The present invention relates to a system and the like for determining the deterioration state of a secondary battery such as a lithium-ion battery.
The present applicant has proposed a technical method that makes it possible to determine the deterioration state of a target secondary battery even when no initial measurement result of the characteristic parameters of the secondary battery itself is available (refer to Patent Literature 1). To be specific, based on a present measurement value V (k) of a voltage V of a secondary battery and a present measurement value I (k) of a current I, a past value of the voltage V is specified as an initial characteristic estimated value V (0<-k) according to a multivariable function G that represents an initial characteristic model. The “initial characteristic model” is a model representing the initial characteristics of a reference secondary battery of the same standard as the secondary battery to be subjected to deterioration state determination.
The present applicant has proposed a technical method for evaluating the battery performance of a secondary battery by using a secondary battery model in which the impedance of the internal resistance of the secondary battery is expressed by impulse responses representing each of an IIR system and a FIR system (refer to Patent Literature 2).
However, when there are many model parameters that define a model, there are cases where an arithmetic processing load required for identifying the values of the model parameters becomes excessive. For this reason, there has been a possibility that the scope of application will be inconveniently limited, typically represented by an example in which it becomes difficult to perform, in a device, the on-board battery performance evaluation processing for a secondary battery installed in the device.
Therefore, an object of the present invention is to provide a device and the like that make it possible to evaluate the performance of a secondary battery while reducing an arithmetic processing load required for identifying the values of model parameters that define a model used for evaluating the performance of the secondary battery.
A battery performance evaluation device according to the present invention includes:
The battery performance evaluation device in accordance with the present invention determines different battery models as battery models used for evaluating the performance of a target secondary battery depending on whether a designated condition is satisfied or not. To be specific, when a designated condition is satisfied, then the second battery model is determined, which is defined by a plurality of second model parameters that are fewer than a plurality of first model parameters, and is therefore a simpler battery model than the first battery model defined by the plurality of first model parameters (the battery model determined when the designated condition is not satisfied). Consequently, the arithmetic processing load required for identifying the model parameters of a battery model used for evaluating the performance of a target secondary battery is reduced, as compared with the case where the first battery model is established regardless of whether a designated condition is satisfied.
A battery performance evaluation device 100 as an embodiment of the present invention illustrated in
The battery performance evaluation device 100 includes a first recognition processing element 111, a second recognition processing element 112, a first arithmetic processing element 121, a second arithmetic processing element 122, a battery performance evaluation element 130, and an information provision element 132. Each of the first recognition processing element 111, the second recognition processing element 112, the first arithmetic processing element 121, the second arithmetic processing element 122, the battery performance evaluation element 130, and the information provision element 132 is composed of a processor (arithmetic processing device), a memory (storage device), an I/O circuit, and the like. The memory or a storage device that is separate therefrom stores and holds various data such as measurement results of the voltage response characteristics of the secondary battery 220 with respect to a designated current, as well as programs (software). For example, each of a plurality of identifiers for distinguishing the type of the secondary battery 220 or the target device 200 provided with the secondary battery 220 (specified by standards and characteristics) is associated with each of a plurality of secondary battery models, and stored and held in the memory.
A processor reads necessary programs and data from a memory, and based on the data, performs arithmetic processing according to the programs thereby to perform arithmetic processing or tasks, which will be described later, assigned to the elements 111, 112, 121, 122, 130 and 132. The phrase of each element “recognizing” information means that each element performs any arithmetic processing for preparing information or data required for subsequent arithmetic processing, such as receiving information, retrieving or reading information from an information source such as the database 10, and performing arithmetic processing on basic information thereby to calculate, estimate, specify, identify, or predict information.
The target device 200 includes an input interface 202, an output interface 204, a control unit 210, the secondary battery 220, and a sensor group 230. The target device 200 includes any device such as a personal computer, a mobile phone (smartphone), a home appliance, and a moving vehicle such as an electric bicycle, which use the secondary battery 220 as the power source thereof.
The control unit 210 is composed of a processor (arithmetic processing unit), a memory (storage device), an I/O circuit, and the like. The memory or a storage device that is separate therefrom stores and holds various data such as measurement results of the voltage response characteristics of the secondary battery 220. The control unit 210 operates in response to power supplied from the secondary battery 220 to control the operation of the target device 200 in an energized state. The operation of the target device 200 includes the operation of an actuator (electric actuator or the like) constituting the target device 200. The processor constituting the control unit 210 reads necessary programs and data from the memory, and performs assigned arithmetic processing on the basis of the data according to the programs.
The secondary battery 220 is, for example, a lithium-ion battery, and may be any other secondary battery such as a nickel-cadmium battery. The sensor group 230 measures the values of parameters required for controlling the target device 200, as well as the voltage response characteristics and the temperature of the secondary battery 220. The sensor group 230 is composed of, for example, a voltage sensor, a current sensor, and a temperature sensor, which output signals corresponding to the voltage, the current, and the temperature, respectively, of the secondary battery 220.
The battery performance evaluation device 100 may be installed in the target device 200. In this case, a software server (not illustrated) may transmit deterioration determination software to an arithmetic processing unit that constitutes the control unit 210 installed in the target device 200 so as to impart the function as the battery performance evaluation device 100 to the arithmetic processing unit.
A description to be given later will explain the battery performance evaluation method of the secondary battery 220 (the target secondary battery) performed by the battery performance evaluation device 100 having the above-described configuration.
The first recognition processing element 111 in the battery performance evaluation device 100 recognizes the measurement results of the impedance, such as complex impedance Z, of the secondary battery 220 as various types of reference secondary batteries (STEP112 of
The complex impedance Z of the secondary battery 220 as a reference secondary battery in a state of not being installed in the target device 200 is measured. Alternatively, the complex impedance Z of the secondary battery 220 as a reference secondary battery in a state of being installed in the target device 200 may be measured. For example, the target device 200 can be connected to a power source, such as a commercial power source, for charging the secondary battery 220, and sinusoidal signals can be output by the power supplied from the power source.
In the battery performance evaluation device 100, the first arithmetic processing element 121 determines whether a designated condition is satisfied (STEP114 of
In addition to or in place of the above-described condition, a condition or conditions defined as a designated condition or conditions may include a condition that the arithmetic processing load (CPU usage rate or the like) of the first arithmetic processing element 121 is a reference value or more, a condition that the target device 200 is a device in which the required accuracy or urgency of the performance evaluation of the secondary battery 220 is a threshold value or less (e.g., a device in which the degree of functional deterioration attributable to the performance deterioration of the secondary battery 220 is low, such as a smartphone and a personal computer), and/or a condition that the period of time elapsed from the point of time of the previous performance evaluation of the secondary battery 220 to be subjected to a present performance evaluation is less than a designated period of time.
When it is determined that a designated condition is not satisfied (NO in STEP114 of
The first battery model is a model that represents a voltage V (z) output from the secondary battery 220 when a current I (z) is input to the secondary battery 220. The first battery model (full model) is defined by, for example, an equivalent circuit in which a resistance r0 corresponding to the transfer resistance in the electrolyte, a Warburg impedance W, an i-th RC parallel circuit (i=1, 2, . . . , m) composed of a resistance r1 corresponding to a charge transfer resistance and a capacitor Ci, and an LR parallel circuit composed of a coil L and a resistance rL are connected in series, as illustrated in
The number of the RC parallel circuits to be connected in series may be less than three, or more than three. The Warburg impedance W may be connected with a resistance R in series in at least one RC parallel circuit. The capacitor C may be replaced by a CPE (Constant Phase Element).
The first battery model is defined by a relational expression (11) using an open-circuit voltage OCV (z) and an internal resistance transfer function H1 (z) of the secondary battery 220.
Here, OCV (z) indicates that the open-circuit voltage increases or decreases according to the charging and/or discharging of the current I (z).
The internal resistance transfer function Hi(z) in the first battery model is defined by a relational expression (16) using a transfer function H0 (z) of the resistance r0 defined by a relational expression (12), the transfer function Hi (z) in the i-th RC parallel circuit defined by a relational expression (13), a transfer function Hw (z) of the Warburg impedance W defined by a relational expression (14), and a transfer function HL (z) of the LR parallel circuit defined by a relational expression (15).
Here, ai, bi0, and bi1 are represented by coefficient relational expressions (131) and (132) using a sampling cycle T.
The transfer function hw (s) of the Warburg impedance W that matches the experiment data is represented by a relational expression (141) or (142) in a frequency domain.
In order to correspond to an impulse response, the transfer function is expanded to FIR and represented by relational expressions (14) to (16).
The approximate curve of the complex impedance Z of the secondary battery represented by the Nyquist plot indicated by the solid line in
The value of the open-circuit voltage OCV in the secondary battery model is identified by the measurement value of the open-circuit voltage OCV (refer to the relational expression (11)). Then, based on the values of the parameters, the first battery model is established as the secondary battery 220 as the reference secondary battery of various characteristics or specifications.
On the other hand, when it is determined that the designated condition is satisfied (YES in STEP114 of
As with the first battery model, the second battery model is a model that represents the voltage V (z) output from the secondary battery 220 when the current I (z) is input to the secondary battery 220. The second battery model is a simplified model, as compared with the first battery model, in the case where the time constant of the transfer function H; (z) of the i-th RC parallel circuit defined by the relational expression (13) is sufficiently smaller than the sampling cycle T. For example, the second battery model is defined by the equivalent circuit in which a single resistance R0 and a single Warburg impedance W are connected in series, as illustrated in
The second battery model is defined by a relational expression (21) using the open-circuit voltage OCV (z) and the transfer function H2 (z) of the internal resistance of the secondary battery 220.
The transfer function H1 (z) of the internal resistance in the second battery model is defined by a relational expression (26) using the transfer function H0 (z) of the resistance R0 defined by a relational expression (22) and the transfer function Hw(z) of the Warburg impedance W defined by the relational expression (14). The resistance R is regarded as a single resistance as an aggregated result of the resistance r0 corresponding to the transfer resistance in the electrolyte and a resistance ri(i=1, 2, . . . , m) corresponding to the charge transfer resistance.
The approximate curve (especially the linear portion in the region of −ImZ>0) of the complex impedance Z of the secondary battery represented by the Nyquist plot indicated by the solid line in
The number of the second model parameters (R0, w1, w2, and w3) is four, which is smaller than the number “12” of the first model parameters (r0, ri (i=1 to 3), Ci(i=1 to 3), w1, w2, w3, rL, and L). Further, some of the second model parameters, which are the parameters (w1, w2, and w3) defining the Warburg impedance W, are some of the first model parameters common to the parameters (w1, w2, and w3) also defining the Warburg impedance W.
In the target device 200, the control unit 210 in an energized state determines whether a first condition is satisfied (STEP212 of
When it is determined that the first condition is not satisfied (NO in STEP212 of
When it is determined that the first condition is satisfied (YES in STEP212 of
Based on an output signal of the sensor group 230, a voltage response characteristic V (t) and a temperature T of the secondary battery 220 are measured by the control unit 210 (STEP216 of
Subsequently, the control unit 210 determines whether a second condition is satisfied (STEP218 of
When it is determined that the second condition is not satisfied (NO in STEP218 of
When it is determined that the second condition is satisfied (YES in STEP218 of
In the battery performance evaluation device 100, the measurement results of the voltage response characteristic V (t) and the temperature T of the secondary battery 220 are recognized as second measurement results by the second recognition processing element 112 (STEP122 of
The second arithmetic processing element 122 selects, among a number of secondary battery models registered in the database 10, a first battery model or a second battery model associated with an identifier ID related to the second measurement results and the measurement result of the temperature T included in the second measurement results (STEP124 of
Further, the designated current I (t) is input to the selected first battery model or second battery model by the second arithmetic processing element 122 (STEP126 of
The second arithmetic processing element 122 specifies the voltage response characteristic Vmodel (t) output from the first battery model or the second battery model as the output signal of the first battery model or the second battery model (STEP128 of
Subsequently, the battery performance evaluation element 130 evaluates the performance of the secondary battery 220 on the basis of the result of comparison between the voltage response characteristic V (t) of the secondary battery 220 as the target secondary battery and the voltage response characteristic Vmodel (t) of the first battery model or the second battery model (STEP130 of
The battery performance evaluation element 130 generates deterioration diagnosis information Info (D (i)) based on the deterioration degree D (i) of the secondary battery 220 (STEP132 of
In the target device 200, the deterioration diagnosis information Info (D (i)) is received by a receiving device constituting the input interface 202 (STEP222 of
In the above-described embodiment, the temperature T when measuring the voltage response characteristic V (t) of each of the reference secondary battery and the target secondary battery was taken into account in selecting the first battery model and/or the second battery model to evaluate the performance of the secondary battery 220 as the target secondary battery. Meanwhile, as another embodiment, the performance of the secondary battery 220 as the target secondary battery may be evaluated by selecting the first battery model and/or the second battery model on the basis of an identifier representing the characteristics or the like of the target secondary battery without taking the temperature T into account at the time of measuring the voltage response characteristic V (t) of each of the reference secondary battery and the target secondary battery.
According to the battery performance evaluation device 100 in accordance with the present invention and the battery performance evaluation method performed thereby, a different battery model is determined as a battery model used to evaluate the performance of a target secondary battery according to whether a designated condition is satisfied or not. To be specific, when a designated condition is satisfied, then the second battery model is determined, which is a simplified battery model defined by the second model parameters, which are fewer than those of the first battery model defined by a plurality of first model parameters (the battery model determined when a designated condition is not satisfied) (refer to YES in STEP114->STEP118 in
10 . . . database; 100 . . . battery performance evaluation device; 111 . . . first recognition processing element; 112 . . . second recognition processing element; 121 . . . first arithmetic processing element; 122 . . . second arithmetic processing element; 130 . . . battery performance evaluation element; 200 . . . target device; 202 . . . input interface; 204 . . . output interface; 210 . . . control unit; 220 . . . secondary battery; 221 . . . reference secondary battery; 222 . . . target secondary battery; and 230 . . . sensor group.
Number | Date | Country | Kind |
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2021-080843 | May 2021 | JP | national |
Filing Document | Filing Date | Country | Kind |
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PCT/JP2022/008648 | 3/1/2022 | WO |