Arrangement to increase the thermal fatigue resistance of glass tubes flown through by fluid and pressure-loaded

Information

  • Patent Application
  • 20030221734
  • Publication Number
    20030221734
  • Date Filed
    February 10, 2003
    21 years ago
  • Date Published
    December 04, 2003
    20 years ago
Abstract
The invention relates to an arrangement (2; 2.2; 2.6; 2.7) to increase the thermal fatigue resistance of glass tubes (1; 1.2; 1.6; 1.7) flown through by fluid and pressure-loaded. This arrangement comprises a glass tube (1; 1.2; 1.6; 1.7), into which an interior component (3; 3.2; 3.6; 3.7) is inserted. The interior component (3; 3.2; 3.6; 3.7) can be designed as thin-walled tube (19; 19.2) or tubular component. In accordance with a first design example the cavity enclosed by the interior component (3; 3.2) is hydraulically connected with the interior (10) of the glass tube (1; 1.2). The wall thickness (s3) of the interior component (3; 3.2) is smaller than the wall thickness of the glass tube (1; 1.2) and the interior component (3; 3.2) is in the condition of being flown through by fluid at least partially free from a direct heat connection with the glass tube (1; 1.2). In accordance with a second design example the interior component (3.6; 3.7) increases the wall thickness of the glass tube (1.6; 1.7). In this case the interior component (3.6; 3.7) is touching the interior circumference of the glass tube.
Description


[0001] The invention relates to an arrangement to increase the thermal fatigue resistance of glass tubes flown through by fluid and pressure-loaded, in detail with the features of the generic term of the claims 1 and 13, furthermore the use of such an arrangement in a heat exchanger or an absorber tube for solar collectors.


[0002] Tubular components made from glass are frequently used to guide a flow medium in heat exchangers and absorber tubes of solar collectors. The thermal fatigue resistance presents thereby a substantial problem, whereby said thermal fatigue resistance can be described as a function of the type of glass, the geometrical design and the dimensioning. Glass tubes flown through by fluid must usually exhibit a minimum wall thickness due to the pressure prevailing in the interior. This leads to the fact that extreme temperature changes of the fluid flowing in the interior can lead to glass breaks due to the thermal conducting behavior of the tube wall and the associated stresses. In particular when filling an absorber tube made from glass in high-evacuated solar collectors, which is filled during downtime conditions with a cold heat transfer medium, temperature change of approx. 250 K can occur. This leads then to the fact that the inside of the glass tube cools down significantly, however a high difference between the interior circumference and the outer circumference of the glass tube can be observed due to the thermal conducting behavior in the wall of the glass tube. The ensuing unacceptable high temperature gradient in the wall of the glass tube usually causes a damage of the glass tube due to the associated stresses, which can often lead to a complete break. In order to solve this problem so far, essentially two solution courses were followed. In accordance with a first solution a fluid contact with the inner wall of the glass tube was avoided by a hydraulically separated fluid-containing tube, which was slid into the glass tube, whereby said separate tube was connected heat-conclusively to the glass tube by suitable dimensioning and/or additional heat-transferring measures. A substantial disadvantage of this design consisted in the associated higher costs as well as a poor heat transfer between the glass tube and the fluid, as the heat transfer could not take place directly, but took place first at the wall of the fluid-containing tube and then via convection in the gas contained in the gap and then again heat transfer took place from the wall of the glass tube to the inner wall of the glass tube respectively in reverse order with a cooled down flow medium.


[0003] In accordance with a second solution it was striven for the use of high-quality glasses, which already exhibit a sufficient thermal fatigue resistance. This solution is however characterized by substantially higher costs, whereby the availability of such materials must be ensured likewise. Furthermore it is not possible to use know standardized prefabricated simple glass tubes for certain standard applications, but only these special, high-quality tubes.


[0004] It is therefore the task of the invention, to develop an arrangement to increase the thermal fatigue resistance of glass tubes flown through by fluid and pressure-loaded, which is characterized by a low expenditure for design and production, causes low costs and which does not make special demands regarding the availability of the materials to be used. The manufacturing is to take place as easily as possible and the individual glass tube should be able to be integrated into this arrangement as easily as possible.


[0005] The solution according to the invention is characterized by the features of the claims 1 and 16. Favorable embodiments are described in the sub claims.


[0006] The arrangement to increase the thermal fatigue resistance of glass tubes flown through by fluid and pressure-loaded comprises a glass tube which can be flown through by fluid and can be pressure-loaded in this condition, into which a hollow cylindrical interior component is inserted according to the invention, which exhibits a smaller wall thickness than the glass tube and which is at least partially, preferably completely, free of a direct heat connection with the glass tube in the condition of the glass tube being flown through by fluid. I.e. that the interior component is circulated around by fluid on two sides—at the outer circumference and at the interior circumference. The flow takes place pressure-free with a completely coaxial arrangement of the interior component to the glass tube. Between the interior of the interior component and the remaining interior of the glass tube consists a hydraulic connection, i.e. no fluid guidance separate from the fluid guidance in the gap between outer circumference of the interior component and interior circumference of the glass tube takes place in the interior of the interior component, i.e. the area circumscribed by the interior circumference. Due to the associated heat transfer between the fluid and the interior component the cooling of the inner surface of the glass tube can be delayed, so that unacceptable temperature gradients at the wall of the glass tubes are avoided. The interior component exhibits a smaller wall thickness than the glass tube.


[0007] The hollow cylindrical interior component can be formed by a


[0008] 1) pipe-shaped component or


[0009] 2) a tubular component.


[0010] In the first case the interior component is formed by a thin-walled glass tube or plastic tube. In the second case the interior component can be designed flexible according to the material choice and the dimensioning in axial and/or radial direction. This offers the benefit that the solution according to the invention can be used with very high elasticity of the tubular interior component also very easily in curved longer tubes, whereby the expenditure for inserting the interior component is relatively low. In accordance with a particularly favorable embodiment thin-walled plastic tubes are preferably used as interior components for easy assembly. With these no additional consideration has to be given to the possible danger of fracture because of mechanical stress during assembly.


[0011] The interior component, independently of its arrangement as thin-walled glass tube or plastic tube or tubular component, can thereby be guided freely in the glass tube without guide device or however with guide device. In the arrangement without guide device the interior component is adjacent to the interior circumference of the glass tube in the condition of no fluid flowing through, while in the condition of fluid flowing through the position of the interior tube is localized in relation to the glass tube due to the flowing fluid. In the other case, the design with guide device, the guide device can either be designed as


[0012] a) one-piece with the glass tube


[0013] b) one-piece with the interior component


[0014] c) separate component.


[0015] The solution c) is preferably used, since no special accommodations at the components glass tube or interior component are to be made and therefore standardized components and/or prefabricated components can be used, which can be combined if necessary with an additional guide device. This guide device can be connected with the glass tube interlocking and positively actuated. The guide device is preferably located positively actuated in the glass tube, for example through clamping. The guide can furthermore be connected with the interior component interlocking and/or positively actuated. In order to avoid unnecessary stresses the connection between guide device and interior component is provided with a very large fit, so that only a crude position adjustment of the interior component in relation to the glass tube takes place. The main function of the guide device is thereby a position adjustment in the condition of no fluid flowing through, in particular during the transport of the arrangement according to the invention in order to avoid damages to the interior component or the glass tube.


[0016] The interior component extends preferably over the whole axial extension of the glass tube, so that a similar cooling behavior can be achieved over the total length of the glass tube. It is however also conceivable, in particular with very long glass tubes, that a multiplicity of interior components is intended, which are arranged neighboring each other but do not have a connection with one another. This offers the benefit that the interior component does not inevitably have to be adapted to the length of the glass tube, but that also here prefabricated, possibly standardized interior components can be used, which from the unit interior component by being assembled.


[0017] With the first solution a heat connection between the interior component and the wall of the glass tube is made by the fluid. In accordance with a further second solution the heat connection between interior component and glass tube is realized by the fact that either


[0018] a) the interior component is designed in such a manner, that its outer circumference is adjacent to the interior circumference of the glass tube or


[0019] b) the glass tube is provided with a coating, which takes over the function of the interior component.


[0020] In this case thereby the arrangement of a multilayer wall takes place, whereby the layers exhibit different thermal conductivity. Thus the direct contact of the fluid with the inner surface of the glass tube is avoided and a cooling takes place only indirect through the coating respectively the interior component. The interior component is here likewise formed by a pipe-shaped or tubular component, whereby the interior circumference of the glass tube corresponds to the outer circumference of the interior component. Preferably synthetic materials are used as materials, for example PTFE.


[0021] The solution according to the invention can be used with glass tubes with only an external wall and glass tubes with tubes arranged in the inside for the coaxial guidance of the flow medium. Special fields of application for the arrangement according to the invention are heat exchangers, where the components guiding the heat distribution media are formed by glass tubes and furthermore absorber tubes for solar collectors.






[0022] The solution according to the invention is following described with the figures. The following is detailed represented:


[0023]
FIG. 1 illustrates a first design according to the invention in a diagrammatic simplified view using a cross-section through a glass tube;


[0024]
FIGS. 2

a
and 2b illustrate a second design according to the invention using a sectional view through a glass tube;


[0025]
FIG. 3 illustrates a design with interior component, which extends in axial direction over the length of the glass tube;


[0026]
FIG. 4 illustrates a design with interior components arranged one behind the other in axial direction;


[0027]
FIG. 5 illustrates an arrangement with a guide device of the interior component in the glass tube;


[0028]
FIG. 6 shows a further design with an interior component, which is connected thermic directly with the wall of the glass tube;


[0029]
FIG. 7 illustrates an arrangement of a glass tube with coating at the inner surface.






[0030]
FIG. 1 illustrates an arrangement according to the invention using a diagrammatic simplified sectional view through a glass tube 1 to increase the thermal fatigue resistance of glass tubes flown through by fluid and pressure-loaded. The arrangement is marked with 2. This comprises an interior component 3 in form of a thin-walled glass tube 19, which is slid into the to be protected glass tube 1, in particular into the interior 10 surrounded by said glass tube. Glass tube 1 and interior component 3 are connected hydraulically with one another, i.e. the interior component 3 does not form a separate interior to the interior 10. The outside diameter dA3 of the thin-walled tube 19 is smaller than the inside diameter dI1 of the glass tube 1. In the condition of being flown through by fluid of the glass tube 1 both—both glass tube 1 and thin-walled tube 19—are free of a direct heat connection by direct contact, in particular the inner surface 4 of the glass tube 1 characterized by the inside diameter dI1 and the external surface 5 of the interior component 3 in form of the thin-walled tube 19, which is characterized by the outside diameter dA3. The thin-walled tube 19 exhibits thereby when viewed in the cross section a smaller wall thickness s3 than the glass tube 1. The wall thickness s1 is thereby a function of the pressure prevailing by the fluid in the glass tube 1. This requires a certain minimum wall thickness s1 during flow The minimum wall thickness of the thin-walled tube 19 can be substantially smaller, since due to the circulation on two sides, i.e. at the interior circumference and at the outer circumference, no one-sided pressure is exercised on the wall 6 of the interior component 3, which is executed as thin-walled tube 19. A change of the temperature of the fluid flowing through the glass tube 1 causes due to thermal conduction, heat transfer and convection in the fluid a change of the temperature at the wall 7 of the glass tube 1, in particular at the inner surface 4 characterized by the inside diameter dI. The glass tube 1 is filled with a cold fluid during downtime conditions in particular in applications in heat exchangers or absorber tubes. The temperature change can be thereby approx. 250 K. A heat transfer only between the wall 7 and the fluid leads to the fact that the inner surface 4 of the glass tube 1 cools down fast. By providing the interior component 3 in form of the thin-walled tube 19, due to convection in the fluid a transition between said tube and the wall 6 and the fluid takes also here place. Between both tubes—glass tube 1 and tube 19—thereby no direct heat exchange takes place, but only indirect heat exchange via the fluid flowing through the glass tube 1. The thin-walled tube 19 is preferably manufactured from glass.


[0031]
FIGS. 2

a
and 2b illustrate an arrangement 2.2 according to the invention for a glass tube 1.2 with coaxial flow, as for example for applications in vacuum tube collectors, in two sectional views. The glass tube 1.2 comprises a first, exterior tube 20 closed on one side, which forms the external wall 9 for the limitation of the interior 10. Furthermore the glass tube 1.2 comprises a second internal glass tube 21, which is arranged in the interior 10 and enables a coaxial through-flow of the glass tube 1.2. For this the second internal glass tube 21 is arranged coaxially to the first, exterior tube 20 closed on one side, inside said exterior tube and is designed open to the interior circumference at the exterior tube 20, in particular the closed side. The interior 10 is thus limited by the interior circumference 8 of the internal glass tube 21, the outer circumference 11 of the second internal glass tube 21 and the interior circumference 12 of the external wall 9, which is formed by the first, exterior tube 20 closed on one side. According to the invention a hollow cylindrical interior component 3.2 in form of a thin-walled tube 19.2, preferably made of glass is inserted into the interior 10 of the hollow tube. Said component is arranged in such a manner in the interior 10 between internal tube 21 and exterior tube 20 that it is at least in the condition of being flown through by fluid partially, preferably completely free of a contact with the outer circumference 11 and/or with the interior circumference 12 of the internal glass tube 21 respectively the external wall 9 formed by the first exterior tube 20. Also here the wall thicknesses of first exterior tube 20 and second internal tube 21 are designed different in relation to the wall thickness s3, whereby the tubes 20 and 21 are characterized by a larger wall thickness than the one of the interior component 3.2. The interior tube 3.2 is therefore also called thin-walled tube. Also here the cooling at the interior circumference 12 of the external wall 9 can be delayed due to convection in the fluid and the heat transfer to the thin-walled tube 19.2, which contributes to the improvement of the thermal fatigue resistance of the glass tube 1.2. The second internal tube 21 withstands thereby the thermal shock stress since both its interior circumference 8 and outer circumference of 11 are circulated around by fluid. Unacceptable temperature gradients at the walls of the tubes 20 and 21 of the glass tube 1.2 can thus be avoided.


[0032] With the designs represented in FIGS. 1 and 2 the interior component 3 is designed as thin-walled tube 19, 19.2, i.e. as tubular component with fixed respectively constant cross section. Furthermore the thin-walled tube is characterized by the fact that it is characterized by a fixed shaping over its axial extension.


[0033] In accordance with a further solution instead of a thin-walled tube 19, 19.2 for the interior component 3, 3.2 also a tubular component, preferably a thin-walled flexible hose, preferably made of synthetic material, can be used. The arrangement according to the invention corresponds then to those described in FIGS. 1 and 2, whereby however the thin-walled plastic tubing exhibits both in radial and axial direction a larger flexibility than the thin-walled tube. For both solutions exists the possibility, to guide the interior components 3 freely in the glass tube 1, i.e. without localizing of the position in relation to the glass tube 1. In this case the position localization takes place only due to the forces affecting the interior component 3 when fluid is flowing through.


[0034] According to a particularly favorable arrangement the interior component 3 extends, as in FIG. 3 for designs of the interior component as interior tube or thin-walled plastic tubing over the total extension I of the glass tube 1. For particularly long glass tubes 1 however the insertion of the interior component 3 is associated with an increased expenditure, if damages are to be avoided. Therefore it is conceivable, as shown in FIG. 4, to intend a multiplicity of interior components 3a, 3b and 3c which are arranged in axial direction one behind the other respectively neighboring each other, whereby said components do not have a direct connection with one another. In order to meet the requirement according to the invention, it is however not inevitably required that the individual interior components 3a to 3.n have to touch each other at their faces 14.12 and 14.21 to 14.n2 and 14.(n+1)1 which face each other. Distances a between two interior components 3.n and 3.n+1 arranged in axial direction neighboring each other would be likewise conceivable, whereby these distances a should be kept as small as possible and should not be larger than the axial extension of an interior component 3.n. Such an arrangement is shown in FIG. 4 in a diagrammatic simplified view as side view of a glass tube 1.


[0035] Concerning the position localization between the glass tube 1 and the interior component 3 the further possibility consists of locating the interior component 3 inside the glass tube 1. One possibility is represented in FIG. 5. From this figure it is evident that in each case suitable guide devices 15 and 16 are arranged within the axial end areas 13a, 13b of the interior component 3. These guide devices can be designed differently and can be formed by the glass tube 1 or however preferably by a separate component, which is interlocking or positively actuated connected with the interior component 3 and the glass tube 1.


[0036]
FIG. 5 illustrates thereby in each case the design of the guide devices 15 and 16 in form of a fixture, which fits in the interior component 3 and is clamped in relation to the interior circumference of the glass tube 1. These guide devices 15 and 16 are located in the glass tube 1 preferably positively actuated, in this case by clamping. Furthermore the guide device can be connected with the interior component interlocking and/or positively actuated. In the represented case the connection between guide 15 respectively 16 and interior component 3 is provided with at least one clearance fit in order to avoid unnecessary stresses, so that only a crude position adjustment of the interior component in relation to the glass tube takes place. The main function of the guide device is thereby a position adjustment in the condition of no fluid flowing through, in particular during the transport of the arrangement according to the invention in order to avoid damages to the interior component or the glass tube.


[0037]
FIG. 6 illustrates a second design example of an arrangement 2.6 according to the invention to increase the thermal fatigue resistance of glass tubes 1.6 flown through by fluid and pressure-loaded. The glass tube 1.6 is shown as cross section in a diagrammatic simplified view. Within this design the outside diameter dA3 of the interior component 3.6 is dimensioned in such a manner that its external surface 5.6 is adjacent to the inner surface 4.6 of the glass tube 1.6. The interior component however is not connected with the glass tube 1.6 interlocking or positively actuated. The wall 7.6 of the glass tube 1.6 and the wall 6.6 of the interior component 3.6 form thereby functionally a multilayer wall 17.6, which consists of two layers. Both layers, the layer formed by the wall 6.6 and the layer formed by the wall 7.6, are characterized by a different heat transfer behavior, so that a cooling of the inner surface 4.6 of the glass tube 1.6 takes place only slowly when fluid of a low temperature flows through the tube, as basically the wall 6.6 is inserted as the first layer. If a material is selected for the wall 6.6, which exhibits a bad thermal conductivity, the cooling of the inner surface 4.6 can be very strongly delayed, so that unacceptable high stresses, which lead to the damage of the glass tube 1.6, are avoided. It is preferable to use materials for the interior component 3.6, which exhibit a high heat transfer coefficient.


[0038] The interior component 3.6 in accordance with FIG. 6 can thereby again be formed by a thin-walled glass tube or however by a thin-walled hose-like component, preferably a plastic tubing.


[0039] In accordance with an improvement of the design of FIG. 6 in accordance with FIG. 7 the glass tube 1.7 is provided with a coating 18 at the inner surface 4.7, whereby said coating takes over the function of the interior component 3.7. A synthetic material is preferably used as coating 18, which is preferably characterized by a high heat transfer coefficient. In this case the interior component 3.7 is connected material-interlocking with the interior circumference 4.7 of the glass tube 1.7.


[0040] Reference Symbol List


[0041]

1
; 1.2; 1.6; 1.7 glass tube


[0042]

2
; 2.2; 2.6; 2.7 arrangement to increase the thermal fatigue resistance of glass tubes flown through by fluid and pressure-loaded


[0043]

3
; 3.2; 3.6; 3.7 interior component


[0044]

4
inner surface of the glass tube


[0045]

5
external surface of the interior component


[0046]

6
wall


[0047]

7
wall


[0048]

8
interior circumference


[0049]

9
external wall


[0050]

10
interior


[0051]

11
outer circumference


[0052]

12
interior circumference


[0053]

13


a,


13


b
axial end areas


[0054]

14
.11 to 14.nn face


[0055]

15
fixture


[0056]

16
fixture


[0057]

17
wall


[0058]

18
coating


[0059]

19
thin-walled tube


[0060]

20
first exterior tube, closed on one side


[0061]

21
second internal glass tube


[0062] dA3 outside diameter of the interior component


[0063] dI1 inside diameter of the glass tube


[0064] dA1 outside diameter of the glass tube


[0065] dI3 inside diameter of the interior component


[0066] s3 wall thickness of the interior component


[0067] s1 wall thickness of the glass tube


[0068] s8 wall thickness of the inner wall 8


[0069] s9 wall thickness of the external wall 9

Claims
  • 1. Arrangement (2; 2.2) to increase the thermal fatigue resistance of glass tubes (1; 1.2) 1.1. with a glass tube (1; 1.2) flown through by fluid, characterized by the following features: 1.2. with a hollow cylindrical interior component (3; 3.2) which can be inserted into the glass tube (1; 1.2); 1.3. the cavity enclosed by the interior component (3; 3.2) is hydraulically connected with the interior of the glass tube; 1.4. the wall thickness (s3) of the interior component (3; 3.2) is smaller than the wall thickness of the glass tube (1; 1.2); 1.5. the interior component (3; 3.2) is at least partially free of a direct heat connection with the glass tube (1; 1.2) in the condition of the glass tube being flown through by fluid;
  • 2. Arrangement (2; 2.2) according to claim 1, characterized by the fact that the interior component (3; 3.2) in the condition of the glass tube (1; 1.2) being flown through by fluid is completely free of a direct heat connection with the glass tube (1; 1.2).
  • 3. Arrangement (2; 2.2) according to claim 1 or 2, characterized by the fact that the interior component (3; 3.2) is formed by a tubular component.
  • 4. Arrangement (2; 2.2) according to one of the claims 1 to 3, characterized by the fact that the interior component is flexible in axial and/or radial direction.
  • 5. Arrangement (2; 2.2) according to one of the claims 1 to 4, characterized by the fact that the interior component (3; 3.2) is made of synthetic material.
  • 6. Arrangement (2; 2.2) according to claim 1 or 2, characterized by the fact that the hollow cylindrical interior component (3; 3.2) is formed by a thin-walled glass tube (19; 19.2).
  • 7. Arrangement (2; 2.2) according to one of the claims 1 to 6, characterized by the fact that the interior component (3; 3.2) exhibits less thermal conductivity than the glass tube (1; 1.2).
  • 8. Arrangement (2; 2.2) according to one of the claims 1 to 7, characterized by the fact that the interior component (3; 3.2) extends over the whole axial extension of the glass tube (1; 1.2).
  • 9. Arrangement (2; 2.2) according to one of the claims 1 to 8, characterized by the fact that multiple interior components (3a, 3b, 3c) are intended, which are arranged neighboring each other and which do not have a connection with one another.
  • 10. Arrangement (2; 2.2) according to one of the claims 1 to 9, characterized by the fact that the interior component (3) is guided in the glass tube (1; 1.2).
  • 11. Arrangement (2; 2.2) according to claim 10, characterized by the fact that the guide is designed in the glass tube (1; 1.2).
  • 12. Arrangement (2; 2.2) according to claim 11, characterized by the fact that the interior component is guided by means of a separate guide (15, 16) at the glass tube (1; 1.2).
  • 13. Arrangement (2.2) according to one of the claims 1 to 12, characterized by the fact that the glass tube (1.2) comprises a first, exterior tube (20) closed on one side, which forms the external wall (9) of the glass tube (1.2), and that it comprises a second glass tube (21), arranged inside in said exterior tube, which is designed to be open towards the closed side of the exterior tube (20) and that the interior component (3.2) in the condition of being flown through by fluid is at least partially free of a direct heat connection with the exterior and internal tube (20, 21).
  • 14. Arrangement (2.2) according to claim 13, characterized by the fact that the internal tube (21) is arranged coaxially to the exterior tube (20).
  • 15. Arrangement (2.2) according to one of the claims 1 to 14, characterized by the fact that the outer circumference (11) of the interior component (3; 3.2) is slightly smaller than the interior circumference (12) of the glass tube (1; 1.2).
  • 16. Arrangement (2.6; 2.7) to increase the thermal fatigue resistance of glass tubes (1; 1.2) 16.1. with a glass tube that can be flown through by fluid (1; 1.2), characterized by the following features: 16.2. with a hollow cylindrical interior component (3; 3.2) which is arranged in the glass tube (1.6; 1.7), its outer circumference (11) being adjacent to the interior circumference (12) of the glass tube (1.6, 1.7).
  • 17. Arrangement (2.6) according to claim 16, characterized by the fact that the interior component (3.6) is formed by a tubular component.
  • 18. Arrangement (2.6) according to one of the claims 16 or 17, characterized by the fact that the interior component (3.6) is flexible in axial and/or radial direction.
  • 19. Arrangement (2.6; 2.7) according to one of the claims 16 to 18, characterized by the fact that the interior component (3.6; 3.7) is made of synthetic material.
  • 20. Arrangement (2.7) according to one of the claims 15 to 18, characterized by the fact that the interior component (3.7) is connected material-interlocking with the glass tube (1.7) and forms a coating (18).
  • 21. Use of an arrangement in accordance with one of the claims 1 to 20 in a heat exchanger.
  • 22. Use of an arrangement in accordance with one of the claims 1 to 21 in an absorber tube of a solar collector.
Priority Claims (1)
Number Date Country Kind
102 05 548.3 Feb 2002 DE