Claims
- 1. A composition comprising a reaction product of
a. an asymmetrical, saturated polyisocyanate that is non-cyclic, non-aromatic, and has at least 3 carbon atoms in the polyisocyanate per isocyanate group, b. a material that is at least one of
i. a primary carbamate material having at least one functional group reactive with an isocyanate and at least one primary carbamate group or a group convertible to a primary carbamate group, and ii. a reaction product of the primary carbamate material and an extending agent, and c. optionally, a chain extension agent that has at least difunctional reactivity with an isocyanate.
- 2. The composition of claim 1, wherein the functional group reactive with an isocyanate on the primary carbamate material is at least one of a hydroxyl group, an amine group, and a thiol group.
- 3. The composition of claim 1, wherein the primary carbamate material is at least one of a hydroxyalkyl carbamate, a ring opened glycerine carbonate, and an allyl alcohol reaction product.
- 4. The composition of claim 1, wherein the primary carbamate material is represented by the following structure:
- 5. The composition of claim 1, wherein the primary carbamate material is at least one of hydroxy ethyl carbamate, hydroxy propyl carbamate, and hydroxy butyl carbamate.
- 6. The composition of claim 1, wherein the extending agent is at least one of a lactone and a hydroxy carboxylic acid.
- 7. The composition of claim 1, wherein the extending agent is ε-caprolactone.
- 8. The composition of claim 1, wherein the material is a blend of the primary carbamate material and the reaction product of the primary carbamate material and the extending agent.
- 9. The composition of claim 8, wherein in the blend, the primary carbamate material is present in an amount from about 10% to about 90% based on the equivalents of carbamate groups.
- 10. The composition of claim 1, wherein in the reaction product of the primary carbamate material and the extending agent, there are from 1 to about 20 extending agents connected to each other per primary carbamate material based on an average of all reaction product molecules.
- 11. The composition of claim 1, wherein in the reaction product of the primary carbamate material and the extending agent, there are from 1 to about 3 extending agents connected to each other per primary carbamate material based on an average of all reaction product molecules.
- 12. The composition of claim 1, wherein in the reaction product of the primary carbamate material and the extending agent, there is 1 extending agent per primary carbamate material.
- 13. The composition of claim 1, wherein the asymmetrical, saturated polyisocyanate is a trimethylhexamethylene polyisocyanate.
- 14. The composition of claim 1, wherein the asymmetrical, saturated polyisocyanate is 1,8-diisocyanto-4-(isocyantomethyl)octane.
- 15. The composition of claim 1, wherein the asymmetrical, saturated polyisocyanate is at least one of a dimer of a polyisocyanate, a trimer of a polyisocyanate, a homopolymer of a polyisocyanate, and a polyurethane prepolymer of a polyisocyanate.
- 16. The composition of claim 1, wherein the chain extension agent has two functional groups reactive with an isocyanate.
- 17. The composition of claim 1, wherein the functional group reactive with an isocyanate on the chain extension agent is at least one of hydroxyl, amine, and thiol.
- 18. The composition of claim 1, wherein the chain extension agent has two hydroxyl groups.
- 19. The composition of claim 1, wherein the chain extension agent contains a heteroatom.
- 20. The composition of claim 1, wherein the chain extension agent is selected from the group consisting of 2-ethyl-1,3 hexanediol; 2-methyl-2,4-pentane diol; 2,2,4-trimethyl-1,3-pentanediol; 2,4-diethyl-1,5-octanediol; 1-hydroxymethyl cyclohexan-4-ol; 1-amino-hexan-6-ol; 2-ethyl-3N-methyl-1,3-hexane diamine; isomers of the preceding materials; 1,6-hexane diol; 1,10-decane diol; 2-methyl-1,6-hexane diol; 3-methyl-1,10-decane diol, and mixtures thereof.
- 21. The composition of claim 1, wherein the chain extension agent is asymmetrical.
- 22. The composition of claim 1, wherein the primary carbamate material is asymmetrical.
- 23. The composition of claim 1, wherein the extending agent is asymmetrical.
- 24. The composition of claim 1, wherein the primary carbamate material, the extending agent, and the chain extension agent are each asymmetrical.
- 25. The composition of claim 1, wherein the primary carbamate material is a mixture of isomers.
- 26. The composition of claim 1, wherein the primary carbamate material is a mixture of isomers and is asymmetrical.
- 27. The composition of claim 1, wherein the reaction product is soluble in at least one of an aliphatic solvent, aromatic solvent, a ketone solvent, an alcohol, and an ester solvent.
- 28. The composition of claim 1, wherein the reaction product has a Tg of less than or equal to about 30° C.
- 29. The composition of claim 1, wherein a ratio of urethane structures to ester structures in the reaction product is at least 2:1.
- 30. The composition of claim 1, wherein a ratio of urethane structures to ester structures in the reaction product is 4:1.
- 31. The composition of claim 1, wherein the reaction product has a structure represented by one of:
a. (material)-(polyisocyanate)-(material), b. (material)-(asymmetrical, saturated polyisocyanate)-(chain extension agent-asymmetrical, saturated polyisocyanate)m-(material), wherein m is any number that is at least 1 and is based on an average of all reaction products, wherein carbamate groups of the material are terminal ends of the reaction product.
- 32. The composition of claim 1, wherein the reaction product has a number average molecular weight of about 464 to about 4000.
- 33. The composition of claim 1 further comprising a polymer that is at least one of an acrylic, a vinyl, a polyurethane, a polycarbonate, a polyester, an alkyd, and a polysiloxane.
- 34. A method for forming the composition of claim 1 comprising reacting the asymmetrical, saturated polyisocyanate, the material, and optionally the chain extension agent.
- 35. The method of claim 34, wherein the reacting is one of
a. reacting the polyisocyanate, the chain extension agent, and the material together in one reaction, b. reacting the polyisocyanate with the chain extension agent to form a reaction product A, and then reacting reaction product A with the material, and c. reacting the material with the polyisocyanate to form a reaction product B, and then reacting reaction product B with the chain extension agent.
- 36. A coating composition comprising the composition of claim 1.
- 37. The coating composition of claim 36 further comprising at least one of a crosslinker, a solvent, a catalyst, a surfactant, a filler, a stabilizer, a wetting agent, a dispersing agent, an adhesion promoter, a UV absorber, a hindered amine light stabilizer, a coloring agent, and an additional polymer.
- 38. The coating composition of claim 37 wherein the crosslinker is an aminoplast.
- 39. A method comprising applying the coating composition of claim 36 to a substrate.
- 40. A coating prepared from the coating composition of claim 36.
- 41. The coating of claim 40, wherein the coating is at least one of a primer, a base coat, a top coat, a clearcoat, and a laminate.
- 42. The coating of claim 40, wherein the coating has flex of from about 8 to about 10 as measured by General Motors GM9503P.
- 43. The coating of claim 40, wherein the coating has an etch of from about 2 to about 8 as measured by General Motors World Specification GM W-3005 paragraph 5.15.
CROSS-REFERENCE TO RELATED APPLICATIONS
[0001] This application is a non-provisional application of U.S. Serial No. 60/341,470 filed on Dec. 17, 2001, which is incorporated herein by reference.
Provisional Applications (1)
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Number |
Date |
Country |
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60341470 |
Dec 2001 |
US |