Claims
- 1. In a process for recovery of copper from an aqueous ammoniacal solution containing copper values comprising:
- (A) contacting a copper pregnant aqueous ammoniacal solution containing copper values with a water insoluble beta-diketone copper extractant dissolved in a water-immiscible organic solvent to extract copper values from said aqueous ammoniacal solution into said organic solution thereby forming a copper pregnant organic phase and a copper depleted aqueous phase;
- (B) separating said aqueous phase and said organic phase;
- (C) contacting the copper pregnant organic phase with an aqueous acidic stripping solution;
- (D) separating said aqueous acidic stripping solution now containing the copper values from the organic phase; and
- (E) recovering the copper from said aqueous acidic stripping solution;
- wherein the improvement comprises said water insoluble beta-diketone extractant being a highly sterically hindered beta-diketone.
- 2. A process as defined in claim 1 wherein the sterically hindered beta-diketone has the formula I: ##STR6## wherein R.sub.1 through R.sub.3 and R.sub.5 through R.sub.7 are the same or different, and are chosen from the group consisting of hydrogen, an aryl radical, an alkaryl radical containing from 6 to about 18 carbon atoms, and an alkyl radical containing from 1 to about 13 carbon atoms, and R.sub.4 is chosen from the group consisting of H, chloro, nitro and cyano with the provisos that (a) any two of R.sub.1 through R.sub.7 may together form a carbocyclic ring, (b) no more than three of R.sub.1 through R.sub.7 may be hydrogen, and (c) the overall molecule contains at least 12 carbon atoms, and (d) R.sub.5, R.sub.6, R.sub.7 taken together comprise a mixture of at least two isomers.
- 3. A process as defined in claim 1, wherein the sterically hindered beta-diketone has the formula II: ##STR7## where R is phenyl or alkyl substituted phenyl, R' is alkyl, R" is chosen from the group consisting of H, chloro, nitro and cyano, and R'" and R"" are the same or different and are chosen from the group consisting of H, alkyl having from 1 to about 8 carbon atoms, and aralkyl having from 7 to about 14 carbon atoms, with the proviso that (a) no more than one of R", R'" and R"" are H and (b) the total number of carbons in all R groups is at least 11, and (c) R', R'" and R"" taken together comprise a mixture of at least two isomers.
- 4. A process as defined in claim 3, wherein R is phenyl, R" is H, R' is propyl or isopropyl and R'" is ethyl and R"" is methyl.
- 5. A process as defined in claim 3 wherein R is phenyl, R" is H, R' is branched hexyl, R'" and R"" are methyl.
- 6. A process as defined in claim 3, wherein R is phenyl, R" is H, R' is a mixture of straight and branched chain alkyl groups having from 3-8 carbon atoms and R'" and R"" are methyl.
- 7. A process as defined in claim 3 wherein the group ##STR8## is a neoalkyl group in which R', R'" and R"", which may be the same or different, are all alkyl groups containing from 1 to 8 carbon atoms and the total number of carbon atoms in R', R'" and R"" is from 5 to about 16.
- 8. A process as defined in claim 1 wherein the diketone is a mixture of branched and straight chain isomers of 1-phenyl-4,4-dimethyl-1,3-undecanedione.
- 9. A process as defined in claim 1 wherein the diketone is 1-phenyl-3-neodecyl-1,3-propanedione.
- 10. A process as defined in claim 1 wherein the diketone is 1-phenyl-3-neoheptyl-1,3-propanedione.
- 11. A process as defined in claim 1 wherein the diketone is 1-phenyl-3-neohexyl-1,3-propanedione.
- 12. A process as defined in claim 1 wherein the diketone is 1-phenyl-3-neooctyl-1,3-propanedione.
- 13. A process as defined in claim 1 wherein the diketone is 1-phenyl-3-neononyl-1,3-propanedione.
- 14. A process as defined in claim 1, in which the extractant further comprises an hydroxy aryl oxime.
- 15. A process as defined in claim 14, wherein said hydroxy aryl oxime is present in a catalytic amount.
- 16. A process as defined in claim 14, wherein said hydroxyaryl oxime is a co-extractant with the beta-diketone.
- 17. A process as defined in claim 14, wherein said hydroxy aryl oxime has the formula: ##STR9## where R.sup.1 is a saturated aliphatic group of 1-25 carbon atoms or an ethylenically unsaturated group of 3-25 carbon atoms or OR.sup.3, where R.sup.3 is a saturated or ethylenically unsaturated group as defined above, a is an integer of 0, 1, 2, 3 or 4 and R.sup.2 is H, or a saturated or ethylenically unsaturated group as defined above, with the proviso that the total number of carbon atoms in R.sup.1 and R.sup.2 is from 3-25, or is phenyl or R.sup.4 substituted phenyl where R.sup.4 is a saturated or ethylenically unsaturated group as defined above, which may be the same or different from R.sup.1.
- 18. A process as defined in claim 17, in which said hydroxy aryl oxime is selected from the group consisting of 5-heptyl salicylaldoxime, 5-octyl salicylaldoxime, 5-nonyl salicylaldoxime, 5-dodecyl salicylaldoxime, 5-nonyl-2-hydroxyacetophenone oxime, 5-dodecyl-2-hydroxyacetophenone oxime, 2-hydroxy-5-nonyl benzophenone oxime and 2-hydroxy-5-dodecyl benzophenone oxime.
- 19. A beta-diketone extractant compound adapted for extracting copper values from aqueous ammoniacal copper containing solutions comprising a beta-diketone compound of the formula II: ##STR10## where R is phenyl or alkyl substituted phenyl, R' is alkyl, R" is selected from the group of H and an electron withdrawing group selected from the group consisting of chloro, nitro and cyano and R'" and R"" are the same or different and are chosen from the group consisting of H, alkyl having from 1 to about 8 carbon atoms, and aralkyl having from 7 to about 14 carbon atoms, with the proviso that (a) no more than one of R", R'" and R"" are H (b) the total number of carbons in all R groups is at least 11, and (c) R', R'" and R"" taken together comprise a mixture of at least two isomers.
- 20. A beta-diketone compound as defined in claim 19, wherein R is phenyl, R" is H, R' is propyl or isopropyl and R'" is ethyl and R"" is methyl.
- 21. A beta-diketone compound as defined in claim 19, wherein R is phenyl, R" is H, R' is branched hexyl and R'" and R"" are methyl.
- 22. A beta-diketone compound as defined in claim 19, wherein R is phenyl, R" is H, R' is a branched chain alkyl group having from 3-8 carbon atoms and R'" and R"" are methyl.
- 23. A beta-diketone compound as defined in claim 19 wherein the group ##STR11## is a neoalkyl group in which R', R'" and R"", which may be the same or different, are all alkyl groups containing from 1-8 carbon atoms and the total number of carbon atoms in R', R'" and R"" is from 5 to about 16.
- 24. A mixture of isomers of 1-phenyl-4,4-dimethyl-1,3-undecanedione.
- 25. 1-phenyl-3-neoheptyl-1,3-propanedione.
- 26. 1-phenyl-3-neohexyl-1,3-propanedione.
- 27. 1-phenyl-3-neooctyl-1,3-propanedione.
- 28. 1-phenyl-3-neononyl-1,3-propanedione.
Parent Case Info
This application is a continuation-in-part application of U.S. Ser. No. 08/780,759 filed Jan. 8, 1997 the entire disclosure of which is hereby incorporated herein by reference.
US Referenced Citations (7)
Foreign Referenced Citations (4)
Number |
Date |
Country |
668358 |
Aug 1996 |
AUX |
0 036 401 |
Sep 1981 |
EPX |
2 355 064 |
Jan 1976 |
FRX |
WO9304208 |
Mar 1993 |
WOX |
Non-Patent Literature Citations (2)
Entry |
"Physical and Chemical Separations via the Arbiter Process", Kuhn & Arbiter, International Mining Congress, Apr., 1975, Cagliari, Italy, pp. 831-847. |
"Anaconda's Arbiter Process for Copper", Kuhn & Arbiter, CIM Bulletin, Feb., 1974. |
Continuation in Parts (1)
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Number |
Date |
Country |
Parent |
780759 |
Jan 1997 |
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