Bar coating apparatus and bar coating method

Information

  • Patent Grant
  • 6815008
  • Patent Number
    6,815,008
  • Date Filed
    Thursday, September 12, 2002
    22 years ago
  • Date Issued
    Tuesday, November 9, 2004
    20 years ago
Abstract
A bar coating apparatus includes a coating bar for contacting an object to be coated, which object is conveyed in a constant direction, so as to apply a coating solution to and remove excess coating solution from the object to be coated, a weir member for forming a bead of the coating solution between the object to be coated and the coating bar, the weir member being disposed upstream of the coating bar in a direction in which the object to be coated is conveyed, a pressing member for pressing the object to be coated from a side thereof opposite from the coating bar, the pressing member being disposed near the coating bar; and a moving device for moving the pressing member in a thickness direction of the object to be coated.
Description




BACKGROUND OF THE INVENTION




1. Field of the Invention




The present invention relates to a bar coating apparatus and a bar coating method. More specifically, the invention relates to the bar coating apparatus and the bar coating method that are capable of applying a desired amount of coating solution to an object to be coated.




2. Description of the Related Art




In order to apply a coating solution to an object to be coated such as a metal plate and to remove excessive coating solution from the object to be coated (so-called measurement), a bar coating apparatus


102


as shown in

FIG. 23

is conventionally used.




The bar coating apparatus


102


has a columnar coating bar


106


, which is arranged so as to contact with a coating surface (lower surface) of a metal plate


104


in a direction perpendicular to a conveyance direction of the metal plate


104


(direction of arrow F


1


), which is conveyed at a constant conveyance speed. The coating bar


106


rotates due to friction with the metal plate


104


at a peripheral speed equal to the conveyance speed of the metal plate


104


. A coating solution


108


is raised by the rotation of the coating bar


106


, and a bead


110


is arranged between a weir member


112


and the metal plate


104


. Namely, the coating solution in the bead


110


is applied to the metal plate


104


and any excess coating solution is removed (measured) from the metal plate


104


.




Plates of various thicknesses are used for the metal plate


104


as an object to be coated. However, with changes in the thickness of the metal plate


104


, a clearance between the metal plate


104


and the weir member


112


also changes. As a result, the bead


110


becomes unstable, which causes difficulty in obtaining uniformly coated surface quality.




In addition, the metal plate


104


occasionally flaps vertically and ripples due to conveyance. For this reason, the contacted state between the metal plate


104


and the coating bar


106


cannot be maintained constantly, and the bead


110


occasionally becomes unstable. Particularly recently, the conveyance speed of the metal plate


104


tends to be increased, and thus the possibility of the bead


110


not maintaining stability increases due to the higher speed. When the bead


110


becomes unstable, for example, it becomes difficult to obtain a uniformly coated surface quality because a coating streak is caused by the disturbance of the bead


110


.




Further, the instability of the bead


110


due to the increased conveyance speed of the metal plate


104


causes the generation of so-called entrained air (air that is trapped inside the coating solution at the time of coating), which can decrease the coated surface quality. When the clearance between the weir member


112


and the object to be coated (metal plate


104


) is large, the effect of the entrained air upon the coating solution is particularly noticeable. Hence, the bead


110


has a tendency to become unstable, and that in turn causes difficulty in obtaining uniform coated surface quality.




Furthermore, factors such as increased conveyance speed of the plate, increased viscosity of the coating solution, and varying conditions at the time of coating can hinder maintenance of stability in the bead


110


. Disturbance of the bead results in problems such as difficulty in obtaining uniform coated surface quality due to coating streaks and coating breakage.




SUMMARY OF THE INVENTION




In view of the above facts, an object of the present invention is to provide a bar coating apparatus and a bar coating method, which are capable of obtaining uniformly coated surface qualities by corresponding to the various thickness of the objects to be coated.




In addition, it is another object of the invention to provide a bar coating apparatus and a bar coating method which are capable of obtaining uniformly coated surface quality even if a conveyance speed of an object to be coated is increased or a viscosity of a coating solution is increased.




A first aspect of the invention is a bar coating apparatus comprising: a coating bar for contacting an object to be coated, which object is conveyed in a constant direction, so as to apply a coating solution to and remove excess coating solution from the object to be coated; a weir member for forming a bead of the coating solution between the object to be coated and the coating bar, the weir member being disposed upstream of the coating bar in a direction in which the object to be coated is conveyed; a pressing member for pressing the object to be coated from a side thereof opposite from the coating bar, the pressing member being disposed near the coating bar; and a moving device for moving the pressing member in a thickness direction of the object to be coated.




Further, in the first aspect, the pressing member is a pressing roll that is rotatingly driven by friction with the object to be coated.




Furthermore, in the first aspect, the bar coating apparatus further comprises a rotational drive for rotating the coating bar at a peripheral speed that differs from a peripheral speed corresponding to the speed at which the object to be coated is conveyed.




A second aspect of the invention is a bar coating method of bringing a coating bar into contact with an object to be coated, which object is conveyed in a constant direction, so as to apply a coating solution to and remove excess coating solution from the object to be coated, comprising the steps of: supplying the object to be coated; pressing, with a pressing member disposed near the coating bar, the object to be coated from a side thereof opposite from the coating bar; and moving, in correspondence to a coating state, the pressing member in a thickness direction of the object to be coated.




Further, in the second aspect of the invention, the coating bar is rotated at a peripheral speed that differs from a peripheral speed corresponding to the speed at which the object to be coated is conveyed.




In the bar coating apparatus according to the first aspect, the coating bar is brought into contact with the object to be coated, which is conveyed, and the coating solution is applied to the object to be coated. The object to be coated is pressed by the pressing member from the opposite side of the coating bar in the vicinity of the coating bar. The pressing member can be moved in a thickness direction of the object to be coated by the moving apparatus. Therefore, even if the objects to be coated have various thicknesses, the pressing member is moved, and the clearance between the object to be coated and the weir plate is adjusted, so that the bead of the coating solution formed among the weir member, the coating bar and the object to be coated can be stabilized. For this reason, a coated surface quality of the object to be coated is also stabilized, and even if the object to be coated has various thicknesses, the uniform coated surface quality can be obtained.




In addition, a member that merely contacts and presses the object to be coated may be used as the pressing member. However, when the pressing member is a pressing roll, which is driven to rotate by friction with the object to be coated, the object to be coated can be prevented from being rubbed and damaged by the pressing roll.




Further, when the coating bar is not rotated by the friction with the object to be coated, but is actively rotated by the rotation drive at a peripheral speed different from a peripheral speed corresponding to the conveyance speed of the object to be coated, the bead formed among the weir plate, the coating bar and the object to be coated can be stabilized. Therefore, for example, even in the case where the conveyance speed of the object to be coated is increased and the viscosity of the coating solution is increased, the uniform coated surface quality can be obtained.




In the bar coating method according to the second aspect, the coating bar is brought into contact with the object to be coated, which is conveyed, and the coating solution is transferred and applied to the object to be coated. The object to be coated is pressed from the opposite side of the coating bar by the pressing member in the vicinity of the coating bar, and the pressing member is moved in the thickness direction of the object to be coated according to a coating state. Therefore, the pressing member is moved in the thickness direction of the object to be coated in accordance to the various thickness of the object to be coated, so that the clearance between the object to be coated and the weir member is adjusted and the bead can be stabilized. For this reason, the coated surface quality of the object to be coated is also stable, and the uniform coated surface quality can be obtained even when the object to be coated has various thickness.




In addition, the coating bar is not rotated by friction with the object to be coated and the coating bar, but is actively rotated at a peripheral speed different from a peripheral speed corresponding to the conveyance speed of the object to be coated. As a result, the bead formed among the weir plate, the coating bar and the object to be coated can be stabilized. Therefore, for example, even in cases where the conveyance speed of the object to be coated is increased and the viscosity of the coating solution is increased, the uniform coated surface quality can be obtained.




A third aspect of the invention is a bar coating apparatus comprising: a coating bar for contacting an object to be coated, which object is conveyed in a constant direction, so as to apply a coating solution to and remove excess coating solution from the object to be coated; a weir member for forming a bead of the coating solution between the object to be coated and the coating bar, the weir member being disposed upstream of the coating bar in a direction in which the object to be coated is conveyed; and a pressing member for pressing the object to be coated from a side thereof opposite from the coating bar, the member being disposed near the coating bar.




Further, in the third aspect, the pressing member is a pressing roll that is rotatingly driven by friction with the object to be coated.




Furthermore, in the third aspect, the bar coating apparatus further comprises a rotational drive for rotating the coating bar at a peripheral speed that differs from a peripheral speed corresponding to the speed at which the object to be coated is conveyed.




A fourth aspect of the invention is a bar coating method of bringing a coating bar into contact with an object to be coated, which object is conveyed in a constant direction, so as to apply a coating solution to and remove excess coating solution from the object to be coated, comprising the steps of: supplying the object to be coated; and pressing, with a pressing member disposed near the coating bar, the object to be coated from a side thereof opposite from the coating bar.




Further, in the fourth aspect of the invention, the coating bar is rotated at a peripheral speed that differs from a peripheral speed corresponding to the speed at which the object to be coated is conveyed.




In the bar coating apparatus according to the third aspect, the coating bar is brought into contact with the object to be coated, which is conveyed, and the coating solution is applied to the object to be coated. The object to be coated is pressed by the pressing member from the opposite side of the coating bar in the vicinity of the coating bar. Therefore, flapping of the object to be coating during conveyance is prevented, and the bead of the coating solution formed among the weir member, the coating bar and the object to be coated is stabilized. For this reason, a coated surface quality of the object to be coated is also stabilized. Further, even if, for example, the conveyance speed of the object to be coated is increased, the uniform coated surface quality can be obtained.




In addition, a member that merely contacts and presses the object to be coated may be used as the pressing member. However, when the pressing member is a pressing roll, which is driven to rotate by friction with the object to be coated, the object to be coated can be prevented from being rubbed and damaged by the pressing roll.




Further, the coating bar is not rotated by friction with the object to be coated, but is actively rotated at a peripheral speed different from a peripheral speed corresponding to the conveyance speed of the object to be coated. As a result, the bead formed among the weir plate, the coating bar and the object to be coated can be stabilized. Therefore, for example, even in cases where the conveyance speed of the object to be coated is increased and the viscosity of the coating solution is increased, the uniform coated surface quality can be obtained.




In the bar coating method according to the fourth aspect, the coating bar is brought into contact with the object to be coated, which is conveyed, and the coating solution is transferred and applied to the object to be coated. The object to be coated is pressed from the opposite side of the coating bar by the pressing member in a vicinity of the coating bar. Therefore, the flapping of the object to be coated during conveyance is prevented, and the bead of the coating solution is stabilized. For this reason, the coated surface quality of the object to be coated is also stable. Further, even if, for example, the conveyance speed of the object to be coated is increased, the uniform coated surface quality can be obtained.




In addition, the coating bar is not rotated by friction with the object to be coated, but is actively rotated at a peripheral speed different from a peripheral speed corresponding to the conveyance speed of the object to be coated. As a result, the bead formed among the weir member, the coating bar and the object to be coated can be stabilized. Therefore, for example, even in cases where the conveyance speed of the object to be coated is increased and the viscosity of the coating solution is increased, the uniform coated surface quality can be obtained.




A fifth aspect of the invention is a bar coating apparatus comprising: a coating bar for contacting an object to be coated, which object is conveyed in a constant direction, so as to apply a coating solution to and remove excess coating solution from the object to be coated; a weir member for forming a bead of the coating solution between the object to be coated and the coating bar, the weir member being disposed upstream of the coating bar in a direction in which the object to be coated is conveyed; and a clearance-maintaining mechanism for maintaining clearance between the weir member and the object to be coated at a predetermined value of no more than 5 mm.




Further, in the fifth aspect, the bar coating apparatus further comprises a pressing member for pressing the object to be coated from a side thereof opposite from the coating bar, the member being disposed near the coating bar, wherein the clearance-maintaining mechanism comprises a moving device for moving at least one of the weir member and the pressing member in a thickness direction of the object to be coated.




Furthermore, in the fifth aspect, the bar coating apparatus further comprises a rotational drive for rotating the coating bar at a peripheral speed that differs from a peripheral speed corresponding to the speed at which the object to be coated is conveyed.




A sixth aspect of the invention is a bar coating method of bringing a coating bar into contact with an object to be coated, which object is conveyed in a constant direction, so as to apply a coating solution to and remove excess coating solution from the object to be coated, comprising the steps of: supplying the object to be coated; and forming a bead of the coating solution between the object to be coated and the coating bar with a weir member disposed upstream of the coating bar in a direction in which the object to be coated is conveyed, wherein clearance between the weir member and the object to be coated is maintained at a predetermined value of no more than 5 mm.




Further, in the sixth aspect, the coating bar is rotated at a peripheral speed that differs from a peripheral speed corresponding to the speed at which the object to be coated is conveyed.




In the bar coating apparatus according to the fifth aspect, the coating bar is brought into contact with the object to be coated, which is conveyed, and the coating solution is applied to the object to be coated. At this time, the bead of the coating solution is formed among the weir member, the coating bar and the object to be coated.




The clearance between the weir member and the object to be coated is maintained in a predetermined value of 5 mm or less by the clearance-maintaining mechanism. When the upper limit of the clearance is defined, the trapping of the entrained air is reduced (preferably, entrained air is not generated), so that the bead can be maintained stably. For this reason, the coated surface quality of the object to be coated is stabilized, and even in the case where the conveyance speed of the object to be coated is increased, the uniform coated surface quality can be obtained.




In addition, the weir member itself may be approached to and/or be separated from the object to be coated, or the pressing member may press the object to be coated and move the object to be coated so as to approach to and/or separate from the weir member.




Further, since the coating bar is not rotated by friction with the object to be coated, but is actively rotated by the rotation drive at a peripheral speed different from a peripheral speed corresponding to the conveyance speed of the object to be coated, the bead formed among the weir plate, the coating bar and the object to be coated can be stable. Therefore, for example, even in cases where the conveyance speed of the object to be coated is increased and the viscosity of the coating solution is increased, the uniform coated surface quality can be obtained.




In the bar coating method according to the sixth aspect, the coating bar is brought into contact with the object to be coated, which is conveyed, and the coating solution is transferred and applied to the object to be coated. At this time, the bead of the coating solution is formed among the weir member, the coating bar and the object to be coated.




Here, the clearance between the weir member and the object to be coated is maintained in a predetermined value of 5 mm or less. When the upper limit of the clearance is defined, the trapping of the entrained air is reduced (preferably, entrained air is not generated), and the bead can be maintained stably. For this reason, the coated surface quality of the object to be coated is stable, and even in the case where, for example, the conveyance speed of the object to be coated is increased, the uniform coated surface quality can be obtained.




In addition, since the coating bar is not rotated by friction with the object to be coated, but is actively rotated at a peripheral speed different from a peripheral speed corresponding to the conveyance speed of the object to be coated. As a result, the bead formed among the weir member, the coating bar and the object to be coated can be stabilized. Therefore, for example, even in cases where the conveyance speed of the object to be coated is increased and the viscosity of the coating solution is increased, the uniform coated surface quality can be obtained.




In the invention, the length of the clearance does not have a lower limit value from a viewpoint of reducing entrained air trapped in the coating solution. However, in order to prevent unnecessary contact of the weir member with the object to be coated, it is preferable that the length is maintained at 0.1 mm or more.




In addition, the “different periphery speed” includes the case where the coating bar rotates in the same direction as the conveyance direction of the object to be coated and the case where the coating bar rotates in the opposite direction of the conveyance direction of the object to be coated.




A seventh aspect of the invention is a bar coating apparatus comprising: a coating bar for contacting an object to be coated, which object is conveyed in a constant direction, so as to apply a coating solution to and remove excess coating solution from the object to be coated; a weir member for forming a bead of the coating solution between the object to be coated and the coating bar, the weir member being disposed upstream of the coating bar in a direction in which the object to be coated is conveyed; and a rotational drive for rotating the coating bar at a peripheral speed that differs from a peripheral speed corresponding to the speed at which the object to be coated is conveyed.




Further, in the seventh aspect, the number of revolutions of the coating bar is within ±500/min.




Furthermore, in the seventh aspect, the bar coating apparatus further comprises a switching mechanism for switching a rotational driving force of the rotational drive between a transmitting state, in which the driving force is transmitted to the coating bar, and a non-transmitting state, in which the driving force is not transmitted to the coating bar.




An eighth aspect of the invention is a bar coating method of bringing a coating bar into contact with an object to be coated, which object is conveyed in a constant direction, so as to apply a coating solution to and remove excess coating solution from the object to be coated, comprising the steps of: supplying the object to be coated; and rotating the coating bar at a peripheral speed that differs from a peripheral speed corresponding to the speed at which the object to be coated is conveyed.




Further, in the eighth aspect, the number of revolutions of the coating bar is within ±500/min.




In the bar coating apparatus according to the seventh aspect, the coating bar is brought into contact with the object to be coated, which is conveyed, and the coating solution is applied to the object to be coated. In the bar coating apparatus, the coating bar is not rotated by friction with the object to be coated, but is actively rotated by the rotation drive so that its peripheral speed is different from a peripheral speed corresponding to the conveyance speed of the object to be coated. As a result, the bead of the coating solution formed among the weir member, the coating bar and the object to be coated can be stabilized. Therefore, for example, in cases where the conveyance speed of the object to be coated is increased and the viscosity of the coating solution is increased, the uniform coated surface quality can be obtained.




In addition, the number of revolutions of the coating bar is not particularly limited as long as its peripheral speed is different from a peripheral speed corresponding to the conveyance speed of the object to be coated. However, the number of revolutions of the coating bar is within ±500/min, so that the bead can be securely stabilized.




Further, the rotational driving force of the rotation drive can be prevented from being transmitted to the coating bar by the switching mechanism. As a result, the coating bar can be rotated by friction with the object to be coated as the conventional structure.




In the bar coating method according to the eighth aspect, the coating bar is not rotated by friction with the object to be coated, but is actively rotated at a peripheral speed different from a peripheral speed corresponding to the conveyance speed of the object to be coated. As a result, the bead of the coating solution can be stabilized. Therefore, for example, even in cases where the conveyance speed of the object to be coated is increased and the viscosity of the coating solution is increased, the uniform coated surface quality can be obtained.




In addition, the number of revolutions of the coating bar is not particularly limited as long as its peripheral speed is different from a peripheral speed corresponding to the conveyance speed of the object to be coated as mentioned above. However, when the number of revolutions of the coating bar is within ±500/min, the bead can be securely stabilized.




The “number of revolution” is indicated by “+” when the contact portion of the coating bar with the object to be coated moves in the same direction as the conveyance direction of the object to be coated. Therefore, when the number of revolutions is indicated by “−”, the contact portion of the coating bar with the object to be coated moves in the opposite direction of the conveyance direction of the object to be coated.











BRIEF DESCRIPTION OF THE DRAWINGS





FIG. 1

is a perspective view showing a schematic structure of a bar coating apparatus according to a first embodiment of the present invention.





FIG. 2A

is a front view showing a schematic structure of the bar coating apparatus when not coating, according to the first embodiment of the invention.





FIG. 2B

is a front view showing the schematic structure of the bar coating apparatus when coating, according to the first embodiment of the invention.





FIG. 2C

is a front view showing the schematic structure of the bar coating apparatus when coating, according to the first embodiment of the invention.





FIG. 3

is a plan view showing a rotation drive of the bar coating apparatus according to the first embodiment of the invention.





FIG. 4

is a side view showing the rotation drive of the bar coating apparatus according to the first embodiment of the invention.





FIG. 5

is an explanatory diagram illustrating a clearance between an aluminum web and a weir plate in the bar coating apparatus of the invention.





FIG. 6A

is a front view showing a schematic structure of the bar coating apparatus when not coating, according to a second embodiment of the invention.





FIG. 6B

is a front view showing a schematic structure of the bar coating apparatus when coating, according to the second embodiment of the invention.





FIG. 6C

is a front view showing a schematic structure of the bar coating apparatus when coating, according to the second embodiment of the invention.





FIG. 7A

is a front view showing a schematic structure of the bar coating apparatus when not coating, according to a third embodiment of the invention.





FIG. 7B

is a front view showing a schematic structure of the bar coating apparatus when coating, according to the third embodiment of the invention.





FIG. 7C

is a front view showing a schematic structure of the bar coating apparatus when coating, according to the third embodiment of the invention.





FIG. 8

is a perspective view showing a schematic structure of the bar coating apparatus according to a fourth embodiment of the invention.





FIG. 9A

is a front view showing a schematic structure of the bar coating apparatus when not coating, according to the fourth embodiment of the invention.





FIG. 9B

is a front view showing a schematic structure of the bar coating apparatus when coating, according to the fourth embodiment of the invention.





FIG. 10

is a plan view showing the rotation drive of the bar coating apparatus according to the fourth embodiment of the invention.





FIG. 11

is a side view showing the rotation drive of the bar coating apparatus according to the fourth embodiment of the invention.





FIG. 12A

is a front view showing a schematic structure of the bar coating apparatus when not coating, according to a fifth embodiment of the invention.





FIG. 12B

is a front view showing a schematic structure of the bar coating apparatus when coating, according to the fifth embodiment of the invention.





FIG. 13A

is a front view showing a schematic structure of the bar coating apparatus when not coating, according to a sixth embodiment of the invention.





FIG. 13B

is a front view showing a schematic structure of the bar coating apparatus when coating, according to the sixth embodiment of the invention.





FIG. 14

is a perspective view showing a schematic structure of the bar coating apparatus according to a seventh embodiment of the invention.





FIG. 15A

is a front view showing a schematic structure of the bar coating apparatus when not coating, according to the seventh embodiment of the invention.





FIG. 15B

is a front view showing a schematic structure of the bar coating apparatus when coating, according to the seventh embodiment of the invention.





FIG. 16

is a plan view showing the rotation drive of the bar coating apparatus according to the seventh embodiment of the invention.





FIG. 17

is a side view showing the rotation drive of the bar coating apparatus according to the seventh embodiment of the invention.





FIG. 18

is an explanatory diagram illustrating a clearance between an aluminum web and a weir plate in the bar coating apparatus according to the seventh embodiment of the invention.





FIG. 19

is a perspective view showing a schematic structure of the bar coating apparatus according to an eighth embodiment of the invention.





FIG. 20A

is a front view showing a schematic structure of the bar coating apparatus when not coating, according to the eighth embodiment of the invention.





FIG. 20B

is a front view showing a schematic structure of the bar coating apparatus when coating, according to the eighth embodiment of the invention.





FIG. 21

is a plan view showing the rotation drive of the bar coating apparatus according to the eighth embodiment of the invention.





FIG. 22

is a side view showing the rotation drive of the bar coating apparatus according to the eighth embodiment of the invention.





FIG. 23

is a cross section showing a schematic structure of a conventional bar coating apparatus.











DESCRIPTION OF THE PREFERRED EMBODIMENTS





FIGS. 1

,


2


A,


2


B and


2


C show a bar coating apparatus


12


according to a first embodiment of the present invention. The bar coating apparatus


12


is incorporated into a manufacturing line of a planographic printing plate precursor. The bar coating apparatus


12


is used for applying a coating solution


50


(photosensitive solution or the like) to an aluminum web


14


, which is a substrate of the planographic printing plate precursor. The aluminum web


14


is conveyed in the longitudinal direction thereof at a predetermined conveyance speed by a conveyance device (not shown). Hereafter, “conveyance direction” refers to the conveyance direction of the aluminum web


14


and the direction is indicated by an arrow F in the drawings. Moreover, “width direction” refers to a direction of the width of the aluminum web


14


and is indicated by an arrow W in the drawings.




The bar coating apparatus


12


has a coating bar


16


which is arranged so as to come in contact with the aluminum web


14


from below. The coating bar


16


is formed into an approximately columnar shape (or approximately cylindrical shape), and is supported by a bearing member


18


so that its longitudinal direction coincides with the width direction of the aluminum web


14


.




An upper surface of the bearing member


18


is a supporting surface


18


S which is formed into an arc shape along an outer peripheral surface of the coating bar


16


. The coating bar


16


contacts the supporting surface


18


S and is rotatably supported thereon.




Weir plates


20


and


22


are arranged on upstream and downstream sides of the bearing member


18


, respectively. Predetermined clearances are provided between the weir plates


20


,


22


and the bearing member


18


, respectively. The clearance between the weir plate


20


on the upstream side and the bearing member


18


serves as a coating solution supply path


24


. A coating solution


50


, which is fed from a coating solution supply device (not shown), passes through the coating solution supply path


24


and is successively raised by rotation of the coating bar


16


so as to be transferred to the aluminum web


14


. Further, upstream of the portion at which the aluminum web


14


and the coating bar


16


contact, a bead


52


of the coating solution


50


is formed among the aluminum web


14


, the weir plate


20


, and the coating bar


16


.




As shown in

FIGS. 2A

,


2


B and


2


C, the bearing member


18


and the weir plates


20


,


22


are held integrally by a holder


28


so as to compose a coating device


30


. Moreover, support rolls


32


and


34


which come in contact with the aluminum web


14


from the opposite side to the coating device


30


(i.e., from above the aluminum web


14


) are disposed both upstream and downstream of the coating device


30


, respectively (in

FIG. 1

, the support rolls


32


and


34


are not shown). When the support rolls


32


and


34


press down upon the aluminum web


14


from above, a predetermined tension is being applied to the aluminum web


14


, and thus, the aluminum web


14


can be brought into contact with the coating bar


16


.




When an elevating device (not shown) is driven, the bearing member


18


and the weir plates


20


,


22


composing the coating device


30


can be integrally moved vertically. As shown in

FIG. 2A

, in a state where the coating device


30


is lowered down away from the aluminum web


14


, the coating bar


16


does not come in contact with the aluminum web


14


. Therefore, the coating solution


50


is not applied to the aluminum web


14


. However, as shown in

FIG. 2B

, by lifting up the coating device


30


, the coating bar


16


is brought into contact with the aluminum web


14


, and the aluminum web


14


can be coated with the coating solution


50


. Further, the contact pressure can be adjusted to a desired pressure by slightly moving the coating device vertically while maintaining the contact between the coating bar


16


and the aluminum web


14


. As a result, appropriate coating can be carried out to meet the needs of different types of aluminum webs


14


and coating solutions


50


.





FIGS. 3 and 4

show schematic structures of a rotation drive


36


for driving the rotation of the coating bar


16


.




The rotation drive


36


is structured to include a motor and a reduction device and the like, and has a drive source


38


for generating a rotational driving force at a predetermined torque and at a predetermined angular velocity. An output shaft


40


of the drive source


38


is connected to a shaft


44


via a first universal joint


42


. Further, the shaft


44


is connected to a switching member


48


via a second universal joint


46


. The switching member


48


moves between a transmission position where the switching member


48


is connected to the coating bar


16


to enable to transmit rotational driving force thereto (a position shown by a solid line in

FIG. 3

) and a non-transmission position, where the connection with the coating bar


16


is released and the rotational driving force is not transmitted (a position shown by the two-dot chain line in FIG.


3


).




In addition, since the drive source


38


is connected to the coating bar


16


via the two universal joints


42


and


46


, the rotational driving force of the drive source


38


can be transmitted to the coating bar


16


while an angle between the output shaft


40


of the drive source


38


and the coating bar


16


is being always kept constant (parallel in the present embodiment). For example, in the case where the coating device


30


is slightly moved vertically or, as shown by the two-dot chain line in

FIG. 4

, the coating device


30


is lowered down so that the coating bar


16


is separated from the aluminum web


14


, the output shaft


40


of the drive source


38


is parallel with the coating bar


16


, and the coating bar


16


receives the rotational driving force of the drive source


38


so as to rotate.




In the bar coating apparatus


12


of the present embodiment, the coating bar


16


can be actively rotated by the rotational driving force from the drive source


38


so that a peripheral speed of the coating bar


16


differs from a peripheral speed corresponding to the conveyance speed of the aluminum web


14


.




A pressing roll


54


, which comes in contact with the aluminum web


14


from above the aluminum web


14


, namely, the opposite side to the coating bar


16


, is disposed between the support roll


32


and the coating bar


16


. The pressing roll


54


is rotatably supported by a supporting device


55


so that the axial direction thereof coincides with the width direction of the aluminum web


14


. Further, the supporting device


55


supports the pressing roll


54


so as to allow movement in the same direction as a thickness direction of the aluminum web


14


(i.e., the vertical direction). As shown in

FIG. 2A

, the pressing roll


54


contacts the aluminum web


14


to an extent that planarity of the aluminum web


14


between the support rolls


32


and


34


is not impaired, when the coating device


30


is in the lowered position. The pressing roll


54


rotates due to friction with the aluminum web


14


when the aluminum web


14


is conveyed.




In contrast, as shown in

FIGS. 2B and 2C

, where the coating device


30


is raised and the aluminum web


14


is coated with the coating solution


50


, the length CL of the clearance C between the aluminum web


14


and the weir plate


20


(see

FIG. 5

) can be adjusted by moving the pressing roll


54


vertically against the aluminum


14


, which is supported between the support rolls


32


and


34


.




The position of the pressing roll


54


in the conveyance direction is not particularly limited as long as the length of the clearance between the aluminum web


14


and the weir plate


20


can be adjusted. As shown in

FIG. 2B

, if it is assumed that the distance from the center of the coating bar


16


to the center of the pressing roll


54


is a pressing position L when the coating bar


16


and the pressing roll


54


are in contact with the aluminum web


14


so as to allow application of the coating solution


50


, it is preferable that the pressing position L is within the range of 10 to 150 mm, and more preferable in the range of 15 to 60 mm.




The vertical position and the amount of vertical movement of the pressing roll


54


are not particularly limited as long as the length CL of the clearance C between the aluminum web


14


and the weir plate


20


is adjusted so that the position and amount can be within a desirable range. As shown in

FIG. 2C

, if it is assumed that the length from an apex of the coating bar


16


to a lower end position of the pressing roll


54


which is measured in the same direction as the ascent and descent direction of the coating device


30


is a forcing amount P when the coating bar


16


and the pressing roll


54


is in contact with the aluminum web


14


so as to allow application of the coating solution


50


, it is preferable that the forcing amount P is within the range of 1 to 30 mm.




Next, a method of applying the coating solution


50


to the aluminum web


14


using the bar coating apparatus


12


of the present embodiment and a function of the bar coating apparatus


12


will now be described.




When the coating solution


50


is applied to the aluminum web


14


, the aluminum web


14


is conveyed at a constant conveyance speed by the conveyance device (not shown).




In addition, the coating device


30


is lifted up as shown in

FIG. 2B

, and the coating bar


16


is brought into contact with the aluminum web


14


, and the coating solution


50


is supplied from the coating solution supply device (not shown). Here, in the bar coating apparatus


12


of the present embodiment, the aluminum web


14


is pressed by the pressing roll


54


from the opposite side of the coating bar


16


, and the vertical position of the pressing roll


54


is movable by the supporting device


55


. Therefore, the length CL of the clearance C between the aluminum web


14


and the weir plate


20


is adjusted, for example, according to a thickness of the aluminum web


14


, so that the bead


52


formed among the aluminum web


14


, the weir plate


20


and the coating bar


16


can be retained stably. In the cases where the object to be coated is thick, the aluminum web


14


is rigid, and thus the length CL of the clearance C elongates due to lack of pressing by the pressing roll


54


. On the other hand, in cases where a relatively thin aluminum web


14


is used, the rigidity of the aluminum web


14


is low and thus the length CL of the clearance C narrows when not being pressed by the pressing roll


54


. Therefore, the vertical position of the pressing roll


54


is adjusted and the length CL of the clearance C is kept constant (or nearly constant), so that the bead


52


can be kept stable. As a result, the bead


52


arranged among the aluminum web


14


, the weir plate


20


and the coating bar


16


becomes stable. For this reason, coating streak or the like due to disturbance of the bead does not occur in the coated coating solution


50


, and an uniformly coated surface quality can be obtained on the aluminum web


14


.




Needless to say, the length CL of the clearance C fluctuates due to other factors besides the rigidity of the aluminum web


14


. In the bar coating apparatus


12


of the present embodiment, the length CL is maintained constant and the bead


52


can be retained stably regardless of the factors that cause fluctuation of the length CL of the clearance C.




In addition, in the bar coating apparatus


12


of the present embodiment, the switching member


48


is moved to the transmission position of the driving force when coating, as shown by a solid line in FIG.


3


. The rotational driving force of the drive source


38


can be transmitted to the coating bar


16


. As a result, the coating bar


16


is actively rotated at a peripheral speed, which differs from a peripheral speed corresponding to the conveyance speed of the aluminum web


14


.




Generally, when the bead


52


is arranged among the aluminum web


14


, the weir plate


20


and the coating bar


16


, and the bead


52


is viewed from a contact portion T between the aluminum web


14


and the coating bar


16


(shown by the chain line in FIG.


1


), in the case where an edge portion


52


E of the bead


52


draws a periodic curved line in the width direction, the coated surface quality becomes fine. Particularly when the edge portion


52


E has a sine curve shape or a shape close to a sine curve, the coated surface quality becomes even better.




As mentioned above, the peripheral speed of the coating bar


16


is set to be different from the peripheral speed corresponding to the conveyance speed of the aluminum web


14


. As a result, the edge portion


52


E of the bead


52


has a shape similar to the sine curve, and the bead


52


is maintained stably. Therefore, streak coating of the coating solution


50


or the like due to disturbance of the bead does not occur, and a uniform coated surface quality can be obtained.




Particularly in cases where the coating solution


50


having a high viscosity is used, or in cases where the conveyance speed of the aluminum web


14


is increased, the edge portion


52


E of the bead


52


has a shape similar to a sine curve, and the bead


52


can be maintained stably. Therefore, the coated surface quality can be uniform. From this viewpoint, the rotation speed of the coating bar


16


is not particularly limited as long as it is a peripheral speed different from the peripheral speed corresponding to the conveyance speed of the aluminum web


14


.




Needless to say, there are occasions when it is preferable that the coating bar


16


is rotated (driven) by friction with the aluminum web


14


similarly to the conventional structure, depending on the conveyance speed of the aluminum web


14


, the viscosity of the coating solution


50


and the other conditions. In such instances, the rotational driving force of the drive source


38


can be easily prevented from being transmitted to the coating bar


16


just by moving the switching member


48


to the non-transmission position of the driving force, as shown by the two-dot chain line in FIG.


3


.




A second embodiment of the invention will now be described. Components that are substantially the same as components previously described in the first embodiment are designated by the same reference numerals, and description thereof is omitted.





FIGS. 6A

,


6


B and


6


C show a bar coating apparatus


56


of the second embodiment. In the bar coating apparatus


56


, in addition to a pressing roll


54


that is similar to the first embodiment, a pressing roll


58


is also arranged.




As is clear from

FIGS. 6A

,


6


B and


6


C, the pressing roll


58


is arranged in a position that is symmetrical with the pressing roll


54


with respect to a center line C passing through centers of a coating bar


16


and a bearing member


18


. Moreover, as with to the pressing roll


54


, the pressing roll


58


is rotatably supported by a supporting device


55


so that the axial direction of the pressing roll


58


coincides with the width direction of the aluminum web


14


. Furthermore, the pressing roll


58


is moveable in the same direction as the thickness direction of the aluminum web


14


(i.e., a vertical direction). As shown in

FIG. 6A

, when the coating device


30


is lowered down away from the aluminum web


14


, both the pressing rolls


54


and


58


contact the aluminum web


14


only to an extent that the planarity of the aluminum web


14


between support rolls


32


and


34


are not impaired. The pressing rolls


54


and


58


rotate due to friction with the aluminum web


14


when the aluminum web


14


is conveyed.




The bar coating apparatus


56


of the second embodiment, having the above structure, exhibits the same effects as that of the bar coating apparatus


12


in the first embodiment. Namely, the positions of the pressing rolls


54


and


58


in the vertical direction are adjusted according to conditions such as the thickness of the aluminum web


14


, and thus the length CL of the clearance C between the aluminum web


14


and the weir plate


20


is adjusted to be within a desirable range. Hence, the bead


52


is formed among the aluminum web


14


, the weir plate


20


and the coating bar


16


, and can be retained stably.




In the second embodiment, since the pressing roll


58


is also moved vertically downstream of the coating bar


16


, particularly when there is a anxiety that, for example, the length CL of the clearance C changes due to the conveying state or the like of the aluminum web


14


on the downstream side of the coating bar


16


, the bar coating apparatus


56


stabilizes the bead


50


and makes the coated surface quality of the aluminum web


14


fine.




A third embodiment of the present invention will now be described. Components that are substantially the same as components described in the previous embodiments are designated by the same reference numerals, and description thereof is omitted.





FIG. 7

shows a bar coating apparatus


62


according to the third embodiment of the invention. In the bar coating apparatus


62


, the pressing roll


54


is not provided, and only the pressing roll


58


, which is similar to the pressing roll


58


of the second embodiment, is provided. The pressing roll


58


is supported by the supporting device


55


so as to be movable in the vertical direction.




The bar coating apparatus


62


, having the structure described above, also exhibits the same effects as that of the bar coating apparatus


12


in the first embodiment. Namely, the vertical position of the pressing roll


58


is adjusted according to conditions such as the thickness of the aluminum web


14


, so that the amount of deflection of the aluminum web


14


changes on the downstream side of the coating bar


16


. Therefore, a deflection amount of the aluminum web


14


also changes on the upstream side of the coating bar


16


, and the length CL of the clearance C between the aluminum web


14


and the weir plate


20


is adjusted. As a result, the bead


52


formed among the aluminum web


14


, the weir plate


20


and the coating bar


16


is retained stably, and the coated surface quality of the aluminum web


14


can be fine.




As described above in the first through third embodiments of the invention, the vertical position of at least one of the pressing rolls


54


and


58


is changed according to various condition such as the thickness of the aluminum web


14


, and the length CL of the clearance C is adjusted. This ensures that the coated surface quality of the aluminum web


14


can be uniform, even if the aluminum web


14


has an uneven thickness.




A fourth embodiment of the present invention will now be described. Components that are substantially the same as components described in the previous embodiments are designated by the same reference numerals, and description thereof is omitted.





FIGS. 8

,


9


A and


9


B show a bar coating apparatus


212


according to the fourth embodiment. The bar coating apparatus


212


is incorporated into a manufacturing line of a planographic printing plate precursor. The bar coating apparatus


212


is used for applying a coating solution


50


(photosensitive solution or the like) to an aluminum web


14


, which is a substrate of the planographic printing plate precursor. The aluminum web


14


is conveyed in the longitudinal direction thereof at a predetermined conveyance speed by a conveyance device (not shown).




The bar coating apparatus


212


has a coating bar


216


which is arranged so as to come in contact with the aluminum web


14


from below. The coating bar


216


is formed into an approximately columnar shape (or approximately cylindrical shape), and is supported by a bearing member


18


so that its longitudinal direction coincides with the width direction of the aluminum web


14


.




An upper surface of the bearing member


218


is a supporting surface


218


S which is formed into an arc shape along an outer peripheral surface of the coating bar


216


. The coating bar


216


contacts the supporting surface


218


S and is rotatably supported thereon.




Weir plates


220


and


222


are arranged on upstream and downstream sides of the bearing member


218


, respectively. Predetermined clearances are provided between the weir plates


220


,


222


and the bearing member


218


, respectively. The clearance between the weir plate


220


on the upstream side and the bearing member


218


serves as a coating solution supply path


224


. A coating solution


50


, which is fed from a coating solution supply device (not shown), passes through the coating solution supply path


224


and is successively raised by rotation of the coating bar


216


so as to be transferred to the aluminum web


14


. Further, upstream of the portion at which the aluminum web


14


and the coating bar


216


contact, a bead


52


of the coating solution


50


is formed among the aluminum web


14


, the weir plate


220


, and the coating bar


216


.




As shown in

FIGS. 9A and 9B

, the bearing member


218


and the weir plates


220


,


222


are held integrally by a holder


228


so as to compose a coating device


230


. Moreover, support rolls


232


and


234


which come in contact with the aluminum web


14


from the opposite side to the coating device


230


(i.e., from above the aluminum web


14


) are disposed both upstream and downstream of the coating device


230


, respectively (in

FIG. 8

, the support rolls


232


and


234


are not shown). When the support rolls


232


and


234


press down upon the aluminum web


14


from above, a predetermined tension is being applied to the aluminum web


14


, and thus, the aluminum web


14


can be brought into contact with the coating bar


216


.




When an elevating device (not shown) is driven, the bearing member


218


and the weir plates


220


,


222


composing the coating device


230


can be integrally moved vertically. As shown in

FIG. 9A

, in a state where the coating device


230


is lowered down away from the aluminum web


14


, the coating bar


216


does not come in contact with the aluminum web


14


. Therefore, the coating solution


50


is not applied to the aluminum web


14


. However, as shown in

FIG. 9B

, when the coating device


230


is lifted up, the coating bar


216


is brought into contact with the aluminum web


14


so that the coating solution


50


can be applied. Moreover, when the coating device


230


is moved up or down while contact is being maintained, a desirable contact pressure is obtained, so that the coating can be carried out in accordance with the different types of the aluminum webs


14


and the coating solutions


50


.





FIGS. 10 and 11

show schematic structures of a rotation drive


236


for driving the rotation of the coating bar


216


.




The rotation drive


236


is structured to include a motor and a reduction device and the like, and has a drive source


238


for generating a rotational driving force at a predetermined torque and at a predetermined angular velocity. An output shaft


240


of the drive source


238


is connected to a shaft


244


via a first universal joint


242


. Further, the shaft


244


is connected to a switching member


248


via a second universal joint


246


. The switching member


248


moves between a transmission position where the switching member


248


is connected to the coating bar


216


to enable to transmit rotational driving force thereto (a position shown by a solid line in

FIG. 10

) and a non-transmission position, where the connection with the coating bar


216


is released and the rotational driving force is not transmitted (a position shown by the two-dot chain line in FIG.


10


).




In addition, since the drive source


238


is connected to the coating bar


216


via the two universal joints


242


and


246


, the rotational driving force of the drive source


238


can be transmitted to the coating bar


216


while an angle between the output shaft


240


of the drive source


238


and the coating bar


216


is being always kept constant. For example, in the case where the coating device


230


is slightly moved vertically or, as shown by the two-dot chain line in

FIG. 11

, the coating device


230


is lowered down so that the coating bar


216


is separated from the aluminum web


14


, the output shaft


240


of the drive source


238


is parallel with the coating bar


216


, and the coating bar


216


receives the rotational driving force of the drive source


238


so as to rotate.




In the bar coating apparatus


212


of the present embodiment, the coating bar


216


can be actively rotated by the rotational driving force from the drive source


238


so that a peripheral speed of the coating bar


216


differs from a peripheral speed corresponding to the conveyance speed of the aluminum web


14


.




A pressing roll


254


, which comes in contact with the aluminum web


14


from above the aluminum web


14


, namely, the opposite side to the coating bar


216


, is disposed between the support roll


232


and the coating bar


216


. The pressing roll


254


is rotatably supported by a bearing member (not shown) so that the axial direction thereof coincides with the width direction of the aluminum web


14


. As shown in

FIG. 9A

, the pressing roll


254


contacts the aluminum web


14


to an extent that planarity of the aluminum web


14


between the support rolls


232


and


234


is not impaired, when the coating device


230


is in the lowered position. The pressing roll


254


rotates due to friction with the aluminum web


14


when the aluminum web


14


is conveyed.




In contrast, as shown in

FIG. 9B

, when the coating device


230


is lifted up and the aluminum web


14


is coated with the coating solution


50


, the aluminum web


14


is pressed by the support rolls


232


and


234


from above and further pressed by the pressing roll


254


as it is pushed by the coating bar


216


from below. Thus, the aluminum web


14


is conveyed with it being bent slightly upwards and downwards. The aluminum web


14


is conveyed by the pressing roll


254


from the opposite side to the coating bar


216


while the movement in the vertical direction (thickness direction) is being limited. Therefore, the aluminum web


14


is prevented from flapping during conveyance.




The position of the pressing roll


254


in the conveyance direction is not particularly limited as long as the flapping of the aluminum web


14


during conveyance can be prevented. Moreover, also in the present embodiment, it is preferable that a pressing position L shown in

FIG. 9B

is within the range of 10 to 150 mm, and even more preferable within the range of 15 to 60 mm.




The vertical position of the pressing roll


254


is also not limited as long as the flapping of the aluminum web


14


during conveyance can be prevented. Moreover, in the present embodiment, it is preferable that a forcing amount P shown in

FIG. 9B

is within the range of 1 to 30 mm. The forcing amount P can be set to a desirable value by previously setting the position of the pressing roll


254


suitably, and also the desirable value can be obtained by adjusting the amount of lift of the coating device


230


.




Next, a method of applying the coating solution


50


to the aluminum web


14


using the bar coating apparatus


212


of the present embodiment and a function of the bar coating apparatus


212


will now be described.




When the coating solution


50


is applied to the aluminum web


14


, the aluminum web


14


is conveyed at a constant conveyance speed by the conveyance device (not shown).




In addition, the coating device


230


is lifted up as shown in

FIG. 9B

, and the coating bar


216


is brought into contact with the aluminum web


14


, and the coating solution


50


is supplied from the coating solution supply device (not shown). In the bar coating apparatus


212


of the present embodiment, the aluminum web


14


is pressed by the pressing roll


254


from the opposite side of the coating bar


216


, and thus the movement of the aluminum web


14


during conveyance in the thickness direction is limited. Namely, since the flapping of the aluminum web


14


during conveyance is prevented, the aluminum web


14


contacts with the coating bar


216


and the contacting situation is constantly maintained. Further, the vertical movement of the aluminum web


14


with respect to the weir plate


220


is also limited to a constant range. As a result, the bead


52


arranged among the aluminum web


14


, the weir plate


220


and the coating bar


216


becomes stable. For this reason, coating streak or the like due to disturbance of the bead does not occur in the coated coating solution


50


, and an uniformly coated surface quality can be obtained on the aluminum web


14


. Particularly when the conveyance speed of the aluminum web


14


is increased, there is a strong tendency for the aluminum web


14


to flap vertically, but in the bar coating apparatus


212


of the present embodiment, since the flapping of the aluminum web


14


is prevented securely, a uniform coated surface quality can be obtained.




In addition, in the bar coating apparatus


212


of the present embodiment, the switching member


248


is moved to the transmission position of the driving force when coating, as shown by a solid line in FIG.


10


. The rotational driving force of the drive source


238


can be transmitted to the coating bar


216


. As a result, the coating bar


216


is actively rotated at a peripheral speed, which differs from a peripheral speed corresponding to the conveyance speed of the aluminum web


14


.




Generally, when the bead


52


is arranged among the aluminum web


14


, the weir plate


220


and the coating bar


216


, and the bead


52


is viewed from a contact portion T between the aluminum web


14


and the coating bar


216


(shown by the chain line in FIG.


8


), in the case where an edge portion


52


E of the bead


52


draws a periodic curved line in the width direction, the coated surface quality becomes fine. Particularly when the edge portion


52


E has a sine curve shape or a shape close to a sine curve, the coated surface quality becomes even better.




As mentioned above, the peripheral speed of the coating bar


216


is set to be different from the peripheral speed corresponding to the conveyance speed of the aluminum web


14


. As a result, the edge portion


52


E of the bead


52


has a shape similar to the sine curve, and the bead


52


is maintained stably. Therefore, streak coating of the coating solution


50


or the like due to disturbance of the bead does not occur, and a uniform coated surface quality can be obtained.




Particularly in cases where the coating solution


50


having a high viscosity is used, or in cases where the conveyance speed of the aluminum web


14


is increased, the edge portion


52


E of the bead


52


has a shape similar to a sine curve, and the bead


52


can be maintained stably. Therefore, the coated surface quality can be uniform. From this viewpoint, the rotation speed of the coating bar


216


is not particularly limited as long as it is a peripheral speed different from the peripheral speed corresponding to the conveyance speed of the aluminum web


14


.




Needless to say, there are occasions when it is preferable that the coating bar


216


is rotated (driven) by friction with the aluminum web


14


similarly to the conventional structure, depending on the conveyance speed of the aluminum web


14


, the viscosity of the coating solution


50


and the other conditions. In such instances, the rotational driving force of the drive source


238


can be easily prevented from being transmitted to the coating bar


216


just by moving the switching member


248


to the non-transmission position of the driving force, as shown by the two-dot chain line in FIG.


10


.




A fifth embodiment of the invention will now be described. Components that are substantially the same as components described in the previous embodiments are designated by the same reference numerals, and description thereof is omitted.





FIGS. 12A and 12B

show a bar coating apparatus


256


of the fifth embodiment. In the bar coating apparatus


256


, in addition to a pressing roll


254


that is similar to the fourth embodiment, a pressing roll


258


is also arranged.




As is clear from

FIGS. 12A and 12B

, the pressing roll


258


is arranged in a position that is symmetrical with the pressing roll


254


with respect to a center line C passing through centers of the coating bar


216


and the bearing member


218


. Moreover, as with the pressing roll


254


, the pressing roll


258


is rotatably supported by a supporting member (not shown) so that its axial direction coincides with the width direction of the aluminum web


14


. As shown in

FIG. 12A

, when the coating device


230


is lowered down, the pressing roll


258


contacts the aluminum web


14


only to the extent that the planarity of the aluminum web


14


between the support rolls


232


and


234


are not impaired. The pressing rolls


254


and


258


rotate due to friction with the aluminum web


14


when the aluminum web


14


is conveyed.




The bar coating apparatus


256


of the second embodiment, having the above structure, exhibits the same effects as that of the bar coating apparatus


212


in the fourth embodiment. Namely, the flapping of the aluminum web


14


is prevented, so that the bead


52


is stabilized and a good-coated surface quality can be obtained.




Further, the pressing roll


258


also contacts the aluminum web


14


on the downstream side of the coating bar


216


so that the flapping is prevented. Especially, in such cases where there is a concern that the bead


52


could become unstable due to the flapping of the aluminum web


14


on the downstream side of the coating bar


216


, the bead


52


is further stabilized so that good coated surface quality of the aluminum web


14


can be obtained in the bar coating apparatus


256


.




A sixth embodiment of the present invention will now be described. Components that are substantially the same as components described in the previous embodiments are designated by the same reference numerals, and description thereof is omitted.





FIGS. 13A and 13B

show a bar coating apparatus


262


of the sixth embodiment. In the bar coating apparatus


262


of the sixth embodiment, the pressing rolls


254


and


258


of the fourth and fifth embodiments are not provided. However, the support roll


232


on upstream from the coating bar


216


is provided in approximately the same position as the position of the pressing roll


254


is provided in the fourth embodiment.




Therefore, in the bar coating apparatus


262


of the sixth embodiment, the support roll


232


also essentially serves as the pressing roll


254


of the fourth embodiment. Namely, since the aluminum web


14


is pressed upon by the support roll


232


from the opposite side to the coating bar


216


, the flapping of the aluminum web


14


during conveyance is prevented. For this reason, the bead


52


formed among the aluminum web


14


, the weir plate


220


and the coating bar


216


is stabilized, so that a uniform coated surface quality can be obtained on the aluminum web


14


.




In addition, in the bar coating apparatus


262


, as mentioned above, the support roll


232


also serves as the pressing roll


254


, and thus the number of parts is less than in the bar coating apparatus


212


of the fourth embodiment. Therefore, the structure of the bar coating apparatus of the present embodiment is simplified.




As described above, in the fourth through sixth embodiments of the invention, since the flapping of the aluminum web


14


during conveyance is prevented, the bead


52


is stabilized. Therefore, coating streak or the like due to disturbance of the bead does not occur in the coated coating solution


50


and a uniform coated surface quality can be obtained on the aluminum web


14


. Particularly when the conveyance speed of the aluminum web


14


is increased, the flapping of the aluminum web


14


is securely prevented so that a coated surface quality can be maintained uniformly in the bar coating apparatuses


212


,


256


and


262


of the respective embodiments.




A seventh embodiment of the present invention will now be described. Components that are substantially the same as components described in the previous embodiments are designated by the same reference numerals, and description thereof is omitted.





FIGS. 14

,


15


A and


15


B show a bar coating apparatus


312


according to the seventh embodiment of the present invention. The bar coating apparatus


312


is incorporated into a manufacturing line of a planographic printing plate precursor. The bar coating apparatus


312


is used for applying a coating solution


50


(photosensitive solution or the like) to an aluminum web


14


, which is a substrate of the planographic printing plate precursor. The aluminum web


14


is conveyed in the longitudinal direction thereof at a predetermined conveyance speed by a conveyance device (not shown).




The bar coating apparatus


312


has a coating bar


316


which is arranged so as to come in contact with the aluminum web


14


from below. The coating bar


316


is formed into an approximately columnar shape (or approximately cylindrical shape), and is supported by a bearing member


318


so that its longitudinal direction coincides with the width direction of the aluminum web


14


.




An upper surface of the bearing member


318


is a supporting surface


18


S which is formed into an arc shape along an outer peripheral surface of the coating bar


316


. The coating bar


316


contacts the supporting surface


18


S and is rotatably supported thereon.




Weir plates


320


and


322


are arranged on upstream and downstream sides of the bearing member


318


, respectively. Predetermined clearances are provided between the weir plates


320


,


322


and the bearing member


318


, respectively. The clearance between the weir plate


320


on the upstream side and the bearing member


318


especially serves as a coating solution supply path


324


. A coating solution


50


, which is fed from a coating solution supply device (not shown), passes through the coating solution supply path


324


and is successively raised by rotation of the coating bar


316


so as to be transferred to the aluminum web


14


. Further, upstream of the portion at which the aluminum web


14


and the coating bar


316


contact, a bead


52


of the coating solution


50


is formed among the aluminum web


14


, the weir plate


320


, and the coating bar


316


.




As shown in

FIGS. 15A and 15B

, the bearing member


318


and the weir plates


320


,


322


are held integrally by a holder


28


so as to compose a coating device


330


. Moreover, support rolls


332


and


334


which come in contact with the aluminum web


14


from the opposite side to the coating device


330


(i.e., from above the aluminum web


14


) are disposed both upstream and downstream of the coating device


30


, respectively (in

FIG. 14

, the support rolls


332


and


334


are not shown). When the support rolls


332


and


334


press down upon the aluminum web


14


from above, a predetermined tension is being applied to the aluminum web


14


, and thus, the aluminum web


14


can be brought into contact with the coating bar


316


.




When an elevating device (not shown) is driven, the bearing member


318


and the weir plates


320


,


322


composing the coating device


330


can be integrally moved vertically. As shown in

FIG. 15A

, in a state where the coating device


330


is lowered down away from the aluminum web


14


, the coating bar


316


does not come in contact with the aluminum web


14


. Therefore, the coating solution


50


is not applied to the aluminum web


14


. However, as shown in

FIG. 15B

, by lifting up the coating device


330


, the coating bar


316


is brought into contact with the aluminum web


14


, and the aluminum web


14


can be coated with the coating solution


50


. Moreover, when the coating device


330


is slightly moved vertically while contact between the coating bar


316


and the aluminum web


14


is being maintained, a length CL of the clearance C arranged between the weir plate


320


and the aluminum web


14


(see

FIG. 18

) can be maintained so as to have a predetermined value.





FIGS. 16 and 17

show schematic structures of a rotation drive


336


for driving the rotation of the coating bar


316


.




The rotation drive


336


is structured to include a motor and a reduction device and the like, and has a drive source


338


for generating a rotational driving force at a predetermined torque and at a predetermined angular velocity. An output shaft


340


of the drive source


338


is connected to a shaft


344


via a first universal joint


342


. Further, the shaft


344


is connected to a switching member


348


via a second universal joint


346


. The switching member


348


moves between a transmission position where the switching member


348


is connected to the coating bar


316


to enable to transmit rotational driving force thereto (a position shown by a solid line in

FIG. 16

) and a non-transmission position, where the connection with the coating bar


316


is released and the rotational driving force is not transmitted (a position shown by the two-dot chain line in FIG.


16


).




In addition, since the drive source


338


is connected to the coating bar


316


via the two universal joints


342


and


346


, the rotational driving force of the drive source


338


can be transmitted to the coating bar


316


while an angle between the output shaft


340


of the drive source


338


and the coating bar


316


is being always kept constant. For example, in the case where the coating device


330


is slightly moved vertically or, as shown by the two-dot chain line in

FIG. 17

, the coating device


330


is lowered down so that the coating bar


316


is separated from the aluminum web


14


, the output shaft


340


of the drive source


338


is parallel with the coating bar


316


, and the coating bar


316


receives the rotational driving force of the drive source


338


so as to rotate.




In the bar coating apparatus


312


of the present embodiment, the coating bar


316


can be actively rotated by the rotational driving force from the drive source


338


so that a peripheral speed of the coating bar


316


differs from a peripheral speed corresponding to the conveyance speed of the aluminum web


14


.




A pressing roll


354


, which comes in contact with the aluminum web


14


from above the aluminum web


14


, namely, the opposite side to the coating bar


316


, is disposed between the support roll


332


and the coating bar


316


. The pressing roll


354


is rotatably supported by a bearing member (not shown) so that the axial direction thereof coincides with the width direction of the aluminum web


14


. As shown in

FIG. 15A

, the pressing roll


354


contacts the aluminum web


14


to an extent that planarity of the aluminum web


14


between the support rolls


332


and


334


is not impaired, when the coating device


330


is in the lowered position. The pressing roll


354


rotates due to friction with the aluminum web


14


when the aluminum web


14


is conveyed.




In contrast, as shown in

FIG. 15B

, when the coating device


330


is lifted up and the aluminum web


14


is coated with the coating solution


50


, the aluminum web


14


is pressed by the support rolls


332


and


334


from above and further pressed by the pressing roll


354


as it is pushed by the coating bar


316


from below. Thus, the aluminum web


14


is conveyed with it being bent slightly upwards and downwards. The aluminum web


14


is conveyed by the pressing roll


354


from the opposite side to the coating bar


316


while the movement in the vertical direction (thickness direction) is being limited. Therefore, the aluminum web


14


is prevented from flapping during conveyance.




The position of the pressing roll


354


in the conveyance direction is not particularly limited as long as the flapping of the aluminum web


14


during conveyance can be prevented. Moreover, also in the present embodiment, it is preferable that a pressing position L shown in

FIG. 15B

is within the range of 10 to 150 mm, and even more preferable within the range of 15 to 60 mm.




The vertical position of the pressing roll


354


is also not limited as long as the flapping of the aluminum web


14


during conveyance can be prevented. Moreover, in the present embodiment, it is preferable that a forcing amount P shown in

FIG. 15B

is within the range of 1 to 30 mm. The forcing amount P can be set to a desirable value by previously setting the position of the pressing roll


354


suitably, and also the desirable value can be obtained by adjusting the amount of lift of the coating device


330


.




Next, a method of applying the coating solution


50


to the aluminum web


14


using the bar coating apparatus


312


of the present embodiment and a function of the bar coating apparatus


312


will now be described.




When the coating solution


50


is applied to the aluminum web


14


, the aluminum web


14


is conveyed at a constant conveyance speed by the conveyance device (not shown).




In addition, as shown in

FIG. 15B

, the coating device


330


is lifted up and the coating bar


316


is brought into contact with the aluminum web


14


, and the coating solution


50


is supplied from the coating solution supply device (not shown).




At this time, in the bar coating apparatus


312


of the present embodiment, when the coating device


330


is moved vertically, the length CL of the clearance C formed between the weir plate


320


and the aluminum web


14


is adjusted so as to have a predetermined value, and even when the aluminum web


14


is conveyed, the set value can be maintained as shown in FIG.


18


. Generally, when the length CL of the clearance C is large, so-called entrained air is trapped in the solution at the time of coating, and the bead


52


becomes unstable. In cases where the conveyance speed of the aluminum web


14


is increased, the entrained air is especially easily trapped in the solution, and the bead


52


becomes even more unstable. In the present embodiment, the length CL of the clearance C is set to no more than an upper limit value at which the trapping of the entrained air is reduced (preferably, entrained air is not generated), so that the coating solution


50


can be applied. For this reason, even when the conveyance speed of the aluminum web


14


is increased, the bead


52


is stabilized, so that a uniform coated surface quality can be obtained.




In the bar coating apparatus


312


of the present embodiment, the aluminum web


14


is pressed by the pressing roll


354


from the opposite side of the coating bar


316


, and thus the movement of the aluminum web


14


during conveyance in the thickness direction is limited. Namely, since the flapping of the aluminum web


14


during conveyance is prevented, the aluminum web


14


contacts with the coating bar


316


and the contacting situation is constantly maintained. Further, the vertical movement of the aluminum web


14


with respect to the weir plate


320


is also limited to a constant range. As a result, the bead


52


arranged among the aluminum web


14


, the weir plate


320


and the coating bar


316


becomes stable. For this reason, coating streak or the like due to disturbance of the bead does not occur in the coated coating solution


50


, and an uniformly coated surface quality can be obtained on the aluminum web


14


.




A supporting device, which supports the pressing roll


354


and allows vertical movement thereof, may be provided. As a result, the length CL of the clearance C may be maintained in a desirable value by using the supporting device to move the pressing roll


354


vertically in place of the vertical movement of the coating device


330


or using both the vertical movement of the coating device and the pressing roll


354


. Further, it is not necessary for the pressing member to have the above-mentioned roll shape (columnar or cylindrical shape), and it may be a bar-shaped member or a plate member. However, in the case of the roll-shaped member, it is preferable that the diameter thereof is within the range of φ10 to φ200 mm from a viewpoint of the planarity of the aluminum web


14


(supporting body) being secured or prevention of slip at the time of conveyance.




Further, in the bar coating apparatus


312


of the present embodiment, the switching member


348


is moved to the transmission position of the driving force when coating, as shown by a solid line in FIG.


16


. The rotational driving force of the drive source


338


can be transmitted to the coating bar


316


. As a result, the coating bar


316


is actively rotated at a peripheral speed, which differs from a peripheral speed corresponding to the conveyance speed of the aluminum web


14


.




Generally, when the bead


52


is arranged among the aluminum web


14


, the weir plate


320


and the coating bar


316


, and the bead


52


is viewed from a contact portion T between the aluminum web


14


and the coating bar


316


(shown by the chain line in FIG.


14


), in the case where an edge portion


52


E of the bead


52


draws a periodic curved line in the width direction, the coated surface quality becomes fine. Particularly when the edge portion


52


E has a sine curve shape or a shape close to a sine curve, the coated surface quality becomes even better.




As mentioned above, the peripheral speed of the coating bar


316


is set to be different from the peripheral speed corresponding to the conveyance speed of the aluminum web


14


. As a result, the edge portion


52


E of the bead


52


has a shape similar to the sine curve, and the bead


52


is maintained stably. Therefore, streak coating of the coating solution


50


or the like due to disturbance of the bead does not occur, and a uniform coated surface quality can be obtained.




Needless to say, there are occasions when it is preferable that the coating bar


316


is rotated (driven) by friction with the aluminum web


14


similarly to the conventional structure, depending on the conveyance speed of the aluminum web


14


, the viscosity of the coating solution


50


and the other conditions. In such instances, the rotational driving force of the drive source


338


can be easily prevented from being transmitted to the coating bar


316


just by moving the switching member


348


to the non-transmission position of the driving force, as shown by the two-dot chain line in FIG.


16


.




An eighth embodiment of the present invention will now be described. Components that are substantially the same as components described in the previous embodiments are designated by the same reference numerals, and description thereof is omitted.





FIGS. 19

,


20


A and


20


B show a bar coating apparatus


412


according to the eighth embodiment. The bar coating apparatus


412


is incorporated into a manufacturing line of a planographic printing plate precursor. The bar coating apparatus


412


is used for applying a coating solution


50


(photosensitive solution or the like) to an aluminum web


14


, which is a substrate of the planographic printing plate precursor. The aluminum web


14


is conveyed in the longitudinal direction thereof at a predetermined conveyance speed by a conveyance device (not shown).




The bar coating apparatus


412


has a coating bar


416


which is arranged so as to come in contact with the aluminum web


14


from below. The coating bar


416


is formed into an approximately columnar shape (or approximately cylindrical shape), and is supported by a bearing member


418


so that its longitudinal direction coincides with the width direction of the aluminum web


14


.




An upper surface of the bearing member


418


is a supporting surface


418


S which is formed into an arc shape along an outer peripheral surface of the coating bar


416


. The coating bar


416


contacts the supporting surface


418


S and is rotatably supported thereon.




Weir plates


420


and


422


are arranged on upstream and downstream sides of the bearing member


418


, respectively. Predetermined clearances are provided between the weir plates


420


,


422


and the bearing member


418


, respectively. The clearance between the weir plate


420


on the upstream side and the bearing member


218


serves as a coating solution supply path


424


. A coating solution


50


, which is fed from a coating solution supply device (not shown), passes through the coating solution supply path


424


and is successively raised by rotation of the coating bar


416


so as to be transferred to the aluminum web


14


. Moreover, the bead


52


of the coating solution


50


is formed among the aluminum web


14


, the weir plate


420


and the coating bar


416


on the upper stream side of a contact portion between the aluminum web


14


and the coating bar


416


.




As shown in

FIGS. 20A and 20B

, the bearing member


418


and the weir plates


420


,


422


are held integrally by a holder


428


so as to compose a coating device


430


. Moreover, support rolls


432


and


434


which come in contact with the aluminum web


14


from the opposite side to the coating device


430


(i.e., from above the aluminum web


14


) are disposed both upstream and downstream of the coating device


430


, respectively (in

FIG. 19

, the support rolls


432


and


434


are not shown). When the support rolls


432


and


434


press down upon the aluminum web


14


from above, a predetermined tension is being applied to the aluminum web


14


, and thus, the aluminum web


14


can be brought into contact with the coating bar


416


.




When an elevating device (not shown) is driven, the bearing member


418


and the weir plates


420


,


422


composing the coating device


430


can be integrally moved vertically. As shown in

FIG. 20A

, in a state where the coating device


430


is lowered down away from the aluminum web


14


, the coating bar


416


does not come in contact with the aluminum web


14


. Therefore, the coating solution


50


is not applied to the aluminum web


14


. However, as shown in

FIG. 20B

, by lifting up the coating device


430


, the coating bar


416


is brought into contact with the aluminum web


14


, and the aluminum web


14


can be coated with the coating solution


50


. Moreover, while the state that the coating bar


16


contacts with the aluminum web


14


is being maintained, the coating device


430


is moved vertically slightly, so that a desired contact pressure can be provided. As a result, appropriate coating can be carried out to meet the needs of different types of aluminum webs


14


and coating solutions


50


.





FIGS. 21 and 22

show schematic structures of a rotation drive


436


for driving the rotation of the coating bar


416


.




The rotation drive


436


is structured to include a motor and a reduction device and the like, and has a drive source


438


for generating a rotational driving force at a predetermined torque and at a predetermined angular velocity. An output shaft


440


of the drive source


438


is connected to a shaft


444


via a first universal joint


442


. Further, the shaft


444


is connected to a switching member


448


via a second universal joint


446


. The switching member


448


moves between a transmission position where the switching member


448


is connected to the coating bar


416


to enable to transmit rotational driving force thereto (a position shown by a solid line in

FIG. 21

) and a non-transmission position, where the connection with the coating bar


416


is released and the rotational driving force is not transmitted (a position shown by the two-dot chain line in FIG.


21


).




In addition, since the drive source


438


is connected to the coating bar


416


via the two universal joints


442


and


446


, the rotational driving force of the drive source


438


can be transmitted to the coating bar


416


while an angle between the output shaft


440


of the drive source


438


and the coating bar


416


is being always kept constant. For example, in the case where the coating device


430


is slightly moved vertically or, as shown by the two-dot chain line in

FIG. 22

, the coating device


430


is lowered down so that the coating bar


416


is separated from the aluminum web


14


, the output shaft


440


of the drive source


438


is parallel with the coating bar


416


, and the coating bar


416


receives the rotational driving force of the drive source


438


so as to rotate.




In the bar coating apparatus


412


of the present embodiment, the coating bar


416


can be actively rotated by the rotational driving force from the drive source


438


so that a peripheral speed of the coating bar


416


differs from a peripheral speed corresponding to the conveyance speed of the aluminum web


14


.




Next, a method of applying the coating solution


50


to the aluminum web


14


using the bar coating apparatus


412


of the present embodiment and a function of the bar coating apparatus


412


will now be described.




When the coating solution


50


is applied to the aluminum web


14


, the aluminum web


14


is conveyed at a constant conveyance speed by the conveyance device (not shown).




In addition, as shown in

FIG. 20B

, the coating device


430


is lifted up and the coating bar


416


is brought into contact with the aluminum web


14


, and the coating solution


50


is supplied from the coating solution supply device (not shown). In the bar coating apparatus


412


of the present embodiment, the switching member


448


is moved to the transmission position of the driving force when coating, as shown by a solid line in FIG.


21


. The rotational driving force of the drive source


438


can be transmitted to the coating bar


416


. As a result, the coating bar


416


is actively rotated at a peripheral speed, which differs from a peripheral speed corresponding to the conveyance speed of the aluminum web


14


.




Generally, when the bead


52


is arranged among the aluminum web


14


, the weir plate


420


and the coating bar


416


, and the bead


52


is viewed from a contact portion T between the aluminum web


14


and the coating bar


416


(shown by the chain line in FIG.


19


), in the case where an edge portion


52


E of the bead


52


draws a periodic curved line in the width direction, the coated surface quality becomes fine. Particularly when the edge portion


52


E has a sine curve shape or a shape close to a sine curve, the coated surface quality becomes even better.




As mentioned above, the peripheral speed of the coating bar


416


is set to be different from the peripheral speed corresponding to the conveyance speed of the aluminum web


14


. As a result, the edge portion


52


E of the bead


52


has a shape similar to the sine curve, and the bead


52


is maintained stably. Therefore, streak coating of the coating solution


50


or the like due to disturbance of the bead does not occur, and a uniform coated surface quality can be obtained.




Particularly in cases where the coating solution


50


having a high viscosity is used, or in cases where the conveyance speed of the aluminum web


14


is increased, the edge portion


52


E of the bead


52


has a shape similar to a sine curve, and the bead


52


can be maintained stably. Therefore, the coated surface quality can be uniform. From this viewpoint, the rotation speed of the coating bar


416


is not particularly limited as long as it is a peripheral speed different from the peripheral speed corresponding to the conveyance speed of the aluminum web


14


. However, it is preferable that the rotation speed is within ±500 rpm and more preferably within ±200 rpm. Here, “+” shows the case where the contact portion of the coating bar


416


with the aluminum web


14


moves to the same direction as the conveyance direction of the aluminum web


14


. Therefore, in the case of “−”, the contact portion of the coating bar


416


with the aluminum web


14


moves to the opposite direction to the conveyance direction of the aluminum web


14


.




In the present embodiment, the coating bar


416


is essentially rotated at a lower speed than that in the conventional structure where the coating bar


416


is rotated by friction with the aluminum web


14


(the rotational driving force is not given). Therefore, splashing of the coating solution


50


(so-called solution spattering) can be prevented when the coating solution


50


is raised by the coating bar


416


.




In addition, when the coating bar


416


is rotated at a lower speed than that in the conventional structure, the coating solution


50


composing the bead


50


can be prevented also from wrapping around to the downstream from the contact portion


54


on both ends of the aluminum web


14


in the width direction. Therefore, so-called thick-coating of the coating solution


50


on both the ends of the aluminum web


14


in the width direction can be also prevented.




Needless to say, there are occasions when it is preferable that the coating bar


416


is rotated (driven) by friction with the aluminum web


14


similarly to the conventional structure, depending on the conveyance speed of the aluminum web


14


, the viscosity of the coating solution


50


and the other conditions. In such instances, the rotational driving force of the drive source


438


can be easily prevented from being transmitted to the coating bar


416


just by moving the switching member


448


to the non-transmission position of the driving force, as shown by the two-dot chain line in FIG.


21


.




As the coating bars


16


,


216


,


316


and


416


of the invention, the following can be used: A bar having a flat peripheral surface; a wire bar in which a wire is wound around the peripheral surface of the bar in the peripheral direction such that there are substantially no gaps between each wound loop and grooves are formed between adjacent wires; and further, a grooved bar in which a groove is provided along an entire length of the bar in the peripheral direction or in necessary portions, and the like can be used. It is preferable that an outer diameter of the coating bars


16


,


216


,


316


and


416


is within the range of φ1 to 30 mm from a viewpoint of bar rolling accuracy (straightness and roundness), angular moment (torque), weight balance and the like, and even more preferable within the range of φ6 to 20 mm.




In addition, the bearing members


18


,


218


,


318


and


418


are not limited as long as they can securely support the corresponding coating bars


16


,


216


,


316


and


416


, respectively. However, when smooth rotation of the coating bars


16


,


216


,


316


and


416


is considered, the bearing members having a low coefficient of friction with the coating bars


16


,


216


,


316


and


416


are preferable, and further, the bearing members having high resistance to wear are preferable. As materials that satisfy the above-stated conditions, polyethylene resin, fluorine contained resin, polyacetal resin, and the like can be used. When at least the supporting surfaces


18


S,


218


S,


318


S and


418


S (portions that support the corresponding coating bars, respectively) are made of the above materials, the aforementioned effects can be produced.




The structure of the pressing member is not particularly limited as long as it is capable of pressing and preventing flapping of the aluminum web


14


. For example, it is not necessary for the pressing member to be formed into the above-mentioned roll shape (columnar or cylindrical shape), and thus a bar-shaped member or a plate member may also be used. However, when the pressing member has a roll shape, it is preferable that its diameter is within the range of φ10 to φ200 mm, in terms of the planarity of the aluminum web


14


(supporting body) being secured and prevention of slip at the time of conveyance.




In addition, as the object to be coated (supporting body) to be coated with the coating solution


50


by means of the bar coating apparatuses


12


,


212


,


312


and


412


, a band-type object or a sheet-type object may be used, such as a thin plate metal made of aluminum or the like (the above-mentioned aluminum web


14


), paper, plastic film, resin coating paper, synthetic paper and the like. In the case where an aluminum plate is used as the supporting body of the planographic printing plate precursor, A1050, A1100 and A1070 which are pure aluminum materials according to the Japanese Industrial Standard (JIS) can be used, as well as aluminum alloy materials such as Al—Mg based alloy, Al—Mn based alloy, Al—Mn—Mg based alloy, Al—Zr based alloy and Al—Mg—Si based alloy. Materials of the plastic film that can be used are, polyolefines such as polyethylene and polypropylene, vinyl polymers such as polyvinyl acetate, polyvinyl chloride and polystyrene, polyamides such as 6,6-nylon and 6-nylon, polyesters such as polyethylene terephthalate and polyethylene-2,6-naphthalate, cellulose acetates such as polycarbonate, cellulose triacetate, cellulose diacetate or the like is used. Moreover, as the resin to be used for the resin coating paper, polyolefin including polyethylene is typical, but the resin is not limited to this.




The thickness of the aluminum web


14


is not particularly limited, but the aluminum web having a thickness of about 0.01 mm to 1.0 mm is advantageous in terms of handling and versatility.




Further, the coating solution


50


is not limited to the above-mentioned photosensitive solution, and other solution such as an aqueous solution of high-molecular compound, an organic aqueous solution, a pigment dispersion liquid, a colloidal solution, and the like can also be used. As the coating solution


50


for forming a photosensitive layer of the planographic printing plate precursor, photosensitive solutions that form photosensitive layers of the following modes (1) to (11) can be used:




(1) A mode where the photosensitive layer contains infrared absorber, a compound that generates acid due to heat, and a compound that crosslinks due to acid;




(2) A mode where the photosensitive layer contains an infrared absorber and a compound to be alkali resolvable due to heat;




(3) A mode where the photosensitive layer includes two layers, a layer containing a compound that generates a radical due to laser beam emission and a binder soluble with alkali and a multifunctional monomer or prepolymer and an oxygen barring layer;




(4) A mode where the photosensitive layer is composed of two layers: a physical phenomenon nucleus layer; and a silver halide emulsion layer;




(5) A mode where the photosensitive layer includes three layers, a polymeric layer containing a multifunctional monomer and multifunctional binder, a layer containing silver halide and a reducing agent, and an oxygen barring layer;




(6) A mode where the photosensitive layer is composed of two layers, a layer containing novolac resin and naphthoquinonediazido, and a layer containing silver halide;




(7) A mode where the photosensitive layer includes an organic photoconductor;




(8) A mode where the photosensitive layer is composed of two to three layers, a laser beam absorbing layer, which is removed by laser beam emission, and a lipophilic layer and/or a hydrophilic layer;




(9) A mode where the photosensitive layer contains a compound that absorbs energy and generates acid, a high-molecular compound having a functional group in a side chain that generates sulfonic acid or carboxylic acid due to acid, and a compound which absorbs visible light so as to give energy to an acid generator;




(10) A mode where the photosensitive layer contains a quinonediazide compound and a novolac resin;




(11) A mode where the photosensitive layer contains a compound that decomposes due to light or ultraviolet rays and forms a structure where its molecules are crosslinked (or its molecules are crosslinked with other molecules in the layer), and a binder that is soluble with alkali.




As the bar coating apparatus of the invention, the bar coating apparatuses


12


,


212


,


312


and


412


, which apply the photosensitive solution to the aluminum web


14


(supporting body) in the manufacturing line that manufactures a planographic printing plate precursor, are described in the above explanation, but the apparatuses are not limited to the aforementioned usage.




Examples 1, 2, 3 and 4 of the invention will now be detailed. However, the invention is not limited to the Examples.




EXAMPLE 1




In Example 1, the bar coating apparatus


12


of the first embodiment was used to apply the coating solution


50


to the aluminum web


14


.




First, an aluminum plate was subject to the necessary treatments such as graining, etching, electrolytic surface-roughing and anodizing, so as to obtain the aluminum web


14


. The aluminum web


14


was coated with the coating solution


50


by the bar coating apparatus


12


, then it was dried, and then wound up into a roll shape. In addition, the aluminum web was unwound, and the coated surface quality was evaluated by visual inspection.




The coating conditions were set as follows:




Width of the aluminum web: 500 mm




Thickness of the aluminum web: 0.3 mm, 0.2 mm




Conveyance speed: 50 m/min




Coating amount: 0.02 l/m


2






Diameter of the coating bar: 10 mm




Number of revolutions of the coating bar: −50/min (reverse rotation)




Viscosity of the coating solution: 5 mPa·s




Diameter of the pressing roll: φ50 mm




Pressing position: L: 30 mm




The forcing amount P was changed variously according to the above conditions, so that the length CL of the clearance C, the coating properties of the coating solution


50


to the aluminum web


14


, and the coated surface quality of the aluminum web


14


(particularly, coating streak due to disturbance of the bead) were evaluated. Moreover, as for a bar coating apparatus in the structure without the pressing roll


54


, the same evaluation was made for comparison.



















TABLE 1











Thickness




Existence/







Coated surface







of




nonexistence




Forcing






quality (existence/







aluminum




of pressing




amount




Length of




Coating properties




nonexistence of







web




roll




P




clearance




(stability of bead)




coating streak)






























Comparative




0.3 mm




Nonexistent









6.0 mm




X (unstable)




X (existent)






Example 1-1






Example 1-1




0.3 mm




Existent




  8 mm




4.0 mm




⊚ (stable)




⊚ (nonexistent)






Example 1-2




0.2 mm




Existent




  8 mm




5.5 mm




◯ (slightly unstable)




◯ (slightly existent)






Example 1-3




0.2 mm




Existent




  10 mm




4.0 mm




⊚ (stable)




⊚ (nonexistent)






Example 1-4




0.2 mm




Existent




  14 mm




1.0 mm




⊚ (stable)




⊚ (nonexistent)






Example 1-5




0.2 mm




Existent




14.7 mm




0.5 mm




⊚ (stable)




⊚ (nonexistent)






Example 1-6




0.2 mm




Existent




15.2 mm




0.1 mm




⊚ (stable)




⊚ (nonexistent)














In the table, the ⊚ symbol denotes an acceptable result, namely, where a problem or disadvantage did not arise. The ◯ symbol denotes a result that is somewhat inferior to ⊚ but that did not cause problems and disadvantages in practical use. Results marked by X indicate that problems and/or disadvantages arose.




As is clear, in the examples from Table 1, when the length CL of the clearance C is in a constant range (within 5.5 mm), the coating properties and the coated surface quality become acceptable, and particularly when the length CL of the clearance C does not exceed 4.0 mm (Example 1-1, Example 1-3 to Example 1-6), the coating properties and the coated surface quality became particularly better.




On the other hand, when coating was carried out by the bar coating apparatus in the structure without the pressing roll


54


(Comparative Example 1-1), the length CL of the clearance C could not be adjusted. As a result, the bead was unstable, and the coated surface quality deteriorated to an extent that causes problems and disadvantages.




EXAMPLE 2




In Example 2, the bar coating apparatus


212


of the fourth embodiment was used so as to apply the coating solution


50


to the aluminum web


14


.




First, an aluminum plate was subject to the necessary treatments such as graining, etching, electrolytic surface-roughing, and anodizing, so as to obtain the aluminum web


14


. The aluminum web


14


was coated with the coating solution


50


by the bar coating apparatus


212


, then it was dried, and then wound up into a roll shape. Further, the aluminum web was unwound, and the coated surface quality was evaluated by visual inspection.




The coating conditions were set as follows:




Width of the aluminum web: 500 mm




Thickness of the aluminum web: 0.3 mm




Conveyance speed: 100 m/min




Coating amount: 0.02 l/m


2






Diameter of the coating bar: 10 mm




Number of revolutions of the coating bar: −50/min (reverse rotation)




Viscosity of the coating solution: 5 mPa·s




Diameter of the pressing roll: φ50 mm




Forcing amount P: 2 mm




Normally, the conveyance speed of the aluminum web


14


in the manufacturing operation of the planographic printing plate precursor is mostly 50 m/min or less. Therefore, the above conveyance speed (100 m/min) is relatively high as the conveyance speed of the aluminum web


14


in the manufacturing operation of the planographic printing plate precursor.




The pressing position L was changed within the range of 10 to 150 mm according to the above conditions, so that the coating properties of the coating solution


50


to the aluminum web


14


, and the coated surface quality of the aluminum web


14


(particularly, coating streak due to disturbance of the bead) were evaluated. Moreover, as for a bar coating apparatus in the structure without the pressing roll


54


, the same evaluation was made for comparison.




As for the results, the evaluation was roughly divided into three ranges where the pressing position L was within a range of 10 mm to 60 mm (Example 2-1), a range greater than 60 mm to 100 mm (Example 2-2) and a range greater than 100 mm to 150 mm (Example 2-3). For this reason, the results are shown according to these three ranges, respectively.

















TABLE 2











Existence/





Coating




Coated surface







non-





properties




quality (existence/







existence of




Pressing




(flapping of




nonexistence of







pressing roll




position L




aluminum web)




coating streak)




























Com-




Nonexistent




 —




X (existent)




X (existent)






parative






example






2-1






Example




Existent




10 mm to




⊚ (nonexistent)




⊚ (nonexistent)






2-1





60 mm






Example




Existent




larger than




◯ (extremely




◯ (extremely






2-2





60 mm to




slightly




slightly existent)








100 mm




existent)






Example




Existent




larger than




Δ (slightly




Δ (slightly






2-3





100 mm to




existent)




existent)








150 mm














In the table, the ⊚ symbol denotes an acceptable result, namely, where problems or disadvantages did not arise. The ◯ symbol denotes a result that is somewhat inferior to ⊚ but that did not cause problems and disadvantages. The Δ symbol denotes a result that is inferior to ◯ but that did not cause significant problems or disadvantages depending on the final usage of the planographic printing plate precursor. In other words, the planographic printing plate precursor is sufficiently useful even in cases where the result is denoted as Δ. Results marked by X indicates that problems and/or disadvantages arose.




As is clear from Table 2, when the pressing position L was within the range of 10 mm to 60 mm (Example 2-1), the flapping of the aluminum web


14


was extremely small, and the coated surface quality was good. Moreover, when the pressing position L was within the range greater than 60 mm to 100 mm (Example 2-2), coating streak occurred on the aluminum web


14


due to disturbance of the bead, but was extremely little, and problem and disadvantage practically did not arise. Further, when the pressing position L was adjusted within the range greater than 100 mm to 150 mm (Example 2-3), the similar coating streak as described above occurred, but problems did not arise depending on the usage of the planographic printing plate precursor.




On the other hand, when the coating was carried out by the bar coating apparatus in the structure without the pressing roll


254


(Comparative Example 2-1), the flapping of the aluminum web


14


was large and the bead was not stable, and coating streak occurred, and the coated surface quality deteriorated to an extent that causes problems and disadvantages.




EXAMPLE 3




In Example 3, the bar coating apparatus


312


of the seventh embodiment was used to apply the coating solution


50


to the aluminum web


14


.




First, an aluminum plate was subject to the necessary treatments such as graining, etching, electrolytic surface-roughing and anodizing, so as to obtain the aluminum web


14


. The aluminum web


14


was coated with the coating solution


50


by the bar coating apparatus


312


, then it was dried, and then wound up into a roll shape. Further, the aluminum web was unwound, and the coated surface quality was evaluated by visual inspection.




The coating conditions were set as follows:




Width of the aluminum web: 500 mm




Thickness of the aluminum web: 0.3 mm




Conveyance speed: 100 m/min




Coating amount: 0.02 l/m


2






Diameter of the coating bar: 10 mm




Number of revolution of the coating bar: −50/min (reverse rotation)




Viscosity of the coating solution: 10 mPa·s




Diameter of the pressing roll: φ50 mm




Pressing position L: 30 mm




Normally, the conveyance speed of the aluminum web


14


in the manufacturing operation of the planographic printing plate precursor is mostly 50 m/min or less. Therefore, the above conveyance speed (100 m/min) is relatively high as the conveyance speed of the aluminum web


14


in the manufacturing operation of the planographic printing plate precursor.




The length CL of the clearance C was changed within the range of 5.0 mm to 0.1 mm under the above conditions, and the coating properties of the coating solution


50


to the aluminum web


14


and the coated surface quality of the aluminum web


14


(particularly coating streak due to disturbance of the bead) were evaluated for the respective lengths. Moreover, the similar evaluation was made in the case where the length CL of the clearance C was adjusted to 7.0 mm and 6.0 mm as comparison.
















TABLE 3












Coating









properties




Coated surface quality







Length of




(stability of




(existence/nonexistence







clearance




bead)




of coating streak)



























Comparative




7.0 mm




X (unstable)




X (existent)






Example 3-1






Comparative




6.0 mm




X (unstable)




X (existent)






Example 3-2






Example 3-1




5.0 mm




◯ (stable)




◯ (nonexistent)






Example 3-2




4.0 mm




◯ (stable)




◯ (nonexistent)






Example 3-3




1.0 mm




◯ (stable)




◯ (nonexistent)






Example 3-4




0.5 mm




◯ (stable)




◯ (nonexistent)






Example 3-5




0.1 mm




◯ (stable)




◯ (nonexistent)














In the Table, the ◯ symbol denotes an acceptable result, namely, where problems and disadvantages did not arise, and the X symbol denotes that problems and/or disadvantages arose.




As is clear from Table 3, when the length CL of the clearance C was adjusted within the range of 0.1 mm to 5.0 mm (Examples 3-1 to 3-5), the bead became stable, and the coated surface quality was good.




On the other hand, when the length CL of the clearance C was adjusted to 7.0 mm and 6.0 mm (Comparative Examples 3-1 and 3-2), the bead was not stable, and coating streak was generated, and the coated surface quality deteriorated to an extent that causes problems and disadvantages.




EXAMPLE 4




In Example 4, the bar coating apparatus


412


of the eighth embodiment was used to apply the coating solution


50


to the aluminum web


14


.




First, an aluminum plate was subject to the necessary treatments such as graining, etching, electrolytic surface-roughing and anodizing, so as to obtain the aluminum web


14


. The aluminum web


14


was coated with the coating solution


50


by the bar coating apparatus


412


(at this time, as shown in the following Table 4, the coating bar


416


was rotated at a peripheral speed different from a peripheral speed corresponding to the conveyance speed of the aluminum web


14


), then it was dried, and then wound up into a roll shape. Further, the aluminum web was unwound, and the coated surface quality was evaluated by visual inspection.




The coating conditions were set as follows:




Width of the aluminum web: 500 mm




Thickness of the aluminum web: 0.3 mm




Conveyance speed: 150 m/min




Coating amount: 0.02 l/m


2






Diameter of the coating bar: 10 mm




Number of revolution of the coating bar: −50/min (reverse rotation)




Viscosity of the coating solution: 15 mPa·s




In addition, as the comparative example, when the conveyance speed of the aluminum web


14


was 50 m/min and the viscosity of the coating solution was 2 mPa·s or 5 mPa·s (Comparative Example 4-1 or 4-2), when the conveyance speed of the aluminum web


14


was 100 m/min and the viscosity of the coating solution was 5 mPa·s (Comparative Example 4-3) and when the conveyance speed of the aluminum web


14


was 150 m/min and the viscosity of the coating solution was 15 mPa·s (Comparative Example 4-4), coating bar


416


was driven to be rotated by friction with the aluminum web


14


, so that the coated surface quality could be evaluated similarly to the Examples 4-1 to 4-6.




Normally, the conveyance speed of the aluminum web


14


in the manufacturing operation of the planographic printing plate precursor is mostly 50 m/min or less. Therefore, the above conveyance speed (100 m/min and 150 m/min) is relatively high as the conveyance speed of the aluminum web


14


in the manufacturing operation of the planographic printing plate precursor.


















TABLE 4











Number of





Viscosity of









revolutions




Conveyance




coating





Coated surface quality







of coating




speed




solution




Coating properties




(existence/nonexistence







bar (/min)




(m/min)




(mPa · s)




(stability of bead)




of coating streak)





























Comparative




+1590 (driven)




50




2




◯ (stable)




◯ (nonexistent)






Example 4-1






Comparative




+1590 (driven)




50




5




X (unstable)




X (existent)






Example 4-2






Comparative




+3180 (driven)




100




5




X (unstable)




X (existent)






Example 4-3






Comparative




+4770 (driven)




150




15




X (unstable)




X (existent)






Example 4-4






Example 4-1




 +700 drive




150




15




Δ (slightly unstable)




Δ (slightly existent)






Example 4-2




 +500 drive




150




15




◯ (stable)




◯ (nonexistent)






Example 4-3




 +200 drive




150




15




⊚ (extremely stable)




⊚ (nonexistent)






Example 4-4




 −200 drive




150




15




⊚ (extremely stable)




⊚ (nonexistent)






Example 4-5




 −500 drive




150




15




◯ (stable)




◯ (nonexistent)






Example 4-6




 −700 drive




150




15




Δ (slightly unstable)




Δ (slightly existent)














In the table, the ⊚ symbol denotes an acceptable result, namely, where problems and disadvantages did not arise. The ◯ symbol denotes a result that is somewhat inferior to ⊚ but did not cause problems and disadvantages in practical use. The Δ symbol denotes a result that is further inferior to ◯ but did not cause significant problems or disadvantages depending on the final usage of the planographic printing plate precursor. In other words, the planographic printing plate precursor is sufficiently useful even in cases where the result is denoted as Δ. Results marked by X indicates that problems and/or disadvantages arose.




As is clear from Table 4, in the case where the coating bar


416


rotated at a peripheral speed different from a peripheral speed corresponding to the conveyance speed of the aluminum web


14


, even when the conveyance speed of the aluminum web


14


was high and the viscosity of the coating solution


50


was high, the coated surface quality was good (see Example 4-1 through Example 4-6). Particularly when the coating bar


416


rotated in the range of +500 rpm to −500 rpm, the coated surface quality was good regardless of types and applications of the planographic printing plate precursor (see Example 4-2 through Example 4-5). When the coating bar


416


rotated in the range of +200 rpm to −200 rpm, the coated surface quality of the planographic printing plate precursor was even better (see Example 4-3 and Example 4-4).




On the other hand, in the case where the coating bar


416


was driven to be rotated, when the conveyance speed of the aluminum web


14


was 50 m/min and the viscosity of the coating solution


50


was 2 mPa·s (Comparative Example 4-1), the bead was stable and good coated surface quality could be obtained. However, when the viscosity of the coating solution


50


was 5 mPa·s (Comparative Example 4-2) and the conveyance speed of the aluminum web


14


was 100 m/min (Comparative Example 4-3), and in the case where the viscosity of the coating solution was 15 mPa·s and the conveyance speed of the aluminum web


14


was 150 m/min (Comparative Example 4-4), the bead was unstable, and the coated surface quality deteriorated to an extent that causes problems and inconveniences.




Since the invention has the above structure, even if the conveyance speed of the object to be coated is increased or the viscosity of the coating solution is increased, the uniform coated surface quality can be obtained.



Claims
  • 1. A bar coating method of bringing a coating bar into contact with an object to be coated, which object is conveyed in a constant direction, comprising the steps of:a. supplying the object to be coated; b. pressing, with a pressing member disposed near the coating bar, the object to be coated from a side thereof opposite from the coating bar, wherein a distance between a center of the coating bar and a pressing position of the pressing member is within a range of 15 to 60 mm; c. moving, in correspondence to a coating state, the pressing member in a thickness direction of the object to be coated; and d. applying a coating solution to and removing excess coating solution from the object to be coated.
  • 2. The bar coating method of claim 1, wherein the coating bar is rotated at a peripheral speed that differs from a peripheral speed corresponding to the speed at which the object to be coated is conveyed.
  • 3. A bar coating method of bringing a coating bar into contact with an object to be coated, which object is conveyed in a constant direction, comprising the steps of:a. supplying the object to be coated; b. forming a bead of the coating solution between the object to be coated and the coating bar with a weir member disposed upstream of the coating bar in a direction in which the object to be coated is conveyed; and c. applying a coating solution to and removing excess coating solution from the object to be coated, wherein a clearance between the weir member and the object to be coated is maintained at a predetermined value of no more than 5 mm.
  • 4. The bar coating method of claim 3, wherein the coating bar is rotated at a peripheral speed that differs from a peripheral speed corresponding to the speed at which the object to be coated is conveyed.
  • 5. The bar coating method according to claim 3, further comprising:pressing, with a pressing member disposed near the coating bar, the object to be coated from a side thereof opposite from the coating bar, wherein a distance between a center of the coating bar and a pressing position of the pressing member is within a range of 15 to 60 mm.
  • 6. A bar coating method of bringing a coating bar into contact with an object to be coated, which object is conveyed in a constant direction, comprising the steps of:a. supplying the object to be coated; b. rotating the coating bar at a peripheral speed that differs from a peripheral speed corresponding to the speed at which the object to be coated is conveyed; c. forming a bead of a coating solution between the object to be coated and the coating bar with a weir member disposed upstream of the coating bar in a direction in which the object to be coated is conveyed; and d. applying a coating solution to and removing excess coating solution from the object to be coated, wherein a clearance between the weir member and the object to be coated is maintained at a predetermined value of no more than 5 mm.
  • 7. The bar coating method of claim 6, wherein the number of revolutions of the coating bar is within ±500/mm.
  • 8. A bar coating apparatus comprising:a coating bar for contacting an object to be coated, which object is conveyed in a constant direction, so as to apply a coating solution to and remove excess coating solution from the object to be coated; a weir member for forming a bead of the coating solution between the object to be coated and the coating bar, the weir member being disposed upstream of the coating bar in a direction in which the object to be coated is conveyed; a pressing member for pressing the object to be coated from a side thereof opposite from the coating bar, the pressing member being disposed near the coating bar; and a moving device for moving the pressing member in a thickness direction of the object to be coated, wherein a distance between a center of the coating bar and a pressing position of the pressing member on the object to be coated is within a range of 15 to 60 mm.
  • 9. The bar coating apparatus of claim 8, wherein the pressing member is a pressing roll that is rotatingly driven by friction with the object to be coated.
  • 10. The bar coating apparatus of claim 9, further comprising a rotational drive for rotating the coating bar at a peripheral speed that differs from a peripheral speed corresponding to the speed at which the object to be coated is conveyed.
  • 11. A bar coating apparatus comprising:a coating bar for contacting an object to be coated, which object is conveyed in a constant direction, so as to apply a coating solution to and remove excess coating solution from the object to be coated; a weir member for forming a bead of the coating solution between the object to be coated and the coating bar, the weir member being disposed upstream of the coating bar in a direction in which the object to be coated is conveyed; and a pressing member for pressing the object to be coated from a side thereof opposite from the coating bar, the member being disposed near the coating bar, wherein a distance between a center of the coating bar and a pressing position of the pressing member on the object to be coated is within a range of 15 to 60 mm.
  • 12. The bar coating apparatus of claim 11, wherein the pressing member is a pressing roll that is rotatingly driven by friction with the object to be coated.
  • 13. The bar coating apparatus of claim 12, further comprising a rotational drive for rotating the coating bar at a peripheral speed that differs from a peripheral speed corresponding to the speed at which the object to be coated is conveyed.
  • 14. A bar coating apparatus comprising:a coating bar for contacting an object to be coated, which object is conveyed in a constant direction, so as to apply a coating solution to and remove excess coating solution from the object to be coated; a weir member for forming a bead of the coating solution between the object to be coated and the coating bar, the weir member being disposed upstream of the coating bar in a direction in which the object to be coated is conveyed; and a clearance-maintaining mechanism for maintaining clearance between the weir member and the object to be coated at a predetermined value of no more than 5 mm.
  • 15. The bar coating apparatus of claim 14, further comprising a pressing member for pressing the object to be coated from a side thereof opposite from the coating bar, the member being disposed near the coating bar, wherein the clearance-maintaining mechanism comprises a moving device for moving at least one of the weir member and the pressing member in a thickness direction of the object to be coated.
  • 16. The bar coating apparatus according to claim 15, further comprising a rotational drive for rotating the coating bar at a peripheral speed that differs from a peripheral speed corresponding to the speed at which the object to be coated is conveyed.
  • 17. A bar coating apparatus comprising:a coating bar for contacting an object to be coated, which object is conveyed in a constant direction, so as to apply a coating solution to and remove excess coating solution from the object to be coated; a weir member for forming a bead of the coating solution between the object to be coated and the coating bar, the weir member being disposed upstream of the coating bar in a direction in which the object to be coated is conveyed; a rotational drive for rotating the coating bar at a peripheral speed that differs from a peripheral speed corresponding to the speed at which the object to be coated is conveyed; and a clearance-maintaining mechanism for maintaining clearance between the weir member and the object to be coated at a predetermined value of no more than 5 mm.
  • 18. The bar coating apparatus of claim 17, wherein the number of revolutions of the coating bar is within ±500/mm.
  • 19. The bar coating apparatus of claim 18, further comprising a switching mechanism for switching a rotational driving force of the rotational drive between a transmitting state, in which the driving force is transmitted to the coating bar, and a non-transmitting state, in which the driving force is not transmitted to the coating bar.
Priority Claims (4)
Number Date Country Kind
2001-277542 Sep 2001 JP
2001-277543 Sep 2001 JP
2001-291205 Sep 2001 JP
2001-302877 Sep 2001 JP
US Referenced Citations (3)
Number Name Date Kind
4263870 Saito et al. Apr 1981 A
5582870 Shigesada et al. Dec 1996 A
20030051371 Ishizuka et al. Mar 2003 A1
Foreign Referenced Citations (1)
Number Date Country
2000-107661 Apr 2000 JP