The present application is a 35 U.S.C. § 371 National Stage Patent Application of International PCT Application Serial No. PCT/EP2015/060262 having an International filing date of 8 May 2015 and that was published on 12 Nov. 2015 under international publication number WO 2015/169965, which claims priority to German Patent Application No. 102014006909.5 filed 9 May 2014. This Application claims priority to and incorporates by reference the above-identified applications in their entirety for all purposes.
The invention relates to an arrangement with multiple heat exchangers for evaporating a working fluid by the transferring heat of a heat source medium as well as a method for evaporating a working fluid by the transferring heat of a heat source medium in such an arrangement. This arrangement and the method can be used in a particularly advantageous manner in connection with a system and a method for recovering energy from heat in a thermodynamic cycle process, in which the waste heat is used as the heat source medium.
Thermodynamic cycles for converting externally supplied heat energy into mechanical work are known for example in the form of the classic steam engine cycle, the Stirling cycle, the Clausius-Rankine cycle and the organic Rankine cycle (or ORC process). In the ORC process and in contrast to a classic steam engine cycle, one uses instead of water an organic, low boiling point-material as the working fluid, which continually circulates between a heat exchanger used as an evaporator, in which the initially liquid working fluid is evaporated by means of the externally supplied heat, a turbine, in which the vaporous working fluid is expanded under the extraction of mechanical work, and a condenser, in which the working fluid is cooled back down and made liquid again. With the ORC process, one is attempting through the selection of a suitable working fluid and through the optimization of the pressure and temperature to process parameters also cost-effectively transform small sources of thermal energy into mechanical work or electric energy. However, to cost-effectively operate an ORC process, a temperature level of more than 100° Celsius is required, because the efficiency drops substantially at lower process temperatures and given a small temperature spread between the heat source and the heat sink, the efficiency drops substantially.
The use of heat sources with a temperature level below 100° Celsius is relatively uneconomical, but increasingly of environmental interest and, because of the higher prices of primary energy in the form of fossil fuels, also of economic interest. Such heat or waste heat sources with relatively low temperature levels are represented for example by geothermal energy, thermal solar systems, the cooling circuits of stationary and mobile large-scale combustion engines or turbines, the waste heat of power generation in all forms (e.g., in combined heat and power plants or CHP plants), industrial process heat, or waste heat from biogas facilities. To date, waste heat remains largely unused if it cannot be utilized on site for space heating or process water heating, and it is released into the environment because transporting the heat over considerable distances or storage or conversion and other use in the form of electrical or mechanical energy at this temperature level has not been economically possible to date.
A variation to the ORC process is known from DE 102013009351 B3, which is referred to hereafter as the “Misselhorn” process and which serves as a basis for a system and a method to recover energy from heat in a thermodynamic cycle, with which the use of heat sources is possible with appropriate efficiency and under economic conditions, which have a temperature level of less than 100° Celsius. With this system, the cycle process has the following intercommunicating connected components: a condenser for recooling and liquefying a working fluid, an evaporation arrangement provided downstream—in relation to the flow direction of the working fluid—from the condenser for supplying the heat energy to the working fluid to raise its temperature and pressure, wherein the evaporator or heat exchanger arrangement has at least two heat transmission units operating independently from each other as evaporators, a work chamber, provided downstream from the heat exchanger arrangement, of a work engine for decompressing the working fluid from the heat exchanger arrangement, to draw energy out of the working fluid, and a return for the at least partially decompressed working fluid to the condenser. A pump for the working fluid is arranged between the condenser and the heat exchanger arrangement. Upstream and downstream from the heat transmission units, a valve arrangement is provided, which can be actuated in such a manner that working fluid can flow selectively into the heat transmission unit for each heat transmission unit in a first phase, the heat transmission unit is completely separated from the cycle process in a second phase to heat the collected working fluid and raise its pressure, and in a third phase the heated or evaporated working fluid can flow out to the work chamber. The valve arrangement controls the connection/separation of the heat transmission units with/of the cycle process in such a manner that the heat transmission units pass through these phases sequentially and in a time-delayed manner respectively. However, the heat source medium passes through the heat source medium through-passages of the individual heat transmission units in a parallel and continual manner. A diagram of this heat exchanger arrangement and the integration into the “Misselhorn” process is depicted in
With the system or the method according to the “Misselhom” process, one is able to have an almost continual supply of pressurized non-continuously heated working fluid under pressure or of evaporated working fluid to the work chamber of the work engine is possible, where it is decompressed through the conversion into mechanical energy. Because the working fluid is heated and pressure-boosted or evaporated in multiple fractions separated from each other and time-offset in separate heat transmission units, heat sources with a relatively low temperature level can also be used effectively. By means of the heating and evaporation, which are time-offset and separated into fractions, of the individual fractions of the working fluid, there is in each case a longer time span available to evaporate the working fluid.
DE 102010033124 A1 describes a combustion engine with a heat recovery device having a feed unit, at least two heat exchangers arranged in parallel in a working fluid cycle and having the capacity to have a working fluid flow through them, an expansion device, and a condenser. Between the feed unit and the heat exchanger in the working fluid cycle, a distribution apparatus is arranged in such a manner that the working fluid flow can be divided into working fluid sub-flows and the working fluid sub-flow flowing through the respective heat exchanger can be controlled and/or regulated to adapt to the operating conditions of the combustion engine. The heat exchangers are arranged one after the other in the exhaust gas stream serving as the heat source medium and are subjected sequentially to the lost heat of the exhaust gas stream.
DE 10200706259 A1 describes a similar arrangement of multiple heat exchangers arranged parallel relative to the working fluid sub-flow in a combustion engine, wherein no controllable distribution device is provided but a separate pump is assigned to each heat transfer device.
EP 2522828 A2 describes an ORC cycle, in which multiple transfer devices arranged parallel relative to the working fluid sub-flow have a charge air flow serving as a heat source medium flow sequentially through them to use its heat to preheat the working fluid in the cycle process.
CA 2744404 A1 describes an ORC cycle process in which to increase the absorbable heat quantity from the ground or the ambient air, a plurality of evaporators are arranged in a matrix parallel and in series relative to the working fluid sub-flow, and all evaporators have the heat source medium flow through them in a parallel and simultaneous manner.
With the invention, the process of evaporating the working fluid, particularly for use in a system and a method for recovering energy from heat in a thermodynamic cycle, preferably but not exclusively the “Misselhorn” process, is to be further improved so that the utilization of energy from the respective heat source can occur with greater efficiency, and [a] vaporous working fluid can be provided at high pressure as constantly as possible, and in particular so that the pinch point limitation of conventional ORC systems can be avoided.
For solution purposes, the invention proposes an arrangement with multiple heat exchangers for evaporating a working fluid by transferring heat from a heat source medium and a method for evaporating a working fluid by transferring heat from a heat source medium in an arrangement with multiple heat exchangers. Preferred embodiments of the arrangement and the method are provided in the dependent claims.
Accordingly, the invention relates to an arrangement with multiple heat exchangers for evaporating a working fluid by transferring heat from a heat source medium, wherein each heat exchanger has a heat source medium through-passage and separated from that a working fluid chamber, and the heat source medium through-passages of the heat exchangers are or can be serially interconnected, preferably in a ring arrangement, wherein between the heat source medium through-passages of any two serially consecutive heat exchangers in the ring arrangement, one valve means is provided in each case, wherein a supply line is provided for the heat source medium, which can be connected selectively to the inlet of the heat source medium through-passage of each heat exchanger, and wherein a discharge line is provided for the heat source medium, which can be connected selectively to the outlet of the heat source medium through-passage of each heat exchanger.
Accordingly, the invention also relates to a method for evaporating a working fluid by transferring heat from a heat source medium in an arrangement with multiple heat exchangers, which each have a heat source medium through-passage and separated from that a working fluid chamber, and their heat source medium through-passages are or can be interconnected in series, preferably in a ring arrangement, with the steps of a sequential connecting of a supply line for the heat source medium to the inlet of the heat source medium through-passage of a first heat exchanger and a sequential connecting of a discharge line for the heat source medium to the outlet of the heat source medium through-passage of a second heat exchanger, while the supply line and discharge line are separated from the inlet of the heat source medium through-passage of the second or of the outlet of the heat source medium through-passage of the first heat exchanger and, if present, is separated from the inlets and outlets of the heat source medium through-passages of additional heat exchangers of the arrangement.
The arrangement according to the invention or the method according to the invention allows a more efficient utilization of the heat energy of the respective heat source, by the heat source medium of the heat source being introduced directly into the heat exchanger for example, and the heat source medium being directed, after passing through a first heat exchanger and a partial extraction of the heat energy, serially through the other heat exchangers of the arrangement. The sequence of the heat source medium passing through the heat exchangers can be cyclically switched over so that in every cycle the liquid working fluid is introduced into another heat exchanger (which in this phase has the lowest temperature and/or pressure level of the working fluid) or the heated and evaporated working fluid is discharged out of another heat exchanger (which in this phase has the highest temperature and/or pressure level of the working fluid).
With the arrangement according to the invention, the pinch-point limitation of conventional ORC systems is avoided. By means of the in-series arrangement, preferably in a ring arrangement, of multiple heat exchangers operating as evaporators in batch mode, and the routing of the hot heat source medium from evaporators having a higher temperature of the working fluid to evaporators with a lower temperature of the working fluid, the respective necessary pinch-point is maintained in each evaporator. Since only the evaporator with the highest temperature of the heat source medium is connected to the work or expansion engine, the result is always a high pressure of the working fluid when flowing out to the expansion engine and thus good thermal efficiency of the system. In the evaporators connected just downstream from the work engine, the heat source is further cooled by transferring heat to the working fluid in the respective evaporator and the system efficiency increases (see
“Pinch point” refers to the temperature difference between the heat-emitting (the relatively hot) and the heat-absorbing (the relatively cool) mass flow at the point that describes the closest proximity of the TQ curves of heat source medium and working fluid. Only when there is a temperature difference between the hot and the cold medium, which should generally be at least 5K to 10K, a heat transfer occurs in finite time and with economically feasible heat transfer surfaces. In principle, the ORC process can be run in 2 different modes (and intermediate stages thereof):
a) Good utilization of the heat source, i.e., largest possible temperature decrease of the hot heat source medium, i.e., optimized system efficiency. System efficiency is a measure of how much total heat available is converted into work (see
b) Good utilization of the transferred heat outlet, i.e., high thermal efficiency, however then with poorer utilization of the heat source and correspondingly lower system efficiently. The thermal efficiency describes how efficient the actually transferred heat is converted into work (see
Often, a compromise is desired, depending on the utilization possibilities of the residual heat after the ORC and/or other factors. In order to achieve the highest possible outlet of the ORC system, the pressure level of the working fluid, which leaves the evaporator and flows into the work or expansion engine, e.g., a turbine or a piston engine, must be as high as possible. Due to thermodynamics, a high pressure requires a high temperature of the working fluid. This high temperature plus the temperature difference due to the pinch point generates the minimum required temperature of the hot heat source medium in the evaporator. The higher the desire pressure and temperature levels of the working fluid, the less the heat source can thus be cooled. To achieve the highest possible system efficiency, the heat source is cooled to a greater degree, the maximum temperature of the working fluid lies below the low, cooled temperature of the heat source medium by the pinch point interval. The high temperatures of the heat source medium remain unused, i.e., only a relatively low pressure of the working fluid and thus a low outlet of the expansion engine can be achieved.
The combination of the arrangement according to the invention of heat exchangers to evaporate a working fluid through the exchange of heat with a heat source medium ca thus be combined in a particularly advantageous manner in connection with the system, known from DE 102013009351, to recover energy from heat in a thermodynamic cycle process because this system on the cyclic connection always provides of a heat exchanger with multiple heat exchangers with the work chamber of a work engine, which has the highest temperature level or the working fluid with the highest temperature and/or pressure level, while the or another heat exchanger is supplied with a liquid working fluid and heated, and additional heat exchangers including the working fluid are heated.
The arrangement and the method according to the invention are explained hereafter using the attached drawings. Depicted are:
When increasing the number of heat exchangers operating as evaporators and that having the heat source medium passing through them sequentially, the curve shape of the working fluid and the heat source medium continue to approach each other in the arrangement's T-Q diagram. Furthermore, one shall note that the working fluid lines and working fluid chambers of the heat exchangers are not depicted in
Each heat exchanger 10.1, 10.2, 10.3 of the arrangement has a heat source medium through-passage with an inlet and outlet (not depicted) and a working fluid chamber separated therefrom, also having an inlet and outlet (not depicted), so that the material flows of the heat source medium and working fluid are separated. Between the heat source medium through-passage and the working fluid chamber, one shall ensure that the heat exchange is as efficient as possible, wherein the specific construction of the heat exchangers is not significant for the functioning of the invention, but only represents an optimization task. For example, the heat exchangers may be designed as pipe bundle-heat exchangers.
The heat source medium through-passages of the heat exchangers are or can be interconnected in series, preferably in a ring arrangement or ring line 16, by the outlet of the heat source medium through-passage of a heat exchanger being connected to the inlet of the heat source medium through-passage of a subsequent heat exchanger in the ring arrangement, wherein between the heat source medium through-passages of any two serially consecutive heat exchangers 10.1, 10.2, 10.3 in the ring arrangement, there is provided in each case one valve 12.1, 12.2, 12.3, with which the connection can be selectively disconnected. Valves 12.1, 12.2, 12.3 are designed as switchable and preferably remote-actuated valves. They may be designed as controlled or simple check valves, if one ensures based on the pressure level of the heat source medium that a backflow into the heat source medium through-passage of a heat exchanger within the ring arrangement does not occur upstream of the heat source medium introduction location.
A supply line 14 for the heat source medium can be selectively connected to the inlet of the heat source medium through-passage of each heat exchanger and a discharge line 15 for the heat source medium can also be selectively connected to the outlet of the heat source medium through-passage of each heat exchanger. To do so, there are also provided, in the connecting lines between the supply line and the section of the ring line between the respective ring line valve 12.1, 12.2, 12.3 and its respective heat exchanger located downstream, switchable and preferably remote-actuated valves 11.1, 11.2, 11.3 to create and disconnect the selective connections of the supply line to the heat source medium through-passages. Accordingly, switchable and preferably remote-actuated valves 13.1, 13.2, 13.3 are provided in the connection lines between discharge line 15 and the section of the ring line between the respective ring line valve 12.1, 12.2, 12.3 and its respective heat exchanger located upstream in order to create and to disconnect the selection connections of the discharge line to the heat source medium through-passages.
The combination of connection lines and valves as well as the switchability of the valves of the arrangement is designed in such a manner that within a cycle still to be described below the inlet of the heat source medium through-passage of the heat exchanger, which has the highest pressure and/or temperature level of the working fluid among the heat exchangers of the ring arrangement, can be connected to the discharge line for the heat source medium, and that the outlet of the heat source medium through-passage of the heat exchanger, which has the lowest pressure and/or temperature level of the work medium among the heat exchangers of the ring arrangement, can be connected to the supply line for the heat source medium. When there are more than two heat exchangers in the arrangement, for the heat exchanger(s) that do not have the highest or the lowest pressure or temperature level of the working fluid, the heat source medium through-passage can only be connected to the heat source medium through-passage of the, or one of the other, heat exchanger(s), so that the heat source medium is directed in series through the heat exchanger.
Preferably, the supply and discharge lines for the heat source medium can be sequentially and synchronously connected to the heat source medium through-passages of the heat exchanger of the arrangement, so that the described further switching of the heat exchangers can occur within any given cycle in a simultaneous and clearly delineated manner. Furthermore, the arrangement is designed in such a manner that the duration of the connection of the supply and discharge lines for the heat source medium to the heat source medium through-passage of a respective heat exchanger is preset to a duration corresponding to the configuration of the arrangement and at least for a certain operating period over several cycles. Preferably, it is also possible however that the duration is controlled depending on the pressure and/or temperature of the working fluid in the heat exchanger, which among the heat exchangers in the arrangement has the highest pressure or temperature level of the working fluid, because this heat exchanger provides the evaporated working fluid for the work engine. With this control unit, one can ensure a quasi-continual supply of vaporous working fluid to the work engine at a pressure as constant as possible and one can thereby ensure operation without large outlet or engine speed fluctuations.
The connection lines and switchable valves for the working fluid as well as the working fluid chambers are not depicted in
run through the individual phases of feeding in the working fluid, heating the working fluid, including in the respective heat exchangers, and discharging the vaporous working fluid out of the heat exchanger into the work engine in a sequential and time-offset manner in each case.
The arrangement is thereby to be designed in such a manner that the introduction of the working fluid takes place into the working fluid chamber of the heat exchanger, which among the heat exchangers of the arrangement has the lowest pressure and/or temperature level of the working fluid, and the discharge of the working fluid occurs out of the working fluid chamber of the heat exchanger, which among the heat exchangers of the arrangement has the highest pressure and/or temperature level of the working fluid, and wherein the timespan of the introduction phase and the timespan of the discharge phase are essentially the same length, and the switchover of the introduction and discharge phases occurs between the heat exchangers of the arrangement in a synchronous and sequential manner. If the arrangement preferably has at least three heat exchangers, it is also designed in such a manner that the heat exchanger(s), which does/do not have the highest or the lowest pressure or temperature level of the working fluid, the working fluid remains enclosed in the working fluid chamber during the introduction and discharge phases of the other heat exchanger. For n evaporators or heat exchangers, there will basically be n different circuit situations of the valves when operating the arrangement according to these phases.
Hereinafter, a switch cycle of the arrangement of the heat exchangers will be described for example purposes using an arrangement with 3 heat exchangers and in reference to
In switch situation 1 (
In switch situation 2 (
In switch situation 3 (
In a (not depicted) preferred embodiment of the arrangement with multiple heat exchangers according to the invention, the heat exchangers of the arrangement are arranged or designed in such a manner that the inlet of the heat source medium through-passage of each heat exchanger is located at a lower position level than the outlet of the respective heat exchanger. In this preferred embodiment, the heat source medium flows through the heat source medium through-passages of the heat exchanger in a vertical manner from bottom to top and thus against the influence of gravity. Even if the heat source medium through-passage in the heat exchanger has a zig-zag shape for example, it is ensured that the heat source medium is conducted through the heat source medium through-passages of the heat exchanger in such a manner that it flows through the heat source medium through-passages at least partially against the influence of gravity.
The schematic illustrations of embodiments of the invention serve only to explain the invention. For that reason, the distances of the connection lines between the individual components and the arrangement, [as well as] the number and design of valves are only for example purposes and serve to explain the operating principle. Furthermore, it shall be pointed out in particular that the schematically depicted arrangements of heat exchangers or heat transfer devices each have three heat exchanging units, wherein according to the invention one heat exchanger arrangement with at least two heat exchanger units independent of each other may be sufficient and more than the three heat exchanger units may also be used.
In addition, the invention is not limited to a certain construction of the heat exchangers, wherein in particular the illustration of the heat exchangers in
As work media for the arrangement according to the invention, all media usable in conventional cycles, such as the ORC cycles and the “Misselhorn” process, are considered, in particular organic or synthetic materials, for example R245fa, ethanol or R134a.
The term “heat source medium” also comprises both the medium supplied directly by a heat source and usable directly in the heat exchangers, such as hot wastewater, cooling water, etc., and also a heat transport medium such as thermal oil and similar, which circulates in a closed intermediate circuit and serves to transport the heat from a distant heat source or a heat source not suited for direct use to the heat exchangers of the cycle.
As a heat source for the arrangement according to the invention, ultimately one can consider all heat sources in the form of useful heat or waste heat from the sources described in the introduction, which supply a sufficiently high temperature level of at least 600 Celsius, preferably 60-100° Celsius and a sufficiently large volume or mass flow. However, the arrangement according to the invention can also be used with heat sources having higher temperature levels.
Even though
Number | Date | Country | Kind |
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10 2014 006 909 | May 2014 | DE | national |
Filing Document | Filing Date | Country | Kind |
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PCT/EP2015/060262 | 5/8/2015 | WO | 00 |
Publishing Document | Publishing Date | Country | Kind |
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WO2015/169965 | 11/12/2015 | WO | A |
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Number | Date | Country | |
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20170336067 A1 | Nov 2017 | US |