This document relates generally to energy storage and particularly to sintered electrodes to store energy in an implantable medical device.
Electrical stimulation therapy has been found to benefit some patients. For example, some patients suffer from an irregular heartbeat or arrhythmia and may benefit from application of electrical stimulation to the heart. Some patients suffer from a particular type of arrhythmia called a fibrillation. Fibrillations may affect different regions of the heart, such as the atria or the ventricles. When a fibrillation occurs in the ventricles, the heart's ability to pump blood is dramatically reduced, putting the patient at risk of harm. It has been found that applying an electrical stimulation to the patient can effectively treat patients suffering disorders such as from fibrillation by restoring a regular heartbeat.
Because disorders such as fibrillations can happen at any time, it is helpful to have a device that is easily accessible to treat them. In some cases, it is helpful if that device is portable or implantable. In developing a device that is portable or implantable, it is helpful to have access to components that are compact and lightweight and that can perform to desired specifications.
In example 1, an apparatus includes a capacitor case sealed to retain electrolyte; a plurality of sintered anodes disposed in the capacitor case, each of the plurality of sintered anodes having a hole at least partially through the sintered anode; and at least one post through the holes of the plurality of sintered anodes to electrically couple the sintered anodes.
In example 2, the subject matter of claim 1 can optionally include each of the holes in the plurality of anodes being a threaded hole.
In example 3, the subject matter of claim 1 or 2 can optionally include two threaded posts used to interconnect the plurality of sintered anodes.
In example 4, the subject matter of any of claims 1-3 can optionally include one of the plurality of anodes including a second hole configured to receive a threaded feedthrough post.
In example 5, a method of assembling a capacitor includes sintering cathode material directly to an inside surface of a capacitor case, the cathode material forming one or more sintered cathodes having a shape; and placing a sintered anode over or around the sintered cathodes, the sintered anode having one or more mating portions that match the shape of the one or more sintered cathodes such that the mating portions matingly receive the sintered cathodes.
In example 6, the subject matter of example 5 can optionally include the mating portions of the sintered anode being shaped like a fin and the sintered cathode having a fin shape.
In example 7, the subject matter of example 5 can optionally include the sintered cathode having a cylindrical shape and the mating portions of the sintered anode including rounded cut-outs at one or more corners of the sintered anode.
In example 8, the subject matter of example 5 can optionally include, the mating portions being conical and the sintered cathode being conical.
In example 9, the subject matter of any of examples 5-8 can optionally include the cathode including a bed of nails structure.
In example 10, the subject matter of any of examples 5-9 can optionally include a separator applied to the cathode, wherein the separator includes a high dielectric polymer directly applied to an outer surface of the sintered cathode.
In example 11, a method of assembling a capacitor includes sintering cathode material directly to a PCB within a capacitor case, the cathode material forming one or more sintered cathodes having a shape; and placing a sintered anode over the sintered cathodes, the sintered anode having one or more mating portions that match the shape of the one or more sintered cathodes such that the mating portions matingly receive the sintered cathodes.
In example 12, the subject matter of example 11 can optionally include the mating portions of the sintered anode being shaped like a fin and the sintered cathode having a fin shape.
In example 13, the subject matter of claim 12 can optionally include the sintered cathode having a cylindrical shape and the mating portions of the sintered anode including rounded cut-outs at one or more corners of the sintered anode.
In example 14, the subject matter of example 11 can optionally include the mating portions being conical and the sintered cathode being conical.
In example 15, a method of assembling a capacitor includes sintering cathode material onto a aluminum foil, the cathode material forming one or more sintered cathodes having a shape; and placing a sintered anode over the sintered cathodes, the sintered anode having one or more mating portions that match the shape of the one or more sintered cathodes such that the mating portions matingly receive the sintered cathodes; and applying a polymer coating over the sintered anode, the sintered cathode and the aluminum foil.
This Summary is an overview of some of the teachings of the present application and not intended to be an exclusive or exhaustive treatment of the present subject matter. Further details about the present subject matter are found in the detailed description and appended claims. Other aspects of the invention will be apparent to persons skilled in the art upon reading and understanding the following detailed description and viewing the drawings that form a part thereof. The scope of the present invention is defined by the appended claims and their legal equivalents.
The drawings illustrate generally, by way of example, various embodiments discussed in the present document. The drawings are for illustrative purposes only and may not be to scale.
The following detailed description of the present invention refers to subject matter in the accompanying drawings which show, by way of illustration, specific aspects and embodiments in which the present subject matter may be practiced. These embodiments are described in sufficient detail to enable those skilled in the art to practice the present subject matter. References to “an”, “one”, or “various” embodiments in this disclosure are not necessarily to the same embodiment, and such references contemplate more than one embodiment. The following detailed description is, therefore, not to be taken in a limiting sense, and the scope is defined only by the appended claims, along with the full scope of legal equivalents to which such claims are entitled.
This document concerns sintered electrodes for use in an electrical energy storage device. Specific examples include sintered anodes formed of aluminum or its alloys. Certain examples are for use in aluminum electrolytic capacitors. Additional benefits stem from an increased surface area that is a product of sintering.
Sintering results in many interstices (i.e., spaces) between grains of the electrode. Sintered electrodes resemble crushed grains with interstices between the grains. The interstices are filled with electrolyte, thereby increasing capacitance per unit of volume, as capacitance is proportional to a surface area exposed to electrolyte. An electrode with such interstices offers improved lateral or parallel movement of electrons in relation to a major surface of a flat electrode layer, as etched electrodes restrict lateral movement because the etchings result in voids that are typically perpendicular to the major surface of the flat layer. Accordingly, some examples have a lower ESR (equivalent series resistance) compared to etched foils due to this enhance ionic flow.
Overall, an energy storage device using the sintered electrodes described here is well suited for use in an implantable medical device such as a defibrillator. Because sintering can produce a variety of shapes, sintered electrodes can be used to create energy storage devices such as capacitors that have custom shapes versus simple rolled cylinders or a prism having a parallelogram as its base. Further, manufacturing efficiency is improved, by easing the steps and parts in manufacturing a capacitor and by reducing waste. The interstices are very small, making the electrodes rigid and able to withstand handling by a machine or assembly personnel. These electrodes demonstrate an improved energy density over etched electrodes and are therefore useful to make smaller implantable devices that are able to deliver an amount of energy for a particular therapy.
Electronics 104 are to monitor the patient, such as by monitoring a sensor 105, and to monitor and control activity within the system 100. In some examples, the electronics 104 are to monitor a patient, diagnose a condition to be treated such as an arrhythmia, and control delivery of a stimulation pulse of energy to the patient. The electronics 104 can be powered wirelessly using an inductor. Alternatively, the electronics 104 can be powered by a battery 106. In some examples, electronics 104 are to direct small therapeutic bursts of energy to a patient from the battery 106.
For therapies, such as defibrillation, that use energy discharge rates exceeding what battery 106 is able to provide, a capacitor 108 is used. Energy from the battery 106 is controlled by the electronics 104 to charge the capacitor 108. The capacitor 108 is controlled by the electronics 104 to discharge to a patient to treat the patient. In some examples, the capacitor 108 completely discharges to a patient, and in additional examples, the capacitor is switched on to provide therapeutic energy and switched off to truncate therapy delivery.
Some examples of a medical system 100 include an optional lead system 101. In certain instances, after implantation, the lead system 101 or a portion of the lead system 101 is in electrical communication with tissue to be stimulated. For example, some configurations of lead system 101 contact tissue with a stimulation electrode 102. The lead system 101 couples to other portions of the system 100 via a connection in a header 103. Examples of the system 101 use different numbers of stimulation electrodes and/or sensors in accordance with the needs of the therapy to be performed.
Additional examples function without a lead 101. Leadless examples can be positioned in contact with the tissue to be stimulated, or can be positioned proximal to tissue to shock the tissue to be stimulated through intermediary tissue. Leadless examples can be easier to implant and can be less expensive as they do not require the additional lead components. The housing 110 can be used as an electrode in leadless configurations.
In certain embodiments, the electronics 104 include an electronic cardiac rhythm management circuit coupled to the battery 106 and the capacitor 108 to discharge the capacitor 108 to provide a therapeutic pulse, such as a defibrillation pulse. In some examples, the system 100 includes an anode and a cathode sized to deliver a pulse of at least approximately 50 joules. Other configurations can deliver larger amounts of energy. Some configurations deliver less energy. In some examples, the energy level is predetermined to achieve a delivered energy level mandated by a governing body or standard associated with a geographic region, such as a European country. In an additional embodiment, the anode and cathode are sized to deliver a defibrillation pulse of at least approximately 60 joules. In some examples, this is the energy level is predetermined to achieve an energy level mandated by a governing body of another region, such as the United States. In some examples, electronics 104 are to control discharge of a defibrillation pulse so that the medical system 100 delivers only the energy mandated by the region in which the system 100 is used.
One characteristic of some sintered electrode examples is that at least one anode and a cathode have a DC capacitance that is approximately 23% greater than a AC capacitance for the at least one anode and the cathode of an etched capacitor that has 74.5 microfarads per cubic centimeter. In some examples, the at least one anode and the cathode have an AC capacitance of at least 96.7 microfarads per cubic centimeter at 445 total voltage. In some examples, this is comparable to an operating voltage of about 415 volts. This is a 30% improvement over an etched capacitor that has 74.5 microfarads per cubic centimeter. Total voltage is the voltage that allows 1 milliamp of leakage per square centimeter for an electrode. Some examples are aged to 415 volts.
In certain examples, the capacitor 108 includes a capacitor case 113 sealed to retain electrolyte. In some examples, the capacitor case 113 is welded. In some instances, the capacitor case 113 is hermetically sealed. In additional examples, the capacitor case 113 is sealed to retain electrolyte, but is sealed with a seal to allow flow of other matter, such as gaseous diatomic hydrogen or a helium molecule. Some of these examples use an epoxy seal. The capacitor further includes a conductor 109 coupled to one of the electrodes of the capacitor 108. The conductor 109 sealingly extends through the capacitor case to a first terminal 112 disposed on an exterior of the capacitor case 113. A second terminal 114 can be disposed on the exterior of the capacitor case 113 and in electrical communication with the other electrode of the capacitor 108. The first terminal 112 and the second terminal 114 are electrically isolated from one another.
A hermetically sealed device housing 110 is used to house components, such as the battery 106, the electronics 104, and the capacitor 108. Hermeticity is provided by welding components into the hermetically sealed device housing 110, in some examples. Other examples bond portions of the housing 110 together with an adhesive such as a resin based adhesive such as epoxy. Accordingly, some examples of the housing 110 include an epoxy sealed seam or port. Several materials can be used to form housing 110, including, but not limited to, titanium, stainless steel, nickel, a polymeric material, or combinations of these materials. In various examples, the housing 110 and the case 113 are biocompatible.
The capacitor 108 is improved by the present electrode technology in part because it can be made smaller and with less expense and a variety of shapes and configurations. The improvement provided by these electrodes is pertinent to any application where high-energy, high-voltage, or space-efficient capacitors are desirable, including, but not limited to, capacitors used for photographic flash equipment. The present subject matter extends to energy storage devices that benefit from high surface area sintered electrodes including, but not limited to, aluminum. The electrodes described here can be incorporated into cylindrical capacitors that are wound, in addition to stacked capacitors.
The present system allows for different concepts for the design of high voltage aluminum electrolytic capacitors. As will be discussed, the present system allows for reducing assembly time and cost by providing shapes that allow for ease of assembly with reduction of precise robotic assembly.
The capacitor 300 generally includes a capacitor case 301 which can be sealed to retain electrolyte and a plurality of sintered anodes 302-314. The anodes 302-314 each have a hole 317 at least partially through the sintered anode 302-314. An interconnect post, such as a threaded interconnect post 316 can be placed through the holes 317 of the plurality of sintered anodes 302-314 to electrically couple the sintered anodes. In one example, each of the holes 317 can be a threaded hole, configured to match the thread of post 316. In an example, each of the anodes 302-314 are made of sintered aluminum and the threaded post 316 is made from aluminum. This system allows the interconnection to be made between the anodes with requiring the welding of tabs or other structures. In one example, the case 301 can be cathodic. Optionally, a sintered cathode can be formed to cover the anodes with a separator there between. For example an e-spun polymer can be coated on at least a portion of the cathode. Other examples, as discussed below, can also be used.
For example, to assemble the capacitor 500, cathode material can be sintered directly to the inside surface of a capacitor case 502, the sintered cathode material forming one or more sintered cathodes 508 having a given shape. Then, the sintered anode 520 can be placed over or around the sintered cathodes 508. The sintered anode 506 can include one or more mating portions such as voids 520 that match the shape of the one or more sintered cathodes 508 such that the voids 520 matingly receive the sintered cathodes 508.
In one example, the mating portions of the sintered anode 506 can shaped like a fin and the sintered cathode 508 can have a fin shape. In one example, the void shape 520 can be conical and the sintered cathode 508 can be conical. In one example, the cathode 508 can include a bed of nails structure and a mating anode can be dropped over the bed of nails. Such shapes and structures allow for ease of assembly with lower complexity. In an example, a separator 510 can be applied to the cathode 508. For example, the separator 510 can include a high dielectric polymer directly applied to an outer surface of the sintered cathode.
As described above for
This application is intended to cover adaptations or variations of the present subject matter. It is to be understood that the above description is intended to be illustrative and not restrictive. The scope of the present subject matter should be determined with reference to the appended claims, along with the full scope of legal equivalents to which such claims are entitled.
This application claims the benefit of priority under 35 U.S.C. §119(e) of U.S. Provisional Patent Application Ser. No. 62/219,278, filed on Sep. 16, 2015, which is herein incorporated by reference in its entirety.
Number | Date | Country | |
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62219278 | Sep 2015 | US |