Claims
- 1. A surgical article having improved knot repositioning characteristics, the article comprising a multifilamentary strand, the strand having a bioabsorbable coating, the coating comprising a block copolymer having one or more A blocks solely manufactured from the monomer caprolactone, and one or more B blocks manufactured from the monomer caprolactone randomly copolymerized with one or more monomers selected from the group consisting of lactides, carbonates and a lactone other than caprolactone, the total caprolactone linkages in the copolymer being more than 50 to about 80 percent by weight of said copolymer.
- 2. An article of claim 1 wherein the caprolactone is .epsilon.-caprolactone.
- 3. An article of claim 1 wherein the caprolactone in the one or more A blocks is up to 70 percent by weight of the copolymer.
- 4. An article of claim 3 wherein the caprolactone in the one or more A blocks is about 40 percent by weight of the copolymer.
- 5. An article of claim 1 wherein the one or more B blocks are manufactured from caprolactone and glycolide.
- 6. An article of claim 5 wherein the glycolide in the one or more B blocks comprises up to 50 percent by weight of the copolymer.
- 7. An article of claim 5 wherein the glycolide in the one or more B blocks comprises up to about 65 percent by weight of said B blocks.
- 8. An article of claim 1 wherein the inherent viscosity of the copolymer is about 0.1 to 1.0 dl/g (0.5 g/dl in CHCl.sub.3, 30.degree. C.).
- 9. An article of claim 7 wherein the inherent viscosity of the copolymer is about 0.4 to 0.8 dl/g (0.5 g/dl in CHCl.sub.3, 30.degree. C.).
- 10. An article of claim 1 wherein the surgical article is bioabsorbable.
- 11. An article of claim 10 wherein the bioabsorbable surgical article is a suture or ligature.
- 12. An article of claim 11 wherein the suture or ligature is manufactured from a polymer prepared from one or more monomers selected from the group consisting of lactides, carbonates and lactones.
- 13. An article of claim 12 wherein the suture or ligature is manufactured from a homopolymer prepared from the monomer glycolide.
- 14. An article of claim 12 wherein the suture or ligature is manufactured from a polymer prepared from at least the monomer lactide.
- 15. An article of claim 12 wherein the suture or ligature is manufactured from a copolymer prepared from the monomers glycolide and 1,3-dioxan-2-one.
- 16. An article of claim 14 wherein the suture or ligature is manufactured from a copolymer prepared from the monomers glycolide and lactide.
- 17. An article of claim 12 or 14 wherein the coating comprises about 1/10 to 5% by weight of the coated suture or ligature.
- 18. An article of claim 17 wherein the coating comprises about 1/4 to 3% by weight of the coated suture or ligature.
- 19. A surgical suture or ligature having improved knot repositioning characteristics, comprising a bioabsorbable, multifilamentary strand manufactured from a polymer prepared from one or more monomers selected from the group consisting of glycolide, lactide, 1,3-dioxan-2-one and 1,4-dioxane-2-one, the strand having a bioabsorbable coating, the coating comprising a block copolymer having one or more A blocks comprising caprolactone, wherein the caprolactone in the one or more A blocks is about 40 percent by weight of the copolymer, and one or more B blocks manufactured from the monomer caprolactone randomly polymerized with one or more monomers selected from the group consisting of lactides, the total caprolactone linkages in the copolymer being about 70 percent by weight of said copolymer, wherein the coating comprises about 1/10 to 5 percent by weight of the coated suture or ligature.
- 20. A suture or ligature of claim 19 wherein the one or more B blocks are manufactured from caprolactone and glycolide.
- 21. A suture or ligature of claim 20 wherein the inherent viscosity of the copolymer is about 0.4 to 0.8 dl/g (0.5 g/gl in CHCl.sub.3, 30.degree. C.).
- 22. A suture or ligature of claim 21 wherein the coating comprises about 1/4 to 3% by weight of the coated suture or ligature.
- 23. A surgical suture or ligature having improved knot repositioning characteristics, comprising a bioabsorbable, multifilamentary strand manufactured from a polymer prepared from one or more monomers selected from the group consisting of glycolide, lactide, 1,3-dioxan-2-one and 1,4-dioxan-2-one, the strand having a bioabsorbable coating, the coating comprising a block copolymer having one or more A blocks comprising caprolactone, wherein the caprolactone in the one or more A blocks is about 40 percent by weight of the copolymer, and one or more B blocks manufactured from one or more monomers selected from the group consisting of lactides, carbonates and a lactone other than caprolactone, the total carprolactone linkages in the copolymer being about 70 percent by weight of said polymer, wherein the coating comprises about 1/10 to 5 percent by weight of the coated suture or ligature.
- 24. A suture or ligature of claim 23 wherein the one or more B blocks are manufactured from glycolide and 1,3-dioxan-2-one.
- 25. A suture or ligature of claim 24 wherein the inherent viscosity of the copolymer is about 0.1 to 04. dl/g (0.5 g/gl in CHCl.sub.3, 30.degree. C.).
- 26. A suture or ligature of claim 25 wherein the coating comprises about 1/4 to 3% by weight of the coated suture or ligature.
CROSS-REFERENCE TO RELATED APPLICATION
This is a continuation-in-part application of U.S. Ser. No. 910,598 filed Sept. 23, 1986, now abondoned.
US Referenced Citations (8)
Continuation in Parts (1)
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Number |
Date |
Country |
Parent |
910598 |
Sep 1986 |
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