The present invention contains subject matter related to Japanese Patent Application No. 2004-243892 filed in the Japanese Patent Office on Aug. 24, 2004, the entire contents of which being incorporated herein by reference.
1. Field of the Invention
The invention relates to a battery pack having a circuit substrate in an external package and to its manufacturing method.
2. Description of the Related Arts
In recent years, as a power source of a portable electronic apparatus, a battery pack in which a protecting circuit substrate on that a protecting circuit and the like have been mounted and a battery device are enclosed in an external package has been used. A box-shaped casing formed by upper and lower casings and the like is widely used as an external package which is used for the battery pack as mentioned above (for example, refer to JP-A-2002-260608).
However, the above construction using such a casing has a problem of an increase in thickness. According to the current molding technique, an upper limit value of the thickness of casing is equal to about 0.2 to 0.3 mm. Such a technique that the protecting circuit substrate on which the protecting circuit has been mounted and the battery device are integratedly molded by resin molding has been proposed (for example, refer to JP-A-2003-162987).
However, in the related battery pack with such a construction, since resin melting heat upon molding is directly transferred to electronic parts mounted on the protecting circuit substrate, there is such a problem that the electronic parts are damaged.
It is desirable to provide a battery pack in which a protecting circuit substrate and a battery device can be integrated without damaging electronic parts provided for a protecting circuit and to provide its manufacturing method.
To solve the above problem, according to an embodiment of the present invention, there is provided a battery pack having at least a battery device enclosed in an external package and a cover adapted to be fitted into an opening formed at one end of the battery device enclosed in the external package, wherein
According to the embodiment of the present invention, since the lower molding body exists between the circuit substrate and the molten resin, by filling the molten resin between the cover and the battery device and solidifying it, when the cover and the battery device are adhered, it is possible to prevent heat of the molten resin from being propagated to the circuit substrate.
According to another embodiment of the present invention, there is provided a manufacturing method of a battery pack, comprising the steps of:
According to the embodiment of the present invention, since the lower molding body exists between the circuit substrate and the molten resin, it is possible to prevent the heat of the molten resin filled between the lower molding body and the battery device from being directly propagated to the circuit substrate.
According to another embodiment of the present invention, there is provided a manufacturing method of a battery pack, comprising the steps of:
According to the embodiment of the present invention, since the lower molding body exists between the circuit substrate and the molten resin, it is possible to prevent the heat of the molten resin filled between the lower molding body and the battery device from being directly propagated to the circuit substrate.
As described above, according to an embodiment of the invention, since the lower molding body is inserted into the opening so that the surface of the lower molding body where the circuit substrate has been arranged faces the outside and the resin is injected between the lower molding body and the battery device and hardened, it is possible to prevent the heat of the molten resin from being directly propagated to the circuit substrate. Therefore, the circuit substrate and the battery device can be integrated without damaging the electronic parts provided for the circuit substrate.
The above and other features of the present invention will become apparent from the following detailed description and the appended claims with reference to the accompanying drawings.
An embodiment of the invention will be described hereinbelow with reference to the drawings. The same or corresponding portions in all diagrams of the following embodiment are designated by the same reference numerals.
As shown in
<Battery Device>
As shown in
In the positive electrode, a positive electrode active substance layer is formed on a belt-shaped positive electrode collector and a polymer electrolyte layer is further formed on the positive electrode active substance layer. In the negative electrode, a negative electrode active substance layer is formed on a belt-shaped negative electrode collector and a polymer electrolyte layer is further formed on the negative electrode active substance layer. The leads 5a and 5b are joined to the positive electrode collector and the negative electrode collector, respectively. Materials which have already been proposed can be used for the positive electrode active substance, the negative electrode active substance, and the polymer electrolyte.
The positive electrode can be constructed by using a metal oxide, a metal sulfide, or a specific high polymer as a positive electrode active substance in accordance with a kind of target battery. In the case of constructing, for example, a lithium ion battery, a lithium compound oxide or the like mainly containing LixMO2 (in which, M denotes one or more kinds of transition metals and x is ordinarily equal to a value within a range from 0.05 or more to 1.10 or less although it differs depending on a charging/discharging state of the battery) can be used as a positive electrode active substance. It is preferable to use Co, Ni, Mn, or the like as a transition metal M constructing the lithium compound oxide.
LiCoO2, LiNiO2, LiNiyCo1-yO2 (in which, 0<y<1) LiMn2O4, or the like can be mentioned as a specific example of the lithium ion compound oxide. Those lithium ion compound oxides can generate a high voltage and have excellent energy density. A metal sulfide or oxide containing no lithium such as TiS2, MOS2, NbSe2, V2O5, or the like can be also used as a positive electrode active substance. A plurality of kinds of those positive electrode active substances can be also used for the positive electrode. When the positive electrode is formed by using the positive electrode active substances as mentioned above, a conductive material, a binder, or the like can be also added.
A material which can dope or dedope lithium can be used as a negative electrode material. For example, a carbon material such as graphitization resisting carbon material or graphite material can be used. More specifically speaking, it is possible to use a carbon material such as pyrolytic carbon class, coke class (pitch coke, needle coke, petroleum coke), graphite class, vitrified carbon class, organic polymer compound baked body (obtained by baking phenol resin, furan resin, or the like at a proper temperature and carbonizing), carbon fiber, activated carbon, or the like. Further, a high polymer such as polyacetylene, polypyrrole, or the like or an oxide such as SnO2 or the like can be used as a material which can dope or dedope lithium. When the negative electrode is made of such a material, a binder or the like can be also added.
The polymer electrolyte is made by injecting a gel electrolyte obtained by mixing a high polymer material, an electrolyte solution, and electrolyte salt into a polymer. The high polymer material has such a nature that it is miscible into the electrolyte solution and silicon gel, acrylic gel, acrylonitrile gel, polyphosphorzen denaturation polymer, polyethylene oxide, polypropylene oxide, and their compound polymer, crosslinking polymer, denaturation polymer, or the like are used as a high polymer material, or as a fluorinated polymer, for example, a high polymer material such as poly (vinylidene fluoride), poly (vinylidene fluoride-co-tetrafluoro safluoropropylene), poly (vinylidene fluoride-co-trifluoroethylene), or the like, and their mixture are used.
The electrolyte solution component can distribute the above-mentioned high polymer materials. For example, ethylene carbonate (EC), propylene carbonate (PC), butylene carbonate (BC), or the like is used as a non-protic solvent. A material which is miscible with a solvent is used as electrolyte salt. A cation and an anion are combined. An alkali metal or an alkali earth metal is used as a cation. Cl−, Br−, I−, SCN−, ClO4−, BF4−, PF6−, CF3SO3−, or the like is used as an anion. Specifically speaking, hexafluoride lithium phosphate or tetrafluoride lithium borate is used as electrolyte salt at such a density that it is soluble into the electrolyte solution.
<External Package>
The external package 1 is, for example, a hard laminating material and is formed by two kinds of laminating materials 1a and 1b as shown in
As a laminating material 1a, it is preferable to use a material which is suitable to form the concave portion by the drawing and is softer than the laminating material 1b. As shown in
The polypropylene (PP) layer 16a has a function of preventing alteration of the polymer electrolyte. A cast polypropylene (CPP) or the like is used as a polypropylene (PP) layer 16a. A thickness of polypropylene (PP) layer 16a is equal to, for example, about 30 μm.
The soft aluminum metal layer 17a has a function of preventing the moisture from entering the inside. As a material of the soft aluminum metal layer 17a, for example, aluminum (3003-O JIS H 4160), (3004-O JIS H 4160), or the like obtained after an annealing process can be used. A thickness of soft aluminum metal layer 17a is set to a value within approximately a range, for example, from 30 to 130 μm. The nylon/PET layer 18a has a function of protecting the surface. A thickness of nylon/PET layer 18a is set to a value within approximately a range, for example, from 10 to 30 μm.
The other laminating material 1b is a hard laminating material which maintains the shape after it was bent and can endure deformation applied from the outside. The laminating material 1b has a laminated structure obtained by sequentially laminating a polypropylene layer as an adhesive layer, a hard aluminum metal layer, and a nylon layer or PET layer as a surface protective layer.
The polypropylene layer and the nylon layer or PET layer of the laminating material 1b are similar to those of the laminating material 1a. As a hard aluminum metal layer, aluminum (3003-O JIS H 4160), (3004-O JIS H 4160), or the like obtained without performing the annealing process can be used and its thickness is set to a value within approximately a range, for example, from 30 to 130 μm. The thickness of each layer of the laminating materials 1a and 1b is selected to a proper value in consideration of a total thickness.
The laminating material 1b is arranged so as to overlap the laminating material 1a and cover the opening surface of the concave portion. In this case, as shown in
The front side long sides 11a and 11b and the rear side long sides 12a and 12b are set to almost the same length. The lengths of those long sides are selected so that the short sides (the short sides 13a and 14a; the short sides 13b and 14b) which face in the state where an enclosing portion of the battery device 4 is enclosed are come into contact with each other or the edge surfaces of the short sides face with a small gap.
It is assumed that the short sides 13a and 14a of the laminating material 1a are slightly shorter than the short sides 13b and 14b of the laminating material 1b. Therefore, the laminating materials 1a and 1b can be laminated so that only the laminating material 1b exists on the front side. In such a case, it is possible to obtain such an advantage that a peripheral surface of the front cover 2 provided for the opening of the front side can be thermally melt-bonded by the polypropylene layer of the laminating material 1b. Also on the rear side, it is possible to construct in such a manner that a peripheral surface of the rear cover 3 provided for the opening of the rear side can be thermally melt-bonded by the polypropylene layer of the laminating material 1b so as to expose an adhesive layer of the laminating material 1b.
As shown in
As shown in
<Front Cover>
The lower molding body 21 has two lead-out holes 24a and 24b at positions which are slightly inside than both end portions in the longitudinal direction. The lead-out holes 24a and 24b are through-holes for leading out auxiliary tabs 33a and 33b provided for the protecting circuit substrate 31 and are pierced from both sides where the protecting circuit substrate 31 is arranged toward the surface on the side which faces the battery device 4. For example, a resin such as polypropylene (PP) or the like can be used as a material constructing the lower molding body 21.
The lower molding body 21 has resin injection holes 25a and 25b in the both end portions in the longitudinal direction. The resin injection holes 25a and 25b are through-holes for injecting a molten resin between the edge surface of the front side of the battery device 4 and the front cover 2 fitted into the opening of the front side and pierced from both sides where the protecting circuit substrate 31 is arranged toward the surface on the side which faces the battery device 4. The case where the two resin injection holes 25a and 25b are provided for the lower molding body 21 is shown as an example here. The number of resin injection holes is not particularly limited and can be set to 1 or 2 or more.
Grooves are formed in injection port portions of the resin injection holes 25a and 25b. When the molten resin is solidified in those grooves, projections are formed and the position of the front cover 2 is fixed by the projections, thereby preventing the front cover 2 from being pulled out.
The protecting circuit 32 including a temperature protecting device such as fuse, PTC, thermistor, or the like, an ID resistor to discriminate the battery pack, and the like are mounted on one principal plane of the protecting circuit substrate 31. The PTC is serially connected to the battery device. When a temperature of the battery is higher than a set temperature, an electric resistance rises suddenly, thereby substantially shutting off a current flowing in the battery. The fuse and the thermistor are also serially connected to the battery device. When the temperature of the battery is higher than the set temperature, the current flowing in the battery is shut off.
A plurality of, for example, two contact portions 34 are provided on the other principal plane of the protecting circuit substrate 31. The protecting circuit 32 is fitted into the groove 22 and the protecting circuit substrate 31 is fitted into the groove 23 so that one principal plane side on which the protecting circuit 32 and the like are provided becomes the lower molding body 21 side.
The auxiliary tabs 33a and 33b corresponding to the positive and negative electrodes are joined to the protecting circuit substrate 31 or the protecting circuit 32. The auxiliary tabs 33a and 33b are joined to the leads 5a and 5b provided at the edge surfaces of the front side of the battery device 4.
The upper molding body 41 is provided in the first groove 22 so as to cover the protecting circuit substrate 31. The upper molding body 41 has three openings 42 at the positions corresponding to the contact portions 34. The contact portions 34 face the outside through the openings 42. For example, a resin such as polypropylene (PP) or the like can be used as a material constructing the upper molding body 41.
<Rear Cover>
The rear cover 3 is used to cover the opening of the rear side and has almost the same shape as that of the opening of the rear side. For example, a resin such as polypropylene (PP) or the like can be used as a material constructing the rear cover 3.
An example of a manufacturing method of the battery pack according to an embodiment of the invention will now be described with reference to
<Manufacturing Step of Battery Device>
First, for example, the positive and negative electrodes in which the gel electrolyte layers are formed on both surfaces and separators are sequentially laminated in order of the negative electrode, the separator, the positive electrode, and the separator. An obtained laminate body is wound around a core in a flat shape in the longitudinal direction a number of times, thereby forming the winding type battery device 4.
<External Package Coating Step>
Subsequently, a concave portion into which the battery device 4 is inserted is previously formed in the laminating material 1a by, for example, deep drawing molding. In this instance, as shown in
Subsequently, as shown in
Subsequently, in the state of the layout relation as shown in
Subsequently, as shown in
In the state where the laminating materials 1a and 1b are opened as shown in
The battery pack in which the hard laminating material 1b also functions as an external package can be manufactured without using a box-shaped casing made of a resin and without arranging frames made of a resin to both sides as mentioned above.
<Fitting Step of the Front Cover>
Subsequently, the lower molding body 21 is molded by, for example, an injection molding or a hot melting method. As shown in
Subsequently, as shown in
Subsequently, as shown in
Subsequently, a molten resin is filled between the lower molding body 21 and the battery device 4 through the resin injection holes 25a and 25b, a resin is also filled into the resin injection holes 25a and 25b up to the groove portions thereof, and those resins are solidified. Thus, the front cover 2 is adhered to the edge surface of the battery device 4.
As a resin to be filled, it is sufficient to use a resin having a low viscosity state upon injection molding and it is not particularly limited to such a resin. For example, a resin of a polyamide system, a hot melting resin, a polyorefin system hot melting resin, nylon, PP, PC, ABS, or the like can be used.
<Fitting Step of the Rear Cover>
Subsequently, the rear cover 3 is preliminarily formed by, for example, the injection molding or the like and fitted into the opening of the rear side of the battery device 4 covered with the external package 1. It is preferable that the surfaces between the rear cover 3 and the edge surface on the rear side of the battery device 4 are coated with an adhesive agent. A forming method of the rear cover 3 is not limited to the above method but the rear cover 3 can be also formed on the opening of the rear side by filling the molten resin into the opening of the rear side and hardening it.
After that, the whole length is suppressed by a tool and the thermal melt-bonding is executed as shown in
By the above steps, the battery pack according to the embodiment of the invention is manufactured.
According to the embodiment of the invention, the following effects can be obtained.
The protecting circuit 32 is fitted into the first groove 22 of the lower molding body 21 and the protecting circuit substrate 31 is fitted into the second groove 23. The molten resin is filled onto the protecting circuit substrate 31 so as to fill the second groove 23 and hardened and the upper molding body 41 is formed, thereby obtaining the front cover 2. The auxiliary tabs 33a and 33b provided for the protecting circuit substrate 31 and the leads 5a and 5b are joined. After that, the front cover 2 is fitted into the opening of the front side of the battery device 4 covered with the external package 1. The molten resin is filled between the battery device 4 and the front cover 2 from the resin injection holes 25a and 25b and hardened. Since the lower molding body 21 exists between the molten resin and the protecting circuit 32, it is possible to prevent the heat of the molten resin from being directly propagated to electronic parts such as a protecting circuit and the like. Therefore, the front cover and the battery device 4 can be integrated without damaging the electronic parts such as a protecting circuit and the like.
Although the embodiment of the invention has specifically been described above, the invention is not limited to the foregoing embodiment but various modifications based on the technical idea of the invention are possible.
For example, the numerical values mentioned in the foregoing embodiment are merely shown as an example and other numerical values different from them can be also used as necessary.
Although the example in which the invention is applied to the non-aqueous electrolyte secondary battery of the winding type in that the electrolyte layer is provided between the positive electrode and the negative electrode and the positive and negative electrodes are wound has been described in the above embodiment, the invention can be also applied to a non-aqueous electrolyte secondary battery of a laminating type in which the positive electrode, the electrolyte layer, and the negative electrode are sequentially laminated.
Although the example in which the invention is applied to the battery having the gel electrolyte as an electrolyte has been described in the above embodiment, the invention can be also applied to a battery having a solid electrolyte containing electrolyte salt as an electrolyte. The invention can be also applied to a battery having an electrolyte solution such as a non-aqueous electrolyte solution or the like as an electrolyte.
Although the case where the step of forming the upper molding body 41 and the step of injecting the molten resin into the resin injection holes 25a and 25b are separately executed has been shown as an example in the above embodiment, those steps can be also executed in the same step. In such a case, such an advantage that the number of steps is reduced and manufacturing efficiency can be further improved can be obtained.
It should be understood by those skilled in the art that various modifications, combinations, sub-combinations and alterations may occur depending on design requirements and other factors insofar as they are within the scope of the appended claims or the equivalents thereof.
Number | Date | Country | Kind |
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P2004-243892 | Aug 2004 | JP | national |