Patent Application
20200199784
Embodiments of the present disclosure generally relate to artificial turf filaments, articles incorporating artificial turf filaments, and their manufacture.
Synthetic or artificial turfs are increasingly being used as an alternative to natural grass turf for use on sport athletic fields, playgrounds, landscaping, and in other leisure applications. Unlike natural grass turf, synthetic or artificial turfs can absorb heat from the sun. In hotter climates, this may cause the surface of synthetic or artificial turfs to become very warm and uncomfortable for players. A major contributor to heat generation are the components exposed to the sun, such as, the turf yarn and the infill.
Watering of synthetic or artificial turfs has been used as a solution to decrease the surface temperature of synthetic or artificial turfs via evaporative cooling. The evaporation of the water from the surface of the synthetic or artificial turf yarns is endothermic and provides the cooling effect. However, many synthetic or artificial turf yarns are produced from non-polar polymers, which have a low affinity to water. Limited evaporative cooling may occur due to lower amounts of water remaining on the surface of a synthetic or artificial turf yarn. In addition, the industry desires the use of less water for heat management of synthetic or artificial turfs.
Accordingly, alternative artificial turf filaments and/or artificial turfs having improved water retention is desired.
Disclosed in embodiments herein are artificial turf filaments. The artificial turf filaments comprise one or more ethylene/alpha-olefin copolymers having a density of from 0.900 to 0.955 g/cc and a melt index, I2, as measured in accordance with ASTM D1238 (at 190° C. and 2.16 kg), of from 0.1 g/10 min to 20 g/10 min; an ethoxylated alcohol having the formula, R1(OCH2CH2)xOH, where x is an integer from 2 to 10 and R1 is a straight or branched chain alkyl of 20 to 50 carbon atoms; and a functionalized ethylene-based polymer. The artificial turf filaments may be manufactured by providing a formulation comprising one or more ethylene/alpha-olefin copolymers having a density of from 0.900 to 0.955 g/cc and a melt index, I2, as measured in accordance with ASTM D1238 (at 190° C. and 2.16 kg), of from 0.1 g/10 min to 20 g/10 min; an ethoxylated alcohol having the formula, R1(OCH2CH2)xOH, where x is an integer from 2 to 10 and R1 is a straight or branched chain alkyl of 20 to 50 carbon atoms; and a functionalized ethylene-based polymer; and extruding the formulation to form an artificial turf filament.
Also disclosed in embodiments herein are artificial turfs. The artificial turfs comprise a primary backing having a top side and a bottom side; and at least one artificial turf filament; wherein the at least one artificial turf filament is affixed to the primary backing such that the at least one artificial turf filament provides a tufted face extending outwardly from the top side of the primary backing. The artificial turf filament comprises one or more ethylene/alpha-olefin copolymers having a density of from 0.900 to 0.955 g/cc and a melt index, I2, as measured in accordance with ASTM D1238 (at 190° C. and 2.16 kg), of from 0.1 g/10 min to 20 g/10 min; an ethoxylated alcohol having the formula, R1(OCH2CH2)xOH, where x is an integer from 2 to 10 and R1 is a straight or branched chain alkyl of 20 to 50 carbon atoms; and a functionalized ethylene-based polymer.
Additional features and advantages of the embodiments will be set forth in the detailed description which follows, and in part will be readily apparent to those skilled in the art from that description or recognized by practicing the embodiments described herein, including the detailed description which follows, the claims, as well as the appended drawings.
It is to be understood that both the foregoing and the following description describe various embodiments and are intended to provide an overview or framework for understanding the nature and character of the claimed subject matter. The accompanying drawings are included to provide a further understanding of the various embodiments, and are incorporated into and constitute a part of this specification. The drawings illustrate the various embodiments described herein, and together with the description serve to explain the principles and operations of the claimed subject matter.
Reference will now be made in detail to embodiments of artificial turf filaments, artificial turfs incorporating artificial turf filaments, and method of making artificial turf filaments and artificial turfs, characteristics of which are illustrated in the accompanying drawings. As used herein, “filament” refers to monofilaments, multifilaments, extruded films, fibers, yarns, such as, for example, tape yarns, fibrillated tape yarn, slit-film yarn, continuous ribbon, and/or other fibrous materials used to form synthetic grass blades or strands of an artificial turf field. The artificial turf filaments described herein comprise an ethylene/alpha-olefin copolymer, an ethoxylated alcohol, and a functionalized ethylene-based polymer, which are further detailed below. In some embodiments, the artificial turf filaments may further comprise a chemical foaming agent.
One or more ethylene/alpha-olefin copolymers may be present in the artificial turf filament. The one or more ethylene/alpha-olefin copolymers may be present in the artificial turf filament in an amount of at least 50 wt. %. All individual values and subranges of at least 50 wt. % are included and disclosed herein. For example, in some embodiments, the artificial turf filament comprises at least 75 wt. %, at least 80 wt. %, at least 85 wt. %, or at least 90 wt. % of the one or more ethylene/alpha-olefin copolymers.
The ethylene/alpha-olefin copolymer comprises greater than or equal to 70 wt. % of the units derived from ethylene and less than or equal to 30 wt. % of the units derived from one or more alpha-olefin comonomers. In some embodiments, the ethylene/alpha-olefin copolymer comprises (a) greater than or equal to 75%, greater than or equal to 80%, greater than or equal to 85%, greater than or equal to 90%, greater than or equal to 92%, greater than or equal to 95%, greater than or equal to 97%, greater than or equal to 98%, greater than or equal to 99%, greater than or equal to 99.5%, from 70% to 99.5%, from 70% to 99%, from 70% to 97% from 70% to 94%, from 80% to 99.5%, from 80% to 99%, from 80% to 97%, from 80% to 94%, from 80% to 90%, from 85% to 99.5%, from 85% to 99%, from 85% to 97%, from 88% to 99.9%, 88% to 99.7%, from 88% to 99.5%, from 88% to 99%, from 88% to 98%, from 88% to 97%, from 88% to 95%, from 88% to 94%, from 90% to 99.9%, from 90% to 99.5% from 90% to 99%, from 90% to 97%, from 90% to 95%, from 93% to 99.9%, from 93% to 99.5% from 93% to 99%, or from 93% to 97%, by weight, of the units derived from ethylene; and (b) less than or equal to 25 percent, or less than or equal to 20 percent, less than or equal to 18%, less than or equal to 15%, less than or equal to 12%, less than or equal to 10%, less than or equal to 8%, less than or equal to 5%, less than or equal to 4%, less than or equal to 3%, less than or equal to 2%, less than or equal to 1%, from 0.1 to 20%, from 0.1 to 15%, 0.1 to 12%, 0.1 to 10%, 0.1 to 8%, 0.1 to 5%, 0.1 to 3%, 0.1 to 2%, 0.5 to 12%, 0.5 to 10%, 0.5 to 8%, 0.5 to 5%, 0.5 to 3%, 0.5 to 2.5%, 1 to 10%, 1 to 8%, 1 to 5%, 1 to 3%, 2 to 10%, 2 to 8%, 2 to 5%, 3.5 to 12%, 3.5 to 10%, 3.5 to 8%, 3.5% to 7%, or 4 to 12%, 4 to 10%, 4 to 8%, or 4 to 7%, by weight, of units derived from an alpha-olefin comonomer. The comonomer content may be measured using any suitable technique, such as techniques based on nuclear magnetic resonance (“NMR”) spectroscopy, and, for example, by 13C NMR analysis as described in U.S. Pat. No. 7,498,282, which is incorporated herein by reference.
Suitable alpha-olefin comonomers may include alpha-olefin comonomers having no more than 20 carbon atoms. The one or more alpha-olefins may be selected from the group consisting of C3-C20 acetylenically unsaturated monomers and C4-C18 diolefins. For example, the alpha-olefin comonomers may have 3 to 10 carbon atoms, or 3 to 8 carbon atoms. Exemplary alpha-olefin comonomers include, but are not limited to, propylene, 1-butene, 1-pentene, 1-hexene, 1-heptene, 1-octene, 1-nonene, 1-decene, and 4-methyl-1-pentene. The one or more alpha-olefin comonomers may, for example, be selected from the group consisting of propylene, 1-butene, 1-hexene, and 1-octene; or in the alternative, from the group consisting of 1-butene, 1-hexene and 1-octene. In some embodiments, the ethylene/alpha-olefin copolymer comprises greater than 0 wt. % and less than 30 wt. % of units derived from one or more of octene, hexene, or butene comonomers.
The ethylene/alpha-olefin copolymer may be made according to any suitable polymerization process, including but not limited to solution, slurry, or gas phase polymerization processes in the presence of a metallocene, constrained geometry catalyst systems, Ziegler-Natta catalysts, or bisphenyl phenol catalyst systems. The solution, slurry, or gas phase polymerization may occur in a single reactor, or alternatively, in a dual reactor system wherein the same product is produced in each of the dual reactors. Information on preparation and use of the multimetallic catalysts are found in U.S. Pat. No. 9,255,160, the disclosure of which is incorporated herein by reference in its entirety.
Suitable polymers may include, for example, high density polyethylene (HDPE), linear low density polyethylene (LLDPE), ultra-low density polyethylene (ULDPE), homogeneously branched linear ethylene polymers, and homogeneously branched substantially linear ethylene polymers (that is, homogeneously branched long chain branched ethylene polymers). In some embodiments, the ethylene/alpha-olefin copolymer is an LLDPE. Commercial examples of suitable ethylene/alpha-olefin copolymers include those sold under the trade names ATTANE™, AFFINITY™, DOWLEX™, ELITE™, ELITE AT™, and INNATE™ all available from The Dow Chemical Company (Midland, Mich.); LUMICENE® available from Total SA; and EXCEED™ and EXACT™ available from Exxon Chemical Company.
In embodiments herein, the ethylene/alpha-olefin copolymer is characterized by a density of 0.900 g/cc to 0.955 g/cc. All individual values and subranges of at least 0.900 g/cc to 0.955 g/cc are included and disclosed herein. For example, in some embodiments, the ethylene/alpha-olefin copolymer is characterized by a density of 0.910 to 0.940 g/cc, 0.915 to 0.940 g/cc, 0.915 to 0.935 g/cc, 0.915 to 0.930 g/cc, 0.915 to 0.925 g/cc, 0.920 g/cc to 0.940 g/cc, 0.920 to 0.935 g/cc, or 0.920 to 0.930 g/cc. Density may be measured in accordance with ASTM D792.
In addition to density, the ethylene/alpha-olefin copolymer is characterized by melt index, I2, as measured in accordance with ASTM D1238 (at 190° C. and 2.16 kg), of from 0.1 g/10 min to 20 g/10 min. All individual values and subranges of at least 0.1 g/10 min to 20 g/10 min are included and disclosed herein. For example, in some embodiments, the ethylene/alpha-olefin copolymer is characterized by a melt index, I2, of 0.1 g/10 min to 10.0 g/10 min, 0.5 g/10 min to 10.0 g/10 min, 1.0 g/10 min to 10.0 g/10 min. In other embodiments, the ethylene/alpha-olefin copolymer is characterized by a melt index, I2, 1.0 g/10 min to 7.0 g/10 min, 1.0 g/10 min to 5.0 g/10 min, or 1.0 g/10 min to 4.0 g/10 min Melt index, I2, is measured in accordance with ASTM D1238 (at 190° C. and 2.16 kg).
In addition to density and melt index, I2, the ethylene/alpha-olefin copolymer may be characterized by a melt flow ratio, 110/12, of 6.0 to 10.0. All individual values and subranges of 6.0 to 10.0 are included and disclosed herein. For example, in some embodiments, the ethylene/alpha-olefin copolymer may be characterized by a melt flow ratio, 110/12, of 6.5 to 9.0. In other embodiments, the ethylene/alpha-olefin copolymer may be characterized by a melt flow ratio, 110/12, of 7.0 to 8.5. Melt index, I10, is measured in accordance with ASTM D1238 (190° C. and 10.0 kg).
In addition to density, melt index, I2, and melt flow ratio, 110/12, the ethylene/alpha-olefin copolymer may be characterized by a molecular weight distribution (Mw/Mn) of from 1.9 to 6.0. All individual values and subranges of from 1.9 to 6.0 are included and disclosed herein. For example, the ethylene/alpha-olefin copolymer may be characterized by a molecular weight distribution (Mw/Mn) of from 2.0 to 4.5. In some embodiments, the ethylene/alpha-olefin copolymer may be characterized by a molecular weight distribution (Mw/Mn) of from 2.0 to 3.0 or from 3.0 to 4.3. The Mw/Mn ratio may be determined by conventional gel permeation chromatography (GPC) as outlined below.
The ethoxylated alcohol may be present in the artificial turf filament in an amount of from 0.05 wt. % to 10 wt. %. All individual values and subranges of from 0.05 wt. % to 10 wt. % are included and disclosed herein. For example, in some embodiments, the artificial turf filament comprises from 0.05 wt. % to 7.5 wt. %, from 0.05 wt. % to 5.0 wt. %, or from 0.05 wt. % to 3.0 wt. % of the ethoxylated alcohol.
The ethoxylated alcohol has the formula, R1(OCH2CH2)xOH, where x is an integer from 2 to 10 and R1 is a linear or branched alkyl group of 20 to 50 carbon atoms. The chain length of R1 and the number (x) of monomer units of the hydrophilic oligomer may be discrete values, or alternatively, may be average values. In one embodiment, R1 is a straight chain alkyl with an average of 30 carbon atoms and x has an average value of 2.5, and the ethoxylated alcohol may have the following formula: CH3CH2(CH2CH2)13CH2CH2(OCH2CH2)2.5OH. Examples of suitable ethoxylated alcohols that are commercially available may include Unithox™ ethoxylates, available from Baker Petrolite Corporation (Tulsa, Okla.). In embodiments described herein, the ethoxylated alcohol may also include mixtures of two or more compounds of the formula, R1(OCH2CH2)xOH, where x is an integer from 2 to 10 and R1 is a straight or branched chain alkyl of 20 to 50 carbon atoms.
The ethoxylated alcohol may have a melting point, as determined according to ASTM D-127, of from 60 to 110° C. All individual values and subranges of from 60 to 110° C. are included and disclosed herein. For example, in some embodiments, the ethoxylated alcohol may have a melting point, as determined according to ASTM D-127, of from 65 to 110° C., from 70 to 110° C., from 80 to 110° C., from 80 to 100° C., or from 85 to 95° C.
The ethoxylated alcohol may have a hydroxyl number, as determined according to ASTM E-222, of from 10 to 90 mg KOH/g sample. All individual values and subranges of from 10 to 90 mg KOH/g sample are included and disclosed herein. For example, in some embodiments, the ethoxylated alcohol may have a hydroxyl number, as determined according to ASTM E-222, of from 15 to 90 mg KOH/g sample, from 25 to 90 mg KOH/g sample, from 35 to 90 mg KOH/g sample, from 45 to 90 mg KOH/g sample, or from 60 to 90 mg KOH/g sample.
The functionalized ethylene-based polymer may be present in the artificial turf filament in an amount of from 0.05 wt. % to 10 wt. %. All individual values and subranges of from 0.05 wt. % to 10 wt. % are included and disclosed herein. For example, in some embodiments, the artificial turf filament comprises from 0.05 wt. % to 7.5 wt. %, from 0.05 wt. % to 5.0 wt. %, or from 0.05 wt. % to 3.0 wt. % of the functionalized ethylene-based polymer.
The term “functionalized ethylene-based polymer,” as used herein, refers to an ethylene-based polymer that comprises at least one functional group (chemical substituent), linked by a covalent bond, and which group comprises at least one hetero-atom. A heteroatom is defined as an atom of an organic molecule that is not carbon or hydrogen. Common heteroatoms include, but are not limited to, oxygen, nitrogen, sulfur, and phosphorus. The at least one functional group (for example, maleic anhydride or acrylic acid) can react with a carbon atom located on the backbone of the ethylene-based polymer.
In embodiments herein, the functionalized ethylene-based polymer may have a density from 0.860 to 0.965 g/cc, from 0.865 to 0.960 g/cc, or from 0.870 to 0.955 g/cc. Density is measured according to ASTM D792. In addition to the density, the functionalized ethylene-based polymer may have a melt index, I2, (2.16 kg/190° C.) from 0.5 g/10 min to 1300 g/10 min, from 1 g/10 min to 300 g/10 min, 1 g/10 min to 50 g/10 min, or from 5 g/10 min to 50 g/10 min Melt Index, I2, is measured according to ASTM D1238 at 2.16 kg and 190° C.
The functionalized ethylene-based polymer may be an acid-functionalized ethylene-based polymer, anhydride-grafted ethylene-based polymer, or an ester-functionalized ethylene-based polymer. Examples of suitable commercial functionalized ethylene-based polymers include PRIMACOR™ Copolymers and AMPLIFY™ Functional Polymers, both available from The Dow Chemical Company (Midland, Mich.). The functionalized ethylene-based polymer may comprise a combination of two or more embodiments as described herein, for e.g., an ethylene acrylic acid and ethylene methacrylate.
The acid functionalized ethylene-based polymer may be an acid-functionalized ethylene-based interpolymer or copolymer. The acid functionality is present in a majority molar amount, based on the amount of functional groups bonded to the polymer. In some embodiments, the acid functionalized ethylene-based polymer comprises units derived from ethylene and a carboxylic acid. In other embodiments, the acid functionalized ethylene-based polymer comprises units derived from ethylene and acrylic acid. In further embodiments, the acid functionalized ethylene-based polymer comprises units derived from ethylene and methacrylic acid.
In some embodiments herein, the functionalized ethylene-based polymer is an ethylene acrylic acid copolymer or an ethylene methacrylic acid copolymer. In other embodiments herein, the functionalized ethylene-based polymer is an ethylene acrylic acid copolymer. The ethylene acrylic acid copolymer or ethylene methacrylic acid copolymer may comprise from 5 to 20, or from 7 to 12, weight percent of acid in the copolymer. In addition to the weight percent acid content, the ethylene acrylic acid copolymer or ethylene methacrylic acid copolymer may have a melt index (I2) from 1 to 50 g/10 min, from 2 to 25 g/10 min, from 3 to 12 g/10 min Melt Index, I2, is measured according to ASTM D1238 at 2.16 kg and 190° C.
In some embodiments herein, the functionalized ethylene-based polymer is an anhydride-grafted ethylene/α-olefin polymer. The anhydride-grafted ethylene/α-olefin polymer comprises units derived from ethylene, alpha-olefin, and maleic anhydride. The anhydride functionality is present in a majority molar amount, based on the amount of functional groups bonded to the polymer. The anhydride-grafted ethylene/α-olefin polymer may comprise from 0.2 to 5, or from 0.5 to 2, weight percent maleic anhydride in the polymer. In addition to the weight percent of maleic anhydride content, the anhydride-grafted ethylene/α-olefin polymer may have a melt index (I2) from 0.2 to 10/10 min or from 0.5 to 5 g/10 min, as measured according to ASTM D1238 at 2.16 kg and 190° C.
In some embodiments herein, the functionalized ethylene-based polymer is an ester-functionalized ethylene-based polymer. In an ester-functionalized ethylene-based polymer, ester functionality is present in a majority molar amount, based on the amount of functional groups bonded to the polymer. Ester-functionalized ethylene-based polymer may be selected from ethylene acrylate copolymers (such as ethylene butyl-acrylate copolymers, ethylene ethyl-acrylate copolymers and ethylene methyl-acrylate copolymers (EBAs, EEAs and EMAs)); ethylene/butyl acrylate/carbon monoxide (EnBACO); ethylene/butyl acrylate/glycidyl methyacrylate (EnBAGMA); ethylene butylacrylate, or ethylene glycidyl methacrylate. In some embodiments, the functionalized ethylene-based polymer comprises units derived from ethylene and an acrylate. The acrylate may be selected from ethylacrylate, methylacrylate, or butylacrylate. The ester-functionalized ethylene-based polymer may comprise from 5 to 20, or from 7 to 12, weight percent of ester content. In addition to the weight percent of ester content, the ester-functionalized ethylene-based polymer may have a melt index (I2) from 1 to 50 g/10 min, from 2 to 25 g/10 min, or from 5 to 12 g/10 min, as measured according to ASTM D1238 at 2.16 kg and 190° C.
In embodiments herein, the artificial turf filaments may further include one or more polyethylene resins. For example, the artificial turf filaments may, optionally, comprise an ultra-low or very low density polyethylene (ULDPE or VLDPE), a low density polyethylene (LDPE), a linear low density polyethylene (LLDPE), a medium density polyethylene (MDPE), a high density polyethylene (HDPE), or combinations thereof.
In embodiments herein, the artificial turf filaments may further include one or more optional additives. Nonlimiting examples of suitable additives include chemical foaming agents, antioxidants, pigments, colorants, UV stabilizers, UV absorbers, curing agents, cross linking co-agents, boosters and retardants, processing aids, fillers, coupling agents, ultraviolet absorbers or stabilizers, antistatic agents, nucleating agents, slip agents, plasticizers, lubricants, viscosity control agents, tackifiers, anti-blocking agents, surfactants, extender oils, acid scavengers, and metal deactivators. Additives can be used in amounts ranging from less than about 0.01 wt % to more than about 10 wt % based on the weight of the composition.
In some embodiments herein, the artificial turf filaments further comprise chemical foaming agents. The chemical foaming agent may be present in the artificial turf filament in an amount of from 0.05 wt. % to 10 wt. %. All individual values and subranges of from 0.05 wt. % to 10 wt. % are included and disclosed herein. For example, in some embodiments, the artificial turf filament comprises from 0.05 wt. % to 7.5 wt. %, from 0.05 wt. % to 5.0 wt. %, or from 0.05 wt. % to 3.0 wt. % of the chemical foaming agent.
Suitable chemical foaming agents may include sodium bicarbonate, ammonium carbonate and ammonium hydrogen carbonate, citric acid or citrates, such as sodium citrate, sodium glutaminate, phthalic anhydride, benzoic acid, benzoates, such as aluminum benzoate, azodicarbonamide, azoisobutyronitrile and dinitropentamethylene. The use of chemical foaming agents is exemplified by the teachings to processes of making ethylenic polymer foam structures and processing them in Chapter 9 of the “Handbook of Polymeric Foams and Technology” entitled “Polyolefin Foam”, written by C. P. Park, edited by D. Klempner and K. C. Frisch, Hanser Publishers, Munich, Vienna, New York Barcelona (1991), which is herein incorporated in reference. Examples of commercially available chemical foaming agents may be obtained from Bergan International under their FOAMAZOL™ brand name, Clariant under their HYDROCEROL™ brand name, or Lehmann & Voss & Co under their LUVOBATCH™ brand name.
The artificial turf filaments described herein may be made using any appropriate process for the production of artificial turf filament from polymer compositions as the artificial turf filaments described herein are process independent. Referring to
Artificial turf filaments may be made by extrusion. Suitable artificial turf filament extruders may be equipped with a single PE/PP general purpose screw and a melt pump (“gear pump” or “melt pump”) to precisely control the consistency of polymer volume flow into the die 105. Artificial turf filament dies 105 may have multiple single holes for the individual filaments distributed over a circular or rectangular spinplate. The shape of the holes corresponds to the desired filament cross-section profile, including for example, diamond, rectangular, dog-bone, and v-shaped. A standard spinplate has 50 to 160 die holes of specific dimensions. Lines can have output rates from 150 kg/h to 350 kg/h.
The artificial turf filaments 110 may be extruded into a water bath 115 with a die-to-water bath distance of from 16 to 40 mm Coated guiding bars in the water redirect the filaments 110 towards the first takeoff set of rollers 120. The linear speed of this first takeoff set of rollers 120 may vary from 15 to 70 m/min. The first takeoff set of rollers 120 can be heated and used to preheat the filaments 110 after the waterbath 115 and before entering the stretching oven 125. The stretching oven 125 may be a heated air or water bath oven. The filaments 110 may be stretched in the stretching oven 125 to a predetermined stretched ratio. In some embodiments, the stretch ratio is at least 4. In other embodiments, the stretch ratio is at least 4.5, 4.8, 5.0, 5.2, or 5.5. The stretching ratio is the ratio between the speed of the second takeoff set of rollers 130 after the stretching oven and the speed of the first takeoff set of rollers 120 before the stretching oven (V2/V1 as shown in
After the filaments 110 are passed over the second takeoff set of rollers 130, they are then drawn through a set of three annealing ovens 135, 140, and 145. The three annealing ovens 135, 140, and 145 may be either a hot air oven with co- or countercurrent hot air flow, which can be operated from 50 to 150° C. or a hot water-oven, wherein the filaments 110 are oriented at temperatures from 50 to 98° C. At the exit of the first annealing oven 135, the filaments 110 are passed onto a third set of rollers 150 that may be run at a different (higher or lower) speed than the second set of rollers 130. The linear velocity ratio of the third set of rollers 150 located after the oven to the second set of rollers 130 located in front of the oven may be referred to as either a stretching or relaxation ratio. At the exit of the second annealing oven 140, the filaments 110 are passed onto a fourth set of rollers 155 that may be run at a different (higher or lower) speed than the third set of rollers 150. At the exit of the third annealing oven 145, the filaments 110 are passed onto a fifth set of rollers 160 that may be run at a different (higher or lower) speed than the fourth set of rollers 155.
In some embodiments, a method of manufacturing an artificial turf filament comprises providing a formulation comprising of one or more ethylene/alpha-olefin copolymers as previously described herein, an ethoxylated alcohol as previously described herein, and a functionalized ethylene-based polymer as previously described herein, and extruding the formulation into an artificial turf filament. The artificial turf filament may be extruded to a specified width, thickness, and/or cross-sectional shape depending on the physical dimensions of the extruder. As mentioned above, the artificial turf filament can include a monofilament, a multifilament, a film, a fiber, a yarn, such as, for example, tape yarn, fibrillated tape yarn, or slit-film yarn, a continuous ribbon, and/or other fibrous materials used to form synthetic grass blades or strands of an artificial turf field.
The artificial turf filament may optionally undergo further post-extrusion processing (e.g., annealing, cutting, etc.).
One or more embodiments of the artificial turf filaments described herein may be used to form an artificial turf field. Referring to
The primary backing 205 can include, but is not limited to, woven, knitted, or non-woven fibrous webs or fabrics made of one or more natural or synthetic fibers or yarns, such as polypropylene, polyethylene, polyamides, polyesters, and rayon. The artificial turf field 200 may further comprise a secondary backing 230 bonded to at least a portion of the bottom side 215 of the primary backing 205 such that the at least one artificial turf filament 220 is affixed in place to the bottom side 215 of the primary backing 205. The secondary backing 230 may comprise polyurethane (including, for example, polyurethane supplied under the name ENFORCER™ or ENHANCER™ available from The Dow Chemical Company) or latex-based materials, such as, styrene-butadiene latex, or acrylates.
The primary backing 205 and/or secondary backing 230 may have apertures through which moisture can pass. The apertures may be generally annular in configuration and are spread throughout the primary backing 205 and/or secondary backing 230. Of course, it should be understood that there may be any number of apertures, and the size, shape and location of the apertures may vary depending on the desired features of the artificial turf field 200.
The artificial turf field 200 may be manufactured by providing at least one artificial turf filament 220 as described herein and affixing the at least one artificial turf filament 220 to a primary backing 205 such that that at least one artificial turf filament 220 provides a tufted face 225 extending outwardly from a top side 210 of the primary backing 205. The artificial turf field 200 may further be manufactured by bonding a secondary backing 230 to at least a portion of the bottom side 215 of the primary backing 205 such that the at least one artificial turf filament 220 is affixed in place to the bottom side 215 of the primary backing 205.
The artificial turf field 200 may optionally comprise a shock absorption layer underneath the secondary backing of the artificial turf field. The shock absorption layer can be made from polyurethane, PVC foam plastic or polyurethane foam plastic, a rubber, a closed-cell crosslinked polyethylene foam, a polyurethane underpad having voids, elastomer foams of polyvinyl chloride, polyethylene, polyurethane, and polypropylene. Non-limiting examples of a shock absorption layer are DOW® ENFORCER™ Sport Polyurethane Systems, and DOW® ENHANCER™ Sport Polyurethane Systems.
The artificial turf field 200 may optionally comprise an infill material. Suitable infill materials include, but are not limited to, mixtures of granulated rubber particles like SBR (styrene butadiene rubber) recycled from car tires, EPDM (ethylene-propylene-diene monomer), other vulcanised rubbers or rubber recycled from belts, thermoplastic elastomers (TPEs) and thermoplastic vulcanizates (TPVs).
The artificial turf field 200 may optionally comprise a drainage system. The drainage system allows water to be removed from the artificial turf field and prevents the field from becoming saturated with water. Nonlimiting examples of drainage systems include stone-based drainage systems, EXCELDRAIN™ Sheet 100, EXCELDRAIN™ Sheet 200, AND EXCELDRAIN™ EX-T STRIP (available from American Wick Drain Corp., Monroe, N.C.).
The embodiments described herein may be further illustrated by the following non-limiting examples.
Density is measured according to ASTM D792.
Melt index, or 12, is measured according to ASTM D1238 at 190° C., 2.16 kg. Melt index, or I10, is measured in accordance with ASTM D1238 at 190° C., 10 kg.
The gel permeation chromatographic system consists of either a Polymer Laboratories Model PL-210 or a Polymer Laboratories Model PL-220 instrument. The column and carousel compartments are operated at 140° C. Three Polymer Laboratories 10-micron Mixed-B columns are used. The solvent is 1,2,4-trichlorobenzene. The samples are prepared at a concentration of 0.1 grams of polymer in 50 milliliters of solvent containing 200 ppm of butylated hydroxytoluene (BHT). Samples are prepared by agitating lightly for 2 hours at 160° C. The injection volume used is 100 microliters and the flow rate is 1.0 ml/minute.
Calibration of the GPC column set is performed with 21 narrow molecular weight distribution polystyrene standards with molecular weights ranging from 580 to 8,400,000, arranged in 6 “cocktail” mixtures with at least a decade of separation between individual molecular weights. The standards are purchased from Polymer Laboratories (Shropshire, UK). The polystyrene standards are prepared at 0.025 grams in 50 milliliters of solvent for molecular weights equal to or greater than 1,000,000, and 0.05 grams in 50 milliliters of solvent for molecular weights less than 1,000,000. The polystyrene standards are dissolved at 80° C. with gentle agitation for 30 minutes. The narrow standards mixtures are run first and in order of decreasing highest molecular weight component to minimize degradation. The polystyrene standard peak molecular weights are converted to polyethylene molecular weights using the following equation (as described in Williams and Ward, J. Polym. Sci., Polym. Let., 6, 621 (1968)): mpolyethylene=0.4316×(Mpolystyrene). Polyethylene equivalent molecular weight calculations are performed using Viscotek TriSEC software Version 3.0.
Number-, weight- and z-average molecular weights are calculated according to the following equations:
wherein Mn is the number average molecular weight, Mw, is the weight average molecular weight, Mz is the z-average molecular weight, Wfi is the weight fraction of the molecules with a molecular weight of Mi.
Drying rate test method was performed in Sartorius Moisture Analyzer MA100, based on an adaptation of the standard work instruction PORTAR-FIBER 89.00. Film samples were cut into discs of 5 cm diameter and submerged in distilled water for at least 15 minutes (no difference in water adsorption was observed when watering for 15 minutes and overnight). Subsequently, specimens were hold in air for 30 seconds and then they were introduced in an infrared heating oven with a weighting device for 12 minutes. The heating program was defined as a constant temperature of 80° C. Weight loss, due to water evaporation, was recorded during the 12 minutes. Performance is evaluated through the following parameter:
Water Adsorption.
It reflects the amount of water that the film is able to capture, which should correlate to the amount of water present in the pitch just after watering. The index is weighted per gram of polymer, as shown in Equation 1, since samples are slightly different in weight. The calculation takes into account the weight of water after watering for 15 minutes (difference between the total weight at the beginning of the drying test, i.e. t=0, and the dry weight) and the polymer dry weight.
Water Adsorption after Rinsing.
In order to simulate the loss in water adsorption capability after pitch usage (due to surfactant release from the surface), a mild organic solvent rinsing was conducted. Samples were immersed in methanol for 2 seconds and then held under a dry nitrogen stream to stop the rinsing. Water adsorption was then measured, as described above, on the rinsed samples.
Contact angle measurements of water are performed using a Dataphysics OCA20 device. A droplet of 1 μL is dispensed and a digital image was recorded as soon as possible after deposition. The drop shape was fitted to a circle and the contact angle was then calculated from this drop profile using the software supplied with the OCD20 device. At least ten separate drops of water are employed for each film. The average contact angle is determined and reported in degrees (°).
A single filament of 250 mm length is measured in a Zwick tensile dynamometer at 250 mm/min until the fiber breaks. Tenacity is defined as the tensile force at break divided by the linear weight, and expressed in cN/dtex. Ultimate elongation is the strain at fiber break, expressed in percentage of deformation.
Basis weight is evaluated by cutting 50 meters of yarns and weighting it on a standard weighing balance. The basis weight is defined as grams per 10,000 meters and expressed as dtex.
The shrinkage of a monofilament (expressed as the percentage reduction in length of a 1 meter sample of the monofilament) is measured by immersing the monofilament for 20 seconds in a bath of silicon oil maintained at 90° C. Shrinkage is then calculated as: (length before−length after)/length before*100%.
The ethylene alpha-olefin copolymer is DOWLEX™ 2107 GC, available from The Dow Chemical Company (Midland, Mich.) having a density of 0.917 g/cc, a melt index, I2, of 2.3 g/10 min, an 110/12 of 8.1, and a Mw/Mn of 3.7. The ethoxylated alcohol is UNITHOX™ 420, available from Baker Hughes Inc. (Houston, Tex.), having a melting point of 91° C. and a Hydroxyl Number of 85 mg KOH/g sample. The functionalized ethylene-based polymer is PRIMACOR™ 1430, available from The Dow Chemical Company (Midland, Mich.), which is an ethylene acrylic acid copolymer having a density of 0.930 g/cc, a melt index, I2, of 5.0 g/10 min, and an acrylic acid content of 9.7 wt. %. The chemical foaming agent is LUVOBATCH™ PE BA 9537, available from Lehmann & Voss & Co. (Hamburg, Germany).
Film formulations CE2, CE3, and IE1 in Table 1 were melt blended in a Buss compounder. Monolayer films were fabricated using the film formulations on a Dr. Collin GmbH cast extrusion line equipped with one extruder. The processing temperature was set at around 200 to 260° C. with melt temperature at around 240° C. The extrudate was cooled by chilling rolls set at 30° C. The final film thickness is 200 micrometers. Additional processing parameters are shown in Table 2 below.
As shown in Table 3, the inventive film (IE1) shows enhanced water adsorption capability over its direct counterpart (CE2) at initial conditions. In addition, after mild organic solvent rinsing the inventive film showed the highest water adsorption, even above that with higher surfactant content (CE3).
Inventive and comparative artificial turf monofilaments were prepared from the inventive and comparative formulations listed below.
Each of the artificial turf monofilaments was prepared on an extrusion line from Oerlikon Barmag (Remscheid, Germany) (See
The inventive and comparative monofilaments were tested for various properties, and the results are shown in Table 6.
As shown in Table 6, the inventive filaments could be successfully processed with good yarn properties for the turf application. Tenacity and elongation were not significantly modified in the inventive examples as compared with the comparative examples. Shrinkage and processability as a function of pressure of the inventive examples was either comparable or improved over the comparative examples.
The dimensions and values disclosed herein are not to be understood as being strictly limited to the exact numerical values recited. Instead, unless otherwise specified, each such dimension is intended to mean both the recited value and a functionally equivalent range surrounding that value. For example, a dimension disclosed as “40 mm” is intended to mean “about 40 mm.”
Every document cited herein, if any, including any cross-referenced or related patent or application and any patent application or patent to which this application claims priority or benefit thereof, is hereby incorporated herein by reference in its entirety unless expressly excluded or otherwise limited. The citation of any document is not an admission that it is prior art with respect to any invention disclosed or claimed herein or that it alone, or in any combination with any other reference or references, teaches, suggests or discloses any such invention. Further, to the extent that any meaning or definition of a term in this document conflicts with any meaning or definition of the same term in a document incorporated by reference, the meaning or definition assigned to that term in this document shall govern.
While particular embodiments of the present invention have been illustrated and described, it would be obvious to those skilled in the art that various other changes and modifications can be made without departing from the spirit and scope of the invention. It is therefore intended to cover in the appended claims all such changes and modifications that are within the scope of this invention.
| Number | Date | Country | Kind |
|---|---|---|---|
| 17382419.4 | Jun 2017 | EP | regional |
| Filing Document | Filing Date | Country | Kind |
|---|---|---|---|
| PCT/US2018/039945 | 6/28/2018 | WO | 00 |
