The present invention relates to a ballpoint pen refill and a ballpoint pen.
Japanese Patent Application Laid-Open (JP-A) No. 2013-252655 discloses a ballpoint pen that can draw a thick and thin writing line according to a writing angle by the action of an outer. JP-A No. 2012-148423 discloses a ballpoint pen using a resin for a ball receiving seat and to which a metal cover is attached. JP-A No. 2001-113874 discloses a ballpoint pen using an ink conduit core made of a resin for a ball receiving seat. JP-A No. 2019-10843 discloses a ballpoint pen in which a support member having a resilient action is attached to a rear end of a cylindrical receiving seat member inserted into a cylindrical body holding a ball. JP-A No. 2019-10844 discloses a ballpoint pen in which a ball is pressed in a distal direction by a spring.
An object of an embodiment of the present disclosure is to provide a ballpoint pen refill and a ballpoint pen capable of securing sufficient ball holding force and drawing line representation like a writing brush while forming a ball receiving seat and a pressing member for pressing in a distal direction as a single member.
A first aspect of the present application is a ballpoint pen refill including: an ink storage tube made of a synthetic resin and storing an ink thereinside; a ball holder made of a synthetic resin and attached to a distal end of the ink storage tube; a ball pressing rod mounted inside the ball holder; and a writing ball stored in a distal end of the ball holder and having a rear end side held by the ball pressing rod, in which the ball pressing rod includes: a fixing portion fixed to the ball holder; a movable portion slidable in a front-rear direction with respect to the ball holder; a compression portion connecting the fixing portion and the movable portion; and a rearward movement restricting portion protruding from a distal end of the fixing portion and provided with a gap from a rear end of the compression portion.
According to the configuration of the first aspect of the present application, the ball pressing rod can serve as both a ball receiving seat and a spring enabling the writing ball to slide forward and backward.
In a second aspect of the present application, in addition to the configuration of the first aspect, the compression portion has a bellows shape. With this configuration, the ball pressing rod can be easily formed by injection molding of a synthetic resin, and a resilient force can be secured by the bellows shape.
In a third aspect of the present application, in addition to the configuration of the first aspect or the second aspect, a slit is formed rearward from the distal end of the ball holder.
In a fourth aspect of the present application, in addition to the configuration of any one of the first aspect to the third aspect, all members thereof, except the ink, are made of a synthetic resin. With this configuration, since a metal material is not used for the ballpoint pen refill, it is not necessary to dispose of the ballpoint pen refill separately from the metal, and it is easy to recycle the members.
A ballpoint pen of a fifth aspect of the present application stores the ballpoint pen refill of any one of the first aspect to the fourth aspect in a shaft tube.
Since the embodiment of the present disclosure is configured as described above, it is possible to provide a ballpoint pen refill and a ballpoint pen capable of securing sufficient ball holding force and drawing line representation like a writing brush while forming a ball receiving seat and a pressing member for pressing in a distal direction as a single member.
Hereinafter, an embodiment of the disclosure will be described with reference to the drawings. In the following description, a “distal end” refers to a side on which a writing ball is provided in a ballpoint pen, and a “rear end” refers to an opposite side thereof. Moreover, the same reference numerals in the drawings indicate the same members or parts without any particular reference in the following description of the drawings. In each drawing, the right side of the drawing is the distal end side and the bottom surface side, and the left side is the rear end side and the plane side.
A ballpoint pen 10 of a first embodiment is illustrated in a front view (
As illustrated in the cross-sectional view of
The ballpoint pen refill 20 used in the ballpoint pen 10 in
As illustrated in the cross-sectional view of
The ink 24 of this embodiment is an aqueous gel ink. This ink 24 preferably contains a coloring pigment, a polyvinyl alcohol-based resin as a dispersion resin, and an alkali swelling associative thickener. Each component will be described below.
As the coloring pigment, either an inorganic coloring pigment or an organic coloring pigment can be used. Specifically, black pigments such as carbon black; red pigments such as permanent carmine FB, Lake Red C, Permanent Red FGR, and Fast Red; blue pigments such as phthalocyanine blue, fast sky blue, and ultramarine blue, and mixtures thereof can be used.
As the carbon black typically used as the coloring pigment of the ink, a commercially available carbon black, a carbon black for rubber, or the like can be used, but a commercially available carbon black for a black colorant of an ink, a paint, or the like is preferable. As the type of carbon black, any of channel black, furnace black, acetylene black, thermal black, and the like can be used. The particle size of the carbon black is preferably from 10 to 80 nm. As the surface property of the carbon black, any of acidic, neutral, and alkaline can be used, but carbon black having a pH of from 7.5 to 8.5 is preferably used.
The content of the coloring pigment varies depending on the type of the coloring pigment, but is preferably from 8 to 25% by weight with respect to the total amount of the ink. In a case in which the content is less than 8% by weight, coloring becomes insufficient in relation to the amount of the dispersion resin, and the quality of the color of the drawn line cannot be satisfied. On the other hand, in a case in which the content is more than 25% by weight, it is necessary to increase the amount of the polyvinyl alcohol-based resin required for stably dispersing the coloring pigment, and as a result, the viscosity is high and the writing feeling is heavy.
The polyvinyl alcohol-based resin as a dispersion resin is contained as a water-soluble resin for uniformly dispersing a coloring pigment such as carbon black in water and as a fixing agent to paper.
The polyvinyl alcohol-based resin may be one obtained by saponifying polyvinyl acetate, and is preferably a polyvinyl alcohol having a polymerization degree of from 300 to 2000 and a saponification degree of from 80 to 95 mol %. In a case in which the polymerization degree is too low, the viscosity of the ink may be too low, and there is a concern that the blobbing of the ink cannot be sufficiently suppressed even in the case of being used in combination with an alkali swelling associative thickener. In a case in which the saponification degree is too low, the water resistance of the drawn line is deteriorated.
The polyvinyl alcohol-based resin used in this embodiment is not limited to a saponified product of polyvinyl acetate of 100% vinyl acetate, and a polyvinyl alcohol-based copolymer obtained by copolymerizing another vinyl-based monomer or a polyvinyl alcohol-based resin modified after acetylation or the like may be used as long as the content thereof is about 10 mol % or less, but a saponified product of polyvinyl acetate of 100% vinyl acetate is preferable. The content of the polyvinyl alcohol-based resin is preferably from 2 to 10% by weight with respect to the total amount of the ink. In a case in which the content is less than 2% by weight, the dispersion of the coloring pigment is not sufficiently stabilized, and the storage stability is deteriorated, for example, the coloring pigment settles over time. In a case in which the content is more than 10% by weight, the viscosity increases too much and the writing feeling becomes heavy.
The alkali swelling associative thickener can impart thixotropic behavior to the ink. In other words, even in a case in which the ink in a resting state has a high viscosity, the viscosity is reduced by applying a high shearing force at the time of writing, and writing becomes possible.
Examples of the alkali swelling associative thickener include, among alkali swelling type thickeners which are unneutralized acrylic polymers, water-soluble or water-swellable polymers modified with a hydrophobic group, and aqueous solutions and emulsions thereof, and hydrophobically modified alkali-soluble emulsions, hydrophobically modified poly(meth)acrylic acids, (meth)acrylic acid copolymers, mixtures thereof, and aqueous solutions and emulsions thereof. Examples of the hydrophobic group include a chain or cyclic hydrocarbon group, an aromatic hydrocarbon group, a halogenated alkyl group, an organosilicon group, and a fluorocarbon group, and the modification with a hydrophobic group can be performed by esterification with a hydrophobic chain transfer agent (for example, dodecyl mercaptan), a hydrophobic monomer (for example, decyl methacrylate or a nonionic vinyl monomer), a hydrophobic group-containing alcohol (for example, dodecanol), and a nonionic surfactant, or the like. The alkali swelling associative thickener having the configuration as described above is neutralized with an alkali to form a network structure, and spreads in a dispersion medium while swelling to thicken the ink. Furthermore, hydrophilic groups or hydrophobic groups in the molecule, and further, a hydrophilic group or hydrophobic group and a dispersion resin can be associated with each other by formation of a hydrogen bond or the like. Although the viscosity is increased by association, the association state is broken by a high shearing force, and the viscosity decreases, so that good fluidity can be exhibited.
As described above, the thixotropy can be imparted to the ink by adding the alkali swelling associative thickener. Specifically, a thixotropy index (TI value) represented by a ratio (η0.6/η6) of the viscosity (η0.6) at 0.6 rpm to the viscosity (η6) at 6 rpm as measured with a rotary viscometer can be set to 3.0 or more by adding the alkali swelling associative thickener. The TI value is preferably about from 3.0 to 10. It is preferable that the thixotropy index is within the above range and the viscosity at 6 rpm is 0.3 Pa·s or more. By adjusting the contents of the coloring pigment and the polyvinyl alcohol-based resin, the thixotropy index can be adjusted within the above range, but the thickening effect is insufficient, and in a case in which the viscosity at 6 rpm is too low, the viscosity at rest is low, and consequently, the blobbing of the ink cannot be sufficiently prevented. In this respect, the addition of the alkali swelling associative thickener makes it possible to increase the viscosity and impart the thixotropy so as to satisfy both the blobbing prevention of the ink and the writing property. On the other hand, even in a case in which the viscosity is increased by adjusting the addition amount of the alkali swelling associative thickener, the viscosity of the ink at a rotation speed of 6 rpm as measured with an EM type rotary viscometer can be set to less than 25 Pa·s. By increasing the viscosity in a range of less than 25 Pa·s in a state in which a shearing force is applied, it is possible to prevent the blobbing of the ink due to an increase in viscosity without impairing the writing property.
Note that examples of the associative thickener include a urethane block copolymer aqueous solution modified with a urethane monomer or the like. The urethane associative thickener can also impart thixotropy in which the association and separation of molecules are repeated depending on the magnitude of the shearing force, but the viscosity increase level is insufficient or the viscosity decrease under a high shearing force is insufficient.
The content of the alkali swelling associative thickener is preferably from 0.1 to 5.0% by weight with respect to the total amount of the ink. In a case in which the content is less than 0.1% by weight, imparting of thixotropy becomes insufficient. In a case in which the content is more than 5.0% by weight, the viscosity increases too much and the writing property deteriorates.
In the ink of this embodiment, in order for the alkali swelling associative thickener to effectively impart thixotropy, it is preferable that the ink is neutral to alkaline, specifically, has a pH of from 7.0 to 9.5.
Therefore, an alkaline compound may be added in order to set the pH of the ink within the above range. As the alkaline compound, triethanolamine, monoethanolamine, diethanolamine, ammonia, and the like can be used.
The ink of this embodiment may further contain additives such as a dispersion stabilizing aid, a surfactant, an antiseptic, and an antifoaming agent if necessary. As the dispersion stabilizing aid, ethylene glycol, diethylene glycol, triethylene glycol, glycerin, and the like are preferably used.
The ink containing components as described above has thixotropy. Specifically, it is preferable that the thixotropy index (TI value) represented by the ratio (η0.6/η6) of the viscosity (η0.6) at 0.6 rpm to the viscosity (η6) at 6 rpm as measured with an EM type rotary viscometer is 3.0 or more, and the viscosity at 6 rpm is 0.3 Pa·s or more. The thixotropy index is more preferably 3.5 or more. Moreover, the viscosity at 6 rpm is more preferably 0.5 Pa·s or more.
The viscosity measured with a rotary viscometer at a rotation speed of 6 rpm is preferably 25 Pa·s or less. The viscosity is a value at a rotation speed of 100 rpm and 25° C. in an EM type rotary viscometer.
As illustrated in
The ball holder 60 used in the ballpoint pen refill 20 in
The attachment portion 61 has a substantially cylindrical shape, and is a portion press-fitted to the distal end of the ink storage tube 23 as illustrated in
The intermediate portion 63 has a slightly tapered cylindrical shape, and an outer diameter thereof is smaller than an outer diameter of the attachment portion 61. The distal end portion 64 having a substantially cylindrical shape with a smaller outer diameter is formed on the distal end side of the intermediate portion 63. An abutment portion 63A, which is a step height between the intermediate portion 63 and the distal end portion 64, abuts on the inside of the distal end opening of the shaft tube 30 in a case in which the ballpoint pen refill 20 is attached to the shaft tube 30 (see
The inside of the ball holder 60 has a hollow structure as illustrated in
The ball pressing rod 50 mounted inside the ball holder 60 is illustrated in a front view (
Although each of the fixing portion 51, the compression portion 54, and the movable portion 52 has a substantially columnar shape, two opposing surfaces are formed as a large flat surface portion 50A and a small flat surface portion 50B that are scraped in a planar shape, and a groove-shaped ink groove 57 is formed in each of the other opposing two surfaces to have a planar shape as illustrated in
The fixing portion 51 is a portion fixed to the ball holder 60 in a case in which the ball pressing rod 50 is attached to the ball holder 60 by press-fitting a press-fitting portion 51A having a larger diameter into a front part of the rear reduced diameter portion 66A (see
The pressing portion 53 protruding from the movable portion 52 in the distal direction includes a wide portion 53A, which is a portion coming into contact with the rear end of the writing ball 26 in a case in which the ball pressing rod 50 is attached to the ball holder 60 (see
The compression portion 54 connects the fixing portion 51 and the movable portion 52 to each other in a shape bent twice in a bellows shape. A bent part on the rear side is a rear bent portion 54A, and a bent part on the front side is a front bent portion 54B. Moreover, the rearward movement restricting portion 55 has a plate-like shape extending from the fixing portion 51 toward the movable portion 52, and in a state in which the ball pressing rod 50 is attached to the ball holder 60 and writing pressure is not applied to the writing ball 26, a gap is generated between the rearward movement restricting portion 55 and the movable portion 52 (see
As illustrated in
A pressing state in which writing pressure is applied to the writing ball 26 at the distal end of the ballpoint pen refill 20 in the state illustrated in
The ball pressing rod 50 in the state illustrated in
As described above, the distal end edge of the rearward movement restricting portion 55 is the limit of rearward movement due to the pressing of the writing ball 26. Moreover, the intermediate reduced diameter portion 66B of the back hole 66 is the limit of forward movement of the ball pressing rod 50. Further, the writing ball 26 is constantly urged forward by the spring effect of the compression portion 54. Furthermore, in a case in which writing pressure is applied to the writing ball 26, the compression portion 54 compresses and bends through the movable portion 52, so that it is possible to give a user a writing feeling in which the pen tip bends. As a result, it is possible to achieve drawing line representation such as tome (stop), hane (upward brushstroke), or harai (sweeping) like a hair brush.
Moreover, the ball holder 60 and the ball pressing rod 50 have a shape that can be injection molded with a synthetic resin, and a flow path of the ink inside the ball holder 60 is secured by the ink groove 57, the large flat surface portion 50A, and the small flat surface portion 50B provided in the ball pressing rod 50. Furthermore, since all the members constituting the ballpoint pen 10 except for the ink are made of a synthetic resin and do not use metal parts, it is not necessary to perform sorting at the time of disposal, and it is easy to recycle the synthetic resin material.
The appearance of the ballpoint pen 10 of the second embodiment is the same as that of the first embodiment as illustrated in the front view of
The ballpoint pen refill 20 used in the ballpoint pen 10 of the second embodiment is illustrated in a front view (
The ball holder 60 used in the ballpoint pen refill 20 in
The structure of the intermediate portion 63 is similar to that of the first embodiment. The structure of the distal end portion 64 is the same as that of the first embodiment except that the extending portion 64D extending in the distal direction from the distal end edge of the caulking portion 64B is formed.
The inside of the ball holder 60 has a hollow structure as illustrated in
Note that a sealing surface 64C that comes into contact with the outer peripheral surface of the writing ball 26 is formed on the inner peripheral surface of the caulking portion 64B (see
In the ballpoint pen refill 20 of this embodiment, as illustrated in the enlarged perspective view of the distal end part in
The ball pressing rod 50 (see
A pressing state in which writing pressure is applied to the writing ball 26 at the distal end of the ballpoint pen refill 20 in the state illustrated in
As described above, also in this embodiment, as in the first embodiment, the distal end edge of the rearward movement restricting portion 55 is the limit of rearward movement due to the pressing of the writing ball 26. Moreover, the intermediate reduced diameter portion 66B of the back hole 66 is the limit of forward movement of the ball pressing rod 50. Further, the writing ball 26 is constantly urged forward by the spring effect of the compression portion 54. Furthermore, in a case in which writing pressure is applied to the writing ball 26, the compression portion 54 compresses and bends through the movable portion 52, so that it is possible to give a user a writing feeling in which the pen tip bends. As a result, it is possible to achieve drawing line representation such as tome (stop), hane (upward brushstroke), or harai (sweeping) like a hair brush.
Moreover, the ball holder 60 and the ball pressing rod 50 have a shape that can be injection molded with a synthetic resin, and a flow path of the ink inside the ball holder 60 is secured by the ink groove 57, the large flat surface portion 50A, and the small flat surface portion 50B provided in the ball pressing rod 50. Furthermore, since all the members constituting the ballpoint pen 10 except for the ink are made of a synthetic resin and do not use metal parts, it is not necessary to perform sorting at the time of disposal, and it is easy to recycle the synthetic resin material.
The invention is applicable to a ballpoint pen refill and a ballpoint pen using the same.
Number | Date | Country | Kind |
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2021-178197 | Oct 2021 | JP | national |
2022-076687 | May 2022 | JP | national |
Filing Document | Filing Date | Country | Kind |
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PCT/JP2022/038996 | 10/19/2022 | WO |