The present invention is directed to new systems and methods for preparing woven nanofiber yarns for use in sensors, electronics, high performance composite material, biotech and biomedical industry and manufacturing of nanomaterials.
When continuous filaments are not possible (e.g., wool, cotton, electrospun fibers, etc.) discrete length fibers can be interlocked into a continuous staple yarn. Prior to staple yarn spinning, fiber meshes can be sorted, carded, and combed to break up locks and clumps, and align disorganized fibers. Cotton carding with metal wire brushes is illustrated in
Given the importance of fiber properties such as surface area, and coefficient of friction to yarn properties, it is hypothesized that nano-yarns can exhibit unique behaviors.
Despite the inherent challenges, efforts have been made to produce electrospun nanofiber yarns. For example, continuous yarns have been spun from a nanofiber web collected on the surface of water. In another example, without liquids, continuous bundles of nanofibers have been formed by the attraction with two oppositely charged electrospinning jets that could be twisted into a yarn. In yet another example, a grounded needle and an AC current have been used to induce single electrospinning jets to self-bundle. In yet another example, dual rotating collectors have been used to twist aligned electrospun fibers into discontinuous bundles and later to wind long yarns. Though successful, all of these yarns were spun from fibers directly fed by an electrospun jet or by twisting a randomly oriented mesh. Thus, fiber length, feed rate, and uniformity can be difficult to measure and control. Direct collection from the electrospinning jet also precludes complete solvent evaporation and nanofiber post-processing before yarn assembly.
Staple yarn spinning in the traditional textile industry is a highly developed technology with a mechanistic understanding of the relationships between yarn structure and yarn strength. Polymer nanofiber materials are not compatible with traditional staple yarn manufacturing methods. Most attempts to produce electrospun yarns have been assembled from fibers directly intertwined from the electrospinning jet or from a randomly oriented nanofiber mesh floated on water. Under these conditions, it can be impossible to tightly control parameters such as nanofiber length, feed rate, and fiber organization. Thus, there is still little understanding of how conventional yarn structure-function relationships translate to the nanoscale.
The present disclosure provides a system and method for producing nanofibers. The system includes an automated track system including a first track having a first face; and a second track having a second face facing the first face of the first track. The first track and the second track are positioned to define a proximal gap and a distal gap. The first track and the second track are adapted and configured to transfer a nanofiber coupled to the first face and the second face from the proximal gap to the distal gap. The system also includes a roving belt that is positioned to be partially disposed within the distal gap and is adapted and configured to decouple the nanofiber from the first face and the second face.
In another aspect, the present disclosure provides a method for producing nanofibers. The method includes: coupling a first end of a nanofiber to a first face of a first track and a second end of the nanofiber to a second face of a second track, wherein the first track and the second track are positioned to define a proximal gap and a distal gap, wherein the coupling occurs in the proximal gap; translating the first face and the second face such that the nanofiber travels from the distal to the proximal gap; disposing the nanofiber from the first face and the second face to a surface of a roving belt within the distal gap, such that a length of the nanofiber is in contact with the surface of the roving belt; and translating the roving belt such that the nanofiber travels out of the distal gap.
The instant invention is most clearly understood with reference to the following definitions.
As used herein, the singular form “a,” “an,” and “the” include plural references unless the context clearly dictates otherwise.
Unless specifically stated or obvious from context, as used herein, the term “about” is understood as within a range of normal tolerance in the art, for example within 2 standard deviations of the mean. “About” can be understood as within 10%, 9%, 8%, 7%, 6%, 5%, 4%, 3%, 2%, 1%, 0.5%, 0.1%, 0.05%, or 0.01% of the stated value. Unless otherwise clear from context, all numerical values provided herein are modified by the term about.
As used in the specification and claims, the terms “comprises,” “comprising,” “containing,” “having,” and the like can have the meaning ascribed to them in U.S. patent law and can mean “includes,” “including,” and the like.
Unless specifically stated or obvious from context, the term “or,” as used herein, is understood to be inclusive.
Ranges provided herein are understood to be shorthand for all of the values within the range. For example, a range of 1 to 50 is understood to include any number, combination of numbers, or sub-range from the group consisting 1, 2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15, 16, 17, 18, 19, 20, 21, 22, 23, 24, 25, 26, 27, 28, 29, 30, 31, 32, 33, 34, 35, 36, 37, 38, 39, 40, 41, 42, 43, 44, 45, 46, 47, 48, 49, or 50 (as well as fractions thereof unless the context clearly dictates otherwise).
For a fuller understanding of the nature and desired objects of the present invention, reference is made to the following detailed description taken in conjunction with the accompanying drawing figures wherein like reference characters denote corresponding parts throughout the several views.
The invention is best understood from the following detailed description when read in connection with the accompanying drawings. It is emphasized that, according to common practice, the various features of the drawing are not to scale. On the contrary, the dimensions of the various features are arbitrarily deformed or reduced for clarity. Included in the drawings are the following figures:
Described herein is a method to assemble stabilized, uniform length, aligned nanofibers into staple yarns in a highly controlled continuous process. The present disclosure provides a system and method to spin staple yarns from highly ordered electrospun polymer nanofibers with precise control over manufacturing parameters. In certain embodiments, the system and methods produce yarns from fixed-end, ordered, electrospun nanofiber arrays. Tight controls over nanofiber properties and spinning conditions can facilitate systematic investigation of fundamental textile manufacturing parameters (e.g., fiber twist, length, surface area, coefficient of friction, etc.). Certain systems and methods of the present disclosure can further knowledge about polymer nanofiber material response (e.g., in textile nanomanufacturing procedures) and develop a mechanistic understanding of yarn structure-strength relationships in the nanoscale.
In at least one aspect of the invention, automated tracks provide a continuous feed of aligned nanofiber arrays which are then spun to form staple yarns. In at least one embodiment, track designs can be integrated with a rotating leader that twists and winds. In at least one embodiment, the rotating leader is configured for automated track spinning from the fiber center. In at least one embodiment, the rotating leader is configured for automated track spinning from the fiber ends. In at least one embodiment, device designs will incorporate: (1) adjustable geometry of fiber contact with the spinning leader to allow for contact angles from 0-90° at any point from the middle to the end of fiber; (2) clean, consistent fiber end detachment from the tracks; and (3) adjustable track widths to accommodate a range of nanofiber lengths of at least 1-6 cm.
Those of ordinary skill in the art can appreciate that the present disclosure, among other uses has application, in tissue engineering scaffolds, lithium ion batteries, supercapacitors, dye-sensitized solar cells, sensors, electronics, high performance composite material, catalysis and direct manufacturer/distributor of nanomaterial.
The utility of uniaxial fiber bundles lies in the ability to spin them into continuous staple yarns that are compatible with the textile industry. However, nanofibers cannot be processed into staple yarns using traditional techniques because of their small size and mechanical integrity. The present disclosure provides alternative systems and methods of staple yarn spinning that circumvents fiber pre-sorting and alignment processing by directly fabricating and delivering electrospun nanofibers as ordered aligned arrays. Highly organized, high strength staple yarns produced by systems and methods of the present disclosure allow electrospinning to become compatible with the textile industry and result in a multitude of polymer nano-fabric products.
Automated tracks can provide a continuous feed of aligned nanofiber arrays for spinning staple yarns. Several track geometries will be integrated with a twisting leader. Devices can be evaluated for a range of fiber-leader contact geometries, fiber lengths, and fiber detachment methods. PCL nanofibers with 250-1000 nm diameters will be assembled into 10-100 μm diameter yarns with twist angles from 10-70°. Assembled yarns can be characterized and compared to conventional microfiber models to ascertain the influence of the nanoscale on the structure-strength relationship.
Automated tracks can provide a continuous feed of aligned nanofiber arrays for spinning staple yarns in a fully integrated system. Horizontal tracks can replace the static collecting rack used in previous systems. A method to collect aligned electrospun nanofibers includes a nanofiber collecting device including two automated parallel tracks separated by an air gap (as illustrated in
A feed can take the place of the roving illustrated in
In at least one experiment, PCL nanofibers with diameters from 250-1000 nm can be electrospun and fed to a rotating yarn leader, in accordance with an exemplary embodiment of the present disclosure. Exemplary systems can be tested within the full range of fiber geometry limits described above. Nanofibers with packing densities from 10-100% can be fed at rates from 0-50 mm/s, for example. Leader rotation and translation rates can be optimized to form tightly wound yarns with target diameters, for example, from 10-100 μm and twist angles, for example, from 10-70°. The range of each parameter can be adjusted if the forces generated cause nanofiber breakage. In order to investigate the effect of coefficient of friction on yarn mechanical properties, yarns from blended PCL and poly (ethylene glycol) (PEG) nanofibers can be spun. Blended fibers can be electrospun from PCL solutions with PEG added, for example, at 0-30% weight in the common solvent HFIP. Manufactured yarns can be evaluated with a scanning electron microscope (SEM) to characterize overall yarn diameter, fiber count, nominal twist, variation of twist and irregularities. The mechanical properties of yarns can be evaluated for tensile strength and elongation at maximum force using a universal testing machine. The experimental values can be compared to expected values predicted by mechanistic models for conventional microfiber yarns. The design can provide a system where electrospinning, post-drawing, and staple yarn spinning are seamlessly integrated. Such a system and design can combine multiple devices and matching the rates of fiber collection and yarn feed by modifying device parameters. Multiple electrospinning jets can be used if the electrospinning rate is much lower than the required yarn feed rate.
Exemplary embodiments of the present disclosure can be best described in connection with the drawings.
System 100 also includes a roving belt 116. Roving belt 116 is positioned partially disposed within the distal gap. Roving belt 116 is adapted and configured to decouple nanofiber 118 from first face 106 and second face 110. For example, roving belt 116 is illustrated having decoupled a fiber 118a from a plurality of fibers 118 disposed between first track 104 and second track 108. Fiber 118a can be decoupled by shearing off the tracks onto a roving belt (similar to a static rack illustrated in
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In certain embodiments, the present disclosure describes an approach to assemble staple yarns directly from a supply of discrete length aligned nanofibers delivered by an automated track. The present disclosure further provides a method of manufacturing ordered polymer nanofiber staple yarns. In certain embodiments, the methods of the disclosure allow for continuous manufacture of nanofiber staple yarns that can be compatible with higher order textile processing. In certain embodiments, the methods of the disclosure allow for roving from automated tracks. the methods of the disclosure allow for assembly of continuous nanofiber yarn from discrete length polymer nanofibers.
In certain embodiments, an intermediate step is added where aligned nanofibers are transferred to a continuous “roving”.
In certain embodiments, the fixed ends of the fibers are removed from the track and incorporated into the roving such that the ends of the fibers are no longer fixed.
In certain embodiments, the roving is translated on a continuous conveyor belt with the fibers aligned in the direction of translation.
In certain embodiments, staple yarns are spun from the roving.
The following enumerated embodiments are provided, the numbering of which is not to be construed as designating levels of importance.
Embodiment 1 provides a system for producing nanofibers, the system comprising: an automated track system including a first track having a first face, and a second track having a second face facing the first face of the first track, wherein the first track and the second track are positioned to define a proximal gap and a distal gap, and the first track and the second track are adapted and configured to transfer a nanofiber coupled to the first face and the second face from the proximal gap to the distal gap; and a roving belt that is positioned to be partially disposed within the distal gap and is adapted and configured to decouple the nanofiber from the first face and the second face.
Embodiment 2 provides the system of embodiment 1, wherein the roving belt is configured and adapted to transfer the nanofiber external to the distal gap.
Embodiment 3 provides the system of any one of embodiments 1-2, wherein the roving belt is configured and adapted to actuate at a speed independent of a speed of the first track and the second track.
Embodiment 4 provides the system of embodiment 3, wherein the speed of the roving belt is less than the speed of the first track and the second track.
Embodiment 5 provides the system of any one of embodiments 1-4, wherein the roving belt is adapted and configured to intermittently actuate.
Embodiment 6 provides the system of any one of embodiments 1-5, wherein the portion of the roving belt disposed in the distal gap is parallel to a length of the nanofiber.
Embodiment 7 provides the system of any one of embodiments 1-6, wherein the roving belt is adapted and configured to collect a second nanofiber, wherein a length of the second nanofiber at least partially overlaps a length of the nanofiber when coupled to the roving belt.
Embodiment 8 provides the system of any one of embodiments 1-7, wherein the roving belt is adapted and configured to transfer the nanofiber to a yarn spinner.
Embodiment 9 provides the system of any one of embodiments 1-8, wherein a portion of the roving belt disposed in the distal gap is perpendicular to a length of the nanofiber.
Embodiment 10 provides a method for producing nanofibers (e.g., using the system of any one of embodiments 1-9), comprising: coupling a first end of a nanofiber to a first face of a first track and a second end of the nanofiber to a second face of a second track, wherein the first track and the second track are positioned to define a proximal gap and a distal gap, wherein the coupling occurs in the proximal gap; translating the first face and the second face such that the nanofiber travels from the distal to the proximal gap; disposing the nanofiber from the first face and the second face to a surface of a roving belt within the distal gap, such that a length of the nanofiber is in contact with the surface of the roving belt; and translating the roving belt such that the nanofiber travels out of the distal gap.
Embodiment 11 provides the method of claim 10 wherein the disposing includes heating a portion of the nanofiber.
The present application claims priority to U.S. Provisional Patent Application No. 63/302,740, filed Jan. 25, 2022, which is incorporated herein by reference in its entirety.
This invention was made with government support under grant number 1653329 awarded by the National Science Foundation. The government has certain rights in the invention.
Filing Document | Filing Date | Country | Kind |
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PCT/US23/11538 | 1/25/2023 | WO |
Number | Date | Country | |
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63302740 | Jan 2022 | US |