This invention relates to forming or securing fiber strands in sheet form and, more particularly, to forming or securing fiber strands in sheet form for use in a ballistic-resistant laminate.
Unidirectional fiber materials are used in ballistic-resistant structures and are disclosed, e.g., in U.S. Pat. Nos. 4,916,000, 4,079,161, 4,309,487, and 4,213,812. A non-woven ballistic-resistant laminate referred to by the trademark “Spectra-Shield” is manufactured by Allied-Signal, Inc. The laminate structure is used in soft body armor to protect the wearer against high-velocity bullets and fragments. “Spectra-shield” was made by first forming a non-woven unidirectional tape, which was composed of unidirectional polyethylene fibers and an elastic resin material that held the fibers together. The resin penetrated the fibers, effectively impregnating the entire structure with the resin product. Two layers, or arrays, of the unidirectional tape were then laminated together (cross-plied) at right angles to form a panel. The panel was then covered on both sides with a film of polyethylene. The film prevented adjacent panels from sticking together when the panels were layered in the soft body armor. The final panel was heavier and stiffer than desired for use as a ballistic-resistant panel. The weight and stiffness were due in part to the penetration of the entire structure with the resin product.
Non-woven ballistic-resistant laminates without resins are disclosed, e.g., in U.S. Pat. Nos. 5,437,905, 5,443,882, 5,443,883, and 5,547,536. A sheet of non-woven ballistic-resistant laminate structure was constructed of high performance fibers without using resins to hold the fibers together. Instead of resin, thermoplastic film was bonded to outer surfaces of two cross-plied layers of unidirectional fibers to hold the fibers in place. The film did not penetrate into the fibers. A sufficient amount of film resided between the bonded layers to adhere the layers together to form a sheet. Bonding the two layers of unidirectional fibers cross-plied to one another was necessary to meet structural requirements of the ballistic-resistant panel, such as impact force distribution. The individual sheets were placed loosely in a fabric envelope of an armored garment to form a ballistic-resistant panel.
A ballistic-resistant laminate assembly is provided that overcomes drawbacks experienced in the prior art and achieves other benefits. One aspect of the invention provides a ballistic-resistant laminate assembly having a first layer with a plurality of ballistic-resistant fiber strands positioned adjacent to each other, a plurality of first bonding strips, and a plurality of second bonding strips. The first bonding strips are spaced apart from each other by a selected distance and are at a first orientation with the fiber strands. The second bonding strips are cross-plied relative to the first bonding strips to form a bi-directional array of bonding strips connected to the fiber strands. The second bonding strips are spaced apart from each other by a selected distance and are connected to the fiber strands at a predetermined angle relative to the fiber strands. In one embodiment, the first and second bonding fibers include ballistic-resistant fibers coated with an adhesive material. In one embodiment, the first and second bonding strips are bonding fibers configured in a woven arrangement with the fiber strands. A first laminate film is positioned on one side of the fiber strands and bonded to the first layer. A second laminate film is positioned adjacent to a side of the fiber strands opposite the first laminate film.
The inventors have found limitations and inefficiencies with respect to the performance and to the manufacturing of the prior art ballistic-resistant panels. The prior art laminated panels gave structure to the unidirectional fibers and served to prohibit adjacent sheets from sticking together, but they also facilitated movement between the sheets. Thus, the initial impact from, e.g., a bullet to a ballistic-resistant panel comprised of loose laminated sheets displaced and rotated the sheets within the pocket such that the anti-ballistic characteristics were compromised for subsequent bullets. Additionally, the impact from the bullet bunched and pulled the individual fiber strands in the sheets and further degraded the integrity of the ballistic panel.
When an armor vest is tested in accordance with nationally recognized standards, the vest is shot six times at a pre-established distance and in a specific shot pattern. The inventors found with the prior art that, when the bullet pulled the fibers toward entry, the bullet significantly weakened the areas that fibers were pulled from such that by the fourth and fifth shots, bullets penetrated a raised weakened strike area. Further, in the absence of resins or adhesives, the number of fibers per inch in a panel must be reduced to get opposing laminated sheets to fuse together. Increasing the density of the fibers to improve ballistic performance resulted in a panel that delaminated. To form the prior art sheets, fiber spools were unwound as thermoplastic sheets simultaneously laminated the fibers to provide alternating layers of fibers and thermoplastic sheets. It was not always feasible, economical, or ballistically prudent to simultaneously bond the thermoplastic film on one side of the unspooling fibers. Without the thermoplastic film, however, the unspooled fibers lacked structure and collapsed.
Under one aspect of the invention, a ballistic-resistant fiber panel includes a plurality of ballistic-resistant fiber strands and bonding strips, such as a plurality of bonding fibers connected to the fiber strands. Under another aspect of the invention, two thermoplastic sheets laminate the fiber panel between them. Under another aspect, one set of bonding strips is connected to the fiber strands at one predetermined angle, and a second set of bonding strips at another angle relative to fiber strands is cross-plied with the first bonding strips to form an array of bi-directional bonding strips connected to the ballistic-resistant fiber strands. Under yet another aspect of the invention, several of the laminated ballistic-resistant fiber panels are stitched or otherwise bound together to form packets. Methods for forming or securing ballistic-resistant fiber strands in sheet form are described in detail below. In the following description, numerous specific details are provided, such as specific uses, fiber orientations, numbers of layers, etc., to provide a thorough understanding of embodiments of the invention. One skilled in the relevant art will readily recognize that the invention can be practiced without one or more of the specific details. In other instances, well-known structures or operations are not shown or described in detail to avoid obscuring aspects of the invention.
As illustrated in
As the ballistic-resistant fibers 120 are unspooled to form a fiber panel 110, the bonding fibers 130 are interwoven at an angle with respect to the ballistic-resistant fibers 120. In the illustrative embodiment, the bonding fibers 130 are interwoven perpendicular to the ballistic-resistant fibers 120 on approximately one-inch centers. Preferably the bonding fibers 130 are spaced one-half inch to two inches, and more preferably, the bonding fibers 130 are evenly spaced one inch apart. The bonding fibers 130 are positioned to alternatively go under and over adjacent sets of the ballistic-resistant fibers 120 in a woven arrangement, thereby providing a bi-directional, or multidirectional arrangement of fibers. In selected embodiments, the sets of ballistic-resistant fibers 120 that the bonding fibers go over or under have a width of about one-half inch to two inches, so as to substantially correspond to the distance between adjacent bonding fibers 130.
In one embodiment, the bonding fibers 130 are an ethylene vinyl acetate with a polyester core. The coating may be made of natural or manmade polymers, copolymers, waxes, or mixtures thereof. The coating is configured to at least partially coat and securely adhere to the ballistic-resistant fibers 120, thereby substantially holding the ballistic-resistant fibers together. Representative examples include, but do not limit the scope of use to, the following: styrene, butadiene, poly-butadiene, polyvinylchloride, polyethylene, polypropylene, polyvinyl acetate (plasticized), acrylics, polyvinyl pyrrolidene compounds, natural latex, paraffin wax of the hot melt type, casein, carboxy cellulose esters, and ethers. The core may alternatively be constructed out of nylon, cotton, or aramid fiber or other high performance fibers having a tensile strength of at least 9 grams/denier. In other embodiments, the bonding fibers 130 are constructed of a ballistic-resistant fiber, such as an aramid fiber, with a coating of heat- or pressure-sensitive adhesive that will adhere to the ballistic-resistant fibers 120. The bonding fibers 130 can be substantially the same as the ballistic-resistant fibers 120. Alternately, the bonding fibers 130 can be a different size than the ballistic-resistant fiber 120.
After the bonding fibers 130 are interwoven with the ballistic-resistant fibers 120, they are bonded into a ballistic-resistant oriented fiber panel 110, for example, with heat and pressure from either static heat or an autoclave. The desired temperature range during heating is preferably up to 500 degree F., more preferably in the range of 225-375 degree F., and most preferably 265 degree F. under 45 psi of pressure. In addition to heat bonding the bonding fibers 130 to the ballistic-resistant fibers 120, bonding can be effected by other methods depending upon the particular chemical composition of the fiber's coating. For example, bonding can be done by moisture, the use of organic solvents, high-pressure alone, or contact pressure. Such bonding techniques, however, should not adversely affect the ballistic-resistant fibers 120 or destroy the configuration of the fibers that the bonding fibers 130 are to reinforce. Further, the coating of the bonding fibers 130 must bond with whatever surface coating or laminate is to be applied to the ballistic-resistant fiber panel 110.
Interweaving the bonding fibers 130 with the ballistic-resistant fibers 120 allows the fiber panel 110 to be handled, transported, and processed either at a different location or at a later time. This feature provides advantages, including both efficiency and economy. Under traditional manufacturing methods, it was necessary to secure the thermoplastic film onto one side of the fibers at the same time the ballistic-resistant fibers were unspooled to provide structure for the ballistic-resistant fibers and to preserve the sheet configuration of the fibers. The bonding fibers 130 provide this structure to the ballistic-resistant fibers 120. Thus, a thermoplastic film may be laminated to the ballistic-resistant fibers 120 either at the same time as the ballistic-resistant fibers 120 are unspooled or at a later time.
In another embodiment shown in
The bonding strips 1228 and 1230 of one embodiment can be applied the ballistic-resistant fibers 120 while the ballistic resistant fibers are being unspooled and arranged in the parallel configuration, or the bonding strips can be applied after the ballistic-resistant fibers have been arranged in the parallel configuration. The cross-plied bonding strips 1228 and 1230 form a bi-directional array 1210 of bonding strips that hold the ballistic-resistant fibers 120 in a parallel orientation. The fiber panel 200 can then be handled and manipulated in the manufacturing processes to form ballistic-resistant panels or the like. The bonding strips 1228 and 1230 of different embodiments can be fibrous or non-fibrous. The bonding strips 1228 and 1230 in selected embodiments can be applied in a liquid or semi-liquid format to form spaced-apart stripes of bonding material that act, inter alia, to hold the ballistic-resistant fibers 120 together. In other embodiments the bonding strips 1228 and 1230 can be elongated lengths of material, such as a tape-like material, applied to the ballistic resistant fibers 120 during or after the ballistic-resistant fibers are arranged in the parallel configuration.
In another embodiment shown in
The bonding fibers 230 in the second set are also made of ballistic-resistant fibers, such as aramid fibers, coated with a selected heat and/or pressure sensitive adhesive. The bonding fibers 230 in this embodiment are not perpendicular or parallel to the ballistic-resistant fibers 120. In one embodiment, the angle of the second set of bonding fibers 230 relative to the ballistic-resistant fibers 120 is between 90 degrees and 180 degrees. In another embodiment, the angle is between approximately 120 degrees and 150 degrees, inclusive. In one embodiment, the second set of bonding fibers 230 are woven with the ballistic-resistant fibers 120 and with the first set of bonding fibers 228. The first and second sets of bonding fibers 228 and 230 can be perpendicularly oriented relative to each other, or they can be oriented at other angles to provide the bi-directional woven array of bonding fibers. Accordingly, the ballistic-resistant fibers and the first and second sets of bonding fibers 228 and 230 in the illustrated embodiment form a triaxial array of ballistic resistant fibers that form the ballistic-resistant fiber panel.
In another embodiment, a ballistic-resistant panel is formed with the bonding fibers 120 and three or more sets of spaced apart bonding fibers made of ballistic-resistant fibers coated with a selected heat and/or pressure-sensitive adhesive. Each set of these spaced apart bonding fibers are angularly offset relative to each other and relative to the ballistic-resistant fibers 120. Accordingly, the ballistic-resistant panel is formed with a multi-axial array of ballistic-resistant bonding fibers.
In one embodiment, the ballistic-resistant bonding fibers 228 and 230 can be made of the same material as the ballistic-resistant fibers 120 and coated with a selected adhesive coating. Alternatively, the bonding fibers 228 and 230 can be made of an adhesive-coated ballistic-resistant material having performance characteristics different than the ballistic-resistant fibers 120. As an example, the ballistic-resistant bonding fibers 228 and 230 can be coated aramid fibers with a smaller denier fiber construction and smaller diameter than the denier fiber construction and diameter of the ballistic-resistant fibers 120.
In yet another embodiment shown in
As illustrated in
In one embodiment, the laminate film will coat the exterior surfaces of the ballistic-resistant fibers 120 to encapsulate them, but will not impregnate the fibers. Sufficient plasticized film material flows between adjacent ballistic-resistant fibers 120 to bond the thermoplastics films 340 and 342 to the ballistic-resistant fibers. The thermoplastic films 340 and 342 may be a polyethylene film. Due to the structure provided by bonding fibers 130 and 230 (shown in phantom lines in
The bonding fibers 130 further provide structure to which the thermoplastic films 340 and 342 can bond. Because the thermoplastic films 340 and 342 bond with the interwoven bonding fibers 130, the fiber panel 110 may contain a greater density of ballistic-resistant fibers 120. The bonding fibers 130 of these embodiments thus provide at least two functions: the bonding fibers help prevent the ballistic-resistant fiber panel from spreading or delaminating before and after the thermoplastic films 340 and 342 are laminated over the ballistic-resistant fibers 120, and the bonding fibers provide the panel enhanced buoyant characteristics. The greater density of the ballistic-resistant fibers 120 in the panel combine with the bonding fibers 130 to form interstitial air pockets 344 trapped between the laminate films 340 and 342.
The bonding fibers 130 allow the density of the ballistic-resistant fibers 120 to be maximized by giving the fiber panel 110 further structure while preventing delamination of the laminated fiber sheet 300 by bonding with the thermoplastic film. The bond between the thermoplastic sheets 340 and 342 and the bonding fibers 130 create equally spaced sealed interstitial air pockets that, when used in a ballistic panel, produce buoyant ballistic panels. In the embodiments shown in
The fiber panels 110, 200, and 300 discussed above are substantially flexible ballistic-resistant panels. In other embodiments, sufficient heat or heat with sufficient pressure can be applied to the thermoplastic films 340 and 342 for a sufficient duration to melt one or both of the thermoplastic films 340 and 342 into the ballistic-resistant fiber 120 to form a semi-rigid or rigid structure. Before heating the thermoplastic films 340 and 342, the laminated ballistic-resistant fiber sheet 300 may be configured into any variety of shapes. This semi-rigid or rigid structure may be used alone or may be used in combination with other panels to form any variety of items, including, but not limited to, cargo boxes, storage boxes, aircraft containers, water skis, snow skis, hockey sticks, vehicle bodies such as boat hulls, and protective elements such as helmets for racing, military use, or bicycling.
As illustrated in
The decision to produce either a rigid or a flexible fiber sheet is typically dictated by the end use of the fiber sheet 400. Multiple pliable panels or sheets 110, 200, 300, or 400 can be used to form flexible ballistic-resistant panels used in a wearable garment, while providing ballistic protection to the wearer. Several sheets 110, 200, 300, or 400 in a rigid configuration can be used for other ballistic-related structures, such as helmets configured to fit the wearer's head.
As illustrated in
In one embodiment, the bonding fibers 130 are visual indicators that allow for easy confirmation that adjacent fiber panels 110 are cross-plied relative to each other. As an example, the bonding fibers 130 parallel to the ballistic-resistant fibers 120 in each laminated sheet 512 are colored differently than the ballistic-resistant fibers. Accordingly, when the two laminated sheets 510 and 512 are adjacent to each other, a person can quickly and easily determine whether the ballistic-resistant fibers 120 are cross-plied by looking at the relative orientation of the colored bonding fibers. If the colored bonding fibers 130 of each adjacent laminated sheet 510/512 are cross-plied relative to each other, the person knows that the ballistic-resistant fibers are properly cross-plied. In one embodiment adjacent fiber panels 110 can have different colored bonding fibers 130, and in alternate embodiments the bonding fibers in each fiber panel can have the same color although different from the ballistic-resistant fibers 120. In the embodiment having the bi-directional array 210 of bonding fibers 130, the bonding fibers can be configured so that some or all of the bonding fibers 230 parallel to the ballistic-resistant fibers 120 have a different color than the cross-plied bonding fibers 228 in that fiber panel 110.
The laminated panel assembly 500 of the illustrated embodiment has multiple cross-plied fiber panels 110, and each fiber panel 110 is laminated between lower and upper laminate films 340 and 342, thereby forming laminated sheets 510 and 512 with a configuration of film/fiber panel/film. Multiple laminated sheets 510, 512 can be joined together such that the ballistic-resistant fibers 120 of adjacent layers are cross-plied relative to each other. The resulting laminated sheet 500 has a lamination configuration of film/fiber panel/film/film/fiber panel/film. . . . The multiple laminated layers 510, 512 can be retained together by an adhesive provided between layers, or by stitching the layers together or by other laminating techniques. As discussed above, the bonding fibers 130 provide structure to the ballistic-resistant fibers 120 and allow the panel 110 to be manufactured without the thermoplastic film 340 or 342. Alternatively, if the thermoplastic film 340 or 342 is bonded to either a first or a second surface when the ballistic-resistant fibers 120 are unspooled and combined with the bonding fibers 130 in the weave pattern to form the ballistic-resistant panel 110, then the thermoplastic film may be used to provide additional structure to the panel.
When the ballistic-resistant fibers 120 are combined with the bonding fibers 130 in the weave pattern, layered on or between thermoplastic films 340 and 342, and laminated to produce a flexible sheet 500, the resulting flexible sheet is easy to handle without damaging, loosening, or substantially degrading the effectiveness of the ballistic-resistant fibers. The flexible, laminated sheet 500 is also quite buoyant because of the interstitial air pockets 344 trapped within the sheet between the laminate films 340 and 342.
In the laminated sheet 600 as illustrated in
The laminated sheet 700 illustrated in
In another embodiment, adjacent sheets 300/400/500/600/700 can be secured together with an adhesive provided between the adjacent layers. The adhesive can be applied in selected patterns on the facing surfaces, so as to control the stiffness or rigidity of the resulting stack of layers 800. The stack of layers 800 adhered together can also be stitched together at selected locations or patterns as needed for the particular application for which the packet 820 is to be used. Further, any one of the sheets illustrated in
Stitching the layers 800 together to form the packet 820 provides improved resistance to ballistic penetration in a ballistic panel with fewer total fiber panels required, as described below. In one embodiment, preferably four to ten packets of laminated sheets 500 are used to form a ballistic panel, more preferably four to eight packets and most preferably six packets are used to form a ballistic-resistant packet 820. When a bullet hits a ballistic-resistant panel 820, the bullet penetrates the initial layers 500 and the impact force of the bullet displaces secondary layers. When the ballistic-resistant panel 820 is made up of several individual ballistic-resistant fiber sheets or panels, the force of the bullet causes some fibers in the panel to push apart and separate and other fibers at the tip of the bullet to bunch. Adjacent fibers that the bullet does not actually penetrate are pulled out of position and weakened by the impact force of the bullet. This creates a path of reduced resistance through the panel. The result is that the integrity of the ballistic-resistant panel is significantly impaired after the first impact. Packets of ballistic-resistant fiber layers retain the benefit that the movement between the individual layers allows, i.e., shifting the bullet off course and diffusing the straight-line penetration of the bullet, while decreasing the penetration and the bunching caused by the bullet. The packets act like individual panels within the ballistic-resistant panel in that each individual packet acts independently of the adjacent packet. Thus the bullet's trajectory angles at each packet so that it does not create a path through the panel.
Fewer layers are used to form a ballistic-resistant panel of equivalent characteristics compared to prior systems; therefore, the resultant panel is more flexible and lighter in weight. When a bullet impacts a ballistic-resistant panel, the panel is subject to both the impact force of the bullet and a reverberating energy wave sent out ahead of the bullet. The components of the packet of this embodiment combine to provide a more efficient ballistic-resistant panel. Components include any one of or a combination of the following: density of the ballistic-resistant fibers in the panel, bonding thread, the cross-plied positioning of the fiber panels, thermoplastic films, the laminated fiber panels, and laminated panel assemblies stitched together in packets. The interaction between the individual packets works in a cooperative effort to provide an improved ballistic-resistant panel. Among other things, sewing the layers in a packet maximizes the anti-ballistic properties of the individual layers such that the resultant packet is stronger than the sum of the individual layers. Additionally, because fewer layers are required, the ballistic-resistant panel is less expensive to manufacture.
Stitching the layers 800 to form the packet 820 may be done by any variety of stitching patterns and is illustrated in
As illustrated in
The ballistic-resistant sheets 1202 are oriented so the ballistic-resistant fibers 120 of each sheet is cross-plied at a selected angle relative to the ballistic-resistant fibers of the adjacent sheets. The ballistic-resistant fibers 120 of adjacent sheets can be cross-plied approximately a 90 degree orientation, although angular orientations can be used. When the ballistic-resistant sheets 1202 are positioned together to form the panel 1200, the bonding fibers 130 in each sheet bond to the ballistic-resistant fibers 120 of the sheet and also to the ballistic-resistant fibers and/or the bonding fibers of the adjacent sheets. The bonding fibers 130 securely retain the adjacent ballistic-resistant sheets 1202 together while maintaining the desired degree of flexibility or rigidity of the ballistic-resistant panel 1200. The plurality of ballistic-resistant sheets 1202 in alternate embodiments can also be stitched together, as discussed above.
The impact of the bullet indents the ballistic-resistant panel and causes some of the fibers in the ballistic-resistant panel to compact at the front of the bullet while stretching and pulling other fibers out of position as the bullet moves through the ballistic-resistant panel. Additionally, the indentation from the force of the bullet in the ballistic-resistant panel in one location causes a resulting protrusion of the panel's flat surface surrounding the indentation. This protrusion can buckle the surface of the entire panel depending on the entry location of the bullet. This buckling creates an air pocket between the panel and the wearer's chest, which in turn impacts the integrity of the entire ballistic-resistant panel.
The various embodiments described above can be combined to provide further embodiments. All of the above U.S. patents and applications are incorporated by reference. Aspects of the invention can be modified, if necessary, to employ the systems, circuits, and concepts of the various patents and applications described above to provide yet further embodiments of the invention.
These and other changes can be made to the invention in light of the above detailed description. In general, in the following claims, the terms used should not be construed to limit the invention to the specific embodiments disclosed in the specification and the claims, but should be construed to include all ballistic-resistant fiber sheets that operate under the claims. Accordingly, the invention is not limited by the disclosure, but instead its scope is to be determined entirely by the following claims.
This application is a continuation-in-part application of U.S. patent application Ser. No. 10/421,627, entitled METHOD FOR FORMING OR SECURING UNIDIRECTIONALLY-ORIENTED FIBER STRANDS IN SHEET FORM, SUCH AS FOR USE IN A BALLISTIC-RESISTANT PANEL, which is a continuation of U.S. patent application Ser. No. 09/528,782, entitled METHOD FOR FORMING OR SECURING UNIDIRECTIONALLY ORIENTED FIBER STRANDS IN SHEET FORM, SUCH AS FOR USE IN A BALLISTIC-RESISTANT PANEL, filed Mar. 17, 2002, which is incorporated herein in its entirety by reference, and which claims priority to U.S. Provisional Patent Application No. 60/125,403, also incorporated herein in its entirety by reference.
Number | Date | Country | |
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60125403 | Mar 1999 | US |
Number | Date | Country | |
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Parent | 11447595 | Jun 2006 | US |
Child | 12930317 | US | |
Parent | 10777389 | Feb 2004 | US |
Child | 11447595 | US | |
Parent | 09528782 | Mar 2000 | US |
Child | 10421627 | US |
Number | Date | Country | |
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Parent | 10421627 | Apr 2003 | US |
Child | 10777389 | US |