The present invention relates generally to the carbonation of fluids, and more particularly to the use of backward-facing steps for initiating the carbonation of fluid in an aquaculture, such as an algae cultivation pond.
Provided herein are exemplary systems, methods and media for carbonation of fluid in an algae cultivation pond via the use of backward-facing steps. In a first aspect, a method for initiating carbonation of a fluid flow in an algae cultivation pond is disclosed. Fluid flow is initiated over a backward-facing step in the algae cultivation pond. A backflow region is generated in the fluid flow downstream of the backward-facing step. Carbon dioxide is provided to the backflow region.
In a second aspect, a system for initiating carbonation of a fluid flow in an algae cultivation pond is disclosed. The system includes a step forming a portion of a pond bed of an algae cultivation pond. The system further includes a gas diffuser coupled to the pond bed of the algae cultivation pond downstream of the step. The gas diffuser is configured to introduce carbon dioxide in gas form into the fluid flow.
In a third aspect, a system for initiating carbonation of fluid in an algae cultivation pond is disclosed. The system includes a step forming a portion of a pond bed of the algae cultivation pond. The system further includes a nozzle coupled to a pressurized fluid source a carbonation source, and the step. The nozzle is configured to generate a jet of carbonated fluid from the pressurized fluid source and the carbonation source.
In a fourth aspect, a system for initiating carbonation of fluid in an algae cultivation pond is disclosed. The system includes a step forming a portion of a pond bed of the algae cultivation pond. The system includes a carbonation input forming a portion of the pond bed of the algae cultivation pond downstream of the step. The carbonation input is configured to release carbon dioxide into the fluid flow. The system includes a pH sensor. The system includes a processor and a computer-readable storage medium having embodied thereon a program executable by the processor to perform a method for adjusting a concentration of carbon dioxide in the algae cultivation pond. The computer-readable storage medium is coupled to the processor. The processor executes instructions on the computer-readable storage medium to measure a pH associated with the fluid in the algae cultivation pond via the pH sensor and initiate the release of carbon dioxide from the carbonation input based on the measured pH.
The methods described herein may be performed via a set of instructions stored on storage media (e.g., computer readable media). The instructions may be retrieved and executed by a processor. Some examples of instructions include software, program code, and firmware. Some examples of storage media comprise memory devices and integrated circuits. The instructions are operational when executed by the processor to direct the processor to operate in accordance with embodiments of the present invention. Those skilled in the art are familiar with instructions, processor(s), and storage media.
Provided herein are exemplary systems, methods and media for providing carbon dioxide to fluid in an algae cultivation pond. The fluid in the algae cultivation pond, e.g., algae cultivation pond fluid, may provide dissolved nutrients and/or raw materials to algae suspended therein. For instance, algae cultivation pond fluid may be composed of a mixture of fresh water and seawater, nutrients to promote algae growth, dissolved gases, disinfectants, waste products, and the like. Algal uptake of carbon dioxide dissolved in the algae cultivation pond fluid may facilitate photosynthesis, resulting in the accumulation of products such as algal biomass, lipids, and oxygen. The algae cultivation pond may exploit the natural process of photosynthesis in order to produce algae for high-volume applications, such as the production of biofuels.
The systems, methods, and media disclosed herein make use of a step forming a portion of the algae cultivation pond bed in a channel of an algae cultivation pond. The step may be referred to as backward-facing since the depth of the algae cultivation pond increases immediately downstream of the step. The step as referred to in this disclosure may be a backward-facing step, a rearward-facing step, and/or a backstep.
Fluid flow incident to a backward facing step may undergo boundary layer separation. Some of the fluid flow maintains characteristics of fluid flow upstream to the step, for instance, bulk flow may be maintained in the original direction of fluid flow.
Separation of the boundary layer, however, may result in flow separation, which leads to substantially different mean (e.g., bulk flow) characteristics and turbulent flow characteristics. A portion of the fluid flow in the algae cultivation pond may flow in a reverse and/or alternate direction from the direction of bulk fluid motion in the algae cultivation pond. This flow may be referred to as a backflow, and a region in which such reverse flow may be observed in the algae cultivation pond may be referred to as a backflow region. The backflow region may be located immediately downstream of the backward-facing step. The backflow region as referred to in this disclosure may include, for instance a recirculation region, a closed flow loop, a separation bubble, a dynamic bubble, and/or the like. For the purposes of the present disclosure, the ‘backflow region’ is considered to be distinct and separate from bulk motion of fluid in the algae cultivation pond, and the corresponding behaviors that may be observed in the bulk flow, e.g., circulation.
The backflow may further contact a surface of the step, which may induce further forward movement of the backflow. Thus, fluid flow may be captured in a closed flow loop immediately downstream of the backward-facing step. Fluid from the bulk fluid flow may be exchanged with fluid from the backflow region. Therefore, the backflow region may include reverse flow due to the separation of the boundary layer, as well as the flow that results when the backflow contacts a surface of the step and is re-oriented in the direction of the bulk flow.
Due to the presence of the step, the flow in the backflow region may become unsteady as a result of unsteady periodic vortex shedding due to the presence of the step. The backflow region may therefore result in the formation of one or more coherent structures (also termed ‘coherent vortices’ herein) along the width of the channel downstream of the step. The coherent structure may be substantially elliptical in shape and measure, at its greatest diameter, approximately six times to eight times the height of the step. However, the coherent structure may be dynamic in that it contracts, expands, shifts location in any or all directions, or any combination thereof, based on variations in the bulk flow.
The backflow region may interface with the bulk flow via a dividing streamline in a dividing streamline region. The dividing streamline may form a portion of the boundary layer downstream of the backward-facing step. The region in which the dividing streamline interfaces the pond bed downstream of the backward-facing step may be referred to as a reattachment region of the boundary layer of the fluid flow.
The carbon dioxide consumed during algal photosynthesis may be introduced in the algae cultivation pond based on a location of a step in an algae cultivation pond. Carbon dioxide may be introduced in a region of the algae cultivation pond via one or carbonation inputs. Carbonation inputs may include, for instance, gas diffusers, venturi nozzles, and/or the like. Carbonation inputs may be placed in a variety of configurations (e.g., arrays) downstream of the step. In some embodiments, the carbonation inputs form a portion of the algae cultivation pond bed. The position of the carbonation inputs relative to the location of the step may be determined based on various parameters of the step, such as step height, flow characteristics (e.g. flow velocity), and/or the type of carbonation input. The carbonation inputs may be placed in various configurations in the channel, as is described more fully herein.
Additionally, the carbonation inputs may be coupled to the backward-facing step. The carbonation inputs coupled to the step may issue jets of carbonated fluid, which in some instances may entrain a co-flow of fluid in the algae cultivation pond. The jet entrainment may promote the diffusion and/or advection of carbon dioxide into the algae cultivation pond fluid, yielding a substantially homogeneous mixture downstream from the jets. The resultant flow associated with one or more jets, i.e. jet flow, may induce bulk movement of fluid in the algae cultivation pond, i.e. circulation, or pond flow.
Introducing carbon dioxide to algae cultivation pond fluid, i.e. carbonation, in conjunction with a step may present benefits. Increases in turbulent kinetic energy may result in a turbulent boundary layer at the algal cell and enhance the rate of mass transfer to algal cells, thereby enhancing the uptake of carbon dioxide, in addition to other nutrients. The presence of a backflow region may impede the development of undesirable concentration gradients in the algae cultivation pond fluid.
The separation of flow over the step may enhance the dissolution of carbon dioxide into the algae cultivation pond fluid. The separation of flow induces the formation of coherent structures, which are characterized by high magnitude of vorticity, consistent structure, and periodic nature. The breakdown of these coherent vortices into smaller eddies—fluctuations of fluid flow random in time and structure—may enhance mixing of algae cultivation pond fluid in the backflow region and even downstream of the backflow region. Such enhanced mixing promotes a higher level of carbon dioxide dissolution in the algae cultivation pond fluid, thereby reducing or even eliminating carbon dioxide dissipation into the surrounding environment.
The elements discussed herein may be coupled to one another via paths 105-185, and paths 105-185 represent exemplary relationships between elements 110-180 in the pond carbonation system 100. The paths may represent, for instance, electronic communication between elements. Additionally, the paths may represent physical paths, such as piping, among elements 110-180. Contents that may be transferred in the pond carbonation system 100 may include, for instance, algae cultivation pond fluid, algae suspension, water, carbon dioxide, algae biomass, or any combinations thereof. One skilled in the art will likewise recognize that the any number of paths 15-185 may be present in the pond carbonation system 100.
In some embodiments, fluid distribution system 110 may provide algae cultivation pond fluid to the pond 140 via the path 115. The fluid distribution system may introduce and/or initiate circulation in the algae cultivation pond 140 by initiating bulk fluid flow in one or more regions of the pond 140. These regions may be referred to as circulation regions of the pond 140. The bulk fluid flow generated in the circulation region may be sustained far downstream. Algae cultivation pond fluid may be introduced to the pond 140 via an intake (not shown in
The fluid distribution system 110 may include, for instance, a paddle wheel system, a jet circulation system, or any combinations thereof. The jet circulation system is detailed further in U.S. patent application Ser. No. 12/485,862. Components of the fluid distribution system 110 may be located in the pond 140, despite not being shown in
Carbon dioxide is provided to the pond carbonation system 100 from the carbonation source 130. The carbonation source 130 may be, for instance, a power plant, a steel mill, a concrete mill, a byproduct of a chemical reaction, or any combination of these. The carbonation source 130 may provide pure carbon dioxide in gaseous form or a mixture of gases including carbon dioxide. Carbon dioxide may be provided to the pond 140 via path 135 as shown in
The pond carbonation system 100 may be used to cultivate algae for large volume applications, such as in the production of biofuels. The pond carbonation system 100 as such may be coupled to, for example, a harvesting system 150 and/or an extraction system 170. Algae may be harvested periodically from the pond 140. While harvesting is taking place, algae cultivation pond fluid may be routed from the pond 140 via a path 145. Upon harvesting, algae biomass may be routed to an extraction system 170 and algae cultivation pond fluid may be routed to the make-up 180 and/or the fluid distribution system 110 via paths 155 and 185 respectively. Alternatively, the algae cultivation pond fluid may be discarded (not shown in
In order to maintain a desired level of algae cultivation pond fluid, a harvesting bypass 160 may be available in pond carbonation system 100. The harvesting bypass 160 may include an overflow component, which may act as a reservoir for surplus algae cultivation pond fluid (overflow component not shown in
Components may be added to pond carbonation system 110 based on conditions that may play a role in algae cultivation and/or the needs of the particular genus or species of algae being cultivated. For instance, algae cultivation ponds having several acres of exposed surface area may lose large quantities of water via evaporation to the surrounding environment. Evaporation therefore may change concentrations of carbon dioxide, various nutrients and/or disinfectants in the algae cultivation pond fluid, and/or the pond temperature. In order to maintain desired concentrations of these nutrients and/or disinfectants, a make-up 180 may be available in pond carbonation system 100. The make-up 180 may introduce additional fresh water, seawater, disinfectants, and/or nutrients such as Aqua Ammonia, Phosphorous solutions, and trace metals, such as Co, Zn, Cu, Mn, Fe and Mo in appropriate concentrations. In some embodiments, the make-up 180 may draw fluid from the harvesting bypass 160 via the path 185.
The fluid distribution system 110, the carbonation source 130, the pond 140, the harvesting system 150, the harvesting bypass 160, the extraction 180, and the make-up 190 may be coupled to, controlled by and/or otherwise monitored by the control center 120. The control center 120 may include any number of components, i.e. sensors, gauges, probes, control valves, servers, databases, clients, and any combination of these (not shown in
In order to measure pH in the pond 140, the control center 120 may include a plurality of pH probes (not shown in
The control center 120 may store and/or execute software programs and/or instructions in order to take action based on the measured parameters. For instance, a software module associated with the control center 120 can be executed to compare measured parameters from the pond 140 to a desired set of parameters. If the measured parameters are not within a predetermined range of the desired set of parameters (e.g., within ten percent), the control center 120 can execute a software module (e.g., a software routine or code), to adjust the operation of any of the fluid distribution system 110, the pond 140, the harvesting system 150, the harvesting bypass 160, the extraction 170, and the make-up 180 in order to bring the measured parameters within the predetermined ranges.
For instance, a desired set of parameters may be set by a user of the control center 120 (via user input). An exemplary pH range may be set by a user, for instance, between 7.4 to 8.0. If the measured pH is lower than 7.4, the control center 120 may automatically provide instructions to the carbonation source 130 to discontinue providing carbon dioxide to the pond 140. Additionally, the control center 120 may provide instructions to the fluid distribution system 110 to and increase the intake of algae cultivation pond fluid from make-up 180 until the measured pH is in line with the predefined parameters. Alternatively, if the measured pH is found to be higher than 8.0, then the control center 120 may automatically provide carbon dioxide to the pond 140.
The pond 140 includes an outer wall 210 and divider 220, forming two channels 230 on either side of the divider 220. In some embodiments, the divider 220 may be located in the center of the pond 140, forming channels of substantially equal width in the pond 140. Alternatively, the divider 220 may be located off-center such that one of the two channels 230 is wider. The pond 140 may include one or more step regions 242 including one or more steps 142. A step 142 may be constructed along the width and/or along a portion of the width of the pond bed as indicated in
The pond 140 includes one or more steps 142. A step 142 may form a portion of the pond bed (shown in
As shown in
Fluid flow in the step region 242, upon being incident to a step 142, may undergo flow separation. While a portion of the fluid flow may maintain characteristics of the bulk fluid flow upstream of the step region 242, a portion of the bulk fluid may flow in a reverse and/or alter direction from the direction of bulk fluid motion in the algae cultivation pond. The portion of flow which may reverse and/or change direction may be referred to as a backflow, is discussed further in the context of
A carbonation input 240 may be located immediately downstream of the step 142. Carbonation inputs 240 may be coupled to one or more carbonation sources, such as the carbonation source 130 discussed in the context of
Presence of the step 142 in the pond 140 initiates flow separation in the bulk flow. As mentioned earlier, when the flow is incident to the step 142, boundary layer separation may occur, thereby inducing flow separation. A portion of the flow immediately downstream of the step may possess characteristics of the bulk flow upstream of the step. This flow is represented in
A portion of the flow immediately downstream of the step may reverse or otherwise proceed in a direction alternate to the bulk flow (e.g., in a direction contrary to that indicated by the arrow 370). This reverse flow, indicated by the streamline 355, may form a backflow region 350 which is represented by the dashed line shown in
The backflow region 350 may form a region that is distinct from the bulk flow along the step 142 and/or across the width of the channel 230. Contact of the bulk flow with the tip 142a of the step 140 generates a velocity gradient and high Reynolds stress in the vicinity of the tip 142a. The high Reynolds stresses correspond to the production of turbulence in the vicinity of the step 142, and sustained turbulent flow downstream of the step 142.
The bulk fluid flow and the backflow downstream of the step 142 are dynamic and unsteady processes (e.g., not steady with respect to time). Thus, the size and position of the backflow region 350 may change with time, despite being represented by a time-averaged profile and position. For instance, the backflow region 350 may contract or expand, alter in shape, and/or drift spatially in any direction with respect to the time-averaged profile and/or position. Since the backflow region 350 may be dynamic in nature, the time-averaged position and/or profile of the reattachment region 330 may vary in accordance with variations in the backflow region 350.
Any number of gas diffusers 340 may be positioned in various configurations in the step region 242. For instance, diffusers 340 may be organized in an array forming a portion of the pond bed 320 along the width of the channel 230. Alternatively, the diffusers 340 may be coupled to the pond bed 320 in a dynamic array which may be controlled by execution of software modules at the control center 120 (as discussed in the context of
Further, any amount and concentration of carbon dioxide may be provided to the backflow region 350 by the gas diffuser 340. For instance, carbon dioxide may be released in gas form from the gas diffuser 340 at a rate of approximately 2.2 to 2.9 standard cubic feet per hour per meter of a channel width associated the backflow region 350. The channel width, for instance, may be determined based on the characteristics of the channel 230 as disclosed in the context of
Upon release of carbon dioxide into the backflow region 350, the carbon dioxide is dissolved into solution. Any carbon dioxide that remains in gas form may be captured by the closed flow loop of the backflow region 350. The turbulence generated in the bulk flow by the backflow region 350 increases the rate of mass transfer of carbon dioxide to the algae cultivation pond fluid, thereby maximizing the efficiency associated with the dissolution of carbon dioxide and minimizing the loss of carbon dioxide to the surrounding environment.
In the embodiment illustrated in
The height of the step may determine characteristics of the backflow region 350, such as a time-averaged position of the backflow region 350, time-averaged profile of the backflow region 350, and the like. The height of the step may also determine the location of the reattachment region 330 of the boundary layer. In some embodiments, the approximate location of the reattachment region 330 as measured downstream from the step 142 may be determined by the following relation:
location of reattachment region≈step height*n
where n is a dimensionless constant ranging between approximately 5 to approximately 10.
The configurations of carbonation inputs 240 in the step region 242 may exploit the conditions generated by the step 142 in the pond 140. The height of the step 142 may play a significant role in determining positions for carbonation inputs 240 that enhance carbonation efficiency and minimize loss of carbon dioxide into the surroundings. For instance, carbonation inputs 240 may be positioned such that carbon dioxide is provided directly to the backflow region 350. Alternatively, carbonation inputs 240 may be positioned such that carbon dioxide is provided to the bulk flow of algae cultivation pond fluid as described in the context of
The control center 120 may measure carbon dioxide concentrations in any of the aforementioned regions in the step region 242. In some embodiments, the control center 120 may execute a software module to simulate the pH profile of the algae cultivation pond fluid using as inputs, for instance, the height of the step 142, flow characteristics of the algae cultivation pond fluid (e.g., flow velocity, flow rate), and initial carbon dioxide concentrations. The control center 120 may then determine the mean position of the backflow region 350, the mean profile of the backflow region 350, the reattachment region 330 and/or the mean position of the dividing streamline 360 (e.g. a dividing streamline region) and provide carbon dioxide accordingly.
The nozzles 640 may also provide carbon dioxide in solution to the step region 242. For instance, carbon dioxide may be mixed with algae cultivation pond fluid at the carbonation source 130. The algae cultivation pond fluid may be received from one of the harvesting system 150, the harvesting bypass 160, the make-up 180, or any combination thereof (path not shown in
Various parameters corresponding to the nozzle 640 may be controlled, adjusted, and/or otherwise manipulated at the control center 120 by execution of a software module. Parameters that may be controlled include, but are not limited to nozzle position, frequency of nozzle discharge, location of discharge, direction and/or angle of discharge (e.g., discharge directed upstream or downstream). The nozzle 640 may be configured to discharge in the backflow region 350. In some embodiments, these parameters may be manipulated by user input to the control center 120.
As shown in
Pure carbon dioxide was provided to the algae cultivation pond in experiments conducted by the inventors. In a first experiment, the pure carbon dioxide was introduced to the algae cultivation pond fluid by venturi nozzles in a ratio of approximately 200 mg of pure carbon dioxide per gallon of algae cultivation pond fluid. The mixture was then introduced into the pond which resulted in no loss of carbon dioxide to atmosphere. In a second experiment, pure carbon dioxide was provided by a diffuser at a rate of approximately 2.2 to approximately 2.9 standard cubic feet per hour per meter of a channel width associated with the backflow region.
In step 710, fluid flow is generated in an algae cultivation pond. Fluid flow may be generated, for instance, by the fluid distribution system 110 in the pond 140. As mentioned earlier, the fluid distribution system 110 may include, for instance, a paddle wheel and/or a jet circulation system as disclosed in the context of U.S. patent application Ser. No. 12/485,862. Various components of the fluid distribution system 110 may be present in the pond 140 in order to generate fluid flow.
In step 720, a backflow region is generated in the fluid flow. The backflow region 350 as shown in
In step 730, a location in which to measure carbon dioxide is selected. Step 730 may, for instance, be selected by the control center 120 upon execution of a software module. The software module may determine, for instance, a mean position region in the backflow region 350 in the fluid flow, as indicated by the dashed line in
In step 740, a concentration of carbon dioxide in the selected location may be determined. Step 740 may be conducted by, for instance, the control center 120 via execution of a software module configured to receive data from a pH sensor in the pond 140. In some embodiments, the control center 120 may provide measurements corresponding to carbon dioxide concentration for display on a display device associated with the control center 120. Alternatively, the control center 120 may generate a report and/or generate a log event in a database associated with the control center 120.
In step 750, a determination as to whether further carbon dioxide should be provided to the location may be made. Step 750 may be conducted by the control center 120. For instance, the control center 120, via execution of a software program, may determine whether the measurements from the pH sensor correspond to acceptable carbon dioxide concentrations for the selected region.
If the carbon dioxide concentration is determined in step 750 to be outside of acceptable ranges, then the control center 120 may transmit instructions to the carbonation source 130 to discontinue providing carbon dioxide to the algae cultivation pond fluid. Alternatively, if the carbon dioxide concentration determined in step 750 is determined to be within acceptable ranges, further carbon dioxide may be provided to the algae cultivation pond fluid in step 760 via the carbonation inputs 240.
The above-described functions and/or methods may include instructions that are stored on storage media. The instructions can be retrieved and executed by a processor. Some examples of instructions are software, program code, and firmware. Some examples of storage media are memory devices, tapes, disks, integrated circuits, and servers. The instructions are operational when executed by the processor to direct the processor to operate in accord with the invention. Those skilled in the art are familiar with instructions, processor(s), and storage media. Exemplary storage media in accordance with embodiments of the invention are discussed in the context of, for example, the control center 120 of
The computing system 800 of
The components shown in
Mass storage device 830, which can be implemented with a magnetic disk drive or an optical disk drive, is a non-volatile storage device for storing data and instructions for use by processor unit 810. Mass storage device 830 can store the system software for implementing embodiments of the present invention for purposes of loading that software into main memory 820.
Portable storage device 840 operates in conjunction with a portable non-volatile storage medium, such as a floppy disk, compact disk or Digital video disc, to input and output data and code to and from the computer system 800 of
Input devices 860 provide a portion of a user interface. Input devices 860 may include an alpha-numeric keypad, such as a keyboard, for inputting alpha-numeric and other information, or a pointing device, such as a mouse, a trackball, stylus, or cursor direction keys. Additionally, the system 800 as shown in
Display system 870 may include a CRT, a liquid crystal display (LCD) or other suitable display device. Display system 870 receives textual and graphical information, and processes the information for output to the display device.
Peripherals 880 may include any type of computer support device to add additional functionality to the computer system. For example, peripheral device(s) 880 may include a modem or a router.
The components contained in the computer system 800 of
Upon reading this paper, it will become apparent to one skilled in the art that various modifications may be made to the systems, methods, and media disclosed herein without departing from the scope of the disclosure. As such, this disclosure is not to be interpreted in a limiting sense but as a basis for support of the appended claims.
The present application is related to U.S. patent application Ser. No. 12/485,862 titled “Systems, Methods, and Media for Circulating Fluid in an Algae Cultivation Pond,” filed on Jun. 16, 2009.