly dispersed into the flow path by the discharge apertures of the tube element.
According to the present invention, each discharge aperture may comprise an opening, a spray nozzle or a discharge head. The reductant may be arranged to enter into the flow path uniformly as a gas via the discharge apertures whereby a direct mix with the exhaust gases may be achieved. An effect of using spray nozzles is that the reductant may be dispersed as a stream in gas form, or e.g. as small droplets, inside the flow path. As such, the reductant entering may therefore mix directly with the exhaust gases in the flow path.
According to the present invention, the arrangement may further comprise a mixing unit for mixing air with the ammonia gas before said ammonia gas is dispersed into the exhaust gases. The air being mixed with the ammonia gas may e.g. be pressurized assistant gas which may consist of air or other equivalent alternatives to air. The ammonia gas adapted for being mixed into the exhaust gases is the reductant for the process. Assistant gas may be pressurized by e.g. a boost pressure, exhaust manifold pressure, compressor or other means and or methods. Boost pressure may be a preferred method as it in general is present in the vehicles. Boost pressure may therefore be non expensive and fairly easy to adapt for pressurizing the assistant gas. The volume of the reductant to be used for dispersing into the exhaust gases may be increased by mixing air, e.g. assistant gas, into the ammonia gas prior to entry into the exhaust gases. The mixing effect is improved when a large volume of reductant is introduced into the exhaust gases. The mixing may further results in an improved distribution of the ammonia gas with and against the substrates of the catalytic converter. A low volume of reductant having a high concentration of ammonia gas being mixed into the exhaust gases may result in poor mixing compared to a large volume of reductant having a lower concentration of ammonia gas introduced into the exhaust gases. The reductant may be introduced into the flow path under high pressure.
A second aspect of the present invention relates to an exhaust pipe system comprising an exhaust pipe and an exhaust gas treatment arrangement according to the first aspect of the present invention. A supply element may lead ammonia gas into the exhaust gases in the flow path via at least one gas inlet through a wall element in the exhaust pipe system.
According to the second aspect of the present invention, the system may comprise a catalytic converter having a first substrate and a second substrate arranged in the exhaust gas flow path between an inlet and an outlet of said catalytic converter. The second substrate is arranged upstream of said first substrate, and the discharge apertures are arranged in the flow path between said first substrate and second substrate. A partial first cleaning of the exhaust gases may take place at the second substrate when the exhaust gases enter into the catalytic converter. After having passed through the second substrate the exhaust gases may enter into a space arranged in the flow path after the second substrate and before the first substrate. The reductant may be introduced and mixed into the exhaust gases flowing through the flow path in such a space. The mixture of exhaust gases and reductant continues from the space into the first substrate. In the first substrate the mixture of exhaust gases and reductant reacts with the surface of the first substrate resulting in a reduction of the NOx in the exhaust gases.
The reductant in gas form, e.g. ammonia gas, may be introduced or dispersed directly into the exhaust pipe system. This has the effect that the mixing length, where the reductant may be conversed from a liquid phase into a gaseous phase, therefore will be superfluous. The shortening of the mixing length results in to a reduction of the total distance between the combustion engine and the catalytic converter. Such a reduction of the length of the exhaust gas flow before entering the catalytic converter results in an increased temperature of the exhaust gases. A high temperature of the exhaust gases inside the catalytic converter has a positive impact on the catalytic effect of the catalytic converter.
According to the second aspect of the present invention, the discharge apertures may, with respect to each other seen in a cross-section of the flow path, be arranged symmetrically in the flow path. By spraying or introducing the reductant into the exhaust gases from the cross sectionally symmetrically arranged discharge apertures a uniform mixture between the exhaust gases and reductant may be achieved.
According to the second aspect of the present invention, the catalytic converter may comprise a Selective Catalytic Reduction (SCR) catalytic converter or a SCR coated substrate. Further, the catalytic converter may also comprise a particulate filter or another substrate which comprises a SCR coating. A SCR catalytic converter is a catalytic converter which is arranged for converting nitrogen oxides, also referred to as NOx, into water, H2O, and diatomic nitrogen, N2, by using a reductant which may be mixed with the exhaust gases.
A third aspect of the present invention relates to a method of treating exhaust gases flowing along a flow path in an exhaust pipe system. The method comprises the step of discharging an ammonia gas into said flow path from at least two discharge apertures in at least two discharge directions.
According to the third aspect of the present invention, the method comprises the step of discharging ammonia gas symmetrically in three discharge directions. This has the effect that a rapid and good mixture between the ammonia gas and the exhaust gas is achieved.
According to the third aspect of the present invention, the method comprises the step of discharging ammonia gas into said flow path upstream of a first substrate in a catalytic converter. This has the effect that the exhaust gases, which enter into the first substrate, comprises a mixture of reductant.
According to the third aspect of the present invention, the method comprises the step of mixing ammonia gas with air, e.g. pressurized assistant gas, prior to discharging ammonia gas into said flow path. A highly pressurized reductant gas may, upon entering into the exhaust flow path via small openings in the discharge aperture, generate a spray-like distribution of the reductant gas into the exhaust gases.
The present invention will hereinafter be explained in greater detail by means of non-limiting examples and with references and with reference to the appended drawings in which:
a illustrates, in a side view, a supply element having discharge apertures formed in a tube element which partly extends through a flow path;
b illustrates the supply element in accordance with
c illustrates the supply element in accordance with
It should be noted that the appended drawings are not necessarily drawn to scale and that the dimensions of some features of the present invention may have been exaggerated for the sake of clarity.
The invention will, in the following, be exemplified by embodiments. It is to be understood, however, that the embodiments are included in order to explain principles of the invention and not to limit the scope of the invention defined by the appended claims.
The exhaust pipe system (3) comprises the exhaust pipe (9) or catalytic converter (12).
The supply element (4) is adapted to be arranged on an outside of the exhaust pipe system (3). This because the supply element (4), or part of the supply element (4), is configured to either directly or indirectly connect with the source (5) which may be arranged outside the flow path (2). The source (5) may in the vehicle be arranged such that it may be filled, charged and/or loaded with the reductant. The source (5) may further in the vehicle be arranged such that the source (5) can be changed or replaced if being e.g. damaged. Therefore, the supply element (4) may be arranged on an outside of the flow path (2) and the supply element (4) may thereafter connect the source (5) directly or indirectly with the exhaust pipe system (3).
The supply element (4) is arranged with discharge apertures (6a, 6b, 6c), see
The arrangement (1) comprises a mixing unit (8) for mixing air with the ammonia gas before said ammonia gas is dispersed into the exhaust gases. The mixing unit (8) is arranged such that it comprises a connection communicating with the source (5). Further comprises the mixing unit (8) an air supply (18). The air supply (18) may be a unit providing air into the mixing unit (8). The reductant, e.g. the ammonia gas, is in the mixing unit (8) mixed with the air. The mixture of ammonia gas and air is then guided through the supply channel (4) towards the exhaust pipe system (3). The supply channel (4) is connected with the exhaust pipe system (3) via a gas inlet (10). The gas inlet (10) may be arranged against a wall element (11) of the exhaust pipe system (3). The reductant may through said gas inlet (10) be directly lead or streamed into the flow path (2), e.g. as a mist. The wall element (11) may be a part of a surface of the exhaust pipe (9) being part of the exhaust pipe system (3). The wall element (11) may also be a part of a surface of a casing or shell of the catalytic converter (12). The catalytic converter (12) may further be part of the exhaust pipe system (3). The exhaust pipe (9) is in the exhaust pipe system (3) arranged between the catalytic converter (12) and the engine of the vehicle.
The catalytic converter (12) may comprise a first substrate (13). The catalytic converter (12) may further comprise a second substrate (14). A substrate in a catalytic converter is a block being e.g. monolith and made of e.g. ceramic or stainless steel. The block may be covered with e.g. a precious metal. The precious metal may e.g. be platinum, palladium and/or rhodium. The block may comprise a structure of fine channels. These channels may have a surface which preferably may be fairly coarsed. A chemical reaction will occur when the exhaust gases mixed with the reductant comes into contact with the channels. The chemical reaction results in that the NOx in the exhaust gases thus may be reduced.
The catalytic converter (12) in accordance with the invention may comprise a diesel oxidated catalyst (DOC), diesel particulate filter (DPF), selective catalytic converter (SCR) or a SCR coated DPF. A SCR catalytic converter is a catalytic converter which is adapted for converting nitrogen oxides, also referred to as NOx, into water, H2O, diatomic nitrogen, N2, by using a reductant.
The first and the second substrate (13, 14) may in the catalytic converter (12) be arranged one block with a space (19) between the substrates (13, 14) or in separate catalytic converter blocks. If the wall element (11) in accordance with above is configured to be the wall element of the catalytic converter (12), then said gas inlet (10) may be arranged in the wall element (11) of the catalytic converter (12). The gas inlet (10) may then communicate with the space (19) inside the catalytic converter (12).
The catalytic converter (12) comprises an inlet (15) and an outlet (16). The inlet (15) is connected with the exhaust pipe (9) whereby the exhaust gases may enter into the catalytic converter (12). The substrates (13, 14) are arranged between said inlet and outlet in the flow path (2) extending through the catalytic converter (12). The second substrate (14) may be arranged upstream of the first substrate (13) in the flow path (2).
In the flow path (2) after the catalytic converter (12) is an exhaust box (17) arranged. The exhaust box (17) may also be referred to as a muffler. The exhaust box (17) may be connected with the catalytic converter (12) via a pipe member extending there between. The exhaust box (17) may be a part of the exhaust pipe system (3) whereby the flow path (2) therefore may be extending through said exhaust box (17). When the exhaust gases have passed through the exhaust box (17), the exhaust gases may via a passage (24) leave the exhaust pipe system (3). The passage (24) may be arranged in the exhaust box (17) as a hole or opening through which the exhaust gases may exit after have passed through the exhaust box (17). Alternatively, the passage (24) may be arranged at an end part of a conduit member being connected with the hole or opening of the exhaust box (17). The exhaust gases leaving the exhaust pipe system (3) via the outlet may have reduced its content of NOx due to the treatment achieved when flowing through the catalytic converter (12).
In accordance with
A discharge aperture (6a, 6b, 6c) may consist of a small hole or opening in the exhaust pipe (9) or in the catalytic converter. Via the small hole or opening may the reductant be introduced into the flow path and mixed with the exhaust gases therein.
The spray nozzles may be arranged with respect to each other in the flow path (2) such that the respective discharge direction (7a, 7b, 7c) or directions from each spray nozzle may be symmetrically directed with respect to each discharge direction (7a, 7b, 7c) of each spray nozzle.
In accordance with one embodiment as illustrated in
In accordance with the embodiment of
a and 7b illustrates an embodiment in accordance with the invention where the supply element (4) comprises a tube element (23). The tube element (23) in accordance with
b is a view in the flow path (2). The view of
c illustrates an alternative to the arrangements of the discharge apertures (6a, 6b, 6c) of
The embodiments in accordance with
In accordance with the alternative embodiments of
While there have been shown and described and pointed out fundamental novel features of the invention as applied to a preferred embodiment thereof, it will be understood that various omissions and substitutions and changes in the form and details of the devices illustrated, and in their operation, may be made by those skilled in the art. For example, it is expressly intended that all combinations of those elements and/or method steps which perform substantially the same function in substantially the same way to achieve the same results are within the scope of the invention. Moreover, it should be recognized that structures and/or elements and/or method steps shown and/or described in connection with any disclosed form or embodiment of the invention may be incorporated in any other disclosed or described or suggested form or embodiment as a general matter of design choice. It is the intention, therefore, to be limited only as indicated by the scope of the claims appended hereto.
Number | Date | Country | Kind |
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10188558.0 | Oct 2010 | EP | regional |