Benzoyl derivatives

The present invention relates to novel benzoyl derivatives having herbicidal action, processes for preparing the benzoyl derivatives, compositions which contain the latter and the use of these derivatives or compositions containing the latter for controlling weeds.
Herbicidally active 2-aroylcyclohexanediones are disclosed in the literature, for example in EP 283261, EP 90262, EP 135191, EP 186118, EP 186119, EP 186120, EP 319075, WO 9005712, WO 9404524, WO 9408988, JO3052862 and JO 3120202.
The herbicidal properties of the known compounds and the tolerability for crop plants, however, are only satisfactory to a limited extent.
It is an object of the present invention to find novel 2-aroylcyclohexanediones having improved properties.
We have found that this object is achieved by the benzoyl derivatives of the formula I ##STR3## where the substituents have the following meanings: L and M are hydrogen, C.sub.1 -C.sub.6 -alkyl, C.sub.2 -C.sub.6 -alkenyl, C.sub.2 -C.sub.6 -alkynyl, C.sub.1 -C.sub.4 -alkoxy, it being possible for these groups to be unsubstituted or substituted by one to five halogen atoms or C.sub.1 -C.sub.4 -alkoxy; halogen, cyano, nitro, a group --(A).sub.m --S(O).sub.n R.sup.1 or a group --(A).sub.m --CO--R.sup.2 ;
Y is C.dbd.O, C.dbd.N--R.sup.3, CR.sup.7 --NR.sup.5 R.sup.6, CR.sup.7 --OR.sup.8, CR.sup.10 R.sup.11, CR.sup.7 --SR.sup.8 ; 1, 3-dioxanyl or 1,3-dioxolanyl substituted by hydrogen or C.sub.1 -C.sub.4 -alkyl; a heteroatom selected from the group oxygen, sulfur and nitrogen;
X is a chain (--CR.sup.12 R.sup.13 --), (--CR.sup.12 R.sup.13 --CR.sup.21 R.sup.22 --), (--CR.sup.12 .dbd.CR.sup.13 --), (--CR.sup.12 R.sup.13 --CR.sup.12 .dbd.CR.sup.13 --); NR.sup.23 the bond between X and Y can be saturated or unsaturated;
A is 0 or NR.sup.14 ;
m is zero or one;
n is zero, one or two;
R.sup.1 is C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -haloalkyl or NR.sup.14 ;
R.sup.2 is C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -haloalkyl, C.sub.1 -C.sub.4 -alkoxy or NR.sup.14 ;
R.sup.3 is hydrogen, --NR.sup.9 R.sup.4 ; C.sub.1 -C.sub.6 -alkyl, C.sub.1 -C.sub.6 -haloalkyl, C.sub.1 -C.sub.6 -alkoxy, C.sub.1 -C.sub.6 -haloalkoxy, C.sub.2 -C.sub.6 -alkenyl, C.sub.2 -C.sub.6 -haloalkenyl, C.sub.2 -C.sub.6 -alkynyl; monosubstituted to polysubstituted phenyl, it being possible for the substituents to consist of C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -haloalkoxy, C.sub.1 -C.sub.4 -haloalkyl, halogen, cyano, nitro; mono- to polysubstituted benzyl, it being possible for the substituents to consist of C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -haloalkoxy, C.sub.1 -C.sub.4 -haloalkyl, halogen, cyano, nitro; mono- to polysubstituted benzyloxy, it being possible for the substituents to consist of C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -haloalkoxy, C.sub.1 -C.sub.4 -haloalkyl, halogen, cyano, nitro;
R.sup.4 is hydrogen, C.sub.1 -C.sub.6 -alkyl, C.sub.1 -C.sub.6 -haloalkyl, C.sub.2 -C.sub.6 -alkenyl, C.sub.2 -C.sub.6 -alkynyl, C.dbd.O--NR.sup.14 ; monosubstituted to polysubstituted phenyl, it being possible for the substituents to consist of C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -haloalkoxy, C.sub.1 -C.sub.4 -haloalkyl, halogen, cyano, nitro; mono- to polysubstituted benzyl, it being possible for the substituents to consist of C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -haloalkoxy, C.sub.1 -C.sub.4 -haloalkyl, halogen, cyano, nitro;
R.sup.9 is hydrogen, C.sub.1 -C.sub.6 -alkyl, C.sub.1 -C.sub.6 -haloalkyl, C.sub.2 -C.sub.6 -alkenyl, C.sub.2 -C.sub.6 -alkynyl, C.dbd.O--NR.sup.14 ; monosubstituted to polysubstituted phenyl, it being possible for the substituents to consist of C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -haloalkoxy, C.sub.1 -C.sub.4 -haloalkyl, halogen, cyano, nitro; mono- to polysubstituted benzyl, it being possible for the substituents to consist of C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -haloalkoxy, C.sub.1 -C.sub.4 -haloalkyl, halogen, cyano, nitro;
R.sup.5 and R.sup.6 independently of one another are hydrogen, C.sub.1 -C.sub.6 -alkyl, C.sub.2 -C.sub.6 -alkenyl, C.sub.1 -C.sub.4 -haloalkyl, C.sub.2 -C.sub.6 -haloalkenyl, C.sub.1 -C.sub.6 -alkoxy, C.sub.1 -C.sub.6 -haloalkoxy; monosubstituted to polysubstituted phenyl, it being possible for the substituents to consist of C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -haloalkoxy, C.sub.1 -C.sub.4 -haloalkyl, halogen, cyano, nitro; mono- to polysubstituted benzyl, it being possible for the substituents to consist of C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -haloalkoxy, C.sub.1 -C.sub.4 -haloalkyl, halogen, cyano, nitro;
R.sup.7 is hydrogen, C.sub.1 -C.sub.6 -alkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -haloalkyl, C.sub.l -C.sub.4 -haloalkoxy; substituted or unsubstituted phenyl, it being possible for the substituents to consist of one to three halogens, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -haloalkoxy, nitro; R.sup.7 and R.sup.21 or R.sup.7 and R.sup.23 or R.sup.7 and R.sup.12 can form a bond;
R.sup.8 is hydrogen, C.sub.1 -C.sub.6 -alkyl, C.sub.1 -C.sub.4 -haloalkyl, substituted phenyl, it being possible for the substituents to consist of C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -haloalkoxy, C.sub.1 -C.sub.4 -haloalkyl, halogen, cyano, nitro; substituted benzyl, it being possible for the substituents to consist of C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -haloalkoxy, C.sub.1 -C.sub.4 -haloalkyl, halogen, cyano, nitro;
R.sup.10 and R.sup.11 independently of one another are hydrogen, C.sub.1 -C.sub.6 -alkyl; phenyl which is unsubstituted or substituted by one to three halogens, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -haloalkoxy, nitro; R.sup.10 and R.sup.12 or R.sup.10 and R.sup.23 or R.sup.10 and R.sup.21 can form a bond;
R.sup.12 and R.sup.13 independently of one another are hydrogen, C.sub.1 -C.sub.6 -alkyl, C.sub.1 -C.sub.6 -haloalkyl, C.sub.1 -C.sub.6 -alkoxy, C.sub.1 -C.sub.6 -haloalkoxy; unsubstituted or substituted phenyl, it being possible for the substituents to consist of C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -haloalkoxy, C.sub.1 -C.sub.4 -haloalkyl, halogen, cyano, nitro;
R.sup.14 is C.sub.1 -C.sub.4 -alkyl;
R.sup.21 is hydrogen, C.sub.1 -C.sub.6 -alkyl, C.sub.1 -C.sub.6 -haloalkyl, C.sub.1 -C.sub.6 -alkoxy, C.sub.1 -C.sub.6 -haloalkoxy; unsubstituted or substituted phenyl, it being possible for the substituents to consist of C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -haloalkoxy, C.sub.1 -C.sub.4 -haloalkyl, halogen, cyano, nitro;
R.sup.22 is hydrogen, C.sub.1 -C.sub.6 -alkyl, C.sub.1 -C.sub.6 -haloalkyl, C.sub.1 -C.sub.6 -alkoxy, C.sub.1 -C.sub.6 -haloalkoxy; unsubstituted or substituted phenyl, it being possible for the substituents to consist of C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -haloalkoxy, C.sub.1 -C.sub.4 -haloalkyl, halogen, cyano, nitro;
R.sup.23 is hydrogen, C.sub.1 -C.sub.6 -alkyl, C.sub.2 -C.sub.6 -alkenyl, C.sub.1 -C.sub.6 -alkoxy; phenyl or benzyl which is unsubstituted or substituted by C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -haloalkoxy, C.sub.1 -C.sub.4 -haloalkyl, halogen, cyano, nitro;
Q is a cyclohexane-1,3-dione ring, which is linked in the 2-position, of the formula II, ##STR4## where R.sup.15, R.sup.16, R.sup.18, and R.sup.20 are hydrogen or C.sub.1 -C.sub.4 -alkyl,
R.sup.19 is hydrogen, C.sub.1 -C.sub.4 -alkyl or a group --COOR.sup.14,
R.sup.17 is hydrogen, C.sub.1 -C.sub.4 -alkyl, C.sub.3 -C.sub.4 -cycloalkyl, it being possible for these groups, if desired, to carry one to three of the following substituents: halogen, C.sub.1 -C.sub.4 -alkylthio or C.sub.1 -C.sub.4 -alkoxy,
or
R.sup.17 is tetrahydropyran-3-yl, tetrahydropyran-4-yl or tetrahydrothiopyran-3-yl,
or
R.sup.17 and R.sup.20 together form a bond or a three to six-membered carbocyclic ring,
where in the case where Y=C.dbd.O, X is not equal to NR.sup.23,
and agriculturally customary salts of the compound [sic] I.
Compounds of the formula Ia-Ie are obtained by reacting compounds of the formula II with a benzoic acid derivative of the formula III and rearranging to give benzoyl derivatives of the formula Ia-Ie. ##STR5##
In the above scheme 1, T in said formulae has the meaning halogen or OH and L, M, X, Y and n have the meanings given above.
The first step of the reaction sequence, the acylation, is carried out in a generally known manner, e.g. by adding an acid chloride of the formula III (T=Cl) or a carboxylic acids III (T=OH) activated, for example, with DCC (dicyclocarbodiimides or similar agents known from the literature, e.g. triphenylphosphine/DEAD=diethyl azodicarboxylate, 2-pyridine disulfide/triphenylphosphine to the solution or suspension of a cyclohexanedione II, if appropriate in the presence of an auxiliary base. The reactants and the auxiliary base are in this case expediently employed in equimolar amounts. A small excess, e.g. from 1.2 to 1.5 molar equivalents, based on II, of the auxiliary base can be advantageous under certain circumstances.
Suitable auxiliary bases are tertiary alkylamines, pyridine or alkali metal carbonates. The solvents used can be, e.g. methylene chloride, dioxane, diethyl ether, toluene, acetonitrile or ethyl acetate.
During the addition of the acid chloride, the reaction mixture is preferably cooled to from 0 to 10.degree. C., then it is stirred at from 20 to 100.degree. C., in particular 25 to 50.degree. C., until the reaction is complete. working up is carried out in the customary manner, e.g. the reaction mixture is poured into water and the useful product is extracted, e.g. with methylene chloride. After drying the organic phase and removing the solvent, the crude enol ester can be employed without further purification for the rearrangement. Preparation examples for benzoyl enol esters of cyclohexane-1,3-diones are found, for example, EP-A 186 118 or U.S. Pat. No. 4,780,127.
The rearrangement of the enol esters to the compounds of the formula Ia-Ie is expediently carried out at from 20 to 40.degree. C. in a solvent and in the presence of an auxiliary base and also with the aid of a cyano compound as a catalyst.
The solvents used can be, e.g. acetonitrile, methylene chloride, 1,2-dichloroethane, ethyl acetate or toluene. A preferred solvent is acetonitrile. Suitable auxiliary bases are tertiary alkylamines, pyridine or alkali metal carbonates, which are preferably employed in equimolar amounts or up to a four-fold excess, based on the benzoyl enol ester. A preferred auxiliary base is triethylamine in twice the amount.
Suitable catalysts are potassium cyanide, acetone cyanohydrin and trimethylsilyl cyanide, preferably in an amount of from 1 to 50 mol percent, based on the enol ester. Preferably, acetone cyanohydrin is added, e.g. in the amounts from 5 to 15, in particular 10 mol percent. Examples of the cyanide-catalyzed rearrangement of enol esters are found, for example, in EP-A 186118 or U.S. Pat. No. 4,780,127.
Working up is carried out in a manner known per se, e.g. the reaction mixture is acidified with dilute mineral acids such as 5% strength hydrochloric acid or sulfuric acid and extracted with an organic solvent such as methylene chloride or ethyl acetate. For purification, the extract is extracted with cold 5 to 10% strength alkali metal carbonate solution, the final product passing into the aqueous phase. By acidifying the aqueous solution, the product of the formula Ia-Ie is precipitated or extracted again with methylene chloride or ethyl acetate, dried and then freed from the solvent.
The 1,3-diketones of the formula II used as a starting material are known and can be prepared by processes known per se, such as are described, for example, in EP-A 71707, EP-A 142741, EP-A 243313, U.S. Pat. No. 4,249,937 and WO 92/13821. Cyclohexanedione and imedone are commercially available compounds.
Benzoic acids of the formula III can be prepared as follows:
Benzoyl halides, for example benzoyl chlorides of the formula III (T=Cl), are prepared in a known manner by reacting the benzoic acids of the formula III (T=OH) with thionyl chloride.
The benzoic acids of the formula III (T=OH) can be prepared in a known manner by acidic or basic hydrolysis of the corresponding esters of the formula III (T=C.sub.1 -C.sub.4 -alkoxy).
The intermediates of the formula III are known in some cases or can be prepared by processes known from the literature. ##STR6##
After this, for example, arylthio compounds IV as shown in scheme 2 can be reacted with substituted haloalkenyl as described in J. Med. Chem. 1984, 27, 1516, substituted alkynylcarboxylic acids as described in J. Org. Chem. 1980, 45, 4611 or J. Am. Chem. Soc. 1983, 105, 883, substituted haloalkylcarboxylic acids as desribed in Chem. Ber. 1925, 58, 1612 in the presence of a base such as alkali metal hydroxide, alkali metal hydride or alkali metal carbonate. The resulting compounds V are cyclized to VI under Friedel-Crafts conditions with addition of a Lewis acid 45 or a protic acid. Preferred Lewis acids are AlCl.sub.3 or SnCl.sub.4 and preferred protic acids are polyphoshoric acid and sulfuric acid as described in Can. J. Chem. 1981, 59, 199; Chem. Ber. 1925, 58, 1625; Chem. Ber. 1926, 59, 1074; Phosp. and Sulf. 1984, 19, 31.
Thiochromenone acids can furthermore be prepared by, for example, elimination of hydrogen halide from 3-halothiochromanone acids or, for example, by reaction of the substituted thiophenol acids with substituted .alpha.-alkylacetic esters in the presence of phosphorus pentoxide as described in Ann. Chem. 1964, 680, 40.
The arylthio compounds IV can be obtained, for example, by Sandmeyer reaction from corresponding anilines, which for their part are synthesized by reduction of suitable nitro compounds as described in Organicum 19th Edition 1992, 552 ff.
In the case where, for example, X is equal to (--CR.sup.12 R.sup.13 --) or (--CR.sup.12 R.sup.13 CR.sup.21 R.sup.22 --), Y is equal to C.dbd.O and T is equal to C.sub.1 -C.sub.4 -alkoxy, the thiochromonone ester or dihydrobenzothiophene ester as described in scheme 2 can be prepared by alkylation of the arylthio compound IV with halopropionic acid or haloacetic acid in solvent or water in the presence of one of the abovementioned bases and cyclized to VI.
The reactants and the base are in this case expediently employed in equimolar amounts. The reaction mixture is preferably stirred at 20-100.degree. C., in particular at 20-40.degree. C. Working-up is carried out, for example, in such a way that the reaction mixture is poured onto water, the aqueous phase is rendered acidic using mineral acids such as hydrochloric acid or sulfuric acid and the useful product is filtered off with suction or extracted by extraction with methylene chloride or ethyl acetate, and the extract is dried and freed from the solvent. The ester can be reacted without further purification.
By stirring V in, for example, polyphosphoric acid at 40-140.degree. C., in particular at 70-100.degree. C., or by activating the carboxylic acid by conversion into the acid chloride and stirring with 2-6, in particular 3.5 to 4.5, mol equivalents of a Lewis acid such as AlCl.sub.3 or SnCl.sub.4 in a solvent or by stirring with or in sulfuric acid, an intermediate of the formula III is obtained by working up in a manner known per se, ie. adding ice water and filtering off the useful product with suction or extracting the aqueous phase with ethyl acetate or methylene chloride, drying and removing the solvent.
In the case where, for example, X is equal to an ethylene group (--CR.sup.12 .dbd.CR.sup.13 --), Y is equal to C.dbd.O and T is equal to C.sub.1 -C.sub.4 -alkoxy, the thiochromenone ester can be converted by, for example, reaction of an arylthio compound with an acetylenecarboxylic acid derivative in water or solvent at 0-140.degree. C. Working up is carried out in a manner known per se by adding water and dilute mineral acid, e.g. hydrochloric acid. The useful product is either filtered off with suction or obtained by extraction with methylene chloride or ethyl acetate, then drying and removing the solvent.
The intermediates of the formula III can be further functionalized by reactions known from the literature, such as reduction as described in Jerry March, Advanced Organic Chemistry, Fourth Ed., e.g. p.910ff, oximation as described in Jerry March, Advanced Organic Chemistry, Fourth Ed., e.g. p. 934, 935, 1039, 1226, 405ff, conversion into imines and amines as described in Jerry March, Advanced Organic Chemistry, Fourth Ed., ketalization, alkylation, halogenation, elimination and oxidation as described in Jerry March, Advanced Organic Chemistry, Fourth Ed.
The acids of the 3-alkoxy-1,2-benzisothiazole-1,1-dioxides or 3-alkoxy-1,2-benzisothiazoles can be obtained starting from corresponding saccharin derivatives or 1,2-benzisothiazoles by, for example, reaction with PCl.sub.5, POCl.sub.3 or chlorine and alcohol, if appropriate in the presence of an auxiliary base such as triethylamine, which is described, for example, in U.S. Pat. No. 4,571,429, Arch. Pharm. 1984, 317, 807, U.S. Pat. Nos. 4,461,901, 450,916, J. Med. Chem. 1986, 29, 359. Saccharincarboxylic acids can be obtained by processes known from the literature as described in Ann. Chem. 427, 231, 1922, Chem. Ber. 13, 1554, 1980, Chem. Ber. 25, 1740, 1892, German Offenlegungsschrift 3607343, German Patent Application P 44 27 995.7.
The derivatives of the benzo-1,4-oxathiin acids are known in some cases, e.g. from J. Org. Chem. 1968, 33, 456 or can be synthesized, for example, by reaction from the corresponding phenol derivatives as described in Chem. Comm., 1975, 451, J. Org. Chem. 1974, 39, 1811, J. Am. Chem. Soc. 1954, 76, 1068 or by combination of, for example, substitution reactions of halogen-substituted thiophenol derivatives and secondary reactions such as oxidation, reduction or addition as described in J. Het. Chem. 1983, 20, 867.
The benzoic acids of the formula III can also be obtained by reacting the corresponding bromo- or iodo-substituted compound of the formula VII ##STR7## T is OH, C.sub.1 -C.sub.4 -alkoxy Y,L,M,X, have the meanings described above
with carbon monoxide and water at elevated pressure in the presence of a palladium, nickel, cobalt or rhodium transition metal catalyst and a base.
The catalysts nickel, cobalt, rhodium and in particular palladium can be present in metallic form or in the form of customary salts, such as in the form of halogen compounds, e.g. PdCl.sub.2, RhCl.sub.3.H.sub.2 O, acetates, e.g. Pd(OAc).sub.2, cyanides etc., in the known valency states. Metal complexes with tertiary phosphines, metal alkylcarbonyls, metal carbonyls, e.g. CO.sub.2 (CO).sub.8, Ni(CO).sub.4, metal carbonyl complexes with tertiary phosphines, e.g. (PPh.sub.3).sub.2 Ni(CO).sub.2, or transition metal salts complexed with tertiary phosphines can further be present. The last-mentioned embodiment is preferred, in particular, in the case of palladium as a catalyst. The nature of the phosphine ligands here is widely variable. For example, they can be represented by the following formulae: ##STR8## where n is the numbers 1, 2, 3 or 4 and the radicals R.sup.24 to R.sup.27 are low molecular weight alkyl, e.g. C.sub.1 -C.sub.6 -alkyl, aryl, C.sub.1 -C.sub.4 -alkylaryl, e.g. benzyl, phenethyl or aryloxy. Aryl is, for example, naphthyl, anthryl and preferably unsubstituted or substituted phenyl, where with respect to the substituents attention only has to be paid to their inertness to the carboxylation reaction, otherwise they can be widely varied and include all inert C-organic radicals such as C.sub.1 -C.sub.6 -alkyl radicals, e.g. methyl, carboxyl radicals such as COOH, COOM (M is, for example, an alkali metal, alkaline earth metal or ammonium salt or C-organic radicals bonded via oxygen, such as C.sub.1 -C.sub.6 -alkoxy radicals.
The phosphine complexes can be prepared in a manner known per se, e.g. as described in the documents mentioned at the outset. For example, the starting materials used are customary commercially available metal salts such as PdCl.sub.2 or Pd(OCOCH.sub.3).sub.2 and the phosphine for example P(C.sub.6 H.sub.5).sub.3, P(n-C.sub.4 H.sub.9).sub.3, PCH.sub.3 (C.sub.6 H.sub.5).sub.2, 1,2-bis(diphenylphosphino)ethane is added.
The amount of phosphine, based on the transition metal, is customarily from 0 to 20, in particular 0.1 to 10, mol equivalents, particularly preferably 1 to 5 mol equivalents.
The amount of transition metal is not critical. Of course, for cost reasons, rather a small amount, e.g. from 0.1 to 10 mol %, in particular from 1 to 5 mol %, based on the starting substance II or III, is used.
For the preparation of the benzoic acids III (T=OH), the reaction is carried out with carbon monoxide and at least equimolar amounts of water, based on the starting substances VI. The reaction component water can simultaneously be used also as a solvent, ie. the maximum amount is not critical.
However, depending on the starting substances and the catalysts used, it can also be advantageous instead of the reaction component to use as the solvent another inert solvent or the base used for the carboxylation.
Suitable inert solvents are solvents customary for carboxylation reactions, such as hydrocarbons, e.g. toluene, xylene, hexane, pentane, cyclohexane, ethers, e.g. methyl tert-butyl ether, tetrahydrofuran, dioxane, dimethoxyethane, substituted amides such as dimethylformamide, persubstituted ureas such as tetra-C.sub.1 -C.sub.4 -alkylureas, or nitrites such as benzonitrile or acetonitrile.
In a preferred embodiment of the process, one of the reaction components, in particular the base, is used in an excess so that no additional solvent is necessary.
Bases suitable for the process are all inert bases which are able to bind the hydrogen iodide or hydrogen bromide liberated in the reaction. Examples which may be mentioned here are tertiary amines such as tert-alkylamines, e.g. trialkylamines such as triethylamine, cyclic amines such as N-methylpiperidine or N,N'-dimethylpiperazine, pyridine, alkali metal carbonates or hydrogen carbonates, or tetraalkyl-substituted urea derivatives such as tetra-C.sub.1 -C.sub.4 -alkylurea, e.g. tetramethylurea.
The amount of base is not critical, customarily from 1 to 10, in particular from 1 to 5, mol are used. When the base is simultaneously used as a solvent, the amount is generally proportioned such that the reaction components are dissolved, unnecessarily high excesses being avoided for practicability reasons, in order to save costs, to be able to employ small reaction vessels and to guarantee maximum contact of the reaction components.
During the reaction, the carbon monoxide pressure is adjusted such that an excess of CO, based on VI, is always present. Preferably, the carbon monoxide pressure at room temperature is from 1 to 250 bar, in particular from 5 to 150 bar of CO.
The carbonylation is generally carried out continuously or batchwise at from 20 to 250.degree. C., in particular 30 to 150.degree. C. In the case of batchwise operation, carbon monoxide is expediently injected into the reaction mixture continuously to maintain a constant pressure.
The arylhalogen compounds VII used as starting compounds are known or can easily be prepared by suitable combination of known syntheses and by reaction sequences described above.
With respect to the intended use of the benzoyl derivatives of the general formula I, suitable substituents are the following radicals:
L and M are hydrogen,
C.sub.1 -C.sub.6 -alkyl such as methyl, ethyl, propyl, 1-methylethyl, butyl, 1-methylpropyl, 2-methylpropyl, 1,1-dimethylethyl, pentyl, 1-methylbutyl, 2-methylbutyl, 3-methylbutyl, 1,1-dimethylpropyl, 1,2-dimethylpropyl, 2,2-dimethylpropyl, 1-ethylpropyl, hexyl, 1-methylpentyl, 2-methylpentyl, 3-methylpentyl, 4-methylpentyl, 1,1-dimethylbutyl, 1,2-dimethylbutyl, 1,3-dimethylbutyl, 2,2-dimethylbutyl, 2,3-dimethylbutyl, 3,3-dimethylbutyl, 1-ethylbutyl, 1,1,2-trimethylpropyl, 1,2,2-trimethylpropyl, 1-ethyl-1-methylpropyl or 1-ethyl-2-methylpropyl,
in particular methyl, ethyl, 1-methylethyl, 1-methylpropyl, 2-methylpropyl, 1, 1-dimethylethyl and 1, 1-dimethylpropyl;
C.sub.2 -C.sub.6 -alkenyl such as 2-propenyl, 2-butenyl, 3-butenyl, 1-methyl-2-propenyl, 2-methyl-2-propenyl, 2-pentenyl, 3-pentenyl, 4-pentenyl, 3-methyl-2-butenyl, 1-methyl-2-butenyl, 2-methyl-2-butenyl, 1-methyl-3-butenyl, 2-methyl-4-butenyl, 3-methyl-3-butenyl, 1,1-dimethyl-2-propenyl, 1,2-dimethyl-2-propenyl, 1-ethyl-2-propenyl, 2-hexenyl, 3-hexenyl, 4-hexenyl, 5-hexenyl, 1-methyl-2-pentenyl, 2-methyl-2-pentenyl, 3-methyl-2-pentenyl, 4-methyl-2-pentenyl, 1-methyl-3-pentenyl, 2-methyl-3-pentenyl, 3-methyl-3-pentenyl, 4-methyl-3-pentenyl, 1-methyl-4-pentenyl, 2-methyl-4-pentenyl, 3-methyl-4-pentenyl, 4-methyl-4-pentenyl, 1,1-dimethyl-2-butenyl, 1,1-dimethyl-3-butenyl, 1,2-dimethyl-2-butenyl, 1,3-dimethyl-3-butenyl, 2,2-dimethyl-3-butenyl, 2,3-dimethyl-2-butenyl, 2,3-dimethyl-3-butenyl, 1-ethyl-2-butenyl, 1-ethyl-3-butenyl, 2-ethyl-2-butenyl, 2-ethyl-3-butenyl, 1,1,2-trimethyl-2-propenyl, 1-ethyl-1-methyl-2-propenyl and ethyl-2-methyl-2-propenyl,
in particular 1-methyl-2-propenyl, 1-methyl-2-butenyl, 1,1-dimethyl-2-propenyl and 1,1-dimethyl-2-butenyl;
C.sub.2 -C.sub.6 -alkynyl such as propargyl, 2-butynyl, 3-butenyl, 2-pentynyl, 3-pentynyl, 4-pentynyl, 1-methyl-3-butynyl, 2-methyl-3-butynyl, 1-methyl-2-butynyl, 1,1-dimethyl-2-propynyl, 1-ethyl-2-propynyl, 2-hexynyl, 3-hexynyl, 4-hexynyl, 5-hexynyl, 1-methyl-2-pentynyl, 1-methyl-3-pentynyl, 1-methyl-4-pentynyl, 3-methyl-4-pentynyl, 4-methyl-2-pentynyl, 1,1-dimethyl-2-butynyl, 1,1-dimethyl-3-butynyl, 1,2-dimethyl-3-butynyl, 2,2-dimethyl-3-butynyl, 1-ethyl-2-butynyl, 1-ethyl-3-butynyl, 2-ethyl-3-butynyl and 1-ethyl-l-methyl-2-propynyl;
C.sub.1 -C.sub.4 -alkoxy such as methoxy, ethoxy, n-propoxy, 1-methylethoxy, n-butoxy, 1-methylpropoxy, 2-methylpropoxy and 1,1-dimethylethoxy,
in particular C.sub.1 -C.sub.3 -alkoxy such as methoxy, ethoxy or i-propoxy,
where these groups can be unsubstituted or substituted by one to five halogen atoms such as fluorine, chlorine, bromine and iodine, preferably fluorine and chlorine or C.sub.1 -C.sub.4 -alkoxy as mentioned above.
The group --(A).sub.m --S(O).sub.n R.sup.1 defined above is, for example
C.sub.1 -C.sub.4 -alkylthio such as methylthio, ethylthio, n-propylthio, 1-methylethylthio, n-butylthio, 1-methylpropylthio, 2-methylpropylthio and 1,1-dimethylethylthio, in particular methylthio;
C.sub.1 -C.sub.4 -alkylsulfinyl such as methylsulfinyl, ethylsulfinyl, n-propylsulfinyl, 1-methylethylsulfinyl, n-butylsulfinyl, 1-methylpropylsulfinyl, 2-methylpropylsulfinyl and 1,1-dimethylethylsulfinyl, in particular methylsulfinyl;
C.sub.1 -C.sub.4 -alkylsulfonyl such as methylsulfonyl, ethylsulfonyl, n-propylsulfonyl, 1-methylethylsulfonyl, n-butylsulfonyl, 1-methylpropylsulfonyl, 2-methylpropylsulfonyl and 1,1-dimethylethylsulfonyl, in particular methylsulfonyl;
C.sub.1 -C.sub.4 -alkoxysulfonyl such as methoxysulfonyl, ethoxysulfonyl, n-propoxysulfonyl, 1-methylethoxysulfonyl, n-butoxysulfonyl, 1-methylpropoxysulfonyl, 2-methylpropoxysulfonyl and 1,1-dimethylethoxysulfonyl, in particular methoxysulfonyl;
N-C.sub.1 -C.sub.4 -alkylsulfamoyl such as N-methylsulfamoyl, N-ethylsulfamoyl, N-n-propylsulfamoyl, N-1-methylethylsulfamoyl, N-n-butylsulfamoyl, N-1,1-methylpropylsulfamoyl, N-2-methylpropylsulfamoyl and N-1,1-dimethylethylsulfamoyl, in particular N-methylsulfamoyl;
N-C.sub.1 -C.sub.4 -alkylsulfinamoyl such as N-methylsulfinamoyl, N-ethylsulfinamoyl, N-n-propylsulfinamoyl, N-1-methylethylsulfinamoyl, N-n-butylsulfinamoyl, N-1-methylpropylsulfinamoyl, N-2-methylpropylsulfinamoyl and N-1,1-dimethylethylsulfinamoyl, in particular N-methylsulfinamoyl;
di-C.sub.1 -C.sub.4 -alkylsulfamoyl such as dimethylsulfamoyl, diethylsulfamoyl, dipropylsulfamoyl, dibutylsulfamoyl, N-methyl-N-ethylsulfamoyl, N-methyl-N-propylsulfamoyl, N-methyl-N-1-methylethylsulfamoyl, N-methyl-N--C.sub.i, 1-dimethylethylsulfamoyl, di-1-methylethylsulfamoyl, N-ethyl-N-1-methylethylsulfamoyl and N-ethyl-N-1-dimethylethylsulfamoyl; in particular dimethylsulfamoyl;
di-C.sub.1 -C.sub.4 -alkylsulfinamoyl such as dimethylsulfinamoyl, diethylsulfinamoyl, dipropylsulfinamoyl, dibutylsulfinamoyl, N-methyl-N-ethylsulfinamoyl, N-methyl-N-propylsulfinamoyl, N-methyl-N-1-methylethylsulfinamoyl, N-methyl-N-1,1-dimethylethylsulfinamoyl, di-1-methylethylsulfinamoyl, N-ethyl-N-1-methylethylsulfinamoyl and N-ethyl-N-1,1-dimethylethylsulfinamoyl; in particular dimethylsulfinamoyl,
C.sub.1 -C.sub.4 -alkylsulfinyloxy such as methylsulfinyloxy, ethylsulfinyloxy, n-propylsulfinyloxy, 1-methylethylsulfinyloxy, n-butylsulfinyloxy, 1-methylpropylsulfinyloxy, 2-methylpropylsulfinyloxy and 1,1-dimethylethylsulfinyloxy, in particular methylsulfinyloxy;
C.sub.1 -C.sub.4 -alkylsulfonyloxy such as methylsulfonyloxy, ethylsulfonyloxy, n-propylsulfonyloxy, 1-methylethylsulfonyloxy, n-butylsulfonyloxy, 1-methylpropylsulfonyloxy, 2-methylpropylsulfonyloxy
and 1,1-dimethylethylsulfonyloxy, in particular methylsulfonyloxy;
C.sub.1 -C.sub.4 -alkylsulfinylamino such as methylsulfinylamino, ethyl sulfinylamino, n-propylsulfinylamino, 1-methylethylsulfinylamino, n-butylsulfinylamino, 1-methylpropylsulfinylamino, 2-methylpropylsulfinylamino and 1,1-dimethylethylsulfinylamino, in particular methylsulfinylamino;
C.sub.1 -C.sub.4 -alkylsulfonylamino such as methylsulfonylamino, ethylsulfonylamino, n-propylsulfonylamino, 1-methylethylsulfonylamino, n-butylsulfonylamino, 1-methylpropylsulfonylamino, 2-methylpropylsulfonylamino and 1,1-dimethylethylsulfonylamino, in particular methylsulfonylamino;
N-C.sub.1 -C.sub.4 -alkylsulfinyl-N-methylamino such as N-methylsulfinyl-N-methylamino, N-ethylsulfinyl-N-methylamino, N-n-propylsulfinyl-N-methylamino, N-1-methylethylsulfinyl-N-methylamino, N-n-butylsulfinyl-N-methylamino, N-1-methylpropylsulfinyl-N-methylamino, N-2-methylpropylsulfinyl-N-methylamino and N-1,1-dimethylethylsulfinyl-N-methylamino, in particular N-methylsulfinyl-N-methylamino;
N-C.sub.1 -C.sub.4 -alkylsulfinyl-N-ethylamino such as N-methylsulfinyl-N-ethylamino, N-ethylsulfinyl-N-ethylamino, N-n-propylsulfinyl-N-ethylamino, N-1-methylethylsulfinyl-N-ethylamino, N-n-butylsulfinyl-N-ethylamino, N-1-methylpropylsulfinyl-N-ethylamino, N-2-methylpropylsulfinyl-N-ethylamino and N-1,1-dimethylethylsulfinyl-N-ethylamino, in particular N-methylsulfinyl-N-ethylamino;
N-C.sub.1 -C.sub.4 -alkylsulfonyl-N-methylamino such as N-methylsulfonyl-N-methylamino, N-ethylsulfonyl-N-methylamino, N-n-propylsulfonyl-N-methylamino, N-1-methylethylsulfonyl-N-methylamino, N-n-butylsulfonyl-N-methyl-amino, N-1-methylpropylsulfonyl-N-methylamino, N-2-methylpropylsulfonyl-N-methylamino and N-1,1-dimethylethylsulfonyl-N-methylamino, in particular N-methylsulfonyl-N-methylamino;
N-C.sub.1 -C.sub.4 -alkylsulfonyl-N-ethylamino such as N-methylsulfonyl-N-ethylamino, N-ethylsulfonyl-N-ethylamino, N-n-propylsulfonyl-N-ethylamino, N-1-methylethylsulfonyl-N-ethylamino, N-n-butylsulfonyl-N-ethylamino, N-1-methylpropylsulfonyl-N-ethylamino, N-2-methylpropylsulfonyl-N-ethylamino and N-1,1-dimethylethylsulfonyl-N-ethylamino, in particular N-methylsulfonyl-N-ethylamino;
C.sub.1 -C.sub.4 -haloalkylthio such as chloromethylthio, dichloromethylthio, trichloromethylthio, fluoromethylthio, difluoromethylthio, trifluoromethylthio, chlorofluoromethylthio, chlorodifluoromethylthio, 1-fluoroethylthio, 2-fluoroethylthio, 2,2-difluoroethylthio, 2,2,2-trifluoroethylthio, 2-chloro-2,2-difluoroethylthio, 2,2-dichloro-2 fluoroethylthio, 2,2,2-trichloroethylthio and pentafluoroethylthio, in particular trifluoromethylthio.
The group --(A).sub.m --CO--R.sup.2 defined above is, for example,
C.sub.1 -C.sub.4 -alkylcarbonyl such as methylcarbonyl, ethylcarbonyl, n-propylcarbonyl, 1-methylethylcarbonyl, n-butylcarbonyl, 1-methylpropylcarbonyl, 2-methylpropylcarbonyl and 1,1-dimethylethylcarbonyl, in particular methylcarbonyl;
C.sub.1 -C.sub.4 -alkoxycarbonyl such as methoxycarbonyl, ethoxycarbonyl, n-propoxycarbonyl, 1-methylethoxycarbonyl, n-butoxycarbonyl, 1-methylpropoxycarbonyl, 2-methylpropoxycarbonyl and 1,1-dimethylethoxycarbonyl, in particular methoxycarbonyl;
N-C.sub.1 -C.sub.4 -alkylcarbamoyl such as N-methylcarbamoyl, N-ethylcarbamoyl, N-n-propylcarbamoyl, N-1-methylethylcarbamoyl, N-n-butylcarbamoyl, N-1-methylpropylcarbamoyl, N-2-methylpropylcarbamoyl and N-1,1-dimethylethylcarbamoyl, in particular N-methylcarbamoyl;
di-C.sub.1 -C.sub.4 -alkylcarbamoyl such as dimethylcarbamoyl, diethylcarbamoyl, dipropylcarbamoyl, dibutylcarbamoyl, N-methyl-N-ethylcarbamoyl, N-methyl-N-propylcarbamoyl, N-methyl-N-1-methylethylcarbamoyl, N-methyl-N-1,1-dimethylethylcarbamoyl, di-1-methylethylcarbamoyl, N-ethyl-N-1-methylethylcarbamoyl and N-ethyl-N-1,1-dimethylethylcarbamoyl; in particular dimethylcarbamoyl;
C.sub.1 -C.sub.4 -alkylcarbonyloxy such as methylcarbonyloxy, ethylcarbonyloxy, n-propylcarbonyloxy, 1-methylethylcarbonyloxy, n-butylcarbonyloxy, 1-methylpropylcarbonyloxy, 2-methylpropylcarbonyloxy and 1,1-dimethylethylcarbonyloxy, in particular methylcarbonyloxy;
C.sub.1 -C.sub.4 -alkylcarbonylamino such as methylcarbonylamino, ethylcarbonylamino, n-propylcarbonylamino, 1-methylethylcarbonylamino, n-butylcarbonylamino, 1-methylpropylcarbonylamino, 2-methylpropylcarbonylamino and 1,1-dimethylethylcarbonylamino, in particular methylcarbonylamino;
N-C.sub.1 -C.sub.4 -alkylcarbonyl-N-methylamino such as N-methylcarbonyl-N-methylamino, N-ethylcarbonyl-N-methylamino, N-n-propylcarbonyl-N-methylamino, N-1-methylethylcarbonyl-N-methylamino, N-n-butylcarbonyl-N-methylamino, N-1-methylpropylcarbonyl-N-methylamino, N-2-methylpropylcarbonyl-N-methylamino and N-1,1-dimethylethylcarbonyl-N-methyl-amino, in particular N-methylcarbonyl-N-methylamino.
X is, for example: CH.sub.2, CH(CH.sub.3), C((CH.sub.3).sub.2), CH(C.sub.2 H.sub.5), C((C.sub.2 H.sub.5).sub.2), CH(C.sub.6 H.sub.5), CH.sub.2 --CH.sub.2, CH.sub.2 --CH(CH.sub.3), CH.sub.2 --C((CH.sub.3).sub.2), CH(CH.sub.3)--CH(CH.sub.3), CH(CH.sub.3)--C((CH.sub.3).sub.2), C((CH.sub.3).sub.2)--C((CH.sub.3).sub.2), CH.sub.2 --CH(C.sub.2 H.sub.5), CH.sub.2 --C((C.sub.2 H.sub.5).sub.2), CH(C.sub.2 H.sub.5)--CH(C.sub.2 H.sub.5), CH(C.sub.2 H.sub.5)--C((C.sub.2 H.sub.5).sub.2), C((C.sub.2 H.sub.5).sub.2)--C((C.sub.2 H.sub.5).sub.2), CH.sub.2 --CH(C.sub.3 H.sub.7), CH.sub.2 --CH(iC.sub.3 H.sub.7), CH.sub.2 --CH(C.sub.4 H.sub.9), CH.sub.2 --CH(iC.sub.4 H.sub.9), CH.sub.2 --CH(Br), CH.sub.2 --C((Br).sub.2), CH(Br)--CH(Br), C((Br).sub.2)--C((Br).sub.2), CH.sub.2 --CH(Cl), CH.sub.2 --C((Cl).sub.2), CH(Cl)--C((Cl.sub.2), C((Cl).sub.2)--C((Cl).sub.2), CH.sub.2 --CH(C.sub.6 H.sub.5), CH(C.sub.6 H.sub.5)--CH(C.sub.6 H.sub.5), CH.sub.2 --CH(p-NO.sub.2 C.sub.6 H.sub.5)]CH.dbd.CH, C(CH.sub.3).dbd.CH, C(CH.sub.3).dbd.CCH.sub.3, CH.dbd.CBr, CH.dbd.CCl, CBr.dbd.CBr, CCl.dbd.CCl, CH.dbd.C(OCH.sub.3), CH.dbd.C(C.sub.6 H.sub.5), C(C.sub.6 H.sub.5).dbd.C(C.sub.6 H.sub.5), C(C.sub.2 H.sub.5).dbd.CH, C(C.sub.2 H.sub.5).dbd.C(C.sub.2 H.sub.5), CH.dbd.C(C.sub.3 H.sub.5), CH.dbd.C(C.sub.4 H.sub.7), CH.sub.2 --CH.dbd.CH, CH(CH.sub.3)--C.dbd.CH, C((CH.sub.3).sub.2)--CH.dbd.CH, CH.sub.2 --CH.dbd.C(CH.sub.3), CH.sub.2 --C(CH.sub.3).dbd.CH, CH.sub.2 --C(CH.sub.3).dbd.C(CH.sub.3), CH(CH.sub.3)--C(CH.sub.3).dbd.C(CH.sub.3), C((CH.sub.3).sub.2)--C(CH.sub.3).dbd.C(CH.sub.3), N--H, N--CH.sub.3, N--C.sub.2 H.sub.5, N--C.sub.3 H.sub.7, N--C.sub.4 H.sub.9, N-iCH.sub.3 H.sub.7, N--OCH.sub.3, N--OC.sub.2 H.sub.5, N--CH.sub.2 C.sub.6 H.sub.5, N--C.sub.6 H.sub.5 ;
Y is, for example:
C.dbd.O, CH--OH, CH--OCH.sub.3, CH--OC.sub.2 H.sub.5, CH--OC.sub.3 H.sub.7, CH--OiPr, CH--OC.sub.4 H.sub.9, CH--OiBu, CH--OC.sub.5 H.sub.11, CH--OC.sub.6 H.sub.13, CH--OC.sub.6 H.sub.5, C(CH.sub.3)--OCH.sub.3, C(CH.sub.3)--OC.sub.2 H.sub.5, C(CH.sub.3)--OC.sub.3 H.sub.7, C(CH.sub.3)--OC.sub.4 H.sub.9, C(CH.sub.3)--OiPr, C(CH.sub.3)--OiBu, C(CH.sub.3)--OtBu, C(CH.sub.3)--OPh, CH.sub.2, CH(CH.sub.3), C((CH.sub.3).sub.2), C.dbd.N--CH.sub.3, C.dbd.N--C.sub.2 H.sub.5, C.dbd.N-C.sub.3 H.sub.7, C.dbd.N-C.sub.4 H.sub.9, C.dbd.N-iC.sub.4 H.sub.9, C.dbd.N-tC.sub.4 H.sub.9, C.dbd.N-iPr, C.dbd.N--OCH.sub.3, C.dbd.N-OC.sub.2 H.sub.5, C.dbd.N--OC.sub.3 H.sub.7, C.dbd.N--OC.sub.4 H.sub.9, C.dbd.N--OiC.sub.4 H.sub.9, C.dbd.N--OtC.sub.4 H.sub.9, C.dbd.N--OCH.sub.2 CH.dbd.CH.sub.2, C.dbd.N--OCH(CH.sub.3)CH.dbd.CH.sub.2, C.dbd.N--OCH.sub.2 CH.dbd.CHCH.sub.3, C.dbd.N--OCH.sub.2 CH.dbd.C(CH.sub.3).sub.2, C.dbd.N--OCH.sub.2 CH.dbd.CHBr, C.dbd.N--OCH.sub.2 CH.dbd.CHCl, C.dbd.N--OCH.sub.2 CH.dbd.CHC.sub.2 H.sub.5, C.dbd.N--OCH.sub.2 C.tbd.CH, C.dbd.N--OCH.sub.2 C.tbd.CCH3, C.dbd.N--OCH.sub.2 C.sub.6 H.sub.5, CH--NH(OCH.sub.3), CH--NH(OC.sub.2 H.sub.5), CH--NH(OiPr), CH--NH(OnPr), CH--NH(OC.sub.6 H.sub.5), CH--NCH.sub.3 (OCH.sub.3), CH--NCH.sub.3 (OC.sub.2 H.sub.5), CH--NCH.sub.3 (OiPr), CH--NCH.sub.3 (OnPr), CH--NCH.sub.3 (OC.sub.6 H.sub.5), CH--NH(CH.sub.3), CH--NH(C.sub.2 H.sub.5), CH--NH(C.sub.3 H.sub.7), CH--NH(C.sub.4 H.sub.9), CH--NH(iPr), CH--NH(iBu), CH--NH(tBu), CH--NH(C.sub.6 H.sub.5), CH--N(CH.sub.3).sub.2, CH--NCH.sub.3 (C.sub.2 H.sub.5), CH--NCH.sub.3 (C.sub.3 H.sub.7), CH--NCH.sub.3 (C.sub.4 H.sub.9), CH--NCH.sub.3 (iPr), CH--NCH.sub.3 (iBu), C.dbd.N--NH.sub.2, C.dbd.N--NHCH.sub.3, C.dbd.N--((CH.sub.3).sub.2), C.dbd.N--NH(C.sub.2 H.sub.5), C.dbd.N--NCH.sub.3 (C.sub.2 H.sub.5), C.dbd.N--N((C.sub.2 H.sub.5).sub.2), CH--SCH.sub.3, CH--SC.sub.2 H.sub.5, CH--SC.sub.3 H.sub.7, CH--SC.sub.4 H.sub.9, CH--SPr, CH--SiBu, CH--SH, C(CH.sub.3)--SCH.sub.3, C(CH.sub.3)--SC.sub.2 H.sub.5, C(CH.sub.3)--SC.sub.3 H.sub.7, 1,3-dioxanyl, 1,3-dioxolanyl, 5,5-dimethyl-1,3-dioxanyl
Preferred benzoyl derivatives are those of the formula Ia, ##STR9## where L is hydrogen, C.sub.1 -C.sub.6 -alkyl, C.sub.2 -C.sub.6 -alkenyl, C.sub.2 -C.sub.6 -alkynyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -alkylthio, C.sub.1 -C.sub.4 -haloalkyl, C.sub.1 -C.sub.4 -haloalkoxy, C.sub.1 -C.sub.4 -haloalkylthio, C.sub.1 -C.sub.4 -alkylsulfonyl, halogen, nitro or cyano and M is hydrogen, C.sub.1 -C.sub.6 -alkyl, C.sub.2 -C.sub.6 -alkenyl, C.sub.2 -C.sub.6 -alkynyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -alkylthio, C.sub.1 -C.sub.4 -haloalkyl, C.sub.1 -C.sub.4 -haloalkoxy, C.sub.1 -C.sub.4 -haloalkoxy, C.sub.1 -C.sub.4 -haloalkylthio, C.sub.1 -C.sub.4 -alkylsulfonyl, halogen, nitro or cyano and Q, X, n and Y have the meanings given in claim 1, where in the case where Y=C.dbd.O, X is not equal to NR.sup.23.
Furthermore preferred benzoyl derivatives are those of the formula Ib, ##STR10## where L is C.sub.1 -C.sub.6 -alkyl, C.sub.2 -C.sub.6 -alkenyl, C.sub.2 -C.sub.6 -alkynyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -haloalkyl, C.sub.-C.sub.1 -C.sub.4 -haloalkoxy, halogen, nitro or cyano and M is hydrogen, C.sub.1 -C.sub.6 -alkyl, C.sub.2 -C.sub.6 -alkenyl, C.sub.2 -C.sub.6 -alkynyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -haloalkyl, C.sub.1 -C.sub.4 -haloalkoxy, halogen, nitro or cyano and Q, X, n and Y have the meanings given in claim 1, where in the case where Y=C.dbd.O, X is not equal to NR.sup.23.
Preferred benzoyl derivatives are also those of the formula I as claimed in claim 1, where the radicals L and M are hydrogen, methyl, methoxy, chlorine, cyano, nitro or trifluoromethyl.
Preferred benzoyl derivatives are those of the formula Ic, ##STR11## where L is hydrogen, C.sub.1 -C.sub.6 -alkyl, C.sub.2 -C.sub.6 -alkenyl, C.sub.2 -C.sub.6 -alkynyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -haloalkyl, C.sub.1 -C.sub.4 -haloalkoxy, halogen, nitro or cyano and M is hydrogen, C.sub.1 -C.sub.6 -alkyl, C.sub.2 -C.sub.6 -alkenyl, C.sub.2 -C.sub.6 -alkynyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -haloalkyl, C.sub.1 -C.sub.4 -haloalkoxy, halogen, nitro or cyano and Q, n, Y and also R.sup.22, R.sup.21, R.sup.12 and R.sup.13 have the meanings given in claim 1.
Likewise preferred benzoyl derivatives are those of the formula Id, ##STR12## where L is hydrogen, C.sub.1 -C.sub.6 -alkyl, C.sub.2 -C.sub.6 -alkenyl, C.sub.2 -C.sub.6 -alkynyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.1 -C.sub.4 -haloalkyl, C.sub.1 -C.sub.4 -haloalkoxy, halogen, nitro or cyano and M is hydrogen, C.sub.1 -C.sub.6 -alkyl, C.sub.2 -C.sub.6 -alkenyl, C.sub.2 -C.sub.6 -alkynyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -haloalkyl, C.sub.1 -C.sub.4 -haloalkoxy, halogen, nitro or cyano and Q, n, Y and also R.sup.12 and R.sup.13 have the meanings given in claim 1.
Also preferred benzoyl derivatives are those of the formula Ie, ##STR13## where L is hydrogen, C.sub.1 -C.sub.6 -alkyl, C.sub.2 -C.sub.6 -alkenyl, C.sub.2 -C.sub.6 -alkynyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -haloalkyl, C.sub.1 -C.sub.4 -haloalkoxy, halogen, nitro or cyano and M is hydrogen, C.sub.1 -C.sub.6 -alkyl, C.sub.2 -C.sub.6 -alkenyl, C.sub.2 -C.sub.6 -alkynyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -haloalkyl, C.sub.1 -C.sub.4 -haloalkoxy, halogen, nitro or cyano and Q, n, Y and also R.sup.12 and R.sup.13 have the meanings given in claim 1.
Preferred benzoyl derivatives are likewise those of the formula I as claimed in claim 1, where n is 1 or 2 and Y is CR.sup.7 --OR.sup.8, where R.sup.7 and R.sup.8 have the meanings given in claim 1.
TABLE 1__________________________________________________________________________Compounds of the formula ##STR14##No. R.sup.17 R.sup.18 R.sup.19 n R.sup.12 R.sup.13 Y L M__________________________________________________________________________1.1 H H H 0 H H C.dbd.O H H1.2 H H H 2 H H C.dbd.O H H1.3 H H H 0 H H CHOCH.sub.3 H H1.4 H H H 2 H H CHOCH.sub.3 H H1.5 H H H 0 H H CHOC.sub.2 H.sub.5 H H1.6 H H H 2 H H CHOC.sub.2 H.sub.5 H H1.7 H H H 0 H H CHOiPr H H1.8 H H H 2 H H CHOiPr H H1.9 H H H 0 H H CHOH H H1.10 H H H 2 H H CHOH H H1.11 H H H 0 H H C.dbd.NOCH.sub.3 H H1.12 H H H 2 H H C.dbd.NOCH.sub.3 H H1.13 H H H 0 H H C.dbd.NOC.sub.2 H.sub.5 H H1.14 H H H 2 H H C.dbd.NOC.sub.2 H.sub.5 H H1.15 H H H 0 H H C.dbd.NOiPr H H1.16 H H H 2 H H C.dbd.NOiPr H H1.17 H H H 0 H H C.dbd.NOCH.sub.2 CH.dbd.CHCl H H1.18 H H H 2 H H C.dbd.NOCH.sub.2 CH.dbd.CHCl H H1.19 H H H 0 H H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 H H1.20 H H H 2 H H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 H H1.21 H H H 0 H H C(CH.sub.3).sub.2 H H1.22 H H H 2 H H C(CH.sub.3).sub.2 H H1.23 CH.sub.3 H H 0 H H C.dbd.O H H1.24 CH.sub.3 H H 2 H H C.dbd.O H H1.25 CH.sub.3 H H 0 H H CHOCH.sub.3 H H1.26 CH.sub.3 H H 2 H H CHOCH.sub.3 H H1.27 CH.sub.3 H H 0 H H CHOC.sub.2 H.sub.5 H H1.28 CH.sub.3 H H 2 H H CHOC.sub.2 H.sub.5 H H1.29 CH.sub.3 H H 0 H H CHOiPr H H1.30 CH.sub.3 H H 2 H H CHOiPr H H1.31 CH.sub.3 H H 0 H H CHOH H H1.32 CH.sub.3 H H 2 H H CHOH H H1.33 CH.sub.3 H H 0 H H C.dbd.NOCH.sub.3 H H1.34 CH.sub.3 H H 2 H H C.dbd.NOCH.sub.3 H H1.35 CH.sub.3 H H 0 H H C.dbd.NOC.sub.2 H.sub.5 H H1.36 CH.sub.3 H H 2 H H C.dbd.NOC.sub.2 H.sub.5 H H1.37 CH.sub.3 H H 0 H H C.dbd.NOiPr H H1.38 CH.sub.3 H H 2 H H C.dbd.NOiPr H H1.39 CH.sub.3 H H 0 H H C.dbd.NOCH.sub.2 CH.dbd.CHCl H H1.40 CH.sub.3 H H 2 H H C.dbd.NOCH.sub.2 CH.dbd.CHCl H H1.41 CH.sub.3 H H 0 H H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 H H1.42 CH.sub.3 H H 2 H H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 H H1.43 CH.sub.3 H H 0 H H C(CH.sub.3).sub.2 H H1.44 CH.sub.3 H H 2 H H C(CH.sub.3).sub.2 H H1.45 CH.sub.3 CH.sub.3 H 0 H H C.dbd.O H H1.46 CH.sub.3 CH.sub.3 H 2 H H C.dbd.O H H1.47 CH.sub.3 CH.sub.3 H 0 H H CHOCH.sub.3 H H1.48 CH.sub.3 CH.sub.3 H 2 H H CHOCH.sub.3 H H1.49 CH.sub.3 CH.sub.3 H 0 H H CHOC.sub.2 H.sub.5 H H1.50 CH.sub.3 CH.sub.3 H 2 H H CHOC.sub.2 H.sub.5 H H1.51 CH.sub.3 CH.sub.3 H 0 H H CHOiPr H H1.52 CH.sub.3 CH.sub.3 H 2 H H CHOiPr H H1.53 CH.sub.3 CH.sub.3 H 0 H H C.dbd.NOCH.sub.3 H H1.54 CH.sub.3 CH.sub.3 H 2 H H C.dbd.NOCH.sub.3 H H1.55 CH.sub.3 CH.sub.3 H 0 H H C.dbd.NOC.sub.2 H.sub.5 H H1.56 CH.sub.3 CH.sub.3 H 2 H H C.dbd.NOC.sub.2 H.sub.5 H H1.57 CH.sub.3 CH.sub.3 H 0 H H C.dbd.NOiPr H H1.58 CH.sub.3 CH.sub.3 H 2 H H C.dbd.NOiPr H H1.59 CH.sub.3 CH.sub.3 H 0 H H C.dbd.NOCH.sub.2 CH.dbd.CHCl H H1.60 CH.sub.3 CH.sub.3 H 2 H H C.dbd.NOCH.sub.2 CH.dbd.CHCl H H1.61 CH.sub.3 CH.sub.3 H 0 H H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 H H1.62 CH.sub.3 CH.sub.3 H 2 H H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 H H1.63 CH.sub.3 CH.sub.3 H 0 H H C(CH.sub.3).sub.2 H H1.64 CH.sub.3 CH.sub.3 H 2 H H C(CH.sub.3).sub.2 H H1.65 H H H 0 H H C.dbd.O H CH.sub.31.66 H H H 2 H H C.dbd.O H CH.sub.31.67 H H H 0 H H CHOCH.sub.3 H CH.sub.31.68 H H H 2 H H CHOCH.sub.3 H CH.sub.31.69 H H H 0 H H CHOC.sub.2 H.sub.5 H CH.sub.31.70 H H H 2 H H CHOC.sub.2 H.sub.5 H CH.sub.31.71 H H H 0 H H CHOiPr H CH.sub.31.72 H H H 2 H H CHOiPr H CH.sub.31.73 H H H 0 H H C.dbd.NOCH.sub.3 H CH.sub.31.74 H H H 2 H H C.dbd.NOCH.sub.3 H CH.sub.31.75 H H H 0 H H C.dbd.NOC.sub.2 H.sub.5 H CH.sub.31 76 H H H 2 H H C.dbd.NOC.sub.2 H.sub.5 H CH.sub.31.77 H H H 0 H H C.dbd.NOiPr H CH.sub.31.78 H H H 2 H H C.dbd.NOiPr H CH.sub.31.79 H H H 0 H H C.dbd.NOCH.sub.2 CH.dbd.CHCl H CH.sub.31.80 H H H 2 H H C.dbd.NOCH.sub.2 CH.dbd.CHCl H CH.sub.31.81 H H H 0 H H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 H CH.sub.31.82 H H H 2 H H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 H CH.sub.31.83 H H H 0 H H C(CH.sub.3).sub.2 H CH.sub.31.84 H H H 2 H H C(CH.sub.3).sub.2 H CH.sub.31.85 CH.sub.3 H H 0 H H C.dbd.O H CH.sub.31.86 CH.sub.3 H H 2 H H C.dbd.O H CH.sub.31.87 CH.sub.3 H H 0 H H CHOCH.sub.3 H CH.sub.31.88 CH.sub.3 H H 2 H H CHOCH.sub.3 H CH.sub.31.89 CH.sub.3 H H 0 H H CHOC.sub.2 H.sub.5 H CH.sub.31.90 CH.sub.3 H H 2 H H CHOC.sub.2 H.sub.5 H CH.sub.31.91 CH.sub.3 H H 0 H H CHOiPr H CH.sub.31.92 CH.sub.3 H H 2 H H CHOiPr H CH.sub.31.93 CH.sub.3 H H 0 H H C.dbd.NOCH.sub.3 H CH.sub.31.94 CH.sub.3 H H 2 H H C.dbd.NOCH.sub.3 H CH.sub.31.95 CH.sub.3 H H 0 H H C.dbd.NOC.sub.2 H.sub.5 H CH.sub.31.96 CH.sub.3 H H 2 H H C.dbd.NOC.sub.2 H.sub.5 H CH.sub.31.97 CH.sub.3 H H 0 H H C.dbd.NOiPr H CH.sub.31.98 CH.sub.3 H H 2 H H C.dbd.NOiPr H CH.sub.31.99 CH.sub.3 H H 0 H H C.dbd.NOCH.sub.2 CH.dbd.CHCl H CH.sub.31.100 CH.sub.3 H H 2 H H C.dbd.NOCH.sub.2 CH.dbd.CHCl H CH.sub.31.101 CH.sub.3 H H 0 H H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 H CH.sub.31.102 CH.sub.3 H H 2 H H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 H CH.sub.31.103 CH.sub.3 H H 0 H H C(CH.sub.3).sub.2 H CH.sub.31.104 CH.sub.3 H H 2 H H C(CH.sub.3).sub.2 H CH.sub.31.105 CH.sub.3 CH.sub.3 H 0 H H C.dbd.O H CH.sub.31.106 CH.sub.3 CH.sub.3 H 2 H H C.dbd.O H CH.sub.31.107 CH.sub.3 CH.sub.3 H 0 H H CHOCH.sub.3 H CH.sub.31.108 CH.sub.3 CH.sub.3 H 2 H H CHOCH.sub.3 H CH.sub.31.109 CH.sub.3 CH.sub.3 H 0 H H CHOC.sub.2 H.sub.5 H CH.sub.31.110 CH.sub.3 CH.sub.3 H 2 H H CHOC.sub.2 H.sub.5 H CH.sub.31.111 CH.sub.3 CH.sub.3 H 0 H H CHOiPr H CH.sub.31.112 CH.sub.3 CH.sub.3 H 2 H H CHOiPr H CH.sub.31.113 CH.sub.3 CH.sub.3 H 0 H H CHOH H CH.sub.31.114 CH.sub.3 CH.sub.3 H 2 H H CHOH H CH.sub.31.115 CH.sub.3 CH.sub.3 H 0 H H C.dbd.NOCH.sub.3 H CH.sub.31.116 CH.sub.3 CH.sub.3 H 2 H H C.dbd.NOCH.sub.3 H CH.sub.31.117 CH.sub.3 CH.sub.3 H 0 H H C.dbd.NOC.sub.2 H.sub.5 H CH.sub.31.118 CH.sub.3 CH.sub.3 H 2 H H C.dbd.NOC.sub.2 H.sub.5 H CH.sub.31.119 CH.sub.3 CH.sub.3 H 0 H H C.dbd.NOiPr H CH.sub.31.120 CH.sub.3 CH.sub.3 H 2 H H C.dbd.NOiPr H CH.sub.31.121 CH.sub.3 CH.sub.3 H 0 H H C.dbd.NOCH.sub.2 CH.dbd.CHCl H CH.sub.31.122 CH.sub.3 CH.sub.3 H 2 H H C.dbd.NOCH.sub.2 CH.dbd.CHCl H CH.sub.31.123 CH.sub.3 CH.sub.3 H 0 H H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 H CH.sub.31.124 CH.sub.3 CH.sub.3 H 2 H H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 H CH.sub.31.125 CH.sub.3 CH.sub.3 H 0 H H C(CH.sub.3).sub.2 H CH.sub.31.126 CH.sub.3 CH.sub.3 H 2 H H C(CH.sub.3).sub.2 H CH.sub.31.127 H H H 0 H H C.dbd.O H Cl1.128 H H H 2 H H C.dbd.O H Cl1.129 H H H 0 H H CHOCH.sub.3 H Cl1.130 H H H 2 H H CHOCH.sub.3 H Cl1.131 H H H 0 H H CHOC.sub.2 H.sub.5 H Cl1.132 H H H 2 H H CHOC2 H.sub.5 H Cl1.133 H H H 0 H H CHOiPr H Cl1.134 H H H 2 H H CHOiPr H Cl1.135 H H H 0 H H C.dbd.NOCH.sub.3 H Cl1.136 H H H 2 H H C.dbd.NOCH.sub.3 H Cl1.137 H H H 0 H H C.dbd.NOC.sub.2 H.sub.5 H Cl1.138 H H H 2 H H C.dbd.NOC.sub.2 H.sub.5 H Cl1.139 H H H 0 H H C.dbd.NOiPr H Cl1.140 H H H 2 H H C.dbd.NOiPr H Cl1.141 H H H 0 H H C.dbd.NOCH.sub.2 CH.dbd.CHCl H Cl1.142 H H H 2 H H C.dbd.NOCH.sub.2 CH.dbd.CHCl H Cl1.143 H H H 0 H H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 H Cl1.144 H H H 2 H H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 H Cl1.145 H H H 0 H H C(CH.sub.3).sub.2 H Cl1.146 H H H 2 H H C(CH.sub.3).sub.2 H Cl1.147 CH.sub.3 H H 0 H H C.dbd.O H Cl1.148 CH.sub.3 H H 2 H H C.dbd.O H Cl1.149 CH.sub.3 H H 0 H H CHOCH.sub.3 H Cl1.150 CH.sub.3 H H 2 H H CHOCH.sub.3 H Cl1.151 CH.sub.3 H H 0 H H CHOC.sub.2 H.sub.5 H Cl1.152 CH.sub.3 H H 2 H H CHOC.sub.2 H.sub.5 H Cl1.153 CH.sub.3 H H 0 H H CHOiPr H Cl1.154 CH.sub.3 H H 2 H H CHOiPr H Cl1.155 CH.sub.3 H H 0 H H C.dbd.NOCH.sub.3 H Cl1.156 CH.sub.3 H H 2 H H C.dbd.NOCH.sub.3 H Cl1.157 CH.sub.3 H H 0 H H C.dbd.NOC.sub.2 H.sub.5 H Cl1158 CH.sub.3 H H 2 H H C.dbd.NOC.sub.2 H.sub.5 H Cl1.159 CH.sub.3 H H 0 H H C.dbd.NOiPr H Cl1.160 CH.sub.3 H H 2 H H C.dbd.NOiPr H Cl1.161 CH.sub.3 H H 0 H H C.dbd.NOCH.sub.2 CH.dbd.CHCl H Cl1.162 CH.sub.3 H H 2 H H C.dbd.NOCH.sub.2 CH.dbd.CHCl H Cl1.163 CH.sub.3 H H 0 H H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 H Cl1.164 CH.sub.3 H H 2 H H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 H Cl1.165 CH.sub.3 H H 0 H H C(CH.sub.3).sub.2 H Cl1.166 CH.sub.3 H H 2 H H C(CH.sub.3).sub.2 H Cl1.167 CH.sub.3 CH.sub.3 H 0 H H C.dbd.O H Cl1.168 CH.sub.3 CH.sub.3 H 2 H H C.dbd.O H Cl1.169 CH.sub.3 CH.sub.3 H 0 H H CHOCH.sub.3 H Cl1.170 CH.sub.3 CH.sub.3 H 2 H H CHOCH.sub.3 H Cl1.171 CH.sub.3 CH.sub.3 H 0 H H CHOC.sub.2 H.sub.5 H Cl1.172 CH.sub.3 CH.sub.3 H 2 H H CHOC.sub.2 H.sub.5 H Cl1.173 CH.sub.3 CH.sub.3 H 0 H H CHOiPr H Cl1.174 CH.sub.3 CH.sub.3 H 2 H H CHOiPr H Cl1.175 CH.sub.3 CH.sub.3 H 0 H H C.dbd.NOCH.sub.3 H Cl1.176 CH.sub.3 CH.sub.3 H 2 H H C.dbd.NOCH.sub.3 H Cl1.177 CH.sub.3 CH.sub.3 H 0 H H C.dbd.NOC.sub.2 H.sub.5 H Cl1.178 CH.sub.3 CH.sub.3 H 2 H H C.dbd.NOC.sub.2 H.sub.5 H Cl1.179 CH.sub.3 CH.sub.3 H 0 H H C.dbd.NOiPr H Cl1.180 CH.sub.3 CH.sub.3 H 2 H H C.dbd.NOiPr H Cl1.181 CH.sub.3 CH.sub.3 H 0 H H C.dbd.NOCH.sub.2 CH.dbd.CHCl H Cl1.182 CH.sub.3 CH.sub.3 H 2 H H C.dbd.NOCH.sub.2 CH.dbd.CHCl H Cl1.183 CH.sub.3 CH.sub.3 H 0 H H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 H Cl1.184 CH.sub.3 CH.sub.3 H 2 H H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 H Cl1.185 CH.sub.3 CH.sub.3 H 0 H H C(CH.sub.3).sub.2 H Cl1.186 CH.sub.3 CH.sub.3 H 2 H H C(CH.sub.3).sub.2 H Cl__________________________________________________________________________
TABLE 2______________________________________Compounds of the formula ##STR15##The radicals R.sup.12 of X and R.sup.7 of Y form a bondNo. R.sup.17 R.sup.18 R.sup.19 n R.sup.13 Y L M______________________________________2.1 H H H 0 H COCH.sub.3 H H2.2 H H H 2 H COCH.sub.3 H H2.3 H H H 0 H COC.sub.2 H.sub.5 H H2.4 H H H 2 H COC.sub.2 H.sub.5 H H2.5 H H H 0 H COiPr H H2.6 H H H 2 H COiPr H H2.7 CH.sub.3 H H 0 H COCH.sub.3 H H2.8 CH.sub.3 H H 2 H COCH.sub.3 H H2.9 CH.sub.3 H H 0 H COC.sub.2 H.sub.5 H H2.10 CH.sub.3 H H 2 H COC.sub.2 H.sub.5 H H2.11 CH.sub.3 H H 0 H COiPr H H2.12 CH.sub.3 H H 2 H COiPr H H2.13 CH.sub.3 CH.sub.3 H 0 H COCH.sub.3 H H2.14 CH.sub.3 CH.sub.3 H 2 H COCH.sub.3 H H2.15 CH.sub.3 CH.sub.3 H 0 H COC.sub.2 H.sub.5 H H2.16 CH.sub.3 CH.sub.3 H 2 H COC.sub.2 H.sub.5 H H2.17 CH.sub.3 CH.sub.3 H 0 H COiPr H H2.18 CH.sub.3 CH.sub.3 H 2 H COiPr H H2.19 H H H 0 H COCH.sub.3 H CH.sub.32.20 H H H 2 H COCH.sub.3 H CH.sub.32.21 H H H 0 H COC.sub.2 H.sub.5 H CH.sub.32.22 H H H 2 H COC.sub.2 H.sub.5 H CH.sub.32.23 H H H 0 H COiPr H CH.sub.32.24 H H H 2 H COiPr H CH.sub.32.25 CH.sub.3 H H 0 H COCH.sub.3 H CH.sub.32.26 CH.sub.3 H H 2 H COCH.sub.3 H CH.sub.32.27 CH.sub.3 H H 0 H COC.sub.2 H.sub.5 H CH.sub.32.28 CH.sub.3 H H 2 H COC.sub.2 H.sub.5 H CH.sub.32.29 CH.sub.3 H H 0 H COiPr H CH.sub.32.30 CH.sub.3 H H 2 H COiPr H CH.sub.32.31 CH.sub.3 CH.sub.3 H 0 H COCH.sub.3 H CH.sub.32.32 CH.sub.3 CH.sub.3 H 2 H COCH.sub.3 H CH.sub.32.33 CH.sub.3 CH.sub.3 H 0 H COC.sub.2 H.sub.5 H CH.sub.32.34 CH.sub.3 CH.sub.3 H 2 H COC.sub.2 H.sub.5 H CH.sub.32.35 CH.sub.3 CH.sub.3 H 0 H COiPr H CH.sub.32.36 CH.sub.3 CH.sub.3 H 2 H COiPr H CH.sub.32.37 H H H 0 H COCH.sub.3 H Cl2.38 H H H 2 H COCH.sub.3 H Cl2.39 H H H 0 H COC.sub.2 H.sub.5 H Cl2.40 H H H 2 H COC.sub.2 H.sub.5 H Cl2.41 H H H 0 H COiPr H Cl2.42 H H H 2 H COiPr H Cl2.43 CH.sub.3 H H 0 H COCH.sub.3 H Cl2.44 CH.sub.3 H H 2 H COCH.sub.3 H Cl2.45 CH.sub.3 H H 0 H COC.sub.2 H.sub.5 H Cl2.46 CH.sub.3 H H 2 H COC.sub.2 H.sub.5 H Cl2.47 CH.sub.3 H H 0 H COiPr H Cl2.48 CH.sub.3 H H 2 H COiPr H Cl2.49 CH.sub.3 CH.sub.3 H 0 H COCH.sub.3 H Cl2.50 CH.sub.3 CH.sub.3 H 2 H COCH.sub.3 H Cl2.51 CH.sub.3 CH.sub.3 H 0 H COC.sub.2 H.sub.5 H Cl2.52 CH.sub.3 CH.sub.3 H 2 H COC.sub.2 H.sub.5 H Cl2.53 CH.sub.3 CH.sub.3 H 0 H COiPr H Cl2.54 CH.sub.3 CH.sub.3 H 2 H COiPr H Cl______________________________________
TABLE 3__________________________________________________________________________Compounds of the formula ##STR16##No. R.sup.17 R.sup.18 R.sup.19 n R.sup.12 R.sup.13 Y L M__________________________________________________________________________3.1 H H H 0 H H C.dbd.O CH.sub.3 H3.2 H H H 2 H H C.dbd.O CH.sub.3 H3.3 H H H 0 H H CHOCH.sub.3 CH.sub.3 H3.4 H H H 2 H H CHOCH.sub.3 CH.sub.3 H3.5 H H H 0 H H CHOC.sub.2 H.sub.5 CH.sub.3 H3.6 H H H 2 H H CHOC.sub.2 H.sub.5 CH.sub.3 H3.7 H H H 0 H H CHOiPr CH.sub.3 H3.8 H H H 2 H H CHOiPr CH.sub.3 H3.9 H H H 0 H H C.dbd.NOCH.sub.3 CH.sub.3 H3.10 H H H 2 H H C.dbd.NOCH.sub.3 CH.sub.3 H3.11 H H H 0 H H C.dbd.NOC.sub.2 H.sub.5 CH.sub.3 H3.12 H H H 2 H H C.dbd.NOC.sub.2 H.sub.5 CH.sub.3 H3.13 H H H D H H C.dbd.NOiPr CH.sub.3 H3.14 H H H 2 H H C.dbd.NOiPr CH.sub.3 H3.15 H H H 0 H H C.dbd.NOCH.sub.2 CH.dbd.CHCl CH.sub.3 H3.16 H H H 2 H H C.dbd.NOCH.sub.2 CH.dbd.CHCl CH.sub.3 H3.17 H H H 0 H H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 CH.sub.3 H3.18 H H H 2 H H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 CH.sub.3 H3.19 H H H 0 H H C(CH.sub.3).sub.2 CH.sub.3 H3.20 H H H 2 H H C(CH.sub.3).sub.2 CH.sub.3 H3.21 CH.sub.3 H H 0 H H C.dbd.O CH.sub.3 H3.22 CH.sub.3 H H 2 H H C.dbd.O CH.sub.3 H3.23 CH.sub.3 H H 0 H H CHOCH.sub.3 CH.sub.3 H3.24 CH.sub.3 H H 2 H H CHOCH.sub.3 CH.sub.3 H3.25 CH.sub.3 H H 0 H H CHOC.sub.2 H.sub.5 CH.sub.3 H3.26 CH.sub.3 H H 2 H H CHOC.sub.2 H.sub.5 CH.sub.3 H3.27 CH.sub.3 H H 0 H H CHOiPr CH.sub.3 H3.28 CH.sub.3 H H 2 H H CHOiPr CH.sub.3 H3.29 CH.sub.3 H H 0 H H C.dbd.NOCH.sub.3 CH.sub.3 H3.30 CH.sub.3 H H 2 H H C.dbd.NOCH.sub.3 CH.sub.3 H3.31 CH.sub.3 H H 0 H H C.dbd.NOC.sub.2 H.sub.5 CH.sub.3 H3.32 CH.sub.3 H H 2 H H C.dbd.NOC.sub.2 H.sub.5 CH.sub.3 H3.33 CH.sub.3 H H 0 H H C.dbd.NOiPr CH.sub.3 H3.34 CH.sub.3 H H 2 H H C.dbd.NOiPr CH.sub.3 H3.35 CH.sub.3 H H 0 H H C.dbd.NOCH.sub.2 CH.dbd.CHCl CH.sub.3 H3.36 CH.sub.3 H H 2 H H C.dbd.NOCH.sub.2 CH.dbd.CHCl CH.sub.3 H3.37 CH.sub.3 H H 0 H H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 CH.sub.3 H3.38 CH.sub.3 H H 2 H H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 CH.sub.3 H3.39 CH.sub.3 H H 0 H H C(CH.sub.3).sub.2 CH.sub.3 H3.40 CH.sub.3 H H 2 H H C(CH.sub.3).sub.2 CH.sub.3 H3.41 CH.sub.3 CH.sub.3 H 0 H H C.dbd.O CH.sub.3 H3.42 CH.sub.3 CH.sub.3 H 2 H H C.dbd.O CH.sub.3 H3.43 CH.sub.3 CH.sub.3 H 0 H H CHOCH.sub.3 CH.sub.3 H3.44 CH.sub.3 CH.sub.3 H 2 H H CHOCH.sub.3 CH.sub.3 H3.45 CH.sub.3 CH.sub.3 H 0 H H CHOC.sub.2 H.sub.5 CH.sub.3 H3.46 CH.sub.3 CH.sub.3 H 2 H H CHOC.sub.2 H.sub.5 CH.sub.3 H3.47 CH.sub.3 CH.sub.3 H 0 H H CHOiPr CH.sub.3 H3.48 CH.sub.3 CH.sub.3 H 2 H H CHOiPr CH.sub.3 H3.49 CH.sub.3 CH.sub.3 H 0 H H C.dbd.NOCH.sub.3 CH.sub.3 H3.50 CH.sub.3 CH.sub.3 H 2 H H C.dbd.NOCH.sub.3 CH.sub.3 H3.51 CH.sub.3 CH.sub.3 H 0 H H C.dbd.NOC.sub.2 H.sub.5 CH.sub.3 H3.52 CH.sub.3 CH.sub.3 H 2 H H C.dbd.NOC.sub.2 H.sub.5 CH.sub.3 H3.53 CH.sub.3 CH.sub.3 H 0 H H C.dbd.NOiPr CH.sub.3 H3.54 CH.sub.3 CH.sub.3 H 2 H H C.dbd.NOiPr CH.sub.3 H3.55 CH.sub.3 CH.sub.3 H 0 H H C.dbd.NOCH.sub.2 CH.dbd.CHCl CH.sub.3 H3.56 CH.sub.3 CH.sub.3 W 2 H H C.dbd.NOCH.sub.2 CH.dbd.CHCl CH.sub.3 H3.57 CH.sub.3 CH.sub.3 H 0 H H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 CH.sub.3 H3.58 CH.sub.3 CH.sub.3 H 2 H H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 CH.sub.3 H3.59 CH.sub.3 CH.sub.3 H 0 H H C(CH.sub.3).sub.2 CH.sub.3 H3.60 CH.sub.3 CH.sub.3 H 2 H H C(CH.sub.3).sub.2 CH.sub.3 H3.61 H H H 0 H H C.dbd.O Cl H3.62 H H H 2 H H C.dbd.O Cl H3.63 H H H 0 H H CHOCH.sub.3 Cl H3.64 H H H 2 H H CHOCH.sub.3 Cl H3.65 H H H 0 H H CHOC.sub.2 H.sub.5 Cl H3.66 H H H 2 H H CHOC.sub.2 H.sub.5 Cl H3.67 H H H 0 H H CHOiPr Cl H3.68 H H H 2 H H CHOiPr Cl H3.69 H H H 0 H H C.dbd.NOCH.sub.3 Cl H3.70 H H H 2 H H C.dbd.NOCH.sub.3 Cl H3.71 H H H 0 H H C.dbd.NOC.sub.2 H.sub.5 Cl H3.72 H H H 2 H H C.dbd.NOC.sub.2 H.sub.5 Cl H3.73 H H H 0 H H C.dbd.NOiPr Cl H3.74 H H H 2 H H C.dbd.NOiPr Cl H3.75 H H H 0 H H C.dbd.NOCH.sub.2 CH.dbd.CHCl Cl H3.76 H H H 2 H H C.dbd.NOCH.sub.2 CH.dbd.CHCl Cl H3 77 H H H 0 H H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 Cl H3.78 H H H 2 H H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 Cl H3.79 H H H 0 H H C(CH.sub.3).sub.2 Cl H3.80 H H H 2 H H C(CH.sub.3).sub.2 Cl H3.81 CH.sub.3 H H 0 H H C.dbd.O Cl H3.82 CH.sub.3 H H 2 H H C.dbd.O Cl H3.83 CH.sub.3 H H 0 H H CHOCH.sub.3 Cl H3.84 CH.sub.3 H H 2 H H CHOCH.sub.3 Cl H3.85 CH.sub.3 H H 0 H H CHOC.sub.2 H.sub.5 Cl H3.86 CH.sub.3 H H 2 H H CHOC.sub.2 H.sub.5 Cl H3.87 CH.sub.3 H H 0 H H CHOiPr Cl H3.88 CH.sub.3 H H 2 H H CHOiPr Cl H3.89 CH.sub.3 H H 0 H H C.dbd.NOCH.sub.3 Cl H3.90 CH.sub.3 H H 2 H H C.dbd.NOCH.sub.3 Cl H3.91 CH.sub.3 H H 0 H H C.dbd.NOC.sub.2 H.sub.5 Cl H3.92 CH.sub.3 H H 2 H H C.dbd.NOC.sub.2 H.sub.5 Cl H3.93 CH.sub.3 H H 0 H H C.dbd.NOiPr Cl H3.94 CH.sub.3 H H 2 H H C.dbd.NOiPr Cl H3.95 CH.sub.3 H H 0 H H C.dbd.NOCH.sub.2 CH.dbd.CHCl Cl H3.96 CH.sub.3 H H 2 H H C.dbd.NOCH.sub.2 CH.dbd.CHCl Cl H3.97 CH.sub.3 H H 0 H H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 Cl H3.98 CH.sub.3 H H 2 H H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 Cl H3.99 CH.sub.3 H H 0 H H C(CH.sub.3).sub.2 Cl H3.100 CH.sub.3 H H 2 H H C(CH.sub.3).sub.2 Cl H3.101 CH.sub.3 CH.sub.3 H 0 H H C.dbd.O Cl H3.102 CH.sub.3 CH.sub.3 H 2 H H C.dbd.O Cl H3.103 CH.sub.3 CH.sub.3 H 0 H H CHOCH.sub.3 Cl H3.104 CH.sub.3 CH.sub.3 H 2 H H CHOCH.sub.3 Cl H3.105 CH.sub.3 CH.sub.3 H 0 H H CHOC.sub.2 H.sub.5 Cl H3.106 CH.sub.3 CH.sub.3 H 2 H H CHOC.sub.2 H.sub.5 Cl H3.107 CH.sub.3 CH.sub.3 H 0 H H CHOiPr Cl H3.108 CH.sub.3 CH.sub.3 H 2 H H CHOiPr Cl H3.109 CH.sub.3 CH.sub.3 H 0 H H C.dbd.N--OCH.sub.3 Cl H3.110 CH.sub.3 CH.sub.3 H 2 H H C.dbd.NOCH.sub.3 Cl H3.111 CH.sub.3 CH.sub.3 H 0 H H C.dbd.NOC.sub.2 H.sub.5 Cl H3.112 CH.sub.3 CH.sub.3 H 2 H H C.dbd.NOC.sub.2 H.sub.5 Cl H3.113 CH.sub.3 CH.sub.3 H 0 H H C.dbd.NOiPr Cl H3.114 CH.sub.3 CH.sub.3 H 2 H H C.dbd.NOiPr Cl H3.115 CH.sub.3 CH.sub.3 H 0 H H C.dbd.NOCH.sub.2 CH.dbd.CHCl Cl H3.116 CH.sub.3 CH.sub.3 H 2 H H C.dbd.NOCH.sub.2 CH.dbd.CHCl Cl H3.117 CH.sub.3 CH.sub.3 H 0 H H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 Cl H3.118 CH.sub.3 CH.sub.3 H 2 H H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 Cl H3.119 CH.sub.3 CH.sub.3 H 0 H H C(CH.sub.3).sub.2 Cl H3.120 CH.sub.3 CH.sub.3 H 2 H H C(CH.sub.3).sub.2 Cl H3.121 H H H 0 H CH.sub.3 C.dbd.O CH.sub.3 H3.122 H H H 2 H CH.sub.3 C.dbd.O CH.sub.3 H3.123 H H H 0 H CH.sub.3 CHOCH.sub.3 CH.sub.3 H3.124 H H H 2 H CH.sub.3 CHOCH.sub.3 CH.sub.3 H3.125 H H H 0 H CH.sub.3 CHOC.sub.2 H.sub.5 CH.sub.3 H3.126 H H H 2 H CH.sub.3 CHOC.sub.2 H.sub.5 CH.sub.3 H3.127 H H H 0 H CH.sub.3 CHOiPr CH.sub.3 H3.128 H H H 2 H CH.sub.3 CHOiPr CH.sub.3 H3.129 H H H 0 H CH.sub.3 C.dbd.NOCH.sub.3 CH.sub.3 H3.130 H H H 2 H CH.sub.3 C.dbd.NOCH.sub.3 CH.sub.3 H3.131 H H H 0 H CH.sub.3 C.dbd.NOC.sub.2 H.sub.5 CH.sub.3 H3.132 H H H 2 H CH.sub.3 C.dbd.NOC.sub.2 H.sub.5 CH.sub.3 H3.133 H H H 0 H CH.sub.3 C.dbd.NOiPr CH.sub.3 H3.134 H H H 2 H CH.sub.3 C.dbd.NOiPr CH.sub.3 H3.135 H H H 0 H CH.sub.3 C.dbd.NOCH.sub.2 CH.dbd.CHCl CH.sub.3 H3.136 H H H 2 H CH.sub.3 C.dbd.NOCH.sub.2 CH.dbd.CHCl CH.sub.3 H3.137 H H H 0 H CH.sub.3 C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 CH.sub.3 H3.138 H H H 2 H CH.sub.3 C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 CH.sub.3 H3.139 H H H 0 H CH.sub.3 C(CH.sub.3).sub.2 CH.sub.3 H3.140 H H H 2 H CH.sub.3 C(CH.sub.3).sub.2 CH.sub.3 H3.141 CH.sub.3 H H 0 H CH.sub.3 C.dbd.O CH.sub.3 H3.142 CH.sub.3 H H 2 H CH.sub.3 C.dbd.O CH.sub.3 H3.143 CH.sub.3 H H 0 H CH.sub.3 CHOCH.sub.3 CH.sub.3 H3.144 CH.sub.3 H H 2 H CH.sub.3 CHOCH.sub.3 CH.sub.3 H3.145 CH.sub.3 H H 0 H CH.sub.3 CHOC.sub.2 H.sub.5 CH.sub.3 H3.146 CH.sub.3 H H 2 H CH.sub.3 CHOC.sub.2 H.sub.5 CH.sub.3 H3.147 CH.sub.3 H H 0 H CH.sub.3 CHOiPr CH.sub.3 H3.148 CH.sub.3 H H 2 H CH.sub.3 CHOiPr CH.sub.3 H3.149 CH.sub.3 H H 0 H CH.sub.3 C.dbd.NOCH.sub.3 CH.sub.3 H3.150 CH.sub.3 H H 2 H CH.sub.3 C.dbd.NOCH.sub.3 CH.sub.3 H3.151 CH.sub.3 H H 0 H CH.sub.3 C.dbd.NOC.sub.2 H.sub.5 CH.sub.3 H3.152 CH.sub.3 H H 2 H CH.sub.3 C.dbd.NOC.sub.2 H.sub.5 CH.sub.3 H3.153 CH.sub.3 H H 0 H CH.sub.3 C.dbd.NOiPr CH.sub.3 H3.154 CH.sub.3 H H 2 H CH.sub.3 C.dbd.NOiPr CH.sub.3 H3.155 CH.sub.3 H H 0 H CH.sub.3 C.dbd.NOCH.sub.2 CH.dbd.CHCl CH.sub.3 H3.156 CH.sub.3 H H 2 H CH.sub.3 C.dbd.NOCH.sub.2 CH.dbd.CHCl CH.sub.3 H3.157 CH.sub.3 H H 0 H CH.sub.3 C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 CH.sub.3 H3.158 CH.sub.3 H H 2 H CH.sub.3 C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 CH.sub.3 H3.159 CH.sub.3 H H 0 H CH.sub.3 C(CH.sub.3).sub.2 CH.sub.3 H3.160 CH.sub.3 H H 2 H CH.sub.3 C(CH.sub.3).sub.2 CH.sub.3 H3.161 CH.sub.3 CH.sub.3 H 0 H CH.sub.3 C.dbd.O CH.sub.3 H3.162 CH.sub.3 CH.sub.3 H 2 H CH.sub.3 C.dbd.O CH.sub.3 H3.163 CH.sub.3 CH.sub.3 H 0 H CH.sub.3 CHOCH.sub.3 CH.sub.3 H3.164 CH.sub.3 CH.sub.3 H 2 H CH.sub.3 CHOCH.sub.3 CH.sub.3 H3.165 CH.sub.3 CH.sub.3 H 0 H CH.sub.3 CHOC.sub.2 H.sub.5 CH.sub.3 H3.166 CH.sub.3 CH.sub.3 H 2 H CH.sub.3 CHOC.sub.2 H.sub.5 CH.sub.3 H3.167 CH.sub.3 CH.sub.3 H 0 H CH.sub.3 CHOiPr CH.sub.3 H3.168 CH.sub.3 CH.sub.3 H 2 H CH.sub.3 CHOiPr CH.sub.3 H3.169 CH.sub.3 CH.sub.3 H 0 H CH.sub.3 C.dbd.NOCH.sub.3 CH.sub.3 H3.170 CH.sub.3 CH.sub.3 H 2 H CH.sub.3 C.dbd.NOCH.sub.3 CH.sub.3 H3.171 CH.sub.3 CH.sub.3 H 0 H CH.sub.3 C.dbd.NOC.sub.2 H.sub.5 CH.sub.3 H3.172 CH.sub.3 CH.sub.3 H 2 H CH.sub.3 C.dbd.NOC.sub.2 H.sub.5 CH.sub.3 H3.173 CH.sub.3 CH.sub.3 H 0 H CH.sub.3 C.dbd.NOiPr CH.sub.3 H3.174 CH.sub.3 CH.sub.3 H 2 H CH.sub.3 C.dbd.NOiPr CH.sub.3 H3.175 CH.sub.3 CH.sub.3 H 0 H CH.sub.3 C.dbd.NOCH.sub.2 CH.dbd.CHCl CH.sub.3 H3.176 CH.sub.3 CH.sub.3 H 2 H CH.sub.3 C.dbd.NOCH.sub.2 CH.dbd.CHCl CH.sub.3 H3.177 CH.sub.3 CH.sub.3 H 0 H CH.sub.3 C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 CH.sub.3 H3.178 CH.sub.3 CH.sub.3 H 2 H CH.sub.3 C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 CH.sub.3 H3.179 CH.sub.3 CH.sub.3 H 0 H CH.sub.3 C(CH.sub.3).sub.2 CH.sub.3 H3.180 CH.sub.3 CH.sub.3 H 2 H CH.sub.3 C(CH.sub.3).sub.2 CH.sub.3 H3.181 H H H 0 H CH.sub.3 C.dbd.O Cl H3.182 H H H 2 H CH.sub.3 C.dbd.O Cl H3.183 H H H 0 H CH.sub.3 CHOCH.sub.3 Cl H3.184 H H H 2 H CH.sub.3 CHOCH.sub.3 Cl H3.185 H H H 0 H CH.sub.3 CHOC.sub.2 H.sub.5 Cl H3.186 H H H 2 H CH.sub.3 CHOC.sub.2 H.sub.5 Cl H3.187 H H H 0 H CH.sub.3 CHOiPr Cl H3.188 H H H 2 H CH.sub.3 CHOiPr Cl H3.189 H H H 0 H CH.sub.3 C.dbd.NOCH.sub.3 Cl H3.190 H H H 2 H CH.sub.3 C.dbd.NOCH.sub.3 Cl H3.191 H H H 0 H CH.sub.3 C.dbd.NOC.sub.2 H.sub.5 Cl H3.192 H H H 2 H CH.sub.3 C.dbd.NOC.sub.2 H.sub.5 Cl H3.193 H H H 0 H CH.sub.3 C.dbd.NOiPr Cl H3.194 H H H 2 H CH.sub.3 C.dbd.NOiPr Cl H3.195 H H H 0 H CH.sub.3 C.dbd.NOCH.sub.2 CH.dbd.CHCl Cl H3.196 H H H 2 H CH.sub.3 C.dbd.NOCH.sub.2 CH.dbd.CHCl Cl H3.197 H H H 0 H CH.sub.3 C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 Cl H3.198 H H H 2 H CH.sub.3 C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 Cl H3.199 H H H 0 H CH.sub.3 C(CH.sub.3).sub.2 Cl H3.200 H H H 2 H CH.sub.3 C(CH.sub.3).sub.2 Cl H3.201 CH.sub.3 H H 0 H CH.sub.3 C.dbd.O Cl H3.202 CH.sub.3 H H 2 H CH.sub.3 C.dbd.O Cl H3.203 CH.sub.3 H H 0 H CH.sub.3 CHOCH.sub.3 Cl H3.204 CH.sub.3 H H 2 H CH.sub.3 CHOCH.sub.3 Cl H3.205 CH.sub.3 H H 0 H CH.sub.3 CHOC.sub.2 H.sub.5 Cl H3.206 CH.sub.3 H H 2 H CH.sub.3 CHOC.sub.2 H.sub.5 Cl H3.207 CH.sub.3 H H 0 H CH.sub.3 CHOiPr Cl H3.208 CH.sub.3 H H 2 H CH.sub.3 CHOiPr Cl H3.209 CH.sub.3 H H 0 H CH.sub.3 C.dbd.NOCH.sub.3 Cl H3.210 CH.sub.3 H H 2 H CH.sub.3 C.dbd.NOCH.sub.3 Cl H3.211 CH.sub.3 H H 0 H CH.sub.3 C.dbd.NOC.sub.2 H.sub.5 Cl H3.212 CH.sub.3 H H 2 H CH.sub.3 C.dbd.NOC.sub.2 H.sub.5 Cl H3.213 CH.sub.3 H H 0 H CH.sub.3 C.dbd.NOiPr Cl H3.214 CH.sub.3 H H 2 H CH.sub.3 C.dbd.NOiPr Cl H3.215 CH.sub.3 H H 0 H CH.sub.3 C.dbd.NOCH.sub.2 CH.dbd.CHCl Cl H3.216 CH.sub.3 H H 2 H CH.sub.3 C.dbd.NOCH.sub.2 CH.dbd.CHCl Cl H3.217 CH.sub.3 H H 0 H CH.sub.3 C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 Cl H3.218 CH.sub.3 H H 2 H CH.sub.3 C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 Cl H3.219 CH.sub.3 H H 0 H CH.sub.3 C(CH.sub.3).sub.2 Cl H3.220 CH.sub.3 H H 2 H CH.sub.3 C(CH.sub.3).sub.2 Cl H3.221 CH.sub.3 CH.sub.3 H 0 H CH.sub.3 C.dbd.O Cl H3.222 CH.sub.3 CH.sub.3 H 2 H CH.sub.3 C.dbd.O Cl H3.223 CH.sub.3 CH.sub.3 H 0 H CH.sub.3 CHOCH.sub.3 Cl H3.224 CH.sub.3 CH.sub.3 H 2 H CH.sub.3 CHOCH.sub.3 Cl H3.225 CH.sub.3 CH.sub.3 H 0 H CH.sub.3 CHOC.sub.2 H.sub.5 Cl H3.226 CH.sub.3 CH.sub.3 H 2 H CH.sub.3 CHOC.sub.2 H.sub.5 Cl H3.227 CH.sub.3 CH.sub.3 H 0 H CH.sub.3 CHOiPr Cl H3.228 CH.sub.3 CH.sub.3 H 2 H CH.sub.3 CHOiPr Cl H3.229 CH.sub.3 CH.sub.3 H 0 H CH.sub.3 C.dbd.NOCH.sub.3 Cl H3.230 CH.sub.3 CH.sub.3 H 2 H CH.sub.3 C.dbd.NOCH.sub.3 Cl H3.231 CH.sub.3 CH.sub.3 H 0 H CH.sub.3 C.dbd.NOC.sub.2 H.sub.5 Cl H3.232 CH.sub.3 CH.sub.3 H 2 H CH.sub.3 C.dbd.NOC.sub.2 H.sub.5 Cl H3.233 CH.sub.3 CH.sub.3 H 0 H CH.sub.3 C.dbd.NOiPr Cl H3.234 CH.sub.3 CH.sub.3 H 2 H CH.sub.3 C.dbd.NOiPr Cl H3.235 CH.sub.3 CH.sub.3 H 0 H CH.sub.3 C.dbd.NOCH.sub.2 CH.dbd.CHCl Cl H3.236 CH.sub.3 CH.sub.3 H 2 H CH.sub.3 C.dbd.NOCH.sub.2 CH.dbd.CHCl Cl H3.237 CH.sub.3 CH.sub.3 H 0 H CH.sub.3 C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 Cl H3.238 CH.sub.3 CH.sub.3 H 2 H CH.sub.3 C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 Cl H3.239 CH.sub.3 CH.sub.3 H 0 H CH.sub.3 (CH.sub.3).sub.2 Cl H3.240 CH.sub.3 CH.sub.3 H 2 H CH.sub.3 C(CH.sub.3).sub.2 Cl H3.241 H H H 0 H CH.sub.3 C.dbd.O CH.sub.3 CH.sub.33.242 H H H 2 H CH.sub.3 C.dbd.O CH.sub.3 CH.sub.33.243 H H H 0 H CH.sub.3 CHOCH.sub.3 CH.sub.3 CH.sub.33.244 H H H 2 H CH.sub.3 CHOCH.sub.3 CH.sub.3 CH.sub.33.245 H H H 0 H CH.sub.3 CHOC.sub.2 H.sub.5 CH.sub.3 CH.sub.33.246 H H H 2 H CH.sub.3 CHOC.sub.2 H.sub.5 CH.sub.3 CH.sub.33.247 H H H 0 H CH.sub.3 CHOiPr CH.sub.3 CH.sub.33.248 H H H 2 H CH.sub.3 CHOiPr CH.sub.3 CH.sub.33.249 H H H 0 H CH.sub.3 COCH.sub.3 CH.sub.3 CH.sub.33.250 H H H 2 H CH.sub.3 COCH.sub.3 CH.sub.3 CH.sub.33.251 H H H 0 H CH.sub.3 COC.sub.2 H.sub.5 CH.sub.3 CH.sub.33.252 H H H 2 H CH.sub.3 COC.sub.2 H.sub.5 CH.sub.3 CH.sub.33.253 H H H 0 H CH.sub.3 C.dbd.NOCH.sub.3 CH.sub.3 CH.sub.33.254 H H H 2 H CH.sub.3 C.dbd.NOCH.sub.3 CH.sub.3 CH.sub.33.255 H H H 0 H CH.sub.3 C.dbd.NOC.sub.2 H.sub.5 CH.sub.3 CH.sub.33.256 H H H 2 H CH.sub.3 C.dbd.NOC.sub.2 H.sub.5 CH.sub.3 CH.sub.33.257 H H H 0 H CH.sub.3 C.dbd.NOiPr CH.sub.3 CH.sub.33.258 H H H 2 H CH.sub.3 C.dbd.NOiPr CH.sub.3 CH.sub.33.259 H H H 0 H CH.sub.3 C.dbd.NOCH.sub.2 CH.dbd.CHCl CH.sub.3 CH.sub.33.260 H H H 2 H CH.sub.3 C.dbd.NOCH.sub.2 CH.dbd.CHCl CH.sub.3 CH.sub.33.261 H H H 0 H CH.sub.3 C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 CH.sub.3 CH.sub.33.262 H H H 2 H CH.sub.3 C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 CH.sub.3 CH.sub.33.263 H H H 0 H CH.sub.3 C(CH.sub.3).sub.2 CH.sub.3 CH.sub.33.264 H H H 2 H CH.sub.3 C(CH.sub.3).sub.2 CH.sub.3 CH.sub.33.265 CH.sub.3 H H 0 H CH.sub.3 C.dbd.O CH.sub.3 CH.sub.33.266 CH.sub.3 H H 2 H CH.sub.3 C.dbd.O CH.sub.3 CH.sub.33.267 CH.sub.3 H H 0 H CH.sub.3 CHOCH.sub.3 CH.sub.3 CH.sub.33.268 CH.sub.3 H H 2 H CH.sub.3 CHOCH.sub.3 CH.sub.3 CH.sub.33.269 CH.sub.3 H H 0 H CH.sub.3 CHOC.sub.2 H.sub.5 CH.sub.3 CH.sub.33.270 CH.sub.3 H H 2 H CH.sub.3 CHOC.sub.2 H.sub.5 CH.sub.3 CH.sub.33.271 CH.sub.3 H H 0 H CH.sub.3 CHOiPr CH.sub.3 CH.sub.33.272 CH.sub.3 H H 2 H CH.sub.3 CHOiPr CH.sub.3 CH.sub.33.273 CH.sub.3 H H 0 H CH.sub.3 C.dbd.NOCH.sub.3 CH.sub.3 CH.sub.33.274 CH.sub.3 H H 2 H CH.sub.3 C.dbd.NOCH.sub.3 CH.sub.3 CH.sub.33.275 CH.sub.3 H H 0 H CH.sub.3 C.dbd.NOC.sub.2 H.sub.5 CH.sub.3 CH.sub.33.276 CH.sub.3 H H 2 H CH.sub.3 C.dbd.NOC.sub.2 H.sub.5 CH.sub.3 CH.sub.33.277 CH.sub.3 H H 0 H CH.sub.3 C.dbd.NOiPr CH.sub.3 CH.sub.33.278 CH.sub.3 H H 2 H CH.sub.3 C.dbd.NOiPr CH.sub.3 CH.sub.33.279 CH.sub.3 H H 0 H CH.sub.3 C.dbd.NOCH.sub.2 CH.dbd.CHCl CH.sub.3 CH.sub.33.280 CH.sub.3 H H 2 H CH.sub.3 C.dbd.NOCH.sub.2 CH.dbd.CHCl CH.sub.3 CH.sub.33.281 CH.sub.3 H H 0 H CH.sub.3 C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 CH.sub.3 CH.sub.33.282 CH.sub.3 H H 2 H CH.sub.3 C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 CH.sub.3 CH.sub.33.283 CH.sub.3 H H 0 H CH.sub.3 C(CH.sub.3).sub.2 CH.sub.3 CH.sub.33.284 CH.sub.3 H H 2 H CH.sub.3 C(CH.sub.3).sub.2 CH.sub.3 CH.sub.33.285 CH.sub.3 CH.sub.3 H 0 H CH.sub.3 C.dbd.O CH.sub.3 CH.sub.33.286 CH.sub.3 CH.sub.3 H 2 H CH.sub.3 C.dbd.O CH.sub.3 CH.sub.33.287 CH.sub.3 CH.sub.3 H 0 H CH.sub.3 CHOCH.sub.3 CH.sub.3 CH.sub.33.288 CH.sub.3 CH.sub.3 H 2 H CH.sub.3 CHOCH.sub.3 CH.sub.3 CH.sub.33.289 CH.sub.3 CH.sub.3 H 0 H CH.sub.3 CHOC.sub.2 H.sub.5 CH.sub.3 CH.sub.33.290 CH.sub.3 CH.sub.3 H 2 H CH.sub.3 CHOC.sub.2 H.sub.5 CH.sub.3 CH.sub.33.291 CH.sub.3 CH.sub.3 H 0 H CH.sub.3 CHOiPr CH.sub.3 CH.sub.33.292 CH.sub.3 CH.sub.3 H 2 H CH.sub.3 CHOiPr CH.sub.3 CH.sub.33.293 CH.sub.3 CH.sub.3 H 0 H CH.sub.3 C.dbd.NOCH.sub.3 CH.sub.3 CH.sub.33.294 CH.sub.3 CH.sub.3 H 2 H CH.sub.3 C.dbd.NOCH.sub.3 CH.sub.3 CH.sub.33.295 CH.sub.3 CH.sub.3 H 0 H CH.sub.3 C.dbd.NOC.sub.2 H.sub.5 CH.sub.3 CH.sub.33.296 CH.sub.3 CH.sub.3 H 2 H CH.sub.3 C.dbd.NOC.sub.2 H.sub.5 CH.sub.3 CH.sub.33.297 CH.sub.3 CH.sub.3 H 0 H CH.sub.3 C.dbd.NOiPr CH.sub.3 CH.sub.33.298 CH.sub.3 CH.sub.3 H 2 H CH.sub.3 C.dbd.NOiPr CH.sub.3 CH.sub.33.299 CH.sub.3 CH.sub.3 H 0 H CH.sub.3 C.dbd.NOCH.sub.2 CH.dbd.CHCl CH.sub.3 CH.sub.33.300 CH.sub.3 CH.sub.3 H 2 H CH.sub.3 C.dbd.NOCH.sub.2 CH.dbd.CHCl CH.sub.3 CH.sub.33.301 CH.sub.3 CH.sub.3 H 0 H CH.sub.3 C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 CH.sub.3 CH.sub.33.302 CH.sub.3 CH.sub.3 H 2 H CH.sub.3 C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 CH.sub.3 CH.sub.33.303 CH.sub.3 CH.sub.3 H 0 H CH.sub.3 C(CH.sub.3).sub.2 CH.sub.3 CH.sub.33.304 CH.sub.3 CH.sub.3 H 2 H CH.sub.3 C(CH.sub.3).sub.2 CH.sub.3 CH.sub.3__________________________________________________________________________
TABLE 4__________________________________________________________________________Compounds of the formula ##STR17##No. R.sup.17 R.sup.18 R.sup.19 n R.sup.12 R.sup.13 R.sup.21 R.sup.22 Y L M__________________________________________________________________________4.1 H H H 0 H H H H C.dbd.O H H4.2 H H H 1 H H H H C.dbd.O H H4.3 H H H 2 H H H H C.dbd.O H H4.4 H H H 0 H H H H CHOH H H4.5 H H H 1 H H H H CHOH H H4.6 H H H 2 H H H H CHOH H H4.7 H H H 0 H H H H CHOCH.sub.3 H H4.8 H H H 1 H H H H CHOCH.sub.3 H H4.9 H H H 2 H H H H CHOCH.sub.3 H H4.10 H H H 0 H H H H CHOC.sub.2 H.sub.5 H H4.11 H H H 1 H H H H CHOC.sub.2 H.sub.5 H H4.12 H H H 2 H H H H CHOC.sub.2 H.sub.5 H H4.13 H H H 0 H H H H CHOiPr H H4.14 H H H 1 H H H H CHOiPr H H4.15 H H H 2 H H H H CHOiPr H H4.16 H H H 0 H H H H C.dbd.NOCH.sub.3 H H4.17 H H H 1 H H H H C.dbd.NOCH.sub.3 H H4.18 H H H 2 H H H H C.dbd.NOCH.sub.3 H H4.19 H H H 0 H H H H C.dbd.NOC.sub.2 H.sub.5 H H4.20 H H H 1 H H H H C.dbd.NOC.sub.2 H.sub.5 H H4.21 H H H 2 H H H H C.dbd.NOC.sub.2 H.sub.5 H H4.22 H H H 0 H H H H C.dbd.NOiPr H H4.23 H H H 1 H H H H C.dbd.NOiPr H H4.24 H H H 2 H H H H C.dbd.NOiPr H H4.25 H H H 0 H H H H C.dbd.NOCH.sub.2 CH.dbd.CHCl H H4.26 H H H 1 H H H H C.dbd.NOCH.sub.2 CH.dbd.CHCl H H4.27 H H H 2 H H H H C.dbd.NOCH.sub.2 CH.dbd.CHCl H H4.28 H H H 0 H H H H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 H H4.29 H H H 1 H H H H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 H H4.30 H H H 2 H H H H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 H H4.31 H H H 0 H H H H C(CH.sub.3).sub.2 H H4.32 H H H 1 H H H H C(CH.sub.3).sub.2 H H4.33 H H H 2 H H H H C(CH.sub.3).sub.2 H H4.34 H H H 0 H H H H ##STR18## H H4.35 H H H 1 H H H H ##STR19## H H4.36 H H H 2 H H H H ##STR20## H H4.37 H H H 0 H H H H ##STR21## H H4.38 H H H 1 H H H H ##STR22## H H4.39 H H H 2 H H H H ##STR23## H H4.40 H H H 0 H H H H C.dbd.N--CH.sub.3 H H4.41 H H H 1 H H H H C.dbd.N--CH.sub.3 H H4.42 H H H 2 H H H H C.dbd.N--CH.sub.3 H H4.43 H H H 0 H H H H C.dbd.NC.sub.2 H.sub.5 H H4.44 H H H 1 H H H H C.dbd.NC.sub.2 H.sub.5 H H4.45 H H H 2 H H H H C.dbd.NC.sub.2 H.sub.5 H H4.46 H H H 0 H H H H CH--NHCH.sub.3 H H4.47 H H H 1 H H H H CH--NHCH.sub.3 H H4.48 H H H 2 H H H H CH--NHCH.sub.3 H H4.49 H H H 0 H H H H CH--NHC.sub.2 H.sub.5 H H4.50 H H H 1 H H H H CH--NHC.sub.2 H.sub.5 H H4.51 H H H 2 H H H H CH--NHC.sub.2 H.sub.5 H H4.52 H H H 0 H H H H CH--N(CH.sub.3).sub.2 H H4.53 H H H 1 H H H H CH--N(CH.sub.3).sub.2 H H4.54 H H H 2 H H H H CH--N(CH.sub.3).sub.2 H H4.55 H H H 0 H H H H CH--NHOC.sub.2 H.sub.5 H H4.56 H H H 1 H H H H CH--NHOC.sub.2 H.sub.5 H H4.57 H H H 2 H H H H CH--NHOC.sub.2 H.sub.5 H H4.58 H H H 0 H H H H CH--N(CH.sub.3)OC.sub.2 H.sub.5 H H4.59 H H H 1 H H H H CH--N(CH.sub.3)OC.sub.2 H.sub.5 H H4.60 H H H 2 H H H H CH--N(CH.sub.3)OC.sub.2 H.sub.5 H H4.61 H H H 0 H H H H C.dbd.N--NH.sub.2 H H4.62 H H H 1 H H H H C.dbd.N--NH.sub.2 H H4.63 H H H 2 H H H H C.dbd.N--NH.sub.2 H H4.64 H H H 0 H H H H C.dbd.N--N(CH.sub.3).sub.2 H H4.65 H H H 1 H H H H C.dbd.N--N(CH.sub.3).sub.2 H H4.66 H H H 2 H H H H C.dbd.N--N(CH.sub.3).sub.2 H H4.67 H H H 0 H H H H CH--N(CH.sub.3)OCH.sub.2 C.sub.6 H.sub.5 H H4.68 H H H 1 H H H H CH--N(CH.sub.3)OCH.sub.2 C.sub.6 H.sub.5 H H4.69 H H H 2 H H H H CH--N(CH.sub.3)OCH.sub.2 C.sub.6 H.sub.5 H H4.70 H H H 0 H H H H C(CH.sub.3)--OCH.sub.3 H H4.71 H H H 1 H H H H C(CH.sub.3)--OCH.sub.3 H H4.72 H H H 2 H H H H C(CH.sub.3)--OCH.sub.3 H H4.73 H H H 0 H H H H O H H4.74 H H H 1 H H H H O H H4.75 H H H 2 H H H H O H H4.76 CH.sub.3 H H 0 H H H H C.dbd.O H H4.77 CH.sub.3 H H 1 H H H H C.dbd.O H H4.78 CH.sub.3 H H 2 H H H H C.dbd.O H H4.79 CH.sub.3 H H 0 H H H H CHOH H H4.80 CH.sub.3 H H 1 H H H H CHOH H H4.81 CH.sub.3 H H 2 H H H H CHOH H H4.82 CH.sub.3 H H 0 H H H H CHOCH.sub.3 H H4.83 CH.sub.3 H H 1 H H H H CHOCH.sub.3 H H4.84 CH.sub.3 H H 2 H H H H CHOCH.sub.3 H H4.85 CH.sub.3 H H 0 H H H H CHOC.sub.2 H.sub.5 H H4.86 CH.sub.3 H H 1 H H H H CHOC.sub.2 H.sub.5 H H4.87 CH.sub.3 H H 2 H H H H CHOC.sub.2 H.sub.5 H H4.88 CH.sub.3 H H 0 H H H H CHOiPr H H4.89 CH.sub.3 H H 1 H H H H CHOiPr H H4.90 CH.sub.3 H H 2 H H H H CHOiPr H H4.91 CH.sub.3 H H 0 H H H H C.dbd.NOCH.sub.3 H H4.92 CH.sub.3 H H 1 H H H H C.dbd.NOCH.sub.3 H H4.93 CH.sub.3 H H 2 H H H H C.dbd.NOCH.sub.3 H H4.94 CH.sub.3 H H 0 H H H H C.dbd.NOC.sub.2 H.sub.5 H H4.95 CH.sub.3 H H 1 H H H H C.dbd.NOC.sub.2 H.sub.5 H H4.96 CH.sub.3 H H 2 H H H H C.dbd.NOC.sub.2 H.sub.5 H H4.97 CH.sub.3 H H 0 H H H H C.dbd.NOiPr H H4.98 CH.sub.3 H H 1 H H H H C.dbd.NOiPr H H4.99 CH.sub.3 H H 2 H H H H C.dbd.NOiPr H H4.100 CH.sub.3 H H 0 H H H H C.dbd.NOCH.sub.2 CH.dbd.CHCl H H4.101 CH.sub.3 H H 1 H H H H C.dbd.NOCH.sub.2 CH.dbd.CHCl H H4.102 CH.sub.3 H H 2 H H H H C.dbd.NOCH.sub.2 CH.dbd.CHCl H H4.103 CH.sub.3 H H 0 H H H H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 H H4.104 CH.sub.3 H H 1 H H H H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 H H4.105 CH.sub.3 H H 2 H H H H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 H H4.106 CH.sub.3 H H 0 H H H H C(CH.sub.3).sub.2 H H4.107 CH.sub.3 H H 1 H H H H C(CH.sub.3).sub.2 H H4.108 CH.sub.3 H H 2 H H H H C(CH.sub.3).sub.2 H H4.109 CH.sub.3 H H 0 H H H H ##STR24## H H4.110 CH.sub.3 H H 1 H H H H ##STR25## H H4.111 CH.sub.3 H H 2 H H H H ##STR26## H H4.112 CH.sub.3 H H 0 H H H H ##STR27## H H4.113 CH.sub.3 H H 1 H H H H ##STR28## H H4.114 CH.sub.3 H H 2 H H H H ##STR29## H H4.115 CH.sub.3 H H 0 H H H H C.dbd.N--CH.sub.3 H H4.116 CH.sub.3 H H 1 H H H H C.dbd.N--CH.sub.3 H H4.117 CH.sub.3 H H 2 H H H H C.dbd.N--CH.sub.3 H H4.118 CH.sub.3 H H 0 H H H H C.dbd.NC.sub.2 H.sub.5 H H4.119 CH.sub.3 H H 1 H H H H C.dbd.NC.sub.2 H.sub.5 H H4.120 CH.sub.3 H H 2 H H H H C.dbd.NC.sub.2 H.sub.5 H H4.121 CH.sub.3 H H 0 H H H H CH--NHCH.sub.3 H H4.122 CH.sub.3 H H 1 H H H H CH--NHCH.sub.3 H H4.123 CH.sub.3 H H 2 H H H H CH--NHCH.sub.3 H H4.124 CH.sub.3 H H 0 H H H H CH--NHC.sub.2 H.sub.5 H H4.125 CH.sub.3 H H 1 H H H H CH--NHC.sub.2 H.sub.5 H H4.126 CH.sub.3 H H 2 H H H H CH--NHC.sub.2 H.sub.5 H H4.127 CH.sub.3 H H 0 H H H H CH--N(CH.sub.3).sub.2 H H4.128 CH.sub.3 H H 1 H H H H CH--N(CH.sub.3).sub.2 H H4.129 CH.sub.3 H H 2 H H H H CH--N(CH.sub.3).sub.2 H H4.130 CH.sub.3 H H 0 H H H H CH--NHOC.sub.2 H.sub.5 H H4.131 CH.sub.3 H H 1 H H H H CH--NHOC.sub.2 H.sub.5 H H4.132 CH.sub.3 H H 2 H H H H CH--NHOC.sub.2 H.sub.5 H H4.133 CH.sub.3 H H 0 H H H H CH--N(CH.sub.3)OC.sub.2 H.sub.5 H H4.134 CH.sub.3 H H 1 H H H H CH--N(CH.sub.3)OC.sub.2 H.sub.5 H H4.135 CH.sub.3 H H 2 H H H H CH--N(CH.sub.3)OC.sub.2 H.sub.5 H H4.136 CH.sub.3 H H 0 H H H H C.dbd.N--NH.sub.2 H H4.137 CH.sub.3 H H 1 H H H H C.dbd.N--NH.sub.2 H H4.138 CH.sub.3 H H 2 H H H H C.dbd.N--NH.sub.2 H H4.139 CH.sub.3 H H 0 H H H H C.dbd.N--N(CH.sub.3).sub.2 H H4.140 CH.sub.3 H H 1 H H H H C.dbd.N--N(CH.sub.3).sub.2 H H4.141 CH.sub.3 H H 2 H H H H C.dbd.N--N(CH.sub.3).sub.2 H H4.142 CH.sub.3 H H 0 H H H H CH--N(CH.sub.3)OCH.sub.2 C.sub.6 H.sub.5 H H4.143 CH.sub.3 H H 1 H H H H CH--N(CH.sub.3)OCH.sub.2 C.sub.6 H.sub.5 H H4.144 CH.sub.3 H H 2 H H H H CH--N(CH.sub.3)OCH.sub.2 C.sub.6 H.sub.5 H H4.145 CH.sub.3 H H 0 H H H H C(CH.sub.3)--OCH.sub.3 H H4.146 CH.sub.3 H H 1 H H H H C(CH.sub.3)--OCH.sub.3 H H4.147 CH.sub.3 H H 2 H H H H C(CH.sub.3)--OCH.sub.3 H H4.148 CH.sub.3 H H 0 H H H H O H H4.149 CH.sub.3 H H 1 H H H H O H H4.150 CH.sub.3 H H 2 H H H H O H H4.151 CH.sub.3 CH.sub.3 H 0 H H H H C.dbd.O H H4.152 CH.sub.3 CH.sub.3 H 1 H H H H C.dbd.O H H4.153 CH.sub.3 CH.sub.3 H 2 H H H H C.dbd.O H H4.154 CH.sub.3 CH.sub.3 H 0 H H H H CHOH H H4.155 CH.sub.3 CH.sub.3 H 1 H H H H CHOH H H4.156 CH.sub.3 CH.sub.3 H 2 H H H H CHOH H H4.157 CH.sub.3 CH.sub.3 H 0 H H H H CHOCH.sub.3 H H4.158 CH.sub.3 CH.sub.3 H 1 H H H H CHOCH.sub.3 H H4.159 CH.sub.3 CH.sub.3 H 2 H H H H CHOCH.sub.3 H H4.160 CH.sub.3 CH.sub.3 H 0 H H H H CHOC.sub.2 H.sub.5 H H4.161 CH.sub.3 CH.sub.3 H 1 H H H H CHOC.sub.2 H.sub.5 H H4.162 CH.sub.3 CH.sub.3 H 2 H H H H CHOC.sub.2 H.sub.5 H H4.163 CH.sub.3 CH.sub.3 H 0 H H H H CHOiPr H H4.164 CH.sub.3 CH.sub.3 H 1 H H H H CHOiPr H H4.165 CH.sub.3 CH.sub.3 H 2 H H H H CHOiPr H H4.166 CH.sub.3 CH.sub.3 H 0 H H H H C.dbd.NOCH.sub.3 H H4.167 CH.sub.3 CH.sub.3 H 1 H H H H C.dbd.NOCH.sub.3 H H4.168 CH.sub.3 CH.sub.3 H 2 H H H H C.dbd.NOCH.sub.3 H H4.169 CH.sub.3 CH.sub.3 H 0 H H H H C.dbd.NOC.sub.2 H.sub.5 H H4.170 CH.sub.3 CH.sub.3 H 1 H H H H C.dbd.NOC.sub.2 H.sub.5 H H4.171 CH.sub.3 CH.sub.3 H 2 H H H H C.dbd.NOC.sub.2 H.sub.5 H H4.172 CH.sub.3 CH.sub.3 H 0 H H H H C.dbd.NOiPr H H4.173 CH.sub.3 CH.sub.3 H 1 H H H H C.dbd.NOiPr H H4.174 CH.sub.3 CH.sub.3 H 2 H H H H C.dbd.NOiPr H H4.175 CH.sub.3 CH.sub.3 H 0 H H H H C.dbd.NOCH.sub.2 CH.dbd.CHCl H H4.176 CH.sub.3 CH.sub.3 H 1 H H H H C.dbd.NOCH.sub.2 CH.dbd.CHCl H H4.177 CH.sub.3 CH.sub.3 H 2 H H H H C.dbd.NOCH.sub.2 CH.dbd.CHCl H H4.178 CH.sub.3 CH.sub.3 H 0 H H H H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 H H4.179 CH.sub.3 CH.sub.3 H 1 H H H H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 H H4.180 CH.sub.3 CH.sub.3 H 2 H H H H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 H H4.181 CH.sub.3 CH.sub.3 H 0 H H H H C(CH.sub.3).sub.2 H H4.182 CH.sub.3 CH.sub.3 H 1 H H H H C(CH.sub.3).sub.2 H H4.183 CH.sub.3 CH.sub.3 H 2 H H H H C(CH.sub.3).sub.2 H H4.184 CH.sub.3 CH.sub.3 H 0 H H H H ##STR30## H H4.185 CH.sub.3 CH.sub.3 H 1 H H H H ##STR31## H H4.186 CH.sub.3 CH.sub.3 H 2 H H H H ##STR32## H H4.187 CH.sub.3 CH.sub.3 H 0 H H H H ##STR33## H H4.188 CH.sub.3 CH.sub.3 H 1 H H H H ##STR34## H H4.189 CH.sub.3 CH.sub.3 H 2 H H H H ##STR35## H H4.190 CH.sub.3 CH.sub.3 H 0 H H H H C.dbd.N--CH.sub.3 H H4.191 CH.sub.3 CH.sub.3 H 1 H H H H C.dbd.N--CH.sub.3 H H4.192 CH.sub.3 CH.sub.3 H 2 H H H H C.dbd.N--CH.sub.3 H H4.193 CH.sub.3 CH.sub.3 H 0 H H H H C.dbd.NC.sub.2 H.sub.5 H H4.194 CH.sub.3 CH.sub.3 H 1 H H H H C.dbd.NC.sub.2 H.sub.5 H H4.195 CH.sub.3 CH.sub.3 H 2 H H H H C.dbd.NC.sub.2 H.sub.5 H H4.196 CH.sub.3 CH.sub.3 H 0 H H H H CH--NHCH.sub.3 H H4.197 CH.sub.3 CH.sub.3 H 1 H H H H CH--NHCH.sub.3 H H4.198 CH.sub.3 CH.sub.3 H 2 H H H H CH--NHCH.sub.3 H H4.199 CH.sub.3 CH.sub.3 H 0 H H H H CH--NHC.sub.2 H.sub.5 H H4.200 CH.sub.3 CH.sub.3 H 1 H H H H CH--NHC.sub.2 H.sub.5 H H4.201 CH.sub.3 CH.sub.3 H 2 H H H H CH--NHC.sub.2 H.sub.5 H H4.202 CH.sub.3 CH.sub.3 H 0 H H H H CH--N(CH.sub.3).sub.2 H H4.203 CH.sub.3 CH.sub.3 H 1 H H H H CH--N(CH.sub.3).sub.2 H H4.204 CH.sub.3 CH.sub.3 H 2 H H H H CH--N(CH.sub.3).sub.2 H H4.205 CH.sub.3 CH.sub.3 H 0 H H H H CH--NHOC.sub.2 H.sub.5 H H4.206 CH.sub.3 CH.sub.3 H 1 H H H H CH--NHOC.sub.2 H.sub.5 H H4.207 CH.sub.3 CH.sub.3 H 2 H H H H CH--NHOC.sub.2 H.sub.5 H H4.208 CH.sub.3 CH.sub.3 H 0 H H H H CH--N(CH.sub.3)OC.sub.2 H.sub.5 H H4.209 CH.sub.3 CH.sub.3 H 1 H H H H CH--N(CH.sub.3)OC.sub.2 H.sub.5 H H4.210 CH.sub.3 CH.sub.3 H 2 H H H H CH--N(CH.sub.3)OC.sub.2 H.sub.5 H H4.211 CH.sub.3 CH.sub.3 H 0 H H H H C.dbd.N--NH.sub.2 H H4.212 CH.sub.3 CH.sub.3 H 1 H H H H C.dbd.N--NH.sub.2 H H4.213 CH.sub.3 CH.sub.3 H 2 H H H H C.dbd.N--NH.sub.2 H H4.214 CH.sub.3 CH.sub.3 H 0 H H H H C.dbd.N--N(CH.sub.3).sub.2 H H4.215 CH.sub.3 CH.sub.3 H 1 H H H H C.dbd.N--N(CH.sub.3).sub.2 H H4.216 CH.sub.3 CH.sub.3 H 2 H H H H C.dbd.N--N(CH.sub.3).sub.2 H H4.217 CH.sub.3 CH.sub.3 H 0 H H H H CH--N(CH.sub.3)OCH.sub.2 C.sub.6 H.sub.5 H H4.218 CH.sub.3 CH.sub.3 H 1 H H H H CH--N(CH.sub.3)OCH.sub.2 C.sub.6 H.sub.5 H H4.219 CH.sub.3 CH.sub.3 H 2 H H H H CH--N(CH.sub.3)OCH.sub.2 C.sub.6 H.sub.5 H H4.220 CH.sub.3 CH.sub.3 H 0 H H H H C(CH.sub.3)--OCH.sub.3 H H4.221 CH.sub.3 CH.sub.3 H 1 H H H H C(CH.sub.3)--OCH.sub.3 H H4.222 CH.sub.3 CH.sub.3 H 2 H H H H C(CH.sub.3)--OCH.sub.3 H H4.223 CH.sub.3 CH.sub.3 H 0 H H H H O H H4.224 CH.sub.3 CH.sub.3 H 1 H H H H O H H4.225 CH.sub.3 CH.sub.3 H 2 H H H H O H H4.226 H H H 0 H H H H C.dbd.O H CH.sub.34.227 H H H 1 H H H H C.dbd.O H CH.sub.34.228 H H H 2 H H H H C.dbd.O H CH.sub.34.229 H H H 0 H H H H CHOH H CH.sub.34.230 H H H 1 H H H H CHOH H CH.sub.34.231 H H H 2 H H H H CHOH H CH.sub.34.232 H H H 0 H H H H CHOCH.sub.3 H CH.sub.34.233 H H H 1 H H H H CHOCH.sub.3 H CH.sub.34.234 H H H 2 H H H H CHOCH.sub.3 H CH.sub.34.235 H H H 0 H H H H CHOC.sub.2 H.sub.5 H CH.sub.34.236 H H H 1 H H H H CHOC.sub.2 H.sub.5 H CH.sub.34.237 H H H 2 H H H H CHOC.sub.2 H.sub.5 H CH.sub.34.238 H H H 0 H H H H CHOiPr H CH.sub.34.239 H H H 1 H H H H CHOiPr H CH.sub.34.240 H H H 2 H H H H CHOiPr H CH.sub.34.241 H H H 0 H H H H C.dbd.NOCH.sub.3 H CH.sub.34.242 H H H 1 H H H H C.dbd.NOCH.sub.3 H CH.sub.34.243 H H H 2 H H H H C.dbd.NOCH.sub.3 H CH.sub.34.244 H H H 0 H H H H C.dbd.NOC.sub.2 H.sub.5 H CH.sub.34.245 H H H 1 H H H H C.dbd.NOC.sub.2 H.sub.5 H CH.sub.34.246 H H H 2 H H H H C.dbd.NOC.sub.2 H.sub.5 H CH.sub.34.247 H H H 0 H H H H C.dbd.NOiPr H CH.sub.34.248 H H H 1 H H H H C.dbd.NOiPr H CH.sub.34.249 H H H 2 H H H H C.dbd.NOiPr H CH.sub.34.250 H H H 0 H H H H C.dbd.NOCH.sub.2 CH.dbd.CHCl H CH.sub.34.251 H H H 1 H H H H C.dbd.NOCH.sub.2 CH.dbd.CHCl H CH.sub.34.252 H H H 2 H H H H C.dbd.NOCH.sub.2 CH.dbd.CHCl H CH.sub.34.253 H H H 0 H H H H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 H CH.sub.34.254 H H H 1 H H H H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 H CH.sub.34.255 H H H 2 H H H H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 H CH.sub.34.256 H H H 0 H H H H C(CH.sub.3).sub.2 H CH.sub.34.257 H H H 1 H H H H C(CH.sub.3).sub.2 H CH.sub.34.258 H H H 2 H H H H C(CH.sub.3).sub.2 H CH.sub.34.259 H H H 0 H H H H ##STR36## H CH.sub.34.260 H H H 1 H H H H ##STR37## H CH.sub.34.261 H H H 2 H H H H ##STR38## H CH.sub.34.262 H H H 0 H H H H ##STR39## H CH.sub.34.263 H H H 1 H H H H ##STR40## H CH.sub.34.264 H H H 2 H H H H ##STR41## H CH.sub.34.265 H H H 0 H H H H C.dbd.N--CH.sub.3 H CH.sub.34.266 H H H 1 H H H H C.dbd.N--CH.sub.3 H CH.sub.34.267 H H H 2 H H H H C.dbd.N--CH.sub.3 H CH.sub.34.268 H H H 0 H H H H C.dbd.NC.sub.2 H.sub.5 H CH.sub.34.269 H H H 1 H H H H C.dbd.NC.sub.2 H.sub.5 H CH.sub.34.270 H H H 2 H H H H C.dbd.NC.sub.2 H.sub.5 H CH.sub.34.271 H H H 0 H H H H CH--NHCH.sub.3 H CH.sub.34.272 H H H 1 H H H H CH--NHCH.sub.3 H CH.sub.34.273 H H H 2 H H H H CH--NHCH.sub.3 H CH.sub.34.274 H H H 0 H H H H CH--NHC.sub.2 H.sub.5 H CH.sub.34.275 H H H 1 H H H H CH--NHC.sub.2 H.sub.5 H CH.sub.34.276 H H H 2 H H H H CH--NHC.sub.2 H.sub.5 H CH.sub.34.277 H H H 0 H H H H CH--N(CH.sub.3).sub.2 H CH.sub.34.278 H H H 1 H H H H CH--N(CH.sub.3).sub.2 H CH.sub.34.279 H H H 2 H H H H CH--N(CH.sub.3).sub.2 H CH.sub.34.280 H H H 0 H H H H CH--NHOC.sub.2 H.sub.5 H CH.sub.34.281 H H H 1 H H H H CH--NHOC.sub.2 H.sub.5 H CH.sub.34.282 H H H 2 H H H H CH--NHOC.sub.2 H.sub.5 H CH.sub.34.283 H H H 0 H H H H CH--N(CH.sub.3)OC.sub.2 H.sub.5 H CH.sub.34.284 H H H 1 H H H H CH--N(CH.sub.3)OC.sub.2 H.sub.5 H CH.sub.34.285 H H H 2 H H H H CH--N(CH.sub.3)OC.sub.2 H.sub.5 H CH.sub.34.286 H H H 0 H H H H C.dbd.N--NH.sub.2 H CH.sub.34.287 H H H 1 H H H H C.dbd.N--NH.sub.2 H CH.sub.34.288 H H H 2 H H H H C.dbd.N--NH.sub.2 H CH.sub.34.289 H H H 0 H H H H C.dbd.N--N(CH.sub.3).sub.2 H CH.sub.34.290 H H H 1 H H H H C.dbd.N--N(CH.sub.3).sub.2 H CH.sub.34.291 H H H 2 H H H H C.dbd.N--N(CH.sub.3).sub.2 H CH.sub.34.292 H H H 0 H H H H CH--N(CH.sub.3)OCH.sub.2 C.sub.6 H.sub.5 H CH.sub.34.293 H H H 1 H H H H CH--N(CH.sub.3)OCH.sub.2 C.sub.6 H.sub.5 H CH.sub.34.294 H H H 2 H H H H CH--N(CH.sub.3)OCH.sub.2 C.sub.6 H.sub.5 H CH.sub.34.295 H H H 0 H H H H C(CH.sub.3)--OCH.sub.3 H CH.sub.34.296 H H H 1 H H H H C(CH.sub.3)--OCH.sub.3 H CH.sub.34.297 H H H 2 H H H H C(CH.sub.3)--OCH.sub.3 H CH.sub.34.298 H H H 0 H H H H O H CH.sub.34.299 H H H 1 H H H H O H CH.sub.34.300 H H H 2 H H H H O H CH.sub.34.301 CH.sub.3 H H 0 H H H H C.dbd.O H CH.sub.34.302 CH.sub.3 H H 1 H H H H C.dbd.O H CH.sub.34.303 CH.sub.3 H H 2 H H H H C.dbd.O H CH.sub.34.304 CH.sub.3 H H 0 H H H H CHOH H CH.sub.34.305 CH.sub.3 H H 1 H H H H CHOH H CH.sub.34.306 CH.sub.3 H H 2 H H H H CHOH H CH.sub.34.307 CH.sub.3 H H 0 H H H H CHOCH.sub.3 H CH.sub.34.308 CH.sub.3 H H 1 H H H H CHOCH.sub.3 H CH.sub.34.309 CH.sub.3 H H 2 H H H H CHOCH.sub.3 H CH.sub.34.310 CH.sub.3 H H 0 H H H H CHOC.sub.2 H.sub.5 H CH.sub.34.311 CH.sub.3 H H 1 H H H H CHOC.sub.2 H.sub.5 H CH.sub.34.312 CH.sub.3 H H 2 H H H H CHOC.sub.2 H.sub.5 H CH.sub.34.313 CH.sub.3 H H 0 H H H H CHOiPr H CH.sub.34.314 CH.sub.3 H H 1 H H H H CHOiPr H CH.sub.34.315 CH.sub.3 H H 2 H H H H CHOiPr H CH.sub.34.316 CH.sub.3 H H 0 H H H H C.dbd.NOCH.sub.3 H CH.sub.34.317 CH.sub.3 H H 1 H H H H C.dbd.NOCH.sub.3 H CH.sub.34.318 CH.sub.3 H H 2 H H H H C.dbd.NOCH.sub.3 H CH.sub.34.319 CH.sub.3 H H 0 H H H H C.dbd.NOC.sub.2 H.sub.5 H CH.sub.34.320 CH.sub.3 H H 1 H H H H C.dbd.NOC.sub.2 H.sub.5 H CH.sub.34.321 CH.sub.3 H H 2 H H H H C.dbd.NOC.sub.2 H.sub.5 H CH.sub.34.322 CH.sub.3 H H 0 H H H H C.dbd.NOiPr H CH.sub.34.323 CH.sub.3 H H 1 H H H H C.dbd.NOiPr H CH.sub.34.324 CH.sub.3 H H 2 H H H H C.dbd.NOiPr H CH.sub.34.325 CH.sub.3 H H 0 H H H H C.dbd.NOCH.sub.2 CH.dbd.CHCl H CH.sub.34.326 CH.sub.3 H H 1 H H H H C.dbd.NOCH.sub.2 CH.dbd.CHCl H CH.sub.34.327 CH.sub.3 H H 2 H H H H C.dbd.NOCH.sub.2 CH.dbd.CHCl H CH.sub.34.328 CH.sub.3 H H 0 H H H H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 H CH.sub.34.329 CH.sub.3 H H 1 H H H H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 H CH.sub.34.330 CH.sub.3 H H 2 H H H H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 H CH.sub.34.331 CH.sub.3 H H 0 H H H H C(CH.sub.3).sub.2 H CH.sub.34.332 CH.sub.3 H H 1 H H H H C(CH.sub.3).sub.2 H CH.sub.34.333 CH.sub.3 H H 2 H H H H C(CH.sub.3).sub.2 H CH.sub.34.334 CH.sub.3 H H 0 H H H H ##STR42## H CH.sub.34.335 CH.sub.3 H H 1 H H H H ##STR43## H CH.sub.34.336 CH.sub.3 H H 2 H H H H ##STR44## H CH.sub.34.337 CH.sub.3 H H 0 H H H H ##STR45## H CH.sub.34.338 CH.sub.3 H H 1 H H H H ##STR46## H CH.sub.34.339 CH.sub.3 H H 2 H H H H ##STR47## H CH.sub.34.340 CH.sub.3 H H 0 H H H H C.dbd.N--CH.sub.3 H CH.sub.34.341 CH.sub.3 H H 1 H H H H C.dbd.N--CH.sub.3 H CH.sub.34.342 CH.sub.3 H H 2 H H H H C.dbd.N--CH.sub.3 H CH.sub.34.343 CH.sub.3 H H 0 H H H H C.dbd.NC.sub.2 H.sub.5 H CH.sub.34.344 CH.sub.3 H H 1 H H H H C.dbd.NC.sub.2 H.sub.5 H CH.sub.34.345 CH.sub.3 H H 2 H H H H C.dbd.NC.sub.2 H.sub.5 H CH.sub.34.346 CH.sub.3 H H 0 H H H H CH--NHCH.sub.3 H CH.sub.34.347 CH.sub.3 H H 1 H H H H CH--NHCH.sub.3 H CH.sub.34.348 CH.sub.3 H H 2 H H H H CH--NHCH.sub.3 H CH.sub.34.349 CH.sub.3 H H 0 H H H H CH--NHC.sub.2 H.sub.5 H CH.sub.34.350 CH.sub.3 H H 1 H H H H CH--NHC.sub.2 H.sub.5 H CH.sub.34.351 CH.sub.3 H H 2 H H H H CH--NHC.sub.2 H.sub.5 H CH.sub.34.352 CH.sub.3 H H 0 H H H H CH--N(CH.sub.3).sub.2 H CH.sub.34.353 CH.sub.3 H H 1 H H H H CH--N(CH.sub.3).sub.2 H CH.sub.34.354 CH.sub.3 H H 2 H H H H CH--N(CH.sub.3).sub.2 H CH.sub.34.355 CH.sub.3 H H 0 H H H H CH--NHOC.sub.2 H.sub.5 H CH.sub.34.356 CH.sub.3 H H 1 H H H H CH--NHOC.sub.2 H.sub.5 H CH.sub.34.357 CH.sub.3 H H 2 H H H H CH--NHOC.sub.2 H.sub.5 H CH.sub.34.358 CH.sub.3 H H 0 H H H H CH--N(CH.sub.3)OC.sub.2 H.sub.5 H CH.sub.34.359 CH.sub.3 H H 1 H H H H CH--N(CH.sub.3)OC.sub.2 H.sub.5 H CH.sub.34.360 CH.sub.3 H H 2 H H H H CH--N(CH.sub.3)OC.sub.2 H.sub.5 H CH.sub.34.361 CH.sub.3 H H 0 H H H H C.dbd.N--NH.sub.2 H CH.sub.34.362 CH.sub.3 H H 1 H H H H C.dbd.N--NH.sub.2 H CH.sub.34.363 CH.sub.3 H H 2 H H H H C.dbd.N--NH.sub.2 H CH.sub.34.364 CH.sub.3 H H 0 H H H H C.dbd.N--N(CH.sub.3).sub.2 H CH.sub.34.365 CH.sub.3 H H 1 H H H H C.dbd.N--N(CH.sub.3).sub.2 H CH.sub.34.366 CH.sub.3 H H 2 H H H H C.dbd.N--N(CH.sub.3).sub.2 H CH.sub.34.367 CH.sub.3 H H 0 H H H H CH--N(CH.sub.3)OCH.sub.2 C.sub.6 H.sub.5 H CH.sub.34.368 CH.sub.3 H H 1 H H H H CH--N(CH.sub.3)OCH.sub.2 C.sub.6 H.sub.5 H CH.sub.34.369 CH.sub.3 H H 2 H H H H CH--N(CH.sub.3)OCH.sub.2 C.sub.6 H.sub.5 H CH.sub.34.370 CH.sub.3 H H 0 H H H H C(CH.sub.3)--OCH.sub.3 H CH.sub.34.371 CH.sub.3 H H 1 H H H H C(CH.sub.3)--OCH.sub.3 H CH.sub.34.372 CH.sub.3 H H 2 H H H H C(CH.sub.3)--OCH.sub.3 H CH.sub.34.373 CH.sub.3 H H 0 H H H H O H CH.sub.34.374 CH.sub.3 H H 1 H H H H O H CH.sub.34.375 CH.sub.3 H H 2 H H H H O H CH.sub.34.376 CH.sub.3 CH.sub.3 H 0 H H H H C.dbd.O H CH.sub.34.377 CH.sub.3 CH.sub.3 H 1 H H H H C.dbd.O H CH.sub.34.378 CH.sub.3 CH.sub.3 H 2 H H H H C.dbd.O H CH.sub.34.379 CH.sub.3 CH.sub.3 H 0 H H H H CHOH H CH.sub.34.380 CH.sub.3 CH.sub.3 H 1 H H H H CHOH H CH.sub.34.381 CH.sub.3 CH.sub.3 H 2 H H H H CHOH H CH.sub.34.382 CH.sub.3 CH.sub.3 H 0 H H H H CHOCH.sub.3 H CH.sub.34.383 CH.sub.3 CH.sub.3 H 1 H H H H CHOCH.sub.3 H CH.sub.34.384 CH.sub.3 CH.sub.3 H 2 H H H H CHOCH.sub.3 H CH.sub.34.385 CH.sub.3 CH.sub.3 H 0 H H H H CHOC.sub.2 H.sub.5 H CH.sub.34.386 CH.sub.3 CH.sub.3 H 1 H H H H CHOC.sub.2 H.sub.5 H CH.sub.34.387 CH.sub.3 CH.sub.3 H 2 H H H H CHOC.sub.2 H.sub.5 H CH.sub.34.388 CH.sub.3 CH.sub.3 H 0 H H H H CHOiPr H CH.sub.34.389 CH.sub.3 CH.sub.3 H 1 H H H H CHOiPr H CH.sub.34.390 CH.sub.3 CH.sub.3 H 2 H H H H CHOiPr H CH.sub.34.391 CH.sub.3 CH.sub.3 H 0 H H H H C.dbd.NOCH.sub.3 H CH.sub.34.392 CH.sub.3 CH.sub.3 H 1 H H H H C.dbd.NOCH.sub.3 H CH.sub.34.393 CH.sub.3 CH.sub.3 H 2 H H H H C.dbd.NOCH.sub.3 H CH.sub.34.394 CH.sub.3 CH.sub.3 H 0 H H H H C.dbd.NOC.sub.2 H.sub.5 H CH.sub.34.395 CH.sub.3 CH.sub.3 H 1 H H H H C.dbd.NOC.sub.2 H.sub.5 H CH.sub.34.396 CH.sub.3 CH.sub.3 H 2 H H H H C.dbd.NOC.sub.2 H.sub.5 H CH.sub.34.397 CH.sub.3 CH.sub.3 H 0 H H H H C.dbd.NOiPr H CH.sub.34.398 CH.sub.3 CH.sub.3 H 1 H H H H C.dbd.NOiPr H CH.sub.34.399 CH.sub.3 CH.sub.3 H 2 H H H H C.dbd.NOiPr H CH.sub.34.400 CH.sub.3 CH.sub.3 H 0 H H H H C.dbd.NOCH.sub.2 CH.dbd.CHCl H CH.sub.34.401 CH.sub.3 CH.sub.3 H 1 H H H H C.dbd.NOCH.sub.2 CH.dbd.CHCl H CH.sub.34.402 CH.sub.3 CH.sub.3 H 2 H H H H C.dbd.NOCH.sub.2 CH.dbd.CHCl H CH.sub.34.403 CH.sub.3 CH.sub.3 H 0 H H H H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 H CH.sub.34.404 CH.sub.3 CH.sub.3 H 1 H H H H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 H CH.sub.34.405 CH.sub.3 CH.sub.3 H 2 H H H H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 H CH.sub.34.406 CH.sub.3 CH.sub.3 H 0 H H H H C(CH.sub.3).sub.2 H CH.sub.34.407 CH.sub.3 CH.sub.3 H 1 H H H H C(CH.sub.3).sub.2 H CH.sub.34.408 CH.sub.3 CH.sub.3 H 2 H H H H C(CH.sub.3).sub.2 H CH.sub.34.409 CH.sub.3 CH.sub.3 H 0 H H H H ##STR48## H CH.sub.34.410 CH.sub.3 CH.sub.3 H 1 H H H H ##STR49## H CH.sub.34.411 CH.sub.3 CH.sub.3 H 2 H H H H ##STR50## H CH.sub.34.412 CH.sub.3 CH.sub.3 H 0 H H H H ##STR51## H CH.sub.34.413 CH.sub.3 CH.sub.3 H 1 H H H H ##STR52## H CH.sub.34.414 CH.sub.3 CH.sub.3 H 2 H H H H ##STR53## H CH.sub.34.415 CH.sub.3 CH.sub.3 H 0 H H H H C.dbd.N--CH.sub.3 H CH.sub.34.416 CH.sub.3 CH.sub.3 H 1 H H H H C.dbd.N--CH.sub.3 H CH.sub.34.417 CH.sub.3 CH.sub.3 H 2 H H H H C.dbd.N--CH.sub.3 H CH.sub.34.418 CH.sub.3 CH.sub.3 H 0 H H H H C.dbd.NC.sub.2 H.sub.5 H CH.sub.34.419 CH.sub.3 CH.sub.3 H 1 H H H H C.dbd.NC.sub.2 H.sub.5 H CH.sub.34.420 CH.sub.3 CH.sub.3 H 2 H H H H C.dbd.NC.sub.2 H.sub.5 H CH.sub.34.421 CH.sub.3 CH.sub.3 H 0 H H H H CH--NHCH.sub.3 H CH.sub.34.422 CH.sub.3 CH.sub.3 H 1 H H H H CH--NHCH.sub.3 H CH.sub.34.423 CH.sub.3 CH.sub.3 H 2 H H H H CH--NHCH.sub.3 H CH.sub.34.424 CH.sub.3 CH.sub.3 H 0 H H H H CH--NHC.sub.2 H.sub.5 H CH.sub.34.425 CH.sub.3 CH.sub.3 H 1 H H H H CH--NHC.sub.2 H.sub.5 H CH.sub.34.426 CH.sub.3 CH.sub.3 H 2 H H H H CH--NHC.sub.2 H.sub.5 H CH.sub.34.427 CH.sub.3 CH.sub.3 H 0 H H H H CH--N(CH.sub.3).sub.2 H CH.sub.34.428 CH.sub.3 CH.sub.3 H 1 H H H H CH--N(CH.sub.3).sub.2 H CH.sub.34.429 CH.sub.3 CH.sub.3 H 2 H H H H CH--N(CH.sub.3).sub.2 H CH.sub.34.430 CH.sub.3 CH.sub.3 H 0 H H H H CH--NHOC.sub.2 H.sub.5 H CH.sub.34.431 CH.sub.3 CH.sub.3 H 1 H H H H CH--NHOC.sub.2 H.sub.5 H CH.sub.34.432 CH.sub.3 CH.sub.3 H 2 H H H H CH--NHOC.sub.2 H.sub.5 H CH.sub.34.433 CH.sub.3 CH.sub.3 H 0 H H H H CH--N(CH.sub.3)OC.sub.2 H.sub.5 H CH.sub.34.434 CH.sub.3 CH.sub.3 H 1 H H H H CH--N(CH.sub.3)OC.sub.2 H.sub.5 H CH.sub.34.435 CH.sub.3 CH.sub.3 H 2 H H H H CH--N(CH.sub.3)OC.sub.2 H.sub.5 H CH.sub.34.436 CH.sub.3 CH.sub.3 H 0 H H H H C.dbd.N--NH.sub.2 H CH.sub.34.437 CH.sub.3 CH.sub.3 H 1 H H H H C.dbd.N--NH.sub.2 H CH.sub.34.438 CH.sub.3 CH.sub.3 H 2 H H H H C.dbd.N--NH.sub.2 H CH.sub.34.439 CH.sub.3 CH.sub.3 H 0 H H H H C.dbd.N--N(CH.sub.3).sub.2 H CH.sub.34.440 CH.sub.3 CH.sub.3 H 1 H H H H C.dbd.N--N(CH.sub.3).sub.2 H CH.sub.34.441 CH.sub.3 CH.sub.3 H 2 H H H H C.dbd.N--N(CH.sub.3).sub.2 H CH.sub.34.442 CH.sub.3 CH.sub.3 H 0 H H H H CH--N(CH.sub.3)OCH.sub.2 C.sub.6 H.sub.5 H CH.sub.34.443 CH.sub.3 CH.sub.3 H 1 H H H H CH--N(CH.sub.3)OCH.sub.2 C.sub.6 H.sub.5 H CH.sub.34.444 CH.sub.3 CH.sub.3 H 2 H H H H CH--N(CH.sub.3)OCH.sub.2 C.sub.6 H.sub.5 H CH.sub.34.445 CH.sub.3 CH.sub.3 H 0 H H H H C(CH.sub.3)--OCH.sub.3 H CH.sub.34.446 CH.sub.3 CH.sub.3 H 1 H H H H C(CH.sub.3)--OCH.sub.3 H CH.sub.34.447 CH.sub.3 CH.sub.3 H 2 H H H H C(CH.sub.3)--OCH.sub.3 H CH.sub.34.448 CH.sub.3 CH.sub.3 H 0 H H H H O H CH.sub.34.449 CH.sub.3 CH.sub.3 H 1 H H H H O H CH.sub.34.450 CH.sub.3 CH.sub.3 H 2 H H H H O H CH.sub.34.451 H H H 0 H H H H C.dbd.O H Cl4.452 H H H 1 H H H H C.dbd.O H Cl4.453 H H H 2 H H H H C.dbd.O H Cl4.454 H H H 0 H H H H CHOH H Cl4.455 H H H 1 H H H H CHOH H Cl4.456 H H H 2 H H H H CHOH H Cl4.457 H H H 0 H H H H CHOCH.sub.3 H Cl4.458 H H H 1 H H H H CHOCH.sub.3 H Cl4.459 H H H 2 H H H H CHOCH.sub.3 H Cl4.460 H H H 0 H H H H CHOC.sub.2 H.sub.5 H Cl4.461 H H H 1 H H H H CHOC.sub.2 H.sub.5 H Cl4.462 H H H 2 H H H H CHOC.sub.2 H.sub.5 H Cl4.463 H H H 0 H H H H CHOiPr H Cl4.464 H H H 1 H H H H CHOiPr H Cl4.465 H H H 2 H H H H CHOiPr H Cl4.466 H H H 0 H H H H C.dbd.NOCH.sub.3 H Cl4.467 H H H 1 H H H H C.dbd.NOCH.sub.3 H Cl4.468 H H H 2 H H H H C.dbd.NOCH.sub.3 H Cl4.469 H H H 0 H H H H C.dbd.NOC.sub.2 H.sub.5 H Cl4.470 H H H 1 H H H H C.dbd.NOC.sub.2 H.sub.5 H Cl4.471 H H H 2 H H H H C.dbd.NOC.sub.2 H.sub.5 H Cl4.472 H H H 0 H H H H C.dbd.NOiPr H Cl4.473 H H H 1 H H H H C.dbd.NOiPr H Cl4.474 H H H 2 H H H H C.dbd.NOiPr H Cl4.475 H H H 0 H H H H C.dbd.NOCH.sub.2 CH.dbd.CHCl H Cl4.476 H H H 1 H H H H C.dbd.NOCH.sub.2 CH.dbd.CHCl H Cl4.477 H H H 2 H H H H C.dbd.NOCH.sub.2 CH.dbd.CHCl H Cl4.478 H H H 0 H H H H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 H Cl4.479 H H H 1 H H H H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 H Cl4.480 H H H 2 H H H H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 H Cl4.481 H H H 0 H H H H C(CH.sub.3).sub.2 H Cl4.482 H H H 1 H H H H C(CH.sub.3).sub.2 H Cl4.483 H H H 2 H H H H C(CH.sub.3).sub.2 H Cl4.484 H H H 0 H H H H ##STR54## H Cl4.485 H H H 1 H H H H ##STR55## H Cl4.486 H H H 2 H H H H ##STR56## H Cl4.487 H H H 0 H H H H ##STR57## H Cl4.488 H H H 1 H H H H ##STR58## H Cl4.489 H H H 2 H H H H ##STR59## H Cl4.490 H H H 0 H H H H C.dbd.N--CH.sub.3 H Cl4.491 H H H 1 H H H H C.dbd.N--CH.sub.3 H Cl4.492 H H H 2 H H H H C.dbd.N--CH.sub.3 H Cl4.493 H H H 0 H H H H C.dbd.NC.sub.2 H.sub.5 H Cl4.494 H H H 1 H H H H C.dbd.NC.sub.2 H.sub.5 H Cl4.495 H H H 2 H H H H C.dbd.NC.sub.2 H.sub.5 H Cl4.496 H H H 0 H H H H CH--NHCH.sub.3 H Cl4.497 H H H 1 H H H H CH--NHCH.sub.3 H Cl4.498 H H H 2 H H H H CH--NHCH.sub.3 H Cl4.499 H H H 0 H H H H CH--NHC.sub.2 H.sub.5 H Cl4.500 H H H 1 H H H H CH--NHC.sub.2 H.sub.5 H Cl4.501 H H H 2 H H H H CH--NHC.sub.2 H.sub.5 H Cl4.502 H H H 0 H H H H CH--N(CH.sub.3).sub.2 H Cl4.503 H H H 1 H H H H CH--N(CH.sub.3).sub.2 H Cl4.504 H H H 2 H H H H CH--N(CH.sub.3).sub.2 H Cl4.505 H H H 0 H H H H CH--NHOC.sub.2 H.sub.5 H Cl4.506 H H H 1 H H H H CH--NHOC.sub.2 H.sub.5 H Cl4.507 H H H 2 H H H H CH--NHOC.sub.2 H.sub.5 H Cl4.508 H H H 0 H H H H CH--N(CH.sub.3)OC.sub.2 H.sub.5 H Cl4.509 H H H 1 H H H H CH--N(CH.sub.3)OC.sub.2 H.sub.5 H Cl4.510 H H H 2 H H H H CH--N(CH.sub.3)OC.sub.2 H.sub.5 H Cl4.511 H H H 0 H H H H C.dbd.N--NH.sub.2 H Cl4.512 H H H 1 H H H H C.dbd.N--NH.sub.2 H Cl4.513 H H H 2 H H H H C.dbd.N--NH.sub.2 H Cl4.514 H H H 0 H H H H C.dbd.N--N(CH.sub.3).sub.2 H Cl4.515 H H H 1 H H H H C.dbd.N--N(CH.sub.3).sub.2 H Cl4.516 H H H 2 H H H H C.dbd.N--N(CH.sub.3).sub.2 H Cl4.517 H H H 0 H H H H CH--N(CH.sub.3)OCH.sub.2 C.sub.6 H.sub.5 H Cl4.518 H H H 1 H H H H CH--N(CH.sub.3)OCH.sub.2 C.sub.6 H.sub.5 H Cl4.519 H H H 2 H H H H CH--N(CH.sub.3)OCH.sub.2 C.sub.6 H.sub.5 H Cl4.520 H H H 0 H H H H C(CH.sub.3)--OCH.sub.3 H Cl4.521 H H H 1 H H H H C(CH.sub.3)--OCH.sub.3 H Cl4.522 H H H 2 H H H H C(CH.sub.3)--OCH.sub.3 H Cl4.523 H H H 0 H H H H O H Cl4.524 H H H 1 H H H H O H Cl4.525 H H H 2 H H H H O H Cl4.526 CH.sub.3 H H 0 H H H H C.dbd.O H Cl4.527 CH.sub.3 H H 1 H H H H C.dbd.O H Cl4.528 CH.sub.3 H H 2 H H H H C.dbd.O H Cl4.529 CH.sub.3 H H 0 H H H H CHOH H Cl4.530 CH.sub.3 H H 1 H H H H CHOH H Cl4.531 CH.sub.3 H H 2 H H H H CHOH H Cl4.532 CH.sub.3 H H 0 H H H H CHOCH.sub.3 H Cl4.533 CH.sub.3 H H 1 H H H H CHOCH.sub.3 H Cl4.534 CH.sub.3 H H 2 H H H H CHOCH.sub.3 H Cl4.535 CH.sub.3 H H 0 H H H H CHOC.sub.2 H.sub.5 H Cl4.536 CH.sub.3 H H 1 H H H H CHOC.sub.2 H.sub.5 H Cl4.537 CH.sub.3 H H 2 H H H H CHOC.sub.2 H.sub.5 H Cl4.538 CH.sub.3 H H 0 H H H H CHOiPr H Cl4.539 CH.sub.3 H H 1 H H H H CHOiPr H Cl4.540 CH.sub.3 H H 2 H H H H CHOiPr H Cl4.541 CH.sub.3 H H 0 H H H H C.dbd.NOCH.sub.3 H Cl4.542 CH.sub.3 H H 1 H H H H C.dbd.NOCH.sub.3 H Cl4.543 CH.sub.3 H H 2 H H H H C.dbd.NOCH.sub.3 H Cl4.544 CH.sub.3 H H 0 H H H H C.dbd.NOC.sub.2 H.sub.5 H Cl4.545 CH.sub.3 H H 1 H H H H C.dbd.NOC.sub.2 H.sub.5 H Cl4.546 CH.sub.3 H H 2 H H H H C.dbd.NOC.sub.2 H.sub.5 H Cl4.547 CH.sub.3 H H 0 H H H H C.dbd.NOiPr H Cl4.548 CH.sub.3 H H 1 H H H H C.dbd.NOiPr H Cl4.549 CH.sub.3 H H 2 H H H H C.dbd.NOiPr H Cl4.550 CH.sub.3 H H 0 H H H H C.dbd.NOCH.sub.2 CH.dbd.CHCl H Cl4.551 CH.sub.3 H H 1 H H H H C.dbd.NOCH.sub.2 CH.dbd.CHCl H Cl4.552 CH.sub.3 H H 2 H H H H C.dbd.NOCH.sub.2 CH.dbd.CHCl H Cl4.553 CH.sub.3 H H 0 H H H H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 H Cl4.554 CH.sub.3 H H 1 H H H H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 H Cl4.555 CH.sub.3 H H 2 H H H H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 H Cl4.556 CH.sub.3 H H 0 H H H H C(CH.sub.3).sub.2 H Cl4.557 CH.sub.3 H H 1 H H H H C(CH.sub.3).sub.2 H Cl4.558 CH.sub.3 H H 2 H H H H C(CH.sub.3).sub.2 H Cl4.559 CH.sub.3 H H 0 H H H H ##STR60## H Cl4.560 CH.sub.3 H H 1 H H H H ##STR61## H Cl4.561 CH.sub.3 H H 2 H H H H ##STR62## H Cl4.562 CH.sub.3 H H 0 H H H H ##STR63## H Cl4.563 CH.sub.3 H H 1 H H H H ##STR64## H Cl4.564 CH.sub.3 H H 2 H H H H ##STR65## H Cl4.565 CH.sub.3 H H 0 H H H H C.dbd.N--CH.sub.3 H Cl4.566 CH.sub.3 H H 1 H H H H C.dbd.N--CH.sub.3 H Cl4.567 CH.sub.3 H H 2 H H H H C.dbd.N--CH.sub.3 H Cl4.568 CH.sub.3 H H 0 H H H H C.dbd.NC.sub.2 H.sub.5 H Cl4.569 CH.sub.3 H H 1 H H H H C.dbd.NC.sub.2 H.sub.5 H Cl4.570 CH.sub.3 H H 2 H H H H C.dbd.NC.sub.2 H.sub.5 H Cl4.571 CH.sub.3 H H 0 H H H H CH--NHCH.sub.3 H Cl4.572 CH.sub.3 H H 1 H H H H CH--NHCH.sub.3 H Cl4.573 CH.sub.3 H H 2 H H H H CH--NHCH.sub.3 H Cl4.574 CH.sub.3 H H 0 H H H H CH--NHC.sub.2 H.sub.5 H Cl4.575 CH.sub.3 H H 1 H H H H CH--NHC.sub.2 H.sub.5 H Cl4.576 CH.sub.3 H H 2 H H H H CH--NHC.sub.2 H.sub.5 H Cl4.577 CH.sub.3 H H 0 H H H H CH--N(CH.sub.3).sub.2 H Cl4.578 CH.sub.3 H H 1 H H H H CH--N(CH.sub.3).sub.2 H Cl4.579 CH.sub.3 H H 2 H H H H CH--N(CH.sub.3).sub.2 H Cl4.580 CH.sub.3 H H 0 H H H H CH--NHOC.sub.2 H.sub.5 H Cl4.581 CH.sub.3 H H 1 H H H H CH--NHOC.sub.2 H.sub.5 H Cl4.582 CH.sub.3 H H 2 H H H H CH--NHOC.sub.2 H.sub.5 H Cl4.583 CH.sub.3 H H 0 H H H H CH--N(CH.sub.3)OC.sub.2 H.sub.5 H Cl4.584 CH.sub.3 H H 1 H H H H CH--N(CH.sub.3)OC.sub.2 H.sub.5 H Cl4.585 CH.sub.3 H H 2 H H H H CH--N(CH.sub.3)OC.sub.2 H.sub.5 H Cl4.586 CH.sub.3 H H 0 H H H H C.dbd.N--NH.sub.2 H Cl4.587 CH.sub.3 H H 1 H H H H C.dbd.N--NH.sub.2 H Cl4.588 CH.sub.3 H H 2 H H H H C.dbd.N--NH.sub.2 H Cl4.589 CH.sub.3 H H 0 H H H H C.dbd.N--N(CH.sub.3).sub.2 H Cl4.590 CH.sub.3 H H 1 H H H H C.dbd.N--N(CH.sub.3).sub.2 H Cl4.591 CH.sub.3 H H 2 H H H H C.dbd.N--N(CH.sub.3).sub.2 H Cl4.592 CH.sub.3 H H 0 H H H H CH--N(CH.sub.3)OCH.sub.2 C.sub.6 H.sub.5 H Cl4.593 CH.sub.3 H H 1 H H H H CH--N(CH.sub.3)OCH.sub.2 C.sub.6 H.sub.5 H Cl4.594 CH.sub.3 H H 2 H H H H CH--N(CH.sub.3)OCH.sub.2 C.sub.6 H.sub.5 H Cl4.595 CH.sub.3 H H 0 H H H H C(CH.sub.3)--OCH.sub.3 H Cl4.596 CH.sub.3 H H 1 H H H H C(CH.sub.3)--OCH.sub.3 H Cl4.597 CH.sub.3 H H 2 H H H H C(CH.sub.3)--OCH.sub.3 H Cl4.598 CH.sub.3 H H 0 H H H H O H Cl4.599 CH.sub.3 H H 1 H H H H O H Cl4.600 CH.sub.3 H H 2 H H H H O H Cl4.601 CH.sub.3 CH.sub.3 H 0 H H H H C.dbd.O H Cl4.602 CH.sub.3 CH.sub.3 H 1 H H H H C.dbd.O H Cl4.603 CH.sub.3 CH.sub.3 H 2 H H H H C.dbd.O H Cl4.604 CH.sub.3 CH.sub.3 H 0 H H H H CHOH H Cl4.605 CH.sub.3 CH.sub.3 H 1 H H H H CHOH H Cl4.606 CH.sub.3 CH.sub.3 C H 2 H H H H CHOH H Cl4.607 CH.sub.3 CH.sub.3 H 0 H H H H CHOCH.sub.3 H Cl4.608 CH.sub.3 CH.sub.3 H 1 H H H H CHOCH.sub.3 H Cl4.609 CH.sub.3 CH.sub.3 H 2 H H H H CHOCH.sub.3 H Cl4.610 CH.sub.3 CH.sub.3 H 0 H H H H CHOC.sub.2 H.sub.5 H Cl4.611 CH.sub.3 CH.sub.3 H 1 H H H H CHOC.sub.2 H.sub.5 H Cl4.612 CH.sub.3 CH.sub.3 H 2 H H H H CHOC.sub.2 H.sub.5 H Cl4.613 CH.sub.3 CH.sub.3 H 0 H H H H CHOiPr H Cl4.614 CH.sub.3 CH.sub.3 H 1 H H H H CHOiPr H Cl4.615 CH.sub.3 CH.sub.3 H 2 H H H H CHOiPr H Cl4.616 CH.sub.3 CH.sub.3 H 0 H H H H C.dbd.NOCH.sub.3 H Cl4.617 CH.sub.3 CH.sub.3 H 1 H H H H C.dbd.NOCH.sub.3 H Cl4.618 CH.sub.3 CH.sub.3 H 2 H H H H C.dbd.NOCH.sub.3 H Cl4.619 CH.sub.3 CH.sub.3 H 0 H H H H C.dbd.NOC.sub.2 H.sub.5 H Cl4.620 CH.sub.3 CH.sub.3 H 1 H H H H C.dbd.NOC.sub.2 H.sub.5 H Cl4.621 CH.sub.3 CH.sub.3 H 2 H H H H C.dbd.NOC.sub.2 H.sub.5 H Cl4.622 CH.sub.3 CH.sub.3 H 0 H H H H C.dbd.NOiPr H Cl4.623 CH.sub.3 CH.sub.3 H 1 H H H H C.dbd.NOiPr H Cl4.624 CH.sub.3 CH.sub.3 H 2 H H H H C.dbd.NOiPr H Cl4.625 CH.sub.3 CH.sub.3 H 0 H H H H C.dbd.NOCH.sub.2 CH.dbd.CHCl H Cl4.626 CH.sub.3 CH.sub.3 H 1 H H H H C.dbd.NOCH.sub.2 CH.dbd.CHCl H Cl4.627 CH.sub.3 CH.sub.3 H 2 H H H H C.dbd.NOCH.sub.2 CH.dbd.CHCl H Cl4.628 CH.sub.3 CH.sub.3 H 0 H H H H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 H Cl4.629 CH.sub.3 CH.sub.3 H 1 H H H H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 H Cl4.630 CH.sub.3 CH.sub.3 H 2 H H H H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 H Cl4.631 CH.sub.3 CH.sub.3 H 0 H H H H C(CH.sub.3).sub.2 H Cl4.632 CH.sub.3 CH.sub.3 H 1 H H H H C(CH.sub.3).sub.2 H Cl4.633 CH.sub.3 CH.sub.3 H 2 H H H H C(CH.sub.3).sub.2 H Cl4.634 CH.sub.3 CH.sub.3 H 0 H H H H ##STR66## H Cl4.635 CH.sub.3 CH.sub.3 H 1 H H H H ##STR67## H Cl4.636 CH.sub.3 CH.sub.3 H 2 H H H H ##STR68## H Cl4.637 CH.sub.3 CH.sub.3 H 0 H H H H ##STR69## H Cl4.638 CH.sub.3 CH.sub.3 H 1 H H H H ##STR70## H Cl4.639 CH.sub.3 CH.sub.3 H 2 H H H H ##STR71## H Cl4.640 CH.sub.3 CH.sub.3 H 0 H H H H C.dbd.N--CH.sub.3 H Cl4.641 CH.sub.3 CH.sub.3 H 1 H H H H C.dbd.N--CH.sub.3 H Cl4.642 CH.sub.3 CH.sub.3 H 2 H H H H C.dbd.N--CH.sub.3 H Cl4.643 CH.sub.3 CH.sub.3 H 0 H H H H C.dbd.NC.sub.2 H.sub.5 H Cl4.644 CH.sub.3 CH.sub.3 H 1 H H H H C.dbd.NC.sub.2 H.sub.5 H Cl4.645 CH.sub.3 CH.sub.3 H 2 H H H H C.dbd.NC.sub.2 H.sub.5 H Cl4.646 CH.sub.3 CH.sub.3 H 0 H H H H CH--NHCH.sub.3 H Cl4.647 CH.sub.3 CH.sub.3 H 1 H H H H CH--NHCH.sub.3 H Cl4.648 CH.sub.3 CH.sub.3 H 2 H H H H CH--NHCH.sub.3 H Cl4.649 CH.sub.3 CH.sub.3 H 0 H H H H CH--NHC.sub.2 H.sub.5 H Cl4.650 CH.sub.3 CH.sub.3 H 1 H H H H CH--NHC.sub.2 H.sub.5 H Cl4.651 CH.sub.3 CH.sub.3 H 2 H H H H CH--NHC.sub.2 H.sub.5 H Cl4.652 CH.sub.3 CH.sub.3 H 0 H H H H CH--N(CH.sub.3).sub.2 H Cl4.653 CH.sub.3 CH.sub.3 H 1 H H H H CH--N(CH.sub.3).sub.2 H Cl4.654 CH.sub.3 CH.sub.3 H 2 H H H H CH--N(CH.sub.3).sub.2 H Cl4.655 CH.sub.3 CH.sub.3 H 0 H H H H CH--NHOC.sub.2 H.sub.5 H Cl4.656 CH.sub.3 CH.sub.3 H 1 H H H H CH--NHOC.sub.2 H.sub.5 H Cl4.657 CH.sub.3 CH.sub.3 H 2 H H H H CH--NHOC.sub.2 H.sub.5 H Cl4.658 CH.sub.3 CH.sub.3 H 0 H H H H CH--N(CH.sub.3)OC.sub.2 H.sub.5 H Cl4.659 CH.sub.3 CH.sub.3 H 1 H H H H CH--N(CH.sub.3)OC.sub.2 H.sub.5 H Cl4.660 CH.sub.3 CH.sub.3 H 2 H H H H CH--N(CH.sub.3)OC.sub.2 H.sub.5 H Cl4.661 CH.sub.3 CH.sub.3 H 0 H H H H C.dbd.N--NH.sub.2 H Cl4.662 CH.sub.3 CH.sub.3 H 1 H H H H C.dbd.N--NH.sub.2 H Cl4.663 CH.sub.3 CH.sub.3 H 2 H H H H C.dbd.N--NH.sub.2 H Cl4.664 CH.sub.3 CH.sub.3 H 0 H H H H C.dbd.N--N(CH.sub.3).sub.2 H Cl4.665 CH.sub.3 CH.sub.3 H 1 H H H H C.dbd.N--N(CH.sub.3).sub.2 H Cl4.666 CH.sub.3 CH.sub.3 H 2 H H H H C.dbd.N--N(CH.sub.3).sub.2 H Cl4.667 CH.sub.3 CH.sub.3 H 0 H H H H CH--N(CH.sub.3)OCH.sub.2 C.sub.6 H.sub.5 H Cl4.668 CH.sub.3 CH.sub.3 H 1 H H H H CH--N(CH.sub.3)OCH.sub.2 C.sub.6 H.sub.5 H Cl4.669 CH.sub.3 CH.sub.3 H 2 H H H H CH--N(CH.sub.3)OCH.sub.2 C.sub.6 H.sub.5 H Cl4.670 CH.sub.3 CH.sub.3 H 0 H H H H C(CH.sub.3)--OCH.sub.3 H Cl4.671 CH.sub.3 CH.sub.3 H 1 H H H H C(CH.sub.3)--OCH.sub.3 H Cl4.672 CH.sub.3 CH.sub.3 H 2 H H H H C(CH.sub.3)--OCH.sub.3 H Cl4.673 CH.sub.3 CH.sub.3 H 0 H H H H O H Cl4.674 CH.sub.3 CH.sub.3 H 1 H H H H O H Cl4.675 CH.sub.3 CH.sub.3 H 2 H H H H O H Cl4.676 H H H 0 H H H H C.dbd.O H NO.sub.24.677 H H H 1 H H H H C.dbd.O H NO.sub.24.678 H H H 2 H H H H C.dbd.O H NO.sub.24.679 H H H 0 H H H H CHOCH.sub.3 H NO.sub.24.680 H H H 1 H H H H CHOCH.sub.3 H NO.sub.24.681 H H H 2 H H H H CHOCH.sub.3 H NO.sub.24.682 H H H 0 H H H H CHOC.sub.2 H.sub.5 H NO.sub.24.683 H H H 1 H H H H CHOC.sub.2 H.sub.5 H NO.sub.24.684 H H H 2 H H H H CHOC.sub.2 H.sub.5 H NO.sub.24.685 H H H 0 H H H H CHOiPr H NO.sub.24.686 H H H 1 H H H H CHOiPr H NO.sub.24.687 H H H 2 H H H H CHOiPr H NO.sub.24.688 H H H 0 H H H H C.dbd.NOCH.sub.3 H NO.sub.24.689 H H H 1 H H H H C.dbd.NOCH.sub.3 H NO.sub.24.690 H H H 2 H H H H C.dbd.NOCH.sub.3 H NO.sub.24.691 H H H 0 H H H H C.dbd.NOC.sub.2 H.sub.5 H NO.sub.24.692 H H H 1 H H H H C.dbd.NOC.sub.2 H.sub.5 H NO.sub.24.693 H H H 2 H H H H C.dbd.NOC.sub.2 H.sub.5 H NO.sub.24.694 H H H 0 H H H H C.dbd.NOiPr H NO.sub.24.695 H H H 1 H H H H C.dbd.NOiPr H NO.sub.24.696 H H H 2 H H H H C.dbd.NOiPr H NO.sub.24.697 H H H 0 H H H H C.dbd.NOCH.sub.2 CH.dbd.CHCl H NO.sub.24.698 H H H 1 H H H H C.dbd.NOCH.sub.2 CH.dbd.CHCl H NO.sub.24.699 H H H 2 H H H H C.dbd.NOCH.sub.2 CH.dbd.CHCl H NO.sub.24.700 H H H 0 H H H H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 H NO.sub.24.701 H H H 1 H H H H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 H NO.sub.24.702 H H H 2 H H H H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 H NO.sub.24.703 H H H 0 H H H H C(CH.sub.3).sub.2 H NO.sub.24.704 H H H 1 H H H H C(CH.sub.3).sub.2 H NO.sub.24.705 H H H 2 H H H H C(CH.sub.3).sub.2 H NO.sub.24.706 H H H 0 H H H H ##STR72## H NO.sub.24.707 H H H 1 H H H H ##STR73## H NO.sub.24.708 H H H 2 H H H H ##STR74## H NO.sub.24.709 H H H 0 H H H H ##STR75## H NO.sub.24.710 H H H 1 H H H H ##STR76## H NO.sub.24.711 H H H 2 H H H H ##STR77## H NO.sub.24.712 H H H 0 H H H H C.dbd.N--CH.sub.3 H NO.sub.24.713 H H H 1 H H H H C.dbd.N--CH.sub.3 H NO.sub.24.714 H H H 2 H H H H C.dbd.N--CH.sub.3 H NO.sub.24.715 H H H 0 H H H H C.dbd.NC.sub.2 H.sub.5 H NO.sub.24.716 H H H 1 H H H H C.dbd.NC.sub.2 H.sub.5 H NO.sub.24.717 H H H 2 H H H H C.dbd.NC.sub.2 H.sub.5 H NO.sub.24.718 H H H 0 H H H H CH--NHCH.sub.3 H NO.sub.24.719 H H H 1 H H H H CH--NHCH.sub.3 H NO.sub.24.720 H H H 2 H H H H CH--NHCH.sub.3 H NO.sub.24.721 H H H 0 H H H H CH--NHC.sub.2 H.sub.5 H NO.sub.24.722 H H H 1 H H H H CH--NHC.sub.2 H.sub.5 H NO.sub.24.723 H H H 2 H H H H CH--NHC.sub.2 H.sub.5 H NO.sub.24.724 H H H 0 H H H H CH--N(CH.sub.3).sub.2 H NO.sub.24.725 H H H 1 H H H H CH--N(CH.sub.3).sub.2 H NO.sub.24.726 H H H 2 H H H H CH--N(CH.sub.3).sub.2 H NO.sub.24.727 H H H 0 H H H H CH--NHOC.sub.2 H.sub.5 H NO.sub.24.728 H H H 1 H H H H CH--NHOC.sub.2 H.sub.5 H NO.sub.24.729 H H H 2 H H H H CH--NHOC.sub.2 H.sub.5 H NO.sub.24.730 H H H 0 H H H H CH--N(CH.sub.3)OC.sub.2 H.sub.5 H NO.sub.24.731 H H H 1 H H H H CH--N(CH.sub.3)OC.sub.2 H.sub.5 H NO.sub.24.732 H H H 2 H H H H CH--N(CH.sub.3)OC.sub.2 H.sub.5 H NO.sub.24.733 H H H 0 H H H H C.dbd.N--NH.sub.2 H NO.sub.24.734 H H H 1 H H H H C.dbd.N--NH.sub.2 H NO.sub.24.735 H H H 2 H H H H C.dbd.N--NH.sub.2 H NO.sub.24.736 H H H 0 H H H H C.dbd.N--N(CH.sub.3).sub.2 H NO.sub.24.737 H H H 1 H H H H C.dbd.N--N(CH.sub.3).sub.2 H NO.sub.24.738 H H H 2 H H H H C.dbd.N--N(CH.sub.3).sub.2 H NO.sub.24.739 H H H 0 H H H H CH--N(CH.sub.3)OCH.sub.2 C.sub.6 H.sub.5 H NO.sub.24.740 H H H 1 H H H H CH--N(CH.sub.3)OCH.sub.2 C.sub.6 H.sub.5 H NO.sub.24.741 H H H 2 H H H H CH--N(CH.sub.3)OCH.sub.2 C.sub.6 H.sub.5 H NO.sub.24.742 H H H 0 H H H H C(CH.sub.3)--OCH.sub.3 H NO.sub.24.743 H H H 1 H H H H C(CH.sub.3)--OCH.sub.3 H NO.sub.24.744 H H H 2 H H H H C(CH.sub.3)--OCH.sub.3 H NO.sub.24.745 H H H 0 H H H H O H NO.sub.24.746 H H H 1 H H H H O H NO.sub.24.747 H H H 2 H H H H O H NO.sub.24.748 CH.sub.3 H H 0 H H H H C.dbd.O H NO.sub.24.749 CH.sub.3 H H 1 H H H H C.dbd.O H NO.sub.24.750 CH.sub.3 H H 2 H H H H C.dbd.O H NO.sub.24.751 CH.sub.3 H H 0 H H H H CHOCH.sub.3 H NO.sub.24.752 CH.sub.3 H H 1 H H H H CHOCH.sub.3 H NO.sub.24.753 CH.sub.3 H H 2 H H H H CHOCH.sub.3 H NO.sub.24.754 CH.sub.3 H H 0 H H H H CHOC.sub.2 H.sub.5 H NO.sub.24.755 CH.sub.3 H H 1 H H H H CHOC.sub.2 H.sub.5 H NO.sub.24.756 CH.sub.3 H H 2 H H H H CHOC.sub.2 H.sub.5 H NO.sub.24.757 CH.sub.3 H H 0 H H H H CHOiPr H NO.sub.24.758 CH.sub.3 H H 1 H H H H CHOiPr H NO.sub.24.759 CH.sub.3 H H 2 H H H H CHOiPr H NO.sub.24.760 CH.sub.3 H H 0 H H H H C.dbd.NOCH.sub.3 H NO.sub.24.761 CH.sub.3 H H 1 H H H H C.dbd.NOCH.sub.3 H NO.sub.24.762 CH.sub.3 H H 2 H H H H C.dbd.NOCH.sub.3 H NO.sub.24.763 CH.sub.3 H H 0 H H H H C.dbd.NOC.sub.2 H.sub.5 H NO.sub.24.764 CH.sub.3 H H 1 H H H H C.dbd.NOC.sub.2 H.sub.5 H NO.sub.24.765 CH.sub.3 H H 2 H H H H C.dbd.NOC.sub.2 H.sub.5 H NO.sub.24.766 CH.sub.3 H H 0 H H H H C.dbd.NOiPr H NO.sub.24.767 CH.sub.3 H H 1 H H H H C.dbd.NOiPr H NO.sub.24.768 CH.sub.3 H H 2 H H H H C.dbd.NOiPr H NO.sub.24.769 CH.sub.3 H H 0 H H H H C.dbd.NOCH.sub.2 CH.dbd.CHCl H NO.sub.24.770 CH.sub.3 H H 1 H H H H C.dbd.NOCH.sub.2 CH.dbd.CHCl H NO.sub.24.771 CH.sub.3 H H 2 H H H H C.dbd.NOCH.sub.2 CH.dbd.CHCl H NO.sub.24.772 CH.sub.3 H H 0 H H H H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 H NO.sub.24.773 CH.sub.3 H H 1 H H H H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 H NO.sub.24.774 CH.sub.3 H H 2 H H H H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 H NO.sub.24.775 CH.sub.3 H H 0 H H H H C(CH.sub.3).sub.2 H NO.sub.24.776 CH.sub.3 H H 1 H H H H C(CH.sub.3).sub.2 H NO.sub.24.777 CH.sub.3 H H 2 H H H H C(CH.sub.3).sub.2 H NO.sub.24.778 CH.sub.3 H H 0 H H H H ##STR78## H NO.sub.24.779 CH.sub.3 H H 1 H H H H ##STR79## H NO.sub.24.780 CH.sub.3 H H 2 H H H H ##STR80## H NO.sub.24.781 CH.sub.3 H H 0 H H H H ##STR81## H NO.sub.24.782 CH.sub.3 H H 1 H H H H ##STR82## H NO.sub.24.783 CH.sub.3 H H 2 H H H H ##STR83## H NO.sub.24.784 CH.sub.3 H H 0 H H H H C.dbd.N--CH.sub.3 H NO.sub.24.785 CH.sub.3 H H 1 H H H H C.dbd.N--CH.sub.3 H NO.sub.24.786 CH.sub.3 H H 2 H H H H C.dbd.N--CH.sub.3 H NO.sub.24.787 CH.sub.3 H H 0 H H H H C.dbd.NC.sub.2 H.sub.5 H NO.sub.24.788 CH.sub.3 H H 1 H H H H C.dbd.NC.sub.2 H.sub.5 H NO.sub.24.789 CH.sub.3 H H 2 H H H H C.dbd.NC.sub.2 H.sub.5 H NO.sub.24.790 CH.sub.3 H H 0 H H H H CH--NHCH.sub.3 H NO.sub.24.791 CH.sub.3 H H 1 H H H H CH--NHCH.sub.3 H NO.sub.24.792 CH.sub.3 H H 2 H H H H CH--NHCH.sub.3 H NO.sub.24.793 CH.sub.3 H H 0 H H H H CH--NHC.sub.2 H.sub.5 H NO.sub.24.794 CH.sub.3 H H 1 H H H H CH--NHC.sub.2 H.sub.5 H NO.sub.24.795 CH.sub.3 H H 2 H H H H CH--NHC.sub.2 H.sub.5 H NO.sub.24.796 CH.sub.3 H H 0 H H H H CH--N(CH.sub.3).sub.2 H NO.sub.24.797 CH.sub.3 H H 1 H H H H CH--N(CH.sub.3).sub.2 H NO.sub.24.798 CH.sub.3 H H 2 H H H H CH--N(CH.sub.3).sub.2 H NO.sub.24.799 CH.sub.3 H H 0 H H H H CH--NHOC.sub.2 H.sub.5 H NO.sub.24.800 CH.sub.3 H H 1 H H H H CH--NHOC.sub.2 H.sub.5 H NO.sub.24.801 CH.sub.3 H H 2 H H H H CH--NHOC.sub.2 H.sub.5 H NO.sub.24.802 CH.sub.3 H H 0 H H H H CH--N(CH.sub.3)OC.sub.2 H.sub.5 H NO.sub.24.803 CH.sub.3 H H 1 H H H H CH--N(CH.sub.3)OC.sub.2 H.sub.5 H NO.sub.24.804 CH.sub.3 H H 2 H H H H CH--N(CH.sub.3)OC.sub.2 H.sub.5 H NO.sub.24.805 CH.sub.3 H H 0 H H H H C.dbd.N--NH.sub.2 H NO.sub.24.806 CH.sub.3 H H 1 H H H H C.dbd.N--NH.sub.2 H NO.sub.24.807 CH.sub.3 H H 2 H H H H C.dbd.N--NH.sub.2 H NO.sub.24.808 CH.sub.3 H H 0 H H H H C.dbd.N--N(CH.sub.3).sub.2 H NO.sub.24.809 CH.sub.3 H H 1 H H H H C.dbd.N--N(CH.sub.3).sub.2 H NO.sub.24.810 CH.sub.3 H H 2 H H H H C.dbd.N--N(CH.sub.3).sub.2 H NO.sub.24.811 CH.sub.3 H H 0 H H H H CH--N(CH.sub.3)OCH.sub.2 C.sub.6 H.sub.5 H NO.sub.24.812 CH.sub.3 H H 1 H H H H CH--N(CH.sub.3)OCH.sub.2 C.sub.6 H.sub.5 H NO.sub.24.813 CH.sub.3 H H 2 H H H H CH--N(CH.sub.3)OCH.sub.2 C.sub.6 H.sub.5 H NO.sub.24.814 CH.sub.3 H H 0 H H H H C(CH.sub.3)--OCH.sub.3 H NO.sub.24.815 CH.sub.3 H H 1 H H H H C(CH.sub.3)--OCH.sub.3 H NO.sub.24.816 CH.sub.3 H H 2 H H H H C(CH.sub.3)--OCH.sub.3 H NO.sub.24.817 CH.sub.3 H H 0 H H H H O H NO.sub.24.818 CH.sub.3 H H 1 H H H H O H NO.sub.24.819 CH.sub.3 H H 2 H H H H O H NO.sub.24.820 CH.sub.3 CH.sub.3 H 0 H H H H C.dbd.O H NO.sub.24.821 CH.sub.3 CH.sub.3 H 1 H H H H C.dbd.O H NO.sub.24.822 CH.sub.3 CH.sub.3 H 2 H H H H C.dbd.O H NO.sub.24.823 CH.sub.3 CH.sub.3 H 0 H H H H CHOCH.sub.3 H NO.sub.24.824 CH.sub.3 CH.sub.3 H 1 H H H H CHOCH.sub.3 H NO.sub.24.825 CH.sub.3 CH.sub.3 H 2 H H H H CHOCH.sub.3 H NO.sub.24.826 CH.sub.3 CH.sub.3 H 0 H H H H CHOC.sub.2 H.sub.5 H NO.sub.24.827 CH.sub.3 CH.sub.3 H 1 H H H H CHOC.sub.2 H.sub.5 H NO.sub.24.828 CH.sub.3 CH.sub.3 H 2 H H H H CHOC.sub.2 H.sub.5 H NO.sub.24.829 CH.sub.3 CH.sub.3 H 0 H H H H CHOiPr H NO.sub.24.830 CH.sub.3 CH.sub.3 H 1 H H H H CHOiPr H NO.sub.24.831 CH.sub.3 CH.sub.3 H 2 H H H H CHOiPr H NO.sub.24.832 CH.sub.3 CH.sub.3 H 0 H H H H C.dbd.NOCH.sub.3 H NO.sub.24.833 CH.sub.3 CH.sub.3 H 1 H H H H C.dbd.NOCH.sub.3 H NO.sub.24.834 CH.sub.3 CH.sub.3 H 2 H H H H C.dbd.NOCH.sub.3 H NO.sub.24.835 CH.sub.3 CH.sub.3 H 0 H H H H C.dbd.NOC.sub.2 H.sub.5 H NO.sub.24.836 CH.sub.3 CH.sub.3 H 1 H H H H C.dbd.NOC.sub.2 H.sub.5 H NO.sub.24.837 CH.sub.3 CH.sub.3 H 2 H H H H C.dbd.NOC.sub.2 H.sub.5 H NO.sub.24.838 CH.sub.3 CH.sub.3 H 0 H H H H C.dbd.NOiPr H NO.sub.24.839 CH.sub.3 CH.sub.3 H 1 H H H H C.dbd.NOiPr H NO.sub.24.840 CH.sub.3 CH.sub.3 H 2 H H H H C.dbd.NOiPr H NO.sub.24.841 CH.sub.3 CH.sub.3 H 0 H H H H C.dbd.NOCH.sub.2 CH.dbd.CHCl H NO.sub.24.842 CH.sub.3 CH.sub.3 H 1 H H H H C.dbd.NOCH.sub.2 CH.dbd.CHCl H NO.sub.24.843 CH.sub.3 CH.sub.3 H 2 H H H H C.dbd.NOCH.sub.2 CH.dbd.CHCl H NO.sub.24.844 CH.sub.3 CH.sub.3 H 0 H H H H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 H NO.sub.24.845 CH.sub.3 CH.sub.3 H 1 H H H H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 H NO.sub.24.846 CH.sub.3 CH.sub.3 H 2 H H H H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 H NO.sub.24.847 CH.sub.3 CH.sub.3 H 0 H H H H C(CH.sub.3).sub.2 H NO.sub.24.848 CH.sub.3 CH.sub.3 H 1 H H H H C(CH.sub.3).sub.2 H NO.sub.24.849 CH.sub.3 CH.sub.3 H 2 H H H H C(CH.sub.3).sub.2 H NO.sub.24.850 CH.sub.3 CH.sub.3 H 0 H H H H ##STR84## H NO.sub.24.851 CH.sub.3 CH.sub.3 H 1 H H H H ##STR85## H NO.sub.24.852 CH.sub.3 CH.sub.3 H 2 H H H H ##STR86## H NO.sub.24.853 CH.sub.3 CH.sub.3 H 0 H H H H ##STR87## H NO.sub.24.854 CH.sub.3 CH.sub.3 H 1 H H H H ##STR88## H NO.sub.24.855 CH.sub.3 CH.sub.3 H 2 H H H H ##STR89## H NO.sub.24.856 CH.sub.3 CH.sub.3 H 0 H H H H C.dbd.N--CH.sub.3 H NO.sub.24.857 CH.sub.3 CH.sub.3 H 1 H H H H C.dbd.N--CH.sub.3 H NO.sub.24.858 CH.sub.3 CH.sub.3 H 2 H H H H C.dbd.N--CH.sub.3 H NO.sub.24.859 CH.sub.3 CH.sub.3 H 0 H H H H C.dbd.NC.sub.2 H.sub.5 H NO.sub.24.860 CH.sub.3 CH.sub.3 H 1 H H H H C.dbd.NC.sub.2 H.sub.5 H NO.sub.24.861 CH.sub.3 CH.sub.3 H 2 H H H H C.dbd.NC.sub.2 H.sub.5 H NO.sub.24.862 CH.sub.3 CH.sub.3 H 0 H H H H CH--NHCH.sub.3 H NO.sub.24.863 CH.sub.3 CH.sub.3 H 1 H H H H CH--NHCH.sub.3 H NO.sub.24.864 CH.sub.3 CH.sub.3 H 2 H H H H CH--NHCH.sub.3 H NO.sub.24.865 CH.sub.3 CH.sub.3 H 0 H H H H CH--NHC.sub.2 H.sub.5 H NO.sub.24.866 CH.sub.3 CH.sub.3 H 1 H H H H CH--NHC.sub.2 H.sub.5 H NO.sub.24.867 CH.sub.3 CH.sub.3 H 2 H H H H CH--NHC.sub.2 H.sub.5 H NO.sub.24.868 CH.sub.3 CH.sub.3 H 0 H H H H CH--N(CH.sub.3).sub.2 H NO.sub.24.869 CH.sub.3 CH.sub.3 H 1 H H H H CH--N(CH.sub.3).sub.2 H NO.sub.24.870 CH.sub.3 CH.sub.3 H 2 H H H H CH--N(CH.sub.3).sub.2 H NO.sub.24.871 CH.sub.3 CH.sub.3 H 0 H H H H CH--NHOC.sub.2 H.sub.5 H NO.sub.24.872 CH.sub.3 CH.sub.3 H 1 H H H H CH--NHOC.sub.2 H.sub.5 H NO.sub.24.873 CH.sub.3 CH.sub.3 H 2 H H H H CH--NHOC.sub.2 H.sub.5 H NO.sub.24.874 CH.sub.3 CH.sub.3 H 0 H H H H CH--N(CH.sub.3)OC.sub.2 H.sub.5 H NO.sub.24.875 CH.sub.3 CH.sub.3 H 1 H H H H CH--N(CH.sub.3)OC.sub.2 H.sub.5 H NO.sub.24.876 CH.sub.3 CH.sub.3 H 2 H H H H CH--N(CH.sub.3)OC.sub.2 H.sub.5 H NO.sub.24.877 CH.sub.3 CH.sub.3 H 0 H H H H C.dbd.N--NH.sub.2 H NO.sub.24.878 CH.sub.3 CH.sub.3 H 1 H H H H C.dbd.N--NH.sub.2 H NO.sub.24.879 CH.sub.3 CH.sub.3 H 2 H H H H C.dbd.N--NH.sub.2 H NO.sub.24.880 CH.sub.3 CH.sub.3 H 0 H H H H C.dbd.N--N(CH.sub.3).sub.2 H NO.sub.24.881 CH.sub.3 CH.sub.3 H 1 H H H H C.dbd.N--N(CH.sub.3).sub.2 H NO.sub.24.882 CH.sub.3 CH.sub.3 H 2 H H H H C.dbd.N--N(CH.sub.3).sub.2 H NO.sub.24.883 CH.sub.3 CH.sub.3 H 0 H H H H CH--N(CH.sub.3)OCH.sub.2 C.sub.6 H.sub.5 H NO.sub.24.884 CH.sub.3 CH.sub.3 H 1 H H H H CH--N(CH.sub.3)OCH.sub.2 C.sub.6 H.sub.5 H NO.sub.24.885 CH.sub.3 CH.sub.3 H 2 H H H H CH--N(CH.sub.3)OCH.sub.2 C.sub.6 H.sub.5 H NO.sub.24.886 CH.sub.3 CH.sub.3 H 0 H H H H C(CH.sub.3)--OCH.sub.3 H NO.sub.24.887 CH.sub.3 CH.sub.3 H 1 H H H H C(CH.sub.3)--OCH.sub.3 H NO.sub.24.888 CH.sub.3 CH.sub.3 H 2 H H H H C(CH.sub.3)--OCH.sub.3 H NO.sub.24.889 CH.sub.3 CH.sub.3 H 0 H H H H O H NO.sub.24.890 CH.sub.3 CH.sub.3 H 1 H H H H O H NO.sub.24.891 CH.sub.3 CH.sub.3 H 2 H H H H O H NO.sub.24.892 H H H 0 H H H H C.dbd.O CH.sub.3 CH.sub.34.893 H H H 1 H H H H C.dbd.O CH.sub.3 CH.sub.34.894 H H H 2 H H H H C.dbd.O CH.sub.3 CH.sub.34.895 H H H 0 H H H H CHOCH.sub.3 CH.sub.3 CH.sub.34.896 H H H 1 H H H H CHOCH.sub.3 CH.sub.3 CH.sub.34.897 H H H 2 H H H H CHOCH.sub.3 CH.sub.3 CH.sub.34.898 H H H 0 H H H H CHOC.sub.2 H.sub.5 CH.sub.3 CH.sub.34.899 H H H 1 H H H H CHOC.sub.2 H.sub.5 CH.sub.3 CH.sub.34.900 H H H 2 H H H H CHOC.sub.2 H.sub.5 CH.sub.3 CH.sub.34.901 H H H 0 H H H H CHOiPr CH.sub.3 CH.sub.34.902 H H H 1 H H H H CHOiPr CH.sub.3 CH.sub.34.903 H H H 2 H H H H CHOiPr CH.sub.3 CH.sub.34.904 H H H 0 H H H H C.dbd.NOCH.sub.3 CH.sub.3 CH.sub.34.905 H H H 1 H H H H C.dbd.NOCH.sub.3 CH.sub.3 CH.sub.34.906 H H H 2 H H H H C.dbd.NOCH.sub.3 CH.sub.3 CH.sub.34.907 H H H 0 H H H H C.dbd.NOC.sub.2 H.sub.5 CH.sub.3 CH.sub.34.908 H H H 1 H H H H C.dbd.NOC.sub.2 H.sub.5 CH.sub.3 CH.sub.34.909 H H H 2 H H H H C.dbd.NOC.sub.2 H.sub.5 CH.sub.3 CH.sub.34.910 H H H 0 H H H H C.dbd.NOiPr CH.sub.3 CH.sub.34.911 H H H 1 H H H H C.dbd.NOiPr CH.sub.3 CH.sub.34.912 H H H 2 H H H H C.dbd.NOiPr CH.sub.3 CH.sub.34.913 H H H 0 H H H H C.dbd.NOCH.sub.2 CH.dbd.CHCl CH.sub.3 CH.sub.34.914 H H H 1 H H H H C.dbd.NOCH.sub.2 CH.dbd.CHCl CH.sub.3 CH.sub.34.915 H H H 2 H H H H C.dbd.NOCH.sub.2 CH.dbd.CHCl CH.sub.3 CH.sub.34.916 H H H 0 H H H H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 CH.sub.3 CH.sub.34.917 H H H 1 H H H H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 CH.sub.3 CH.sub.34.918 H H H 2 H H H H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 CH.sub.3 CH.sub.34.919 H H H 0 H H H H C(CH.sub.3).sub.2 CH.sub.3 CH.sub.34.920 H H H 1 H H H H C(CH.sub.3).sub.2 CH.sub.3 CH.sub.34.921 H H H 2 H H H H C(CH.sub.3).sub.2 CH.sub.3 CH.sub.34.922 H H H 0 H H H H ##STR90## CH.sub.3 CH.sub.34.923 H H H 1 H H H H ##STR91## CH.sub.3 CH.sub.34.924 H H H 2 H H H H ##STR92## CH.sub.3 CH.sub.34.925 H H H 0 H H H H ##STR93## CH.sub.3 CH.sub.34.926 H H H 1 H H H H ##STR94## CH.sub.3 CH.sub.34.927 H H H 2 H H H H ##STR95## CH.sub.3 CH.sub.34.928 H H H 0 H H H H C.dbd.N--CH.sub.3 CH.sub.3 CH.sub.34.929 H H H 1 H H H H C.dbd.N--CH.sub.3 CH.sub.3 CH.sub.34.930 H H H 2 H H H H C.dbd.N--CH.sub.3 CH.sub.3 CH.sub.34.931 H H H 0 H H H H C.dbd.NC.sub.2 H.sub.5 CH.sub.3 CH.sub.34.932 H H H 1 H H H H C.dbd.NC.sub.2 H.sub.5 CH.sub.3 CH.sub.34.933 H H H 2 H H H H C.dbd.NC.sub.2 H.sub.5 CH.sub.3 CH.sub.34.934 H H H 0 H H H H CH--NHCH.sub.3 CH.sub.3 CH.sub.34.935 H H H 1 H H H H CH--NHCH.sub.3 CH.sub.3 CH.sub.34.936 H H H 2 H H H H CH--NHCH.sub.3 CH.sub.3 CH.sub.34.937 H H H 0 H H H H CH--NHC.sub.2 H.sub.5 CH.sub.3 CH.sub.34.938 H H H 1 H H H H CH--NHC.sub.2 H.sub.5 CH.sub.3 CH.sub.34.939 H H H 2 H H H H CH--NHC.sub.2 H.sub.5 CH.sub.3 CH.sub.34.940 H H H 0 H H H H CH--N(CH.sub.3).sub.2 CH.sub.3 CH.sub.34.941 H H H 1 H H H H CH--N(CH.sub.3).sub.2 CH.sub.3 CH.sub.34.942 H H H 2 H H H H CH--N(CH.sub.3).sub.2 CH.sub.3 CH.sub.34.943 H H H 0 H H H H CH--NHOC.sub.2 H.sub.5 CH.sub.3 CH.sub.34.944 H H H 1 H H H H CH--NHOC.sub.2 H.sub.5 CH.sub.3 CH.sub.34.945 H H H 2 H H H H CH--NHOC.sub.2 H.sub.5 CH.sub.3 CH.sub.34.946 H H H 0 H H H H CH--N(CH.sub.3)OC.sub.2 H.sub.5 CH.sub.3 CH.sub.34.947 H H H 1 H H H H CH--N(CH.sub.3)OC.sub.2 H.sub.5 CH.sub.3 CH.sub.34.948 H H H 2 H H H H CH--N(CH.sub.3)OC.sub.2 H.sub.5 CH.sub.3 CH.sub.34.949 H H H 0 H H H H C.dbd.N--NH.sub.2 CH.sub.3 CH.sub.34.950 H H H 1 H H H H C.dbd.N--NH.sub.2 CH.sub.3 CH.sub.34.951 H H H 2 H H H H C.dbd.N--NH.sub.2 CH.sub.3 CH.sub.34.952 H H H 0 H H H H C.dbd.N--N(CH.sub.3).sub.2 CH.sub.3 CH.sub.34.953 H H H 1 H H H H C.dbd.N--N(CH.sub.3).sub.2 CH.sub.3 CH.sub.34.954 H H H 2 H H H H C.dbd.N--N(CH.sub.3).sub.2 CH.sub.3 CH.sub.34.955 H H H 0 H H H H CH--N(CH.sub.3)OCH.sub.2 C.sub.6 H.sub.5 CH.sub.3 CH.sub.34.956 H H H 1 H H H H CH--N(CH.sub.3)OCH.sub.2 C.sub.6 H.sub.5 CH.sub.3 CH.sub.34.957 H H H 2 H H H H CH--N(CH.sub.3)OCH.sub.2 C.sub.6 H.sub.5 CH.sub.3 CH.sub.34.958 H H H 0 H H H H C(CH.sub.3)--OCH.sub.3 CH.sub.3 CH.sub.34.959 H H H 1 H H H H C(CH.sub.3)--OCH.sub.3 CH.sub.3 CH.sub.34.960 H H H 2 H H H H C(CH.sub.3)--OCH.sub.3 CH.sub.3 CH.sub.34.961 H H H 0 H H H H O CH.sub.3 CH.sub.34.962 H H H 1 H H H H O CH.sub.3 CH.sub.34.963 H H H 2 H H H H O CH.sub.3 CH.sub.34.964 CH.sub.3 H H 0 H H H H C.dbd.O CH.sub.3 CH.sub.34.965 CH.sub.3 H H 1 H H H H C.dbd.O CH.sub.3 CH.sub.34.966 CH.sub.3 H H 2 H H H H C.dbd.O CH.sub.3 CH.sub.34.967 CH.sub.3 H H 0 H H H H CHOCH.sub.3 CH.sub.3 CH.sub.34.968 CH.sub.3 H H 1 H H H H CHOCH.sub.3 CH.sub.3 CH.sub.34.969 CH.sub.3 H H 2 H H H H CHOCH.sub.3 CH.sub.3 CH.sub.34.970 CH.sub.3 H H 0 H H H H CHOC.sub.2 H.sub.5 CH.sub.3 CH.sub.34.971 CH.sub.3 H H 1 H H H H CHOC.sub.2 H.sub.5 CH.sub.3 CH.sub.34.972 CH.sub.3 H H 2 H H H H CHOC.sub.2 H.sub.5 CH.sub.3 CH.sub.34.973 CH.sub.3 H H 0 H H H H CHOiPr CH.sub.3 CH.sub.34.974 CH.sub.3 H H 1 H H H H CHOiPr CH.sub.3 CH.sub.34.975 CH.sub.3 H H 2 H H H H CHOiPr CH.sub.3 CH.sub.34.976 CH.sub.3 H H 0 H H H H C.dbd.NOCH.sub.3 CH.sub.3 CH.sub.34.977 CH.sub.3 H H 1 H H H H C.dbd.NOCH.sub.3 CH.sub.3 CH.sub.34.978 CH.sub.3 H H 2 H H H H C.dbd.NOCH.sub.3 CH.sub.3 CH.sub.34.979 CH.sub.3 H H 0 H H H H C.dbd.NOC.sub.2 H.sub.5 CH.sub.3 CH.sub.34.980 CH.sub.3 H H 1 H H H H C.dbd.NOC.sub.2 H.sub.5 CH.sub.3 CH.sub.34.981 CH.sub.3 H H 2 H H H H C.dbd.NOC.sub.2 H.sub.5 CH.sub.3 CH.sub.34.982 CH.sub.3 H H 0 H H H H C.dbd.NOiPr CH.sub.3 CH.sub.34.983 CH.sub.3 H H 1 H H H H C.dbd.NOiPr CH.sub.3 CH.sub.34.984 CH.sub.3 H H 2 H H H H C.dbd.NOiPr CH.sub.3 CH.sub.34.985 CH.sub.3 H H 0 H H H H C.dbd.NOCH.sub.2 CH.dbd.CHCl CH.sub.3 CH.sub.34.986 CH.sub.3 H H 1 H H H H C.dbd.NOCH.sub.2 CH.dbd.CHCl CH.sub.3 CH.sub.34.987 CH.sub.3 H H 2 H H H H C.dbd.NOCH.sub.2 CH.dbd.CHCl CH.sub.3 CH.sub.34.988 CH.sub.3 H H 0 H H H H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 CH.sub.3 CH.sub.34.989 CH.sub.3 H H 1 H H H H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 CH.sub.3 CH.sub.34.990 CH.sub.3 H H 2 H H H H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 CH.sub.3 CH.sub.34.991 CH.sub.3 H H 0 H H H H C(CH.sub.3).sub.2 CH.sub.3 CH.sub.34.992 CH.sub.3 H H 1 H H H H C(CH.sub.3).sub.2 CH.sub.3 CH.sub.34.993 CH.sub.3 H H 2 H H H H C(CH.sub.3).sub.2 CH.sub.3 CH.sub.34.994 CH.sub.3 H H 0 H H H H ##STR96## CH.sub.3 CH.sub.34.995 CH.sub.3 H H 1 H H H H ##STR97## CH.sub.3 CH.sub.34.996 CH.sub.3 H H 2 H H H H ##STR98## CH.sub.3 CH.sub.34.997 CH.sub.3 H H 0 H H H H ##STR99## CH.sub.3 CH.sub.34.998 CH.sub.3 H H 1 H H H H ##STR100## CH.sub.3 CH.sub.34.999 CH.sub.3 H H 2 H H H H ##STR101## CH.sub.3 CH.sub.34.1000 CH.sub.3 H H 0 H H H H C.dbd.N--CH.sub.3 CH.sub.3 CH.sub.34.1001 CH.sub.3 H H 1 H H H H C.dbd.N--CH.sub.3 CH.sub.3 CH.sub.34.1002 CH.sub.3 H H 2 H H H H C.dbd.N--CH.sub.3 CH.sub.3 CH.sub.34.1003 CH.sub.3 H H 0 H H H H C.dbd.NC.sub.2 H.sub.5 CH.sub.3 CH.sub.34.1004 CH.sub.3 H H 1 H H H H C.dbd.NC.sub.2 H.sub.5 CH.sub.3 CH.sub.34.1005 CH.sub.3 H H 2 H H H H C.dbd.NC.sub.2 H.sub.5 CH.sub.3 CH.sub.34.1006 CH.sub.3 H H 0 H H H H CH--NHCH.sub.3 CH.sub.3 CH.sub.34.1007 CH.sub.3 H H 1 H H H H CH--NHCH.sub.3 CH.sub.3 CH.sub.34.1008 CH.sub.3 H H 2 H H H H CH--NHCH.sub.3 CH.sub.3 CH.sub.34.1009 CH.sub.3 H H 0 H H H H CH--NHC.sub.2 H.sub.5 CH.sub.3 CH.sub.34.1010 CH.sub.3 H H 1 H H H H CH--NHC.sub.2 H.sub.5 CH.sub.3 CH.sub.34.1011 CH.sub.3 H H 2 H H H H CH--NHC.sub.2 H.sub.5 CH.sub.3 CH.sub.34.1012 CH.sub.3 H H 0 H H H H CH--N(CH.sub.3).sub.2 CH.sub.3 CH.sub.34.1013 CH.sub.3 H H 1 H H H H CH--N(CH.sub.3).sub.2 CH.sub.3 CH.sub.34.1014 CH.sub.3 H H 2 H H H H CH--N(CH.sub.3).sub.2 CH.sub.3 CH.sub.34.1015 CH.sub.3 H H 0 H H H H CH--NHOC.sub.2 H.sub.5 CH.sub.3 CH.sub.34.1016 CH.sub.3 H H 1 H H H H CH--NHOC.sub.2 H.sub.5 CH.sub.3 CH.sub.34.1017 CH.sub.3 H H 2 H H H H CH--NHOC.sub.2 H.sub.5 CH.sub.3 CH.sub.34.1018 CH.sub.3 H H 0 H H H H CH--N(CH.sub.3)OC.sub.2 H.sub.5 CH.sub.3 CH.sub.34.1019 CH.sub.3 H H 1 H H H H CH--N(CH.sub.3)OC.sub.2 H.sub.5 CH.sub.3 CH.sub.34.1020 CH.sub.3 H H 2 H H H H CH--N(CH.sub.3)OC.sub.2 H.sub.5 CH.sub.3 CH.sub.34.1021 CH.sub.3 H H 0 H H H H C.dbd.N--NH.sub.2 CH.sub.3 CH.sub.34.1022 CH.sub.3 H H 1 H H H H C.dbd.N--NH.sub.2 CH.sub.3 CH.sub.34.1023 CH.sub.3 H H 2 H H H H C.dbd.N--NH.sub.2 CH.sub.3 CH.sub.34.1024 CH.sub.3 H H 0 H H H H C.dbd.N--N(CH.sub.3).sub.2 CH.sub.3 CH.sub.34.1025 CH.sub.3 H H 1 H H H H C.dbd.N--N(CH.sub.3).sub.2 CH.sub.3 CH.sub.34.1026 CH.sub.3 H H 2 H H H H C.dbd.N--N(CH.sub.3).sub.2 CH.sub.3 CH.sub.34.1027 CH.sub.3 H H 0 H H H H CH--N(CH.sub.3)OCH.sub.2 C.sub.6 H.sub.5 CH.sub.3 CH.sub.34.1028 CH.sub.3 H H 1 H H H H CH--N(CH.sub.3)OCH.sub.2 C.sub.6 H.sub.5 CH.sub.3 CH.sub.34.1029 CH.sub.3 H H 2 H H H H CH--N(CH.sub.3)OCH.sub.2 C.sub.6 H.sub.5 CH.sub.3 CH.sub.34.1030 CH.sub.3 H H 0 H H H H C(CH.sub.3)--OCH.sub.3 CH.sub.3 CH.sub.34.1031 CH.sub.3 H H 1 H H H H C(CH.sub.3)--OCH.sub.3 CH.sub.3 CH.sub.34.1032 CH.sub.3 H H 2 H H H H C(CH.sub.3)--OCH.sub.3 CH.sub.3 CH.sub.34.1033 CH.sub.3 H H 0 H H H H O CH.sub.3 CH.sub.34.1034 CH.sub.3 H H 1 H H H H O CH.sub.3 CH.sub.34.1035 CH.sub.3 H H 2 H H H H O CH.sub.3 CH.sub.34.1036 CH.sub.3 CH.sub.3 H 0 H H H H C.dbd.O CH.sub.3 CH.sub.34.1037 CH.sub.3 CH.sub.3 H 1 H H H H C.dbd.O CH.sub.3 CH.sub.34.1038 CH.sub.3 CH.sub.3 H 2 H H H H C.dbd.O CH.sub.3 CH.sub.34.1039 CH.sub.3 CH.sub.3 H 0 H H H H CHOCH.sub.3 CH.sub.3 CH.sub.34.1040 CH.sub.3 CH.sub.3 H 1 H H H H CHOCH.sub.3 CH.sub.3 CH.sub.34.1041 CH.sub.3 CH.sub.3 H 2 H H H H CHOCH.sub.3 CH.sub.3 CH.sub.34.1042 CH.sub.3 CH.sub.3 H 0 H H H H CHOC.sub.2 H.sub.5 CH.sub.3 CH.sub.34.1043 CH.sub.3 CH.sub.3 H 1 H H H H CHOC.sub.2 H.sub.5 CH.sub.3 CH.sub.34.1044 CH.sub.3 CH.sub.3 H 2 H H H H CHOC.sub.2 H.sub.5 CH.sub.3 CH.sub.34.1045 CH.sub.3 CH.sub.3 H 0 H H H H CHOiPr CH.sub.3 CH.sub.34.1046 CH.sub.3 CH.sub.3 H 1 H H H H CHOiPr CH.sub.3 CH.sub.34.1047 CH.sub.3 CH.sub.3 H 2 H H H H CHOiPr CH.sub.3 CH.sub.34.1048 CH.sub.3 CH.sub.3 H 0 H H H H C.dbd.NOCH.sub.3 CH.sub.3 CH.sub.34.1049 CH.sub.3 CH.sub.3 H 1 H H H H C.dbd.NOCH.sub.3 CH.sub.3 CH.sub.34.1050 CH.sub.3 CH.sub.3 H 2 H H H H C.dbd.NOCH.sub.3 CH.sub.3 CH.sub.34.1051 CH.sub.3 CH.sub.3 H 0 H H H H C.dbd.NOC.sub.2 H.sub.5 CH.sub.3 CH.sub.34.1052 CH.sub.3 CH.sub.3 H 1 H H H H C.dbd.NOC.sub.2 H.sub.5 CH.sub.3 CH.sub.34.1053 CH.sub.3 CH.sub.3 H 2 H H H H C.dbd.NOC.sub.2 H.sub.5 CH.sub.3 CH.sub.34.1054 CH.sub.3 CH.sub.3 H 0 H H H H C.dbd.NOiPr CH.sub.3 CH.sub.34.1055 CH.sub.3 CH.sub.3 H 1 H H H H C.dbd.NOiPr CH.sub.3 CH.sub.34.1056 CH.sub.3 CH.sub.3 H 2 H H H H C.dbd.NOiPr CH.sub.3 CH.sub.34.1057 CH.sub.3 CH.sub.3 H 0 H H H H C.dbd.NOCH.sub.2 CH.dbd.CHCl CH.sub.3 CH.sub.34.1058 CH.sub.3 CH.sub.3 H 1 H H H H C.dbd.NOCH.sub.2 CH.dbd.CHCl CH.sub.3 CH.sub.34.1059 CH.sub.3 CH.sub.3 H 2 H H H H C.dbd.NOCH.sub.2 CH.dbd.CHCl CH.sub.3 CH.sub.34.1060 CH.sub.3 CH.sub.3 H 1 H H H H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 CH.sub.3 CH.sub.34.1061 CH.sub.3 CH.sub.3 H 0 H H H H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 CH.sub.3 CH.sub.34.1062 CH.sub.3 CH.sub.3 H 1 H H H H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 CH.sub.3 CH.sub.34.1063 CH.sub.3 CH.sub.3 H 0 H H H H C(CH.sub.3).sub.2 CH.sub.3 CH.sub.34.1064 CH.sub.3 CH.sub.3 H 1 H H H H C(CH.sub.3).sub.2 CH.sub.3 CH.sub.34.1065 CH.sub.3 CH.sub.3 H 2 H H H H C(CH.sub.3).sub.2 CH.sub.3 CH.sub.34.1066 CH.sub.3 CH.sub.3 H 0 H H H H ##STR102## CH.sub.3 CH.sub.34.1067 CH.sub.3 CH.sub.3 H 1 H H H H ##STR103## CH.sub.3 CH.sub.34.1068 CH.sub.3 CH.sub.3 H 2 H H H H ##STR104## CH.sub.3 CH.sub.34.1069 CH.sub.3 CH.sub.3 H 0 H H H H ##STR105## CH.sub.3 CH.sub.34.1070 CH.sub.3 CH.sub.3 H 1 H H H H ##STR106## CH.sub.3 CH.sub.34.1071 CH.sub.3 CH.sub.3 H 2 H H H H ##STR107## CH.sub.3 CH.sub.34.1072 CH.sub.3 CH.sub.3 H 0 H H H H C.dbd.N--CH.sub.3 CH.sub.3 CH.sub.34.1073 CH.sub.3 CH.sub.3 H 1 H H H H C.dbd.N--CH.sub.3 CH.sub.3 CH.sub.34.1074 CH.sub.3 CH.sub.3 H 2 H H H H C.dbd.N--CH.sub.3 CH.sub.3 CH.sub.34.1075 CH.sub.3 CH.sub.3 H 0 H H H H C.dbd.NC.sub.2 H.sub.5 CH.sub.3 CH.sub.34.1076 CH.sub.3 CH.sub.3 H 1 H H H H C.dbd.NC.sub.2 H.sub.5 CH.sub.3 CH.sub.34.1077 CH.sub.3 CH.sub.3 H 2 H H H H C.dbd.NC.sub.2 H.sub.5 CH.sub.3 CH.sub.34.1078 CH.sub.3 CH.sub.3 H 0 H H H H CH--NHCH.sub.3 CH.sub.3 CH.sub.34.1079 CH.sub.3 CH.sub.3 H 1 H H H H CH--NHCH.sub.3 CH.sub.3 CH.sub.34.1080 CH.sub.3 CH.sub.3 H 2 H H H H CH--NHCH.sub.3 CH.sub.3 CH.sub.34.1081 CH.sub.3 CH.sub.3 H 0 H H H H CH--NHC.sub.2 H.sub.5 CH.sub.3 CH.sub.34.1082 CH.sub.3 CH.sub.3 H 1 H H H H CH--NHC.sub.2 H.sub.5 CH.sub.3 CH.sub.34.1083 CH.sub.3 CH.sub.3 H 2 H H H H CH--NHC.sub.2 H.sub.5 CH.sub.3 CH.sub.34.1084 CH.sub.3 CH.sub.3 H 0 H H H H CH--N(CH.sub.3).sub.2 CH.sub.3 CH.sub.34.1085 CH.sub.3 CH.sub.3 H 1 H H H H CH--N(CH.sub.3).sub.2 CH.sub.3 CH.sub.34.1086 CH.sub.3 CH.sub.3 H 2 H H H H CH--N(CH.sub.3).sub.2 CH.sub.3 CH.sub.34.1087 CH.sub.3 CH.sub.3 H 0 H H H H CH--NHOC.sub.2 H.sub.5 CH.sub.3 CH.sub.34.1088 CH.sub.3 CH.sub.3 H 1 H H H H CH--NHOC.sub.2 H.sub.5 CH.sub.3 CH.sub.34.1089 CH.sub.3 CH.sub.3 H 2 H H H H CH--NHOC.sub.2 H.sub.5 CH.sub.3 CH.sub.34.1090 CH.sub.3 CH.sub.3 H 0 H H H H CH--N(CH.sub.3)OC.sub.2 H.sub.5 CH.sub.3 CH.sub.34.1091 CH.sub.3 CH.sub.3 H 1 H H H H CH--N(CH.sub.3)OC.sub.2 H.sub.5 CH.sub.3 CH.sub.34.1092 CH.sub.3 CH.sub.3 H 2 H H H H CH--N(CH.sub.3)OC.sub.2 H.sub.5 CH.sub.3 CH.sub.34.1093 CH.sub.3 CH.sub.3 H 0 H H H H C.dbd.N--NH.sub.2 CH.sub.3 CH.sub.34.1094 CH.sub.3 CH.sub.3 H 1 H H H H C.dbd.N--NH.sub.2 CH.sub.3 CH.sub.34.1095 CH.sub.3 CH.sub.3 H 2 H H H H C.dbd.N--NH.sub.2 CH.sub.3 CH.sub.34.1096 CH.sub.3 CH.sub.3 H 0 H H H H C.dbd.N--N(CH.sub.3).sub.2 CH.sub.3 CH.sub.34.1097 CH.sub.3 CH.sub.3 H 1 H H H H C.dbd.N--N(CH.sub.3).sub.2 CH.sub.3 CH.sub.34.1098 CH.sub.3 CH.sub.3 H 2 H H H H C.dbd.N--N(CH.sub.3).sub.2 CH.sub.3 CH.sub.34.1099 CH.sub.3 CH.sub.3 H 0 H H H H CH--N(CH.sub.3)OCH.sub.2 C.sub.6 H.sub.5 CH.sub.3 CH.sub.34.1100 CH.sub.3 CH.sub.3 H 1 H H H H CH--N(CH.sub.3)OCH.sub.2 C.sub.6 H.sub.5 CH.sub.3 CH.sub.34.1101 CH.sub.3 CH.sub.3 H 2 H H H H CH--N(CH.sub.3)OCH.sub.2 C.sub.6 H.sub.5 CH.sub.3 CH.sub.34.1102 CH.sub.3 CH.sub.3 H 0 H H H H C(CH.sub.3)--OCH.sub.3 CH.sub.3 CH.sub.34.1103 CH.sub.3 CH.sub.3 H 1 H H H H C(CH.sub.3)--OCH.sub.3 CH.sub.3 CH.sub.34.1104 CH.sub.3 CH.sub.3 H 2 H H H H C(CH.sub.3)--OCH.sub.3 CH.sub.3 CH.sub.34.1105 CH.sub.3 CH.sub.3 H 0 H H H H O CH.sub.3 CH.sub.34.1106 CH.sub.3 CH.sub.3 H 1 H H H H O CH.sub.3 CH.sub.34.1107 CH.sub.3 CH.sub.3 H 2 H H H H O CH.sub.3 CH.sub.34.1108 H H H 0 H H H H C.dbd.O Cl Cl4.1109 H H H 1 H H H H C.dbd.O Cl Cl4.1110 H H H 2 H H H H C.dbd.O Cl Cl4.1111 H H H 0 H H H H CHOCH.sub.3 Cl Cl4.1112 H H H 1 H H H H CHOCH.sub.3 Cl Cl4.1113 H H H 2 H H H H CHOCH.sub.3 Cl Cl4.1114 H H H 0 H H H H CHOC.sub.2 H.sub.5 Cl Cl4.1115 H H H 1 H H H H CHOC.sub.2 H.sub.5 Cl Cl4.1116 H H H 2 H H H H CHOC.sub.2 H.sub.5 Cl Cl4.1117 H H H 0 H H H H CHOiPr Cl Cl4.1118 H H H 1 H H H H CHOiPr Cl Cl4.1119 H H H 2 H H H H CHOiPr Cl Cl4.1120 H H H 0 H H H H C.dbd.NOCH.sub.3 Cl Cl4.1121 H H H 1 H H H H C.dbd.NOCH.sub.3 Cl Cl4.1122 H H H 2 H H H H C.dbd.NOCH.sub.3 Cl Cl4.1123 H H H 0 H H H H C.dbd.NOC.sub.2 H.sub.5 Cl Cl4.1124 H H H 1 H H H H C.dbd.NOC.sub.2 H.sub.5 Cl Cl4.1125 H H H 2 H H H H C.dbd.NOC.sub.2 H.sub.5 Cl Cl4.1126 H H H 0 H H H H C.dbd.NOiPr Cl Cl4.1127 H H H 1 H H H H C.dbd.NOiPr Cl Cl4.1128 H H H 2 H H H H C.dbd.NOiPr Cl Cl4.1129 H H H 0 H H H H C.dbd.NOCH.sub.2 CH.dbd.CHCl Cl Cl4.1130 H H H 1 H H H H C.dbd.NOCH.sub.2 CH.dbd.CHCl Cl Cl4.1131 H H H 2 H H H H C.dbd.NOCH.sub.2 CH.dbd.CHCl Cl Cl4.1132 H H H 0 H H H H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 Cl Cl4.1133 H H H 1 H H H H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 Cl Cl4.1134 H H H 2 H H H H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 Cl Cl4.1135 H H H 0 H H H H C(CH.sub.3).sub.2 Cl Cl4.1136 H H H 1 H H H H C(CH.sub.3).sub.2 Cl Cl4.1137 H H H 2 H H H H C(CH.sub.3).sub.2 Cl Cl4.1138 H H H 0 H H H H ##STR108## Cl Cl4.1139 H H H 1 H H H H ##STR109## Cl Cl4.1140 H H H 2 H H H H ##STR110## Cl Cl4.1141 H H H 0 H H H H ##STR111## Cl Cl4.1142 H H H 1 H H H H ##STR112## Cl Cl4.1143 H H H 2 H H H H ##STR113## Cl Cl4.1144 H H H 0 H H H H C.dbd.N--CH.sub.3 Cl Cl4.1145 H H H 1 H H H H C.dbd.N--CH.sub.3 Cl Cl4.1146 H H H 2 H H H H C.dbd.N--CH.sub.3 Cl Cl4.1147 H H H 0 H H H H C.dbd.NC.sub.2 H.sub.5 Cl Cl4.1148 H H H 1 H H H H C.dbd.NC.sub.2 H.sub.5 Cl Cl4.1149 H H H 2 H H H H C.dbd.NC.sub.2 H.sub.5 Cl Cl4.1150 H H H 0 H H H H CH--NHCH.sub.3 Cl Cl4.1151 H H H 1 H H H H CH--NHCH.sub.3 Cl Cl4.1152 H H H 2 H H H H CH--NHCH.sub.3 Cl Cl4.1153 H H H 0 H H H H CH--NHC.sub.2 H.sub.5 Cl Cl4.1154 H H H 1 H H H H CH--NHC.sub.2 H.sub.5 Cl Cl4.1155 H H H 2 H H H H CH--NHC.sub.2 H.sub.5 Cl Cl4.1156 H H H 0 H H H H CH--N(CH.sub.3).sub.2 Cl Cl4.1157 H H H 1 H H H H CH--N(CH.sub.3).sub.2 Ci Cl4.1158 H H H 2 H H H H CH--N(CH.sub.3).sub.2 Cl Cl4.1159 H H H 0 H H H H CH--NHOC.sub.2 H.sub.5 Cl Cl4.1160 H H H 1 H H H H CH--NHOC.sub.2 H.sub.5 Cl Cl4.1161 H H H 2 H H H H CH--NHOC.sub.2 H.sub.5 Cl Cl4.1162 H H H 0 H H H H CH--N(CH.sub.3)OC.sub.2 H.sub.5 Cl Cl4.1163 H H H 1 H H H H CH--N(CH.sub.3)OC.sub.2 H.sub.5 Cl Cl4.1164 H H H 2 H H H H CH--N(CH.sub.3)OC.sub.2 H.sub.5 Cl Cl4.1165 H H H 0 H H H H C.dbd.N--NH.sub.2 Cl Cl4.1166 H H H 1 H H H H C.dbd.N--NH.sub.2 Cl Cl4.1167 H H H 2 H H H H C.dbd.N--NH.sub.2 Cl Cl4.1168 H H H 0 H H H H C.dbd.N--N(CH.sub.3).sub.2 Cl Cl4.1169 H H H 1 H H H H C.dbd.N--N(CH.sub.3).sub.2 Cl Cl4.1170 H H H 2 H H H H C.dbd.N--N(CH.sub.3).sub.2 Cl Cl4.1171 H H H 0 H H H H CH--N(CH.sub.3)OCH.sub.2 C.sub.6 H.sub.5 Cl Cl4.1172 H H H 1 H H H H CH--N(CH.sub.3)OCH.sub.2 C.sub.6 H.sub.5 Cl Cl4.1173 H H H 2 H H H H CH--N(CH.sub.3)OCH.sub.2 C.sub.6 H.sub.5 Cl Cl4.1174 H H H 0 H H H H C(CH.sub.3)--OCH.sub.3 Cl Cl4.1175 H H H 1 H H H H C(CH.sub.3)--OCH.sub.3 Cl Cl4.1176 H H H 2 H H H H C(CH.sub.3)--OCH.sub.3 Cl Cl4.1177 H H H 0 H H H H O Cl Cl4.1178 H H H 1 H H H H O Cl Cl4.1179 H H H 2 H H H H O Cl Cl4.1180 CH.sub.3 H H 0 H H H H C.dbd.O Cl Cl4.1181 CH.sub.3 H H 1 H H H H C.dbd.O Cl Cl4.1182 CH.sub.3 H H 2 H H H H C.dbd.O Cl Cl4.1183 CH.sub.3 H H 0 H H H H CHOCH.sub.3 Cl Cl4.1184 CH.sub.3 H H 1 H H H H CHOCH.sub.3 Cl Cl4.1185 CH.sub.3 H H 2 H H H H CHOCH.sub.3 Cl Cl4.1186 CH.sub.3 H H 0 H H H H CHOC.sub.2 H.sub.5 Cl Cl4.1187 CH.sub.3 H H 1 H H H H CHOC.sub.2 H.sub.5 Cl Cl4.1188 CH.sub.3 H H 2 H H H H CHOC.sub.2 H.sub.5 Cl Cl4.1189 CH.sub.3 H H 0 H H H H CHOiPr Cl Cl4.1190 CH.sub.3 H H 1 H H H H CHOiPr Cl Cl4.1191 CH.sub.3 H H 2 H H H H CHOiPr Cl Cl4.1192 CH.sub.3 H H 0 H H H H C.dbd.NOCH.sub.3 Cl Cl4.1193 CH.sub.3 H H 1 H H H H C.dbd.NOCH.sub.3 Cl Cl4.1194 CH.sub.3 H H 2 H H H H C.dbd.NOCH.sub.3 Cl Cl4.1195 CH.sub.3 H H 0 H H H H C.dbd.NOC.sub.2 H.sub.5 Cl Cl4.1196 CH.sub.3 H H 1 H H H H C.dbd.NOC.sub.2 H.sub.5 Cl Cl4.1197 CH.sub.3 H H 2 H H H H C.dbd.NOC.sub.2 H.sub.5 Cl Cl4.1198 CH.sub.3 H H 0 H H H H C.dbd.NOiPr Cl Cl4.1199 CH.sub.3 H H 1 H H H H C.dbd.NOiPr Cl Cl4.1200 CH.sub.3 H H 2 H H H H C.dbd.NOiPr Cl Cl4.1201 CH.sub.3 H H 0 H H H H C.dbd.NOCH.sub.2 CH.dbd.CHCl Cl Cl4.1202 CH.sub.3 H H 1 H H H H C.dbd.NOCH.sub.2 CH.dbd.CHCl Cl Cl4.1203 CH.sub.3 H H 2 H H H H C.dbd.NOCH.sub.2 CH.dbd.CHCl Cl Cl4.1204 CH.sub.3 H H 0 H H H H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 Cl Cl4.1205 CH.sub.3 H H 1 H H H H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 Cl Cl4.1206 CH.sub.3 H H 2 H H H H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 Cl Cl4.1207 CH.sub.3 H H 0 H H H H C(CH.sub.3).sub.2 Cl Cl4.1208 CH.sub.3 H H 1 H H H H C(CH.sub.3).sub.2 Cl Cl4.1209 CH.sub.3 H H 2 H H H H C(CH.sub.3).sub.2 Cl Cl4.1210 CH.sub.3 H H 0 H H H H ##STR114## Cl Cl4.1211 CH.sub.3 H H 1 H H H H ##STR115## Cl Cl4.1212 CH.sub.3 H H 2 H H H H ##STR116## Cl Cl4.1213 CH.sub.3 H H 0 H H H H ##STR117## Cl Cl4.1214 CH.sub.3 H H 1 H H H H ##STR118## Cl Cl4.1215 CH.sub.3 H H 2 H H H H ##STR119## Cl Cl4.1216 CH.sub.3 H H 0 H H H H C.dbd.N--CH.sub.3 Cl Cl4.1217 CH.sub.3 H H 1 H H H H C.dbd.N--CH.sub.3 Cl Cl4.1218 CH.sub.3 H H 2 H H H H C.dbd.N--CH.sub.3 Cl Cl4.1219 CH.sub.3 H H 0 H H H H C.dbd.NC.sub.2 H.sub.5 Cl Cl4.1220 CH.sub.3 H H 1 H H H H C.dbd.NC.sub.2 H.sub.5 Cl Cl4.1221 CH.sub.3 H H 2 H H H H C.dbd.NC.sub.2 H.sub.5 Cl Cl4.1222 CH.sub.3 H H 0 H H H H CH--NHCH.sub.3 Cl Cl4.1223 CH.sub.3 H H 1 H H H H CH--NHCH.sub.3 Cl Cl4.1224 CH.sub.3 H H 2 H H H H CH--NHCH.sub.3 Cl Cl4.1225 CH.sub.3 H H 0 H H H H CH--NHC.sub.2 H.sub.5 Cl Cl4.1226 CH.sub.3 H H 1 H H H H CH--NHC.sub.2 H.sub.5 Cl Cl4.1227 CH.sub.3 H H 2 H H H H CH--NHC.sub.2 H.sub.5 Cl Cl4.1228 CH.sub.3 H H 0 H H H H CH--N(CH.sub.3).sub.2 Cl Cl4.1229 CH.sub.3 H H 1 H H H H CH--N(CH.sub.3).sub.2 Cl Cl4.1230 CH.sub.3 H H 2 H H H H CH--N(CH.sub.3).sub.2 Cl Cl4.1231 CH.sub.3 H H 0 H H H H CH--NHOC.sub.2 H.sub.5 Cl Cl4.1232 CH.sub.3 H H 1 H H H H CH--NHOC.sub.2 H.sub.5 Cl Cl4.1233 CH.sub.3 H H 2 H H H H CH--NHOC.sub.2 H.sub.5 Cl Cl4.1234 CH.sub.3 H H 0 H H H H CH--N(CH.sub.3)OC.sub.2 H.sub.5 Cl Cl4.1235 CH.sub.3 H H 1 H H H H CH--N(CH.sub.3)OC.sub.2 H.sub.5 Cl Cl4.1236 CH.sub.3 H H 2 H H H H CH--N(CH.sub.3)OC.sub.2 H.sub.5 Cl Cl4.1237 CH.sub.3 H H 0 H H H H C.dbd.N--NH.sub.2 Cl Cl4.1238 CH.sub.3 H H 1 H H H H C.dbd.N--NH.sub.2 Cl Cl4.1239 CH.sub.3 H H 2 H H H H C.dbd.N--NH.sub.2 Cl Cl4.1240 CH.sub.3 H H 0 H H H H C.dbd.N--N(CH.sub.3).sub.2 Cl Cl4.1241 CH.sub.3 H H 1 H H H H C.dbd.N--N(CH.sub.3).sub.2 Cl Cl4.1242 CH.sub.3 H H 2 H H H H C.dbd.N--N(CH.sub.3).sub.2 Cl Cl4.1243 CH.sub.3 H H 0 H H H H CH--N(CH.sub.3)OCH.sub.2 C.sub.6 H.sub.5 Cl Cl4.1244 CH.sub.3 H H 1 H H H H CH--N(CH.sub.3)OCH.sub.2 C.sub.6 H.sub.5 Cl Cl4.1245 CH.sub.3 H H 2 H H H H CH--N(CH.sub.3)OCH.sub.2 C.sub.6 H.sub.5 Cl Cl4.1246 CH.sub.3 H H 0 H H H H C(CH.sub.3)--OCH.sub.3 Cl Cl4.1247 CH.sub.3 H H 1 H H H H C(CH.sub.3)--OCH.sub.3 Cl Cl4.1248 CH.sub.3 H H 2 H H H H C(CH.sub.3)--OCH.sub.3 Cl Cl4.1249 CH.sub.3 H H 0 H H H H O Cl Cl4.1250 CH.sub.3 H H 1 H H H H O Cl Cl4.1251 CH.sub.3 H H 2 H H H H O Cl Cl4.1252 CH.sub.3 CH.sub.3 H 0 H H H H C.dbd.O Cl Cl4.1253 CH.sub.3 CH.sub.3 H 1 H H H H C.dbd.O Cl Cl4.1254 CH.sub.3 CH.sub.3 H 2 H H H H C.dbd.O Cl Cl4.1255 CH.sub.3 CH.sub.3 H 0 H H H H CHOCH.sub.3 Cl Cl4.1256 CH.sub.3 CH.sub.3 H 1 H H H H CHOCH.sub.3 Cl Cl4.1257 CH.sub.3 CH.sub.3 H 2 H H H H CHOCH.sub.3 Cl Cl4.1258 CH.sub.3 CH.sub.3 H 0 H H H H CHOC.sub.2 H.sub.5 Cl Cl4.1259 CH.sub.3 CH.sub.3 H 1 H H H H CHOC.sub.2 H.sub.5 Cl Cl4.1260 CH.sub.3 CH.sub.3 H 2 H H H H CHOC.sub.2 H.sub.5 Cl Cl4.1261 CH.sub.3 CH.sub.3 H 0 H H H H CHOiPr Cl Cl4.1262 CH.sub.3 CH.sub.3 H 1 H H H H CHOiPr Cl Cl4.1263 CH.sub.3 CH.sub.3 H 2 H H H H CHOiPr Cl Cl4.1264 CH.sub.3 CH.sub.3 H 0 H H H H C.dbd.NOCH.sub.3 Cl Cl4.1265 CH.sub.3 CH.sub.3 H 1 H H H H C.dbd.NOCH.sub.3 Cl Cl4.1266 CH.sub.3 CH.sub.3 H 2 H H H H C.dbd.NOCH.sub.3 Cl Cl4.1267 CH.sub.3 CH.sub.3 H 0 H H H H C.dbd.NOC.sub.2 H.sub.5 Cl Cl4.1268 CH.sub.3 CH.sub.3 H 1 H H H H C.dbd.NOC.sub.2 H.sub.5 Cl Cl4.1269 CH.sub.3 CH.sub.3 H 2 H H H H C.dbd.NOC.sub.2 H.sub.5 Cl Cl4.1270 CH.sub.3 CH.sub.3 H 0 H H H H C.dbd.NOiPr Cl Cl4.1271 CH.sub.3 CH.sub.3 H 1 H H H H C.dbd.NOiPr Cl Cl4.1272 CH.sub.3 CH.sub.3 H 2 H H H H C.dbd.NOiPr Cl Cl4.1273 CH.sub.3 CH.sub.3 H 0 H H H H C.dbd.NOCH.sub.2 CH.dbd.CHCl Cl Cl4.1274 CH.sub.3 CH.sub.3 H 1 H H H H C.dbd.NOCH.sub.2 CH.dbd.CHCl Cl Cl4.1275 CH.sub.3 CH.sub.3 H 2 H H H H C.dbd.NOCH.sub.2 CH.dbd.CHCl Cl Cl4.1276 CH.sub.3 CH.sub.3 H 0 H H H H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 Cl Cl4.1277 CH.sub.3 CH.sub.3 H 1 H H H H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 Cl Cl4.1278 CH.sub.3 CH.sub.3 H 2 H H H H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 Cl Cl4.1279 CH.sub.3 CH.sub.3 H 0 H H H H C(CH.sub.3).sub.2 Cl Cl4.1280 CH.sub.3 CH.sub.3 H 1 H H H H C(CH.sub.3).sub.2 Cl Cl4.1281 CH.sub.3 CH.sub.3 H 2 H H H H C(CH.sub.3).sub.2 Cl Cl4.1282 CH.sub.3 CH.sub.3 H 0 H H H H ##STR120## Cl Cl4.1283 CH.sub.3 CH.sub.3 H 1 H H H H ##STR121## Cl Cl4.1284 CH.sub.3 CH.sub.3 H 2 H H H H ##STR122## Cl Cl4.1285 CH.sub.3 CH.sub.3 H 0 H H H H ##STR123## Cl Cl4.1286 CH.sub.3 CH.sub.3 H 1 H H H H ##STR124## Cl Cl4.1287 CH.sub.3 CH.sub.3 H 2 H H H H ##STR125## Cl Cl4.1288 CH.sub.3 CH.sub.3 H 0 H H H H C.dbd.N--CH.sub.3 Cl Cl4.1289 CH.sub.3 CH.sub.3 H 1 H H H H C.dbd.N--CH.sub.3 Cl Cl4.1290 CH.sub.3 CH.sub.3 H 2 H H H H C.dbd.N--CH.sub.3 Cl Cl4.1291 CH.sub.3 CH.sub.3 H 0 H H H H C.dbd.NC.sub.2 H.sub.5 Cl Cl4.1292 CH.sub.3 CH.sub.3 H 1 H H H H C.dbd.NC.sub.2 H.sub.5 Cl Cl4.1293 CH.sub.3 CH.sub.3 H 2 H H H H C.dbd.NC.sub.2 H.sub.5 Cl Cl4.1294 CH.sub.3 CH.sub.3 H 0 H H H H CH--NHCH.sub.3 Cl Cl4.1295 CH.sub.3 CH.sub.3 H 1 H H H H CH--NHCH.sub.3 Cl Cl4.1296 CH.sub.3 CH.sub.3 H 2 H H H H CH--NHCH.sub.3 Cl Cl4.1297 CH.sub.3 CH.sub.3 H 0 H H H H CH--NHC.sub.2 H.sub.5 Cl Cl4.1298 CH.sub.3 CH.sub.3 H 1 H H H H CH--NHC.sub.2 H.sub.5 Cl Cl4.1299 CH.sub.3 CH.sub.3 H 2 H H H H CH--NHC.sub.2 H.sub.5 Cl Cl4.1300 CH.sub.3 CH.sub.3 H 0 H H H H CH--N(CH.sub.3).sub.2 Cl Cl4.1301 CH.sub.3 CH.sub.3 H 1 H H H H CH--N(CH.sub.3).sub.2 Cl Cl4.1302 CH.sub.3 CH.sub.3 H 2 H H H H CH--N(CH.sub.3).sub.2 Cl Cl4.1303 CH.sub.3 CH.sub.3 H 0 H H H H CH--NHOC.sub.2 H.sub.5 Cl Cl4.1304 CH.sub.3 CH.sub.3 H 1 H H H H CH--NHOC.sub.2 H.sub.5 Cl Cl4.1305 CH.sub.3 CH.sub.3 H 2 H H H H CH--NHOC.sub.2 H.sub.5 Cl Cl4.1306 CH.sub.3 CH.sub.3 H 0 H H H H CH--N(CH.sub.3)OC.sub.2 H.sub.5 Cl Cl4.1307 CH.sub.3 CH.sub.3 H 1 H H H H CH--N(CH.sub.3)OC.sub.2 H.sub.5 Cl Cl4.1308 CH.sub.3 CH.sub.3 H 2 H H H H CH--N(CH.sub.3)OC.sub.2 H.sub.5 Cl Cl4.1309 CH.sub.3 CH.sub.3 H 0 H H H H C.dbd.N--NH.sub.2 Cl Cl4.1310 CH.sub.3 CH.sub.3 H 1 H H H H C.dbd.N--NH.sub.2 Cl Cl4.1311 CH.sub.3 CH.sub.3 H 2 H H H H C.dbd.N--NH.sub.2 Cl Cl4.1312 CH.sub.3 CH.sub.3 H 0 H H H H C.dbd.N--N(CH.sub.3).sub.2 Cl Cl4.1313 CH.sub.3 CH.sub.3 H 1 H H H H C.dbd.N--N(CH.sub.3).sub.2 Cl Cl4.1314 CH.sub.3 CH.sub.3 H 2 H H H H C.dbd.N--N(CH.sub.3).sub.2 Cl Cl4.1315 CH.sub.3 CH.sub.3 H 0 H H H H CH--N(CH.sub.3)OCH.sub.2 C.sub.6 H.sub.5 Cl Cl4.1316 CH.sub.3 CH.sub.3 H 1 H H H H CH--N(CH.sub.3)OCH.sub.2 C.sub.6 H.sub.5 Cl Cl4.1317 CH.sub.3 CH.sub.3 H 2 H H H H CH--N(CH.sub.3)OCH.sub.2 C.sub.6 H.sub.5 Cl Cl4.1 CH.sub.3 CH.sub.3 H 0 H H H H C(CH.sub.3)--OCH.sub.3 Cl Cl4.2 CH.sub.3 CH.sub.3 H 1 H H H H C(CH.sub.3)--OCH.sub.3 Cl Cl4.3 CH.sub.3 CH.sub.3 H 2 H H H H C(CH.sub.3)--OCH.sub.3 Cl Cl4.4 CH.sub.3 CH.sub.3 H 0 H H H H O Cl Cl4.5 CH.sub.3 CH.sub.3 H 1 H H H H O Cl Cl4.6 CH.sub.3 CH.sub.3 H 2 H H H H O Cl Cl4.7 H H H 0 CH.sub.3 CH.sub.3 H H C.dbd.O H CH.sub.34.8 H H H 1 CH.sub.3 CH.sub.3 H H C.dbd.O H CH.sub.34.9 H H H 2 CH.sub.3 CH.sub.3 H H C.dbd.O H CH.sub.34.10 H H H 0 CH.sub.3 CH.sub.3 H H CH--OCH.sub.3 H CH.sub.34.11 H H H 1 CH.sub.3 CH.sub.3 H H CH--OCH.sub.3 H CH.sub.34.12 H H H 2 CH.sub.3 CH.sub.3 H H CH--OCH.sub.3 H CH.sub.34.13 H H H 0 CH.sub.3 CH.sub.3 H H CHOC.sub.2 H.sub.5 H CH.sub.34.14 H H H 1 CH.sub.3 CH.sub.3 H H CHOC.sub.2 H.sub.5 H CH.sub.34.15 H H H 2 CH.sub.3 CH.sub.3 H H CHOC.sub.2 H.sub.5 H CH.sub.34.16 H H H 0 CH.sub.3 CH.sub.3 H H CHOiPr H CH.sub.34.17 H H H 1 CH.sub.3 CH.sub.3 H H CHOiPr H CH.sub.34.18 H H H 2 CH.sub.3 CH.sub.3 H H CHOiPr H CH.sub.34.19 H H H 0 CH.sub.3 CH.sub.3 H H C.dbd.NOCH.sub.3 H CH.sub.34.20 H H H 1 CH.sub.3 CH.sub.3 H H C.dbd.NOCH.sub.3 H CH.sub.34.21 H H H 2 CH.sub.3 CH.sub.3 H H C.dbd.NOCH.sub.3 H CH.sub.34.22 H H H 0 CH.sub.3 CH.sub.3 H H C.dbd.NOC.sub.2 H.sub.5 H CH.sub.34.23 H H H 1 CH.sub.3 CH.sub.3 H H C.dbd.NOC.sub.2 H.sub.5 H CH.sub.34.24 H H H 2 CH.sub.3 CH.sub.3 H H C.dbd.NOC.sub.2 H.sub.5 H CH.sub.34.25 H H H 0 CH.sub.3 CH.sub.3 H H C.dbd.NOiPr H CH.sub.34.26 H H H 1 CH.sub.3 CH.sub.3 H H C.dbd.NOiPr H CH.sub.34.27 H H H 2 CH.sub.3 CH.sub.3 H H C.dbd.NOiPr H CH.sub.34.28 H H H 0 CH.sub.3 CH.sub.3 H H C.dbd.NOCH.sub.2 CH.dbd.CHCl H CH.sub.34.29 H H H 1 CH.sub.3 CH.sub.3 H H C.dbd.NOCH.sub.2 CH.dbd.CHCl H CH.sub.34.30 H H H 2 CH.sub.3 CH.sub.3 H H C.dbd.NOCH.sub.2 CH.dbd.CHCl H CH.sub.34.31 H H H 0 CH.sub.3 CH.sub.3 H H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 H CH.sub.34.32 H H H 1 CH.sub.3 CH.sub.3 H H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 H CH.sub.34.33 H H H 2 CH.sub.3 CH.sub.3 H H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 H CH.sub.34.34 H H H 0 CH.sub.3 CH.sub.3 H H C(CH.sub.3).sub.2 H CH.sub.34.35 H H H 1 CH.sub.3 CH.sub.3 H H C(CH.sub.3).sub.2 H CH.sub.34.36 H H H 2 CH.sub.3 CH.sub.3 H H C(CH.sub.3).sub.2 H CH.sub.34.37 H H H 0 CH.sub.3 CH.sub.3 H H ##STR126## H CH.sub.34.38 H H H 1 CH.sub.3 CH.sub.3 H H ##STR127## H CH.sub.34.39 H H H 2 CH.sub.3 CH.sub.3 H H ##STR128## H CH.sub.34.40 H H H 0 CH.sub.3 CH.sub.3 H H ##STR129## H CH.sub.34.41 H H H 1 CH.sub.3 CH.sub.3 H H ##STR130## H CH.sub.34.42 H H H 2 CH.sub.3 CH.sub.3 H H ##STR131## H CH.sub.34.43 H H H 0 CH.sub.3 CH.sub.3 H H C.dbd.N--CH.sub.3 H CH.sub.34.44 H H H 1 CH.sub.3 CH.sub.3 H H C.dbd.N--CH.sub.3 H CH.sub.34.45 H H H 2 CH.sub.3 CH.sub.3 H H C.dbd.N--CH.sub.3 H CH.sub.34.46 H H H 0 CH.sub.3 CH.sub.3 H H C.dbd.NC.sub.2 H.sub.5 H CH.sub.34.47 H H H 1 CH.sub.3 CH.sub.3 H H C.dbd.NC.sub.2 H.sub.5 H CH.sub.34.48 H H H 2 CH.sub.3 CH.sub.3 H H C.dbd.NC.sub.2 H.sub.5 H CH.sub.34.49 H H H 0 CH.sub.3 CH.sub.3 H H CH--NHCH.sub.3 H CH.sub.34.50 H H H 1 CH.sub.3 CH.sub.3 H H CH--NHCH.sub.3 H CH.sub.34.51 H H H 2 CH.sub.3 CH.sub.3 H H CH--NHCH.sub.3 H CH.sub.34.52 H H H 0 CH.sub.3 CH.sub.3 H H CH--NHC.sub.2 H.sub.5 H CH.sub.34.53 H H H 1 CH.sub.3 CH.sub.3 H H CH--NHC.sub.2 H.sub.5 H CH.sub.34.54 H H H 2 CH.sub.3 CH.sub.3 H H CH--NHC.sub.2 H.sub.5 H CH.sub.34.55 H H H 0 CH.sub.3 CH.sub.3 H H CH--N(CH.sub.3).sub.2 H CH.sub.34.56 H H H 1 CH.sub.3 CH.sub.3 H H CH--N(CH.sub.3).sub.2 H CH.sub.34.57 H H H 2 CH.sub.3 CH.sub.3 H H CH--N(CH.sub.3).sub.2 H CH.sub.34.58 H H H 0 CH.sub.3 CH.sub.3 H H CH--NHOC.sub.2 H.sub.5 H CH.sub.34.59 H H H 1 CH.sub.3 CH.sub.3 H H CH--NHOC.sub.2 H.sub.5 H CH.sub.34.60 H H H 2 CH.sub.3 CH.sub.3 H H CH--NHOC.sub.2 H.sub.5 H CH.sub.34.61 H H H 0 CH.sub.3 CH.sub.3 H H CH--N(CH.sub.3)OC.sub.2 H.sub.5 H CH.sub.34.62 H H H 1 CH.sub.3 CH.sub.3 H H CH--N(CH.sub.3)OC.sub.2 H.sub.5 H CH.sub.34.63 H H H 2 CH.sub.3 CH.sub.3 H H CH--N(CH.sub.3)OC.sub.2 H.sub.5 H CH.sub.34.64 H H H 0 CH.sub.3 CH.sub.3 H H C.dbd.N--NH.sub.2 H CH.sub.34.65 H H H 1 CH.sub.3 CH.sub.3 H H C.dbd.N--NH.sub.2 H CH.sub.34.66 H H H 2 CH.sub.3 CH.sub.3 H H C.dbd.N--NH.sub.2 H CH.sub.34.67 H H H 0 CH.sub.3 CH.sub.3 H H C.dbd.N--N(CH.sub.3).sub.2 H CH.sub.34.68 H H H 1 CH.sub.3 CH.sub.3 H H C.dbd.N--N(CH.sub.3).sub.2 H CH.sub.34.69 H H H 2 CH.sub.3 CH.sub.3 H H C.dbd.N--N(CH.sub.3).sub.2 H CH.sub.34.70 H H H 0 CH.sub.3 CH.sub.3 H H CH--N(CH.sub.3)OCH.sub.2 C.sub.6 H.sub.5 H CH.sub.34.71 H H H 1 CH.sub.3 CH.sub.3 H H CH--N(CH.sub.3)OCH.sub.2 C.sub.6 H.sub.5 H CH.sub.34.72 H H H 2 CH.sub.3 CH.sub.3 H H CH--N(CH.sub.3)OCH.sub.2 C.sub.6 H.sub.5 H CH.sub.34.73 H H H 0 CH.sub.3 CH.sub.3 H H C(CH.sub.3)--OCH.sub.3 H CH.sub.34.74 H H H 1 CH.sub.3 CH.sub.3 H H C(CH.sub.3)--OCH.sub.3 H CH.sub.34.75 H H H 2 CH.sub.3 CH.sub.3 H H C(CH.sub.3)--OCH.sub.3 H CH.sub.34.76 H H H 0 CH.sub.3 CH.sub.3 H H O H CH.sub.34.77 H H H 2 CH.sub.3 CH.sub.3 H H O H CH.sub.34.78 CH.sub.3 H H 0 CH.sub.3 CH.sub.3 H H C.dbd.O H CH.sub.34.79 CH.sub.3 H H 1 CH.sub.3 CH.sub.3 H H C.dbd.O H CH.sub.34.80 CH.sub.3 H H 2 CH.sub.3 CH.sub.3 H H C.dbd.O H CH.sub.34.81 CH.sub.3 H H 0 CH.sub.3 CH.sub.3 H H CHOCH.sub.3 H CH.sub.34.82 CH.sub.3 H H 1 CH.sub.3 CH.sub.3 H H CHOCH.sub.3 H CH.sub.34.83 CH.sub.3 H H 2 CH.sub.3 CH.sub.3 H H CHOCH.sub.3 H CH.sub.34.84 CH.sub.3 H H 0 CH.sub.3 CH.sub.3 H H CHOC.sub.2 H.sub.5 H CH.sub.34.85 CH.sub.3 H H 1 CH.sub.3 CH.sub.3 H H CHOC.sub.2 H.sub.5 H CH.sub.34.86 CH.sub.3 H H 2 CH.sub.3 CH.sub.3 H H CHOC.sub.2 H.sub.5 H CH.sub.34.87 CH.sub.3 H H 0 CH.sub.3 CH.sub.3 H H CHOiPr H CH.sub.34.88 CH.sub.3 H H 1 CH.sub.3 CH.sub.3 H H CHOiPr H CH.sub.34.89 CH.sub.3 H H 2 CH.sub.3 CH.sub.3 H H CHOiPr H CH.sub.34.90 CH.sub.3 H H 0 CH.sub.3 CH.sub.3 H H C.dbd.NOCH.sub.3 H CH.sub.34.91 CH.sub.3 H H 1 CH.sub.3 CH.sub.3 H H C.dbd.NOCH.sub.3 H CH.sub.34.92 CH.sub.3 H H 2 CH.sub.3 CH.sub.3 H H C.dbd.NOCH.sub.3 H CH.sub.34.93 CH.sub.3 H H 0 CH.sub.3 CH.sub.3 H H C.dbd.NOC.sub.2 H.sub.5 H CH.sub.34.94 CH.sub.3 H H 1 CH.sub.3 CH.sub.3 H H C.dbd.NOC.sub.2 H.sub.5 H CH.sub.34.95 CH.sub.3 H H 2 CH.sub.3 CH.sub.3 H H C.dbd.NOC.sub.2 H.sub.5 H CH.sub.34.96 CH.sub.3 H H 0 CH.sub.3 CH.sub.3 H H C.dbd.NOiPr H CH.sub.34.97 CH.sub.3 H H 1 CH.sub.3 CH.sub.3 H H C.dbd.NOiPr H CH.sub.34.98 CH.sub.3 H H 2 CH.sub.3 CH.sub.3 H H C.dbd.NOiPr H CH.sub.34.99 CH.sub.3 H H 0 CH.sub.3 CH.sub.3 H H C.dbd.NOCH.sub.2 CH.dbd.CHCl H CH.sub.34.100 CH.sub.3 H H 1 CH.sub.3 CH.sub.3 H H C.dbd.NOCH.sub.2 CH.dbd.CHCl H CH.sub.34.101 CH.sub.3 H H 2 CH.sub.3 CH.sub.3 H H C.dbd.NOCH.sub.2 CH.dbd.CHCl H CH.sub.34.102 CH.sub.3 H H 0 CH.sub.3 CH.sub.3 H H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 H CH.sub.34.103 CH.sub.3 H H 1 CH.sub.3 CH.sub.3 H H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 H CH.sub.34.104 CH.sub.3 H H 2 CH.sub.3 CH.sub.3 H H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 H CH.sub.34.105 CH.sub.3 H H 0 CH.sub.3 CH.sub.3 H H C(CH.sub.3).sub.2 H CH.sub.34.106 CH.sub.3 H H 1 CH.sub.3 CH.sub.3 H H C(CH.sub.3).sub.2 H CH.sub.34.107 CH.sub.3 H H 2 CH.sub.3 CH.sub.3 H H C(CH.sub.3).sub.2 H CH.sub.34.108 CH.sub.3 H H 0 CH.sub.3 CH.sub.3 H H ##STR132## H CH.sub.34.109 CH.sub.3 H H 1 CH.sub.3 CH.sub.3 H H ##STR133## H CH.sub.34.110 CH.sub.3 H H 2 CH.sub.3 CH.sub.3 H H ##STR134## H CH.sub.34.111 CH.sub.3 H H 0 CH.sub.3 CH.sub.3 H H ##STR135## H CH.sub.34.112 CH.sub.3 H H 1 CH.sub.3 CH.sub.3 H H ##STR136## H CH.sub.34.113 CH.sub.3 H H 2 CH.sub.3 CH.sub.3 H H ##STR137## H CH.sub.34.114 CH.sub.3 H H 0 CH.sub.3 CH.sub.3 H H C.dbd.N--CH.sub.3 H CH.sub.34.115 CH.sub.3 H H 1 CH.sub.3 CH.sub.3 H H C.dbd.N--CH.sub.3 H CH.sub.34.116 CH.sub.3 H H 2 CH.sub.3 CH.sub.3 H H C.dbd.N--CH.sub.3 H CH.sub.34.117 CH.sub.3 H H 0 CH.sub.3 CH.sub.3 H H C.dbd.NC.sub.2 H.sub.5 H CH.sub.34.118 CH.sub.3 H H 1 CH.sub.3 CH.sub.3 H H C.dbd.NC.sub.2 H.sub.5 H CH.sub.34.119 CH.sub.3 H H 2 CH.sub.3 CH.sub.3 H H C.dbd.NC.sub.2 H.sub.5 H CH.sub.34.120 CH.sub.3 H H 0 CH.sub.3 CH.sub.3 H H CH--NHCH.sub.3 H CH.sub.34.121 CH.sub.3 H H 1 CH.sub.3 CH.sub.3 H H CH--NHCH.sub.3 H CH.sub.34.122 CH.sub.3 H H 2 CH.sub.3 CH.sub.3 H H CH--NHCH.sub.3 H CH.sub.34.123 CH.sub.3 H H 0 CH.sub.3 CH.sub.3 H H CH--NHC.sub.2 H.sub.5 H CH.sub.34.124 CH.sub.3 H H 1 CH.sub.3 CH.sub.3 H H CH--NHC.sub.2 H.sub.5 H CH.sub.34.125 CH.sub.3 H H 2 CH.sub.3 CH.sub.3 H H CH--NHC.sub.2 H.sub.5 H CH.sub.34.126 CH.sub.3 H H 0 CH.sub.3 CH.sub.3 H H CH--N(CH.sub.3).sub.2 H CH.sub.34.127 CH.sub.3 H H 1 CH.sub.3 CH.sub.3 H H CH--N(CH.sub.3).sub.2 H CH.sub.34.128 CH.sub.3 H H 2 CH.sub.3 CH.sub.3 H H CH--N(CH.sub.3).sub.2 H CH.sub.34.129 CH.sub.3 H H 0 CH.sub.3 CH.sub.3 H H CH--NHOC.sub.2 H.sub.5 H CH.sub.34.130 CH.sub.3 H H 1 CH.sub.3 CH.sub.3 H H CH--NHOC.sub.2 H.sub.5 H CH.sub.34.131 CH.sub.3 H H 2 CH.sub.3 CH.sub.3 H H CH--NHOC.sub.2 H.sub.5 H CH.sub.34.132 CH.sub.3 H H 0 CH.sub.3 CH.sub.3 H H CH--N(CH.sub.3)OC.sub.2 H.sub.5 H CH.sub.34.133 CH.sub.3 H H 1 CH.sub.3 CH.sub.3 H H CH--N(CH.sub.3)OC.sub.2 H.sub.5 H CH.sub.34.134 CH.sub.3 H H 2 CH.sub.3 CH.sub.3 H H CH--N(CH.sub.3)OC.sub.2 H.sub.5 H CH.sub.34.135 CH.sub.3 H H 0 CH.sub.3 CH.sub.3 H H C.dbd.N--NH.sub.2 H CH.sub.34.136 CH.sub.3 H H 1 CH.sub.3 CH.sub.3 H H C.dbd.N--NH.sub.2 H CH.sub.34.137 CH.sub.3 H H 2 CH.sub.3 CH.sub.3 H H C.dbd.N--NH.sub.2 H CH.sub.34.138 CH.sub.3 H H 0 CH.sub.3 CH.sub.3 H H C.dbd.N--N(CH.sub.3).sub.2 H CH.sub.34.139 CH.sub.3 H H 1 CH.sub.3 CH.sub.3 H H C.dbd.N--N(CH.sub.3).sub.2 H CH.sub.34.140 CH.sub.3 H H 2 CH.sub.3 CH.sub.3 H H C.dbd.N--N(CH.sub.3).sub.2 H CH.sub.34.141 CH.sub.3 H H 0 CH.sub.3 CH.sub.3 H H CH--N(CH.sub.3)OCH.sub.2 C.sub.6 H.sub.5 H CH.sub.34.142 CH.sub.3 H H 1 CH.sub.3 CH.sub.3 H H CH--N(CH.sub.3)OCH.sub.2 C.sub.6 H.sub.5 H CH.sub.34.143 CH.sub.3 H H 2 CH.sub.3 CH.sub.3 H H CH--N(CH.sub.3)OCH.sub.2 C.sub.6 H.sub.5 H CH.sub.34.144 CH.sub.3 H H 0 CH.sub.3 CH.sub.3 H H C(CH.sub.3)--OCH.sub.3 H CH.sub.34.145 CH.sub.3 H H 1 CH.sub.3 CH.sub.3 H H C(CH.sub.3)--OCH.sub.3 H CH.sub.34.146 CH.sub.3 H H 2 CH.sub.3 CH.sub.3 H H C(CH.sub.3)--OCH.sub.3 H CH.sub.34.147 CH.sub.3 H H 0 CH.sub.3 CH.sub.3 H H O H CH.sub.34.148 CH.sub.3 H H 2 CH.sub.3 CH.sub.3 H H O H CH.sub.34.149 CH.sub.3 CH.sub.3 H 0 CH.sub.3 CH.sub.3 H H C.dbd.O H CH.sub.34.150 CH.sub.3 CH.sub.3 H 1 CH.sub.3 CH.sub.3 H H C.dbd.O H CH.sub.34.151 CH.sub.3 CH.sub.3 H 2 CH.sub.3 CH.sub.3 H H C.dbd.O H CH.sub.34.152 CH.sub.3 CH.sub.3 H 0 CH.sub.3 CH.sub.3 H H CHOCH.sub.3 H CH.sub.34.153 CH.sub.3 CH.sub.3 H 1 CH.sub.3 CH.sub.3 H H CHOCH.sub.3 H CH.sub.34.154 CH.sub.3 CH.sub.3 H 2 CH.sub.3 CH.sub.3 H H CHOCH.sub.3 H CH.sub.34.155 CH.sub.3 CH.sub.3 H 0 CH.sub.3 CH.sub.3 H H CHOC.sub.2 H.sub.5 H CH.sub.34.156 CH.sub.3 CH.sub.3 H 1 CH.sub.3 CH.sub.3 H H CHOC.sub.2 H.sub.5 H CH.sub.34.157 CH.sub.3 CH.sub.3 H 2 CH.sub.3 CH.sub.3 H H CHOC.sub.2 H.sub.5 H CH.sub.34.158 CH.sub.3 CH.sub.3 H 0 CH.sub.3 CH.sub.3 H H CHOiPr H CH.sub.34.159 CH.sub.3 CH.sub.3 H 1 CH.sub.3 CH.sub.3 H H CHOiPr H CH.sub.34.160 CH.sub.3 CH.sub.3 H 2 CH.sub.3 CH.sub.3 H H CHOiPr H CH.sub.34.161 CH.sub.3 CH.sub.3 H 0 CH.sub.3 CH.sub.3 H H C.dbd.NOCH.sub.3 H CH.sub.34.162 CH.sub.3 CH.sub.3 H 1 CH.sub.3 CH.sub.3 H H C.dbd.NOCH.sub.3 H CH.sub.34.163 CH.sub.3 CH.sub.3 H 2 CH.sub.3 CH.sub.3 H H C.dbd.NOCH.sub.3 H CH.sub.34.164 CH.sub.3 CH.sub.3 H 0 CH.sub.3 CH.sub.3 H H C.dbd.NOC.sub.2 H.sub.5 H CH.sub.34.165 CH.sub.3 CH.sub.3 H 1 CH.sub.3 CH.sub.3 H H C.dbd.NOC.sub.2 H.sub.5 H CH.sub.34.166 CH.sub.3 CH.sub.3 H 2 CH.sub.3 CH.sub.3 H H C.dbd.NOC.sub.2 H.sub.5 H CH.sub.34.167 CH.sub.3 CH.sub.3 H 0 CH.sub.3 CH.sub.3 H H C.dbd.NOiPr H CH.sub.34.168 CH.sub.3 CH.sub.3 H 1 CH.sub.3 CH.sub.3 H H C.dbd.NOiPr H CH.sub.34.169 CH.sub.3 CH.sub.3 H 2 CH.sub.3 CH.sub.3 H H C.dbd.NOiPr H CH.sub.34.170 CH.sub.3 CH.sub.3 H 0 CH.sub.3 CH.sub.3 H H C.dbd.NOCH.sub.2 CH.dbd.CHCl H CH.sub.34.171 CH.sub.3 CH.sub.3 H 1 CH.sub.3 CH.sub.3 H H C.dbd.NOCH.sub.2 CH.dbd.CHCl H CH.sub.34.172 CH.sub.3 CH.sub.3 H 2 CH.sub.3 CH.sub.3 H H C.dbd.NOCH.sub.2 CH.dbd.CHCl H CH.sub.34.173 CH.sub.3 CH.sub.3 H 0 CH.sub.3 CH.sub.3 H H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 H CH.sub.34.174 CH.sub.3 CH.sub.3 H 1 CH.sub.3 CH.sub.3 H H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 H CH.sub.34.175 CH.sub.3 CH.sub.3 H 2 CH.sub.3 CH.sub.3 H H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 H CH.sub.34.176 CH.sub.3 CH.sub.3 H 0 CH.sub.3 CH.sub.3 H H C(CH.sub.3).sub.2 H CH.sub.34.177 CH.sub.3 CH.sub.3 H 1 CH.sub.3 CH.sub.3 H H C(CH.sub.3).sub.2 H CH.sub.34.178 CH.sub.3 CH.sub.3 H 2 CH.sub.3 CH.sub.3 H H C(CH.sub.3).sub.2 H CH.sub.34.179 CH.sub.3 CH.sub.3 H 0 CH.sub.3 CH.sub.3 H H ##STR138## H CH.sub.34.180 CH.sub.3 CH.sub.3 H 1 CH.sub.3 CH.sub.3 H H ##STR139## H CH.sub.34.181 CH.sub.3 CH.sub.3 H 2 CH.sub.3 CH.sub.3 H H ##STR140## H CH.sub.34.182 CH.sub.3 CH.sub.3 H 0 CH.sub.3 CH.sub.3 H H ##STR141## H CH.sub.34.183 CH.sub.3 CH.sub.3 H 1 CH.sub.3 CH.sub.3 H H ##STR142## H CH.sub.34.184 CH.sub.3 CH.sub.3 H 2 CH.sub.3 CH.sub.3 H H ##STR143## H CH.sub.34.185 CH.sub.3 CH.sub.3 H 0 CH.sub.3 CH.sub.3 H H C.dbd.N--CH.sub.3 H CH.sub.34.186 CH.sub.3 CH.sub.3 H 1 CH.sub.3 CH.sub.3 H H C.dbd.N--CH.sub.3 H CH.sub.34.187 CH.sub.3 CH.sub.3 H 2 CH.sub.3 CH.sub.3 H H C.dbd.N--CH.sub.3 H CH.sub.34.188 CH.sub.3 CH.sub.3 H 0 CH.sub.3 CH.sub.3 H H C.dbd.NC.sub.2 H.sub.5 H CH.sub.34.189 CH.sub.3 CH.sub.3 H 1 CH.sub.3 CH.sub.3 H H C.dbd.NC.sub.2 H.sub.5 H CH.sub.34.190 CH.sub.3 CH.sub.3 H 2 CH.sub.3 CH.sub.3 H H C.dbd.NC.sub.2 H.sub.5 H CH.sub.34.191 CH.sub.3 CH.sub.3 H 0 CH.sub.3 CH.sub.3 H H CH--NHCH.sub.3 H CH.sub.34.192 CH.sub.3 CH.sub.3 H 1 CH.sub.3 CH.sub.3 H H CH--NHCH.sub.3 H CH.sub.34.193 CH.sub.3 CH.sub.3 H 2 CH.sub.3 CH.sub.3 H H CH--NHCH.sub.3 H CH.sub.34.194 CH.sub.3 CH.sub.3 H 0 CH.sub.3 CH.sub.3 H H CH--NHC.sub.2 H.sub.5 H CH.sub.34.195 CH.sub.3 CH.sub.3 H 1 CH.sub.3 CH.sub.3 H H CH--NHC.sub.2 H.sub.5 H CH.sub.34.196 CH.sub.3 CH.sub.3 H 2 CH.sub.3 CH.sub.3 H H CH--NHC.sub.2 H.sub.5 H CH.sub.34.197 CH.sub.3 CH.sub.3 H 0 CH.sub.3 CH.sub.3 H H CH--N(CH.sub.3).sub.2 H CH.sub.34.198 CH.sub.3 CH.sub.3 H 1 CH.sub.3 CH.sub.3 H H CH--N(CH.sub.3).sub.2 H CH.sub.34.199 CH.sub.3 CH.sub.3 H 2 CH.sub.3 CH.sub.3 H H CH--N(CH.sub.3).sub.2 H CH.sub.34.200 CH.sub.3 CH.sub.3 H 0 CH.sub.3 CH.sub.3 H H CH--NHOC.sub.2 H.sub.5 H CH.sub.34.201 CH.sub.3 CH.sub.3 H 1 CH.sub.3 CH.sub.3 H H CH--NHOC.sub.2 H.sub.5 H CH.sub.34.202 CH.sub.3 CH.sub.3 H 2 CH.sub.3 CH.sub.3 H H CH--NHOC.sub.2 H.sub.5 H CH.sub.34.203 CH.sub.3 CH.sub.3 H 0 CH.sub.3 CH.sub.3 H H CH--N(CH.sub.3)OC.sub.2 H.sub.5 H CH.sub.34.204 CH.sub.3 CH.sub.3 H 1 CH.sub.3 CH.sub.3 H H CH--N(CH.sub.3)OC.sub.2 H.sub.5 H CH.sub.34.205 CH.sub.3 CH.sub.3 H 2 CH.sub.3 CH.sub.3 H H CH--N(CH.sub.3)OC.sub.2 H.sub.5 H CH.sub.34.206 CH.sub.3 CH.sub.3 H 0 CH.sub.3 CH.sub.3 H H C.dbd.N--NH.sub.2 H CH.sub.34.207 CH.sub.3 CH.sub.3 H 1 CH.sub.3 CH.sub.3 H H C.dbd.N--NH.sub.2 H CH.sub.34.208 CH.sub.3 CH.sub.3 H 2 CH.sub.3 CH.sub.3 H H C.dbd.N--NH.sub.2 H CH.sub.34.209 CH.sub.3 CH.sub.3 H 0 CH.sub.3 CH.sub.3 H H C.dbd.N--N(CH.sub.3).sub.2 H CH.sub.34.210 CH.sub.3 CH.sub.3 H 1 CH.sub.3 CH.sub.3 H H C.dbd.N--N(CH.sub.3).sub.2 H CH.sub.34.211 CH.sub.3 CH.sub.3 H 2 CH.sub.3 CH.sub.3 H H C.dbd.N--N(CH.sub.3).sub.2 H CH.sub.34.212 CH.sub.3 CH.sub.3 H 0 CH.sub.3 CH.sub.3 H H CH--N(CH.sub.3)OCH.sub.2 C.sub.6 H.sub.5 H CH.sub.34.213 CH.sub.3 CH.sub.3 H 1 CH.sub.3 CH.sub.3 H H CH--N(CH.sub.3)OCH.sub.2 C.sub.6 H.sub.5 H CH.sub.34.214 CH.sub.3 CH.sub.3 H 2 CH.sub.3 CH.sub.3 H H CH--N(CH.sub.3)OCH.sub.2 C.sub.6 H.sub.5 H CH.sub.34.215 CH.sub.3 CH.sub.3 H 0 CH.sub.3 CH.sub.3 H H C(CH.sub.3)--OCH.sub.3 H CH.sub.34.216 CH.sub.3 CH.sub.3 H 1 CH.sub.3 CH.sub.3 H H C(CH.sub.3)--OCH.sub.3 H CH.sub.34.217 CH.sub.3 CH.sub.3 H 2 CH.sub.3 CH.sub.3 H H C(CH.sub.3)--OCH.sub.3 H CH.sub.34.218 CH.sub.3 CH.sub.3 H 0 CH.sub.3 CH.sub.3 H H O H CH.sub.34.219 CH.sub.3 CH.sub.3 H 2 CH.sub.3 CH.sub.3 H H O H CH.sub.34.220 H H H 0 CH.sub.3 H H H C.dbd.O H Cl4.221 H H H 1 CH.sub.3 H H H C.dbd.O H Cl4.222 H H H 2 CH.sub.3 H H H C.dbd.O H Cl4.223 H H H 0 CH.sub.3 H H H CHOCH.sub.3 H Cl4.224 H H H 1 CH.sub.3 H H H CHOCH.sub.3 H Cl4.225 H H H 2 CH.sub.3 H H H CHOCH.sub.3 H Cl4.226 H H H 0 CH.sub.3 H H H CHOC.sub.2 H.sub.5 H Cl4.227 H H H 1 CH.sub.3 H H H CHOC.sub.2 H.sub.5 H Cl4.228 H H H 2 CH.sub.3 H H H CHOC.sub.2 H.sub.5 H Cl4.229 H H H 0 CH.sub.3 H H H CHOiPr H Cl4.230 H H H 1 CH.sub.3 H H H CHOiPr H Cl4.231 H H H 2 CH.sub.3 H H H CHOiPr H Cl4.232 H H H 0 CH.sub.3 H H H C.dbd.NOCH.sub.3 H Cl4.233 H H H 1 CH.sub.3 H H H C.dbd.NOCH.sub.3 H Cl4.234 H H H 2 CH.sub.3 H H H C.dbd.NOCH.sub.3 H Cl4.235 H H H 0 CH.sub.3 H H H C.dbd.NOC.sub.2 H.sub.5 H Cl4.236 H H H 1 CH.sub.3 H H H C.dbd.NOC.sub.2 H.sub.5 H Cl4.237 H H H 2 CH.sub.3 H H H C.dbd.NOC.sub.2 H.sub.5 H Cl4.238 H H H 0 CH.sub.3 H H H C.dbd.NOiPr H Cl4.239 H H H 1 CH.sub.3 H H H C.dbd.NOiPr H Cl4.240 H H H 2 CH.sub.3 H H H C.dbd.NOiPr H Cl4.241 H H H 0 CH.sub.3 H H H C.dbd.NOCH.sub.2 CH.dbd.CHCl H Cl4.242 H H H 1 CH.sub.3 H H H C.dbd.NOCH.sub.2 CH.dbd.CHCl H Cl4.243 H H H 2 CH.sub.3 H H H C.dbd.NOCH.sub.2 CH.dbd.CHCl H Cl4.244 H H H 0 CH.sub.3 H H H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 H Cl4.245 H H H 1 CH.sub.3 H H H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 H Cl4.246 H H H 2 CH.sub.3 H H H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 H Cl4.247 H H H 0 CH.sub.3 H H H C(CH.sub.3).sub.2 H Cl4.248 H H H 1 CH.sub.3 H H H C(CH.sub.3).sub.2 H Cl4.249 H H H 2 CH.sub.3 H H H C(CH.sub.3).sub.2 H Cl4.250 H H H 0 CH.sub.3 H H H ##STR144## H Cl4.251 H H H 1 CH.sub.3 H H H ##STR145## H Cl4.252 H H H 2 CH.sub.3 H H H ##STR146## H Cl4.253 H H H 0 CH.sub.3 H H H ##STR147## H Cl4.254 H H H 1 CH.sub.3 H H H ##STR148## H Cl4.255 H H H 2 CH.sub.3 H H H ##STR149## H Cl4.256 H H H 0 CH.sub.3 H H H C.dbd.N--CH.sub.3 H Cl4.257 H H H 1 CH.sub.3 H H H C.dbd.N--CH.sub.3 H Cl4.258 H H H 2 CH.sub.3 H H H C.dbd.N--CH.sub.3 H Cl4.259 H H H 0 CH.sub.3 H H H C.dbd.NC.sub.2 H.sub.5 H Cl4.260 H H H 1 CH.sub.3 H H H C.dbd.NC.sub.2 H.sub.5 H Cl4.261 H H H 2 CH.sub.3 H H H C.dbd.NC.sub.2 H.sub.5 H Cl4.262 H H H 0 CH.sub.3 H H H CH--NHCH.sub.3 H Cl4.263 H H H 1 CH.sub.3 H H H CH--NHCH.sub.3 H Cl4.264 H H H 2 CH.sub.3 H H H CH--NHCH.sub.3 H Cl4.265 H H H 0 CH.sub.3 H H H CH--NHC.sub.2 H.sub.5 H Cl4.266 H H H 1 CH.sub.3 H H H CH--NHC.sub.2 H.sub.5 H Cl4.267 H H H 2 CH.sub.3 H H H CH--NHC.sub.2 H.sub.5 H Cl4.268 H H H 0 CH.sub.3 H H H CH--N(CH.sub.3).sub.2 H Cl4.269 H H H 1 CH.sub.3 H H H CH--N(CH.sub.3).sub.2 H Cl4.270 H H H 2 CH.sub.3 H H H CH--N(CH.sub.3).sub.2 H Cl4.271 H H H 0 CH.sub.3 H H H CH--NHOC.sub.2 H.sub.5 H Cl4.272 H H H 1 CH.sub.3 H H H CH--NHOC.sub.2 H.sub.5 H Cl4.273 H H H 2 CH.sub.3 H H H CH--NHOC.sub.2 H.sub.5 H Cl4.274 H H H 0 CH.sub.3 H H H CH--N(CH.sub.3)OC.sub.2 H.sub.5 H Cl4.275 H H H 1 CH.sub.3 H H H CH--N(CH.sub.3)OC.sub.2 H.sub.5 H Cl4.276 H H H 2 CH.sub.3 H H H CH--N(CH.sub.3)OC.sub.2 H.sub.5 H Cl4.277 H H H 0 CH.sub.3 H H H C.dbd.N--NH.sub.2 H Cl4.278 H H H 1 CH.sub.3 H H H C.dbd.N--NH.sub.2 H Cl4.279 H H H 2 CH.sub.3 H H H C.dbd.N--NH.sub.2 H Cl4.280 H H H 0 CH.sub.3 H H H C.dbd.N--N(CH.sub.3).sub.2 H Cl4.281 H H H 1 CH.sub.3 H H H C.dbd.N--N(CH.sub.3).sub.2 H Cl4.282 H H H 2 CH.sub.3 H H H C.dbd.N--N(CH.sub.3).sub.2 H Cl4.283 H H H 0 CH.sub.3 H H H CH--N(CH.sub.3)OCH.sub.2 C.sub.6 H.sub.5 H Cl4.284 H H H 1 CH.sub.3 H H H CH--N(CH.sub.3)OCH.sub.2 C.sub.6 H.sub.5 H Cl4.285 H H H 2 CH.sub.3 H H H CH--N(CH.sub.3)OCH.sub.2 C.sub.6 H.sub.5 H Cl4.286 H H H 0 CH.sub.3 H H H C(CH.sub.3)--OCH.sub.3 H Cl4.287 H H H 1 CH.sub.3 H H H C(CH.sub.3)--OCH.sub.3 H Cl4.288 H H H 2 CH.sub.3 H H H C(CH.sub.3)--OCH.sub.3 H Cl4.289 H H H 0 CH.sub.3 H H H O H Cl4.290 H H H 2 CH.sub.3 H H H O H Cl4.291 CH.sub.3 H H 0 CH.sub.3 H H H C.dbd.O H Cl4.292 CH.sub.3 H H 1 CH.sub.3 H H H C.dbd.O H Cl4.293 CH.sub.3 H H 2 CH.sub.3 H H H C.dbd.O H Cl4.294 CH.sub.3 H H 0 CH.sub.3 H H H CHOCH.sub.3 H Cl4.295 CH.sub.3 H H 1 CH.sub.3 H H H CHOCH.sub.3 H Cl4.296 CH.sub.3 H H 2 CH.sub.3 H H H CHOCH.sub.3 H Cl4.297 CH.sub.3 H H 0 CH.sub.3 H H H CHOC.sub.2 H.sub.5 H Cl4.298 CH.sub.3 H H 1 CH.sub.3 H H H CHOC.sub.2 H.sub.5 H Cl4.299 CH.sub.3 H H 2 CH.sub.3 H H H CHOC.sub.2 H.sub.5 H Cl4.300 CH.sub.3 H H 0 CH.sub.3 H H H CHOiPr H Cl4.301 CH.sub.3 H H 1 CH.sub.3 H H H CHOiPr H Cl4.302 CH.sub.3 H H 2 CH.sub.3 H H H CHOiPr H Cl4.303 CH.sub.3 H H 0 CH.sub.3 H H H C.dbd.NOCH.sub.3 H Cl4.304 CH.sub.3 H H 1 CH.sub.3 H H H C.dbd.NOCH.sub.3 H Cl4.305 CH.sub.3 H H 2 CH.sub.3 H H H C.dbd.NOCH.sub.3 H Cl4.306 CH.sub.3 H H 0 CH.sub.3 H H H C.dbd.NOC.sub.2 H.sub.5 H Cl4.307 CH.sub.3 H H 1 CH.sub.3 H H H C.dbd.NOC.sub.2 H.sub.5 H Cl4.308 CH.sub.3 H H 2 CH.sub.3 H H H C.dbd.NOC.sub.2 H.sub.5 H Cl4.309 CH.sub.3 H H 0 CH.sub.3 H H H C.dbd.NOiPr H Cl4.310 CH.sub.3 H H 1 CH.sub.3 H H H C.dbd.NOiPr H Cl4.311 CH.sub.3 H H 2 CH.sub.3 H H H C.dbd.NOiPr H Cl4.312 CH.sub.3 H H 0 CH.sub.3 H H H C.dbd.NOCH.sub.2 CH.dbd.CHCl H Cl4.313 CH.sub.3 H H 1 CH.sub.3 H H H C.dbd.NOCH.sub.2 CH.dbd.CHCl H Cl4.314 CH.sub.3 H H 2 CH.sub.3 H H H C.dbd.NOCH.sub.2 CH.dbd.CHCl H Cl4.315 CH.sub.3 H H 0 CH.sub.3 H H H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 H Cl4.316 CH.sub.3 H H 1 CH.sub.3 H H H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 H Cl4.317 CH.sub.3 H H 2 CH.sub.3 H H H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 H Cl4.318 CH.sub.3 H H 0 CH.sub.3 H H H C(CH.sub.3).sub.2 H Cl4.319 CH.sub.3 H H 1 CH.sub.3 H H H C(CH.sub.3).sub.2 H Cl4.320 CH.sub.3 H H 2 CH.sub.3 H H H C(CH.sub.3).sub.2 H Cl4.321 CH.sub.3 H H 0 CH.sub.3 H H H ##STR150## H Cl4.322 CH.sub.3 H H 1 CH.sub.3 H H H ##STR151## H Cl4.323 CH.sub.3 H H 2 CH.sub.3 H H H ##STR152## H Cl4.324 CH.sub.3 H H 0 CH.sub.3 H H H ##STR153## H Cl4.325 CH.sub.3 H H 1 CH.sub.3 H H H ##STR154## H Cl4.326 CH.sub.3 H H 2 CH.sub.3 H H H ##STR155## H Cl4.327 CH.sub.3 H H 0 CH.sub.3 H H H C.dbd.N--CH.sub.3 H Cl4.328 CH.sub.3 H H 1 CH.sub.3 H H H C.dbd.N--CH.sub.3 H Cl4.329 CH.sub.3 H H 2 CH.sub.3 H H H C.dbd.N--CH.sub.3 H Cl4.330 CH.sub.3 H H 0 CH.sub.3 H H H C.dbd.NC.sub.2 H.sub.5 H Cl4.331 CH.sub.3 H H 1 CH.sub.3 H H H C.dbd.NC.sub.2 H.sub.5 H Cl4.332 CH.sub.3 H H 2 CH.sub.3 H H H C.dbd.NC.sub.2 H.sub.5 H Cl4.333 CH.sub.3 H H 0 CH.sub.3 H H H CH--NHCH.sub.3 H Cl4.334 CH.sub.3 H H 1 CH.sub.3 H H H CH--NHCH.sub.3 H Cl4.335 CH.sub.3 H H 2 CH.sub.3 H H H CH--NHCH.sub.3 H Cl4.336 CH.sub.3 H H 0 CH.sub.3 H H H CH--NHC.sub.2 H.sub.5 H Cl4.337 CH.sub.3 H H 1 CH.sub.3 H H H CH--NHC.sub.2 H.sub.5 H Cl4.338 CH.sub.3 H H 2 CH.sub.3 H H H CH--NHC.sub.2 H.sub.5 H Cl4.339 CH.sub.3 H H 0 CH.sub.3 H H H CH--N(CH.sub.3).sub.2 H Cl4.340 CH.sub.3 H H 1 CH.sub.3 H H H CH--N(CH.sub.3).sub.2 H Cl4.341 CH.sub.3 H H 2 CH.sub.3 H H H CH--N(CH.sub.3).sub.2 H Cl4.342 CH.sub.3 H H 0 CH.sub.3 H H H CH--NHOC.sub.2 H.sub.5 H Cl4.343 CH.sub.3 H H 1 CH.sub.3 H H H CH--NHOC.sub.2 H.sub.5 H Cl4.344 CH.sub.3 H H 2 CH.sub.3 H H H CH--NHOC.sub.2 H.sub.5 H Cl4.345 CH.sub.3 H H 0 CH.sub.3 H H H CH--N(CH.sub.3)OC.sub.2 H.sub.5 H Cl4.346 CH.sub.3 H H 1 CH.sub.3 H H H CH--N(CH.sub.3)OC.sub.2 H.sub.5 H Cl4.347 CH.sub.3 H H 2 CH.sub.3 H H H CH--N(CH.sub.3)OC.sub.2 H.sub.5 H Cl4.348 CH.sub.3 H H 0 CH.sub.3 H H H C.dbd.N--NH.sub.2 H Cl4.349 CH.sub.3 H H 1 CH.sub.3 H H H C.dbd.N--NH.sub.2 H Cl4.350 CH.sub.3 H H 2 CH.sub.3 H H H C.dbd.N--NH.sub.2 H Cl4.351 CH.sub.3 H H 0 CH.sub.3 H H H C.dbd.N--N(CH.sub.3).sub.2 H Cl4.352 CH.sub.3 H H 1 CH.sub.3 H H H C.dbd.N--N(CH.sub.3).sub.2 H Cl4.353 CH.sub.3 H H 2 CH.sub.3 H H H C.dbd.N--N(CH.sub.3).sub.2 H Cl4.354 CH.sub.3 H H 0 CH.sub.3 H H H CH--N(CH.sub.3)OCH.sub.2 C.sub.6 H.sub.5 H Cl4.355 CH.sub.3 H H 1 CH.sub.3 H H H CH--N(CH.sub.3)OCH.sub.2 C.sub.6 H.sub.5 H Cl4.356 CH.sub.3 H H 2 CH.sub.3 H H H CH--N(CH.sub.3)OCH.sub.2 C.sub.6 H.sub.5 H Cl4.357 CH.sub.3 H H 0 CH.sub.3 H H H C(CH.sub.3)--OCH.sub.3 H Cl4.358 CH.sub.3 H H 1 CH.sub.3 H H H C(CH.sub.3)--OCH.sub.3 H Cl4.359 CH.sub.3 H H 2 CH.sub.3 H H H C(CH.sub.3)--OCH.sub.3 H Cl4.360 CH.sub.3 H H 0 CH.sub.3 H H H O H Cl4.361 CH.sub.3 H H 2 CH.sub.3 H H H O H Cl4.362 CH.sub.3 CH.sub.3 H 0 CH.sub.3 H H H C.dbd.O H Cl4.363 CH.sub.3 CH.sub.3 H 1 CH.sub.3 H H H C.dbd.O H Cl4.364 CH.sub.3 CH.sub.3 H 2 CH.sub.3 H H H C.dbd.O H Cl4.365 CH.sub.3 CH.sub.3 H 0 CH.sub.3 H H H CHOCH.sub.3 H Cl4.366 CH.sub.3 CH.sub.3 H 1 CH.sub.3 H H H CHOCH.sub.3 H Cl4.367 CH.sub.3 CH.sub.3 H 2 CH.sub.3 H H H CHOCH.sub.3 H Cl4.368 CH.sub.3 CH.sub.3 H 0 CH.sub.3 H H H CHOC.sub.2 H.sub.5 H Cl4.369 CH.sub.3 CH.sub.3 H 1 CH.sub.3 H H H CHOC.sub.2 H.sub.5 H Cl4.370 CH.sub.3 CH.sub.3 H 2 CH.sub.3 H H H CHOC.sub.2 H.sub.5 H Cl4.371 CH.sub.3 CH.sub.3 H 0 CH.sub.3 H H H CHOiPr H Cl4.372 CH.sub.3 CH.sub.3 H 1 CH.sub.3 H H H CHOiPr H Cl4.373 CH.sub.3 CH.sub.3 H 2 CH.sub.3 H H H CHOiPr H Cl4.374 CH.sub.3 CH.sub.3 H 0 CH.sub.3 H H H C.dbd.NOCH.sub.3 H Cl4.375 CH.sub.3 CH.sub.3 H 1 CH.sub.3 H H H C.dbd.NOCH.sub.3 H Cl4.376 CH.sub.3 CH.sub.3 H 2 CH.sub.3 H H H C.dbd.NOCH.sub.3 H Cl4.377 CH.sub.3 CH.sub.3 H 0 CH.sub.3 H H H C.dbd.NOC.sub.2 H.sub.5 H Cl4.378 CH.sub.3 CH.sub.3 H 1 CH.sub.3 H H H C.dbd.NOC.sub.2 H.sub.5 H Cl4.379 CH.sub.3 CH.sub.3 H 2 CH.sub.3 H H H C.dbd.NOC.sub.2 H.sub.5 H Cl4.380 CH.sub.3 CH.sub.3 H 0 CH.sub.3 H H H C.dbd.NOiPr H Cl4.381 CH.sub.3 CH.sub.3 H 1 CH.sub.3 H H H C.dbd.NOiPr H Cl4.382 CH.sub.3 CH.sub.3 H 2 CH.sub.3 H H H C.dbd.NOiPr H Cl4.383 CH.sub.3 CH.sub.3 H 0 CH.sub.3 H H H C.dbd.NOCH.sub.2 CH.dbd.CHCl H Cl4.384 CH.sub.3 CH.sub.3 H 1 CH.sub.3 H H H C.dbd.NOCH.sub.2 CH.dbd.CHCl H Cl4.385 CH.sub.3 CH.sub.3 H 2 CH.sub.3 H H H C.dbd.NOCH.sub.2 CH.dbd.CHCl H Cl4.386 CH.sub.3 CH.sub.3 H 0 CH.sub.3 H H H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 H Cl4.387 CH.sub.3 CH.sub.3 H 1 CH.sub.3 H H H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 H Cl4.388 CH.sub.3 CH.sub.3 H 2 CH.sub.3 H H H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 H Cl4.389 CH.sub.3 CH.sub.3 H 0 CH.sub.3 H H H C(CH.sub.3).sub.2 H Cl4.390 CH.sub.3 CH.sub.3 H 1 CH.sub.3 H H H C(CH.sub.3).sub.2 H Cl4.391 CH.sub.3 CH.sub.3 H 2 CH.sub.3 H H H C(CH.sub.3).sub.2 H Cl4.392 CH.sub.3 CH.sub.3 H 0 CH.sub.3 H H H ##STR156## H Cl4.393 CH.sub.3 CH.sub.3 H 1 CH.sub.3 H H H ##STR157## H Cl4.394 CH.sub.3 CH.sub.3 H 2 CH.sub.3 H H H ##STR158## H Cl4.395 CH.sub.3 CH.sub.3 H 0 CH.sub.3 H H H ##STR159## H Cl4.396 CH.sub.3 CH.sub.3 H 1 CH.sub.3 H H H ##STR160## H Cl4.397 CH.sub.3 CH.sub.3 H 2 CH.sub.3 H H H ##STR161## H Cl4.398 CH.sub.3 CH.sub.3 H 0 CH.sub.3 H H H C.dbd.N--CH.sub.3 H Cl4.399 CH.sub.3 CH.sub.3 H 1 CH.sub.3 H H H C.dbd.N--CH.sub.3 H Cl4.400 CH.sub.3 CH.sub.3 H 2 CH.sub.3 H H H C.dbd.N--CH.sub.3 H Cl4.401 CH.sub.3 CH.sub.3 H 0 CH.sub.3 H H H C.dbd.NC.sub.2 H.sub.5 H Cl4.402 CH.sub.3 CH.sub.3 H 1 CH.sub.3 H H H C.dbd.NC.sub.2 H.sub.5 H Cl4.403 CH.sub.3 CH.sub.3 H 2 CH.sub.3 H H H C.dbd.NC.sub.2 H.sub.5 H Cl4.404 CH.sub.3 CH.sub.3 H 0 CH.sub.3 H H H CH--NHCH.sub.3 H Cl4.405 CH.sub.3 CH.sub.3 H 1 CH.sub.3 H H H CH--NHCH.sub.3 H Cl4.406 CH.sub.3 CH.sub.3 H 2 CH.sub.3 H H H CH--NHCH.sub.3 H Cl4.407 CH.sub.3 CH.sub.3 H 0 CH.sub.3 H H H CH--NHC.sub.2 H.sub.5 H Cl4.408 CH.sub.3 CH.sub.3 H 1 CH.sub.3 H H H CH--NHC.sub.2 H.sub.5 H Cl4.409 CH.sub.3 CH.sub.3 H 2 CH.sub.3 H H H CH--NHC.sub.2 H.sub.5 H Cl4.410 CH.sub.3 CH.sub.3 H 0 CH.sub.3 H H H CH--N(CH.sub.3).sub.2 H Cl4.411 CH.sub.3 CH.sub.3 H 1 CH.sub.3 H H H CH--N(CH.sub.3).sub.2 H Cl4.412 CH.sub.3 CH.sub.3 H 2 CH.sub.3 H H H CH--N(CH.sub.3).sub.2 H Cl4.413 CH.sub.3 CH.sub.3 H 0 CH.sub.3 H H H CH--NHOC.sub.2 H.sub.5 H Cl4.414 CH.sub.3 CH.sub.3 H 1 CH.sub.3 H H H CH--NHOC.sub.2 H.sub.5 H Cl4.415 CH.sub.3 CH.sub.3 H 2 CH.sub.3 H H H CH--NHOC.sub.2 H.sub.5 H Cl4.416 CH.sub.3 CH.sub.3 H 0 CH.sub.3 H H H CH--N(CH.sub.3)OC.sub.2 H.sub.5 H Cl4.417 CH.sub.3 CH.sub.3 H 1 CH.sub.3 H H H CH--N(CH.sub.3)OC.sub.2 H.sub.5 H Cl4.418 CH.sub.3 CH.sub.3 H 2 CH.sub.3 H H H CH--N(CH.sub.3)OC.sub.2 H.sub.5 H Cl4.419 CH.sub.3 CH.sub.3 H 0 CH.sub.3 H H H C.dbd.N--NH.sub.2 H Cl4.420 CH.sub.3 CH.sub.3 H 1 CH.sub.3 H H H C.dbd.N--NH.sub.2 H Cl4.421 CH.sub.3 CH.sub.3 H 2 CH.sub.3 H H H C.dbd.N--NH.sub.2 H Cl4.422 CH.sub.3 CH.sub.3 H 0 CH.sub.3 H H H C.dbd.N--N(CH.sub.3).sub.2 H Cl4.423 CH.sub.3 CH.sub.3 H 1 CH.sub.3 H H H C.dbd.N--N(CH.sub.3).sub.2 H Cl4.424 CH.sub.3 CH.sub.3 H 2 CH.sub.3 H H H C.dbd.N--N(CH.sub.3).sub.2 H Cl4.425 CH.sub.3 CH.sub.3 H 0 CH.sub.3 H H H CH--N(CH.sub.3)OCH.sub.2 C.sub.6 H.sub.5 H Cl4.426 CH.sub.3 CH.sub.3 H 1 CH.sub.3 H H H CH--N(CH.sub.3)OCH.sub.2 C.sub.6 H.sub.5 H Cl4.427 CH.sub.3 CH.sub.3 H 2 CH.sub.3 H H H CH--N(CH.sub.3)OCH.sub.2 C.sub.6 H.sub.5 H Cl4.428 CH.sub.3 CH.sub.3 H 0 CH.sub.3 H H H C(CH.sub.3)--OCH.sub.3 H Cl4.429 CH.sub.3 CH.sub.3 H 1 CH.sub.3 H H H C(CH.sub.3)--OCH.sub.3 H Cl4.430 CH.sub.3 CH.sub.3 H 2 CH.sub.3 H H H C(CH.sub.3)--OCH.sub.3 H Cl4.431 CH.sub.3 CH.sub.3 H 0 CH.sub.3 H H H O H Cl4.432 CH.sub.3 CH.sub.3 H 2 CH.sub.3 H H H O H Cl4.433 H H H 0 CH.sub.3 H CH.sub.3 H C.dbd.O H CH.sub.34.434 H H H 1 CH.sub.3 H CH.sub.3 H C.dbd.O H CH.sub.34.435 H H H 2 CH.sub.3 H CH.sub.3 H C.dbd.O H CH.sub.34.436 H H H 0 CH.sub.3 H CH.sub.3 H CH--OCH.sub.3 H CH.sub.34.437 H H H 1 CH.sub.3 H CH.sub.3 H CH--OCH.sub.3 H CH.sub.34.438 H H H 2 CH.sub.3 H CH.sub.3 H CH--OCH.sub.3 H CH.sub.34.439 H H H 0 CH.sub.3 H CH.sub.3 H CHOC.sub.2 H.sub.5 H CH.sub.34.440 H H H 1 CH.sub.3 H CH.sub.3 H CHOC.sub.2 H.sub.5 H CH.sub.34.441 H H H 2 CH.sub.3 H CH.sub.3 H CHOC.sub.2 H.sub.5 H CH.sub.34.442 H H H 0 CH.sub.3 H CH.sub.3 H CHOiPr H CH.sub.34.443 H H H 1 CH.sub.3 H CH.sub.3 H CHOiPr H CH.sub.34.444 H H H 2 CH.sub.3 H CH.sub.3 H CHOiPr H CH.sub.34.445 H H H 0 CH.sub.3 H CH.sub.3 H C.dbd.NOCH.sub.3 H CH.sub.34.446 H H H 1 CH.sub.3 H CH.sub.3 H C.dbd.NOCH.sub.3 H CH.sub.34.447 H H H 2 CH.sub.3 H CH.sub.3 H C.dbd.NOCH.sub.3 H CH.sub.34.448 H H H 0 CH.sub.3 H CH.sub.3 H C.dbd.NOC.sub.2 H.sub.5 H CH.sub.34.449 H H H 1 CH.sub.3 H CH.sub.3 H C.dbd.NOC.sub.2 H.sub.5 H CH.sub.34.450 H H H 2 CH.sub.3 H CH.sub.3 H C.dbd.NOC.sub.2 H.sub.5 H CH.sub.34.451 H H H 0 CH.sub.3 H CH.sub.3 H C.dbd.NOiPr H CH.sub.34.452 H H H 1 CH.sub.3 H CH.sub.3 H C.dbd.NOC.sub.2 H.sub.5 H CH.sub.34.453 H H H 2 CH.sub.3 H CH.sub.3 H C.dbd.NOiPr H CH.sub.34.454 H H H 0 CH.sub.3 H CH.sub.3 H C.dbd.NOCH.sub.2 CH.dbd.CHCl H CH.sub.34.455 H H H 1 CH.sub.3 H CH.sub.3 H C.dbd.NOCH.sub.2 CH.dbd.CHCl H CH.sub.34.456 H H H 2 CH.sub.3 H CH.sub.3 H C.dbd.NOCH.sub.2 CH.dbd.CHCl H CH.sub.34.457 H H H 0 CH.sub.3 H CH.sub.3 H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 H CH.sub.34.458 H H H 1 CH.sub.3 H CH.sub.3 H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 H CH.sub.34.459 H H H 2 CH.sub.3 H CH.sub.3 H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 H CH.sub.34.460 H H H 0 CH.sub.3 H CH.sub.3 H C(CH.sub.3).sub.2 H CH.sub.34.461 H H H 1 CH.sub.3 H CH.sub.3 H C(CH.sub.3).sub.2 H CH.sub.34.462 H H H 2 CH.sub.3 H CH.sub.3 H C(CH.sub.3).sub.2 H CH.sub.34.463 H H H 0 CH.sub.3 H H ##STR162## H CH.sub.34.464 H H H 1 CH.sub.3 H H H ##STR163## H CH.sub.34.465 H H H 2 CH.sub.3 H H H ##STR164## H CH.sub.34.466 H H H 0 CH.sub.3 H H H ##STR165## H CH.sub.34.467 H H H 1 CH.sub.3 H H H ##STR166## H CH.sub.34.468 H H H 2 CH.sub.3 H H H ##STR167## H CH.sub.34.469 H H H 0 CH.sub.3 H H H C.dbd.N--CH.sub.3 H CH.sub.34.470 H H H 1 CH.sub.3 H H H C.dbd.N--CH.sub.3 H CH.sub.34.471 H H H 2 CH.sub.3 H H H C.dbd.N--CH.sub.3 H CH.sub.34.472 H H H 0 CH.sub.3 H H H C.dbd.NC.sub.2 H.sub.5 H CH.sub.34.473 H H H 1 CH.sub.3 H H H C.dbd.NC.sub.2 H.sub.5 H CH.sub.34.474 H H H 2 CH.sub.3 H H H C.dbd.NC.sub.2 H.sub.5 H CH.sub.34.475 H H H 0 CH.sub.3 H CH.sub.3 H CH--NHCH.sub.3 H CH.sub.34.476 H H H 1 CH.sub.3 H CH.sub.3 H CH--NHCH.sub.3 H CH.sub.34.477 H H H 2 CH.sub.3 H CH.sub.3 H CH--NHCH.sub.3 H CH.sub.34.478 H H H 0 CH.sub.3 H CH.sub.3 H CH--NHC.sub.2 H.sub.5 H CH.sub.34.479 H H H 1 CH.sub.3 H CH.sub.3 H CH--NHC.sub.2 H.sub.5 H CH.sub.34.480 H H H 2 CH.sub.3 H CH.sub.3 H CH--NHC.sub.2 H.sub.5 H CH.sub.34.481 H H H 0 CH.sub.3 H CH.sub.3 H CH--N(CH.sub.3).sub.2 H CH.sub.34.482 H H H 1 CH.sub.3 H CH.sub.3 H CH--N(CH.sub.3).sub.2 H CH.sub.34.483 H H H 2 CH.sub.3 H CH.sub.3 H CH--N(CH.sub.3).sub.2 H CH.sub.34.484 H H H 0 CH.sub.3 H CH.sub.3 H CH--NHOC.sub.2 H.sub.5 H CH.sub.34.485 H H H 1 CH.sub.3 H CH.sub.3 H CH--NHOC.sub.2 H.sub.5 H CH.sub.34.486 H H H 2 CH.sub.3 H CH.sub.3 H CH--NHOC.sub.2 H.sub.5 H CH.sub.34.487 H H H 0 CH.sub.3 H CH.sub.3 H CH--N(CH.sub.3)OC.sub.2 H.sub.5 H CH.sub.34.488 H H H 1 CH.sub.3 H CH.sub.3 H CH--N(CH.sub.3)OC.sub.2 H.sub.5 H CH.sub.34.489 H H H 2 CH.sub.3 H CH.sub.3 H CH--N(CH.sub.3)OC.sub.2 H.sub.5 H CH.sub.34.490 H H H 0 CH.sub.3 H CH.sub.3 H C.dbd.N--NH.sub.2 H CH.sub.34.491 H H H 1 CH.sub.3 H CH.sub.3 H C.dbd.N--NH.sub.2 H CH.sub.34.492 H H H 2 CH.sub.3 H CH.sub.3 H C.dbd.N--NH.sub.2 H CH.sub.34.493 H H H 0 CH.sub.3 H CH.sub.3 H C.dbd.N--N(CH.sub.3).sub.2 H CH.sub.34.494 H H H 1 CH.sub.3 H CH.sub.3 H C.dbd.N--N(CH.sub.3).sub.2 H CH.sub.34.495 H H H 2 CH.sub.3 H CH.sub.3 H C.dbd.N--N(CH.sub.3).sub.2 H CH.sub.34.496 H H H 0 CH.sub.3 H CH.sub.3 H CH--N(CH.sub.3)OCH.sub.2 C.sub.6 H.sub.5 H CH.sub.34.497 H H H 1 CH.sub.3 H CH.sub.3 H CH--N(CH.sub.3)OCH.sub.2 C.sub.6 H.sub.5 H CH.sub.34.498 H H H 2 CH.sub.3 H CH.sub.3 H CH--N(CH.sub.3)OCH.sub.2 C.sub.6 H.sub.5 H CH.sub.34.499 H H H 0 CH.sub.3 H CH.sub.3 H C(CH.sub.3)--OCH.sub.3 H CH.sub.34.500 H H H 1 CH.sub.3 H CH.sub.3 H C(CH.sub.3)--OCH.sub.3 H CH.sub.34.501 H H H 2 CH.sub.3 H CH.sub.3 H C(CH.sub.3)--OCH.sub.3 H CH.sub.34.502 H H H 0 CH.sub.3 H CH.sub.3 H O H CH.sub.34.503 H H H 2 CH.sub.3 H CH.sub.3 H O H CH.sub.34.504 CH.sub.3 H H 0 CH.sub.3 H CH.sub.3 H C.dbd.O H CH.sub.34.505 CH.sub.3 H H 1 CH.sub.3 H CH.sub.3 H C.dbd.O H CH.sub.34.506 CH.sub.3 H H 2 CH.sub.3 H CH.sub.3 H C.dbd.O H CH.sub.34.507 CH.sub.3 H H 0 CH.sub.3 H CH.sub.3 H CHOCH.sub.3 H CH.sub.34.508 CH.sub.3 H H 1 CH.sub.3 H CH.sub.3 H CHOCH.sub.3 H CH.sub.34.509 CH.sub.3 H H 2 CH.sub.3 H CH.sub.3 H CHOCH.sub.3 H CH.sub.34.510 CH.sub.3 H H 0 CH.sub.3 H CH.sub.3 H CHOC.sub.2 H.sub.5 H CH.sub.34.511 CH.sub.3 H H 1 CH.sub.3 H CH.sub.3 H CHOC.sub.2 H.sub.5 H CH.sub.34.512 CH.sub.3 H H 2 CH.sub.3 H CH.sub.3 H CHOC.sub.2 H.sub.5 H CH.sub.34.513 CH.sub.3 H H 0 CH.sub.3 H CH.sub.3 H CHOiPr H CH.sub.34.514 CH.sub.3 H H 1 CH.sub.3 H CH.sub.3 H CHOiPr H CH.sub.34.515 CH.sub.3 H H 2 CH.sub.3 H CH.sub.3 H CHOiPr H CH.sub.34.516 CH.sub.3 H H 0 CH.sub.3 H CH.sub.3 H C.dbd.NOCH.sub.3 H CH.sub.34.517 CH.sub.3 H H 1 CH.sub.3 H CH.sub.3 H C.dbd.NOCH.sub.3 H CH.sub.34.518 CH.sub.3 H H 2 CH.sub.3 H CH.sub.3 H C.dbd.NOCH.sub.3 H CH.sub.34.519 CH.sub.3 H H 0 CH.sub.3 H CH.sub.3 H C.dbd.NOC.sub.2 H.sub.5 H CH.sub.34.520 CH.sub.3 H H 1 CH.sub.3 H CH.sub.3 H C.dbd.NOC.sub.2 H.sub.5 H CH.sub.34.521 CH.sub.3 H H 2 CH.sub.3 H CH.sub.3 H C.dbd.NOC.sub.2 H.sub.5 H CH.sub.34.522 CH.sub.3 H H 0 CH.sub.3 H CH.sub.3 H C.dbd.NOiPr H CH.sub.34.523 CH.sub.3 H H 1 CH.sub.3 H CH.sub.3 H C.dbd.NOiPr H CH.sub.34.524 CH.sub.3 H H 2 CH.sub.3 H CH.sub.3 H C.dbd.NOiPr H CH.sub.34.525 CH.sub.3 H H 0 CH.sub.3 H CH.sub.3 H C.dbd.NOCH.sub.2 CH.dbd.CHCl H CH.sub.34.526 CH.sub.3 H H 1 CH.sub.3 H CH.sub.3 H C.dbd.NOCH.sub.2 CH.dbd.CHCl H CH.sub.34.527 CH.sub.3 H H 2 CH.sub.3 H CH.sub.3 H C.dbd.NOCH.sub.2 CH.dbd.CHCl H CH.sub.34.528 CH.sub.3 H H 0 CH.sub.3 H CH.sub.3 H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 H CH.sub.34.529 CH.sub.3 H H 1 CH.sub.3 H CH.sub.3 H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 H CH.sub.34.530 CH.sub.3 H H 2 CH.sub.3 H CH.sub.3 H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 H CH.sub.34.531 CH.sub.3 H H 0 CH.sub.3 H CH.sub.3 H C(CH.sub.3).sub.2 H CH.sub.34.532 CH.sub.3 H H 1 CH.sub.3 H CH.sub.3 H C(CH.sub.3).sub.2 H CH.sub.34.533 CH.sub.3 H H 2 CH.sub.3 H CH.sub.3 H C(CH.sub.3).sub.2 H CH.sub.34.534 CH.sub.3 H H 0 CH.sub.3 H CH.sub.3 H ##STR168## H CH.sub.34.535 CH.sub.3 H H 1 CH.sub.3 H CH.sub.3 H ##STR169## H CH.sub.34.536 CH.sub.3 H H 2 CH.sub.3 H CH.sub.3 H ##STR170## H CH.sub.34.537 CH.sub.3 H H 0 CH.sub.3 H CH.sub.3 H ##STR171## H CH.sub.34.538 CH.sub.3 H H 1 CH.sub.3 H CH.sub.3 H ##STR172## H CH.sub.34.539 CH.sub.3 H H 2 CH.sub.3 H CH.sub.3 H ##STR173## H CH.sub.34.540 CH.sub.3 H H 0 CH.sub.3 H CH.sub.3 H C.dbd.N--CH.sub.3 H CH.sub.34.541 CH.sub.3 H H 1 CH.sub.3 H CH.sub.3 H C.dbd.N--CH.sub.3 H CH.sub.34.542 CH.sub.3 H H 2 CH.sub.3 H CH.sub.3 H C.dbd.N--CH.sub.3 H CH.sub.34.543 CH.sub.3 H H 0 CH.sub.3 H CH.sub.3 H C.dbd.NC.sub.2 H.sub.5 H CH.sub.34.544 CH.sub.3 H H 1 CH.sub.3 H CH.sub.3 H C.dbd.NC.sub.2 H.sub.5 H CH.sub.34.545 CH.sub.3 H H 2 CH.sub.3 H CH.sub.3 H C.dbd.NC.sub.2 H.sub.5 H CH.sub.34.546 CH.sub.3 H H 0 CH.sub.3 H CH.sub.3 H CH--NHCH.sub.3 H CH.sub.34.547 CH.sub.3 H H 1 CH.sub.3 H CH.sub.3 H CH--NHCH.sub.3 H CH.sub.34.548 CH.sub.3 H H 2 CH.sub.3 H CH.sub.3 H CH--NHCH.sub.3 H CH.sub.34.549 CH.sub.3 H H 0 CH.sub.3 H CH.sub.3 H CH--NHC.sub.2 H.sub.5 H CH.sub.34.550 CH.sub.3 H H 1 CH.sub.3 H CH.sub.3 H CH--NHC.sub.2 H.sub.5 H CH.sub.34.551 CH.sub.3 H H 2 CH.sub.3 H CH.sub.3 H CH--NHC.sub.2 H.sub.5 H CH.sub.34.552 CH.sub.3 H H 0 CH.sub.3 H CH.sub.3 H CH--N(CH.sub.3).sub.2 H CH.sub.34.553 CH.sub.3 H H 1 CH.sub.3 H CH.sub.3 H CH--N(CH.sub.3).sub.2 H CH.sub.34.554 CH.sub.3 H H 2 CH.sub.3 H CH.sub.3 H CH--N(CH.sub.3).sub.2 H CH.sub.34.555 CH.sub.3 H H 0 CH.sub.3 H CH.sub.3 H CH--NHOC.sub.2 H.sub.5 H CH.sub.34.556 CH.sub.3 H H 1 CH.sub.3 H CH.sub.3 H CH--NHOC.sub.2 H.sub.5 H CH.sub.34.557 CH.sub.3 H H 2 CH.sub.3 H CH.sub.3 H CH--NHOC.sub.2 H.sub.5 H CH.sub.34.558 CH.sub.3 H H 0 CH.sub.3 H CH.sub.3 H CH--N(CH.sub.3)OC.sub.2 H.sub.5 H CH.sub.34.559 CH.sub.3 H H 1 CH.sub.3 H CH.sub.3 H CH--N(CH.sub.3)OC.sub.2 H.sub.5 H CH.sub.34.560 CH.sub.3 H H 2 CH.sub.3 H CH.sub.3 H CH--N(CH.sub.3)OC.sub.2 H.sub.5 H CH.sub.34.561 CH.sub.3 H H 0 CH.sub.3 H CH.sub.3 H C.dbd.N--NH.sub.2 H CH.sub.34.562 CH.sub.3 H H 1 CH.sub.3 H CH.sub.3 H C.dbd.N--NH.sub.2 H CH.sub.34.563 CH.sub.3 H H 2 CH.sub.3 H CH.sub.3 H C.dbd.N--NH.sub.2 H CH.sub.34.564 CH.sub.3 H H 0 CH.sub.3 H CH.sub.3 H C.dbd.N--N(CH.sub.3).sub.2 H CH.sub.34.565 CH.sub.3 H H 1 CH.sub.3 H CH.sub.3 H C.dbd.N--N(CH.sub.3).sub.2 H CH.sub.34.566 CH.sub.3 H H 2 CH.sub.3 H CH.sub.3 H C.dbd.N--N(CH.sub.3).sub.2 H CH.sub.34.567 CH.sub.3 H H 0 CH.sub.3 H CH.sub.3 H CH--N(CH.sub.3)OCH.sub.2 C.sub.6 H.sub.5 H CH.sub.34.568 CH.sub.3 H H 1 CH.sub.3 H CH.sub.3 H CH--N(CH.sub.3)OCH.sub.2 C.sub.6 H.sub.5 H CH.sub.34.569 CH.sub.3 H H 2 CH.sub.3 H CH.sub.3 H CH--N(CH.sub.3)OCH.sub.2 C.sub.6 H.sub.5 H CH.sub.34.570 CH.sub.3 H H 0 CH.sub.3 H CH.sub.3 H C(CH.sub.3)--OCH.sub.3 H CH.sub.34.571 CH.sub.3 H H 1 CH.sub.3 H CH.sub.3 H C(CH.sub.3)--OCH.sub.3 H CH.sub.34.572 CH.sub.3 H H 2 CH.sub.3 H CH.sub.3 H C(CH.sub.3)--OCH.sub.3 H CH.sub.34.573 CH.sub.3 H H 0 CH.sub.3 H CH.sub.3 H O H CH.sub.34.574 CH.sub.3 H H 2 CH.sub.3 H CH.sub.3 H O H CH.sub.34.575 CH.sub.3 CH.sub.3 H 0 CH.sub.3 H CH.sub.3 H C.dbd.O H CH.sub.34.576 CH.sub.3 CH.sub.3 H 1 CH.sub.3 H CH.sub.3 H C.dbd.O H CH.sub.34.577 CH.sub.3 CH.sub.3 H 2 CH.sub.3 H CH.sub.3 H C.dbd.O H CH.sub.34.578 CH.sub.3 CH.sub.3 H 0 CH.sub.3 H CH.sub.3 H CHOCH.sub.3 H CH.sub.34.579 CH.sub.3 CH.sub.3 H 1 CH.sub.3 H CH.sub.3 H CHOCH.sub.3 H CH.sub.34.580 CH.sub.3 CH.sub.3 H 2 CH.sub.3 H CH.sub.3 H CHOCH.sub.3 H CH.sub.34.581 CH.sub.3 CH.sub.3 H 0 CH.sub.3 H CH.sub.3 H CHOC.sub.2 H.sub.5 H CH.sub.34.582 CH.sub.3 CH.sub.3 H 1 CH.sub.3 H CH.sub.3 H CHOC.sub.2 H.sub.5 H CH.sub.34.583 CH.sub.3 CH.sub.3 H 2 CH.sub.3 H CH.sub.3 H CHOC.sub.2 H.sub.5 H CH.sub.34.584 CH.sub.3 CH.sub.3 H 0 CH.sub.3 H CH.sub.3 H CHOiPr H CH.sub.34.585 CH.sub.3 CH.sub.3 H 1 CH.sub.3 H CH.sub.3 H CHOiPr H CH.sub.34.586 CH.sub.3 CH.sub.3 H 2 CH.sub.3 H CH.sub.3 H CHOiPr H CH.sub.34.587 CH.sub.3 CH.sub.3 H 0 CH.sub.3 H CH.sub.3 H C.dbd.NOCH.sub.3 H CH.sub.34.588 CH.sub.3 CH.sub.3 H 1 CH.sub.3 H CH.sub.3 H C.dbd.NOCH.sub.3 H CH.sub.34.589 CH.sub.3 CH.sub.3 H 2 CH.sub.3 H CH.sub.3 H C.dbd.NOCH.sub.3 H CH.sub.34.590 CH.sub.3 CH.sub.3 H 0 CH.sub.3 H CH.sub.3 H C.dbd.NOC.sub.2 H.sub.5 H CH.sub.34.591 CH.sub.3 CH.sub.3 H 1 CH.sub.3 H CH.sub.3 H C.dbd.NOC.sub.2 H.sub.5 H CH.sub.34.592 CH.sub.3 CH.sub.3 H 2 CH.sub.3 H CH.sub.3 H C.dbd.NOC.sub.2 H.sub.5 H CH.sub.34.593 CH.sub.3 CH.sub.3 H 0 CH.sub.3 H CH.sub.3 H C.dbd.NOiPr H CH.sub.34.594 CH.sub.3 CH.sub.3 H 1 CH.sub.3 H CH.sub.3 H C.dbd.NOiPr H CH.sub.34.595 CH.sub.3 CH.sub.3 H 2 CH.sub.3 H CH.sub.3 H C.dbd.NOiPr H CH.sub.34.596 CH.sub.3 CH.sub.3 H 0 CH.sub.3 H CH.sub.3 H C.dbd.NOCH.sub.2 CH.dbd.CHCl H CH.sub.34.597 CH.sub.3 CH.sub.3 H 1 CH.sub.3 H CH.sub.3 H C.dbd.NOCH.sub.2 CH.dbd.CHCl H CH.sub.34.598 CH.sub.3 CH.sub.3 H 2 CH.sub.3 H CH.sub.3 H C.dbd.NOCH.sub.2 CH.dbd.CHCl H CH.sub.34.599 CH.sub.3 CH.sub.3 H 0 CH.sub.3 H CH.sub.3 H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 H CH.sub.34.600 CH.sub.3 CH.sub.3 H 1 CH.sub.3 H CH.sub.3 H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 H CH.sub.34.601 CH.sub.3 CH.sub.3 H 2 CH.sub.3 H CH.sub.3 H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 H CH.sub.34.602 CH.sub.3 CH.sub.3 H 0 CH.sub.3 H CH.sub.3 H C(CH.sub.3).sub.2 H CH.sub.34.603 CH.sub.3 CH.sub.3 H 1 CH.sub.3 H CH.sub.3 H C(CH.sub.3).sub.2 H CH.sub.34.604 CH.sub.3 CH.sub.3 H 2 CH.sub.3 H CH.sub.3 H C(CH.sub.3).sub.2 H CH.sub.34.605 CH.sub.3 CH.sub.3 H 0 CH.sub.3 H CH.sub.3 H ##STR174## H CH.sub.34.606 CH.sub.3 CH.sub.3 C H 1 CH.sub.3 H CH.sub.3 H ##STR175## H CH.sub.34.607 CH.sub.3 CH.sub.3 H 2 CH.sub.3 H CH.sub.3 H ##STR176## H CH.sub.34.608 CH.sub.3 CH.sub.3 H 0 CH.sub.3 H CH.sub.3 H ##STR177## H CH.sub.34.609 CH.sub.3 CH.sub.3 H 1 CH.sub.3 H CH.sub.3 H ##STR178## H CH.sub.34.610 CH.sub.3 CH.sub.3 H 2 CH.sub.3 H CH.sub.3 H ##STR179## H CH.sub.34.611 CH.sub.3 CH.sub.3 H 0 CH.sub.3 H CH.sub.3 H C.dbd.N--CH.sub.3 H CH.sub.34.612 CH.sub.3 CH.sub.3 H 1 CH.sub.3 H CH.sub.3 H C.dbd.N--CH.sub.3 H CH.sub.34.613 CH.sub.3 CH.sub.3 H 2 CH.sub.3 H CH.sub.3 H C.dbd.N--CH.sub.3 H CH.sub.34.614 CH.sub.3 CH.sub.3 H 0 CH.sub.3 H CH.sub.3 H C.dbd.NC.sub.2 H.sub.5 H CH.sub.34.615 CH.sub.3 CH.sub.3 H 1 CH.sub.3 H CH.sub.3 H C.dbd.NC.sub.2 H.sub.5 H CH.sub.34.616 CH.sub.3 CH.sub.3 H 2 CH.sub.3 H CH.sub.3 H C.dbd.NC.sub.2 H.sub.5 H CH.sub.34.617 CH.sub.3 CH.sub.3 H 0 CH.sub.3 H CH.sub.3 H CH--NHCH.sub.3 H CH.sub.34.618 CH.sub.3 CH.sub.3 H 1 CH.sub.3 H CH.sub.3 H CH--NHCH.sub.3 H CH.sub.34.619 CH.sub.3 CH.sub.3 H 2 CH.sub.3 H CH.sub.3 H CH--NHCH.sub.3 H CH.sub.34.620 CH.sub.3 CH.sub.3 H 0 CH.sub.3 H CH.sub.3 H CH--NHC.sub.2 H.sub.5 H CH.sub.34.621 CH.sub.3 CH.sub.3 H 1 CH.sub.3 H CH.sub.3 H CH--NHC.sub.2 H.sub.5 H CH.sub.34.622 CH.sub.3 CH.sub.3 H 2 CH.sub.3 H CH.sub.3 H CH--NHC.sub.2 H.sub.5 H CH.sub.34.623 CH.sub.3 CH.sub.3 H 0 CH.sub.3 H CH.sub.3 H CH--N(CH.sub.3).sub.2 H CH.sub.34.624 CH.sub.3 CH.sub.3 H 1 CH.sub.3 H CH.sub.3 H CH--N(CH.sub.3).sub.2 H CH.sub.34.625 CH.sub.3 CH.sub.3 H 2 CH.sub.3 H CH.sub.3 H CH--N(CH.sub.3).sub.2 H CH.sub.34.626 CH.sub.3 CH.sub.3 H 0 CH.sub.3 H CH.sub.3 H CH--NHOC.sub.2 H.sub.5 H CH.sub.34.627 CH.sub.3 CH.sub.3 H 1 CH.sub.3 H CH.sub.3 H CH--NHOC.sub.2 H.sub.5 H CH.sub.34.628 CH.sub.3 CH.sub.3 H 2 CH.sub.3 H CH.sub.3 H CH--NHOC.sub.2 H.sub.5 H CH.sub.34.629 CH.sub.3 CH.sub.3 H 0 CH.sub.3 H CH.sub.3 H CH--N(CH.sub.3)OC.sub.2 H.sub.5 H CH.sub.34.630 CH.sub.3 CH.sub.3 H 1 CH.sub.3 H CH.sub.3 H CH--N(CH.sub.3)OC.sub.2 H.sub.5 H CH.sub.34.631 CH.sub.3 CH.sub.3 H 2 CH.sub.3 H CH.sub.3 H CH--N(CH.sub.3)OC.sub.2 H.sub.5 H CH.sub.34.632 CH.sub.3 CH.sub.3 H 0 CH.sub.3 H CH.sub.3 H C.dbd.N--NH.sub.2 H CH.sub.34.633 CH.sub.3 CH.sub.3 H 1 CH.sub.3 H CH.sub.3 H C.dbd.N--NH.sub.2 H CH.sub.34.634 CH.sub.3 CH.sub.3 H 2 CH.sub.3 H CH.sub.3 H C.dbd.N--NH.sub.2 H CH.sub.34.635 CH.sub.3 CH.sub.3 H 0 CH.sub.3 H CH.sub.3 H C.dbd.N--N(CH.sub.3).sub.2 H CH.sub.34.636 CH.sub.3 CH.sub.3 H 1 CH.sub.3 H CH.sub.3 H C.dbd.N--N(CH.sub.3).sub.2 H CH.sub.34.637 CH.sub.3 CH.sub.3 H 2 CH.sub.3 H CH.sub.3 H C.dbd.N--N(CH.sub.3).sub.2 H CH.sub.34.638 CH.sub.3 CH.sub.3 H 0 CH.sub.3 H CH.sub.3 H CH--N(CH.sub.3)OCH.sub.2 C.sub.6 H.sub.5 H CH.sub.34.639 CH.sub.3 CH.sub.3 H 1 CH.sub.3 H CH.sub.3 H CH--N(CH.sub.3)OCH.sub.2 C.sub.6 H.sub.5 H CH.sub.34.640 CH.sub.3 CH.sub.3 H 2 CH.sub.3 H CH.sub.3 H CH--N(CH.sub.3)OCH.sub.2 C.sub.6 H.sub.5 H CH.sub.34.641 CH.sub.3 CH.sub.3 H 0 CH.sub.3 H CH.sub.3 H C(CH.sub.3)--OCH.sub.3 H CH.sub.34.642 CH.sub.3 CH.sub.3 H 1 CH.sub.3 H CH.sub.3 H C(CH.sub.3)--OCH.sub.3 H CH.sub.34.643 CH.sub.3 CH.sub.3 H 2 CH.sub.3 H CH.sub.3 H C(CH.sub.3)--OCH.sub.3 H CH.sub.34.644 CH.sub.3 CH.sub.3 H 0 CH.sub.3 H CH.sub.3 H O H CH.sub.34.645 CH.sub.3 CH.sub.3 H 2 CH.sub.3 H CH.sub.3 H O H CH.sub.34.646 H H H 0 CH.sub.3 H CH.sub.3 H C.dbd.O H Cl4.647 H H H 1 CH.sub.3 H CH.sub.3 H C.dbd.O H Cl4.648 H H H 2 CH.sub.3 H CH.sub.3 H C.dbd.O H Cl4.649 H H H 0 CH.sub.3 H CH.sub.3 H CHOCH.sub.3 H Cl4.650 H H H 1 CH.sub.3 H CH.sub.3 H CHOCH.sub.3 H Cl4.651 H H H 2 CH.sub.3 H CH.sub.3 H CHOCH.sub.3 H Cl4.652 H H H 0 CH.sub.3 H CH.sub.3 H CHOC.sub.2 H.sub.5 H Cl4.653 H H H 1 CH.sub.3 H CH.sub.3 H CHOC.sub.2 H.sub.5 H Cl4.654 H H H 2 CH.sub.3 H CH.sub.3 H CHOC.sub.2 H.sub.5 H Cl4.655 H H H 0 CH.sub.3 H CH.sub.3 H CHOiPr H Cl4.656 H H H 1 CH.sub.3 H CH.sub.3 H CHOiPr H Cl4.657 H H H 2 CH.sub.3 H CH.sub.3 H CHOiPr H Cl4.658 H H H 0 CH.sub.3 H CH.sub.3 H C.dbd.NOCH.sub.3 H Cl4.659 H H H 1 CH.sub.3 H CH.sub.3 H C.dbd.NOCH.sub.3 H Cl4.660 H H H 2 CH.sub.3 H CH.sub.3 H C.dbd.NOCH.sub.3 H Cl4.661 H H H 0 CH.sub.3 H CH.sub.3 H C.dbd.NOC.sub.2 H.sub.5 H Cl4.662 H H H 1 CH.sub.3 H CH.sub.3 H C.dbd.NOC.sub.2 H.sub.5 H Cl4.663 H H H 2 CH.sub.3 H CH.sub.3 H C.dbd.NOC.sub.2 H.sub.5 H Cl4.664 H H H 0 CH.sub.3 H CH.sub.3 H C.dbd.NOiPr H Cl4.665 H H H 1 CH.sub.3 H CH.sub.3 H C.dbd.NOiPr H Cl4.666 H H H 2 CH.sub.3 H CH.sub.3 H C.dbd.NOiPr H Cl4.667 H H H 0 CH.sub.3 H CH.sub.3 H C.dbd.NOCH.sub.2 CH.dbd.CHCl H Cl4.668 H H H 1 CH.sub.3 H CH.sub.3 H C.dbd.NOCH.sub.2 CH.dbd.CHCl H Cl4.669 H H H 2 CH.sub.3 H CH.sub.3 H C.dbd.NOCH.sub.2 CH.dbd.CHCl H Cl4.670 H H H 0 CH.sub.3 H CH.sub.3 H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 H Cl4.671 H H H 1 CH.sub.3 H CH.sub.3 H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 H Cl4.672 H H H 2 CH.sub.3 H CH.sub.3 H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 H Cl4.673 H H H 0 CH.sub.3 H CH.sub.3 H C(CH.sub.3).sub.2 H Cl4.674 H H H 1 CH.sub.3 H CH.sub.3 H C(CH.sub.3).sub.2 H Cl4.675 H H H 2 CH.sub.3 H CH.sub.3 H C(CH.sub.3).sub.2 H Cl4.676 H H H 0 CH.sub.3 H CH.sub.3 H ##STR180## H Cl4.677 H H H 1 CH.sub.3 H CH.sub.3 H ##STR181## H Cl4.678 H H H 2 CH.sub.3 H CH.sub.3 H ##STR182## H Cl4.679 H H H 0 CH.sub.3 H CH.sub.3 H ##STR183## H Cl4.680 H H H 1 CH.sub.3 H CH.sub.3 H ##STR184## H Cl4.681 H H H 2 CH.sub.3 H CH.sub.3 H ##STR185## H Cl4.682 H H H 0 CH.sub.3 H CH.sub.3 H C.dbd.N--CH.sub.3 H Cl4.683 H H H 1 CH.sub.3 H CH.sub.3 H C.dbd.N--CH.sub.3 H Cl4.684 H H H 2 CH.sub.3 H CH.sub.3 H C.dbd.N--CH.sub.3 H Cl4.685 H H H 0 CH.sub.3 H CH.sub.3 H C.dbd.NC.sub.2 H.sub.5 H Cl4.686 H H H 1 CH.sub.3 H CH.sub.3 H C.dbd.NC.sub.2 H.sub.5 H Cl4.687 H H H 2 CH.sub.3 H CH.sub.3 H C.dbd.NC.sub.2 H.sub.5 H Cl4.688 H H H 0 CH.sub.3 H CH.sub.3 H CH--NHCH.sub.3 H Cl4.689 H H H 1 CH.sub.3 H CH.sub.3 H CH--NHCH.sub.3 H Cl4.690 H H H 2 CH.sub.3 H CH.sub.3 H CH--NHCH.sub.3 H Cl4.691 H H H 0 CH.sub.3 H CH.sub.3 H CH--NHC.sub.2 H.sub.5 H Cl4.692 H H H 1 CH.sub.3 H CH.sub.3 H CH--NHC.sub.2 H.sub.5 H Cl4.693 H H H 2 CH.sub.3 H CH.sub.3 H CH--NHC.sub.2 H.sub.5 H Cl4.694 H H H 0 CH.sub.3 H CH.sub.3 H CH--N(CH.sub.3).sub.2 H Cl4.695 H H H 1 CH.sub.3 H CH.sub.3 H CH--N(CH.sub.3).sub.2 H Cl4.696 H H H 2 CH.sub.3 H CH.sub.3 H CH--N(CH.sub.3).sub.2 H Cl4.697 H H H 0 CH.sub.3 H CH.sub.3 H CH--NHOC.sub.2 H.sub.5 H Cl4.698 H H H 1 CH.sub.3 H CH.sub.3 H CH--NHOC.sub.2 H.sub.5 H Cl4.699 H H H 2 CH.sub.3 H CH.sub.3 H CH--NHOC.sub.2 H.sub.5 H Cl4.700 H H H 0 CH.sub.3 H CH.sub.3 H CH--N(CH.sub.3)OC.sub.2 H.sub.5 H Cl4.701 H H H 1 CH.sub.3 H CH.sub.3 H CH--N(CH.sub.3)OC.sub.2 H.sub.5 H Cl4.702 H H H 2 CH.sub.3 H CH.sub.3 H CH--N(CH.sub.3)OC.sub.2 H.sub.5 H Cl4.703 H H H 0 CH.sub.3 H CH.sub.3 H C.dbd.N--NH.sub.2 H Cl4.704 H H H 1 CH.sub.3 H CH.sub.3 H C.dbd.N--NH.sub.2 H Cl4.705 H H H 2 CH.sub.3 H CH.sub.3 H C.dbd.N--NH.sub.2 H Cl4.706 H H H 0 CH.sub.3 H CH.sub.3 H C.dbd.N--N(CH.sub.3).sub.2 H Cl4.707 H H H 1 CH.sub.3 H CH.sub.3 H C.dbd.N--N(CH.sub.3).sub.2 H Cl4.708 H H H 2 CH.sub.3 H CH.sub.3 H C.dbd.N--N(CH.sub.3).sub.2 H Cl4.709 H H H 0 CH.sub.3 H CH.sub.3 H CH--N(CH.sub.3)OCH.sub.2 C.sub.6 H.sub.5 H Cl4.710 H H H 1 CH.sub.3 H CH.sub.3 H CH--N(CH.sub.3)OCH.sub.2 C.sub.6 H.sub.5 H Cl4.711 H H H 2 CH.sub.3 H CH.sub.3 H CH--N(CH.sub.3)OCH.sub.2 C.sub.6 H.sub.5 H Cl4.712 H H H 0 CH.sub.3 H CH.sub.3 H C(CH.sub.3)--OCH.sub.3 H Cl4.713 H H H 1 CH.sub.3 H CH.sub.3 H C(CH.sub.3)--OCH.sub.3 H Cl4.714 H H H 2 CH.sub.3 H CH.sub.3 H C(CH.sub.3)--OCH.sub.3 H Cl4.715 H H H 0 CH.sub.3 H CH.sub.3 H O H Cl4.716 H H H 2 CH.sub.3 H CH.sub.3 H O H Cl4.717 CH.sub.3 H H 0 CH.sub.3 H CH.sub.3 H C.dbd.O H Cl4.718 CH.sub.3 H H 1 CH.sub.3 H CH.sub.3 H C.dbd.O H Cl4.719 CH.sub.3 H H 2 CH.sub.3 H CH.sub.3 H C.dbd.O H Cl4.720 CH.sub.3 H H 0 CH.sub.3 H CH.sub.3 H CHOCH.sub.3 H Cl4.721 CH.sub.3 H H 1 CH.sub.3 H CH.sub.3 H CHOCH.sub.3 H Cl4.722 CH.sub.3 H H 2 CH.sub.3 H CH.sub.3 H CHOCH.sub.3 H Cl4.723 CH.sub.3 H H 0 CH.sub.3 H CH.sub.3 H CHOC.sub.2 H.sub.5 H Cl4.724 CH.sub.3 H H 1 CH.sub.3 H CH.sub.3 H CHOC.sub.2 H.sub.5 H Cl4.725 CH.sub.3 H H 2 CH.sub.3 H CH.sub.3 H CHOC.sub.2 H.sub.5 H Cl4.726 CH.sub.3 H H 0 CH.sub.3 H CH.sub.3 H CHOiPr H Cl4.727 CH.sub.3 H H 1 CH.sub.3 H CH.sub.3 H CHOiPr H Cl4.728 CH.sub.3 H H 2 CH.sub.3 H CH.sub.3 H CHOiPr H Cl4.729 CH.sub.3 H H 0 CH.sub.3 H CH.sub.3 H C.dbd.NOCH.sub.3 H Cl4.730 CH.sub.3 H H 1 CH.sub.3 H CH.sub.3 H C.dbd.NOCH.sub.3 H Cl4.731 CH.sub.3 H H 2 CH.sub.3 H CH.sub.3 H C.dbd.NOCH.sub.3 H Cl4.732 CH.sub.3 H H 0 CH.sub.3 H CH.sub.3 H C.dbd.NOC.sub.2 H.sub.5 H Cl4.733 CH.sub.3 H H 1 CH.sub.3 H CH.sub.3 H C.dbd.NOC.sub.2 H.sub.5 H Cl4.734 CH.sub.3 H H 2 CH.sub.3 H CH.sub.3 H C.dbd.NOC.sub.2 H.sub.5 H Cl4.735 CH.sub.3 H H 0 CH.sub.3 H CH.sub.3 H C.dbd.NOiPr H Cl4.736 CH.sub.3 H H 1 CH.sub.3 H CH.sub.3 H C.dbd.NOiPr H Cl4.737 CH.sub.3 H H 2 CH.sub.3 H CH.sub.3 H C.dbd.NOiPr H Cl4.738 CH.sub.3 H H 0 CH.sub.3 H CH.sub.3 H C.dbd.NOCH.sub.2 CH.dbd.CHCl H Cl4.739 CH.sub.3 H H 1 CH.sub.3 H CH.sub.3 H C.dbd.NOCH.sub.2 CH.dbd.CHCl H Cl4.740 CH.sub.3 H H 2 CH.sub.3 H CH.sub.3 H C.dbd.NOCH.sub.2 CH.dbd.CHCl H Cl4.741 CH.sub.3 H H 0 CH.sub.3 H CH.sub.3 H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 H Cl4.742 CH.sub.3 H H 1 CH.sub.3 H CH.sub.3 H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 H Cl4.743 CH.sub.3 H H 2 CH.sub.3 H CH.sub.3 H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 H Cl4.744 CH.sub.3 H H 0 CH.sub.3 H CH.sub.3 H C(CH.sub.3).sub.2 H Cl4.745 CH.sub.3 H H 1 CH.sub.3 H CH.sub.3 H C(CH.sub.3).sub.2 H Cl4.746 CH.sub.3 H H 2 CH.sub.3 H CH.sub.3 H C(CH.sub.3).sub.2 H Cl4.747 CH.sub.3 H H 0 CH.sub.3 H CH.sub.3 H ##STR186## H Cl4.748 CH.sub.3 H H 1 CH.sub.3 H CH.sub.3 H ##STR187## H Cl4.749 CH.sub.3 H H 2 CH.sub.3 H CH.sub.3 H ##STR188## H Cl4.750 CH.sub.3 H H 0 CH.sub.3 H CH.sub.3 H ##STR189## H Cl4.751 CH.sub.3 H H 1 CH.sub.3 H CH.sub.3 H ##STR190## H Cl4.752 CH.sub.3 H H 2 CH.sub.3 H CH.sub.3 H ##STR191## H Cl4.753 CH.sub.3 H H 0 CH.sub.3 H CH.sub.3 H C.dbd.N--CH.sub.3 H Cl4.754 CH.sub.3 H H 1 CH.sub.3 H CH.sub.3 H C.dbd.N--CH.sub.3 H Cl4.755 CH.sub.3 H H 2 CH.sub.3 H CH.sub.3 H C.dbd.N--CH.sub.3 H Cl4.756 CH.sub.3 H H 0 CH.sub.3 H CH.sub.3 H C.dbd.NC.sub.2 H.sub.5 H Cl4.757 CH.sub.3 H H 1 CH.sub.3 H CH.sub.3 H C.dbd.NC.sub.2 H.sub.5 H Cl4.758 CH.sub.3 H H 2 CH.sub.3 H CH.sub.3 H C.dbd.NC.sub.2 H.sub.5 H Cl4.759 CH.sub.3 H H 0 CH.sub.3 H CH.sub.3 H CH--NHCH.sub.3 H Cl4.760 CH.sub.3 H H 1 CH.sub.3 H CH.sub.3 H CH--NHCH.sub.3 H Cl4.761 CH.sub.3 H H 2 CH.sub.3 H CH.sub.3 H CH--NHCH.sub.3 H Cl4.762 CH.sub.3 H H 0 CH.sub.3 H CH.sub.3 H CH--NHC.sub.2 H.sub.5 H Cl4.763 CH.sub.3 H H 1 CH.sub.3 H CH.sub.3 H CH--NHC.sub.2 H.sub.5 H Cl4.764 CH.sub.3 H H 2 CH.sub.3 H CH.sub.3 H CH--NHC.sub.2 H.sub.5 H Cl4.765 CH.sub.3 H H 0 CH.sub.3 H CH.sub.3 H CH--N(CH.sub.3).sub.2 H Cl4.766 CH.sub.3 H H 1 CH.sub.3 H CH.sub.3 H CH--N(CH.sub.3).sub.2 H Cl4.767 CH.sub.3 H H 2 CH.sub.3 H CH.sub.3 H CH--N(CH.sub.3).sub.2 H Cl4.768 CH.sub.3 H H 0 CH.sub.3 H CH.sub.3 H CH--NHOC.sub.2 H.sub.5 H Cl4.769 CH.sub.3 H H 1 CH.sub.3 H CH.sub.3 H CH--NHOC.sub.2 H.sub.5 H Cl4.770 CH.sub.3 H H 2 CH.sub.3 H CH.sub.3 H CH--NHOC.sub.2 H.sub.5 H Cl4.771 CH.sub.3 H H 0 CH.sub.3 H CH.sub.3 H CH--N(CH.sub.3)OC.sub.2 H.sub.5 H Cl4.772 CH.sub.3 H H 1 CH.sub.3 H CH.sub.3 H CH--N(CH.sub.3)OC.sub.2 H.sub.5 H Cl4.773 CH.sub.3 H H 2 CH.sub.3 H CH.sub.3 H CH--N(CH.sub.3)OC.sub.2 H.sub.5 H Cl4.774 CH.sub.3 H H 0 CH.sub.3 H CH.sub.3 H C.dbd.N--NH.sub.2 H Cl4.775 CH.sub.3 H H 1 CH.sub.3 H CH.sub.3 H C.dbd.N--NH.sub.2 H Cl4.776 CH.sub.3 H H 2 CH.sub.3 H CH.sub.3 H C.dbd.N--NH.sub.2 H Cl4.777 CH.sub.3 H H 0 CH.sub.3 H CH.sub.3 H C.dbd.N--N(CH.sub.3).sub.2 H Cl4.778 CH.sub.3 H H 1 CH.sub.3 H CH.sub.3 H C.dbd.N--N(CH.sub.3).sub.2 H Cl4.779 CH.sub.3 H H 2 CH.sub.3 H CH.sub.3 H C.dbd.N--N(CH.sub.3).sub.2 H Cl4.780 CH.sub.3 H H 0 CH.sub.3 H CH.sub.3 H CH--N(CH.sub.3)OCH.sub.2 C.sub.6 H.sub.5 H Cl4.781 CH.sub.3 H H 1 CH.sub.3 H CH.sub.3 H CH--N(CH.sub.3)OCH.sub.2 C.sub.6 H.sub.5 H Cl4.782 CH.sub.3 H H 2 CH.sub.3 H CH.sub.3 H CH--N(CH.sub.3)OCH.sub.2 C.sub.6 H.sub.5 H Cl4.783 CH.sub.3 H H 0 CH.sub.3 H CH.sub.3 H C(CH.sub.3)--OCH.sub.3 H Cl4.784 CH.sub.3 H H 1 CH.sub.3 H CH.sub.3 H C(CH.sub.3)--OCH.sub.3 H Cl4.785 CH.sub.3 H H 2 CH.sub.3 H CH.sub.3 H C(CH.sub.3)--OCH.sub.3 H Cl4.786 CH.sub.3 H H 0 CH.sub.3 H CH.sub.3 H O H Cl4.787 CH.sub.3 H H 2 CH.sub.3 H CH.sub.3 H O H Cl4.788 CH.sub.3 CH.sub.3 H 0 CH.sub.3 H CH.sub.3 H C.dbd.O H Cl4.789 CH.sub.3 CH.sub.3 H 1 CH.sub.3 H CH.sub.3 H C.dbd.O H Cl4.790 CH.sub.3 CH.sub.3 H 2 CH.sub.3 H CH.sub.3 H C.dbd.O H Cl4.791 CH.sub.3 CH.sub.3 H 0 CH.sub.3 H CH.sub.3 H CHOCH.sub.3 H Cl4.792 CH.sub.3 CH.sub.3 H 1 CH.sub.3 H CH.sub.3 H CHOCH.sub.3 H Cl4.793 CH.sub.3 CH.sub.3 H 2 CH.sub.3 H CH.sub.3 H CHOCH.sub.3 H Cl4.794 CH.sub.3 CH.sub.3 H 0 CH.sub.3 H CH.sub.3 H CHOC.sub.2 H.sub.5 H Cl4.795 CH.sub.3 CH.sub.3 H 1 CH.sub.3 H CH.sub.3 H CHOC.sub.2 H.sub.5 H Cl4.796 CH.sub.3 CH.sub.3 H 2 CH.sub.3 H CH.sub.3 H CHOC.sub.2 H.sub.5 H Cl4.797 CH.sub.3 CH.sub.3 H 0 CH.sub.3 H CH.sub.3 H CHOiPr H Cl4.798 CH.sub.3 CH.sub.3 H 1 CH.sub.3 H CH.sub.3 H CHOiPr H Cl4.799 CH.sub.3 CH.sub.3 H 2 CH.sub.3 H CH.sub.3 H CHOiPr H Cl4.800 CH.sub.3 CH.sub.3 H 0 CH.sub.3 H CH.sub.3 H C.dbd.NOCH.sub.3 H Cl4.801 CH.sub.3 CH.sub.3 H 1 CH.sub.3 H CH.sub.3 H C.dbd.NOCH.sub.3 H Cl4.802 CH.sub.3 CH.sub.3 H 2 CH.sub.3 H CH.sub.3 H C.dbd.NOCH.sub.3 H Cl4.803 CH.sub.3 CH.sub.3 H 0 CH.sub.3 H CH.sub.3 H C.dbd.NOC.sub.2 H.sub.5 H Cl4.804 CH.sub.3 CH.sub.3 H 1 CH.sub.3 H CH.sub.3 H C.dbd.NOC.sub.2 H.sub.5 H Cl4.805 CH.sub.3 CH.sub.3 H 2 CH.sub.3 H CH.sub.3 H C.dbd.NOC.sub.2 H.sub.5 H Cl4.806 CH.sub.3 CH.sub.3 H 0 CH.sub.3 H CH.sub.3 H C.dbd.NOiPr H Cl4.807 CH.sub.3 CH.sub.3 H 1 CH.sub.3 H CH.sub.3 H C.dbd.NOiPr H Cl4.808 CH.sub.3 CH.sub.3 H 2 CH.sub.3 H CH.sub.3 H C.dbd.NOiPr H Cl4.809 CH.sub.3 CH.sub.3 H 0 CH.sub.3 H CH.sub.3 H C.dbd.NOCH.sub.2 CH.dbd.CHCl H Cl4.810 CH.sub.3 CH.sub.3 H 1 CH.sub.3 H CH.sub.3 H C.dbd.NOCH.sub.2 CH.dbd.CHCl H Cl4.811 CH.sub.3 CH.sub.3 H 2 CH.sub.3 H CH.sub.3 H C.dbd.NOCH.sub.2 CH.dbd.CHCl H Cl4.812 CH.sub.3 CH.sub.3 H 0 CH.sub.3 H CH.sub.3 H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 H Cl4.813 CH.sub.3 CH.sub.3 H 1 CH.sub.3 H CH.sub.3 H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 H Cl4.814 CH.sub.3 CH.sub.3 H 2 CH.sub.3 H CH.sub.3 H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 H Cl4.815 CH.sub.3 CH.sub.3 H 0 CH.sub.3 H CH.sub.3 H C(CH.sub.3).sub.2 H Cl4.816 CH.sub.3 CH.sub.3 H 1 CH.sub.3 H CH.sub.3 H C(CH.sub.3).sub.2 H Cl4.817 CH.sub.3 CH.sub.3 H 2 CH.sub.3 H CH.sub.3 H C(CH.sub.3).sub.2 H Cl4.818 CH.sub.3 CH.sub.3 H 0 CH.sub.3 H CH.sub.3 H ##STR192## H Cl4.819 CH.sub.3 CH.sub.3 H 1 CH.sub.3 H CH.sub.3 H ##STR193## H Cl4.820 CH.sub.3 CH.sub.3 H 2 CH.sub.3 H CH.sub.3 H ##STR194## H Cl4.821 CH.sub.3 CH.sub.3 H 0 CH.sub.3 H CH.sub.3 H ##STR195## H Cl4.822 CH.sub.3 CH.sub.3 H 1 CH.sub.3 H CH.sub.3 H ##STR196## H Cl4.823 CH.sub.3 CH.sub.3 H 2 CH.sub.3 H CH.sub.3 H ##STR197## H Cl4.824 CH.sub.3 CH.sub.3 H 0 CH.sub.3 H CH.sub.3 H C.dbd.N--CH.sub.3 H Cl4.825 CH.sub.3 CH.sub.3 H 1 CH.sub.3 H CH.sub.3 H C.dbd.N--CH.sub.3 H Cl4.826 CH.sub.3 CH.sub.3 H 2 CH.sub.3 H CH.sub.3 H C.dbd.N--CH.sub.3 H Cl4.827 CH.sub.3 CH.sub.3 H 0 CH.sub.3 H CH.sub.3 H C.dbd.NC.sub.2 H.sub.5 H Cl4.828 CH.sub.3 CH.sub.3 H 1 CH.sub.3 H CH.sub.3 H C.dbd.NC.sub.2 H.sub.5 H Cl4.829 CH.sub.3 CH.sub.3 H 2 CH.sub.3 H CH.sub.3 H C.dbd.NC.sub.2 H.sub.5 H Cl4.830 CH.sub.3 CH.sub.3 H 0 CH.sub.3 H CH.sub.3 H CH--NHCH.sub.3 H Cl4.831 CH.sub.3 CH.sub.3 H 1 CH.sub.3 H CH.sub.3 H CH--NHCH.sub.3 H Cl4.832 CH.sub.3 CH.sub.3 H 2 CH.sub.3 H CH.sub.3 H CH--NHCH.sub.3 H Cl4.833 CH.sub.3 CH.sub.3 H 0 CH.sub.3 H CH.sub.3 H CH--NHC.sub.2 H.sub.5 H Cl4.834 CH.sub.3 CH.sub.3 H 1 CH.sub.3 H CH.sub.3 H CH--NHC.sub.2 H.sub.5 H Cl4.835 CH.sub.3 CH.sub.3 H 2 CH.sub.3 H CH.sub.3 H CH--NHC.sub.2 H.sub.5 H Cl4.836 CH.sub.3 CH.sub.3 H 0 CH.sub.3 H CH.sub.3 H CH--N(CH.sub.3).sub.2 H Cl4.837 CH.sub.3 CH.sub.3 H 1 CH.sub.3 H CH.sub.3 H CH--N(CH.sub.3).sub.2 H Cl4.838 CH.sub.3 CH.sub.3 H 2 CH.sub.3 H CH.sub.3 H CH--N(CH.sub.3).sub.2 H Cl4.839 CH.sub.3 CH.sub.3 H 0 CH.sub.3 H CH.sub.3 H CH--NHOC.sub.2 H.sub.5 H Cl4.840 CH.sub.3 CH.sub.3 H 1 CH.sub.3 H CH.sub.3 H CH--NHOC.sub.2 H.sub.5 H Cl4.841 CH.sub.3 CH.sub.3 H 2 CH.sub.3 H CH.sub.3 H CH--NHOC.sub.2 H.sub.5 H Cl4.842 CH.sub.3 CH.sub.3 H 0 CH.sub.3 H CH.sub.3 H CH--N(CH.sub.3)OC.sub.2 H.sub.5 H Cl4.843 CH.sub.3 CH.sub.3 H 1 CH.sub.3 H CH.sub.3 H CH--N(CH.sub.3)OC.sub.2 H.sub.5 H Cl4.844 CH.sub.3 CH.sub.3 H 2 CH.sub.3 H CH.sub.3 H CH--N(CH.sub.3)OC.sub.2 H.sub.5 H Cl4.845 CH.sub.3 CH.sub.3 H 0 CH.sub.3 H CH.sub.3 H C.dbd.N--NH.sub.2 H Cl4.846 CH.sub.3 CH.sub.3 H 1 CH.sub.3 H CH.sub.3 H C.dbd.N--NH.sub.2 H Cl4.847 CH.sub.3 CH.sub.3 H 2 CH.sub.3 H CH.sub.3 H C.dbd.N--NH.sub.2 H Cl4.848 CH.sub.3 CH.sub.3 H 0 CH.sub.3 H CH.sub.3 H C.dbd.N--N(CH.sub.3).sub.2 H Cl4.849 CH.sub.3 CH.sub.3 H 1 CH.sub.3 H CH.sub.3 H C.dbd.N--N(CH.sub.3).sub.2 H Cl4.850 CH.sub.3 CH.sub.3 H 2 CH.sub.3 H CH.sub.3 H C.dbd.N--N(CH.sub.3).sub.2 H Cl4.851 CH.sub.3 CH.sub.3 H 0 CH.sub.3 H CH.sub.3 H CH--N(CH.sub.3)OCH.sub.2 C.sub.6 H.sub.5 H Cl4.852 CH.sub.3 CH.sub.3 H 1 CH.sub.3 H CH.sub.3 H CH--N(CH.sub.3)OCH.sub.2 C.sub.6 H.sub.5 H Cl4.853 CH.sub.3 CH.sub.3 H 2 CH.sub.3 H CH.sub.3 H CH--N(CH.sub.3)OCH.sub.2 C.sub.6 H.sub.5 H Cl4.854 CH.sub.3 CH.sub.3 H 0 CH.sub.3 H CH.sub.3 H C(CH.sub.3)--OCH.sub.3 H Cl4.855 CH.sub.3 CH.sub.3 H 1 CH.sub.3 H CH.sub.3 H C(CH.sub.3)--OCH.sub.3 H Cl4.856 CH.sub.3 CH.sub.3 H 2 CH.sub.3 H CH.sub.3 H C(CH.sub.3)--OCH.sub.3 H Cl4.857 CH.sub.3 CH.sub.3 H 0 CH.sub.3 H CH.sub.3 H O H Cl4.858 CH.sub.3 CH.sub.3 H 2 CH.sub.3 H CH.sub.3 H O H Cl4.859 H H H 0 CH.sub.3 H H H C.dbd.O H CH.sub.34.860 H H H 1 CH.sub.3 H H H C.dbd.O H CH.sub.34.861 H H H 2 CH.sub.3 H H H C.dbd.O H CH.sub.34.862 H H H 0 CH.sub.3 H H H CH--OCH.sub.3 H CH.sub.34.863 H H H 1 CH.sub.3 H H H CH--OCH.sub.3 H CH.sub.34.864 H H H 2 CH.sub.3 H H H CH--OCH.sub.3 H CH.sub.34.865 H H H 0 CH.sub.3 H H H CHOC.sub.2 H.sub.5 H CH.sub.34.866 H H H 1 CH.sub.3 H H H CHOC.sub.2 H.sub.5 H CH.sub.34.867 H H H 2 CH.sub.3 H H H CHOC.sub.2 H.sub.5 H CH.sub.34.868 H H H 0 CH.sub.3 H H H CHOiPr H CH.sub.34.869 H H H 1 CH.sub.3 H H H CHOiPr H CH.sub.34.870 H H H 2 CH.sub.3 H H H CHOiPr H CH.sub.34.871 H H H 0 CH.sub.3 H H H C.dbd.NOCH.sub.3 H CH.sub.34.872 H H H 1 CH.sub.3 H H H C.dbd.NOCH.sub.3 H CH.sub.34.873 H H H 2 CH.sub.3 H H H C.dbd.NOCH.sub.3 H CH.sub.34.874 H H H 0 CH.sub.3 H H H C.dbd.NOC.sub.2 H.sub.5 H CH.sub.34.875 H H H 1 CH.sub.3 H H H C.dbd.NOC.sub.2 H.sub.5 H CH.sub.34.876 H H H 2 CH.sub.3 H H H C.dbd.NOC.sub.2 H.sub.5 H CH.sub.34.877 H H H 0 CH.sub.3 H H H C.dbd.NOiPr H CH.sub.34.878 H H H 1 CH.sub.3 H H H C.dbd.NOiPr H CH.sub.34.879 H H H 2 CH.sub.3 H H H C.dbd.NOiPr H CH.sub.34.880 H H H 0 CH.sub.3 H H H C.dbd.NOCH.sub.2 CH.dbd.CHCl H CH.sub.34.881 H H H 1 CH.sub.3 H H H C.dbd.NOCH.sub.2 CH.dbd.CHCl H CH.sub.34.882 H H H 2 CH.sub.3 H H H C.dbd.NOCH.sub.2 CH.dbd.CHCl H CH.sub.34.883 H H H 0 CH.sub.3 H H H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 H CH.sub.34.884 H H H 1 CH.sub.3 H H H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 H CH.sub.34.885 H H H 2 CH.sub.3 H H H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 H CH.sub.34.886 H H H 0 CH.sub.3 H H H C(CH.sub.3).sub.2 H CH.sub.34.887 H H H 1 CH.sub.3 H H H C(CH.sub.3).sub.2 H CH.sub.34.888 H H H 2 CH.sub.3 H H H C(CH.sub.3).sub.2 H CH.sub.34.889 H H H 0 CH.sub.3 H H H ##STR198## H CH.sub.34.890 H H H 1 CH.sub.3 H H H ##STR199## H CH.sub.34.891 H H H 2 CH.sub.3 H H H ##STR200## H CH.sub.34.892 H H H 0 CH.sub.3 H H H ##STR201## H CH.sub.34.893 H H H 1 CH.sub.3 H H H ##STR202## H CH.sub.34.894 H H H 2 CH.sub.3 H H H ##STR203## H CH.sub.34.895 H H H 0 CH.sub.3 H H H C.dbd.N--CH.sub.3 H CH.sub.34.896 H H H 1 CH.sub.3 H H H C.dbd.N--CH.sub.3 H CH.sub.34.897 H H H 2 CH.sub.3 H H H C.dbd.N--CH.sub.3 H CH.sub.34.898 H H H 0 CH.sub.3 H H H C.dbd.NC.sub.2 H.sub.5 H CH.sub.34.899 H H H 1 CH.sub.3 H H H C.dbd.NC.sub.2 H.sub.5 H CH.sub.34.900 H H H 2 CH.sub.3 H H H C.dbd.NC.sub.2 H.sub.5 H CH.sub.34.901 H H H 0 CH.sub.3 H H H CH--NHCH.sub.3 H CH.sub.34.902 H H H 1 CH.sub.3 H H H CH--NHCH.sub.3 H CH.sub.34.903 H H H 2 CH.sub.3 H H H CH--NHCH.sub.3 H CH.sub.34.904 H H H 0 CH.sub.3 H H H CH--NHC.sub.2 H.sub.5 H CH.sub.34.905 H H H 1 CH.sub.3 H H H CH--NHC.sub.2 H.sub.5 H CH.sub.34.906 H H H 2 CH.sub.3 H H H CH--NHC.sub.2 H.sub.5 H CH.sub.34.907 H H H 0 CH.sub.3 H H H CH--N(CH.sub.3).sub.2 H CH.sub.34.908 H H H 1 CH.sub.3 H H H CH--N(CH.sub.3).sub.2 H CH.sub.34.909 H H H 2 CH.sub.3 H H H CH--N(CH.sub.3).sub.2 H CH.sub.34.910 H H H 0 CH.sub.3 H H H CH--NHOC.sub.2 H.sub.5 H CH.sub.34.911 H H H 1 CH.sub.3 H H H CH--NHOC.sub.2 H.sub.5 H CH.sub.34.912 H H H 2 CH.sub.3 H H H CH--NHOC.sub.2 H.sub.5 H CH.sub.34.913 H H H 0 CH.sub.3 H H H CH--N(CH.sub.3)OC.sub.2 H.sub.5 H CH.sub.34.914 H H H 1 CH.sub.3 H H H CH--N(CH.sub.3)OC.sub.2 H.sub.5 H CH.sub.34.915 H H H 2 CH.sub.3 H H H CH--N(CH.sub.3)OC.sub.2 H.sub.5 H CH.sub.34.916 H H H 0 CH.sub.3 H H H C.dbd.N--NH.sub.2 H CH.sub.34.917 H H H 1 CH.sub.3 H H H C.dbd.N--NH.sub.2 H CH.sub.34.918 H H H 2 CH.sub.3 H H H C.dbd.N--NH.sub.2 H CH.sub.34.919 H H H 0 CH.sub.3 H H H C.dbd.N--N(CH.sub.3).sub.2 H CH.sub.34.920 H H H 1 CH.sub.3 H H H C.dbd.N--N(CH.sub.3).sub.2 H CH.sub.34.921 H H H 2 CH.sub.3 H H H C.dbd.N--N(CH.sub.3).sub.2 H CH.sub.34.922 H H H 0 CH.sub.3 H H H CH--N(CH.sub.3)OCH.sub.2 C.sub.6 H.sub.5 H CH.sub.34.923 H H H 1 CH.sub.3 H H H CH--N(CH.sub.3)OCH.sub.2 C.sub.6 H.sub.5 H CH.sub.34.924 H H H 2 CH.sub.3 H H H CH--N(CH.sub.3)OCH.sub.2 C.sub.6 H.sub.5 H CH.sub.34.925 H H H 0 CH.sub.3 H H H C(CH.sub.3)--OCH.sub.3 H CH.sub.34.926 H H H 1 CH.sub.3 H H H C(CH.sub.3)--OCH.sub.3 H CH.sub.34.927 H H H 2 CH.sub.3 H H H C(CH.sub.3)--OCH.sub.3 H CH.sub.34.928 H H H 0 CH.sub.3 H H H O H CH.sub.34.929 H H H 2 CH.sub.3 H H H O H CH.sub.34.930 CH.sub.3 H H 0 CH.sub.3 H H H C.dbd.O H CH.sub.34.931 CH.sub.3 H H 1 CH.sub.3 H H H C.dbd.O H CH.sub.34.932 CH.sub.3 H H 2 CH.sub.3 H H H C.dbd.O H CH.sub.34.933 CH.sub.3 H H 0 CH.sub.3 H H H CHOCH.sub.3 H CH.sub.34.934 CH.sub.3 H H 1 CH.sub.3 H H H CHOCH.sub.3 H CH.sub.34.935 CH.sub.3 H H 2 CH.sub.3 H H H CHOCH.sub.3 H CH.sub.34.936 CH.sub.3 H H 0 CH.sub.3 H H H CHOC.sub.2 H.sub.5 H CH.sub.34.937 CH.sub.3 H H 1 CH.sub.3 H H H CHOC.sub.2 H.sub.5 H CH.sub.34.938 CH.sub.3 H H 2 CH.sub.3 H H H CHOC.sub.2 H.sub.5 H CH.sub.34.939 CH.sub.3 H H 0 CH.sub.3 H H H CHOiPr H CH.sub.34.940 CH.sub.3 H H 1 CH.sub.3 H H H CHOiPr H CH.sub.34.941 CH.sub.3 H H 2 CH.sub.3 H H H CHOiPr H CH.sub.34.942 CH.sub.3 H H 0 CH.sub.3 H H H C.dbd.NOCH.sub.3 H CH.sub.34.943 CH.sub.3 H H 1 CH.sub.3 H H H C.dbd.NOCH.sub.3 H CH.sub.34.944 CH.sub.3 H H 2 CH.sub.3 H H H C.dbd.NOCH.sub.3 H CH.sub.34.945 CH.sub.3 H H 0 CH.sub.3 H H H C.dbd.NOC.sub.2 H.sub.5 H CH.sub.34.946 CH.sub.3 H H 1 CH.sub.3 H H H C.dbd.NOC.sub.2 H.sub.5 H CH.sub.34.947 CH.sub.3 H H 2 CH.sub.3 H H H C.dbd.NOC.sub.2 H.sub.5 H CH.sub.34.948 CH.sub.3 H H 0 CH.sub.3 H H H C.dbd.NOiPr H CH.sub.34.949 CH.sub.3 H H 1 CH.sub.3 H H H C.dbd.NOiPr H CH.sub.34.950 CH.sub.3 H H 2 CH.sub.3 H H H C.dbd.NOiPr H CH.sub.34.951 CH.sub.3 H H 0 CH.sub.3 H H H C.dbd.NOCH.sub.2 CH.dbd.CHCl H CH.sub.34.952 CH.sub.3 H H 1 CH.sub.3 H H H C.dbd.NOCH.sub.2 CH.dbd.CHCl H CH.sub.34.953 CH.sub.3 H H 2 CH.sub.3 H H H C.dbd.NOCH.sub.2 CH.dbd.CHCl H CH.sub.34.954 CH.sub.3 H H 0 CH.sub.3 H H H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 H CH.sub.34.955 CH.sub.3 H H 1 CH.sub.3 H H H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 H CH.sub.34.956 CH.sub.3 H H 2 CH.sub.3 H H H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 H CH.sub.34.957 CH.sub.3 H H 0 CH.sub.3 H H H C(CH.sub.3).sub.2 H CH.sub.34.958 CH.sub.3 H H 1 CH.sub.3 H H H C(CH.sub.3).sub.2 H CH.sub.34.959 CH.sub.3 H H 2 CH.sub.3 H H H C(CH.sub.3).sub.2 H CH.sub.34.960 CH.sub.3 CH.sub.3 H 0 CH.sub.3 H H H ##STR204## H CH.sub.34.961 CH.sub.3 CH.sub.3 H 1 CH.sub.3 H H H ##STR205## H CH.sub.34.962 CH.sub.3 CH.sub.3 H 2 CH.sub.3 H H H ##STR206## H CH.sub.34.963 CH.sub.3 CH.sub.3 H 0 CH.sub.3 H H H ##STR207## H CH.sub.34.964 CH.sub.3 CH.sub.3 H 1 CH.sub.3 H H H ##STR208## H CH.sub.34.965 CH.sub.3 CH.sub.3 H 2 CH.sub.3 H H H ##STR209## H CH.sub.34.966 CH.sub.3 CH.sub.3 H 0 CH.sub.3 H H H C.dbd.N--CH.sub.3 H CH.sub.34.967 CH.sub.3 CH.sub.3 H 1 CH.sub.3 H H H C.dbd.N--CH.sub.3 H CH.sub.34.968 CH.sub.3 CH.sub.3 H 2 CH.sub.3 H H H C.dbd.N--CH.sub.3 H CH.sub.34.969 CH.sub.3 CH.sub.3 H 0 CH.sub.3 H H H C.dbd.NC.sub.2 H.sub.5 H CH.sub.34.970 CH.sub.3 H H 1 CH.sub.3 H H H C.dbd.NC.sub.2 H.sub.5 H CH.sub.34.971 CH.sub.3 H H 2 CH.sub.3 H H H C.dbd.NC.sub.2 H.sub.5 H CH.sub.34.972 CH.sub.3 H H 0 CH.sub.3 H H H CH--NHCH.sub.3 H CH.sub.34.973 CH.sub.3 H H 1 CH.sub.3 H H H CH--NHCH.sub.3 H CH.sub.34.974 CH.sub.3 H H 2 CH.sub.3 H H H CH--NHCH.sub.3 H CH.sub.34.975 CH.sub.3 H H 0 CH.sub.3 H H H CH--NHC.sub.2 H.sub.5 H CH.sub.34.976 CH.sub.3 H H 1 CH.sub.3 H H H CH--NHC.sub.2 H.sub.5 H CH.sub.34.977 CH.sub.3 H H 2 CH.sub.3 H H H CH--NHC.sub.2 H.sub.5 H CH.sub.34.978 CH.sub.3 H H 0 CH.sub.3 H H H CH--N(CH.sub.3).sub.2 H CH.sub.34.979 CH.sub.3 H H 1 CH.sub.3 H H H CH--N(CH.sub.3).sub.2 H CH.sub.34.980 CH.sub.3 H H 2 CH.sub.3 H H H CH--N(CH.sub.3).sub.2 H CH.sub.34.981 CH.sub.3 H H 0 CH.sub.3 H H H CH--NHOC.sub.2 H.sub.5 H CH.sub.34.982 CH.sub.3 H H 1 CH.sub.3 H H H CH--NHOC.sub.2 H.sub.5 H CH.sub.34.983 CH.sub.3 H H 2 CH.sub.3 H H H CH--NHOC.sub.2 H.sub.5 H CH.sub.34.984 CH.sub.3 H H 0 CH.sub.3 H H H CH--N(CH.sub.3)OC.sub.2 H.sub.5 H CH.sub.34.985 CH.sub.3 H H 1 CH.sub.3 H H H CH--N(CH.sub.3)OC.sub.2 H.sub.5 H CH.sub.34.986 CH.sub.3 H H 2 CH.sub.3 H H H CH--N(CH.sub.3)OC.sub.2 H.sub.5 H CH.sub.34.987 CH.sub.3 H H 0 CH.sub.3 H H H C.dbd.N--NH.sub.2 H CH.sub.34.988 CH.sub.3 H H 1 CH.sub.3 H H H C.dbd.N--NH.sub.2 H CH.sub.34.989 CH.sub.3 H H 2 CH.sub.3 H H H C.dbd.N--NH.sub.2 H CH.sub.34.990 CH.sub.3 H H 0 CH.sub.3 H H H C.dbd.N--N(CH.sub.3).sub.2 H CH.sub.34.991 CH.sub.3 H H 1 CH.sub.3 H H H C.dbd.N--N(CH.sub.3).sub.2 H CH.sub.34.992 CH.sub.3 H H 2 CH.sub.3 H H H C.dbd.N--N(CH.sub.3).sub.2 H CH.sub.34.993 CH.sub.3 H H 0 CH.sub.3 H H H CH--N(CH.sub.3)OCH.sub.2 C.sub.6 H.sub.5 H CH.sub.34.994 CH.sub.3 H H 1 CH.sub.3 H H H CH--N(CH.sub.3)OCH.sub.2 C.sub.6 H.sub.5 H CH.sub.34.995 CH.sub.3 H H 2 CH.sub.3 H H H CH--N(CH.sub.3)OCH.sub.2 C.sub.6 H.sub.5 H CH.sub.34.996 CH.sub.3 H H 0 CH.sub.3 H H H C(CH.sub.3)--OCH.sub.3 H CH.sub.34.997 CH.sub.3 H H 1 CH.sub.3 H H H C(CH.sub.3)--OCH.sub.3 H CH.sub.34.998 CH.sub.3 H H 2 CH.sub.3 H H H C(CH.sub.3)--OCH.sub.3 H CH.sub.34.999 CH.sub.3 H H 0 CH.sub.3 H H H O H CH.sub.34.1000 CH.sub.3 H H 2 CH.sub.3 H H H O H CH.sub.34.1001 CH.sub.3 CH.sub.3 H 0 CH.sub.3 H H H C.dbd.O H CH.sub.34.1002 CH.sub.3 CH.sub.3 H 1 CH.sub.3 H H H C.dbd.O H CH.sub.34.1003 CH.sub.3 CH.sub.3 H 2 CH.sub.3 H H H C.dbd.O H CH.sub.34.1004 CH.sub.3 CH.sub.3 H 0 CH.sub.3 H H H CHOCH.sub.3 H CH.sub.34.1005 CH.sub.3 CH.sub.3 H 1 CH.sub.3 H H H CHOCH.sub.3 H CH.sub.34.1006 CH.sub.3 CH.sub.3 H 2 CH.sub.3 H H H CHOCH.sub.3 H CH.sub.34.1007 CH.sub.3 CH.sub.3 H 0 CH.sub.3 H H H CHOC.sub.2 H.sub.5 H CH.sub.34.1008 CH.sub.3 CH.sub.3 H 1 CH.sub.3 H H H CHOC.sub.2 H.sub.5 H CH.sub.34.1009 CH.sub.3 CH.sub.3 H 2 CH.sub.3 H H H CHOC.sub.2 H.sub.5 H CH.sub.34.1010 CH.sub.3 CH.sub.3 H 0 CH.sub.3 H H H CHOiPr H CH.sub.34.1011 CH.sub.3 CH.sub.3 H 1 CH.sub.3 H H H CHOiPr H CH.sub.34.1012 CH.sub.3 CH.sub.3 H 2 CH.sub.3 H H H CHOiPr H CH.sub.34.1013 CH.sub.3 CH.sub.3 H 0 CH.sub.3 H H H C.dbd.NOCH.sub.3 H CH.sub.34.1014 CH.sub.3 CH.sub.3 H 1 CH.sub.3 H H H C.dbd.NOCH.sub.3 H CH.sub.34.1015 CH.sub.3 CH.sub.3 H 2 CH.sub.3 H H H C.dbd.NOCH.sub.3 H CH.sub.34.1016 CH.sub.3 CH.sub.3 H 0 CH.sub.3 H H H C.dbd.NOC.sub.2 H.sub.5 H CH.sub.34.1017 CH.sub.3 CH.sub.3 H 1 CH.sub.3 H H H C.dbd.NOC.sub.2 H.sub.5 H CH.sub.34.1018 CH.sub.3 CH.sub.3 H 2 CH.sub.3 H H H C.dbd.NOC.sub.2 H.sub.5 H CH.sub.34.1019 CH.sub.3 CH.sub.3 H 0 CH.sub.3 H H H C.dbd.NOiPr H CH.sub.34.1020 CH.sub.3 CH.sub.3 H 1 CH.sub.3 H H H C.dbd.NOiPr H CH.sub.34.1021 CH.sub.3 CH.sub.3 H 2 CH.sub.3 H H H C.dbd.NOiPr H CH.sub.34.1022 CH.sub.3 CH.sub.3 H 0 CH.sub.3 H H H C.dbd.NOCH.sub.2 CH.dbd.CHCl H CH.sub.34.1023 CH.sub.3 CH.sub.3 H 1 CH.sub.3 H H H C.dbd.NOCH.sub.2 CH.dbd.CHCl H CH.sub.34.1024 CH.sub.3 CH.sub.3 H 2 CH.sub.3 H H H C.dbd.NOCH.sub.2 CH.dbd.CHCl H CH.sub.34.1025 CH.sub.3 CH.sub.3 H 0 CH.sub.3 H H H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 H CH.sub.34.1026 CH.sub.3 CH.sub.3 H 1 CH.sub.3 H H H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 H CH.sub.34.1027 CH.sub.3 CH.sub.3 H 2 CH.sub.3 H H H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 H CH.sub.34.1028 CH.sub.3 CH.sub.3 H 0 CH.sub.3 H H H C(CH.sub.3).sub.2 H CH.sub.34.1029 CH.sub.3 CH.sub.3 H 1 CH.sub.3 H H H C(CH.sub.3).sub.2 H CH.sub.34.1030 CH.sub.3 CH.sub.3 H 2 CH.sub.3 H H H C(CH.sub.3).sub.2 H CH.sub.34.1031 CH.sub.3 CH.sub.3 H 0 CH.sub.3 H H H ##STR210## H CH.sub.34.1032 CH.sub.3 CH.sub.3 H 1 CH.sub.3 H H H ##STR211## H CH.sub.34.1033 CH.sub.3 CH.sub.3 H 2 CH.sub.3 H H H ##STR212## H CH.sub.34.1034 CH.sub.3 CH.sub.3 H 0 CH.sub.3 H H H ##STR213## H CH.sub.34.1035 CH.sub.3 CH.sub.3 H 1 CH.sub.3 H H H ##STR214## H CH.sub.34.1036 CH.sub.3 CH.sub.3 H 2 CH.sub.3 H H H ##STR215## H CH.sub.34.1037 CH.sub.3 CH.sub.3 H 0 CH.sub.3 H H H C.dbd.N--CH.sub.3 H CH.sub.34.1038 CH.sub.3 CH.sub.3 H 1 CH.sub.3 H H H C.dbd.N--CH.sub.3 H CH.sub.34.1039 CH.sub.3 CH.sub.3 H 2 CH.sub.3 H H H C.dbd.N--CH.sub.3 H CH.sub.34.1040 CH.sub.3 CH.sub.3 H 0 CH.sub.3 H H H C.dbd.NC.sub.2 H.sub.5 H CH.sub.34.1041 CH.sub.3 CH.sub.3 H 1 CH.sub.3 H H H C.dbd.NC.sub.2 H.sub.5 H CH.sub.34.1042 CH.sub.3 CH.sub.3 H 2 CH.sub.3 H H H C.dbd.NC.sub.2 H.sub.5 H CH.sub.34.1043 CH.sub.3 CH.sub.3 H 0 CH.sub.3 H H H CH--NHCH.sub.3 H CH.sub.34.1044 CH.sub.3 CH.sub.3 H 1 CH.sub.3 H H H CH--NHCH.sub.3 H CH.sub.34.1045 CH.sub.3 CH.sub.3 H 2 CH.sub.3 H H H CH--NHCH.sub.3 H CH.sub.34.1046 CH.sub.3 CH.sub.3 H 0 CH.sub.3 H H H CH--NHC.sub.2 H.sub.5 H CH.sub.34.1047 CH.sub.3 CH.sub.3 H 1 CH.sub.3 H H H CH--NHC.sub.2 H.sub.5 H CH.sub.34.1048 CH.sub.3 CH.sub.3 H 2 CH.sub.3 H H H CH--NHC.sub.2 H.sub.5 H CH.sub.34.1049 CH.sub.3 CH.sub.3 H 0 CH.sub.3 H H H CH--N(CH.sub.3).sub.2 H CH.sub.34.1050 CH.sub.3 CH.sub.3 H 1 CH.sub.3 H H H CH--N(CH.sub.3).sub.2 H CH.sub.34.1051 CH.sub.3 CH.sub.3 H 2 CH.sub.3 H H H CH--N(CH.sub.3).sub.2 H CH.sub.34.1052 CH.sub.3 CH.sub.3 H 0 CH.sub.3 H H H CH--NHOC.sub.2 H.sub.5 H CH.sub.34.1053 CH.sub.3 CH.sub.3 H 1 CH.sub.3 H H H CH--NHOC.sub.2 H.sub.5 H CH.sub.34.1054 CH.sub.3 CH.sub.3 H 2 CH.sub.3 H H H CH--NHOC.sub.2 H.sub.5 H CH.sub.34.1055 CH.sub.3 CH.sub.3 H 0 CH.sub.3 H H H CH--N(CH.sub.3)OC.sub.2 H.sub.5 H CH.sub.34.1056 CH.sub.3 CH.sub.3 H 1 CH.sub.3 H H H CH--N(CH.sub.3)OC.sub.2 H.sub.5 H CH.sub.34.1057 CH.sub.3 CH.sub.3 H 2 CH.sub.3 H H H CH--N(CH.sub.3)OC.sub.2 H.sub.5 H CH.sub.34.1058 CH.sub.3 CH.sub.3 H 0 CH.sub.3 H H H C.dbd.N--NH.sub.2 H CH.sub.34.1059 CH.sub.3 CH.sub.3 H 1 CH.sub.3 H H H C.dbd.N--NH.sub.2 H CH.sub.34.1060 CH.sub.3 CH.sub.3 H 2 CH.sub.3 H H H C.dbd.N--NH.sub.2 H CH.sub.34.1061 CH.sub.3 CH.sub.3 H 0 CH.sub.3 H H H C.dbd.N--N(CH.sub.3).sub.2 H CH.sub.34.1062 CH.sub.3 CH.sub.3 H 1 CH.sub.3 H H H C.dbd.N--N(CH.sub.3).sub.2 H CH.sub.34.1063 CH.sub.3 CH.sub.3 H 2 CH.sub.3 H H H C.dbd.N--N(CH.sub.3).sub.2 H CH.sub.34.1064 CH.sub.3 CH.sub.3 H 0 CH.sub.3 H H H CH--N(CH.sub.3)OCH.sub.2 C.sub.6 H.sub.5 H CH.sub.34.1065 CH.sub.3 CH.sub.3 H 1 CH.sub.3 H H H CH--N(CH.sub.3)OCH.sub.2 C.sub.6 H.sub.5 H CH.sub.34.1066 CH.sub.3 CH.sub.3 H 2 CH.sub.3 H H H CH--N(CH.sub.3)OCH.sub.2 C.sub.6 H.sub.5 H CH.sub.34.1067 CH.sub.3 CH.sub.3 H 0 CH.sub.3 H H H C(CH.sub.3)--OCH.sub.3 H CH.sub.34.1068 CH.sub.3 CH.sub.3 H 1 CH.sub.3 H H H C(CH.sub.3)--OCH.sub.3 H CH.sub.34.1069 CH.sub.3 CH.sub.3 H 2 CH.sub.3 H H H C(CH.sub.3)--OCH.sub.3 H CH.sub.34.1070 CH.sub.3 CH.sub.3 H 0 CH.sub.3 H H H O H CH.sub.34.1071 CH.sub.3 CH.sub.3 H 2 CH.sub.3 H H H O H CH.sub.34.1072 H H H 0 CH.sub.3 CH.sub.3 H H C.dbd.O H Cl4.1073 H H H 1 CH.sub.3 CH.sub.3 H H C.dbd.O H Cl4.1074 H H H 2 CH.sub.3 CH.sub.3 H H C.dbd.O H Cl4.1075 H H H 0 CH.sub.3 CH.sub.3 H H CHOCH.sub.3 H Cl4.1076 H H H 1 CH.sub.3 CH.sub.3 H H CHOCH.sub.3 H Cl4.1077 H H H 2 CH.sub.3 CH.sub.3 H H CHOCH.sub.3 H Cl4.1078 H H H 0 CH.sub.3 CH.sub.3 H H CHOC.sub.2 H.sub.5 H Cl4.1079 H H H 1 CH.sub.3 CH.sub.3 H H CHOC.sub.2 H.sub.5 H Cl4.1080 H H H 2 CH.sub.3 CH.sub.3 H H CHOC.sub.2 H.sub.5 H Cl4.1081 H H H 0 CH.sub.3 CH.sub.3 H H CHOiPr H Cl4.1082 H H H 1 CH.sub.3 CH.sub.3 H H CHOiPr H Cl4.1083 H H H 2 CH.sub.3 CH.sub.3 H H CHOiPr H Cl4.1084 H H H 0 CH.sub.3 CH.sub.3 H H C.dbd.NOCH.sub.3 H Cl4.1085 H H H 1 CH.sub.3 CH.sub.3 H H C.dbd.NOCH.sub.3 H Cl4.1086 H H H 2 CH.sub.3 CH.sub.3 H H C.dbd.NOCH.sub.3 H Cl4.1087 H H H 0 CH.sub.3 CH.sub.3 H H C.dbd.NOC.sub.2 H.sub.5 H Cl4.1088 H H H 1 CH.sub.3 CH.sub.3 H H C.dbd.NOC.sub.2 H.sub.5 H Cl4.1089 H H H 2 CH.sub.3 CH.sub.3 H H C.dbd.NOC.sub.2 H.sub.5 H Cl4.1090 H H H 0 CH.sub.3 CH.sub.3 H H C.dbd.NOiPr H Cl4.1091 H H H 1 CH.sub.3 CH.sub.3 H H C.dbd.NOiPr H Cl4.1092 H H H 2 CH.sub.3 CH.sub.3 H H C.dbd.NOiPr H Cl4.1093 H H H 0 CH.sub.3 CH.sub.3 H H C.dbd.NOCH.sub.2 CH.dbd.CHCl H Cl4.1094 H H H 1 CH.sub.3 CH.sub.3 H H C.dbd.NOCH.sub.2 CH.dbd.CHCl H Cl4.1095 H H H 2 CH.sub.3 CH.sub.3 H H C.dbd.NOCH.sub.2 CH.dbd.CHCl H Cl4.1096 H H H 0 CH.sub.3 CH.sub.3 H H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 H Cl4.1097 H H H 1 CH.sub.3 CH.sub.3 H H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 H Cl4.1098 H H H 2 CH.sub.3 CH.sub.3 H H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 H Cl4.1099 H H H 0 CH.sub.3 CH.sub.3 H H C(CH.sub.3).sub.2 H Cl4.1100 H H H 1 CH.sub.3 CH.sub.3 H H C(CH.sub.3).sub.2 H Cl4.1101 H H H 2 CH.sub.3 CH.sub.3 H H C(CH.sub.3).sub.2 H Cl4.1102 H H H 0 CH.sub.3 CH.sub.3 H H ##STR216## H Cl4.1103 H H H 1 CH.sub.3 CH.sub.3 H H ##STR217## H Cl4.1104 H H H 2 CH.sub.3 CH.sub.3 H H ##STR218## H Cl4.1105 H H H 0 CH.sub.3 CH.sub.3 H H ##STR219## H Cl4.1106 H H H 1 CH.sub.3 CH.sub.3 H H ##STR220## H Cl4.1107 H H H 2 CH.sub.3 CH.sub.3 H H ##STR221## H Cl4.1108 H H H 0 CH.sub.3 CH.sub.3 H H C.dbd.N--CH.sub.3 H Cl4.1109 H H H 1 CH.sub.3 CH.sub.3 H H C.dbd.N--CH.sub.3 H Cl4.1110 H H H 2 CH.sub.3 CH.sub.3 H H C.dbd.N--CH.sub.3 H Cl4.1111 H H H 0 CH.sub.3 CH.sub.3 H H C.dbd.NC.sub.2 H.sub.5 H Cl4.1112 H H H 1 CH.sub.3 CH.sub.3 H H C.dbd.NC.sub.2 H.sub.5 H Cl4.1113 H H H 2 CH.sub.3 CH.sub.3 H H C.dbd.NC.sub.2 H.sub.5 H Cl4.1114 H H H 0 CH.sub.3 CH.sub.3 H H CH--NHCH.sub.3 H Cl4.1115 H H H 1 CH.sub.3 CH.sub.3 H H CH--NHCH.sub.3 H Cl4.1116 H H H 2 CH.sub.3 CH.sub.3 H H CH--NHCH.sub.3 H Cl4.1117 H H H 0 CH.sub.3 CH.sub.3 H H CH--NHC.sub.2 H.sub.5 H Cl4.1118 H H H 1 CH.sub.3 CH.sub.3 H H CH--NHC.sub.2 H.sub.5 H Cl4.1119 H H H 2 CH.sub.3 CH.sub.3 H H CH--NHC.sub.2 H.sub.5 H Cl4.1120 H H H 0 CH.sub.3 CH.sub.3 H H CH--N(CH.sub.3).sub.2 H Cl4.1121 H H H 1 CH.sub.3 CH.sub.3 H H CH--N(CH.sub.3).sub.2 H Cl4.1122 H H H 2 CH.sub.3 CH.sub.3 H H CH--N(CH.sub.3).sub.2 H Cl4.1123 H H H 0 CH.sub.3 CH.sub.3 H H CH--NHOC.sub.2 H.sub.5 H Cl4.1124 H H H 1 CH.sub.3 CH.sub.3 H H CH--NHOC.sub.2 H.sub.5 H Cl4.1125 H H H 2 CH.sub.3 CH.sub.3 H H CH--NHOC.sub.2 H.sub.5 H Cl4.1126 H H H 0 CH.sub.3 CH.sub.3 H H CH--N(CH.sub.3)OC.sub.2 H.sub.5 H Cl4.1127 H H H 1 CH.sub.3 CH.sub.3 H H CH--N(CH.sub.3)OC.sub.2 H.sub.5 H Cl4.1128 H H H 2 CH.sub.3 CH.sub.3 H H CH--N(CH.sub.3)OC.sub.2 H.sub.5 H Cl4.1129 H H H 0 CH.sub.3 CH.sub.3 H H C.dbd.N--NH.sub.2 H Cl4.1130 H H H 1 CH.sub.3 CH.sub.3 H H C.dbd.N--NH.sub.2 H Cl4.1131 H H H 2 CH.sub.3 CH.sub.3 H H C.dbd.N--NH.sub.2 H Cl4.1132 H H H 0 CH.sub.3 CH.sub.3 H H C.dbd.N--N(CH.sub.3).sub.2 H Cl4.1133 H H H 1 CH.sub.3 CH.sub.3 H H C.dbd.N--N(CH.sub.3).sub.2 H Cl4.1134 H H H 2 CH.sub.3 CH.sub.3 H H C.dbd.N--N(CH.sub.3).sub.2 H Cl4.1135 H H H 0 CH.sub.3 CH.sub.3 H H CH--N(CH.sub.3)OCH.sub.2 C.sub.6 H.sub.5 H Cl4.1136 H H H 1 CH.sub.3 CH.sub.3 H H CH--N(CH.sub.3)OCH.sub.2 C.sub.6 H.sub.5 H Cl4.1137 H H H 2 CH.sub.3 CH.sub.3 H H CH--N(CH.sub.3)OCH.sub.2 C.sub.6 H.sub.5 H Cl4.1138 H H H 0 CH.sub.3 CH.sub.3 H H C(CH.sub.3)--OCH.sub.3 H Cl4.1139 H H H 1 CH.sub.3 CH.sub.3 H H C(CH.sub.3)--OCH.sub.3 H Cl4.1140 H H H 2 CH.sub.3 CH.sub.3 H H C(CH.sub.3)--OCH.sub.3 H Cl4.1141 H H H 0 CH.sub.3 CH.sub.3 H H O H Cl4.1142 H H H 2 CH.sub.3 CH.sub.3 H H O H Cl4.1143 CH.sub.3 H H 0 CH.sub.3 CH.sub.3 H H C.dbd.O H Cl4.1144 CH.sub.3 H H 1 CH.sub.3 CH.sub.3 H H C.dbd.O H Cl4.1145 CH.sub.3 H H 2 CH.sub.3 CH.sub.3 H H C.dbd.O H Cl4.1146 CH.sub.3 H H 0 CH.sub.3 CH.sub.3 H H CHOCH.sub.3 H Cl4.1147 CH.sub.3 H H 1 CH.sub.3 CH.sub.3 H H CHOCH.sub.3 H Cl4.1148 CH.sub.3 H H 2 CH.sub.3 CH.sub.3 H H CHOCH.sub.3 H Cl4.1149 CH.sub.3 H H 0 CH.sub.3 CH.sub.3 H H CHOC.sub.2 H.sub.5 H Cl4.1150 CH.sub.3 H H 1 CH.sub.3 CH.sub.3 H H CHOC.sub.2 H.sub.5 H Cl4.1151 CH.sub.3 H H 2 CH.sub.3 CH.sub.3 H H CHOC.sub.2 H.sub.5 H Cl4.1152 CH.sub.3 H H 0 CH.sub.3 CH.sub.3 H H CHOiPr H Cl4.1153 CH.sub.3 H H 1 CH.sub.3 CH.sub.3 H H CHOiPr H Cl4.1154 CH.sub.3 H H 2 CH.sub.3 CH.sub.3 H H CHOiPr H Cl4.1155 CH.sub.3 H H 0 CH.sub.3 CH.sub.3 H H C.dbd.NOCH.sub.3 H Cl4.1156 CH.sub.3 H H 1 CH.sub.3 CH.sub.3 H H C.dbd.NOCH.sub.3 H Cl4.1157 CH.sub.3 H H 2 CH.sub.3 CH.sub.3 H H C.dbd.NOCH.sub.3 H Cl4.1158 CH.sub.3 H H 0 CH.sub.3 CH.sub.3 H H C.dbd.NOC.sub.2 H.sub.5 H Cl4.1159 CH.sub.3 H H 1 CH.sub.3 CH.sub.3 H H C.dbd.NOC.sub.2 H.sub.5 H Cl4.1160 CH.sub.3 H H 2 CH.sub.3 CH.sub.3 H H C.dbd.NOC.sub.2 H.sub.5 H Cl4.1161 CH.sub.3 H H 0 CH.sub.3 CH.sub.3 H H C.dbd.NOiPr H Cl4.1162 CH.sub.3 H H 1 CH.sub.3 CH.sub.3 H H C.dbd.NOiPr H Cl4.1163 CH.sub.3 H H 2 CH.sub.3 CH.sub.3 H H C.dbd.NOiPr H Cl4.1164 CH.sub.3 H H 0 CH.sub.3 CH.sub.3 H H C.dbd.NOCH.sub.2 CH.dbd.CHCl H Cl4.1165 CH.sub.3 H H 1 CH.sub.3 CH.sub.3 H H C.dbd.NOCH.sub.2 CH.dbd.CHCl H Cl4.1166 CH.sub.3 H H 2 CH.sub.3 CH.sub.3 H H C.dbd.NOCH.sub.2 CH.dbd.CHCl H Cl4.1167 CH.sub.3 H H 0 CH.sub.3 CH.sub.3 H H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 H Cl4.1168 CH.sub.3 H H 1 CH.sub.3 CH.sub.3 H H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 H Cl4.1169 CH.sub.3 H H 2 CH.sub.3 CH.sub.3 H H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 H Cl4.1170 CH.sub.3 H H 0 CH.sub.3 CH.sub.3 H H C(CH.sub.3).sub.2 H Cl4.1171 CH.sub.3 H H 1 CH.sub.3 CH.sub.3 H H C(CH.sub.3).sub.2 H Cl4.1172 CH.sub.3 H H 2 CH.sub.3 CH.sub.3 H H C(CH.sub.3).sub.2 H Cl4.1173 CH.sub.3 H H 0 CH.sub.3 CH.sub.3 H H ##STR222## H Cl4.1174 CH.sub.3 H H 1 CH.sub.3 CH.sub.3 H H ##STR223## H Cl4.1175 CH.sub.3 H H 2 CH.sub.3 CH.sub.3 H H ##STR224## H Cl4.1176 CH.sub.3 H H 0 CH.sub.3 CH.sub.3 H H ##STR225## H Cl4.1177 CH.sub.3 H H 1 CH.sub.3 CH.sub.3 H H ##STR226## H Cl4.1178 CH.sub.3 H H 2 CH.sub.3 CH.sub.3 H H ##STR227## H Cl4.1179 CH.sub.3 H H 0 CH.sub.3 CH.sub.3 H H C.dbd.N--CH.sub.3 H Cl4.1180 CH.sub.3 H H 1 CH.sub.3 CH.sub.3 H H C.dbd.N--CH.sub.3 H Cl4.1181 CH.sub.3 H H 2 CH.sub.3 CH.sub.3 H H C.dbd.N--CH.sub.3 H Cl4.1182 CH.sub.3 H H 0 CH.sub.3 CH.sub.3 H H C.dbd.NC.sub.2 H.sub.5 H Cl4.1183 CH.sub.3 H H 1 CH.sub.3 CH.sub.3 H H C.dbd.NC.sub.2 H.sub.5 H Cl4.1184 CH.sub.3 H H 2 CH.sub.3 CH.sub.3 H H C.dbd.NC.sub.2 H.sub.5 H Cl4.1185 CH.sub.3 H H 0 CH.sub.3 CH.sub.3 H H CH--NHCH.sub.3 H Cl4.1186 CH.sub.3 H H 1 CH.sub.3 CH.sub.3 H H CH--NHCH.sub.3 H Cl4.1187 CH.sub.3 H H 2 CH.sub.3 CH.sub.3 H H CH--NHCH.sub.3 H Cl4.1188 CH.sub.3 H H 0 CH.sub.3 CH.sub.3 H H CH--NHC.sub.2 H.sub.5 H Cl4.1189 CH.sub.3 H H 1 CH.sub.3 CH.sub.3 H H CH--NHC.sub.2 H.sub.5 H Cl4.1190 CH.sub.3 H H 2 CH.sub.3 CH.sub.3 H H CH--NHC.sub.2 H.sub.5 H Cl4.1191 CH.sub.3 H H 0 CH.sub.3 CH.sub.3 H H CH--N(CH.sub.3).sub.2 H Cl4.1192 CH.sub.3 H H 1 CH.sub.3 CH.sub.3 H H CH--N(CH.sub.3).sub.2 H Cl4.1193 CH.sub.3 H H 2 CH.sub.3 CH.sub.3 H H CH--N(CH.sub.3).sub.2 H Cl4.1194 CH.sub.3 H H 0 CH.sub.3 CH.sub.3 H H CH--NHOC.sub.2 H.sub.5 H Cl4.1195 CH.sub.3 H H 1 CH.sub.3 CH.sub.3 H H CH--NHOC.sub.2 H.sub.5 H Cl4.1196 CH.sub.3 H H 2 CH.sub.3 CH.sub.3 H H CH--NHOC.sub.2 H.sub.5 H Cl4.1197 CH.sub.3 H H 0 CH.sub.3 CH.sub.3 H H CH--N(CH.sub.3)OC.sub.2 H.sub.5 H Cl4.1198 CH.sub.3 H H 1 CH.sub.3 CH.sub.3 H H CH--N(CH.sub.3)OC.sub.2 H.sub.5 H Cl4.1199 CH.sub.3 H H 2 CH.sub.3 CH.sub.3 H H CH--N(CH.sub.3)OC.sub.2 H.sub.5 H Cl4.1200 CH.sub.3 H H 0 CH.sub.3 CH.sub.3 H H C.dbd.N--NH.sub.2 H Cl4.1201 CH.sub.3 H H 1 CH.sub.3 CH.sub.3 H H C.dbd.N--NH.sub.2 H Cl4.1202 CH.sub.3 H H 2 CH.sub.3 CH.sub.3 H H C.dbd.N--NH.sub.2 H Cl4.1203 CH.sub.3 H H 0 CH.sub.3 CH.sub.3 H H C.dbd.N--N(CH.sub.3).sub.2 H Cl4.1204 CH.sub.3 H H 1 CH.sub.3 CH.sub.3 H H C.dbd.N--N(CH.sub.3).sub.2 H Cl4.1205 CH.sub.3 H H 2 CH.sub.3 CH.sub.3 H H C.dbd.N--N(CH.sub.3).sub.2 H Cl4.1206 CH.sub.3 H H 0 CH.sub.3 CH.sub.3 H H CH--N(CH.sub.3)OCH.sub.2 C.sub.6 H.sub.5 H Cl4.1207 CH.sub.3 H H 1 CH.sub.3 CH.sub.3 H H CH--N(CH.sub.3)OCH.sub.2 C.sub.6 H.sub.5 H Cl4.1208 CH.sub.3 H H 2 CH.sub.3 CH.sub.3 H H CH--N(CH.sub.3)OCH.sub.2 C.sub.6 H.sub.5 H Cl4.1209 CH.sub.3 H H 0 CH.sub.3 CH.sub.3 H H C(CH.sub.3)--OCH.sub.3 H Cl4.1210 CH.sub.3 H H 1 CH.sub.3 CH.sub.3 H H C(CH.sub.3)--OCH.sub.3 H Cl4.1211 CH.sub.3 H H 2 CH.sub.3 CH.sub.3 H H C(CH.sub.3)--OCH.sub.3 H Cl4.1212 CH.sub.3 H H 0 CH.sub.3 CH.sub.3 H H O H Cl4.1213 CH.sub.3 H H 2 CH.sub.3 CH.sub.3 H H O H Cl4.1214 CH.sub.3 CH.sub.3 H 0 CH.sub.3 CH.sub.3 H H C.dbd.O H Cl4.1215 CH.sub.3 CH.sub.3 H 1 CH.sub.3 CH.sub.3 H H C.dbd.O H Cl4.1216 CH.sub.3 CH.sub.3 H 2 CH.sub.3 CH.sub.3 H H C.dbd.O H Cl4.1217 CH.sub.3 CH.sub.3 H 0 CH.sub.3 CH.sub.3 H H CHOCH.sub.3 H Cl4.1218 CH.sub.3 CH.sub.3 H 1 CH.sub.3 CH.sub.3 H H CHOCH.sub.3 H Cl4.1219 CH.sub.3 CH.sub.3 H 2 CH.sub.3 CH.sub.3 H H CHOCH.sub.3 H Cl4.1220 CH.sub.3 CH.sub.3 H 0 CH.sub.3 CH.sub.3 H H CHOC.sub.2 H.sub.5 H Cl4.1221 CH.sub.3 CH.sub.3 H 1 CH.sub.3 CH.sub.3 H H CHOC.sub.2 H.sub.5 H Cl4.1222 CH.sub.3 CH.sub.3 H 2 CH.sub.3 CH.sub.3 H H CHOC.sub.2 H.sub.5 H Cl4.1223 CH.sub.3 CH.sub.3 H 0 CH.sub.3 CH.sub.3 H H CHOiPr H Cl4.1224 CH.sub.3 CH.sub.3 H 1 CH.sub.3 CH.sub.3 H H CHOiPr H Cl4.1225 CH.sub.3 CH.sub.3 H 2 CH.sub.3 CH.sub.3 H H CHOiPr H Cl4.1226 CH.sub.3 CH.sub.3 H 0 CH.sub.3 CH.sub.3 H H C.dbd.NOCH.sub.3 H Cl4.1227 CH.sub.3 CH.sub.3 H 1 CH.sub.3 CH.sub.3 H H C.dbd.NOCH.sub.3 H Cl4.1228 CH.sub.3 CH.sub.3 H 2 CH.sub.3 CH.sub.3 H H C.dbd.NOCH.sub.3 H Cl4.1229 CH.sub.3 CH.sub.3 H 0 CH.sub.3 CH.sub.3 H H C.dbd.NOC.sub.2 H.sub.5 H Cl4.1230 CH.sub.3 CH.sub.3 H 1 CH.sub.3 CH.sub.3 H H C.dbd.NOC.sub.2 H.sub.5 H Cl4.1231 CH.sub.3 CH.sub.3 H 2 CH.sub.3 CH.sub.3 H H C.dbd.NOC.sub.2 H.sub.5 H Cl4.1232 CH.sub.3 CH.sub.3 H 0 CH.sub.3 CH.sub.3 H H C.dbd.NOiPr H Cl4.1233 CH.sub.3 CH.sub.3 H 1 CH.sub.3 CH.sub.3 H H C.dbd.NOiPr H Cl4.1234 CH.sub.3 CH.sub.3 H 2 CH.sub.3 CH.sub.3 H H C.dbd.NOiPr H Cl4.1235 CH.sub.3 CH.sub.3 H 0 CH.sub.3 CH.sub.3 H H C.dbd.NOCH.sub.2 CH.dbd.CHCl H Cl4.1236 CH.sub.3 CH.sub.3 H 1 CH.sub.3 CH.sub.3 H H C.dbd.NOCH.sub.2 CH.dbd.CHCl H Cl4.1237 CH.sub.3 CH.sub.3 H 2 CH.sub.3 CH.sub.3 H H C.dbd.NOCH.sub.2 CH.dbd.CHCl H Cl4.1238 CH.sub.3 CH.sub.3 H 0 CH.sub.3 CH.sub.3 H H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 H Cl4.1239 CH.sub.3 CH.sub.3 H 1 CH.sub.3 CH.sub.3 H H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 H Cl4.1240 CH.sub.3 CH.sub.3 H 2 CH.sub.3 CH.sub.3 H H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 H Cl4.1241 CH.sub.3 CH.sub.3 H 0 CH.sub.3 CH.sub.3 H H C(CH.sub.3).sub.2 H Cl4.1242 CH.sub.3 CH.sub.3 H 1 CH.sub.3 CH.sub.3 H H C(CH.sub.3).sub.2 H Cl4.1243 CH.sub.3 CH.sub.3 H 2 CH.sub.3 CH.sub.3 H H C(CH.sub.3).sub.2 H Cl4.1244 CH.sub.3 CH.sub.3 H 0 CH.sub.3 CH.sub.3 H H ##STR228## H ClCl4.1245 CH.sub.3 CH.sub.3 H 1 CH.sub.3 CH.sub.3 H H ##STR229## H Cl4.1246 CH.sub.3 CH.sub.3 H 2 CH.sub.3 CH.sub.3 H H ##STR230## H Cl4.1247 CH.sub.3 CH.sub.3 H 0 CH.sub.3 CH.sub.3 H H ##STR231## H Cl4.1248 CH.sub.3 CH.sub.3 H 1 CH.sub.3 CH.sub.3 H H ##STR232## H Cl4.1249 CH.sub.3 CH.sub.3 H 2 CH.sub.3 CH.sub.3 H H ##STR233## H Cl4.1250 CH.sub.3 CH.sub.3 H 0 CH.sub.3 CH.sub.3 H H C.dbd.N--CH.sub.3 H Cl4.1251 CH.sub.3 CH.sub.3 H 1 CH.sub.3 CH.sub.3 H H C.dbd.N--CH.sub.3 H Cl4.1252 CH.sub.3 CH.sub.3 H 2 CH.sub.3 CH.sub.3 H H C.dbd.N--CH.sub.3 H Cl4.1253 CH.sub.3 CH.sub.3 H 0 CH.sub.3 CH.sub.3 H H C.dbd.NC.sub.2 H.sub.5 H Cl4.1254 CH.sub.3 CH.sub.3 H 1 CH.sub.3 CH.sub.3 H H C.dbd.NC.sub.2 H.sub.5 H Cl4.1255 CH.sub.3 CH.sub.3 H 2 CH.sub.3 CH.sub.3 H H C.dbd.NC.sub.2 H.sub.5 H Cl4.1256 CH.sub.3 CH.sub.3 H 0 CH.sub.3 CH.sub.3 H H CH--NHCH.sub.3 H Cl4.1257 CH.sub.3 CH.sub.3 H 1 CH.sub.3 CH.sub.3 H H CH--NHCH.sub.3 H Cl4.1258 CH.sub.3 CH.sub.3 H 2 CH.sub.3 CH.sub.3 H H CH--NHCH.sub.3 H Cl4.1259 CH.sub.3 CH.sub.3 H 0 CH.sub.3 CH.sub.3 H H CH--NHC.sub.2 H.sub.5 H Cl4.1260 CH.sub.3 CH.sub.3 H 1 CH.sub.3 CH.sub.3 H H CH--NHC.sub.2 H.sub.5 H Cl4.1261 CH.sub.3 CH.sub.3 H 2 CH.sub.3 CH.sub.3 H H CH--NHC.sub.2 H.sub.5 H Cl4.1262 CH.sub.3 CH.sub.3 H 0 CH.sub.3 CH.sub.3 H H CH--N(CH.sub.3).sub.2 H Cl4.1263 CH.sub.3 CH.sub.3 H 1 CH.sub.3 CH.sub.3 H H CH--N(CH.sub.3).sub.2 H Cl4.1264 CH.sub.3 CH.sub.3 H 2 CH.sub.3 CH.sub.3 H H CH--N(CH.sub.3).sub.2 H Cl4.1265 CH.sub.3 CH.sub.3 H 0 CH.sub.3 CH.sub.3 H H CH--NHOC.sub.2 H.sub.5 H Cl4.1266 CH.sub.3 CH.sub.3 H 1 CH.sub.3 CH.sub.3 H H CH--NHOC.sub.2 H.sub.5 H Cl4.1267 CH.sub.3 CH.sub.3 H 2 CH.sub.3 CH.sub.3 H H CH--NHOC.sub.2 H.sub.5 H Cl4.1268 CH.sub.3 CH.sub.3 H 0 CH.sub.3 CH.sub.3 H H CH--N(CH.sub.3)OC.sub.2 H.sub.5 H Cl4.1269 CH.sub.3 CH.sub.3 H 1 CH.sub.3 CH.sub.3 H H CH--N(CH.sub.3)OC.sub.2 H.sub.5 H Cl4.1270 CH.sub.3 CH.sub.3 H 2 CH.sub.3 CH.sub.3 H H CH--N(CH.sub.3)OC.sub.2 H.sub.5 H Cl4.1271 CH.sub.3 CH.sub.3 H 0 CH.sub.3 CH.sub.3 H H C.dbd.N--NH.sub.2 H Cl4.1272 CH.sub.3 CH.sub.3 H 1 CH.sub.3 CH.sub.3 H H C.dbd.N--NH.sub.2 H Cl4.1273 CH.sub.3 CH.sub.3 H 2 CH.sub.3 CH.sub.3 H H C.dbd.N--NH.sub.2 H Cl4.1274 CH.sub.3 CH.sub.3 H 0 CH.sub.3 CH.sub.3 H H C.dbd.N--N(CH.sub.3).sub.2 H Cl4.1275 CH.sub.3 CH.sub.3 H 1 CH.sub.3 CH.sub.3 H H C.dbd.N--N(CH.sub.3).sub.2 H Cl4.1276 CH.sub.3 CH.sub.3 H 2 CH.sub.3 CH.sub.3 H H C.dbd.N--N(CH.sub.3).sub.2 H Cl4.1277 CH.sub.3 CH.sub.3 H 0 CH.sub.3 CH.sub.3 H H CH--N(CH.sub.3)OCH.sub.2 C.sub.6 H.sub.5 H Cl4.1278 CH.sub.3 CH.sub.3 H 1 CH.sub.3 CH.sub.3 H H CH--N(CH.sub.3)OCH.sub.2 C.sub.6 H.sub.5 H Cl4.1279 CH.sub.3 CH.sub.3 H 2 CH.sub.3 CH.sub.3 H H CH--N(CH.sub.3)OCH.sub.2 C.sub.6 H.sub.5 H Cl4.1280 CH.sub.3 CH.sub.3 H 0 CH.sub.3 CH.sub.3 H H C(CH.sub.3)--OCH.sub.3 H Cl4.1281 CH.sub.3 CH.sub.3 H 1 CH.sub.3 CH.sub.3 H H C(CH.sub.3)--OCH.sub.3 H Cl4.1282 CH.sub.3 CH.sub.3 H 2 CH.sub.3 CH.sub.3 H H C(CH.sub.3)--OCH.sub.3 H Cl4.1283 CH.sub.3 CH.sub.3 H 0 CH.sub.3 CH.sub.3 H H O H Cl4.1284 CH.sub.3 CH.sub.3 H 2 CH.sub.3 CH.sub.3 H H O H Cl__________________________________________________________________________
TABLE 5__________________________________________________________________________Compounds of the formula ##STR234##The radicals R.sup.12 of X and R7 of Y form a bondNo. R.sup.17 R.sup.18 R.sup.19 n R.sup.21 R.sup.22 R.sup.13 Y L M__________________________________________________________________________5.1 H H H 0 H H H COCH.sub.3 H H5.2 H H H 2 H H H COCH.sub.3 H H5.3 H H H 0 H H H COC.sub.2 H.sub.5 H H5.4 H H H 2 H H H COC.sub.2 H.sub.5 H H5.5 H H H 0 H H H COiPr H H5.6 H H H 2 H H H COiPr H H5.7 CH.sub.3 H H 0 H H H COCH.sub.3 H H5.8 CH.sub.3 H H 2 H H H COCH.sub.3 H H5.9 CH.sub.3 H H 0 H H H COC.sub.2 H.sub.5 H H5.10 CH.sub.3 H H 2 H H H COC.sub.2 H.sub.5 H H5.11 CH.sub.3 H H 0 H H H COiPr H H5.12 CH.sub.3 H H 2 H H H COiPr H H5.13 CH.sub.3 CH.sub.3 H 0 H H H COCH.sub.3 H H5.14 CH.sub.3 CH.sub.3 H 2 H H H COCH.sub.3 H H5.15 CH.sub.3 CH.sub.3 H 0 H H H COC.sub.2 H.sub.5 H H5.16 CH.sub.3 CH.sub.3 H 2 H H H COC.sub.2 H.sub.5 H H5.17 CH.sub.3 CH.sub.3 H 0 H H H COiPr H HS.18 CH.sub.3 CH.sub.3 H 2 H H H COiPr H H5.19 H H H 0 H H H COCH.sub.3 H CH.sub.35.20 H H H 2 H H H COCH.sub.3 H CH.sub.35.21 H H H 0 H H H COC.sub.2 H.sub.5 H CH.sub.35.22 H H H 2 H H H COC.sub.2 H.sub.5 H CH.sub.35.23 H H H 0 H H H COiPr H CH.sub.35.24 H H H 2 H H H COiPr H CH.sub.35.25 CH.sub.3 H H 0 H H H COCH.sub.3 H CH.sub.35.26 CH.sub.3 H H 2 H H H COCH.sub.3 H CH.sub.35.27 CH.sub.3 H H 0 H H H COC.sub.2 H.sub.5 H CH.sub.35.28 CH.sub.3 H H 2 H H H COC.sub.2 H.sub.5 H CH.sub.35.29 CH.sub.3 H H 0 H H H COiPr H CH.sub.35.30 CH.sub.3 H H 2 H H H COiPr H CH.sub.35.31 CH.sub.3 CH.sub.3 H 0 H H H COCH.sub.3 H CH.sub.35.32 CH.sub.3 CH.sub.3 H 2 H H H COCH.sub.3 H CH.sub.35.33 CH.sub.3 CH.sub.3 H 0 H H H COC.sub.2 H.sub.5 H CH.sub.35.34 CH.sub.3 CH.sub.3 H 2 H H H COC.sub.2 H.sub.5 H CH.sub.35.35 CH.sub.3 CH.sub.3 H 0 H H H COiPr H CH.sub.35.36 CH.sub.3 CH.sub.3 H 2 H H H COiPr H CH.sub.35.37 H H H 0 H H H COCH.sub.3 H Cl5.38 H H H 2 H H H COCH.sub.3 H Cl5.39 H H H 0 H H H COC.sub.2 H.sub.5 H Cl5.40 H H H 2 H H H COC.sub.2 H.sub.5 H Cl5.41 H H H 0 H H H COiPr H Cl5.42 H H H 2 H H H COiPr H Cl5.43 CH.sub.3 H H 0 H H H COCH.sub.3 H Cl5.44 CH.sub.3 H H 2 H H H COCH.sub.3 H Cl5.45 CH.sub.3 H H 0 H H H COC.sub.2 H.sub.5 H Cl5.46 CH.sub.3 H H 2 H H H COC.sub.2 H.sub.5 H Cl5.47 CH.sub.3 H H 0 H H H COiPr H Cl5.48 CH.sub.3 H H 2 H H H COiPr H Cl5.49 CH.sub.3 CH.sub.3 H 0 H H H COCH.sub.3 H Cl5.50 CH.sub.3 CH.sub.3 H 2 H H H COCH.sub.3 H Cl5.51 CH.sub.3 CH.sub.3 H 0 H H H COC.sub.2 H.sub.5 H Cl5.52 CH.sub.3 CH.sub.3 H 2 H H H COC.sub.2 H.sub.5 H Cl5.53 CH.sub.3 CH.sub.3 H 0 H H H COiPr H Cl5.54 CH.sub.3 CH.sub.3 H 2 H H H COiPr H Cl__________________________________________________________________________
TABLE 6__________________________________________________________________________Compounds of the formula ##STR235##No. R.sup.17 R.sup.18 R.sup.19 n R.sup.21 R.sup.22 R.sup.12 R.sup.13 Y M L__________________________________________________________________________6.1 H H H 0 H H H H C.dbd.O H CH.sub.36.2 H H H 1 H H H H C.dbd.O H CH.sub.36.3 H H H 2 H H H H C.dbd.O H CH.sub.36.4 H H H 0 H H H H CH--OCH.sub.3 H CH.sub.36.5 H H H 1 H H H H CH--OCH.sub.3 H CH.sub.36.6 H H H 2 H H H H CH--OCH.sub.3 H CH.sub.36.7 H H H 0 H H H H CHOC.sub.2 H.sub.5 H CH.sub.36.8 H H H 1 H H H H CHOC.sub.2 H.sub.5 H CH.sub.36.9 H H H 2 H H H H CHOC.sub.2 H.sub.5 H CH.sub.36.10 H H H 0 H H H H CHOiPr H CH.sub.36.11 H H H 1 H H H H CHOiPr H CH.sub.36.12 H H H 2 H H H H CHOiPr H CH.sub.36.13 H H H 0 H H H H C.dbd.NOCH.sub.3 H CH.sub.36.14 H H H 1 H H H H C.dbd.NOCH.sub.3 H CH.sub.36.15 H H H 2 H H H H C.dbd.NOCH.sub.3 H CH.sub.36.16 H H H 0 H H H H C.dbd.NOC.sub.2 H.sub.5 H CH.sub.36.17 H H H 1 H H H H C.dbd.NOC.sub.2 H.sub.5 H CH.sub.36.18 H H H 2 H H H H C.dbd.NOC.sub.2 H.sub.5 H CH.sub.36.19 H H H 0 H H H H C.dbd.NOiPr H CH.sub.36.20 H H H 1 H H H H C.dbd.NOiPr H CH.sub.36.21 H H H 2 H H H H C.dbd.NOiPr H CH.sub.36.22 H H H 0 H H H H C.dbd.NOCH.sub.2 CH.dbd.CHCl H CH.sub.36.23 H H H 1 H H H H C.dbd.NOCH.sub.2 CH.dbd.CHCl H CH.sub.36.24 H H H 2 H H H H C.dbd.NOCH.sub.2 CH.dbd.CHCl H CH.sub.36.25 H H H 0 H H H H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 H CH.sub.36.26 H H H 1 H H H H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 H CH.sub.36.27 H H H 2 H H H H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 H CH.sub.36.28 H H H 0 H H H H C(CH.sub.3).sub.2 H CH.sub.36.29 H H H 1 H H H H C(CH.sub.3).sub.2 H CH.sub.36.30 H H H 2 H H H H C(CH.sub.3).sub.2 H CH.sub.36.31 H H H 0 H H H H ##STR236## H CH.sub.36.32 H H H 1 H H H H ##STR237## H CH.sub.36.33 H H H 2 H H H H ##STR238## H CH.sub.36.34 H H H 0 H H H H ##STR239## H CH.sub.36.35 H H H 1 H H H H ##STR240## H CH.sub.36.36 H H H 2 H H H H ##STR241## H CH.sub.36.37 H H H 0 H H H H C.dbd.N--CH.sub.3 H CH.sub.36.38 H H H 1 H H H H C.dbd.N--CH.sub.3 H CH.sub.36.39 H H H 2 H H H H C.dbd.N--CH.sub.3 H CH.sub.36.40 H H H 0 H H H H C.dbd.NC.sub.2 H.sub.5 H CH.sub.36.41 H H H 1 H H H H C.dbd.NC.sub.2 H.sub.5 H CH.sub.36.42 H H H 2 H H H H C.dbd.NC.sub.2 H.sub.5 H CH.sub.36.43 H H H 0 H H H H CH--NHCH.sub.3 H CH.sub.36.44 H H H 1 H H H H CH--NHCH.sub.3 H CH.sub.36.45 H H H 2 H H H H CH--NHCH.sub.3 H CH.sub.36.46 H H H 0 H H H H CH--NHC.sub.2 H.sub.5 H CH.sub.36.47 H H H 1 H H H H CH--NHC.sub.2 H.sub.5 H CH.sub.36.48 H H H 2 H H H H CH--NHC.sub.2 H.sub.5 H CH.sub.36.49 H H H 0 H H H H CH--N(CH.sub.3).sub.2 H CH.sub.36.50 H H H 1 H H H H CH--N(CH.sub.3).sub.2 H CH.sub.36.51 H H H 2 H H H H CH--N(CH.sub.3).sub.2 H CH.sub.36.52 H H H 0 H H H H CH--NHOC.sub.2 H.sub.5 H CH.sub.36.53 H H H 1 H H H H CH--NHOC.sub.2 H.sub.5 H CH.sub.36.54 H H H 2 H H H H CH--NHOC.sub.2 H.sub.5 H CH.sub.36.55 H H H 0 H H H H CH--N(CH.sub.3)OC.sub.2 H.sub.5 H CH.sub.36.56 H H H 1 H H H H CH--N(CH.sub.3)OC.sub.2 H.sub.5 H CH.sub.36.57 H H H 2 H H H H CH--N(CH.sub.3)OC.sub.2 H.sub.5 H CH.sub.36.58 H H H 0 H H H H C.dbd.N--NH.sub.2 H CH.sub.36.59 H H H 1 H H H H C.dbd.N--NH.sub.2 H CH.sub.36.60 H H H 2 H H H H C.dbd.N--NH.sub.2 H CH.sub.36.61 H H H 0 H H H H C.dbd.N--N(CH.sub.3).sub.2 H CH.sub.36.62 H H H 1 H H H H C.dbd.N--N(CH.sub.3).sub.2 H CH.sub.36.63 H H H 2 H H H H C.dbd.N--N(CH.sub.3).sub.2 H CH.sub.36.64 H H H 0 H H H H CH--N(CH.sub.3)OCH.sub.2 C.sub.6 H.sub.5 H CH.sub.36.65 H H H 1 H H H H CH--N(CH.sub.3)OCH.sub.2 C.sub.6 H.sub.5 H CH.sub.36.66 H H H 2 H H H H CH--N(CH.sub.3)OCH.sub.2 C.sub.6 H.sub.5 H CH.sub.36.67 H H H 0 H H H H C(CH.sub.3)--OCH.sub.3 H CH.sub.36.68 H H H 1 H H H H C(CH.sub.3)--OCH.sub.3 H CH.sub.36.69 H H H 2 H H H H C(CH.sub.3)--OCH.sub.3 H CH.sub.36.70 H H H 0 H H H H O H CH.sub.36.71 H H H 1 H H H H O H CH.sub.36.72 H H H 2 H H H H O H CH.sub.36.73 CH.sub.3 H H 0 H H H H C.dbd.O H CH.sub.36.74 CH.sub.3 H H 1 H H H H C.dbd.O H CH.sub.36.75 CH.sub.3 H H 2 H H H H C.dbd.O H CH.sub.36.76 CH.sub.3 H H 0 H H H H CHOCH.sub.3 H CH.sub.36.77 CH.sub.3 H H 1 H H H H CHOCH.sub.3 H CH.sub.36.78 CH.sub.3 H H 2 H H H H CHOCH.sub.3 H CH.sub.36.79 CH.sub.3 H H 0 H H H H CHOC.sub.2 H.sub.5 H CH.sub.36.80 CH.sub.3 H H 1 H H H H CHOC.sub.2 H.sub.5 H CH.sub.36.81 CH.sub.3 H H 2 H H H H CHOC.sub.2 H.sub.5 H CH.sub.36.82 CH.sub.3 H H 0 H H H H CHOiPr H CH.sub.36.83 CH.sub.3 H H 1 H H H H CHOiPr H CH.sub.36.84 CH.sub.3 H H 2 H H H H CHOiPr H CH.sub.36.85 CH.sub.3 H H 0 H H H H C.dbd.NOCH.sub.3 H CH.sub.36.86 CH.sub.3 H H 1 H H H H C.dbd.NOCH.sub.3 H CH.sub.36.87 CH.sub.3 H H 2 H H H H C.dbd.NOCH.sub.3 H CH.sub.36.88 CH.sub.3 H H 0 H H H H C.dbd.NOC.sub.2 H.sub.5 H CH.sub.36.89 CH.sub.3 H H 1 H H H H C.dbd.NOC.sub.2 H.sub.5 H CH.sub.36.90 CH.sub.3 H H 2 H H H H C.dbd.NOC.sub.2 H.sub.5 H CH.sub.36.91 CH.sub.3 H H 0 H H H H C.dbd.NOiPr H CH.sub.36.92 CH.sub.3 H H 1 H H H H C.dbd.NOiPr H CH.sub.36.93 CH.sub.3 H H 2 H H H H C.dbd.NOiPr H CH.sub.36.94 CH.sub.3 H H 0 H H H H C.dbd.NOCH.sub.2 CH.dbd.CHCl H CH.sub.36.95 CH.sub.3 H H 1 H H H H C.dbd.NOCH.sub.2 CH.dbd.CHCl H CH.sub.36.96 CH.sub.3 H H 2 H H H H C.dbd.NOCH.sub.2 CH.dbd.CHCl H CH.sub.36.97 CH.sub.3 H H 0 H H H H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 H CH.sub.36.98 CH.sub.3 H H 1 H H H H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 H CH.sub.36.99 CH.sub.3 H H 2 H H H H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 H CH.sub.36.100 CH.sub.3 H H 0 H H H H C(CH.sub.3).sub.2 H CH.sub.36.101 CH.sub.3 H H 1 H H H H C(CH.sub.3).sub.2 H CH.sub.36.102 CH.sub.3 H H 2 H H H H C(CH.sub.3).sub.2 H CH.sub.36.103 CH.sub.3 H H 0 H H H H ##STR242## H CH.sub.36.104 CH.sub.3 H H 1 H H H H ##STR243## H CH.sub.36.105 CH.sub.3 H H 2 H H H H ##STR244## H CH.sub.36.106 CH.sub.3 H H 0 H H H H ##STR245## H CH.sub.36.107 CH.sub.3 H H 1 H H H H ##STR246## H CH.sub.36.108 CH.sub.3 H H 2 H H H H ##STR247## H CH.sub.36.109 CH.sub.3 H H 0 H H H H C.dbd.N--CH.sub.3 H CH.sub.36.110 CH.sub.3 H H 1 H H H H C.dbd.N--CH.sub.3 H CH.sub.36.111 CH.sub.3 H H 2 H H H H C.dbd.N--CH.sub.3 H CH.sub.36.112 CH.sub.3 H H 0 H H H H C.dbd.NC.sub.2 H.sub.5 H CH.sub.36.113 CH.sub.3 H H 1 H H H H C.dbd.NC.sub.2 H.sub.5 H CH.sub.36.114 CH.sub.3 H H 2 H H H H C.dbd.NC.sub.2 H.sub.5 H CH.sub.36.115 CH.sub.3 H H 0 H H H H CH--NHCH.sub.3 H CH.sub.36.116 CH.sub.3 H H 1 H H H H CH--NHCH.sub.3 H CH.sub.36.117 CH.sub.3 H H 2 H H H H CH--NHCH.sub.3 H CH.sub.36.118 CH.sub.3 H H 0 H H H H CH--NHC.sub.2 H.sub.5 H CH.sub.36.119 CH.sub.3 H H 1 H H H H CH--NHC.sub.2 H.sub.5 H CH.sub.36.120 CH.sub.3 H H 2 H H H H CH--NHC.sub.2 H.sub.5 H CH.sub.36.121 CH.sub.3 H H 0 H H H H CH--N(CH.sub.3).sub.2 H CH.sub.36.122 CH.sub.3 H H 1 H H H H CH--N(CH.sub.3).sub.2 H CH.sub.36.123 CH.sub.3 H H 2 H H H H CH--N(CH.sub.3).sub.2 H CH.sub.36.124 CH.sub.3 H H 0 H H H H CH--NHOC.sub.2 H.sub.5 H CH.sub.36.125 CH.sub.3 H H 1 H H H H CH--NHOC.sub.2 H.sub.5 H CH.sub.36.126 CH.sub.3 H H 2 H H H H CH--NHOC.sub.2 H.sub.5 H CH.sub.36.127 CH.sub.3 H H 0 H H H H CH--N(CH.sub.3)OC.sub.2 H.sub.5 H CH.sub.36.128 CH.sub.3 H H 1 H H H H CH--N(CH.sub.3)OC.sub.2 H.sub.5 H CH.sub.36.129 CH.sub.3 H H 2 H H H H CH--N(CH.sub.3)OC.sub.2 H.sub.5 H CH.sub.36.130 CH.sub.3 H H 0 H H H H C.dbd.N--NH.sub.2 H CH.sub.36.131 CH.sub.3 H H 1 H H H H C.dbd.N--NH.sub.2 H CH.sub.36.132 CH.sub.3 H H 2 H H H H C.dbd.N--NH.sub.2 H CH.sub.36.133 CH.sub.3 H H 0 H H H H C.dbd.N--N(CH.sub.3).sub.2 H CH.sub.36.134 CH.sub.3 H H 1 H H H H C.dbd.N--N(CH.sub.3).sub.2 H CH.sub.36.135 CH.sub.3 H H 2 H H H H C.dbd.N--N(CH.sub.3).sub.2 H CH.sub.36.136 CH.sub.3 H H 0 H H H H CH--N(CH.sub.3)OCH.sub.2 C.sub.6 H.sub.5 H CH.sub.36.137 CH.sub.3 H H 1 H H H H CH--N(CH.sub.3)OCH.sub.2 C.sub.6 H.sub.5 H CH.sub.36.138 CH.sub.3 H H 2 H H H H CH--N(CH.sub.3)OCH.sub.2 C.sub.6 H.sub.5 H CH.sub.36.139 CH.sub.3 H H 0 H H H H C(CH.sub.3)--OCH.sub.3 H CH.sub.36.140 CH.sub.3 H H 1 H H H H C(CH.sub.3)--OCH.sub.3 H CH.sub.36.141 CH.sub.3 H H 2 H H H H C(CH.sub.3)--OCH.sub.3 H CH.sub.36.142 CH.sub.3 H H 0 H H H H O H CH.sub.36.143 CH.sub.3 H H 1 H H H H O H CH.sub.36.144 CH.sub.3 H H 2 H H H H O H CH.sub.36.145 CH.sub.3 CH.sub.3 H 0 H H H H C.dbd.O H CH.sub.36.146 CH.sub.3 CH.sub.3 H 1 H H H H C.dbd.O H CH.sub.36.147 CH.sub.3 CH.sub.3 H 2 H H H H C.dbd.O H CH.sub.36.148 CH.sub.3 CH.sub.3 H 0 H H H H CHOCH.sub.3 H CH.sub.36.149 CH.sub.3 CH.sub.3 H 1 H H H H CHOCH.sub.3 H CH.sub.36.150 CH.sub.3 CH.sub.3 H 2 H H H H CHOCH.sub.3 H CH.sub.36.151 CH.sub.3 CH.sub.3 H 0 H H H H CHOC.sub.2 H.sub.5 H CH.sub.36.152 CH.sub.3 CH.sub.3 H 1 H H H H CHOC.sub.2 H.sub.5 H CH.sub.36.153 CH.sub.3 CH.sub.3 H 2 H H H H CHOC.sub.2 H.sub.5 H CH.sub.36.154 CH.sub.3 CH.sub.3 H 0 H H H H CHOiPr H CH.sub.36.155 CH.sub.3 CH.sub.3 H 1 H H H H CHOiPr H CH.sub.36.156 CH.sub.3 CH.sub.3 H 2 H H H H CHOiPr H CH.sub.36.157 CH.sub.3 CH.sub.3 H 0 H H H H C.dbd.NOCH.sub.3 H CH.sub.36.158 CH.sub.3 CH.sub.3 H 1 H H H H C.dbd.NOCH.sub.3 H CH.sub.36.159 CH.sub.3 CH.sub.3 H 2 H H H H C.dbd.NOCH.sub.3 H CH.sub.36.160 CH.sub.3 CH.sub.3 H 0 H H H H C.dbd.NOC.sub.2 H.sub.5 H CH.sub.36.161 CH.sub.3 CH.sub.3 H 1 H H H H C.dbd.NOC.sub.2 H.sub.5 H CH.sub.36.162 CH.sub.3 CH.sub.3 H 2 H H H H C.dbd.NOC.sub.2 H.sub.5 H CH.sub.36.163 CH.sub.3 CH.sub.3 H 0 H H H H C.dbd.NOiPr H CH.sub.36.164 CH.sub.3 CH.sub.3 H 1 H H H H C.dbd.NOiPr H CH.sub.36.165 CH.sub.3 CH.sub.3 H 2 H H H H C.dbd.NOiPr H CH.sub.36.166 CH.sub.3 CH.sub.3 H 0 H H H H C.dbd.NOCH.sub.2 CH.dbd.CHCl H CH.sub.36.167 CH.sub.3 CH.sub.3 H 1 H H H H C.dbd.NOCH.sub.2 CH.dbd.CHCl H CH.sub.36.168 CH.sub.3 CH.sub.3 H 2 H H H H C.dbd.NOCH.sub.2 CH.dbd.CHCl H CH.sub.36.169 CH.sub.3 CH.sub.3 H 0 H H H H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 H CH.sub.36.170 CH.sub.3 CH.sub.3 H 1 H H H H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 H CH.sub.36.171 CH.sub.3 CH.sub.3 H 2 H H H H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 H CH.sub.36.172 CH.sub.3 CH.sub.3 H 0 H H H H C(CH.sub.3).sub.2 H CH.sub.36.173 CH.sub.3 CH.sub.3 H 1 H H H H C(CH.sub.3).sub.2 H CH.sub.36.174 CH.sub.3 CH.sub.3 H 2 H H H H C(CH.sub.3).sub.2 H CH.sub.36.175 CH.sub.3 CH.sub.3 H 0 H H H H ##STR248## H CH.sub.36.176 CH.sub.3 CH.sub.3 H 1 H H H H ##STR249## H CH.sub.36.177 CH.sub.3 CH.sub.3 H 2 H H H H ##STR250## H CH.sub.36.178 CH.sub.3 CH.sub.3 H 0 H H H H ##STR251## H CH.sub.36.179 CH.sub.3 CH.sub.3 H 1 H H H H ##STR252## H CH.sub.36.180 CH.sub.3 CH.sub.3 H 2 H H H H ##STR253## H CH.sub.36.181 CH.sub.3 CH.sub.3 H 0 H H H H C.dbd.N--CH.sub.3 H CH.sub.36.182 CH.sub.3 CH.sub.3 H 1 H H H H C.dbd.N--CH.sub.3 H CH.sub.36.183 CH.sub.3 CH.sub.3 H 2 H H H H C.dbd.N--CH.sub.3 H CH.sub.36.184 CH.sub.3 CH.sub.3 H 0 H H H H C.dbd.NC.sub.2 H.sub.5 H CH.sub.36.185 CH.sub.3 CH.sub.3 H 1 H H H H C.dbd.NC.sub.2 H.sub.5 H CH.sub.36.186 CH.sub.3 CH.sub.3 H 2 H H H H C.dbd.NC.sub.2 H.sub.5 H CH.sub.36.187 CH.sub.3 CH.sub.3 H 0 H H H H CH--NHCH.sub.3 H CH.sub.36.188 CH.sub.3 CH.sub.3 H 1 H H H H CH--NHCH.sub.3 H CH.sub.36.189 CH.sub.3 CH.sub.3 H 2 H H H H CH--NHCH.sub.3 H CH.sub.36.190 CH.sub.3 CH.sub.3 H 0 H H H H CH--NHC.sub.2 H.sub.5 H CH.sub.36.191 CH.sub.3 CH.sub.3 H 1 H H H H CH--NHC.sub.2 H.sub.5 H CH.sub.36.192 CH.sub.3 CH.sub.3 H 2 H H H H CH--NHC.sub.2 H.sub.5 H CH.sub.36.193 CH.sub.3 CH.sub.3 H 0 H H H H CH--N(CH.sub.3).sub.2 H CH.sub.36.194 CH.sub.3 CH.sub.3 H 1 H H H H CH--N(CH.sub.3).sub.2 H CH.sub.36.195 CH.sub.3 CH.sub.3 H 2 H H H H CH--N(CH.sub.3).sub.2 H CH.sub.36.196 CH.sub.3 CH.sub.3 H 0 H H H H CH--NHOC.sub.2 H.sub.5 H CH.sub.36.197 CH.sub.3 CH.sub.3 H 1 H H H H CH--NHOC.sub.2 H.sub.5 H CH.sub.36.198 CH.sub.3 CH.sub.3 H 2 H H H H CH--NHOC.sub.2 H.sub.5 H CH.sub.36.199 CH.sub.3 CH.sub.3 H 0 H H H H CH--N(CH.sub.3)OC.sub.2 H.sub.5 H CH.sub.36.200 CH.sub.3 CH.sub.3 H 1 H H H H CH--N(CH.sub.3)OC.sub.2 H.sub.5 H CH.sub.36.201 CH.sub.3 CH.sub.3 H 2 H H H H CH--N(CH.sub.3)OC.sub.2 H.sub.5 H CH.sub.36.202 CH.sub.3 CH.sub.3 H 0 H H H H C.dbd.N--NH.sub.2 H CH.sub.36.203 CH.sub.3 CH.sub.3 H 1 H H H H C.dbd.N--NH.sub.2 H CH.sub.36.204 CH.sub.3 CH.sub.3 H 2 H H H H C.dbd.N--NH.sub.2 H CH.sub.36.205 CH.sub.3 CH.sub.3 H 0 H H H H C.dbd.N--N(CH.sub.3).sub.2 H CH.sub.36.206 CH.sub.3 CH.sub.3 H 1 H H H H C.dbd.N--N(CH.sub.3).sub.2 H CH.sub.36.207 CH.sub.3 CH.sub.3 H 2 H H H H C.dbd.N--N(CH.sub.3).sub.2 H CH.sub.36.208 CH.sub.3 CH.sub.3 H 0 H H H H CH--N(CH.sub.3)OCH.sub.2 C.sub.6 H.sub.5 H CH.sub.36.209 CH.sub.3 CH.sub.3 H 1 H H H H CH--N(CH.sub.3)OCH.sub.2 C.sub.6 H.sub.5 H CH.sub.36.210 CH.sub.3 CH.sub.3 H 2 H H H H CH--N(CH.sub.3)OCH.sub.2 C.sub.6 H.sub.5 H CH.sub.36.211 CH.sub.3 CH.sub.3 H 0 H H H H C(CH.sub.3)--OCH.sub.3 H CH.sub.36.212 CH.sub.3 CH.sub.3 H 1 H H H H C(CH.sub.3)--OCH.sub.3 H CH.sub.36.213 CH.sub.3 CH.sub.3 H 2 H H H H C(CH.sub.3)--OCh.sub.3 H CH.sub.36.214 CH.sub.3 CH.sub.3 H 0 H H H H O H CH.sub.36.215 CH.sub.3 CH.sub.3 H 1 H H H H O H CH.sub.36.216 CH.sub.3 CH.sub.3 H 2 H H H H O H CH.sub.36.217 H H H 0 H H H H C.dbd.O H Cl6.218 H H H 1 H H H H C.dbd.O H Cl6.219 H H H 2 H H H H C.dbd.O H Cl6.220 H H H 0 H H H H CHOCH.sub.3 H Cl6.221 H H H 1 H H H H CHOCH.sub.3 H Cl6.222 H H H 2 H H H H CHOCH.sub.3 H Cl6.223 H H H 0 H H H H CHOC.sub.2 H.sub.5 H Cl6.224 H H H 1 H H H H CHOC.sub.2 H.sub.5 H Cl6.225 H H H 2 H H H H CHOC.sub.2 H.sub.5 H Cl6.226 H H H 0 H H H H CHOiPr H Cl6.227 H H H 1 H H H H CHOiPr H Cl6.228 H H H 2 H H H H CHOiPr H Cl6.229 H H H 0 H H H H C.dbd.NOCH.sub.3 H Cl6.230 H H H 1 H H H H C.dbd.NOCH.sub.3 H Cl6.231 H H H 2 H H H H C.dbd.NOCH.sub.3 H Cl6.232 H H H 0 H H H H C.dbd.NOC.sub.2 H.sub.5 H Cl6.233 H H H 1 H H H H C.dbd.NOC.sub.2 H.sub.5 H Cl6.234 H H H 2 H H H H C.dbd.NOC.sub.2 H.sub.5 H Cl6.235 H H H 0 H H H H C.dbd.NOiPr H Cl6.236 H H H 1 H H H H C.dbd.NOiPr H Cl6.237 H H H 2 H H H H C.dbd.NOiPr H Cl6.238 H H H 0 H H H H C.dbd.NOCH.sub.2 CH.dbd.CHCl H Cl6.239 H H H 1 H H H H C.dbd.NOCH.sub.2 CH.dbd.CHCl H Cl6.240 H H H 2 H H H H C.dbd.NOCH.sub.2 CH.dbd.CHCl H Cl6.241 H H H 0 H H H H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 H Cl6.242 H H H 1 H H H H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 H Cl6.243 H H H 2 H H H H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 H Cl6.244 H H H 0 H H H H C(CH.sub.3).sub.2 H Cl6.245 H H H 1 H H H H C(CH.sub.3).sub.2 H Cl6.246 H H H 2 H H H H C(CH.sub.3).sub.2 H Cl6.247 H H H 0 H H H H ##STR254## H Cl6.248 H H H 1 H H H H ##STR255## H Cl6.249 H H H 2 H H H H ##STR256## H Cl6.250 H H H 0 H H H H ##STR257## H Cl6.251 H H H 1 H H H H ##STR258## H Cl6.252 H H H 2 H H H H ##STR259## H Cl6.253 H H H 0 H H H H C.dbd.N--CH.sub.3 H Cl6.254 H H H 1 H H H H C.dbd.N--CH.sub.3 H Cl6.255 H H H 2 H H H H C.dbd.N--CH.sub.3 H Cl6.256 H H H 0 H H H H C.dbd.NC.sub.2 H.sub.5 H Cl6.257 H H H 1 H H H H C.dbd.NC.sub.2 H.sub.5 H Cl6.258 H H H 2 H H H H C.dbd.NC.sub.2 H.sub.5 H Cl6.259 H H H 0 H H H H CH--NHCH.sub.3 H Cl6.260 H H H 1 H H H H CH--NHCH.sub.3 H Cl6.261 H H H 2 H H H H CH--NHCH.sub.3 H Cl6.262 H H H 0 H H H H CH--NHC.sub.2 H.sub.5 H Cl6.263 H H H 1 H H H H CH--NHC.sub.2 H.sub.5 H Cl6.264 H H H 2 H H H H CH--NHC.sub.2 H5 H Cl6.265 H H H 0 H H H H CH--N(CH.sub.3).sub.2 H Cl6.266 H H H 1 H H H H CH--N(CH.sub.3).sub.2 H Cl6.267 H H H 2 H H H H CH--N(CH.sub.3).sub.2 H Cl6.268 H H H 0 H H H H CH--NHOC.sub.2 H.sub.5 H Cl6.269 H H H 1 H H H H CH--NHOC.sub.2 H.sub.5 H Cl6.270 H H H 2 H H H H CH--NHOC.sub.2 H.sub.5 H Cl6.271 H H H 0 H H H H CH--N(CH.sub.3)OC.sub.2 H.sub.5 H Cl6.272 H H H 1 H H H H CH--N(CH.sub.3)OC.sub.2 H.sub.5 H Cl6.273 H H H 2 H H H H CH--N(CH.sub.3)OC.sub.2 H.sub.5 H Cl6.274 H H H 0 H H H H C.dbd.N--NH.sub.2 H Cl6.275 H H H 1 H H H H C.dbd.N--NH.sub.2 H Cl6.276 H H H 2 H H H H C.dbd.N--NH.sub.2 H Cl6.277 H H H 0 H H H H C.dbd.N--N(CH.sub.3).sub.2 H Cl6.278 H H H 1 H H H H C.dbd.N--N(CH.sub.3).sub.2 H Cl6.279 H H H 2 H H H H C.dbd.N--N(CH.sub.3).sub.2 H Cl6.280 H H H 0 H H H H CH--N(CH.sub.3)OCH.sub.2 C.sub.6 H.sub.5 H Cl6.281 H H H 1 H H H H CH--N(CH.sub.3)OCH.sub.2 C.sub.6 H.sub.5 H Cl6.282 H H H 2 H H H H CH--N(CH.sub.3)OCH.sub.2 C.sub.6 H.sub.5 H Cl6.283 H H H 0 H H H H C(CH.sub.3)--OCH.sub.3 H Cl6.284 H H H 1 H H H H C(CH.sub.3)--OCH.sub.3 H Cl6.285 H H H 2 H H H H C(CH.sub.3)--OCH.sub.3 H Cl6.286 H H H 0 H H H H O H Cl6.287 H H H 1 H H H H O H Cl6.288 H H H 2 H H H H O H Cl6.289 CH.sub.3 H H 0 H H H H C.dbd.O H Cl6.290 CH.sub.3 H H 1 H H H H C.dbd.O H Cl6.291 CH.sub.3 H H 2 H H H H C.dbd.O H Cl6.292 CH.sub.3 H H 0 H H H H CHOCH.sub.3 H Cl6.293 CH.sub.3 H H 1 H H H H CHOCH.sub.3 H Cl6.294 CH.sub.3 H H 2 H H H H CHOCH.sub.3 H Cl6.295 CH.sub.3 H H 0 H H H H CHOC.sub.2 H.sub.5 H Cl6.296 CH.sub.3 H H 1 H H H H CHOC.sub.2 H.sub.5 H Cl6.297 CH.sub.3 H H 2 H H H H CHOC.sub.2 H.sub.5 H Cl6.298 CH.sub.3 H H 0 H H H H CHOiPr H Cl6.299 CH.sub.3 H H 1 H H H H CHOiPr H Cl6.300 CH.sub.3 H H 2 H H H H CHOiPr H Cl6.301 CH.sub.3 H H 0 H H H H C.dbd.NOCH.sub.3 H Cl6.302 CH.sub.3 H H 1 H H H H C.dbd.NOCH.sub.3 H Cl6.303 CH.sub.3 H H 2 H H H H C.dbd.NOCH.sub.3 H Cl6.304 CH.sub.3 H H 0 H H H H C.dbd.NOC.sub.2 H.sub.5 H Cl6.305 CH.sub.3 H H 1 H H H H C.dbd.NOC.sub.2 H.sub.5 H Cl6.306 CH.sub.3 H H 2 H H H H C.dbd.NOC.sub.2 H.sub.5 H Cl6.307 CH.sub.3 H H 0 H H H H C.dbd.NOiPr H Cl6.308 CH.sub.3 H H 1 H H H H C.dbd.NOiPr H Cl6.309 CH.sub.3 H H 2 H H H H C.dbd.NOiPr H Cl6.310 CH.sub.3 H H 0 H H H H C.dbd.NOCH.sub.2 CH.dbd.CHCl H Cl6.311 CH.sub.3 H H 1 H H H H C.dbd.NOCH.sub.2 CH.dbd.CHCl H Cl6.312 CH.sub.3 H H 2 H H H H C.dbd.NOCH.sub.2 CH.dbd.CHCl H Cl6.313 CH.sub.3 H H 0 H H H H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 H Cl6.314 CH.sub.3 H H 1 H H H H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 H Cl6.315 CH.sub.3 H H 2 H H H H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 H Cl6.316 CH.sub.3 H H 0 H H H H C(CH.sub.3).sub.2 H Cl6.317 CH.sub.3 H H 1 H H H H C(CH.sub.3).sub.2 H Cl6.318 CH.sub.3 H H 2 H H H H C(CH.sub.3).sub.2 H Cl6.319 CH.sub.3 H H 0 H H H H ##STR260## H Cl6.320 CH.sub.3 H H 1 H H H H ##STR261## H Cl6.321 CH.sub.3 H H 2 H H H H ##STR262## H Cl6.322 CH.sub.3 H H 0 H H H H ##STR263## H Cl6.323 CH.sub.3 H H 1 H H H H ##STR264## H Cl6.324 CH.sub.3 H H 2 H H H H ##STR265## H Cl6.325 CH.sub.3 H H 0 H H H H C.dbd.N--CH.sub.3 H Cl6.326 CH.sub.3 H H 1 H H H H C.dbd.N--CH.sub.3 H Cl6.327 CH.sub.3 H H 2 H H H H C.dbd.N--CH.sub.3 H Cl6.328 CH.sub.3 H H 0 H H H H C.dbd.NC.sub.2 H.sub.5 H Cl6.329 CH.sub.3 H H 1 H H H H C.dbd.NC.sub.2 H.sub.5 H Cl6.330 CH.sub.3 H H 2 H H H H C.dbd.NC.sub.2 H.sub.5 H Cl6.331 CH.sub.3 H H 0 H H H H CH--NHCH.sub.3 H Cl6.332 CH.sub.3 H H 1 H H H H CH--NHCH.sub.3 H Cl6.333 CH.sub.3 H H 2 H H H H CH--NHCH.sub.3 H Cl6.334 CH.sub.3 H H 0 H H H H CH--NHC.sub.2 H.sub.5 H Cl6.335 CH.sub.3 H H 1 H H H H CH--NHC.sub.2 H.sub.5 H Cl6.336 CH.sub.3 H H 2 H H H H CH--NHC.sub.2 H.sub.5 H Cl6.337 CH.sub.3 H H 0 H H H H CH--N(CH.sub.3).sub.2 H Cl6.338 CH.sub.3 H H 1 H H H H CH--N(CH.sub.3).sub.2 H Cl6.339 CH.sub.3 H H 2 H H H H CH--N(CH.sub.3).sub.2 H Cl6.340 CH.sub.3 H H 0 H H H H CH--NHOC.sub.2 H.sub.5 H Cl6.341 CH.sub.3 H H 1 H H H H CH--NHOC.sub.2 H.sub.5 H Cl6.342 CH.sub.3 H H 2 H H H H CH--NHOC.sub.2 H.sub.5 H Cl6.343 CH.sub.3 H H 0 H H H H CH--N(CH.sub.3)OC.sub.2 H.sub.5 H Cl6.344 CH.sub.3 H H 1 H H H H CH--N(CH.sub.3)OC.sub.2 H.sub.5 H Cl6.345 CH.sub.3 H H 2 H H H H CH--N(CH.sub.3)OC.sub.2 H.sub.5 H Cl6.346 CH.sub.3 H H 0 H H H H C.dbd.N--NH.sub.2 H Cl6.347 CH.sub.3 H H 1 H H H H C.dbd.N--NH.sub.2 H Cl6.348 CH.sub.3 H H 2 H H H H C.dbd.N--NH.sub.2 H Cl6.349 CH.sub.3 H H 0 H H H H C.dbd.N--N(CH.sub.3).sub.2 H Cl6.350 CH.sub.3 H H 1 H H H H C.dbd.N--N(CH.sub.3).sub.2 H Cl6.351 CH.sub.3 H H 2 H H H H C.dbd.N--N(CH.sub.3).sub.2 H Cl6.352 CH.sub.3 H H 0 H H H H CH--N(CH.sub.3)OCH.sub.2 C.sub.6 H.sub.5 H Cl6.353 CH.sub.3 H H 1 H H H H CH--N(CH.sub.3)OCH.sub.2 C.sub.6 H.sub.5 H Cl6.354 CH.sub.3 H H 2 H H H H CH--N(CH.sub.3)OCH.sub.2 C.sub.6 H.sub.5 H Cl6.355 CH.sub.3 H H 0 H H H H C(CH.sub.3)--OCH.sub.3 H Cl6.356 CH.sub.3 H H 1 H H H H C(CH.sub.3)--OCH.sub.3 H Cl6.357 CH.sub.3 H H 2 H H H H C(CH.sub.3)--OCH.sub.3 H Cl6.358 CH.sub.3 H H 0 H H H H O H Cl6.359 CH.sub.3 H H 1 H H H H O H Cl6.360 CH.sub.3 H H 2 H H H H O H Cl6.361 CH.sub.3 CH.sub.3 H 0 H H H H C.dbd.O H Cl6.362 CH.sub.3 CH.sub.3 H 1 H H H H C.dbd.O H Cl6.363 CH.sub.3 CH.sub.3 H 2 H H H H C.dbd.O H Cl6.364 CH.sub.3 CH.sub.3 H 0 H H H H CHOCH.sub.3 H Cl6.365 CH.sub.3 CH.sub.3 H 1 H H H H CHOCH.sub.3 H Cl6.366 CH.sub.3 CH.sub.3 H 2 H H H H CHOCH.sub.3 H Cl6.367 CH.sub.3 CH.sub.3 H 0 H H H H CHOC.sub.2 H.sub.5 H Cl6.368 CH.sub.3 CH.sub.3 H 1 H H H H CHOC.sub.2 H.sub.5 H Cl6.369 CH.sub.3 CH.sub.3 H 2 H H H H CHOC.sub.2 H.sub.5 H Cl6.370 CH.sub.3 CH.sub.3 H 0 H H H H CHOiPr H Cl6.371 CH.sub.3 CH.sub.3 H 1 H H H H CHOiPr H Cl6.372 CH.sub.3 CH.sub.3 H 2 H H H H CHOiPr H Cl6.373 CH.sub.3 CH.sub.3 H 0 H H H H C.dbd.NOCH.sub.3 H Cl6.374 CH.sub.3 CH.sub.3 H 1 H H H H C.dbd.NOCH.sub.3 H Cl6.375 CH.sub.3 CH.sub.3 H 2 H H H H C.dbd.NOCH.sub.3 H Cl6.376 CH.sub.3 CH.sub.3 H 0 H H H H C.dbd.NOC.sub.2 H.sub.5 H Cl6.377 CH.sub.3 CH.sub.3 H 1 H H H H C.dbd.NOC.sub.2 H.sub.5 H Cl6.378 CH.sub.3 CH.sub.3 H 2 H H H H C.dbd.NOC.sub.2 H.sub.5 H Cl6.379 CH.sub.3 CH.sub.3 H 0 H H H H C.dbd.NOiPr H Cl6.380 CH.sub.3 CH.sub.3 H 1 H H H H C.dbd.NOiPr H Cl6.381 CH.sub.3 CH.sub.3 H 2 H H H H C.dbd.NOiPr H Cl6.382 CH.sub.3 CH.sub.3 H 0 H H H H C.dbd.NOCH.sub.2 CH.dbd.CHCl H Cl6.383 CH.sub.3 CH.sub.3 H 1 H H H H C.dbd.NOCH.sub.2 CH.dbd.CHCl H Cl6.384 CH.sub.3 CH.sub.3 H 2 H H H H C.dbd.NOCH.sub.2 CH.dbd.CHCl H Cl6.385 CH.sub.3 CH.sub.3 H 0 H H H H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 H Cl6.386 CH.sub.3 CH.sub.3 H 1 H H H H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 H Cl6.387 CH.sub.3 CH.sub.3 H 2 H H H H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 H Cl6.388 CH.sub.3 CH.sub.3 H 0 H H H H C(CH.sub.3).sub.2 H Cl6.389 CH.sub.3 CH.sub.3 H 1 H H H H C(CH.sub.3).sub.2 H Cl6.390 CH.sub.3 CH.sub.3 H 2 H H H H C(CH.sub.3).sub.2 H Cl6.391 CH.sub.3 CH.sub.3 H 0 H H H H ##STR266## H Cl6.392 CH.sub.3 CH.sub.3 H 1 H H H H ##STR267## H Cl6.393 CH.sub.3 CH.sub.3 H 2 H H H H ##STR268## H Cl6.394 CH.sub.3 CH.sub.3 H 0 H H H H ##STR269## H Cl6.395 CH.sub.3 CH.sub.3 H 1 H H H H ##STR270## H Cl6.396 CH.sub.3 CH.sub.3 H 2 H H H H ##STR271## H Cl6.397 CH.sub.3 CH.sub.3 H 0 H H H H C.dbd.N--CH.sub.3 H Cl6.398 CH.sub.3 CH.sub.3 H 1 H H H H C.dbd.N--CH.sub.3 H Cl6.399 CH.sub.3 CH.sub.3 H 2 H H H H C.dbd.N--CH.sub.3 H Cl6.400 CH.sub.3 CH.sub.3 H 0 H H H H C.dbd.NC.sub.2 H.sub.5 H Cl6.401 CH.sub.3 CH.sub.3 H 1 H H H H C.dbd.NC.sub.2 H.sub.5 H Cl6.402 CH.sub.3 CH.sub.3 H 2 H H H H C.dbd.NC.sub.2 H.sub.5 H Cl6.403 CH.sub.3 CH.sub.3 H 0 H H H H CH--NHCH.sub.3 H Cl6.404 CH.sub.3 CH.sub.3 H 1 H H H H CH--NHCH.sub.3 H Cl6.405 CH.sub.3 CH.sub.3 H 2 H H H H CH--NHCH.sub.3 H Cl6.406 CH.sub.3 CH.sub.3 H 0 H H H H CH--NHC.sub.2 H.sub.5 H Cl6.407 CH.sub.3 CH.sub.3 H 1 H H H H CH--NHC.sub.2 H.sub.5 H Cl6.408 CH.sub.3 CH.sub.3 H 2 H H H H CH--NHC.sub.2 H.sub.5 H Cl6.409 CH.sub.3 CH.sub.3 H 0 H H H H CH--N(CH.sub.3).sub.2 H Cl6.410 CH.sub.3 CH.sub.3 H 1 H H H H CH--N(Cf3)2 H Cl6.411 CH.sub.3 CH.sub.3 H 2 H H H H CH--N(CH.sub.3).sub.2 H Cl6.412 CH.sub.3 CH.sub.3 H 0 H H H H CH--NHOC.sub.2 H.sub.5 H Cl6.413 CH.sub.3 CH.sub.3 H 1 H H H H CH--NHOC.sub.2 H.sub.5 H Cl6.414 CH.sub.3 CH.sub.3 H 2 H H H H CH--NHOC.sub.2 H.sub.5 H Cl6.415 CH.sub.3 CH.sub.3 H 0 H H H H CH--N(CH.sub.3)OC.sub.2 H.sub.5 H Cl6.416 CH.sub.3 CH.sub.3 H 1 H H H H CH--N(CH.sub.3)OC.sub.2 H.sub.5 H Cl6.417 CH.sub.3 CH.sub.3 H 2 H H H H CH--N(CH.sub.3)OC.sub.2 H.sub.5 H Cl6.418 CH.sub.3 CH.sub.3 H 0 H H H H C.dbd.N--NH.sub.2 H Cl6.419 CH.sub.3 CH.sub.3 H 1 H H H H C.dbd.N--NH.sub.2 H Cl6.420 CH.sub.3 CH.sub.3 H 2 H H H H C.dbd.N--NH.sub.2 H Cl6.421 CH.sub.3 CH.sub.3 H 0 H H H H C.dbd.N--N(CH.sub.3).sub.2 H Cl6.422 CH.sub.3 CH.sub.3 H 1 H H H H C.dbd.N--N(CH.sub.3).sub.2 H Cl6.423 CH.sub.3 CH.sub.3 H 2 H H H H C.dbd.N--N(CH.sub.3).sub.2 H Cl6.424 CH.sub.3 CH.sub.3 H 0 H H H H CH--N(CH.sub.3)OCH.sub.2 C.sub.6 H.sub.5 H Cl6.425 CH.sub.3 CH.sub.3 H 1 H H H H CH--N(CH.sub.3)OCH.sub.2 C.sub.6 H.sub.5 H Cl6.426 CH.sub.3 CH.sub.3 H 2 H H H H CH--N(CH.sub.3)OCH.sub.2 C.sub.6 H.sub.5 H Cl6.427 CH.sub.3 CH.sub.3 H 0 H H H H C(CH.sub.3)--OCH.sub.3 H Cl6.428 CH.sub.3 CH.sub.3 H 1 H H H H C(CH.sub.3)--OCH.sub.3 H Cl6.429 CH.sub.3 CH.sub.3 H 2 H H H H C(CH.sub.3)--OCH.sub.3 H Cl6.430 CH.sub.3 CH.sub.3 H 1 H H H H O H Cl6.431 CH.sub.3 CH.sub.3 H 0 H H H H O H Cl6.432 CH.sub.3 CH.sub.3 H 2 H H H H O H Cl__________________________________________________________________________
TABLE 7______________________________________Compounds of the formula ##STR272##The radicals R.sup.7 and R.sup.23 form a bond.No. R.sup.17 R.sup.18 R.sup.19 n Y L M______________________________________7.1 H H H 2 COCH.sub.3 H H7.2 H H H 2 COC.sub.2 H.sub.5 H H7.3 CH.sub.3 H H 2 COCH.sub.3 H H7.4 CH.sub.3 H H 2 COC.sub.2 H.sub.5 H H7.5 CH.sub.3 CH.sub.3 H 2 COCH.sub.3 H H7.6 CH.sub.3 CH.sub.3 H 2 COC.sub.2 H.sub.5 H H7.7 H H H 2 COCH.sub.3 H CH.sub.37.8 H H H 2 COC.sub.2 H.sub.5 H CH.sub.37.9 CH.sub.3 H H 2 COCH.sub.3 H CH.sub.37.10 CH.sub.3 H H 2 COC.sub.2 H.sub.5 H CH.sub.37.11 CH.sub.3 CH.sub.3 H 2 COCH.sub.3 H CH.sub.37.12 CH.sub.3 CH.sub.3 H 2 COC.sub.2 H.sub.5 H CH.sub.37.13 H H H 2 COCH.sub.3 H Cl7.14 H H H 2 COC.sub.2 H.sub.5 H Cl7.15 CH.sub.3 H H 2 COCH.sub.3 H Cl7.16 CH.sub.3 H H 2 COC.sub.2 H.sub.5 H Cl7.17 CH.sub.3 CH.sub.3 H 2 COCH.sub.3 H Cl7.18 CH.sub.3 CH.sub.3 H 2 COC.sub.2 H.sub.5 H Cl7.19 H H H 2 COCH.sub.3 H NO.sub.27.20 H H H 2 COC.sub.2 H.sub.5 H NO.sub.27.21 CH.sub.3 H H 2 COCH.sub.3 H NO.sub.27.22 CH.sub.3 H H 2 COC.sub.2 H.sub.5 H NO.sub.27.23 CH.sub.3 CH.sub.3 H 2 COCH.sub.3 H NO.sub.27.24 CH.sub.3 CH.sub.3 H 2 COC.sub.2 H.sub.5 H NO.sub.27.25 H H H 2 COCH.sub.3 H SO.sub.2 CH.sub.37.26 H H H 2 COC.sub.2 H.sub.5 H SO.sub.2 CH.sub.37.27 CH.sub.3 H H 2 COCH.sub.3 H SO.sub.2 CH.sub.37.28 CH.sub.3 H H 2 COC.sub.2 H.sub.5 H SO.sub.2 CH.sub.37.29 CH.sub.3 CH.sub.3 H 2 COCH.sub.3 H SO.sub.2 CH.sub.37.30 CH.sub.3 CH.sub.3 H 2 COC.sub.2 H.sub.5 H SO.sub.2 CH.sub.37.31 H H H 2 COCH.sub.3 CH.sub.3 CH.sub.37.32 H H H 2 COC.sub.2 H.sub.5 CH.sub.3 CH.sub.37.33 CH.sub.3 H H 2 COCH.sub.3 CH.sub.3 CH.sub.37.34 CH.sub.3 H H 2 COC.sub.2 H.sub.5 CH.sub.3 CH.sub.37.35 CH.sub.3 CH.sub.3 H 2 COCH.sub.3 CH.sub.3 CH.sub.37.36 CH.sub.3 CH.sub.3 H 2 COC.sub.2 H.sub.5 CH.sub.3 CH.sub.37.37 H H H 2 COCH.sub.3 Cl Cl7.38 H H H 2 COC.sub.2 H.sub.5 Cl Cl7.39 CH.sub.3 H H 2 COCH.sub.3 Cl Cl7.40 CH.sub.3 H H 2 COC.sub.2 H.sub.5 Cl Cl7.41 CH.sub.3 CH.sub.3 H 2 COCH.sub.3 Cl Cl7.42 CH.sub.3 CH.sub.3 H 2 COC.sub.2 H.sub.5 Cl Cl______________________________________
TABLE 8______________________________________Compounds of the formula ##STR273##No. R.sup.17 R.sup.18 R.sup.19 n Y M L______________________________________8.1 H H H 2 COCH.sub.3 H CH.sub.38.2 H H H 2 COC.sub.2 H.sub.5 H CH.sub.38.3 CH.sub.3 H H 2 COCH.sub.3 H CH.sub.38.4 CH.sub.3 H H 2 COC.sub.2 H.sub.5 H CH.sub.38.5 CH.sub.3 CH.sub.3 H 2 COCH.sub.3 H CH.sub.38.6 CH.sub.3 CH.sub.3 H 2 COC.sub.2 H.sub.5 H CH.sub.38.7 H H H 2 COCH.sub.3 H Cl8.8 H H H 2 COC.sub.2 H.sub.5 H Cl8.9 CH.sub.3 H H 2 COCH.sub.3 H Cl8.10 CH.sub.3 H H 2 COC.sub.2 H.sub.5 H Cl8.11 CH.sub.3 CH.sub.3 H 2 COCH.sub.3 H Cl8.12 CH.sub.3 CH.sub.3 H 2 COC.sub.2 H.sub.5 H Cl8.13 H H H 2 COCH.sub.3 H NO.sub.28.14 H H H 2 COC.sub.2 H.sub.5 H NO.sub.28.15 CH.sub.3 H H 2 COCH.sub.3 H NO.sub.28.16 CH.sub.3 H H 2 COC.sub.2 H.sub.5 H NO.sub.28.17 CH.sub.3 CH.sub.3 H 2 COCH.sub.3 H NO.sub.28.18 CH.sub.3 CH.sub.3 H 2 COC.sub.2 H.sub.5 H NO.sub.28.19 H H H 2 COCH.sub.3 H SO.sub.2 CH.sub.38.20 H H H 2 COC.sub.2 H.sub.5 H SO.sub.2 CH.sub.38.21 CH.sub.3 H H 2 COCH.sub.3 H SO.sub.2 CH.sub.38.22 CH.sub.3 H H 2 COC.sub.2 H.sub.5 H SO.sub.2 CH.sub.38.23 CH.sub.3 CH.sub.3 H 2 COCH.sub.3 H SO.sub.2 CH.sub.38.24 CH.sub.3 CH.sub.3 H 2 COC.sub.2 H.sub.5 H SO.sub.2 CH.sub.38.25 H H H 2 COCH.sub.3 CH.sub.3 CH.sub.38.26 H H H 2 COC.sub.2 H.sub.5 CH.sub.3 CH.sub.38.27 CH.sub.3 H H 2 COCH.sub.3 CH.sub.3 CH.sub.38.28 CH.sub.3 H H 2 COC.sub.2 H.sub.5 CH.sub.3 CH.sub.38.29 CH.sub.3 CH.sub.3 H 2 COCH.sub.3 CH.sub.3 CH.sub.38.30 CH.sub.3 CH.sub.3 H 2 COC.sub.2 H.sub.5 CH.sub.3 CH.sub.38.31 H H H 2 COCH.sub.3 Cl Cl8.32 H H H 2 COC.sub.2 H.sub.5 Cl Cl8.33 CH.sub.3 H H 2 COCH.sub.3 Cl Cl8.34 CH.sub.3 H H 2 COC.sub.2 H.sub.5 Cl Cl8.35 CH.sub.3 CH.sub.3 H 2 COCH.sub.3 Cl Cl8.36 CH.sub.3 CH.sub.3 H 2 COC.sub.2 H.sub.5 Cl Cl______________________________________
TABLE 9__________________________________________________________________________Compounds of the formula ##STR274##No. R.sup.15 R.sup.16 R.sup.19 n X Y M L__________________________________________________________________________9.1 CH.sub.3 CH.sub.3 H 2 CH.sub.2 C.dbd.O H CH.sub.39.2 CH.sub.3 CH.sub.3 H 0 (CH.sub.2).sub.2 C.dbd.O H CH.sub.39.3 CH.sub.3 CH.sub.3 H 2 (CH.sub.2).sub.2 C.dbd.O H CH.sub.39.4 CH.sub.3 CH.sub.3 H 2 CH.sub.2 CHOCH.sub.3 H CH.sub.39.5 CH.sub.3 CH.sub.3 H 0 (CH.sub.2).sub.2 CHOCH.sub.3 H CH.sub.39.6 CH.sub.3 CH.sub.3 H 2 (CH.sub.2).sub.2 CHOCH.sub.3 H CH.sub.39.7 CH.sub.3 CH.sub.3 H 2 CH.sub.2 CHOC.sub.2 H.sub.5 H CH.sub.39.8 CH.sub.3 CH.sub.3 H 0 (CH.sub.2).sub.2 CHOC.sub.2 H.sub.5 H CH.sub.39.9 CH.sub.3 CH.sub.3 H 2 (CH.sub.2).sub.2 CHOC.sub.2 H.sub.5 H CH.sub.39.10 CH.sub.3 CH.sub.3 H 2 CH.sub.2 CHOiPr H CH.sub.39.11 CH.sub.3 CH.sub.3 H 0 (CH.sub.2).sub.2 CHOiPr H CH.sub.39.12 CH.sub.3 CH.sub.3 H 2 (CH.sub.2).sub.2 CHOiPr H CH.sub.39.13 CH.sub.3 CH.sub.3 H 2 CH.sub.2 C.dbd.NOCH.sub.3 H CH.sub.39.14 CH.sub.3 CH.sub.3 H 2 (CH.sub.2).sub.2 C.dbd.NOCH.sub.3 H CH.sub.39.15 CH.sub.3 CH.sub.3 H 0 (CH.sub.2).sub.2 C.dbd.NOCH.sub.3 H CH.sub.39.16 CH.sub.3 CH.sub.3 H 2 CH.sub.2 C.dbd.NOC.sub.2 H.sub.5 H CH.sub.39.17 CH.sub.3 CH.sub.3 H 2 (CH.sub.2).sub.2 C.dbd.NOC.sub.2 H.sub.5 H CH.sub.39.18 CH.sub.3 CH.sub.3 H 0 (CH.sub.2).sub.2 C.dbd.NOC.sub.2 H.sub.5 H CH.sub.39.19 CH.sub.3 CH.sub.3 H 2 CH.sub.2 C.dbd.NOiPr H CH.sub.39.20 CH.sub.3 CH.sub.3 H 2 (CH.sub.2).sub.2 C.dbd.NOiPr H CH.sub.39.21 CH.sub.3 CH.sub.3 H 0 (CH.sub.2).sub.2 C.dbd.NOiPr H CH.sub.39.22 CH.sub.3 CH.sub.3 H 2 CH.sub.2 C.dbd.NOCH.sub.2 CH.dbd.CHCl H CH.sub.39.23 CH.sub.3 CH.sub.3 H 2 (CH.sub.2).sub.2 C.dbd.NOCH.sub.2 CH.dbd.CHCl H CH.sub.39.24 CH.sub.3 CH.sub.3 H 0 (CH.sub.2).sub.2 C.dbd.NOCH.sub.2 CH.dbd.CHCl H CH.sub.39.25 CH.sub.3 CH.sub.3 H 2 CH.sub.2 C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 H CH.sub.39.26 CH.sub.3 CH.sub.3 H 2 (CH.sub.2).sub.2 C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 H CH.sub.39.27 CH.sub.3 CH.sub.3 H 0 (CH.sub.2).sub.2 C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 H CH.sub.39.28 CH.sub.3 CH.sub.3 H 2 CH.sub.2 C(CH.sub.3).sub.2 H CH.sub.39.29 CH.sub.3 CH.sub.3 H 2 (CH.sub.2).sub.2 C(CH.sub.3).sub.2 H CH.sub.39.30 CH.sub.3 CH.sub.3 H 0 (CH.sub.2).sub.2 C(CH.sub.3).sub.2 H CH.sub.39.31 CH.sub.3 CH.sub.3 H 2 CH.sub.2 ##STR275## H CH.sub.39.32 CH.sub.3 CH.sub.3 H 2 (CH.sub.2).sub.2 ##STR276## H CH.sub.39.33 CH.sub.3 CH.sub.3 H 0 (CH.sub.2).sub.2 ##STR277## H CH.sub.39.34 CH.sub.3 CH.sub.3 H 2 CH.sub.2 ##STR278## H CH.sub.39.35 CH.sub.3 CH.sub.3 H 2 (CH.sub.2).sub.2 ##STR279## H CH.sub.39.36 CH.sub.3 CH.sub.3 H 0 (CH.sub.2).sub.2 ##STR280## H CH.sub.39.37 CH.sub.3 CH.sub.3 H 2 CH.sub.2 CH--NHCH.sub.3 H CH.sub.39.38 CH.sub.3 CH.sub.3 H 2 (CH.sub.2).sub.2 CH--NHCH.sub.3 H CH.sub.39.39 CH.sub.3 CH.sub.3 H 0 (CH.sub.2).sub.2 CH--NHCH.sub.3 H CH.sub.39.40 CH.sub.3 CH.sub.3 H 2 CH.sub.2 CH--NHC.sub.2 H.sub.5 H CH.sub.39.41 CH.sub.3 CH.sub.3 H 2 (CH.sub.2).sub.2 CH--NHC.sub.2 H.sub.5 H CH.sub.39.42 CH.sub.3 CH.sub.3 H 0 (CH.sub.2).sub.2 CH--NHC.sub.2 H.sub.5 H CH.sub.39.43 CH.sub.3 CH.sub.3 H 2 CH.sub.2 CH--N(CH.sub.3).sub.2 H CH.sub.39.44 CH.sub.3 CH.sub.3 H 2 (CH.sub.2).sub.2 CH--N(CH.sub.3).sub.2 H CH.sub.39.45 CH.sub.3 CH.sub.3 H 0 (CH.sub.2).sub.2 CH--N(CH.sub.3).sub.2 H CH.sub.39.46 CH.sub.3 CH.sub.3 H 2 CH.sub.2 CH--NHOC.sub.2 H.sub.5 H CH.sub.39.47 CH.sub.3 CH.sub.3 H 2 (CH.sub.2).sub.2 CH--NHOC.sub.2 H.sub.5 H CH.sub.39.48 CH.sub.3 CH.sub.3 H 0 (CH.sub.2).sub.2 CH--NHOC.sub.2 H.sub.5 H CH.sub.39.49 CH.sub.3 CH.sub.3 H 2 CH.sub.2 CH--N(CH.sub.3)OC.sub.2 H.sub.5 H CH.sub.39.50 CH.sub.3 CH.sub.3 H 2 (CH.sub.2).sub.2 CH--N(CH.sub.3)OC.sub.2 H.sub.5 H CH.sub.39.51 CH.sub.3 CH.sub.3 H 0 (CH.sub.2).sub.2 CH--N(CH.sub.3)OC.sub.2 H.sub.5 H CH.sub.39.52 CH.sub.3 CH.sub.3 H 2 CH.sub.2 C.dbd.N--NH.sub.2 H CH.sub.39.53 CH.sub.3 CH.sub.3 H 2 (CH.sub.2).sub.2 C.dbd.N--NH.sub.2 H CH.sub.39.54 CH.sub.3 CH.sub.3 H 0 (CH.sub.2).sub.2 C.dbd.N--NH.sub.2 H CH.sub.39.55 CH.sub.3 CH.sub.3 H 2 CH.sub.2 C.dbd.N--N(CH.sub.3).sub.2 H CH.sub.39.56 CH.sub.3 CH.sub.3 H 2 (CH.sub.2).sub.2 C.dbd.N--N(CH.sub.3).sub.2 H CH.sub.39.57 CH.sub.3 CH.sub.3 H 0 (CH.sub.2).sub.2 C.dbd.N--N(CH.sub.3).sub.2 H CH.sub.39.58 CH.sub.3 CH.sub.3 H 2 CH.sub.2 CH--N(CH.sub.3)OCH.sub.2 C.sub.6 H.sub.5 H CH.sub.39.59 CH.sub.3 CH.sub.3 H 2 (CH.sub.2).sub.2 CH--N(CH.sub.3)OCH.sub.2 C.sub.6 H.sub.5 H CH.sub.39.60 CH.sub.3 CH.sub.3 H 0 (CH.sub.2).sub.2 CH--N(CH.sub.3)OCH.sub.2 C.sub.6 H.sub.5 H CH.sub.39.61 CH.sub.3 CH.sub.3 H 2 CH.sub.2 C(CH.sub.3)--OCH.sub.3 H CH.sub.39.62 CH.sub.3 CH.sub.3 H 2 (CH.sub.2).sub.2 C(CH.sub.3)--OCH.sub.3 H CH.sub.39.63 CH.sub.3 CH.sub.3 H 0 (CH.sub.2).sub.2 C(CH.sub.3)--OCH.sub.3 H CH.sub.39.64 CH.sub.3 CH.sub.3 H 2 CH.sub.2 O H CH.sub.39.65 CH.sub.3 CH.sub.3 H 2 (CH.sub.2).sub.2 O H CH.sub.39.66 CH.sub.3 CH.sub.3 H 0 (CH.sub.2).sub.2 O H CH.sub.39.67 CH.sub.3 CH.sub.3 Br 2 CH.sub.2 CHOCH.sub.3 H CH.sub.39.68 CH.sub.3 CH.sub.3 Br 2 (CH.sub.2).sub.2 CHOCH.sub.3 H CH.sub.39.69 CH.sub.3 CH.sub.3 Br 0 (CH.sub.2).sub.2 CHOCH.sub.3 H CH.sub.39.70 CH.sub.3 CH.sub.3 Br 2 CH.sub.2 CHOC.sub.2 H.sub.5 H CH.sub.39.71 CH.sub.3 CH.sub.3 Br 2 (CH.sub.2).sub.2 CHOC.sub.2 H.sub.5 H CH.sub.39.72 CH.sub.3 CH.sub.3 Br 0 (CH.sub.2).sub.2 CHOC.sub.2 H.sub.5 H CH.sub.39.73 CH.sub.3 CH.sub.3 Br 2 CH.sub.2 CHOiPr H CH.sub.39.74 CH.sub.3 CH.sub.3 Brr 2 (CH.sub.2).sub.2 CHOiPr H CH.sub.3 [sic]9.75 CH.sub.3 CH.sub.3 Br 0 (CH.sub.2).sub.2 CHOiPr H CH.sub.39.76 CH.sub.3 CH.sub.3 Cl 2 CH.sub.2 CHOCH.sub.3 H CH.sub.39.77 CH.sub.3 CH.sub.3 Cl 2 (CH.sub.2).sub.2 CHOCH.sub.3 H CH.sub.39.78 CH.sub.3 CH.sub.3 Cl 0 (CH.sub.2).sub.2 CHOCH.sub.3 H CH.sub.39.79 CH.sub.3 CH.sub.3 Cl 2 CH.sub.2 CHOC.sub.2 H.sub.5 H CH.sub.39.80 CH.sub.3 CH.sub.3 Cl 2 (CH.sub.2).sub.2 CHOC.sub.2 H.sub.5 H CH.sub.39.81 CH.sub.3 CH.sub.3 Cl 0 (CH.sub.2).sub.2 CHOC.sub.2 H.sub.5 H CH.sub.39.82 CH.sub.3 CH.sub.3 Cl 2 CH.sub.2 CHOiPr H CH.sub.39.83 CH.sub.3 CH.sub.3 Cl 2 (CH.sub.2).sub.2 CHOiPr H CH.sub.39.84 CH.sub.3 CH.sub.3 Cl 0 (CH.sub.2).sub.2 CHOiPr H CH.sub.3__________________________________________________________________________
TABLE 10______________________________________Compounds of the formula ##STR281##No. R.sup.17 R.sup.18 R.sup.19 n R.sup.12 R.sup.13 Y L M______________________________________10.1 H H H 0 H H C.dbd.O H CH.sub.310.2 CH.sub.3 H H 0 H H C.dbd.O H CH.sub.310.3 CH.sub.3 CH.sub.3 H 0 H H C.dbd.O H CH.sub.310.4 H H H 2 H H C.dbd.O H CH.sub.310.5 CH.sub.3 H H 2 H H C.dbd.O H CH.sub.310.6 CH.sub.3 CH.sub.3 H 2 H H C.dbd.O H CH.sub.310.7 H H H 0 H H C.dbd.O H Cl10.8 CH.sub.3 H H 0 H H C.dbd.O H Cl10.9 CH.sub.3 CH.sub.3 H 0 H H C.dbd.O H Cl10.10 H H H 2 H H C.dbd.O H Cl10.11 CH.sub.3 H H 2 H H C.dbd.O H Cl10.12 CH.sub.3 CH.sub.3 H 2 H H C.dbd.O H Cl10.13 H H H 0 H H CHOCH.sub.3 H CH.sub.310.14 CH.sub.3 H H 0 H H CHOCH.sub.3 H CH.sub.310.15 CH.sub.3 CH.sub.3 H 0 H H CHOCH.sub.3 H CH.sub.310.16 H H H 2 H H CHOCH.sub.3 H CH.sub.310.17 CH.sub.3 H H 2 H H CHOCH.sub.3 H CH.sub.310.18 CH.sub.3 CH.sub.3 H 2 H H CHOCH.sub.3 H CH.sub.310.19 H H H 0 H H CHOCH.sub.3 H Cl10.20 CH.sub.3 H H 0 H H CHOCH.sub.3 H Cl10.21 CH.sub.3 CH.sub.3 H 0 H H CHOCH.sub.3 H Cl10.22 H H H 2 H H CHOCH.sub.3 H Cl10.23 CH.sub.3 H H 2 H H CHOCH.sub.3 H Cl10.24 CH.sub.3 CH.sub.3 H 2 H H CHOCH.sub.3 H Cl10.25 H H H 0 H CH.sub.3 C.dbd.O H CH.sub.310.26 CH.sub.3 H H 0 H CH.sub.3 C.dbd.O H CH.sub.310.27 CH.sub.3 CH.sub.3 H 0 H CH.sub.3 C.dbd.O H CH.sub.310.28 H H H 2 H CH.sub.3 C.dbd.O H CH.sub.310.29 CH.sub.3 H H 2 H CH.sub.3 C.dbd.O H CH.sub.310.30 CH.sub.3 CH.sub.3 H 2 H CH.sub.3 C.dbd.O H CH.sub.310.31 H H H 0 H CH.sub.3 C.dbd.O H Cl10.32 CH.sub.3 H H 0 H CH.sub.3 C.dbd.O H Cl10.33 CH.sub.3 CH.sub.3 H 0 H CH.sub.3 C.dbd.O H Cl10.34 H H H 2 H CH.sub.3 C.dbd.O H Cl10.35 CH.sub.3 H H 2 H CH.sub.3 C.dbd.O H Cl10.36 CH.sub.3 CH.sub.3 H 2 H CH.sub.3 C.dbd.O H Cl10.37 H H H 0 H CH.sub.3 CHOCH.sub.3 H CH.sub.310.38 CH.sub.3 H H 0 H CH.sub.3 CHOCH.sub.3 H CH.sub.310.39 CH.sub.3 CH.sub.3 H 0 H CH.sub.3 CHOCH.sub.3 H CH.sub.310.40 H H H 2 H CH.sub.3 CHOCH.sub.3 H CH.sub.310.41 CH.sub.3 H H 2 H CH.sub.3 CHOCH.sub.3 H CH.sub.310.42 CH.sub.3 CH.sub.3 H 2 H CH.sub.3 CHOCH.sub.3 H CH.sub.310.43 H H H 0 H CH.sub.3 CHOCH.sub.3 H Cl10.44 CH.sub.3 H H 0 H CH.sub.3 CHOCH.sub.3 H Cl10.45 CH.sub.3 CH.sub.3 H 0 H CH.sub.3 CHOCH.sub.3 H Cl10.46 H H H 2 H CH.sub.3 CHOCH.sub.3 H Cl10.47 CH.sub.3 H H 2 H CH.sub.3 CHOCH.sub.3 H Cl10.48 CH.sub.3 CH.sub.3 H 2 H CH.sub.3 CHOCH.sub.3 H Cl10.49 H H H 0 H C.sub.6 H.sub.5 C.dbd.O H CH.sub.310.50 CH.sub.3 H H 0 H C.sub.6 H.sub.5 C.dbd.O H CH.sub.310.51 CH.sub.3 CH.sub.3 H 0 H C.sub.6 H.sub.5 C.dbd.O H CH.sub.310.52 H H H 2 H C.sub.6 H.sub.5 C.dbd.O H CH.sub.310.53 CH.sub.3 H H 2 H C.sub.6 H.sub.5 C.dbd.O H CH.sub.310.54 CH.sub.3 CH.sub.3 H 2 H C.sub.6 H.sub.5 C.dbd.O H CH.sub.310.55 H H H 0 H C.sub.6 H.sub.5 C.dbd.O H Cl10.56 CH.sub.3 H H 0 H C.sub.6 H.sub.5 C.dbd.O H Cl10.57 CH.sub.3 CH.sub.3 H 0 H C.sub.6 H.sub.5 C.dbd.O H Cl10.58 H H H 2 H C.sub.6 H.sub.5 C.dbd.O H Cl10.59 CH.sub.3 H H 2 H C.sub.6 H.sub.5 C.dbd.O H Cl10.60 CH.sub.3 CH.sub.3 H 2 H C.sub.6 H.sub.5 C.dbd.O H Cl10.61 H H H 0 H C.sub.6 H.sub.5 CHOCH.sub.3 H CH.sub.310.62 CH.sub.3 H H 0 H C.sub.6 H.sub.5 CHOCH.sub.3 H CH.sub.310.63 CH.sub.3 CH.sub.3 H 0 H C.sub.6 H.sub.5 CHOCH.sub.3 H CH.sub.310.64 H H H 2 H C.sub.6 H.sub.5 CHOCH.sub.3 H CH.sub.310.65 CH.sub.3 H H 2 H C.sub.6 H.sub.5 CHOCH.sub.3 H CH.sub.310.66 CH.sub.3 CH.sub.3 H 2 H C.sub.6 H.sub.5 CHOCH.sub.3 H CH.sub.310.67 H H H 0 H C.sub.6 H.sub.5 CHOCH.sub.3 H Cl10.68 CH.sub.3 H H 0 H C.sub.6 H.sub.5 CHOCH.sub.3 H Cl10.69 CH.sub.3 CH.sub.3 H 0 H C.sub.6 H.sub.5 CHOCH.sub.3 H Cl10.70 H H H 2 H C.sub.6 H.sub.5 CHOCH.sub.3 H Cl10.71 CH.sub.3 H H 2 H C.sub.6 H.sub.5 CHOCH.sub.3 H Cl10.72 CH.sub.3 CH.sub.3 H 2 H C.sub.6 H.sub.5 CHOCH.sub.3 H Cl10.73 H H H 0 H H CH.sub.2 H CH.sub.310.74 CH.sub.3 H H 0 H H CH.sub.2 H CH.sub.310.75 CH.sub.3 CH.sub.3 H 0 H H CH.sub.2 H CH.sub.310.76 H H H 2 H H CH.sub.2 H CH.sub.310.77 CH.sub.3 H H 2 H H CH.sub.2 H CH.sub.310.78 CH.sub.3 CH.sub.3 H 2 H H CH.sub.2 H CH.sub.310.79 H H H 0 H H CH.sub.2 H Cl10.80 CH.sub.3 H H 0 H H CH.sub.2 H Cl10.81 CH.sub.3 CH.sub.3 H 0 H H CH.sub.2 H Cl10.82 H H H 2 H H CH.sub.2 H Cl10.83 CH.sub.3 H H 2 H H CH.sub.2 H Cl10.84 CH.sub.3 CH.sub.3 H 2 H H CH.sub.2 H Cl______________________________________
TABLE 11__________________________________________________________________________Compounds of the formula ##STR282##No. R.sup.17 n X Y L M__________________________________________________________________________11.1 2-Ethylthiopropyl 2 CH.sub.2 C.dbd.O H CH.sub.311.2 2-Ethylthiopropyl 0 (CH.sub.2).sub.2 C.dbd.O H CH.sub.311.3 2-Ethylthiopropyl 2 (CH.sub.2).sub.2 C.dbd.O H CH.sub.311.4 2-Ethylthiopropyl 2 CH.sub.2 CHOCH.sub.3 H CH.sub.311.5 2-Ethylthiopropyl 0 (CH.sub.2).sub.2 CHOCH.sub.3 H CH.sub.311.6 2-Ethylthiopropyl 2 (CH.sub.2).sub.2 CHOCH.sub.3 H CH.sub.311.7 2-Ethylthiopropyl 2 CH.sub.2 CHOC.sub.2 H.sub.5 H CH.sub.311.8 2-Ethylthiopropyl 0 (CH.sub.2).sub.2 CHOC.sub.2 H.sub.5 H CH.sub.311.9 2-Ethylthiopropyl 2 (CH.sub.2).sub.2 CHOC.sub.2 H.sub.5 H CH.sub.311.10 2-Ethylthiopropyl 2 CH.sub.2 CHOiPr H CH.sub.311.11 2-Ethylthiopropyl 0 (CH.sub.2).sub.2 CHOiPr H CH.sub.311.12 2-Ethylthiopropyl 2 (CH.sub.2).sub.2 CHOiPr H CH.sub.311.13 2-Ethylthiopropyl 2 CH.sub.2 C.dbd.NOCH.sub.3 H CH.sub.311.14 2-Ethylthiopropyl 2 (CH.sub.2).sub.2 C.dbd.NOCH.sub.3 H CH.sub.311.15 2-Ethylthiopropyl 0 (CH.sub.2).sub.2 C.dbd.NOCH.sub.3 H CH.sub.311.16 2-Ethylthiopropyl 2 CH.sub.2 C.dbd.NOC.sub.2 H.sub.5 H CH.sub.311.17 2-Ethylthiopropyl 2 (CH.sub.2).sub.2 C.dbd.NOC.sub.2 H.sub.5 H CH.sub.311.18 2-Ethylthiopropyl 0 (CH.sub.2).sub.2 C.dbd.NOC.sub.2 H.sub.5 H CH.sub.311.19 2-Ethylthiopropyl 2 CH.sub.2 C.dbd.NOiPr H CH.sub.311.20 2-Ethylthiopropyl 2 (CH.sub.2).sub.2 C.dbd.NOiPr H CH.sub.311.21 2-Ethylthiopropyl 0 (CH.sub.2).sub.2 C.dbd.NOiPr H CH.sub.311.22 2-Ethylthiopropyl 2 CH.sub.2 C.dbd.NOCH.sub.2 CH.dbd.CHCl H CH.sub.311.23 2-Ethylthiopropyl 2 (CH.sub.2).sub.2 C.dbd.NOCH.sub.2 CH.dbd.CHCl H CH.sub.311.24 2-Ethylthiopropyl 0 (CH.sub.2).sub.2 C.dbd.NOCH.sub.2 CH.dbd.CHCl H CH.sub.311.25 2-Ethylthiopropyl 2 CH.sub.2 C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 H CH.sub.311.26 2-Ethylthiopropyl 2 (CH.sub.2).sub.2 C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 H CH.sub.311.27 2-Ethylthiopropyl 0 (CH.sub.2).sub.2 C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 H CH.sub.311.28 2-Ethylthiopropyl 2 CH.sub.2 C(CH.sub.3).sub.2 H CH.sub.311.29 2-Ethylthiopropyl 2 (CH.sub.2).sub.2 C(CH.sub.3).sub.2 H CH.sub.311.30 2-Ethylthiopropyl 0 (CH.sub.2).sub.2 C(CH.sub.3).sub.2 H CH.sub.311.31 2-Ethylthiopropyl 2 CH.sub.2 CH--NHCH.sub.3 H CH.sub.311.32 2-Ethylthiopropyl 2 (CH.sub.2).sub.2 CH--NHCH.sub.3 H CH.sub.311.33 2-Ethylthiopropyl 0 (CH.sub.2).sub.2 CH--NHCH.sub.3 H CH.sub.311.34 2-Ethylthiopropyl 2 CH.sub.2 CH--NHC.sub.2 H.sub.5 H CH.sub.311.35 2-Ethylthiopropyl 2 (CH.sub.2).sub.2 CH--NHC.sub.2 H.sub.5 H CH.sub.311.36 2-Ethylthiopropyl 0 (CH.sub.2).sub.2 CH--NHC.sub.2 H.sub.5 H CH.sub.311.37 2-Ethylthiopropyl 2 CH.sub.2 CH--N(CH.sub.3).sub.2 H CH.sub.311.38 2-Ethylthiopropyl 2 (CH.sub.2).sub.2 CH--N(CH.sub.3).sub.2 H CH.sub.311.39 2-Ethylthiopropyl 0 (CH.sub.2).sub.2 CH--N(CH.sub.3).sub.2 H CH.sub.311.40 2-Ethylthiopropyl 2 CH.sub.2 CH--NHOC.sub.2 H.sub.5 H CH.sub.311.41 2-Ethylthiopropyl 2 (CH.sub.2).sub.2 CH--NHOC.sub.2 H.sub.5 H CH.sub.311.42 2-Ethylthiopropyl 0 (CH.sub.2).sub.2 CH--NHOC.sub.2 H.sub.5 H CH.sub.311.43 2-Ethylthiopropyl 2 CH.sub.2 CH--N(CH.sub.3)OC.sub.2 H.sub.5 H CH.sub.311.44 2-Ethylthiopropyl 2 (CH.sub.2).sub.2 CH--N(CH.sub.3)OC.sub.2 H.sub.5 H CH.sub.311.45 2-Ethylthiopropyl 0 (CH.sub.2).sub.2 CH--N(CH.sub.3)OC.sub.2 H.sub.5 H CH.sub.311.46 2-Ethylthiopropyl 2 CH.sub.2 C.dbd.N--NH.sub.2 H CH.sub.311.47 2-Ethylthiopropyl 2 (CH.sub.2).sub.2 C.dbd.N--NH.sub.2 H CH.sub.311.48 2-Ethylthiopropyl 0 (CH.sub.2).sub.2 C.dbd.N--NH.sub.2 H CH.sub.311.49 2-Ethylthiopropyl 2 CH.sub.2 C.dbd.N--N(CH.sub.3).sub.2 H CH.sub.311.50 2-Ethylthiopropyl 2 (CH.sub.2).sub.2 C.dbd.N--N(CH.sub.3).sub.2 H CH.sub.311.51 2-Ethylthiopropyl 0 (CH.sub.2).sub.2 C.dbd.N--N(CH.sub.3).sub.2 H CH.sub.311.52 2-Ethylthiopropyl 2 CH.sub.2 CH--N(CH.sub.3)OCH.sub.2 C.sub.6 H.sub.5 H CH.sub.311.53 2-Ethylthiopropyl 2 (CH.sub.2).sub.2 CH--N(CH.sub.3)OCH.sub.2 C.sub.6 H.sub.5 H CH.sub.311.54 2-Ethylthiopropyl 0 (CH.sub.2).sub.2 CH--N(CH.sub.3)OCH.sub.2 C.sub.6 H.sub.5 H CH.sub.311.55 2-Ethylthiopropyl 2 CH.sub.2 C(CH.sub.3)--OCH.sub.3 H CH.sub.311.56 2-Ethylthiopropyl 2 (CH.sub.2).sub.2 C(CH.sub.3)--OCH.sub.3 H CH.sub.311.57 2-Ethylthiopropyl 0 (CH.sub.2).sub.2 C(CH.sub.3)--OCH.sub.3 H CH.sub.311.58 2-Ethylthiopropyl 2 CH.sub.2 O H CH.sub.311.59 2-Ethylthiopropyl 0 (CH.sub.2).sub.2 O H CH.sub.311.60 2-Ethylthiopropyl 2 (CH.sub.2).sub.2 O H CH.sub.311.61 Tetrahydropyran-3-yl 2 CH.sub.2 C.dbd.O H CH.sub.311.62 Tetrahydropyran-3-yl 0 (CH.sub.2).sub.2 C.dbd.O H CH.sub.311.63 Tetrahydropyran-3-yl 2 (CH.sub.2).sub.2 C.dbd.O H CH.sub.311.64 Tetrahydropyran-3-yl 2 CH.sub.2 CHOCH.sub.3 H CH.sub.311.65 Tetrahydropyran-3-yl 0 (CH.sub.2).sub.2 CHOCH.sub.3 H CH.sub.311.66 Tetrahydropyran-3-yl 2 (CH.sub.2).sub.2 CHOCH.sub.3 H CH.sub.311.67 Tetrahydropyran-3-yl 2 CH.sub.2 CHOC.sub.2 H.sub.5 H CH.sub.311.68 Tetrahydropyran-3-yl 0 (CH.sub.2).sub.2 CHOC.sub.2 H.sub.5 H CH.sub.311.69 Tetrahydropyran-3-yl 2 (CH.sub.2).sub.2 CHOC.sub.2 H.sub.5 H CH.sub.311.70 Tetrahydropyran-3-yl 2 CH.sub.2 CHOiPr H CH.sub.311.71 Tetrahydropyran-3-yl 0 (CH.sub.2).sub.2 CHOiPr H CH.sub.311.72 Tetrahydropyran-3-yl 2 (CH.sub.2).sub.2 CHOiPr H CH.sub.311.73 Tetrahydropyran-3-yl 2 CH.sub.2 C.dbd.NOCH.sub.3 H CH.sub.311.74 Tetrahydropyran-3-yl 2 (CH.sub.2).sub.2 C.dbd.NOCH.sub.3 H CH.sub.311.75 Tetrahydropyran-3-yl 0 (CH.sub.2).sub.2 C.dbd.NOCH.sub.3 H CH.sub.311.76 Tetrahydropyran-3-yl 2 CH.sub.2 C.dbd.NOC.sub.2 H.sub.5 H CH.sub.311.77 Tetrahydropyran-3-yl 2 (CH.sub.2).sub.2 C.dbd.NOC.sub.2 H.sub.5 H CH.sub.311.78 Tetrahydropyran-3-yl 0 (CH.sub.2).sub.2 C.dbd.NOC.sub.2 H.sub.5 H CH.sub.311.79 Tetrahydropyran-3-yl 2 CH.sub.2 C.dbd.NOiPr H CH.sub.311.80 Tetrahydropyran-3-yl 2 (CH.sub.2).sub.2 C.dbd.NOiPr H CH.sub.311.81 Tetrahydropyran-3-yl 0 (CH.sub.2).sub.2 C.dbd.NOiPr H CH.sub.311.82 Tetrahydropyran-4-yl 2 CH.sub.2 C.dbd.O H CH.sub.311.83 Tetrahydropyran-4-yl 0 (CH.sub.2).sub.2 C.dbd.O H CH.sub.311.84 Tetrahydropyran-4-yl 2 (CH.sub.2).sub.2 C.dbd.O H CH.sub.311.85 Tetrahydropyran-4-yl 2 CH.sub.2 CHOCH.sub.3 H CH.sub.311.86 Tetrahydropyran-4-yl 0 (CH.sub.2).sub.2 CHOCH.sub.3 H CH.sub.311.87 Tetrahydropyran-4-yl 2 (CH.sub.2).sub.2 CHOCH.sub.3 H CH.sub.311.88 Tetrahydropyran-4-yl 2 CH.sub.2 CHOC.sub.2 H.sub.5 H CH.sub.311.89 Tetrahydropyran-4-yl 0 (CH.sub.2).sub.2 CHOC.sub.2 H.sub.5 H CH.sub.311.90 Tetrahydropyran-4-yl 2 (CH.sub.2).sub.2 CHOC.sub.2 H.sub.5 H CH.sub.311.91 Tetrahydropyran-4-yl 2 CH.sub.2 CHOiPr H CH.sub.311.92 Tetrahydropyran-4-yl 0 (CH.sub.2).sub.2 CHOiPr H CH.sub.311.93 Tetrahydropyran-4-yl 2 (CH.sub.2).sub.2 CHOiPr H CH.sub.311.94 Tetrahydropyran-4-yl 2 CH.sub.2 C.dbd.NOCH.sub.3 H CH.sub.311.95 Tetrahydropyran-4-yl 2 (CH.sub.2).sub.2 C.dbd.NOCH.sub.3 H CH.sub.311.96 Tetrahydropyran-4-yl 0 (CH.sub.2).sub.2 C.dbd.NOCH.sub.3 H CH.sub.311.97 Tetrahydropyran-4-yl 2 CH.sub.2 C.dbd.NOC.sub.2 H.sub.5 H CH.sub.311.98 Tetrahydropyran-4-yl 2 (CH.sub.2).sub.2 C.dbd.NOC.sub.2 H.sub.5 H CH.sub.311.99 Tetrahydropyran-4-yl 0 (CH.sub.2).sub.2 C.dbd.NOC.sub.2 H.sub.5 H CH.sub.311.100 Tetrahydropyran-4-yl 2 CH.sub.2 C.dbd.NOiPr H CH.sub.311.101 Tetrahydropyran-4-yl 2 (CH.sub.2).sub.2 C.dbd.NOiPr H CH.sub.311.102 Tetrahydropyran-4-yl 0 (CH.sub.2).sub.2 C.dbd.NOiPr H CH.sub.311.103 Tetrahydrothiopyran-3-yl 2 CH.sub.2 C.dbd.O H CH.sub.311.104 Tetrahydrothiopyran-3-yl 0 (CH.sub.2).sub.2 C.dbd.O H CH.sub.311.105 Tetrahydrothiopyran-3-yl 2 (CH.sub.2).sub.2 C.dbd.O H CH.sub.311.106 Tetrahydrothiopyran-3-yl 2 CH.sub.2 CHOCH.sub.3 H CH.sub.311.107 Tetrahydrothiopyran-3-yl 0 (CH.sub.2).sub.2 CHOCH.sub.3 H CH.sub.311.108 Tetrahydrothiopyran-3-yl 2 (CH.sub.2).sub.2 CHOCH.sub.3 H CH.sub.311.109 Tetrahydrothiopyran-3-yl 2 CH.sub.2 CHOC.sub.2 H.sub.5 H CH.sub.311.110 Tetrahydrothiopyran-3-yl 0 (CH.sub.2).sub.2 CHOC.sub.2 H.sub.5 H CH.sub.311.111 Tetrahydrothiopyran-3-yl 2 (CH.sub.2).sub.2 CHOC.sub.2 H.sub.5 H CH.sub.311.112 Tetrahydrothiopyran-3-yl 2 CH.sub.2 CHOiPr H CH.sub.311.113 Tetrahydrothiopyran-3-yl 0 (CH.sub.2).sub.2 CHOiPr H CH.sub.311.114 Tetrahydrothiopyran-3-yl 2 (CH.sub.2).sub.2 CHOiPr H CH.sub.311.115 Tetrahydrothiopyran-3-yl 2 CH.sub.2 C.dbd.NOCH.sub.3 H CH.sub.311.116 Tetrahydrothiopyran-3-yl 2 (CH.sub.2).sub.2 C.dbd.NOCH.sub.3 H CH.sub.311.117 Tetrahydrothiopyran-3-yl 0 (CH.sub.2).sub.2 C.dbd.NOCH.sub.3 H CH.sub.311.118 Tetrahydrothiopyran-3-yl 2 CH.sub.2 C.dbd.NOC.sub.2 H.sub.5 H CH.sub.311.119 Tetrahydrothiopyran-3-yl 2 (CH.sub.2).sub.2 C.dbd.NOC.sub.2 H.sub.5 H CH.sub.311.120 Tetrahydrothiopyran-3-yl 0 (CH.sub.2).sub.2 C.dbd.NOC.sub.2 H.sub.5 H CH.sub.311.121 Tetrahydrothiopyran-3-yl 2 CH.sub.2 C.dbd.NOiPr H CH.sub.311.122 Tetrahydrothiopyran-3-yl 2 (CH.sub.2).sub.2 C.dbd.NOiPr H CH.sub.311.123 Tetrahydrothiopyran-3-yl 0 (CH.sub.2).sub.2 C.dbd.NOiPr H CH.sub.311.124 1-Methylthiocyclopropyl 2 CH.sub.2 C.dbd.O H CH.sub.311.125 1-Methylthiocyclopropyl 0 (CH.sub.2).sub.2 C.dbd.O H CH.sub.311.126 1-Methylthiocyclopropyl 2 (CH.sub.2).sub.2 C.dbd.O H CH.sub.311.127 1-Methylthiocyclopropyl 2 CH.sub.2 CHOCH.sub.3 H CH.sub.311.128 1-Methylthiocyclopropyl 0 (CH.sub.2).sub.2 CHOCH.sub.3 H CH.sub.311.129 1-Methylthiocyclopropyl 2 (CH.sub.2).sub.2 CHOCH.sub.3 H CH.sub.311.130 1-Methylthiocyclopropyl 2 CH.sub.2 CHOC.sub.2 H.sub.5 H CH.sub.311.131 1-Methylthiocyclopropyl 0 (CH.sub.2).sub.2 CHOC.sub.2 H.sub.5 H CH.sub.311.132 1-Methylthiocyclopropyl 2 (CH.sub.2).sub.2 CHOC.sub.2 H.sub.5 H CH.sub.311.133 1-Methylthiocyclopropyl 2 CH.sub.2 CHOiPr H CH.sub.311.134 1-Methylthiocyclopropyl 0 (CH.sub.2).sub.2 CHOiPr H CH.sub.311.135 1-Methylthiocyclopropyl 2 (CH.sub.2).sub.2 CHOiPr H CH.sub.311.136 1-Methylthiocyclopropyl 2 CH.sub.2 C.dbd.NOCH.sub.3 H CH.sub.311.137 1-Methylthiocyclopropyl 2 (CH.sub.2).sub.2 C.dbd.NOCH.sub.3 H CH.sub.311.138 1-Methylthiocyclopropyl 0 (CH.sub.2).sub.2 C.dbd.NOCH.sub.3 H CH.sub.311.139 1-Methylthiocyclopropyl 2 CH.sub.2 C.dbd.NOC.sub.2 H.sub.5 H CH.sub.311.140 1-Methylthiocyclopropyl 2 (CH.sub.2).sub.2 C.dbd.NOC.sub.2 H.sub.5 H CH.sub.311.141 1-Methylthiocyclopropyl 0 (CH.sub.2).sub.2 C.dbd.NOC.sub.2 H.sub.5 H CH.sub.311.142 1-Methylthiocyclopropyl 2 CH.sub.2 C.dbd.NOiPr H CH.sub.311.143 1-Methylthiocyclopropyl 2 (CH.sub.2).sub.2 C.dbd.NOiPr H CH.sub.311.144 1-Methylthiocyclopropyl 0 (CH.sub.2).sub.2 C.dbd.NOiPr H CH.sub.311.145 (Dimethoxy)methyl 2 CH.sub.2 C.dbd.O H CH.sub.311.146 (Dimethoxy)methyl 0 (CH.sub.2).sub.2 C.dbd.O H CH.sub.311.147 (Dimethoxy)methyl 2 (CH.sub.2).sub.2 C.dbd.O H CH.sub.311.148 (Dimethoxy)methyl 2 CH.sub.2 CHOCH.sub.3 H CH.sub.311.149 (Dimethoxy)methyl 0 (CH.sub.2).sub.2 CHOCH.sub.3 H CH.sub.311.150 (Dimethoxy)methyl 2 (CH.sub.2).sub.2 CHOCH.sub.3 H CH.sub.311.151 (Dimethoxy)methyl 2 CH.sub.2 CHOC.sub.2 H.sub.5 H CH.sub.311.152 (Dimethoxy)methyl 0 (CH.sub.2).sub.2 CHOC.sub.2 H.sub.5 H CH.sub.311.153 (Dimethoxy)methyl 2 (CH.sub.2).sub.2 CHOC.sub.2 H.sub.5 H CH.sub.311.154 (Dimethoxy)methyl 2 CH.sub.2 CHOiPr H CH.sub.311.155 (Dimethoxy)methyl 0 (CH.sub.2).sub.2 CHOiPr H CH.sub.311.156 (Dimethoxy)methyl 2 (CH.sub.2).sub.2 CHOiPr H CH.sub.311.157 (Dimethoxy)methyl 2 CH.sub.2 C.dbd.NOCH.sub.3 H CH.sub.311.158 (Dimethoxy)methyl 2 (CH.sub.2).sub.2 C.dbd.NOCH.sub.3 H CH.sub.311.159 (Dimethoxy)methyl 0 (CH.sub.2).sub.2 C.dbd.NOCH.sub.3 H CH.sub.311.160 (Dimethoxy)methyl 2 CH.sub.2 C.dbd.NOC.sub.2 H.sub.5 H CH.sub.311.161 (Dimethoxy)methyl 2 (CH.sub.2).sub.2 C.dbd.NOC.sub.2 H.sub.5 H CH.sub.311.162 (Dimethoxy)methyl 0 (CH.sub.2).sub.2 C.dbd.NOC.sub.2 H.sub.5 H CH.sub.311.163 (Dimethoxy)methyl 2 CH.sub.2 C.dbd.NOiPr H CH.sub.311.164 (Dimethoxy)methyl 2 (CH.sub.2).sub.2 C.dbd.NOiPr H CH.sub.311.165 (Dimethoxy)methyl 0 (CH.sub.2).sub.2 C.dbd.NOiPr H CH.sub.3__________________________________________________________________________

PREPARATION EXAMPLES
A) Preparation of the Starting Materials and Intermediates
1. 3-Thio-2-methylbenzoic Acid
100 g (0.66 mol) of 3-amino-2-methylbenzoic acid are initially introduced together with 270 g of ice and 127 ml of concentrated hydrochloric acid. 45.7 g (0.66 mol) of sodium nitrite in 270 ml of water are then added dropwise at 0-10.degree. C.
In a second vessel, 84.2 g (0.79 mol) of sodium carbonate and 106 g (0.66 mol) of potassium methylxanthate are dissolved in 450 ml of water and heated to 60-70.degree. C. The diazonium solution is cautiously added dropwise. The mixture is subsequently stirred for 1 hour. 106 g (2.65 mol) of sodium hydroxide in 270 ml of water are then added, the mixture is stirred for a further 2 hours, the solution is rendered acidic using hydrochloric acid and the resulting precipitate is filtered off with suction. The solid is washed with water and dried.
Yield: 110 g (100% of theory) of 3-thio-2-methylbenzoic acid; melting point 155.degree. C. .sup.1 H-NMR (d.sup.6 -DMSO): .delta. [ppm]=13.0 (1H, bs), 7.7 (2H, m), 7.3 (1H, tr), 2.4 (3H, s).
2. Methyl 3-thio-2-methylbenzoate [sic]
110 g (0.66 mol) of 3-thio-2-methylbenzoic acid are dissolved in 1.6 l of methanol which contains 5% sulfuric acid and the mixture is refluxed for 5 hours. The alcohol is then distilled off, the residue is taken up in ethyl acetate, and the organic phase is washed with water and with sodium carbonate, dried using sodium sulfate and concentrated.
Yield: 104 g (87% of theory) of methyl 3-thio-2-methylbenzoate; .sup.1 H-NMR (CDCl.sub.3):.delta. [ppm]=7.6 (1H, d), 7.4 (1H, d), 7.1 (1H, d), 3.9 (3H, s), 3.4 (1H, s), 2.5 (3H, s).
3. Methyl 3-thio(2'-propionic acid)-2-methylbenzoate ##STR283##
70 g (0.38 mol) of methyl 3-thio-2-methylbenzoate are dissolved in 400 ml of water and refluxed for 7 hours with 30.8 g (0.77 mol) of sodium hydroxide solution and 58.8 g (0.45 mol) of bromopropionic acid. After cooling, the aqueous phase is washed with methyl tert-butyl ether. The aqueous phase is then acidified with 2 N hydrochloric acid, the resulting precipitate is filtered off with suction and washed with water, and the product is dried.
Yield: 75.5 g (78% of theory) of methyl 3-thiopropionic acid-2-methylbenzoate; .sup.1 H-NMR (CDCl.sub.3): .delta. [ppm]=7.66 (1H, d), 7.51 (1H, d), 7.20 (1H, tr), 3.96 (3H, s), 3.18 (2H, tr), 2.70 (2H, tr), 2.63 (3H, s).
4. Methyl 8-methylthiochroman-4-one-7-carboxylate ##STR284##
4 g (15.8 mmol) of methyl 3-thiopropionic acid-2-methylbenzoate are stirred at 70.degree. C. for 15 minutes in 40 g of polyphosphoric acid. The reaction solution is then added to ice-water and the resulting precipitate is filtered off with suction. The product is washed with water and dried in a drying cabinet. As a by-product of the cyclization, methyl 8-methylthiochromen-4-one-carboxylate can be formed, which can be separated off by chromatography.
Yield: 3.1 g (83% of theory) of methyl 8-methylthiochroman-4-one-7-carboxylate; .sup.1 H-NMR (CDCl.sub.3): .delta. [ppm]=8.00 (1H, d), 7.30 (1H, d), 3.94 (3H, s), 3.15 (2H, m), 2.98 (2H, m), 2.50 (3H, s);
Secondary component: methyl 8-methylthiochromen-4-one-carboxylate: .sup.1 H-NMR (CDCl.sub.3): .delta. [ppm]=8.4 (1H, d), 7.9 (1H, d), 7.8 (1H, d), 7.0 (1H, d), 4.0 (3H, s), 2.7 (3H, s).
5. 8-Methylthiochroman-4-one-7-carboxylic acid
41.1 g (0.17 mol) of methyl 8-methylthiochroman-4-one-7-carboxylate are hydrolyzed under reflux with 10.3 g (0.26 mol) of NaOH in a mixture of 400 ml of water and methanol. The methanol is then distilled off and the residue is diluted with water and acidifed with 2N hydrochloric acid. The useful product precipitates out and is filtered off with suction, washed with water and dried.
Yield: 34.4 g (89% of theory) of 8-methylthiochroman-4-one-7-carboxylic acid; melting point: 243-246.degree. C.
6. 8-Methyl-1,1-dioxothiochroman-4-one-7-carboxylic acid ##STR285##
20 g (0.09 mol) of 8-methylthiochroman-4-one-7-carboxylic acid are dissolved in 100 ml of acetic acid. A spatula tipful of sodium tungstate is added. 24.9 g (0.22 mol) of 30% strength hydrogen peroxide solution are then added dropwise at 50.degree. C. The mixture is subsequently stirred at about 20.degree. C. for 1 hour. The reaction solution is then added to water, a precipitate being formed which is filtered off with suction. After washing the product with water, it is dried.
Yield: 18.4 g (80% of theory) of 8-methyl-1,1-dioxothiochroman-4-one-7-carboxylic acid; melting point: 224-225.degree. C.
7. Methyl 4-hydroxy-8-methylthiochroman-7-carboxylate ##STR286##
30 g (0.127 mol) of methyl 8-methylthiochroman-4-one-7-carboxylate are dissolved in a mixture of 120 ml of methylene chloride and 60 ml of methanol and cooled to 0-5.degree. C. 2.4 g (0.064 mol) of sodium borohydride are then added in portions. The mixture is subsequently stirred at this temperature for 1 hour, and 200 ml of 2N hydrochloric acid are added to the reaction solution. Two phases are formed. The organic phase is separated off and dried, and the solvent is removed by distillation. The crude product is directly reacted further without further purification.
Yield: 27.6 g (91% of theory) of methyl 4-hydroxy-8-methylthiochroman-7-carboxylate.
8. Methyl 4-ethoxy-8-methylthiochroman-7-carboxylate
13.8 g (0.058 mol) of methyl 4-hydroxy-8-methylthiochroman-7-carboxylate are heated at boiling point for 4 hours in 60 ml of ethanol with addition of 1 g of sulfuric acid. The solvent is then distilled off and the residue is taken up with water. The aqueous phase is extracted with ethyl acetate. The organic phase is washed with sodium hydrogen carbonate solution, dried and concentrated. The product is purified by chromatography.
Yield: 10.1 g (60% of theory) of methyl 4-ethoxy-8-methylthiochroman-7-carboxylate; .sup.1 H-NMR (CDCl.sub.3): .delta. [ppm]=7.44 (1H, d), 7.13 (1H, d), 4.40 (1H, m), 3.90 (3H, s), 3.60 (2H, m), 3.38 (1 H, dtr), 2.90 (1H, m), 2.50 (3H, g), 2.40 (1H, m), 1.98 (1H, m), 1.10 (3H, tr).
The reaction to give methyl 4-methoxy-8-methylthiochroman-4-one-7-carboxylate and methyl 4-isopropoxy-8-methylthiochroman-4-one-7-carboxylate is carried out analogously to the above procedure, in the case of methyl 4-methoxy-8-methylthiochroman-4-one-7-carboxylate ethanol being replaced by methanol and in the case of methyl 4-isopropoxy-8-methylthiochroman-4-one-7-carboxylate ethanol being replaced by isopropanol.
9. 4-Ethoxy-8-methylthiochroman-7-carboxylic acid
2.1 g of sodium hydroxide solution are dissolved in 20 ml of water. Methyl 4-ethoxy-8-methylthiochroman-4-one-7-carboxylate dissolved in 20 ml of methanol is added dropwise at about 20.degree. C. The mixture is refluxed for 2 hours. The solvent is then distilled off and the residue is added to 2N hydrochloric acid. The aqueous phase is extracted with methylene chloride and the organic phase is dried and concentrated.
Yield: 9.3 g (100% of theory) of 4-ethoxy-8-methylthiochroman-7-carboxylic acid; melting point: 89-98.degree. C.
Hydrolysis of the corresponding esters to 4-ethoxy-8-methylthiochroman-7-carboxylic acid and 4-isopropoxy-8-methylthiochroman-7-carboxylic acid proceeds in a similar manner. The same applies to the hydrolysis of the corresponding benzo[b]thiophene derivatives shown below.
10. 8-Methyl-4-ethoxy-1,1-dioxothiochroman-7-carboxylic acid
8.4 g (0.033 mol) of 4-ethoxy-8-methylthiochroman-7-carboxylic acid are initially introduced in 60 ml of acetic acid. A spatula tipful of sodium tungstate is added. 7.9 g (0.07 mol) is of 30% strength hydrogen peroxide solution are slowly added dropwise at 50.degree. C. and the reaction mixture is subsequently stirred for 2 hours. It is then poured into water and the aqueous phase is extracted with ethyl acetate. The organic phase is washed with bisulfite solution, then dried and concentrated.
Yield: 9.5 g (100% of theory) of 8-methyl-4-ethoxy-1,1-dioxothiochroman-7-carboxylic acid; melting point: 150.degree. C.
11. 8-Methylthiochroman-4-one-7-carboxylic acid O-ethyl oxime ##STR287##
0.88 g (9 mmol) of ethylhydroxylamine is initially introduced in 20 ml of methanol. 0.62 g (4.5 mmol) of potassium carbonate is then added, followed by 2.0 g (9 mmol) of 8-methylthiochroman-4-one-7-carboxylic acid. The reaction is stirred at about 20.degree. C. for 10 days. It is worked up by addition of water and 2N hydrochloric acid, and the resulting precipitate is filtered of f with suction and dried.
Yield: 2.2 g (92% of theory) of 8-methylthiochroman-4-one-7-carboxylic acid O-ethyl oxime; melting point: 166.degree. C.
12. 8-Methyl-1,1-dioxothiochroman-4-one-7-carboxylic acid O-ethyl oxime
3.0 g (0.011 mol) of 8-methylthiochroman-4-one-7-carboxylic acid O-ethyl oxime are initially introduced into 30 ml of acetic acid together with a spatula tipful of sodium tungstate. 2.8 g (0.024 mol) of 30% strength hydrogen peroxide solution are added dropwise at 50.degree. C. After stirring for 1 hour, the reaction mixture is poured into ice-water and the resulting precipitate is filtered off with suction. The product is washed with water and dried.
Yield: 2.5 g (74% of theory) of 8-methyl-1,1-dioxothiochroman-4-one-7-carboxylic acid O-ethyl oxime; melting point 198.degree. C.
13. 8-Methyl-1-oxothiochroman-4-one-7-carboxylic Acid
7.0 g (31.5 mmol) of 8-methylthiochroman-4-one-7-carboxylic acid are initially introduced into 70 ml of acetic acid together with a spatula tipful of sodium tungstate. 3.6 g (31.5 mmol) of 30% strength hydrogen peroxide solution are added dropwise at 50.degree. C. and the reaction solution is subsequently stirred for 3 hours. It is then stirred into water and the product is extracted with ethyl acetate. The organic phase is dried and the solvent is removed. The product is purified by chromatography.
Yield: 5.4 g (72% of theory) of 8-methyl-1-oxothiochroman-4-one-7-carboxylic acid; .sup.1 H-NMR (d.sup.6 -DMSO): .delta. [ppm]=8.0 (2H, m), 3.5 (3H, m), 2.8 (1H, m), 2.7 (3H, s).
14. Methyl 3-carboxymethylthio-2-methylbenzoate ##STR288##
12.4 g (0.068 mmol) of methyl 3-mercapto-2-methylbenzoate in 80 ml of dimethylformamide are added dropwise to 1.6 g (0.068 mol) of sodium hydride in 40 ml of dimethylformamide and the mixture is stirred at about 20.degree. C. for 60 min. 8 g (0.068 mol) of chloroacetic acid are then added and the mixture is stirred at about 20.degree. C. for 4 hours.
The reaction mixture is worked up by stirring it into ice-water containing hydrochloric acid.
The resulting precipitate is filtered off with suction, washed with water and dried.
Yield: 14.6 g (89% of theory) of methyl 3-carboxymethylthio-2-methylbenzoate; .sup.1 H-NMR (d.sup.6 -DMSO): .delta. [ppm]=7.55 (1H, d), 7.45 (1H, d), 7.21 (1H, tr), 3.82 (2H, s), 2.50 (3H, s).
15. Methyl 7-methylbenzo[b]thiophene-3[2H]-one-6-carboxylate ##STR289##
14.3 g (0.06 mmol) of 3-carboxymethylthio-2-methylbenzoic acid are dissolved in 300 ml of methylene chloride and 13.1 g (0.11 mmol) of thionyl chloride are added dropwise. The mixture is refluxed for 1 hour and the solvent and excess thionyl chloride are then distilled off. The residue is taken up in 100 ml of methylene chloride and treated with 31.8 g (0.24 mmol) of aluminum trichloride. The reaction is stirred at about 20.degree. C. for 1 hour. The mixture is then added to ice-water and the organic phase is separated off. After washing and drying the organic phase, the solvent is removed. The product is reacted further without purification.
Yield: 12.9 g (97% of theory) of methyl 7-methylbenzo[b]thiophene-3[2H]-one-6-carboxylate; .sup.1 H-NMR (CDCl.sub.3): .delta. [ppm]=7.65 (2H, m), 3.93 (3H, s), 3.88 (2H, s), 2.50 (3H, s).
16. Methyl 7-methyl-3-hydroxybenzo[b]thiophene-[2H]-6-carboxylate ##STR290##
12.8 g (0.058 mol) of methyl 7-methylbenzo[b]thiophene-3[2H]-one-6-carboxylate are dissolved in 120 ml of methylene chloride and 60 ml of methanol and cooled to 0.degree. C. 1.1 g (0.029 mol) of sodium borohydride is added in portions and the mixture is stirred for 3 hours. The reaction is terminated by adding water. The phases are separated and the aqueous phase is extracted with methylene chloride. The combined organic phases are dried and the solvent is distilled off. The crude product is reacted further.
Yield: 13.2 g (100% of theory) of methyl 7-methyl-3-hydroxybenzo[b]-thiophene-[2H]-6-carboxylate; .sup.1 H-NMR (CDCl.sub.3): .delta. [ppm]=7.6 (2H, m), 5.3 (1H, m), 3.9 (3H, s), 3.7 (1H, m), 3.3 (1H, m), 2.4 (3H, s).
17. Methyl 7-methyl-3-methoxybenzo[b]thiophene-[2H]-6-carboxylate
2.4 g (0.059 mol) of NaH is dissolved in 50 ml of dimethylformamide. 13.2 g of methyl 7-methyl-3-hydroxybenzo[b]thiophene-[2H]-6-carboxylate dissolved in 50 ml are added dropwise and the mixture is subsequently stirred at about 20.degree. C. for 2 hours. 8.4 g (0.059 mol) of iodomethane are then added and the mixture is stirred for a further 2 hours. The reaction solution is added to ice-water and extracted with ethyl acetate. The organic phase is dried and subsequently concentrated, and the product is purified by chromatography.
Yield: 3.5 g (25% of theory) of methyl 7-methyl-3-methoxybenzo[b]thiophene-[2H]-6-carboxylate; .sup.1 H-NMR (CDCl.sub.3): .delta. [ppm]=7.60 (1H, d), 7.20 (1H, d), 5.04 (1H, m), 3.90 (3H, s),3.56 (1H, m), 3.40 (3H, s), 3.38 (1H, m), 2.50 (3H, s).
Similarly to the hydrolysis of the thiochromanone esters described above, the corresponding benzothiophene acids are also obtained.
The compounds shown in the following tables are obtained in a similar manner:
TABLE 12__________________________________________________________________________Intermediates ##STR291##No. T n X Y L M Physical data__________________________________________________________________________12.1 HO 0 (CH.sub.2).sub.2 C.dbd.O H H m.p. [.degree. C.]: 226-23112.2 HO 2 (CH.sub.2).sub.2 C.dbd.O H H m.p. [.degree. C.]: 217-22012.3 HO 0 (CH.sub.2).sub.2 C.dbd.O H CH.sub.3 m.p. [.degree. C.]: 243-24612.4 HO 2 (CH.sub.2).sub.2 C.dbd.O H CH.sub.3 m.p. [.degree. C.]: 224-22512.5 HO 0 (CH.sub.2).sub.2 CHOCH.sub.3 H CH.sub.3 m.p. [.degree. C.]: 117-11812.6 HO 2 (CH.sub.2).sub.2 CHOCH.sub.3 H CH.sub.3 m.p. [.degree. C.]: 167-17212.7 HO 0 (CH.sub.2).sub.2 CHOC.sub.2 H.sub.5 H CH.sub.3 m.p. [.degree. C.]: 89-9812.8 HO 2 (CH.sub.2).sub.2 CHOC.sub.2 H.sub.5 H CH.sub.3 m.p. [.degree. C.]: 15012.9 HO 0 (CH.sub.2).sub.2 CHOiPropyl H CH.sub.3 m.p. [.degree. C.]: 13812.10 HO 2 (CH.sub.2).sub.2 CHOiPropyl H CH.sub.3 m.p. [.degree. C.]: 14212.11 HO 0 (CH.sub.2).sub.2 C.dbd.NOC.sub.2 H.sub.5 H CH.sub.3 m.p. [.degree. C.]: 16612.12 HO 2 (CH.sub.2).sub.2 C.dbd.NOC.sub.2 H.sub.5 H CH.sub.3 m.p. [.degree. C.]: 19812.13 HO 0 (CH.sub.2).sub.2 C.dbd.NOCH.sub.2 CH.dbd.CHCl H CH.sub.3 m.p. [.degree. C.]: 16312.14 HO 2 (CH.sub.2).sub.2 C.dbd.NOCH.sub.2 CH.dbd.CHCl H CH.sub.3 m.p. [.degree. C.]: 17412.15 HO 0 (CH.sub.2).sub.2 C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 H CH.sub.3 m.p. [.degree. C.]: 17812.16 HO 2 (CH.sub.2).sub.2 C.dbd.NO-tButyl H CH.sub.3 m.p. [.degree. C.]: 21712.17 H.sub.3 CO 0 (CH.sub.2).sub.2 C(CH.sub.3).sub.2 H CH.sub.3 m.p. [.degree. C.]: 63-6512.18 HO 2 (CH.sub.2).sub.2 CHOCH.sub.3 H Cl m.p. [.degree. C.]: 137-13912.19 HO 2 (CH.sub.2).sub.2 C.dbd.NOC.sub.2 H.sub.5 H Cl m.p. [.degree. C.]: 20512.20 HO 0 (CH.sub.2) CHOCH.sub.3 H CH.sub.3 .sup.1 H-NMR, 300 MHz (d.sup.6 -DMSO): .delta. [ppm] = 13.0 (1H, s), 7.55 (1H, d), 7.25 (1H, d), 5.10 (1H, s), 3.62 (1H, m), 3.42 (1H, m), 3.41 (3H, s), 2.42 (3H, s)12.21 HO 2 (CH.sub.2) CHOCH.sub.3 H CH.sub.3 .sup.1 H-NMR, 300 MHz (d.sup.6 -DMSO): .delta. [ppm] = 13.5 (1H, bs), 8.10 (1H, d), 7.60 (1H, d), 5.18 (1H, m), 4.07 (1H, m), 3.75 (1H, m), 3.40 (3H, s), 2.70 (3H, s)12.22 HO 2 (CH.sub.2).sub.2 C.dbd.O H Cl .sup.1 H-NMR, 300 MHz (d.sup.6 -DMSO): .delta. [ppm] = 14.2 (1H, bs), 8.10 (1H, d), 7.98 (1H, d), 4.13 (2H, m), 3.30 (2H, m)12.23 HO 0 (CH.sub.2).sub.2 C.dbd.O H Cl .sup.1 H-NMR, 300 MHz (d.sup.6 -DMSO): .delta. [ppm] = 13.9 (1H, bs), 8.10 (1H, d), 7.52 (1H, d), 3.41 (2H, m), 2.90 (2H, m)12.24 H.sub.3 CO 0 (CH.sub.2).sub.2 CHOCH.sub.3 H CH.sub.3 .sup.1 H-NMR, 400 MHz (CDCl.sub.3): .delta. [ppm] = 7.46, 7.13, 4.28, 3.87, 3.38, 3.30, 2.90, 2.48, 2.39, 1.9112.25 H.sub.3 CO 0 (CH.sub.2).sub.2 CHOC.sub.2 H.sub.5 H CH.sub.3 m.p. [.degree. C.]: 94-9812.26 H.sub.3 CO 0 (CH.sub.2).sub.2 CHOiPropyl H CH.sub.3 .sup.1 H-NMR, 250 MHz (CDCl.sub.3): .delta. [ppm] = 7.47, 7.17, 4.48, 3.88, 3.79, 3.29, 2.90, 2.48, 2.29, 1.97, 1.2112.27 HO 1 (CH.sub.2).sub.2 C.dbd.O H CH.sub.3 m.p. [.degree. C.]: 98 (decomp.)12.28 H.sub.3 CO 0 CH.dbd.CH C.dbd.O H CH.sub.3 m.p. [.degree. C.]: 128-13012.29 HO 0 CH.dbd.CH C.dbd.O H CH.sub.3 .sup.1 H-NMR, 250 MHz (d.sup.6 -DMSO): .delta. [ppm] = 13.52, 8.48, 8.30, 7.87, 7.03, 2.6612.30 HO 0 (CH.sub.2).sub.2 C.dbd.NO-tButyl H CH.sub.3 m.p. [.degree. C.]: 21712.31 HO 2 (CH.sub.2).sub.2 C.dbd.NOC.sub.2 H.sub.5 H Cl m.p. [.degree. C.]: 20512.32 HO 0 (CH.sub.2).sub.2 C(CH.sub.3).sub.2 H CH.sub.3 m.p. [.degree. C.]: 21212.33 HO 0 (CH.sub.2).sub.2 CH.sub.2 H CH.sub.3 m.p. [.degree. C.]: 15512.34 HO 0 (CH.sub.2).sub.2 CH(C.sub.6 H.sub.5) H CH.sub.3 m.p. [.degree. C.]: 17512.35 HO 2 (CH.sub.2).sub.2 CH.sub.2 H CH.sub.3 m.p. [.degree. C.]: 20412.36 H.sub.3 CO 0 (CH.sub.2).sub.2 CH(C.sub.6 H.sub.5) H CH.sub.3 m.p. [.degree. C.]: 10312.37 HO 2 (CH.sub.2).sub.2 CH(C.sub.6 H.sub.5) H CH.sub.3 m.p. [.degree. C.]: 14512.38 HO 0 (CH.sub.2).sub.2 CHSC.sub.6 H.sub.5 H CH.sub.3 m.p. [.degree. C.]: 7712.39 HO 2 (CH.sub.2).sub.2 CHSO2C.sub.6 H.sub.5 H CH.sub.3 m.p. [.degree. C.]: 23912.40 HO 0 (CH.sub.2).sub.2 C.dbd.O Cl Cl .sup.1 H-NMR, 250 MHz (CDCl.sub.3): .delta. [ppm] = 7.69, 3.31, 3.0112.41 HO 2 (CH.sub.2).sub.2 C.dbd.O Cl Cl .sup.1 H-NMR, 250 MHz (d.sup.6 -DMSO): .delta. [ppm]= 8.04, 4.16, 3.3112.42 H.sub.3 CO 0 (CH.sub.2).sub.2 CHOH Cl Cl .sup.1 H-NMR, 250 MHz (CDCl.sub.3): .delta. [ppm] = 7.50, 5.20, 4.92, 3.36, 2.89, 2.53, 1.8512.43 HO 2 (CH.sub.2).sub.2 CHOI Cl Cl .sup.1 H-NMR, 250 MHz (d.sup.6 -DMSO): .delta. [ppm] = 8.03, 6.96, 5.08, 3.87, 3.62, 2.54, 2.3712.44 HO 0 (CH.sub.2).sub.2 CHOH H CH.sub.3 m.p. [.degree. C.]: 209__________________________________________________________________________
TABLE 12a__________________________________________________________________________Intermediates ##STR292##No. T n R.sup.12 R.sup.13 R.sup.21 R.sup.22 Y L M Physical data__________________________________________________________________________12.45 H.sub.3 CO 0 CH.sub.3 CH.sub.3 H H C.dbd.O H CH.sub.3 .sup.1 H-NMR, 270 MHz (CDCl.sub.3): .delta. [ppm] = 8.02, 7.50, 3.92, 3.09, 2.50, 1.3312.46 H.sub.3 CO 0 H CH.sub.3 H H C.dbd.O H CH.sub.3 m.p. [.degree. C.]: 7912.47 H.sub.3 CO 0 CH.sub.3 CH.sub.3 H H CHOCH.sub.3 H CH.sub.3 .sup.1 H-NMR, 270 MHz (CDCl.sub.3): .delta. [ppm] = 7.44, 7.02, 3.89, 3.59, 3.33, 3.28, 2.50, 2.48, 1.21, 0.8812.48 H.sub.3 CO 0 H H CH.sub.3 H C.dbd.O H CH.sub.3 m.p. [.degree. C.]: 8312.49 H.sub.3 CO 0 H H CH.sub.3 H CHOCH.sub.3 H CH.sub.3 .sup.1 H-NMR, 270 MHz (CDCl.sub.3): .delta. [ppm] = 7.46, 7.11, 4.31, 3.89, 3.65, 3.37, 2.48, 2.44, 1.64, 1.4412.50 HO 0 H CH.sub.3 H H CHOCH.sub.3 H CH.sub.3 m.p. [.degree. C.]: 12412.51 HO 0 CH.sub.3 CH.sub.3 H H CHOCH.sub.3 H CH.sub.3 m.p. [.degree. C.]: 16812.52 HO 0 H H CH.sub.3 H CHOCH.sub.3 H CH.sub.3 m.p. [.degree. C.]: 14512.53 HO 2 H CH.sub.3 H H CHOCH.sub.3 H CH.sub.3 m.p. [.degree. C.]: 184 (trans)12.54 HO 2 CH.sub.3 CH.sub.3 H H CHOCH.sub.3 H CH.sub.3 m.p. [.degree. C.]: 16112.55 HO 2 H H CH.sub.3 H CHOCH.sub.3 H CH.sub.3 m.p. [.degree. C.]: 182__________________________________________________________________________
Preparation of the Final Products
1. 2-(8-Methyl-1,1-dioxothiochroman-4-one-7-carbonyl)-1,3-cyclohexanedione ##STR293## a) 17.4 g (0.0685 mol) of 8-methyl-1,1-dioxothiochroman-4-one-7-carboxylic acid are dissolved in 170 ml of toluene and treated with one drop of dimethylformamide, and 8.96 g (0.0753 mol) of thionyl chloride are added. After refluxing for 4 hours, the reaction mixture is concentrated. The reaction product is directly reacted further.
Yield: 18.6 g (99% of theory) of 8-methyl-1,1-dioxothiochroman-4-one-7-carbonyl chloride;
b) 0.62 g (5.5 mmol) of cyclohexane-1,3-dione is initially introduced into 10 ml of acetonitrile together with 0.56 g (5.5 mol) of triethylamine. 1.5 (5.5 mmol) of 8-methyl-1,1-dioxothiochroman-4-one-7-carbonyl chloride dissolved in 20 ml of acetonitrile are then added dropwise.
The mixture is subsequently stirred at about 20.degree. C. for one hour. 0.31 g (3.7 mmol) of acetone cyanohydrin and 2.8 g (22.5 mmol) of triethylamine are then added and the mixture is stirred for 1 hour. For working-up, the reaction solution is stirred into 2N hydrochloric acid and the aqueous phase is extracted with ethyl acetate. The organic phase is then extracted with Na.sub.2 CO.sub.3 solution and the alkaline aqueous phase is rendered acidic with cooling. The resulting precipitate is filtered off with suction, washed with water and dried.
Yield: 1.0 g (52% of theory) of 2-(8-methyl-1,1-dioxothiochroman-4-one-7-carbonyl)-1,3-cyclohexanedione melting point: 173-178.degree. C.
2. 2-(8-Methyl-1,1-dioxothiochroman-4-one-7-carbonyl O-ethyl oxime)cyclohexane-1,3-dione ##STR294##
1.0 g (3.4 mmol) of 8-methyl-1,1-dioxochroman-4-one-7-carboxylic acid O-ethyl oxime is initially introduced into 10 ml of acetonitrile together with 0.39 g (3.5 mmol) of cyclohexane-1,3-dione, 0.75 g (3.6 mmol) of dicyclocarbodiimide (DCC) is added and the mixture is stirred for 2 hours. 0.1 ml of acetone cyanohydrin and 0.51 g (5.1 mmol) of triethylamine are then added and the reaction mixture is stirred for a further 2 hours. It is then stirred into sodium carbonate solution and extracted with ethyl acetate, and the organic phase is discarded. The aqueous phase is rendered acidic using hydrochloric acid and extracted again with ethyl acetate, the organic phase is dried and the solvent is distilled off. The product is purified by chromatography.
Yield: 600 mg (45% of theory) of 2-(8-methyl-1,1-dioxothiochroman-4-one-7-carbonyl O-ethyl oxime)cylohexane-1,3-dione; melting point: 143.degree. C.
3. 2-(8-Methyl-4-ethoxy-1,1-dioxothiochroman-7-carbonyl)cyclohexane-1,3-dione ##STR295## a) 8.8 g (0.031 mmol) of 8-methyl-4-ethoxy-1,1-dioxothiochroman-7-carboxylic acid are dissolved in 50 ml of toluene, the solution is treated with 2 drops of dimethylformamide and 4.4 g (0.04 mmol) of thionyl chloride are added. After refluxing for 4 hours, the reaction mixture is concentrated. The acid chloride is directly employed further.
b) 0.56 g of cyclohexane-1,3-dione is initially introduced into 10 ml of methylene chloride together with 0.47 g (6 mmol) of pyridine. 1.5 g (5 mmol) of the acid chloride from 3a) in 20 ml of methylene chloride are then added dropwise and the mixture is stirred for one hour. The reaction solution is added to water and rendered acidic with hydrochloric acid. The aqueous phase is extracted with ethyl acetate, the organic phase is dried and the solvent is removed.
Yield: 1.88 g (99% of theory) of O-acylated product.
c) 1.3 g (3.4 mmol) of the product from 3b are dissolved in 20 ml of acetonitrile. The reaction mixture is then treated with 0.19 g (2.3 mmol) of acetone cyanohydrin and 1.7 g (17.2 mmol) of triethylamine and stirred for 2 hours. It is then added to 2N hydrochloric acid and extracted with ethyl acetate. The organic phase is then washed with sodium carbonate solution and discarded. Finally, the alkaline aqueous phase is rendered acidic using hydrochloric acid. The resulting precipitate is filtered off with suction and dried.
Yield: 0.6 g (46% of theory) of 2-(8-methyl-4-ethoxy-1,1-dioxothiochroman-7-carbonyl)cyclohexane-1,3-dione; .sup.1 H-NMR (CDCl.sub.3): .delta. ppm]=17.5 (1H, s), 7.30 (1H, d), 7.18 (1H, d), 4.47 (1H, m), 3.95-3.83 (1H, m), 3.70-3.50 (2H, m), 3.28 (1H, m), 2.81 (2H, tr), 2.71-2.50 (2H, m), 2.64 (3H,s), 2.43 (2H, tr), 2.05 (2H, m), 1.24 (3H, tr).
The compounds shown in the following tables are obtained in a similar manner:
TABLE 13__________________________________________________________________________Compounds of the formula ##STR296##No. R.sup.17 R.sup.18 R.sup.19 n R.sup.12 R.sup.13 R.sup.21 R.sup.22 Y L M Physical data__________________________________________________________________________13.1 CH.sub.3 CH.sub.3 H 2 H H H H C.dbd.O H H m.p. [.degree. C.]: 11013.2 CH.sub.3 H H 2 H H H H C.dbd.O H CH.sub.3 m.p. [.degree. C.]: 84-8613.3 H H H 2 H H H H C.dbd.O H CH.sub.3 m.p. [.degree. C.]: 173-17813.4 CH.sub.3 CH.sub.3 H 2 H H H H C.dbd.O H CH.sub.3 m.p. [.degree. C.]: 84-8513.5 H H H 0 H H H H C.dbd.O H CH.sub.3 m.p. [.degree. C.]: 148-15013.6 CH.sub.3 H H 0 H H H H C.dbd.O H CH.sub.3 m.p. [.degree. C.]: 128-13013.7 CH.sub.3 CH.sub.3 H 0 H H H H C.dbd.O H CH.sub.3 NMR (CDCl.sub.3), 300 MHz: .delta. [ppm] = 17.5 (1H, s), 8.06 (1H, d), 6.89 (1H, d), 3.25 (2H, m), 2.97 (2H, m), 2.68 (2H, s), 2.31 (2H, s), 2.19 (3H, s), 1.12 (6H, s)13.8 H H H 2 H H H H C.dbd.O H H m.p. [.degree. C.]: 159-16213.9 CH.sub.3 H H 2 H H H H C.dbd.O H H m.p. [.degree. C.]: 161-16313.10 CH.sub.3 CH.sub.3 H 2 H H H H CHOCH.sub.3 H CH.sub.3 NMR (CDCl.sub.3), 300 MHz: .delta. [ppm] = 17.5 (1H, s), 7.30 (1H, d), 7.19 (1H, d), 4.36 (1H, m), 3.41 (3H, s), 3.28 (1H, m), 2.70-2.59 (4H, m), 2.61 (3H, s), 2.30 (2H, m), 1.14 (6H, s)13.11 H H H 2 H H H H CHOCH.sub.3 H CH.sub.3 m.p. [.degree. C.]: 80-8413.12 CH.sub.3 H H 2 H H H H CHOCH.sub.3 H CH.sub.3 m.p. [.degree. C.]: 7313.13 H H H 2 H H H H CHOC.sub.2 H.sub.5 H CH.sub.3 NMR (CDCl.sub.3), 300 MHz: .delta. [ppm] = 17.5 (1H, s), 7.30 (1H, d), 7.18 (1H, d), 4.47 (1H, m), 3.95-3.83 (1H, m), 3.70-3.50 (2H, m), 3.28 (1H, m), 2.81 (2H, tr), 2.71-2.50 (2H, m), 2.64 (3H, s), 2.43 (2H, tr), 2.05 (2H, m), 1.24 (3H, tr)13.14 CH.sub.3 H H 2 H H H H CHOC.sub.2 H.sub.5 H CH.sub.3 m.p. [.degree. C.]: 68-7213.15 CH.sub.3 CH.sub.3 H 2 H H H H CHOC.sub.2 H.sub.5 H CH.sub.3 NMR (CDCl.sub.3), 300 MHz: .delta. [ppm] = 17.5 (1H, s), 7.31 (1H, d), 7.18 (1H, d), 4.47 (1H, m), 3.96-3.82 (1H, m), 3.69-3.50 (2H, m), 3.28 (1H, m), 2.81 (2H, tr), 2.72-2.49 (2H, m), 2.68 (2H, s), 2.60 (3H, s), 2.31 (2H, s), 1.24 (3H, tr), 1.11 (6H, s)13.16 CH.sub.3 CH.sub.3 H 2 H H H H CHOiPropyl H CH.sub.3 m.p. [.degree. C.]: 80-8313.17 H H H 2 H H H H CHOiPropyl H CH.sub.3 m.p. [.degree. C.]: 144-14613.18 CH.sub.3 H H 2 H H H H CHOiPropyl H CH.sub.3 m.p. [.degree. C.]: 8513.19 H H H 1 H H H H C.dbd.O H CH.sub.3 NMR (CDCl.sub.3), 300 MHz: .delta. [ppm] = 17.25 (1H, s), 8.14 (1H, d), 7.33 (1H, d), 3.90-3.57 (1H, m), 3.39-3.26 (1H, m), 2.99-2.79 (3H, m), 3.63 (3H, m), 2.44 (2H, tr), 2.13-2.03 (2H, m)13.20 CH.sub.3 H H 1 H H H H C.dbd.O H CH.sub.3 NMR (CDCl.sub.3), 300 MHz: .delta. [ppm] = 17.25 (1H, s), 8.14 (1H, d), 7.33 (1H, d), 3.87 (1H, m), 3.69-3.58 (1H, m), 3.28 (1H, m), 2.96-2.79 (2H, m), 2.62 (3H, s), 2.57-2.44 (2H, m), 2.40-2.13 (2H, m), 1.15 (3H, d)13.21 CH.sub.3 CH.sub.3 H 1 H H H H C.dbd.O H CH.sub.3 NMR (CDCl.sub.3), 300 MHz: .delta. [ppm] = 17.30 (1H, m), 8.13 (1H, d), 7.34 (1H, d), 3.82 (1H, m), 3.64 (1H, m), 3.40-3.25 (1H, m), 2.91 (1H, m), 2.70 (2H, s), 2.64 (3H, s), 2.31 (2H, s), 1.15 (6H, s)13.22 H H H 2 H H H H C.dbd.NOC.sub.2 H.sub.5 H CH.sub.3 m.p. [.degree. C.]: 14313.23 CH.sub.3 H H 2 H H H H C.dbd.NOC.sub.2 H.sub.5 H CH.sub.3 m.p. [.degree. C.]: 6213.24 CH.sub.3 CH.sub.3 H 2 H H H H C.dbd.NOC.sub.2 H.sub.5 H CH.sub.3 m.p. [.degree. C.]: 7513.25 H H H 2 H H H H C.dbd.NOCH.sub.2 CH.dbd.CHCl H CH.sub.3 m.p. [.degree. C.]: 7513.26 H H H 2 H H H H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 H CH.sub.3 m.p. [.degree. C.]: 19213.27 CH.sub.3 H H 2 H H H H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 H CH.sub.3 m.p. [.degree. C.]: 14313.28 CH.sub.3 CH.sub.3 H 2 H H H H C.dbd.NOCH.sub.2 C.sub.6 H.sub.5 H CH.sub.3 m.p. [.degree. C.]: 12613.29 H H H 2 H H H H C.dbd.NO-tButyl H CH.sub.3 m.p. [.degree. C.]: 9813.30 CH.sub.3 CH.sub.3 H 2 H H H H C.dbd.NO-tButyl H CH.sub.3 m.p. [.degree. C.]: 9113.31 H H H 2 H H H H C.dbd.O H Cl NMR (d.sup.6 -DMSO), 300 MHz: .delta. [ppm] = 8.05 (1H, d), 7.69 (1H, d), 4.18 (2H, m), 3.31 (2H, m), 2.62 (4H, m), 1.96 (2H, m)13.32 CH.sub.3 H H 2 H H H H C.dbd.O H Cl m.p. [.degree. C.]: 6613.33 CH.sub.3 CH.sub.3 H 2 H H H H C.dbd.O H Cl m.p. [.degree. C.]: 10413.34 H H H 2 H H H H CHOCH.sub.3 H Cl m.p. [.degree. C.]: 9713.35 CH.sub.3 H H 2 H H H H CHOCH.sub.3 H Cl m.p. [.degree. C.]: 8613.36 CH.sub.3 CH.sub.3 H 2 H H H H CHOCH.sub.3 H Cl m.p. [.degree. C.]: 9213.37 H H H 2 H H H H C(CH.sub.3).sub.2 H CH.sub.3 m.p. [.degree. C.]: 16513.38 CH.sub.3 H H 2 H H H H C(CH.sub.3).sub.2 H CH.sub.3 m.p. [.degree. C.]: 9213.39 CH.sub.3 CH.sub.3 H 2 H H H H C(CH.sub.3).sub.2 H CH.sub.3 m.p. [.degree. C.]: 10713.40 H H H 2 H H H H C.dbd.NOC.sub.2 H.sub.5 H CH.sub.3 .sup.1 H-NMR (CDCl.sub.3), 250 MHz: .delta. [ppm] = 16.8, 8.20, 7.32, 4.33, 3.37, 2.82, 2.45, 2.08, 1.3513.41 H H H 2 H H H H CH.sub.2 H CH.sub.3 m.p. [.degree. C.]: 19913.42 H H H 2 H CH.sub.3 H H CHOCH.sub.3 (trans) H CH.sub.3 m.p. [.degree. C.]: 95 (decomp.)13.43 CH.sub.3 H H 2 H CH.sub.3 H H CHOCH.sub.3 (trans) H CH.sub.3 m.p. [.degree. C.]: 79-8213.44 CH.sub.3 CH.sub.3 H 2 H CH.sub.3 H H CHOCH.sub.3 (trans) H CH.sub.3 m.p. [.degree. C.]: 136-13713.45 H H H 2 CH.sub.3 CH.sub.3 H H CHOCH.sub.3 H CH.sub.3 m.p. [.degree. C.]: 11813.46 CH.sub.3 H H 2 CH.sub.3 CH.sub.3 H H CHOCH.sub.3 H CH.sub.3 m.p. [.degree. C.]: 11013.47 CH.sub.3 CH.sub.3 H 2 CH.sub.3 CH.sub.3 H H CHOCH.sub.3 H CH.sub.3 m.p. [.degree. C.]: 95 (decomp.)13.48 H H H 0 H H H H CH(C.sub.6 H.sub.5) H CH.sub.3 m.p. [.degree. C.]: 8113.49 H H H 2 H H CH.sub.3 H CHOCH.sub.3 H CH.sub.3 m.p. [.degree. C.]: 10013.50 CH.sub.3 H H 2 H H CH.sub.3 H CHOCH.sub.3 H CH.sub.3 m.p. [.degree. C.]: 8613.51 CH.sub.3 CH.sub.3 H 2 H H CH.sub.3 H CHOCH.sub.3 H CH.sub.3 m.p. [.degree. C.]: 14913.52 H H H 2 H H H H CH(C.sub.6 H.sub.5) H CH.sub.3 m.p. [.degree. C.]: 12413.53 CH.sub.3 CH.sub.3 H 2 H H H H CH(C.sub.6 H.sub.5) H CH.sub.3 m.p. [.degree. C.]: 11513.54 H H H 2 H H H H CHNHOC.sub.2 H.sub.5 H CH.sub.3 m.p. [.degree. C.]: 9813.55 H H H 2 H CH.sub.3 H H CHOCH.sub.3 (cis) H CH.sub.3 m.p. [.degree. C.]: 10813.56 CH.sub.3 CH.sub.3 H 2 H H H H CHSO.sub.2 C.sub.6 H.sub.5 H CH.sub.3 m.p. [.degree. C.]: 14013.57 H H H 2 H H H H CHSO.sub.2 C.sub.6 H.sub.5 H CH.sub.3 m.p. [.degree. C.]: 12513.58 CH.sub.3 CH.sub.3 H 2 H H H H CHOH Cl Cl m.p. [.degree. C.]: 8813.59 H H H 2 H H H H C(CH.sub.3).sub.2 Cl Cl m.p. [.degree. C.]: 200 (decomp.)__________________________________________________________________________
TABLE 14__________________________________________________________________________Compounds of the formula ##STR297## Physical dataNo. R.sup.17 R.sup.18 R.sup.19 n R.sup.12 R.sup.13 Y L M m.p. [.degree. C.]__________________________________________________________________________14.001 H H H 2 H H CHOCH.sub.3 H CH.sub.3 70__________________________________________________________________________
TABLE 15__________________________________________________________________________Compounds of the formula ##STR298## Physical dataNo. R.sup.17 R.sup.18 R.sup.19 n R.sup.12 R.sup.13 Y L M m.p. [.degree. C.]__________________________________________________________________________15.1 H H H 0 H H C.dbd.O H CH.sub.3 18415.2 CH.sub.3 H H 0 H H C.dbd.O H CH.sub.3 178-18015.3 CH.sub.3 CH.sub.3 H 0 H H C.dbd.O H CH.sub.3 198__________________________________________________________________________
TABLE 16__________________________________________________________________________Compounds of the formula ##STR299## Physical dataNo. R.sup.3 n X Y L M m.p. [.degree. C.]__________________________________________________________________________16.1 1-Methylthiocyclopropyl 0 (CH.sub.2).sub.2 C.dbd.O H CH.sub.3 151-15316.2 1-Methylthiocyclopropyl 2 (CH.sub.2).sub.2 C.dbd.O H CH.sub.3 133-135__________________________________________________________________________
The compounds I and their agriculturally utilizable salts are suitable as herbicides, both in the form of isomer mixtures and in pure isomer form. The isomer-containing herbicidal compositions provide highly effective control of plant growth on uncultivated areas, in particular at high application rates. They act against broad-leaved weeds and grass weeds in crops such as wheat, rice, maize, soybeans and cotton without significantly harming the crop plants. This effect occurs especially at low application rates.
In consideration of the versatility of the application methods, the compounds I or compositions containing them can additionally be employed in a further number of crop plants for the elimination of undesired plants. Suitable crops, for example, are the following:
Allium cepa, Ananas comosus, Arachis hypogaea, Asparagus officinalis, Beta vulgaris spec. altissima, Beta vulgaris spec. rapa, Brassica napus var. napus, Brassica napus var. napobrassica, Brassica rapa var. silvestris, Camellia sinensis, Carthamus tinctorius, Carya illinoinensis, Citrus limon, Citrus sinensis, Coffea arabica (Coffea canephora, Coffea liberica), Cucumis sativus, Cynodon dactylon, Daucus carota, Elaeis guineensis, Fragaria vesca, Glycine max, Gossypium hirsutum (Gossypium arboreum, Gossypium herbaceum, Gossypium vitifolium), Helianthus annuus, Hevea brasiliensis, Hordeum vulgare, Humulus lupulus, Ipomoea batatas, Juglans regia, Lens culinaris, Linum usitatissimum, Lycopersicon lycopersicum, Malus spec., Manihot esculenta, Medicago sativa, Musa spec., Nicotiana tabacum (N. rustica), Olea europaea, Oryza sativa, Phaseolus lunatus, Phaseolus vulgaris, Picea abies, Pinus spec., Pisum sativum, Prunus avium, Prunus persica, Pyrus communis, Ribes sylvestre, Ricinus communis, Saccharum officinarum, Secale cereale, Solanum tuberosum, Sorghum bicolor (s. vulgare), Theobroma cacao, Trifolium pratense, Triticum aestivum, Triticum durum, Vicia faba, Vitis vinifera, Zea mays.
Moreover, the compounds I can also be used in crops which are tolerant to the action of herbicides as a result of breeding, including genetic engineering methods.
The compounds I and the herbicidal compositions containing them can be applied by spraying, atomizing, dusting, scattering or watering, for example in the form of directly sprayable aqueous solutions, powders, suspensions, even high-percentage aqueous, oily or other suspensions, or dispersions, emulsions, oil dispersions, pastes, dusting compositions, scattering compositions or granules. The application forms depend on the intended uses; in each case they should if possible ensure the finest dispersion of the active compounds according to the invention.
Suitable inert additives are mineral oil fractions of medium to high boiling point, such as kerosene or diesel oil, further coal tar oils and oils of vegetable or animal origin, aliphatic, cyclic and aromatic hydrocarbons, e.g. paraffin, tetrahydronaphthalene, alkylated naphthalenes or their derivatives, alkylated benzenes or their derivatives, methanol, ethanol, propanol, butanol, cyclohexanol, cyclohexanone or strongly polar solvents, such as N-methylpyrrolidone or water.
Aqueous application forms can be prepared from emulsion concentrates, dispersions, pastes, wettable powders or water-dispersible granules by addition of water. To prepare emulsions, pastes or oil dispersions, the substrates can be homogenized in water as such or dissolved in an oil or solvent, by means of wetting agents, adhesives, dispersants or emulsifiers. However, concentrates consisting of active substance, wetting agent, adhesive, dispersant or emulsifier and possibly solvent or oil can also be prepared which are suitable for dilution with water.
Suitable surface-active substances (adjuvants) are the alkali metal, alkaline earth metal or ammonium salts of aromatic sulfonic acids, e.g. lignosulfonic, phenolsulfonic, naphthalenesulfonic and dibutylnaphthalenesulfonic acid, and also of fatty acids, alkyl and alkylarylsulfonates, alkyl, lauryl ether and fatty alcohol sulfates, as well as salts of sulfated hexa-, hepta- and octadecanols, and also of fatty alcohol glycol ether, condensation products of sulfonated naphthalene and its derivatives with formaldehyde, condensation products of naphthalene or of the naphthalenesulfonic acids with phenol and formaldehyde, polyoxyethylene octylphenol ethers, ethoxylated isooctyl-, octyl- or nonylphenol, alkylphenyl or tributylphenyl polyglycol ethers, alkyl-aryl polyether alcohols, isotridecyl alcohol, fatty alcohol-ethylene oxide condensates, ethoxylated castor oil, polyoxyethylene alkyl ethers or polyoxypropylene alkyl ethers, lauryl alcohol polyglycol ether acetate, sorbitol esters, lignin-sulfite waste liquors or methylcellulose.
Powder, scattering and dusting compositions can be prepared by mixing or joint grinding of the active substances with a solid carrier.
Granules, e.g. coated, impregnated and homogeneous granules, can be prepared by binding the active compounds to solid carriers. Solid carriers are mineral earths such as silicic acids, silica gels, silicates, talc, kaolin, limestone, lime, chalk, bole, loess, clay, dolomite, diatomaceous earth, calcium sulfate and magnesium sulfate, magnesium oxide, ground synthetic materials, fertilizers, such as ammonium sulfate, ammonium phosphate, ammonium nitrate, ureas and vegetable products, such as grain flour, tree bark, wood and nutshell meal, cellulose powder or other solid carriers.
The concentrations of the active compounds I in the ready-to-use preparations can be varied within wide ranges. The formulations in general contain from 0.001 to 98% by weight, preferably from 0.01 to 95% by weight, of at least one active compound. The active compounds are employed here in a purity of from 90 to 100%, preferably 95 to 100% (according to NMR spectrum).
The compounds I according to the invention can be formulated, for example, as follows
I. 20 parts by weight of the compound No. 13.1 are dissolved in a mixture which consists of 80 parts by weight of alkylated benzene, 10 parts by weight of the addition product of from 8 to 10 mol of ethylene oxide to 1 mol of oleic acid N-monoethanolamide, 5 parts by weight of calcium dodecylbenzenesulfonate and 5 parts by weight of the addition product of 40 mol of ethylene oxide to 1 mol of castor oil. By pouring out the solution and finely dispersing it in 100,000 parts by weight of water, an aqueous dispersion is obtained which contains 0.02% by weight of the active compound.
II. 20 parts by weight of the compound No. 13.3 are dissolved in a mixture which consists of 40 parts by weight of cyclohexanone, 30 parts by weight of isobutanol, 20 parts by weight of the addition product of 40 mol of isooctylphenol and 10 parts by weight of the addition product of 40 mol of ethylene oxide to 1 mol of castor oil. By pouring the solution into and finely dispersing it in 100,000 parts by weight of water, an aqueous dispersion is obtained which contains 0.02% by weight of the active compound.
III. 20 parts by weight of the active compound No. 13.8 are dissolved in a mixture which consists of 25 parts by weight of cyclohexanone, 65 parts by weight of a mineral oil fraction of boiling point from 210 to 280.degree. C. and 10 parts by weight of the addition product of 40 mol of ethylene oxide to 1 mol of castor oil. By pouring the solution into and finely dispersing it in 100,000 parts by weight of water, an aqueous dispersion is obtained which contains 0.02% by weight of the active compound.
IV. 20 parts by weight of the active compound No. 13.9 are well mixed with 3 parts by weight of the sodium salt of diisobutylnaphthalene-.alpha.-sulfonic acid, 17 parts by weight of the sodium salt of a lignosulfonic acid from a sulfite waste liquor and 60 parts by weight of powdered silica gel and the mixture is ground in a hammer mill. By finely dispersing the mixture in 20,000 parts by weight of water, a spray mixture is contained obtained which contains 0.1% by weight of the active compound.
V. 3 parts by weight of the active compound No. 13.5 are mixed with 97 parts by weight of finely divided kaolin. In this manner, a dusting composition is obtained which contains 3% by weight of the active compound.
VI. 20 parts by weight of the active compound No. 13.15 are intimately mixed with 2 parts by weight of calcium salt of dodecylbenzenesulfonic acid, 8 parts by weight of fatty alcohol polyglycol ether, 2 parts by weight of sodium salt of a phenol/urea/formaldehyde condensate and 68 parts by weight of a paraffinic mineral oil. A stable oily dispersion is obtained.
VII. 1 part by weight of the active compound No. 13.16 is dissolved in a mixture which consists of 70 parts by weight of cyclohexanone, 20 parts by weight of ethoxylated isooctylphenol and 10 parts by weight of ethoxylated castor oil. A stable emulsion concentrate is obtained.
VIII. 1 part by weight of the active compound No. 13.17 is dissolved in a mixture which consists of 80 parts by weight of cyclohexanone and 20 parts by weight of Wettol.RTM. EM 31 (=nonionic emulsifier based on ethoxylated castor oil). A stable emulsion concentrate is obtained.
The application of the active compounds I or of the herbicidal compositions can be carried out pre-emergence or post-emergence. If the active compounds are less tolerable for certain crop plants, application techniques can be used in which the herbicidal compositions are sprayed with the aid of the spray equipment such that the leaves of the sensitive crop plants are not affected if possible, while the active compounds reach the leaves of undesired plants growing under them or the uncovered soil surface (post-directed, lay-by).
Depending on the aim of control, time of year, target plants and stage of growth, the application rates of active compound are from 0.001 to 3.0, preferably from 0.01 to 1.0, kg/ha of active substance (a.s.).
To widen the spectrum of action and to achieve synergistic effects, the benzoyl derivatives I can be mixed and applied together with numerous representatives of other herbicidal or growth-regulating active compound groups. For example, suitable mixture components are 1,2,4-thiadiazoles, 1,3,4-thiadiazoles, amides, aminophosphoric acid and its derivatives, aminotriazoles, anilides, aryloxy-/heteroaryloxyalkanoic acids and their derivatives, benzoic acid and its derivatives, benzothiadiazinones, 2-(heteroaryl/aroyl)-1,3-cyclohexadiones, heteroaryl aryl ketones, benzylisoxazolidinones, meta-CF.sub.3 -phenyl derivatives, carbamates, quinolinecarboxylic acid and its derivatives, chloroacetanilides, cyclohexane-1,3-dione derivatives, diazines, dichloropropionic acid and its derivatives, dihydrobenzofurans, dihydrofuran-3-ones, dinitroanilines, dinitrophenols, diphenyl ethers, dipyridyls, halocarboxylic acids and their derivatives, ureas, 3-phenyluracils, imidazoles, imidazolinones, N-phenyl-3,4,5,6-tetrahydrophthalimides, oxadiazoles, oxiranes, phenols, aryloxy- and heteroaryloxyphenoxypropionic acid esters, phenylacetic acid and its derivatives, 2-phenylpropionic acid and its derivatives, pyrazoles, phenylpyrazoles, pyridazines, pyridinecarboxylic acid and its derivatives, pyrimidyl ethers, sulfonamides, sulfonylureas, triazines, triazinones, triazolinones, tirazolecarboxamides and uracils.
Additionally, it may be useful to apply the compounds I on their own or in combination with other herbicides additionally mixed with further crop protection agents, for example with agents for controlling pests or phytopathogenic fungi or bacteria. Further of interest is the miscibility with mineral salt solutions, which are employed for the elimination of nutritional and trace element deficiencies. Nonphytotoxic oils and oil concentrates can also be added.
Use Examples
It was possible to show the herbicidal action of the benzoyl derivatives of the formula I by greenhouse tests:
The cultivation containers used were plastic flowerpots containing loamy sand with about 3.0% humus as a substrate. The seeds of the test plants were sown separately according to species.
In the case of pre-emergence treatment, the active compounds suspended or emulsified in water were applied directly after sowing by means of finely dispersing nozzles. The containers were lightly watered to promote germination and growth and then covered with transparent plastic hoods until the plants had taken root. This covering causes uniform germination of the test plants if this has not been adversely affected by the active compounds.
For the purposes of post-emergence application, the test plants, depending on growth form, were first raised to a height growth of from 3 to 15 cm and only then treated with the active compounds suspended or emulsified in water. For this purpose, the test plants were either sown directly and grown in the same containers or they were first raised separately as seedlings and transplanted into the test containers a few days before treatment.
The application rate for post-emergence treatment was from 0.5 to 0.25 kg/ha of a.s.
The plants were kept species-specifically at from 10-25.degree. C. or 20-35.degree. C. The test period extended over 2 to 4 weeks. During this time, the plants were tended and their reaction to the individual treatments was assessed.
Assessment was carried out on a scale of from 0 to 100. 100 here means no emergence of the plants or complete destruction of at least the above-ground parts and 0 means no damage or normal course of growth.
The plants used in the greenhouse tests were made up of the following species:
______________________________________Botanical Name English Name______________________________________Chenopodium album lambs-quarters(CHEAL) (goosefoot)Ipomoea subspecies morning glory(IPOSS)Sinapis alba white mustard(SINAL)Solanum nigrum black nightshade(SOLNI)Triticum aestivum summer wheat(TRZAS)Zea mays Indian corn(ZEAMX)______________________________________
TABLE 17______________________________________Herbicidal activity in the case of post-emergence application inthe greenhouse ##STR300## Ex. No. 13.3 Application rate (kg/ha of a.s.) 0.5 0.25Test plants Damage in %______________________________________TRZAS 0 0CHEAL 95 95SINAL 95 95SOLNI 100 95______________________________________
TABLE 18______________________________________Herbicidal activity in the case of post-emergence application inthe greenhouse ##STR301## Ex. No. 13.13 Application rate (kg/ha of a.s.) 0.5 0.25Test plants Damage in %______________________________________ZEAMX 10 0CHEAL 95 95IPOSS 100 100SOLNI 100 100______________________________________

Number	Name	Date
3758522	Feit et al.	Sep 1973
3897476	Feit et al.	Jul 1975
4740519	Shroot et al.	Apr 1988
4780127	Michaely et al.	Oct 1988
5015658	Chandraratna	May 1991
5420273	Klaus et al.	May 1995
5468878	Nasuno et al.	Nov 1995
5480858	Sakamoto et al.	Jan 1996

Number	Date	Country
903 254	Mar 1986	BEX
139 578	Jan 1973	DKX
50 957	May 1982	EPX
73 663	Mar 1983	EPX
090 262	Oct 1983	EPX
135 191	Mar 1985	EPX
137 963	Apr 1985	EPX
186 120	Jul 1986	EPX
186 119	Jul 1986	EPX
186 118	Jul 1986	EPX
283 261	Oct 1988	EPX
319 075	Jun 1989	EPX
338 992	Oct 1989	EPX
350 846	Jan 1990	EPX
2 321 518	Nov 1973	DEX
24 50 193	May 1975	DEX
44 27 995	Feb 1996	DEX
3052862	Jul 1989	JPX
9005712	May 1990	WOX
9404524	Mar 1994	WOX
9408988	Apr 1994	WOX
9408962	Apr 1994	WOX
9708164	Mar 1997	WOX

Benzoyl derivatives

Information

Patent Number

Date Filed

Date Issued

Inventors

Original Assignees

Examiners

Agents

CPC

US Classifications

Field of Search

US

International Classifications

Abstract

Description

Claims

Priority Claims (1)

Parent Case Info

PCT Information

US Referenced Citations (8)

Foreign Referenced Citations (23)

Non-Patent Literature Citations (1)