Patent Grant
8247366
1. Field of Invention
The present invention is directed to azeotrope-like compositions. More particularly, the invention is directed to azeotrope-like compositions comprising a hydrofluoroolefin and hydrogen fluoride.
2. Description of the Prior Art
Many azeotropes possess properties that make them useful as solvents. For example, azeotropes have a constant boiling point that avoids boiling temperature drift during processing and use. In addition, when an azeotrope is used as a solvent, the properties of the solvent remain constant because the composition of the solvent does not change during boiling or reflux. Azeotropes that are used as solvents also can be recovered conveniently by distillation.
However, the identification of new, environmentally-safe, non-fractionating mixtures that are commercially useful is complicated due to the fact that azeotrope formation is not readily predictable. Therefore, industry is continually seeking new azeotrope and azeotrope-like mixtures. This invention satisfies these needs among others.
A heteroazeotrope-like composition has been found that consists essentially of 1,1,2,3-tetrachloropropene (TCP) and hydrogen fluoride (HF). This azeotrope-like composition is useful as a solvent in various applications, such as removing surface oxidation from metals. Moreover, this azeotrope-like composition is useful as an intermediate in the synthesis of certain hydrofluoroolefins, such as HFO-1234yf.
Accordingly, provided is an azeotrope-like composition consisting essentially of 1,1,2,3-tetrachloropropene and hydrogen fluoride.
In another aspect of the invention, provided is a method for forming an azeotropic or azeotrope-like composition comprising blending hydrogen fluoride with 1,1,2,3-tetrachloropropene at a temperature of from about 0° C. to about 60° C. and at a pressure of about 7 psia to about 58 psia to produce an azeotrope-like mixture consisting essentially of about 1 to about 95 weight percent hydrogen fluoride and from about 5 to about 99 weight percent 1,1,2,3-tetrachloropropene.
In yet another aspect of the invention, provided is a solvent comprising an azeotrope-like composition consisting essentially of 1,1,2,3-tetrachloropropene and hydrogen fluoride.
In another aspect of the invention, provided is a sprayable composition comprising an azeotrope-like composition consisting essentially of 1,1,2,3-tetrachloropropene and hydrogen fluoride.
And in other aspect of the invention, provided is a method for removing surface oxidation from a substrate comprising contacting an oxidized surface of a metal substrate with a solvent comprising the novel azeotrope-like compositions described herein under conditions effective to remove an amount of metal oxides from said surface
The present invention provides compositions which comprise hydrogen fluoride (HF) and 1,1,2,3-tetrachloropropene (TCP) in amounts effective to form an azeotrope-like composition, as well as methods involving such azeotrope-like compositions. In certain preferred embodiments, these azeotrope-like compositions are binary azeotropes which consist essentially of combinations of only hydrogen fluoride with TCP.
As used herein, the term “azeotrope-like” relates to compositions that are strictly azeotropic and/or that generally behave like azeotropic mixtures. An azeotropic mixture is a system of two or more components in which the liquid composition and vapor composition are equal at the stated pressure and temperature. In practice, this means that the components of an azeotropic mixture are constant-boiling or essentially constant-boiling and generally cannot be thermodynamically separated during a phase change. The vapor composition formed by boiling or evaporation of an azeotropic mixture is identical, or substantially identical, to the original liquid composition. Thus, the concentration of components in the liquid and vapor phases of azeotrope-like compositions change only minimally, if at all, as the composition boils or otherwise evaporates. In contrast, boiling or evaporating non-azeotropic mixtures changes the component concentrations in the liquid phase to a significant degree.
As used herein, the terms “heteroazeotrope” and “heterogeneous azeotrope” mean an azeotrope-like composition comprising a vapor phase concurrently with two liquid phases.
As used herein, the term “consisting essentially of”, with respect to the components of an azeotrope-like composition, means the composition contains the indicated components in an azeotrope-like ratio, and may contain additional components provided that the additional components do not form new azeotrope-like systems. For example, azeotrope-like mixtures consisting essentially of two compounds are those that form binary azeotropes, which optionally may include one or more additional components, provided that the additional components do not render the mixture non-azeotropic and do not form an azeotrope with either or both of the compounds (e.g., do not form a ternary azeotrope).
The term “effective amounts” as used herein refers to the amount of each component which, upon combination with the other component, results in the formation of an azeotrope-like composition of the present invention.
The term “dispensed form” as used herein refers to a physical form of a fluid as it is spread, distributed, and/or diffused over an area or through a volume. Examples of dispensed forms include aerosols and sprays.
In certain preferred embodiments, the azeotrope-like composition contains from about 1 to about 95 weight percent HF and from about 5 to about 99 weight percent TCP, more preferably from about 5 weight percent to about 95 weight percent HF and from about 5 weight percent to about 95 weight percent TCP, most preferably from about 55 weight percent to about 95 weight percent HF and from about 5 weight percent to about 45 weight percent TCP.
The composition of the present invention preferably has a boiling point of from about 0° C. to about 60° C. at a pressure from about 7 psia to about 58 psia. For example, a preferred azeotrope-like composition consists essentially of about 95±2 weight percent HF and about 9±2 weight percent TCP and has a normal boiling point of about 23° C.
The azeotrope-like compositions of the present invention can be produced by combining effective amounts of TCP with HF. Any of a wide variety of methods known in the art for combining two or more components to form a composition can be adapted for use in the present methods. For example, TCP and HF can be mixed, blended, or otherwise combined by hand and/or by machine, as part of a batch or continuous reaction and/or process, or via combinations of two or more such steps. In light of the disclosure herein, those of skill in the art will be readily able to prepare azeotrope-like compositions according to the present invention without undue experimentation.
In another embodiment of the invention, the azeotrope-like compositions described herein can be used as a solvent, particularly a cleaning solvent. In certain embodiments, the solvent is contacted with an oxidized surface of a metal substrate to remove or reduce at least a potion of the oxidized surface. Such solvents may be applied to the targeted substrate via any means known in the art, such as dipping, spraying, wiping, and the like.
In certain preferred embodiments, provided is a sprayable composition comprising the novel azeotrope-like compositions described herein. In certain embodiments, the sprayable composition is an aerosol. In certain the sprayable composition further comprises other components such as inert ingredients, co-solvents, propellants, co-propellants, and the like.
In certain embodiments, the novel azeotrope-like compositions described herein are useful intermediates derived from during synthesis of certain hydrofluoroolefins, such as 2,3,3,3-tetrafluoropropene (HFO-1234yf). For example, where TCP and HF are introduced into a reactor during a HFO-1234yf synthesis reaction, at least a portion of these components form an azeotrope which subsequently can be recovered from the associated reaction product stream.
In certain embodiments, method for reducing the boiling point of a hydrochloropropane is provided wherein the method comprises blending effective amounts of TCP and HF to form an azeotrope-like mixture consisting essentially of TCP and HF. Lowering the boiling point of TCP is advantageous when the TCP is used as a reactant in a vapor phase fluorination reaction. More particularly, lowering the boiling point facilitates vaporization of the compound and, thus, helps prevent decomposition of the compound and also reduces the amount of energy required by the fluorination process.
Accordingly, also provided is a method for fluorinating an organic compound comprising (a) providing an azeotrope-like composition consisting essentially of TCP and HF; and (b) reacting at least a portion of said TCP in the vapor phase with a fluorinating agent to produce at least one fluorinated organic compound, preferably a hydrofluoroolefin, more preferably a tetrafluoropropene, and even more preferably a 2,3,3,3-tetrafluoropropene.
The invention is further illustrated in the following example which is intended to be illustrative, but not limiting in any manner.
Approximately 9 g of 1,1,2,3-tetrachloropropene (TCP) was blended in 91 g of HF to at about 25° C. and about 14.6 psia. The formation of a heterogeneous azeotrope-like composition was observed.
TCP and HF were blended to form heterogeneous azeotrope mixtures at different compositions. The vapor pressures of the mixtures are measured at about 0, 25, and 60° C. The results of these measurements are provided in Table 1.
The data in Table 1 demonstrates that these mixtures exhibit azeotrope-like characteristics since the vapor pressures of mixtures of TCP and HF are higher, at all indicated blend proportions, than TCP and HF alone, i.e. as indicated in the first and last rows when HF is 0.0 wt. % and TCP is at 100.0 wt % as well as when TCP is at 0.0 wt. % and HF is at 100.0 wt. %.
The data from Table 1 is depicted graphically in
This example demonstrates the azeotropic-like properties of TCP/HF mixtures via Vapor-Liquid—Liquid Equilibrium (VLLE).
Approximately 14.4 g of 1,1,2,3-tetrachloropropene (TCP) was blended with 15.7 g of HF to form, upon visual observation, a heterogeneous mixture at 23° C. A second mixture of 53 wt % TCP and 47 wt % HF was prepared. The vapor compositions of the two mixtures were sampled at room temperature of 23° C. The result shows that the weight percent of HF in the vapor of mixture 1 is 90.9, and the weight percent of HF in the vapor of mixture 2 is 91.5. Accordingly, an azeotrope-like composition was formed having about 91±2 wt. % HF at 23° C.
This application is a Divisional of U.S. application Ser. No. 12/607,802, filed on Oct. 28, 2009 (now pending) which claims priority benefit of U.S. Provisional Application No. 61/110,227, filed Oct. 31, 2008, each of which is incorporated herein by reference.
| Number | Name | Date | Kind |
|---|---|---|---|
| 4535194 | Woodard | Aug 1985 | A |
| 4650914 | Woodard | Mar 1987 | A |
| 5206367 | Urban | Apr 1993 | A |
| 5811603 | Elsheikh | Sep 1998 | A |
| 5811605 | Tang et al. | Sep 1998 | A |
| 5877359 | Elsheikh | Mar 1999 | A |
| 5969198 | Thenappan et al. | Oct 1999 | A |
| 6013846 | Wismer et al. | Jan 2000 | A |
| 6166274 | Chen et al. | Dec 2000 | A |
| 6198010 | Yoshikawa et al. | Mar 2001 | B1 |
| 6235951 | Sakyu et al. | May 2001 | B1 |
| 6316681 | Yoshikawa et al. | Nov 2001 | B1 |
| 7795480 | Merkel et al. | Sep 2010 | B2 |
| 8008243 | Tung et al. | Aug 2011 | B2 |
| 20020143215 | Tung et al. | Oct 2002 | A1 |
| 20050085674 | Nakada et al. | Apr 2005 | A1 |
| 20050101810 | Owens et al. | May 2005 | A1 |
| 20070007488 | Singh et al. | Jan 2007 | A1 |
| 20090030244 | Merkel et al. | Jan 2009 | A1 |
| 20090224207 | Pham et al. | Sep 2009 | A1 |
| 20090227822 | Pham et al. | Sep 2009 | A1 |
| 20090256110 | Merkel et al. | Oct 2009 | A1 |
| 20090287027 | Merkel et al. | Nov 2009 | A1 |
| 20100113322 | Tung et al. | May 2010 | A1 |
| 20100185030 | Elsheikh et al. | Jul 2010 | A1 |
| 20100191025 | Perdrieux | Jul 2010 | A1 |
| 20110004035 | Merkel et al. | Jan 2011 | A1 |
| Number | Date | Country | |
|---|---|---|---|
| 20110287996 A1 | Nov 2011 | US |
| Number | Date | Country | |
|---|---|---|---|
| 61110227 | Oct 2008 | US |
| Number | Date | Country | |
|---|---|---|---|
| Parent | 12607802 | Oct 2009 | US |
| Child | 13198162 | US |
