This nonprovisional application is based on Japanese Patent Application No. 2021-111650 filed on Jul. 5, 2021, with the Japan Patent Office, the entire contents of which are hereby incorporated by reference.
The present technology relates to a battery.
Conventionally, a structure has been employed in which an electrolyte solution is injected into an exterior container of a battery and then an electrolyte solution injection hole is sealed by a sealing member. Such a structure is described in, for example, Japanese Patent Laying-Open No. 2010-277936, Japanese Patent Laying-Open No. 2014-11074, and WO2014/033822.
In some cases such as the structure described in Japanese Patent Laying-Open No. 2010-277936, the sealing member is fixed to the exterior container by swaging, whereas in other cases such as each of the structures described in Japanese Patent Laying-Open No. 2014-11074 and WO2014/033822, the sealing member is fixed to the exterior container by welding.
In the case where the sealing member is fixed to the exterior container by swaging, it is required to avoid occurrence of insufficient swaging in order to secure the sealing of the exterior container. It is an object of the present technology to provide a battery in which occurrence of insufficient swaging is suppressed.
A battery according to the present technology includes: an electrode assembly and an electrolyte solution; an exterior container that accommodates the electrode assembly and the electrolyte solution and that is provided with an injection hole for the electrolyte solution; a sealing member that is fixed to the exterior container by swaging and that seals the injection hole; and a seal component that has an annular shape and that is located between the exterior container and the sealing member. The sealing member includes a stem portion inserted into the injection hole, a flange portion that is located outside the exterior container and that is located on an outer side with respect to the stem portion in a radial direction of the stem portion, and a protrusion that has a substantially annular shape and that protrudes from the flange portion to the exterior container side. In a state in which the sealing member is fixed to the exterior container by swaging, at least a tip side of the protrusion is embedded in the seal component. In a state before the sealing member is fixed to the exterior container by swaging, when the protrusion of the sealing member and the seal component are brought into abutment with each other, a communication path is formed in the protrusion or the seal component to communicate a space inside the exterior container and a space outside the exterior container with each other.
The foregoing and other objects, features, aspects and advantages of the present invention will become more apparent from the following detailed description of the present invention when taken in conjunction with the accompanying drawings.
Hereinafter, embodiments of the present technology will be described. It should be noted that the same or corresponding portions are denoted by the same reference characters, and may not be described repeatedly.
It should be noted that in the embodiments described below, when reference is made to number, amount, and the like, the scope of the present technology is not necessarily limited to the number, amount, and the like unless otherwise stated particularly. Further, in the embodiments described below, each component is not necessarily essential to the present technology unless otherwise stated particularly.
It should be noted that in the present specification, the terms “comprise”, “include”, and “have” are open-end terms. That is, when a certain configuration is included, a configuration other than the foregoing configuration may or may not be included. Further, the present technology is not limited to one that necessarily exhibits all the functions and effects stated in the present embodiment.
In the present specification, the term “battery” is not limited to a lithium ion battery, and may include another battery such as a nickel-metal hydride battery. In the present specification, the term “electrode” may collectively represent a positive electrode and a negative electrode. Further, the term “electrode plate” may collectively represent a positive electrode plate and a negative electrode plate.
As shown in
Battery case 100 is constituted of: a prismatic exterior body 110 that is provided with an opening and that has a prismatic tubular shape having a bottom; and a sealing plate 120 that seals the opening of prismatic exterior body 110. Each of prismatic exterior body 110 and sealing plate 120 is preferably composed of a metal, and is preferably composed of aluminum or an aluminum alloy.
Sealing plate 120 is provided with an electrolyte solution injection hole 121. After injecting an electrolyte solution into battery case 100 via electrolyte solution injection hole 121, electrolyte solution injection hole 121 is sealed by a sealing member 900 (rivet).
Sealing plate 120 is provided with a gas discharge valve 122. Gas discharge valve 122 is fractured when pressure in battery case 100 becomes more than or equal to a predetermined value. Thus, gas in battery case 100 is discharged to outside of battery case 100.
Electrode assembly 200 is accommodated in battery case 100 together with the electrolyte solution. Electrode assembly 200 is formed by stacking positive electrode plates and negative electrode plates with separators being interposed therebetween. Insulating sheet 300, which is composed of a resin, is disposed between electrode assembly 200 and prismatic exterior body 110.
A positive electrode tab 210A and a negative electrode tab 210B are provided at an end portion of electrode assembly 200 on the sealing plate 120 side.
Positive electrode tab 210A and positive electrode terminal 400 are electrically connected to each other via positive electrode current collecting member 600. Positive electrode current collecting member 600 includes a first positive electrode current collector 610 and a second positive electrode current collector 620. It should be noted that positive electrode current collecting member 600 may be constituted of one component. Positive electrode current collecting member 600 is preferably composed of a metal, and is more preferably composed of aluminum or an aluminum alloy.
Negative electrode tab 210B and negative electrode terminal 500 are electrically connected to each other via negative electrode current collecting member 700. Negative electrode current collecting member 700 includes a first negative electrode current collector 710 and a second negative electrode current collector 720. It should be noted that negative electrode current collecting member 700 may be constituted of one component. Negative electrode current collecting member 700 is preferably composed of a metal, and is more preferably composed of copper or a copper alloy.
Positive electrode terminal 400 is fixed to sealing plate 120 with an outer side insulating member 410 being interposed therebetween, outer side insulating member 410 being composed of a resin. Negative electrode terminal 500 is fixed to sealing plate 120 with an outer side insulating member 510 being interposed therebetween, outer side insulating member 510 being composed of a resin.
Positive electrode terminal 400 is preferably composed of a metal, and is more preferably composed of aluminum or an aluminum alloy. Negative electrode terminal 500 is preferably composed of a metal, and is more preferably composed of copper or a copper alloy. Negative electrode terminal 500 may have: a region that is composed of copper or a copper alloy and that is disposed on the inner side of battery case 100; and a region that is composed of aluminum or an aluminum alloy and that is disposed on the outer side of battery case 100.
Cover member 800 is located between first positive electrode current collector 610 and electrode assembly 200. Cover member 800 may be provided on the negative electrode current collector side. Further, cover member 800 is not an essential member, and may be omitted as appropriate.
The plurality of positive electrode tabs 210A of first electrode assembly element 201 constitute a first positive electrode tab group 211A. The plurality of negative electrode tabs 210B of first electrode assembly element 201 constitute a first negative electrode tab group 211B. The plurality of positive electrode tabs 210A of second electrode assembly element 202 constitute a second positive electrode tab group 212A. The plurality of negative electrode tabs 210B of second electrode assembly element 202 constitute a second negative electrode tab group 212B.
Second positive electrode current collector 620 and second negative electrode current collector 720 are disposed between first electrode assembly element 201 and second electrode assembly element 202. Second positive electrode current collector 620 is provided with a first opening 620A and a second opening 620B. First positive electrode tab group 211A and second positive electrode tab group 212A are connected onto second positive electrode current collector 620 by welding, thereby forming welded connection portions 213. First negative electrode tab group 211B and second negative electrode tab group 212B are connected onto second negative electrode current collector 720 by welding, thereby forming welded connection portions 213. Welded connection portions 213 can be formed by, for example, ultrasonic welding, resistance welding, laser welding, or the like.
First, the following describes attaching of positive electrode current collecting member 600 on sealing plate 120 with reference to
Outer side insulating member 410 composed of a resin is disposed on the outer surface side of sealing plate 120. First positive electrode current collector 610 and insulating member 630 (positive electrode current collector holder) composed of a resin are disposed on the inner surface side of sealing plate 120. Next, positive electrode terminal 400 is inserted into a through hole of outer side insulating member 410, a positive electrode terminal attachment hole of sealing plate 120, a through hole of first positive electrode current collector 610, and a through hole of insulating member 630. A swaged portion 400A located at the tip of positive electrode terminal 400 is connected onto first positive electrode current collector 610 by swaging. Thus, positive electrode terminal 400, outer side insulating member 410, sealing plate 120, first positive electrode current collector 610, and insulating member 630 are fixed. It should be noted that the portions of positive electrode terminal 400 and first positive electrode current collector 610 connected to each other by the swaging are preferably welded by laser welding or the like. It should be noted that first positive electrode current collector 610 is provided with a countersunk hole 610A, and swaged portion 400A is provided in countersunk hole 610A.
Further, second positive electrode current collector 620 is disposed on insulating member 630 such that a portion of second positive electrode current collector 620 overlaps with first positive electrode current collector 610. In first opening 620A provided in second positive electrode current collector 620, second positive electrode current collector 620 is welded to first positive electrode current collector 610 by laser welding or the like.
As shown in
When attaching positive electrode current collecting member 600 on sealing plate 120, first positive electrode current collector 610 is first connected to insulating member 630 on sealing plate 120. Then, second positive electrode current collector 620 connected to electrode assembly 200 is attached to first positive electrode current collector 610. On this occasion, second positive electrode current collector 620 is disposed on insulating member 630 such that a portion of second positive electrode current collector 620 overlaps with first positive electrode current collector 610. Then, the circumference around first opening 620A provided in second positive electrode current collector 620 is welded to first positive electrode current collector 610 by laser welding or the like.
Next, the following describes attaching of negative electrode current collecting member 700 on sealing plate 120 with reference to
Outer side insulating member 510 composed of a resin is disposed on the outer surface side of sealing plate 120. First negative electrode current collector 710 and insulating member 730 (negative electrode current collector holder) composed of a resin are disposed on the inner surface side of sealing plate 120. Next, negative electrode terminal 500 is inserted into a through hole of outer side insulating member 510, a negative electrode terminal attachment hole of sealing plate 120, a through hole of first negative electrode current collector 710, and a through hole of insulating member 730. A swaged portion 500A located at the tip of negative electrode terminal 500 is connected onto first negative electrode current collector 710 by swaging. Thus, negative electrode terminal 500, outer side insulating member 510, sealing plate 120, first negative electrode current collector 710, and insulating member 730 are fixed. It should be noted that the portions of negative electrode terminal 500 and first negative electrode current collector 710 connected to each other by the swaging are preferably welded by laser welding or the like.
Further, second negative electrode current collector 720 is disposed on insulating member 730 such that a portion of second negative electrode current collector 720 overlaps with first negative electrode current collector 710. In first opening 720A provided in second negative electrode current collector 720, second negative electrode current collector 720 is welded to first negative electrode current collector 710 by laser welding or the like.
When attaching negative electrode current collecting member 700 on sealing plate 120, first negative electrode current collector 710 is first connected to insulating member 730 on sealing plate 120. Then, second negative electrode current collector 720 connected to electrode assembly 200 is attached to first negative electrode current collector 710. On this occasion, second negative electrode current collector 720 is disposed on insulating member 730 such that a portion of second negative electrode current collector 720 overlaps with first negative electrode current collector 710. Then, the circumference around first opening 720A provided in second negative electrode current collector 720 is welded to first negative electrode current collector 710 by laser welding or the like.
From the state shown in
First electrode assembly element 201 and second electrode assembly element 202 can be stacked on each other by a tape or the like. Alternatively, first electrode assembly element 201 and second electrode assembly element 202 can be stacked on each other by placing them in an insulating sheet formed in the form of a box or a pouch. Further, first electrode assembly element 201 and second electrode assembly element 202 can be fixed by adhesion.
First electrode assembly element 201 and second electrode assembly element 202 stacked on each other are enclosed with insulating sheet 300 and are inserted into prismatic exterior body 110. Thereafter, sealing plate 120 is welded to prismatic exterior body 110 to seal the opening of prismatic exterior body 110 by sealing plate 120, thereby forming sealed battery case 100.
Thereafter, a nonaqueous electrolyte is injected into battery case 100 through electrolyte solution injection hole 121 provided in sealing plate 120. Examples of the nonaqueous electrolyte solution usable herein include a nonaqueous electrolyte solution including ethylene carbonate (EC), ethyl methyl carbonate (EMC), diethyl carbonate (DEC), and dimethyl carbonate (DMC).
After injecting the nonaqueous electrolyte solution, a decompression step in battery case 100 is performed, and then electrolyte solution injection hole 121 is sealed by sealing member 900. By performing the above steps, prismatic secondary battery 1 is completed.
As shown in
Stem portion 910 is inserted into electrolyte solution injection hole 121 and is fixed to sealing plate 120 by swaging. Flange portion 920 is located outside sealing plate 120 and is located on the outer side with respect to stem portion 910 in the radial direction of stem portion 910. Rib 930 is formed to have an annular shape and protrudes from flange portion 920 to the sealing plate 120 side. Rib 930 may be formed to have a substantially annular shape with a portion including a discontinuous portion.
Mandrel portion 900A is composed of a metal material such as an aluminum alloy (A3003). Each of stem portion 910, flange portion 920, and rib 930 is composed of a metal material such as stainless steel (SUS430).
As shown in
As shown in
In the state shown in
In prismatic secondary battery 1 according to the present embodiment, occurrence of the insufficient swaging is suppressed by providing communication paths 940, 1010 described later.
With the formation of communication path 940 that communicates the space inside battery case 100 and the space outside battery case 100 with each other, an ejection path is formed to allow the electrolyte solution remaining between flange portion 920 of sealing member 900 and the upper surface of sealing plate 120 to be ejected to outside when fixing sealing member 900 by swaging, thereby suppressing the occurrence of the insufficient swaging.
In the state in which sealing member 900 is fixed by swaging, rib 930 is embedded in washer 1000, so that communication path 940 is closed. However, by removing sealing member 900 fixed by swaging and washer 1000 from sealing plate 120 and disassembling them, presence of communication path 940 before the fixation by swaging can be confirmed.
Next, an exemplary communication path 940 will be described with reference to
In each of examples of
When fixing sealing member 900 by swaging, sealing member 900 is embedded in washer 1000 from the tip side of rib 930. By forming the through hole on the root side of rib 930, the ejecting path for the electrolyte solution can be stably secured until immediately before completion of the fixing by swaging.
The through hole may have a substantially quadrangular cross sectional shape as shown in
In order to stably secure the ejection path for the electrolyte solution until immediately before the completion of the fixing by swaging, the cross sectional shape of communication path 940 is preferably wider on the root side of rib 930 than on the tip side of rib 930 as shown in
In the example of
The height (H3) of communication path 940 is preferably as high as possible within the range of the height (H2) of rib 930, and is preferably about 50% or more of the height (H2) of rib 930.
As an example, the cross sectional area of communication path 940 is about 5% or more and 10% or less of the product of the peripheral length of the outermost periphery of rib 930 and the height (H2) of rib 930.
By setting the height and the cross sectional area of communication path 940 to fall within the predetermined ranges, the ejection path for the electrolyte solution during the fixation by swaging can be stably secured.
As shown in
Although the embodiments of the present invention has been described and illustrated in detail, it is clearly understood that the same is by way of illustration and example only and is not to be taken by way of limitation, the scope of the present invention being interpreted by the terms of the appended claims.
Number | Date | Country | Kind |
---|---|---|---|
2021-111650 | Jul 2021 | JP | national |