The present disclosure relates to a battery cell including a current collecting structure and a battery device including the same. More particularly, the present disclosure relates to a battery cell including a current collecting structure capable of reducing a heating value by reducing resistance of the battery cell.
Heat may be generated in prismatic battery cells due to charging or discharging of battery cells. Performance of battery cells may deteriorate due to heat accumulated in battery cells. In addition, a short circuit may occur inside battery cells due to the generated heat, and ignition may occur in battery cells. A structure of battery cells for reducing heat generation inside battery cells has been studied.
An electrode assembly may include a portion coated with an active material and an uncoated portion not coated with an active material and electrically connected to an external terminal. However, when current passes through the uncoated portion, resistance may increase and heat generation may occur due to a current bottleneck.
An increase in resistance and local heat generation may cause a decrease in capacity of a battery cell or a decrease in lifespan of the battery cell.
Present disclosure may be implemented in some embodiments to provide a battery cell capable of reducing heat generation by using a current collecting structure capable of reducing resistance.
In the present disclosure, a battery cell may include an electrode assembly including an active material and a foil, a case accommodating the electrode assembly, a cap assembly connected to the case and including a terminal, and a current collecting structure connecting the foil to the terminal.
According to an embodiment, the foil may include a plurality of anode foils and a plurality of cathode foils. The terminal may include an anode terminal and a cathode terminal. The current collecting structure may include a first current collecting structure connected to the plurality of anode foils and the anode terminal and a second current collecting structure connected to the plurality of cathode foils and the cathode terminal.
According to an embodiment, the current collecting structure may include a clamping portion connected to the foil and a connection portion extending from the clamping portion and contacting the terminal.
According to an embodiment, the foil may be formed to be at least partially folded, and the current collecting structure may be connected to the folded foil.
According to an embodiment, the foil may include an anode foil including a first uncoated portion and a second uncoated portion and a cathode foil including a third uncoated portion and a fourth uncoated portion. The current collecting structure may include a first current collecting structure connected to the anode foil and a second current collecting structure connected to the cathode foil.
According to an embodiment, the first current collecting structure may include a first anode current collecting structure connected to the first uncoated portion and a second anode current collecting structure connected to the second uncoated portion and spaced apart from the first anode current collecting structure. The second current collecting structure may include a first cathode current collecting structure connected to the third uncoated portion and a second cathode current collecting structure connected to the fourth uncoated portion and spaced apart from the first cathode current collecting structure.
According to an embodiment, the terminal may include an anode terminal connected to the first anode current collecting structure and the second anode current collecting structure, and a cathode terminal connected to the first cathode current collecting structure and the second cathode current collecting structure.
According to an embodiment, the current collecting structure may be formed of a conductive metal.
According to an embodiment, the cap assembly may include a first cap assembly connected to a first end portion of the case and including a first terminal, and a second cap assembly connected to a second end portion of the case opposite to the first end portion and including a second terminal. The current collecting structure may include a first current collecting structure connected to the first terminal and a second current collecting structure connected to the second terminal.
According to an embodiment, the cap assembly may include a base plate attached to the case, a first terminal at least partially exposed to the outside of the base plate, and a second terminal spaced apart from the first terminal and at least partially exposed to the outside of the base plate. The current collecting structure may include a first current collecting structure connected to the first terminal and a second current collecting structure connected to the second terminal.
According to an embodiment, the cap assembly may include a base plate attached to the case and an insulator at least partially located between the base plate and the terminal.
According to an embodiment, the cap assembly may include a vent guard connected to a venting portion and the base plate and protecting the venting portion.
According to an embodiment, the foil may include a plurality of anode foils and a plurality of cathode foils. The current collecting structure may include a first current collecting structure connected to the plurality of anode foils and a second current collecting structure connected to the plurality of cathode foils. The terminal may include an anode terminal including a first anode terminal at least partially exposed to the outside of the battery cell and a second anode terminal connected to the first anode terminal and the first current collecting structure and a cathode terminal including a first cathode terminal at least partially exposed to the outside of the battery cell and a second cathode terminal connected to the first cathode terminal and the second current collecting structure.
According to an embodiment, the current collecting structure may include a first clamping portion configured to bring end portions of the plurality of anode foils into close contact with each other and a second clamping portion configured to bring end portions of the plurality of cathode foils into close contact with each other.
In the present disclosure, a battery device including the battery cell may be provided.
Certain aspects, features, and advantages of the present disclosure are illustrated by the following detailed description with reference to the accompanying drawings.
Embodiments of the present disclosure will be more fully described below with reference to the accompanying drawings, in which like symbols indicate like elements throughout the drawings, and embodiments are illustrated. However, embodiments of the claims may be implemented in many different forms and are not limited to the embodiments described herein. The examples given herein are non-limiting and are only examples among other possible examples.
Referring to
The prismatic battery cell 100 includes a rectangular can 104 that may be formed of steel, aluminum, aluminum alloy, plastic, or other metals having sufficient structural strength. The can 104 may be manufactured according to various different methods including deep draw or impact extrusion. The method for manufacturing the can 104 may be combined with wall ironing to achieve the final geometry, thickness, and tolerance. The can 104 may be wrapped with cell cover tape.
A jelly roll 106 includes a stacked anode, cathode, and separator. A jelly roll 106 type electrode assembly configured to have a structure of a long sheet type cathode and a long sheet type anode to which an active material is applied is wound. At the same time, the stacked-type electrode assembly has a structure in which a separator is disposed between a cathode and an anode or has a structure in which a plurality of cathodes and anodes having a predetermined size are sequentially stacked and a separator is disposed between each of the cathodes and the anode. The jelly roll-type electrode assembly is easy to manufacture and has high unit mass and energy density, compared to a sheet-type electrode assembly. In some batteries, one or more jelly rolls 106 are inserted into can 104. Each jelly roll 106 electrode assembly is included inside a polymer jelly roll bag 108 sealed inside the can 104.
Each jelly roll 106 includes a cathode foil 112 formed of aluminum. The aluminum foil is coated with the electrode slurry. A first operation of electrode manufacturing is a slurry mixing process in which an active raw material is combined with a binder, a solvent, and an additive. This mixing process should be performed separately for anode and cathode slurries. Viscosity, density, solids content and other measurable properties of the slurry affect battery quality and electrode uniformity. For example, a slurry having a faster drying rate, a higher solids content, a lower rate capability, and a low viscosity is generated as a solvent content is higher. Thereafter, the cathode slurry is applied to an aluminum foil and dried. A slot die coater is a method of coating a foil in which a slurry is spread through slot gaps on the moving foil receiving tension over rollers. In some embodiments, this may be performed simultaneously on both sides of the foil. This production method enables high speed, while achieving precision in coating thickness. A drying process may be incorporated into a continuous coating. The drying process should achieve three objectives: diffusion of the binder, sedimentation of particles, and evaporation of the solvent. Air floatation is a method of drying the slurry on the foil. Uniformity of the electrode coating and drying process affects the safety, consistency, and life cycle of the prismatic battery cell 100. The electrode should go through a calendaring process in which electrode porosity and twist are controlled by compressing the coated electrode sheet to a uniform thickness and density.
Each jelly roll 106 includes an anode foil 110 formed of copper foil. The anode foil 110 is provided similarly to a cathode foil 112. Each jelly roll 106 may include a cathode connector (not shown) that makes an electrical connection between the inner end portion of the cathode foil 112 and the cathode terminal 128. Each jelly roll 106 may include an anode connector (not shown) that makes an electrical connection between the inner end portion of the anode foil 110 and an anode terminal 126. Each jelly roll 106 may include a cathode connector mask (e.g., a cathode connector mask 118 in
Each prismatic battery cell 100 may have an upper cap assembly 120 welded or otherwise bonded to the top of the can 104. The upper cap assembly 120 may include a base plate 122 attached to the can 104. The base plate 122 isolates the inside and outside of the cell by welding with the can 104. The base plate 122 may serve as a rigid support structure for elements within the upper cap assembly 120. The upper cap assembly 120 may include a plurality of upper insulators 124 to insulate the base plate 122. The upper insulator 124 may prevent leakage of an electrolyte from the prismatic battery cell 100. Additionally, the upper insulator 124 may isolate the can 104 from the cathode foil 112 and prevent penetration of moisture and gases from the outside of the cell. A portion of the upper insulator 124 may protect a current interrupting device. The upper cap assembly 120 includes a cathode terminal 128 electrically connecting the inside and outside of the prismatic battery cell 100. The upper cap assembly 120 includes an anode terminal 126 electrically connecting the inside and outside of the prismatic battery cell 100.
The upper cap assembly 120 may include a venting portion 130 allowing exhaust gases from the prismatic battery cell 100 to be discharged in a controlled direction and at a controlled pressure. The upper cap assembly 120 may include a vent guard 132 protecting the venting portion 130 from the inside of the prismatic battery cell 100 in order to prevent the venting portion 130 from malfunctioning. The upper cap assembly 120 may include an overcharge safety device 134 preventing an external current from being introduced using an internal gas pressure of the prismatic battery cell 100. The upper insulator 124 may be multi-component. In some embodiments, side portions of the upper insulator 124 may be mounted on the edges of the can 104 and the upper cap assembly 120. An electrolyte cap 138 may seal an electrolyte solution inside the prismatic battery cell 100. The upper cap assembly 120 may be referred to as a cap plate or a cap assembly.
The battery cell 100 may include an insulator 136 located between the upper cap assembly 120 and the can 104. In this document, the electrode assembly of the battery cell 100 is described as the jelly roll 106, but the electrode assembly of the battery cell 100 is not limited to the jelly roll 106. For example, the jelly roll 106 may be replaced with a stack type electrode assembly or a Z-folding type electrode assembly. According to an embodiment, the jelly roll 106 described herein may refer to an electrode assembly.
In this document, the can 104 may be referred to as a case.
The upper cap assembly 120 serving as a cover for the prismatic battery cell 100 is a complex assembly including a plurality of welded components. Adhesives may be used instead of welding specific components.
The prismatic battery cell 100 may include the venting portion 130. The venting portion 130 provides overpressure alleviation when temperature and corresponding pressure increase in the prismatic battery cell 100. For example, the venting portion 130 may be activated in a pressure range of 10 to 15 bars. The venting portion 130 may be laser-welded to the upper cap assembly 120.
The prismatic battery cell 100 may include the can 104. The can 104 may generally be formed of deep-drawn aluminum or stainless steel to prevent moisture from entering the cell, while providing diffusion resistance to organic solvents, such as liquid electrolytes. The most important reason the can 104 is typically formed of deep-drawn aluminum alloy or stainless steel is to reduce a welding point to improve the mechanical strength of the can 104. The prismatic battery cell 100 may be filled with an electrolyte. After electrolyte filling, the electrolyte cap 138 may be welded to the upper cap assembly 120 or a locking ball (not shown) may be forced into an opening of the electrolyte cap 138. The cell may have an overcharge safety device 134 that may disconnect current flow when high internal pressure is reached in the prismatic battery cell 100. A rise in pressure is usually a result of high temperatures.
According to an embodiment, the cathode terminal 128 may be provided in plural. For example, the cathode terminal 128 may include a first cathode terminal 128a in which at least a portion is exposed to the outside of the battery cell 100 and a second cathode terminal 128b connected to a cathode foil (e.g., the cathode foil 112 of
According to an embodiment, the anode terminal 126 may be provided in plural. For example, the anode terminal 126 may include a first anode terminal 126a in which at least a portion is exposed to the outside of the battery cell 100 and a second anode terminal 126b connected to an anode foil (e.g., the anode foil 110 of
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According to an embodiment, the battery cell manufacturing process 400 may include a wetting process of the jelly roll 106. For example, the jelly roll 106 may be initially wetted by an electrolyte delivered through an electrolyte injection port. For example, partial vacuum may be formed in the prismatic battery cell 100, and a predetermined amount of electrolyte may be injected through the electrolyte injection port. The partial vacuum may improve the distribution and wetting of all layers within the jelly roll 106. Wetting of all layers within the jelly roll 106 may require a rolling or spinning protocol to enhance wetting.
According to an embodiment, the battery cell manufacturing process 400 may include a quality check process for the initial wetting process, such as checking a weight of the prismatic battery cell 100 immediately after charging. For example, a second electrolyte charging operation in which an electrolyte is charged to achieve a desired weight may be applied to the battery cell. According to an embodiment, the battery cell manufacturing process 400 may include a pre-formation process of charging the prismatic battery cell 100 and discharging gas.
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According to an embodiment (e.g.,
According to an embodiment, the battery cell 100 may include a current collecting structure 700 coupled to the foil 602. For example, the current collecting structure 700 may include a first current collecting structure 710 connected to the anode foil 110 and a second current collecting structure 720 connected to the cathode foil 112. For example, the anode foil 110 may be crimped and welded to the first current collecting structure 710 and the cathode foil 112 may be crimped and welded to the second current collecting structure 720.
In an embodiment, the current collecting structure 700 may be referred to as a clamping structure, a crimp structure, or a connection structure. In an embodiment, the first current collecting structure 710 may be referred to as an anode clamping structure or an anode crimp structure. The second current collecting structure 720 may be referred to as a cathode clamping structure or a cathode crimp structure.
Although the anode foil 110 and the cathode foil 112 are illustrated in the same layer in
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According to an embodiment, the positive electrode active material may include a material (e.g., slurry) capable of providing lithium ions. For example, the positive electrode active material may include at least one of nickel cobalt manganese, nickel cobalt aluminum, lithium iron phosphate, lithium manganese oxide, or lithium cobalt oxide.
According to an embodiment, the negative electrode active material may include a material (e.g., slurry) capable of storing or releasing lithium ions transferred from the positive electrode active material. For example, the negative electrode active material may include at least one of graphite, graphene, silicon dioxide, titanium dioxide, or lithium titanate.
In this document, the anode foil 110 and the cathode foil 112 may be referred to as an uncoated portion of the foil 602 coated with the negative electrode active material and an uncoated portion of the foil 602 coated with the positive electrode active material, respectively.
In
The first length L1 and the first width W1 of the anode foil 110 illustrated in
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According to an embodiment, the electrode plate 103 may have a shape for reducing resistance between the anode foil 110 and the anode terminal (e.g., the anode terminal 126 in
The widths of the anode foil 110 and cathode foil 112 may be selectively designed. According to an embodiment, the widths of the anode foil 110 and the cathode foil 112 may be changed by a die cutting process. For example, a third width W3 of the anode foil 110 of
A fourth width W4 of the cathode foil 112 of
According to an embodiment, the current collecting structure 700 may be designed to correspond to the structures of the foil portions 110 and 112. For example, the width of the current collecting structure 700 may be formed to correspond to the third width W3 of the anode foil 110 and the fourth width W4 of the cathode foil 112.
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According to an embodiment, at least a portion of the electrode plate 103 of
According to an embodiment, the anode foil 110 and the cathode foil 112 may be formed to be longer than normal foil portions. A third length L3 may be 125 to 200% of the first length L1 of
According to an embodiment, the electrode plate 103 may be manufactured by a die-cut process for the foil 602 at least partially folded. In an embodiment, after die cutting, the anode foil 110 and the cathode foil 112 may be folded based on the first folding line F1 and the second folding line F2, respectively. In an embodiment, the process of folding the foil portions 110 and 112 may be performed using a bar or rod placed along the folding lines F1 and F2.
A folding mechanism (not shown) may refer a process or structure for folding the foil portions 110 and 112 before crimping the foil portions 110 and 112 with the current collecting structure 700. The folding mechanism may include a tool (e.g., a bar, rod, or robot) (not shown) for folding the foil portions 110 and 112.
According to an embodiment, by folding the anode foil 110 and the cathode foil 112, a cross-sectional area of the anode foil 110 and the cathode foil 112 and/or a volume of the conductive material may increase and resistance occurring in the anode foil 110 and the cathode foil 112 may decrease.
As the anode foil 110 and the cathode foil 112 are folded, the volume of the conductive material inside the current collecting structure 700 may increase. As the volume of the conductive material increases, resistance may decrease in connection between the jelly roll (e.g., the jelly roll 106 of
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The description of the foil 602, the active material 604, the die-cut foil 608, the anode foil 110, the cathode foil 112, and the current collecting structure 700 of
According to an embodiment, the anode foil 110 and the cathode foil 112 may include a plurality of uncoated portions 110a, 110b, 112a, and 112b. The uncoated portions 110a, 110b, 112a, and 112b may be referred to as electrode tabs.
In an embodiment, one anode foil 110 may include a plurality of uncoated portions 110a and 110b to which the active material 604 is not applied. For example, the anode foil 110 may include a first uncoated portion 110a and a second uncoated portion 110b spaced apart from the first uncoated portion 110a.
In an embodiment, the cathode foil 112 may include a plurality of uncoated portions 112a and 112b to which the active material 604 is not applied. For example, the cathode foil 112 may include a third uncoated portion 112a and a fourth uncoated portion 112b spaced apart from the third uncoated portion 112a.
Since the anode foil 110 and the cathode foil 112 include a plurality of uncoated portions 110a, 110b, 112a, and 112b, a contact area between the anode foil 110 and the anode terminal 126 and a contact area between the cathode foil 112 and the cathode terminal 128 may increase. Since the contact area increases, resistance in the circuit may decrease.
According to an embodiment, the anode foil 110 and/or the cathode foil 112 may be cut through a die-cutting process. For example, by the die cutting process, the anode foil 110 may be formed to have the first uncoated portion 110a and the second uncoated portion 110b. The cathode foil 112 may be formed to have the third uncoated portion 112a and the fourth uncoated portion 112b.
The current collecting structure 700 may include a plurality of current collecting structures 700. For example, the current collecting structure 700 may include a first current collecting structure 710 connected to the anode foil 110 and a second current collecting structure 720 connected to the cathode foil 112. The first current collecting structure 710 may include a first anode current collecting structure 710a connected to the first uncoated portion 110a and a second anode current collecting structure 710b connected to the second uncoated portion 110b. The second current collecting structure 720 may include a first cathode current collecting structure 720a connected to the third uncoated portion 112a and a second cathode current collecting structure 720b connected to the fourth uncoated portion 112b. According to an embodiment, the magnitude of resistance occurring in the electrode plate 103 may be reduced by using the plurality of current collecting structures 700. According to an embodiment, the first anode current collecting structure 710a and the second anode current collecting structure 710b may be connected to an anode terminal (e.g., the second anode terminal 126b of
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According to an embodiment, the electrode assembly 810 may include at least one negative electrode plate, at least one positive electrode plate, and at least one separator 813. The at least one negative electrode plate may include an anode foil 812a and a negative electrode active material 811a coated on the anode foil 812a. The at least one positive electrode plate may include a cathode foil 812b and a positive electrode active material 811b coated on the cathode foil 812b.
The structure of the electrode assembly 810 may be selectively designed. For example, although the electrode assembly 810 including stacked electrode plates is illustrated in
According to an embodiment, the case 820 may provide an accommodating space S for accommodating the electrode assembly 810. The accommodating space S may accommodate an electrolyte solution (not shown) and the electrode assembly 810. Description of the can 104 of
The shape of the case 820 may be selectively designed. For example, according to an embodiment (e.g.,
According to an embodiment, the cap assembly 830 may include a first cap assembly 831 and a second cap assembly 832. The first cap assembly 831 may be connected to a first end portion (e.g., the end portion located on the right side of the case 820 in
According to an embodiment, the current collecting structure 840 may electrically connect the electrode assembly 810 and the terminals 833 and 834. For example, the current collecting structure 840 may be connected to the foil portions 812a and 812b of the electrode assembly 810 and the terminals 833 and 834 of the cap assembly 830. For example, the current collecting structure 840 may include a first current collecting structure 841 connected to the anode foil 812a and anode terminal 833 and a second current collecting structure 842 connected to the cathode foil 812b and the cathode terminal 834. The description of the current collecting structure 700 of
According to an embodiment, the current collecting structure 840 may have a shape for connecting the plurality of foil portions 812a and 812b. For example, the current collecting structure 840 may include clamping portions 841a and 842a pressing the foil (e.g., the anode foil 812a or the cathode foil 812b). The current collecting structure 840 may include connection portions 841b and 842b extending from the clamping portions 841a and 842a. The connection portions 841b and 842b may be bonded to terminals (e.g., the anode terminal 833 or the cathode terminal 834).
According to an embodiment, the electrode assembly 810 may include a plurality of anode foils 812a and a plurality of cathode foils 812b, and the clamping portions 841a and 842a may be coupled, while providing pressure to the plurality of anode foils 812a or the plurality of cathode foils 812b. For example, the clamping portions 841a and 842a of the current collecting structure 840 may include a hinge structure (not shown) or an elastic structure (not shown), and provide pressure so that the plurality of anode foils 812 or the plurality of cathode foils are brought into contact with each other.
According to an embodiment, the current collecting structure 840 may include a first clamping portion 841a configured to bring end portions of the plurality of anode foils 812a into close contact with each other and a second clamping portion 842a configured to bring end portions of the plurality of cathode foils 812b into close contact with each other.
The plurality of anode foils 812a or the plurality of cathode foils 812b may be accommodated in the clamping portions 841a and 842a and electrically connected to the clamping portions 841a and 842a. According to an embodiment, the clamping portions 841a and 842a may be referred to as a crimp structure or a clamping structure. According to an embodiment, the connection portions 841b and 842b may be electrically connected to the anode terminal 833 or the cathode terminal 834.
The current collecting structure 840 may include a plurality of current collecting structures 841 and 842. According to an embodiment, the first current collecting structure 841 may include a first clamping portion 841a connected to the plurality of anode foils 841a and a first extending portion 841b extending from the first clamping portion 841a. The second current collecting structure 842 may include a second clamping portion 842a connected to the plurality of cathode foils 812b and a second extending portion 842b extending from the second clamping portion 842a.
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The battery device 10 may include a battery management system (BMS) 20 for controlling the plurality of battery cells 100 or the battery module. The battery management system 20 may be disposed within the housing 10.
A structure of the housing 10 may be selectively designed. For example, the shape of the housing 10 may be selectively changed. In an embodiment, the housing 10 may include a cover (not shown) covering the plurality of battery cells 100.
The functions performed in the processes and methods may be implemented in a different order. In addition, the schematic operations and actions are provided as examples only, and some of the operations and actions may be optional, combined into fewer operations and actions, or extended to additional operations and actions without detracting from the essence of the disclosed embodiments.
According to an embodiment of the present disclosure, an increase in resistance and heat generation due to current bottleneck may be reduced.
According to an embodiment of the present document, since an overheated battery cell is detected or monitored using the thermochromic member, operator convenience for replacing a battery cell in which an event occurs may be improved. In addition, test costs may be reduced and quality of the battery device may be improved.
Only specific examples of implementations of certain embodiments are described. Variations, improvements and enhancements of the disclosed embodiments and other embodiments may be made based on the disclosure of this patent document.
This patent document claims the benefits of U.S. Provisional Patent Application No. 63/427,648 filed on Nov. 23, 2022, the disclosure of which is incorporated herein by reference in its entirety.
Number | Date | Country | |
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63427648 | Nov 2022 | US |