The present application claims priority to Korean Patent Application No. 10-2021-0150114 filed on Nov. 3, 2021 in the Republic of Korea, the disclosures of which are incorporated herein by reference.
The present disclosure relates to a battery, and more particularly, to a battery module and a battery pack with improved safety and a vehicle including the battery module and the battery pack.
As the demand for portable electronic products such as laptops, video cameras, and mobile phones has recently rapidly increased and the commercialization of robots, electric vehicles, etc. has begun in earnest, research on high-performance secondary batteries capable of repeated charging/discharging has been actively conducted.
Currently commercialized secondary batteries include nickel cadmium batteries, nickel hydride batteries, nickel zinc batteries, and lithium secondary batteries. Among them, lithium secondary batteries are in the spotlight because they have almost no memory effect compared to nickel-based secondary batteries, and thus, have advantages of free charge/discharge, very low self-discharge rate, and high energy density.
A lithium secondary battery mainly uses a lithium-based oxide and a carbon material as a positive electrode active material and a negative electrode active material, respectively. A lithium secondary battery includes an electrode assembly in which a positive electrode plate and a negative electrode plate coated with a positive electrode active material and a negative electrode active material are located with a separator therebetween, and a casing in which the electrode assembly is air-tightly accommodated with an electrolyte, that is, a battery case.
In general, according to a shape of a casing, lithium secondary batteries may be classified into can-type secondary batteries in which an electrode assembly is received in a metal can, and pouch-type secondary batteries in which an electrode assembly is received in a pouch of an aluminum laminate sheet.
Recently, secondary batteries have been widely used for driving or energy storage not only in small devices such as portable electronic devices but also in medium and large-sized devices such as electric vehicles and energy storage systems (ESSs). A plurality of secondary batteries may be electrically connected to each other and accommodated together in a module case to constitute one battery module. A plurality of battery modules may be connected to each other to constitute one battery pack.
However, when a plurality of secondary batteries (battery cells) or a plurality of battery modules are densely arranged in a narrow space, they may be vulnerable to a thermal event. In particular, when an event such as thermal runaway occurs in a battery module, high-temperature gas, flame, or heat may be generated. When the gas, flame, or heat is not appropriately controlled, a fire or explosion may occur in the battery module, and a fire or explosion may also occur in other battery modules. Also, a medium or large-sized battery pack, for example, a battery pack for an electric vehicle, may include a large number of battery cells and battery modules to increase a capacity and/or output. Furthermore, in the case of a battery pack mounted on an electric vehicle or the like, there may be a person such as a driver around the battery pack. Accordingly, when a thermal event occurring in a specific battery module is not appropriately controlled and a chain reaction such as thermal propagation occurs, large property damage as well as loss of life may be caused.
The present disclosure is designed to solve the problems of the related art, and therefore the present disclosure is directed to providing a battery module with an improved structure to improve safety when a thermal event occurs in the battery module, and a battery pack and a vehicle including the battery module.
However, the technical purpose to be solved by the present disclosure is not limited to the above, and other objects not mentioned herein will be clearly understood by one of ordinary skill in the art from the following disclosure.
In one aspect of the present disclosure, there is provided a battery module including a cell assembly including one or more battery cells, a module case having an inner space in which the cell assembly is accommodated, and an expansion member located in the module case, and configured to fill at least a part of an empty space in the module case by being expanded in volume when heat is supplied.
The expansion member may include a phase-change material.
Also, the battery module may further include a fire extinguishing member containing a fire extinguishing material, and configured to release the fire extinguishing material therein when the expansion member is expanded.
Also, the expansion member may be located between the cell assembly and the fire extinguishing member.
Also, the fire extinguishing member may be located over the cell assembly.
Also, a venting hole may be formed in the module case, wherein the expansion member is configured to close at least a part of the venting hole when being expanded.
Also, a degree of expansion of the expansion member may be partially different.
Also, the expansion member may include a plurality of expansion portions having different reaction temperatures for expansion.
In another aspect of the present disclosure, there is also provided a battery pack including the battery module according to the present disclosure.
According to another aspect of the present disclosure, there is provided a battery pack including a cell assembly including one or more battery cells, a pack case having an inner space in which the cell assembly is accommodated, and an expansion member located in the pack case, and configured to fill at least a part of an empty space in the pack case by being expanded in volume when heat is supplied.
According to another aspect of the present disclosure, there is provided a vehicle including the battery module or the battery pack according to the present disclosure.
According to the present disclosure, even when a thermal event occurs in a battery module, safety against the thermal event may be improved.
In particular, according to an aspect of the present disclosure, when a thermal event occurs in a battery module, an empty space may be filled to suppress a fire.
Furthermore, according to an embodiment of the present disclosure, because introduction of external oxygen is prevented or suppressed, a fire may be prevented.
Also, according to an embodiment of the present disclosure, because leakage of a flame or the like is prevented, propagation of thermal runaway or fire to other battery modules may be prevented.
The present disclosure may have various other effects, which will be described in each embodiment, or descriptions of effects that may be easily inferred by one of ordinary skill in the art will be omitted.
The accompanying drawings illustrate a preferred embodiment of the present disclosure and together with the foregoing disclosure, serve to provide further understanding of the technical features of the present disclosure, and thus, the present disclosure is not construed as being limited to the drawing.
Hereinafter, preferred embodiments of the present disclosure will be described in detail with reference to the accompanying drawings. Prior to the description, it should be understood that the terms used in the specification and the appended claims should not be construed as limited to general and dictionary meanings, but interpreted based on the meanings and concepts corresponding to technical aspects of the present disclosure on the basis of the principle that the inventor is allowed to define terms appropriately for the best explanation.
Therefore, the description proposed herein is just a preferable example for the purpose of illustrations only, not intended to limit the scope of the present disclosure, so it should be understood that other equivalents and modifications could be made thereto without departing from the scope of the present disclosure.
Referring to
The cell assembly 100 may include one or more battery cells 110. Each battery cell 110 may refer to a secondary battery. The secondary battery may include an electrode assembly, an electrolyte, and a battery case. In particular, the battery cell 110 provided in the cell assembly 100 may be a pouch-type secondary battery. However, another type of secondary battery, for example, a cylindrical battery or a prismatic battery, may be applied to the cell assembly 100.
A plurality of secondary batteries may be stacked on each other to form the cell assembly 100. For example, the plurality of secondary batteries may be stacked by being arranged in parallel in a horizontal direction (Y axis direction) while erected in a vertical direction (Z axis direction). Each battery cell 110 may include an electrode lead, and the electrode lead may be located at both ends or at one end of the battery cell 110. A secondary battery in which an electrode lead protrudes in both directions may be referred to as a bidirectional cell, and a secondary battery in which an electrode lead protrudes in one direction may be referred to as a unidirectional cell. However, the present disclosure is not limited to a specific type or shape of a secondary battery, and various types of secondary batteries known at the time of filing the present application may be applied to the cell assembly 100.
The module case 200 may include a top plate 210, a base plate 220, and a side plate 230, as shown in
The top plate 210, the base plate 220, and/or the side plate 230 may be formed in a thin sheet shape, that is, a plate shape, but may be formed in a polyhedral shape having a thickness of a certain level or more, for example, a rectangular parallelepiped shape. Furthermore, the side plate 230 may include a left plate 231, a right plate 232, a front plate 233, and a rear plate 234. All or some of the top plate 210, the base plate 220, and/or the side plate 230 may be formed of a metal material. Also, at least some of them may be formed of a plastic material. For example, the left plate 231, the right plate 232, the top plate 210, and the base plate 220 may be formed of a steel material. The front plate 233 and the rear plate 234 may be formed of a plastic material.
At least some of the top plate 210, the base plate 220, and the side plate 230 may be integrally formed with each other. For example, as shown in
However, the module case 200 may be configured in any of various other shapes. For example, the base plate 220 and the four side plates 230 may be integrally formed to constitute a lower case having a box shape. In this case, the top plate 210 may be coupled to an opening portion of an upper end of the lower case having the box shape. In another example, the base plate 220, the left plate 231, the right plate 232, and the top plate 210 may be integrally formed to constitute a case having a pipe shape. In this case, the case having the pipe shape may be referred to as a mono frame.
Various coupling methods may be applied to a configuration in which the top plate 210, the base plate 220, the left plate 231, the right plate 232, the front plate 233, and the rear plate 234 are not integrally manufactured but are coupled in an assembly process of the battery module. For example, the top late 210, the front plate 233, and the rear plate 234 may be coupled to the U-frame by using laser welding or ultrasonic welding. Alternatively, elements of the module case 200 may be coupled to each other by using bolt fastening.
An inner space of the module case 200 may be defined by the top plate 210, the base plate 220, and the side plate 230, and the cell assembly 100 is accommodated in the inner space.
The expansion member 300 may be located in the module case 200. Moreover, one or more expansion members 300 may be included in the module case 200. The expansion member 300 may be configured to be expanded in volume when heat is supplied. In particular, the expansion member 300 may include a material whose volume increases when heat is supplied to reach a certain temperature or higher. Due to this volume expansion, the expansion member 300 may fill at least a part of an empty space in the module case 200. Such a volume expansion configuration will be described in more detail with further reference to
Referring to
For example, there may be an empty space A2 between an upper portion of the cell assembly 100 and a bottom surface of the top late 210 and between a side portion of the cell assembly 100 and the side plate 230, as shown in
In this configuration, the empty space A2 may ensure a tolerance during assembly and provide a heat insulating space. In particular, the battery cell 110 may generate and release heat not only during thermal runaway but also during normal use. In this case, the empty space in the module case 200 may perform a heat insulating function between the battery cells 110 or between the module case 200 and the cell assembly 100. Also, the empty space A2 may provide a path through which, in an initial emergency situation where venting gas is discharged from the battery cell 110, the venting gas is discharged.
When heat is generated and released from at least some of the battery cells 110 provided in the cell assembly 100 due to a thermal event such as thermal runaway, the heat may be supplied to the expansion member 300. Then, the expansion member 300 may be expanded by the supplied heat, and as shown in
According to this aspect of the present disclosure, because an empty space in the module case 200 is filled, a space through which oxygen may be introduced into the battery module may be removed or reduced. Accordingly, in an emergency situation such as thermal runaway, a fire may be prevented from occurring or spreading in the battery module. Also, even when a flame is generated in the battery module, the flame may be blocked or rapidly extinguished.
The expansion member 300 may be formed in a plate shape, as shown in
Also, the expansion member 300 may include a phase-change material. In particular, the expansion member 300 may include a material whose state such as solid, liquid, or gas changes according to a temperature and whose volume increases as a temperature rises. For example, the phase-change material used in the expansion member 300 may be a material whose state changes from solid to liquid by receiving heat and whose volume increases in this case. Alternatively, the phase-change material may include a material whose state changes from liquid to gas, from solid to gas, or from solid to gel or sol when receiving heat and whose volume increases in this case. The present disclosure is not limited to a specific type of the expansion member 300, for example, a specific type of a phase-change material.
The expansion member 300 may be formed so that a material that is expandable by heat, in particular, a phase-change material, is accommodated in a packaging body. In this case, when thermal runaway occurs in the battery module, the phase-change material in the expansion member 300 may be expanded and may leak out of the packaging body. In this case, the packaging body of the expansion member 300 may be configured to be ruptured by expansion of the phase-change material therein or may have an opening that is pre-formed. In particular, when the opening is pre-formed in the packaging body of the expansion member 300, a stopper may be provided at the opening, and the stopper may be configured to be opened when internal pressure increases to a certain level or higher. Alternatively, the packaging body itself may be configured to be expanded together with the expansion material in the expansion member 300. In this case, the expansion material in the expansion member 300 and the packaging body may be expanded together to fill a space in the module case 200. Alternatively, the expansion member 300 may be formed of only a material that is expandable by heat, for example, only a phase-change material, without a separate packaging body.
The expansion member 300 may include a polyurethane (PU) foam composite member or a porous foam (e.g., Si foam) composite member. Moreover, the expansion member 300 may include a composite member in which expanded polypropylene or liquid hydrocarbon is wrapped in a pellet (capsule)-shaped pouch and coupled to polyurethane foam or porous foam. The pouch-type capsule may be a material such as acrylonitrile co-polymers. Also, in this configuration of the expansion member 300, when heat is applied, the pouch-type capsule and the foam may be expanded. Also, in the configuration, when heat is applied to reach a specific temperature, a foam material may start to be foamed. In this case, a foaming start temperature may be appropriately set according to a structure, type, or shape of a battery module or a secondary battery. For example, the foaming start temperature may be 160° C. or higher. Alternatively, the expansion member 300 may include a porous expansion glass. The porous expansion glass may even perform a fire extinguishing function. However, the present disclosure is not necessarily limited to a specific material, type or shape of the expansion member 300.
When various embodiments of the present specification including the present embodiment are described, for parts to which descriptions of the above embodiments are equally or similarly applicable, descriptions thereof are omitted, and different parts are mainly described in each embodiment.
Referring to
In particular, the fire extinguishing member 400 may be configured to release the fire extinguishing material therein when the expansion member 300 is expanded. Moreover, the fire extinguishing member 400 may be configured to be pressed by expansion pressure when the expansion member 300 is expanded by heat. The fire extinguishing member 400 may be configured to release the fire extinguishing material therein when a pressure of a certain level or more is applied to break the exterior part.
For example, a fire extinguishing agent may be sealed in the fire extinguishing member 400, and the fire extinguishing member 400 may have a substantially sheet shape as shown in
According to this embodiment, when thermal runaway occurs in at least one battery cell 110 and heat or flame is ejected, the expansion member 300 may be expanded and thus, the fire extinguishing material may be released from the fire extinguishing member 400 into the module case 200. Then, in the module case 200, the flame may be blocked or a fire may be effectively suppressed due to the fire extinguishing material released from the fire extinguishing member 400.
For example, in an embodiment of
The fire extinguishing member 400 may include any of various fire extinguishing materials known at the time of filing the present application. For example, the fire extinguishing member 400 may include a fire extinguishing material such as sodium hydrogen carbonate, potassium hydrogen carbonate, or ammonium phosphate. Also, the fire extinguishing member 400 may include a powder fire extinguishing material or a granular fire extinguishing material such as a porous expansion glass.
In the embodiment, the expansion member 300 may be located between the cell assembly 100 and the fire extinguishing member 400. That is, the expansion member 300 may be located closer to the cell assembly 100 than the fire extinguishing member 400. For example, referring to the embodiment of
According to the embodiment, when heat generated in the cell assembly 100 is applied to the expansion member 300, the heat may not pass through the fire extinguishing member 400. Accordingly, when heat is generated in the cell assembly 100, the generated heat may be directly transferred to the expansion member 300, and the expansion member 300 may be smoothly expanded by the heat. That is, according to the embodiment, heat of the cell assembly 100 may be well transferred to the expansion member 300 without being disturbed by the fire extinguishing member 400.
Referring to
According to this embodiment of the present disclosure, a fire extinguishing material of the fire extinguishing member 400 may more smoothly contact the cell assembly 100. In particular, as in the embodiment, when the fire extinguishing member 400 releases the fire extinguishing material in a state where the expansion member 300 is located between the fire extinguishing member 400 and the cell assembly 100, the released fire extinguishing material may be introduced into the cell assembly 100 through the through-hole O of the expansion member 300. Accordingly, a fire extinguishing operation of the cell assembly 100 by the fire extinguishing material may be well performed. For example, when the expansion member 300 of
Referring to
Also, a plurality of distribution grooves G may be formed in the base plate 220 to be spaced apart from each other in the front-rear direction. In particular, the distribution groove G formed in the base plate 220 may be connected to the distribution groove formed in the side plate 230. The distribution groove G formed in the base plate 220 may extend long in the left-right direction. In this case, a plurality of battery cells 110 may be stacked on a top surface of the base plate 220 in the left-right direction. Accordingly, the distribution groove G of the base plate 220 may extend long in a stacking direction of the battery cells 110. Furthermore, in an embodiment of
According to this embodiment of the present disclosure, the fire extinguishing material released from the fire extinguishing member 400 may be smoothly supplied to several battery cells 110. For example, referring to
Furthermore, as shown in
Referring to
According to the embodiment, because the fire extinguishing material is supplied from the upper portion of the cell assembly 100, the entire portion of the cell assembly 100 from the upper portion to a lower portion may contact the fire extinguishing material. Accordingly, fire suppression performance and fire extinguishing performance of the cell assembly 100 may be further improved. In particular, in the cell assembly 100, the battery cells 110 may be stacked in the horizontal direction, for example, the left-right direction (Y axis direction), while erected. In this configuration of the cell assembly 100, when the fire extinguishing member 400 is located over the cell assembly 100 as in the above embodiment, the fire extinguishing material may be smoothly provided to all of the battery cells 110.
Also, as shown in
Also, a configuration of the expansion member 300 as shown in
Referring to
In this embodiment, the expansion member 300 may be configured to close at least a part of the venting hole H when expanded. For example, as shown in
According to this embodiment of the present disclosure, external air, in particular, oxygen, may be effectively prevented from being introduced into the module case 200 through the venting hole H. When venting gas is generated in the module case 200, the venting gas may be discharged to the outside through the venting hole H. However, after the venting gas is discharged, oxygen may be introduced into the module case 200 through the venting hole H. However, according to the embodiment, because the venting hole H may be closed by the expansion member 300 after venting gas is discharged, introduction of oxygen through the venting hole H may be prevented. Hence, in this case, exhaust performance through the venting hole H may be ensured, and a fire may be prevented from occurring or spreading through the venting hole H as much as possible.
Referring to
According to this embodiment, a configuration for closing the venting hole H by the expansion of the expansion member 300 may be more easily implemented. Accordingly, in an emergency situation such as thermal runaway, introduction of oxygen through the venting hole H may be more reliably prevented. Also, in the embodiment, a material resistant to a flame or high temperature may be used for the sliding portion S. Accordingly, even when a flame or the like is generated in the battery module, the flame may be reliably prevented from leaking out to the outside through the venting hole H.
As described in the above embodiment, the fire extinguishing member 400 may be included in the battery module according to the present disclosure. Although the expansion member 300 directly presses the fire extinguishing member 400 to discharge a fire extinguishing material of the fire extinguishing member 400 in the above description, the present disclosure is not necessarily limited to this embodiment. For example, the fire extinguishing member 400 may be damaged by an element such as a sharp needle-shaped body when the expansion member 300 is expanded to discharge the fire extinguishing material therein.
In particular, as shown in
In this configuration, when the sliding portion S moves in the direction marked by the arrow B1, that is, rearward, due to expansion of the expansion member 300, the venting hole H may be closed. While the venting hole H is closed, the fire extinguishing member 400 may be ruptured due to the needle-shaped protrusion C provided at the rear end of the sliding portion S. Then, the fire extinguishing material may be ejected into the module case 200 through a ruptured portion of the fire extinguishing member 400.
In particular, in the embodiment, the sliding portion S may be configured to rupture the fire extinguishing member 410 after the venting hole H is closed. To this end, a position of the fire extinguishing member 400 or a shape or a size of the needle-shaped protrusion C may be set so that the sliding portion S contacts the fire extinguishing member 400 after the sliding portion S closes the venting hole H.
According to this embodiment of the present disclosure, because the fire extinguishing material is ejected into the module case 200 after the module case 200 is closed, a fire extinguishing effect by the fire extinguishing material may be further improved. That is, because the fire extinguishing material is ejected in a state where the inside of the module case 200 is sealed by the sliding portion S, the fire extinguishing material may not be discharged to the outside through the venting hole H and may mainly exist only in the module case. Accordingly, in this case, an effect of suppressing a fire by the fire extinguishing material may be increased.
Referring to
According to this embodiment of the present disclosure, when venting gas is generated in the battery module, the venting gas may be easily discharged through the venting hole H formed in the module case 200 and leakage of the expansion member 300 may be prevented. In particular, when the expansion member 300 is changed into a fluid state such as liquid, gas, or gel while being expanded by receiving heat, the expansion member 300 may leak out to the outside of the module case 200. However, in the embodiment, the blocking portion R may prevent leakage of the expansion member 300. For example, in a configuration of
A degree of expansion of the expansion member 300 may be partially different. In particular, for this configuration, the expansion member 300 may include a plurality of expansion portions, which will be described in more detail with reference to
Referring to
According to this configuration of the present disclosure, an effect of discharging venting gas from the inside of the module case 200 to the outside may be further improved. For example, when only the front end portion of the expansion member 300 is expanded and the rear end portion is not expanded yet as shown in
Furthermore, as shown in
According to this embodiment, venting gas in the module case 200 may be guided toward the space A6 where the expansion member 300 is not expanded yet, and the venting gas may be discharged to the outside through the venting hole H. Accordingly, according to the embodiment, when there is venting gas in the module case 200, the venting gas may be smoothly discharged to the outside of the module case 200 when the expansion member 300 is expanded.
In particular, the expansion member 300 may include a plurality of expansion portions having different reaction temperatures for expansion. For example, the expansion member 300 may include a first expansion portion 310 and a second expansion portion 320, as shown in
Moreover, the first expansion portion 310 and the second expansion portion 320 may have different degrees of expansion according to temperature. In particular, the first expansion portion 310 may have a maximum degree of expansion at a temperature T1, and the second expansion portion 320 may have a maximum degree of expansion at a temperature T2 that is different from the temperature T1. A difference in a degree of expansion between the first expansion portion 310 and the second expansion portion 320 may be caused by a difference in a material or a shape of each expansion portion.
Furthermore, in an embodiment of
Also, when an internal temperature of the battery module further increases to reach a higher temperature, for example, T2, the second expansion portion 320 may also be expanded, and the empty space A6 may be filled by the second expansion portion 320. Accordingly, an empty space in an inner space of the module case 200 may be further reduced, and in particular, the venting hole H may be closed. Accordingly, the risk of oxygen introduced into the module case 200 may be further reduced.
A battery pack according to an aspect of the present disclosure may include one or more battery modules according to the present disclosure. Also, the battery pack according to the present disclosure may further include various elements such as a battery management system (BMS) in addition to the battery modules. The BMS may be mounted in an inner space of a battery pack and may control an overall operation such as a charging/discharging operation or a data transmitting/receiving operation of a cell assembly. The BMS may be provided in units of packs, instead of units of modules. In more detail, the BMS may be configured to control or predict a charge/discharge state, a power state, and a performance state of the cell assembly through a pack voltage and pack current. The BMS is known at the time of filing the present application, and thus, a detailed description thereof will be omitted. Also, the battery pack according to the present disclosure may further include various elements of a battery pack known at the time of filing the present application such as a bus bar, a pack case, a relay, and a current sensor.
The battery pack according to another aspect of the present disclosure may not include the module case 200, which will be described with reference to
Referring to
In the battery pack, there is a difference only in that the cell assembly 100, the expansion member 300, and the fire extinguishing member 400 are mounted in the pack case PC, instead of the module case 200, and descriptions of other parts may be equally or similarly applied. For example, most of descriptions made with reference to
For example, although not shown in
The battery module or the battery pack according to the present disclosure may be applied to a vehicle such as an electric vehicle or a hybrid vehicle. That is, a vehicle according to the present disclosure may include the battery module according to the present disclosure or the battery pack according to the present disclosure. Also, the vehicle according to the present disclosure may include various other elements included in a vehicle in addition to the battery module or the battery pack. For example, the vehicle according to the present disclosure may further include a vehicle body, a motor, and a control device such as an electronic control unit (ECU) in addition to the battery module according to the present disclosure.
Also, the battery module or the battery pack according to the present disclosure may be applied to an energy storage system (ESS). That is, an ESS according to the present disclosure may include the battery module according to the present disclosure or the battery pack according to the present disclosure.
It will be understood by one of ordinary skill in the art that when terms indicating directions such as upper, lower, left, right, front, and rear are used, these terms are only for convenience of explanation and may vary according to a position of a target object, a position of an observer, etc.
While one or more embodiments of the present disclosure have been described with reference to the embodiments and figures, the present disclosure is not limited thereto, and it will be understood by one of ordinary skill in the art that various changes in form and details may be made therein without departing from the scope of the present disclosure as defined by the following claims.
Number | Date | Country | Kind |
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10-2021-0150114 | Nov 2021 | KR | national |
Filing Document | Filing Date | Country | Kind |
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PCT/KR2022/016850 | 10/31/2022 | WO |