Biomass Carrier Promoting Simultaneous Nitrification-De-nitrification

Information

  • Patent Application
  • 20070284294
  • Publication Number
    20070284294
  • Date Filed
    May 28, 2007
    18 years ago
  • Date Published
    December 13, 2007
    17 years ago
Abstract
The invention is a biomass carrier used in the biological purification of waste water. The design of the biomass carrier is characterized by a surface morphology designed to produce a specific pattern of variations in bio-film thickness, resulting in optimized bio-film conditions for simultaneous nitrification-de-nitrification and biodegradation of trace organic contaminants.
Description

BRIEF DESCRIPTION OF THE DRAWINGS


FIG. 1 is a cross-sectional view of a preferred embodiment of the biomass carrier of the present invention.



FIG. 2 is the same view as FIG. 1.



FIG. 3 is a view of three possible morphologies of the biomass carrier labelled A, B and C with morphology A being the preferred embodiment.





DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENT

Referring now to FIG. 1, there is shown the proposed design for my invention (10) depicted in cross section. As illustrated, the biomass carrier (10) of my invention consists of a specific geometric design of the carrier framework.


Referring now to FIG. 3, there is illustrated the specific morphology for the surfaces (12), (14), and (16) of the biomass carrier illustrated in FIG. 1.



FIG. 1 depicts the preferred embodiment of the biomass carrier (10) using surface morphology pattern (12). However, the biomass carrier could accommodate any of the alternative patterns (14) or (16) depicted in FIG. 2.


The profile of the preferred embodiment of the biomass carrier (10) has a substantially hollow rectangular body with rounded corners (18), (20), (22) and (24). For the sake of reference, the biomass carrier comprises four walls: top (26), bottom (28), left (30) and right (32). The body is hollow to permit mass transfer there through. Inside these four walls are equally spaced vertical parallel partitions (34) (36), (38), (40) and (42) and a single transverse support member (44). The intersection of the partitions and the support member results in the formation of a plurality of cells (46) within the carrier body (10) having a reticulated matrix pattern. The distance (41) between the vertical parallel partitions is uniform. In other embodiments of the invention there may be additional parallel partitions and transverse support ribs to provide appropriate control on the dimensions of the cells (46) according to production methods and requirements. The cells have a width (47) and a length (49).


Referring now to FIG. 2 which is the same figure as FIG. 1, the biomass carrier (10) further comprises a width (48) and a height (50). The biomass carrier also has a predetermined thickness which is not illustrated in FIG. 1. Each of the four walls has an outside surface (52) to (58) and an inside surface (60) to (66). Each of the parallel partitions has two parallel surfaces (68) and (70). The transverse support rib also has two parallel surfaces (72) and (74). Located on each of the inside surfaces of the walls and the parallel surfaces of the parallel partitions are a plurality of equally spaced projections (76). These projections are integral to the walls, have rounded tips and a height (78) and are separated by separations (80) having a width (82) and a depth (84) equal to the height (78) of the projections (76). They depend inwards from the walls, that is, towards the interior of the cells.


Referring to FIGS. 1, 2 and 3, there are a number of considerations for determining the above-identified design characteristics of the preferred embodiment of my biomass carrier. Consider, first the surface morphology of the biomass carrier as that most directly influences its SNdN capabilities. The biomass carrier design must allow for the highest bulk liquid dissolved oxygen level consistent with maintaining appropriate anoxic micro-sites. In my biomass carrier there are alternating projections (76) and recesses (80) across the previously identified inside surfaces of the cells of the carrier. Upon these surfaces, the biomass in the form of a bio-film (85) grows so as to establish a relatively thick layer (86) in the recesses (80) and a thinner layer (88) over the projections (76).


The bio-film thickness on conventional biomass carriers in conditions anticipated for this invention would be expected to be in the range of 0.3 mm to 0.8 mm, with a typical value of 0.5 mm. With the present invention and under similar operating conditions, the bio-film thickness (86) in the separation areas will be considerably thicker than this, ranging from 0.6 mm to 1.3 mm while the thickness (88) of the bio-film in the projection areas is expected to be close to the typical value of 0.5 mm. Consequently, my biomass carrier will carry more biomass than an equivalent projected area of a conventional (flat) carrier surface under the same operating conditions. In addition, bio-film in well protected separation areas (80) will tend to slough at a slower frequency than projection areas (76) allowing the development of an older bio-film with higher autotroph populations (to facilitate nitrification) as well as anoxic regions to promote de-nitrification.


The depth and width and shape of separations must be optimized to balance several considerations:

    • (1) tendency to slough biomass, thereby affecting bio-film depth and age;
    • (2) oxygen diffusion;
    • (3) substrate transport between aerobic and anoxic conditions; and,
    • (4) Ease of manufacture.


Appropriate dimensions for the separation (80) under typical operating conditions are as follows: maximum depth (84) of 1 mm, with separations bounded by projections such that separations have a width (82) of approximately 1.4 mm. Variations in these dimensions are appropriate depending on the specific process application, however, the height of the projections (78) should be within the range of 0.5-2 mm with the ratio of separation width (82) to depth (84) falling in the range of 1.2:1 to 3:1.


All three surface morphologies depicted in FIG. 3 are acceptable for my biomass carrier. However the preferred embodiment is Pattern A (12). Unlike the other two patterns B (16) and C (18), Pattern A provides 4 interfaces between thin and thick bio-film areas per separation. Under typical operating circumstances, the bio-film will be thinner at the projection tips and the centre of the separation than in the corner areas of the separation resulting in two such interfaces between tip and corner and two such interfaces between corner and centre per separation. This increased interface area provides a diffusion advantage. In addition, Pattern A is more easily produced to exact tolerances in the manufacturing process. Anoxic sites will be preferentially located in the separation corners (90).


The next consideration is the placement of defined morphologies in my biomass carrier (10). Many carriers employ a general tubular shape with one or more concentric rings and several radial partitions. This results in apertures that have a low aspect ratio (square-like or pie shaped). As with a pipe cross section, as bio-film grows, it reduces both the diameter for flow as well as the area of interface between the bio-film and the bulk liquid. Flow in tubular conduits (or apertures in this case) is proportional to the square of the diameter. As the diameter of the pipe decreases the rate and amount of bio-film growth also decreases due to: (1) a reduction in the flow diameter (and therefore flow velocities); and, (2) a reduction in the area for diffusion between bulk liquid and bio-film. With my biomass carrier the intention is to develop bio-films that are thicker, on average, than those possible with prior art carriers while at the same time maximizing the mass flow through the biomass carrier. However, with the use of a plurality of rectangular cells (46) there would normally be severe mass transfer problems through the carrier as the bio-film increased in thickness. To overcome this, I have introduced the benefits of flow between parallel plates, namely, the parallel walls of the cells (46). By introducing the projections (78) inside of each cell, the mass flow through each cell is optimized without the deleterious effects caused by an increase in bio-film thickness. For example, in the preferred embodiment (10) (momentarily ignoring the prominences), each cell (46) has a width (47) of approximately 4.1 mm and a length (49) of approximately 10 mm. This has the same hydraulic radius as a circular aperture 5.8 mm in diameter. In addition, as bio-film thickness increases, the deleterious effect on total bio-film/bulk fluid contact area is less pronounced than with lower aspect ratio apertures. In summary, for the intended application of this invention, surfaces can be most tightly spaced if apertures between the surfaces are elongated. This results in the ability to achieve higher specific surface area values without counterproductive mass transfer effects. It follows that opposing projections should be spaced apart as much as possible to maintain an open channel, to the extent possible.


The preferred embodiment (10) has spacing between the partitions (42) (ignoring projections) of 4.1 mm, however, values in the range of 3 to 6 mm are feasible for this embodiment depending on the specific process application and the dimensions selected for projections.


Finally, we address the overall configuration of the carrier (10). The overall size and aspect ratio of the carrier is based on several considerations:

    • (1) The need for dimensions large enough make the carrier practical to contain in a reactor with simple screens;
    • (2) The need for sufficient size and mass to encourage acceptable internal flow velocities in aerated biomass carrier reactors. Small, light carriers have low drag coefficients are more readily carried along with the water flow and consequently can have low internal flow velocities;
    • (3) The need for high fill fraction capability which is influenced by both size and aspect ratio; and,
    • (4) Practical manufacturing considerations particularly total protected surface area extrudable per machine per hour.


Consideration of the above factors in the light of practical experience has led to the selection of an overall size of 28.6 mm in length (50) by 21.9 mm in width (48). The cut thickness is dependant on the specific application and can vary from approximately 10 mm to 25 mm. Variations in the cross-sectional dimensions are permissible by including more or fewer of the patterned cells (46). For example, cells can be added to the length (50) of the profile.


The predetermined first aspect ratio of length to width is approximately 1.3:1, however, ratios up to 3:1 are considered to be practical. For example, a carrier designed on the basis of the upper or lower half of the preferred embodiment as depicted, would be acceptable and would have an aspect ratio of approximately 2.6:1.


The cells (46) should have high aspect ratios. However, there are practical limitations imposed by the manufacturing process such as the need for rigidity and uniform distance (41) between the vertical partitions in the carrier. In the preferred embodiment, the predetermined second aspect ratio is approximately 3:1. Values between 2.5 and 4.0 are acceptable and feasible. However, the distance (41) must conform to the guidelines stated above.


The carrier is preferably made from a plastic such as HDPE. However, the composition may optionally be amended by the addition of a UV retardant such as carbon black as well as other amendments designed to optimize the specific gravity. In recent experimental work, I have observed that the specific gravity of a biomass carrier has significant impact on the ability of the carrier to be entrained by water circulating throughout bioreactors. This effect is most pronounced at start-up before the media has wetted out and developed a significant bio-film or in process situations where bio-films are ordinarily thin. As bio-film develops, the natural buoyancy of the carrier is reduced and motion is enhanced. Nonetheless, there are numerous situations with conventional carriers where the amount of air required to move the media satisfactorily exceeds the amount required to fulfill biochemical requirements, resulting in a significant incremental expenditure of energy. An example would be a nitrification application, where the invention's large surface area and well protected niches will be advantageous for the growth of nitrifying bacteria but where average bio-film thickness can be expected to be small. In such situations, a carrier with optimized specific gravity can result in significant energy savings. Practical experience by this inventor has indicated that a specific gravity in the range of 0.975 and 0.995 with a preferred value of 0.985 being close to ideal for most applications.


Although the description above contains much specificity, these should not be construed as limiting the scope of the invention but as merely providing illustrations of some presently preferred embodiments of this invention. Thus the scope of the invention should be determined by the appended claims and their legal equivalents rather than by the examples given.

Claims
  • 1. A biomass carrier optimized for simultaneous nitrification-de-nitrification comprising a substantially rectangular body adapted for mass transfer there through, said body having a predetermined first aspect ratio and comprising a reticulated internal matrix of cells having a predetermined inside surface morphology, wherein said inside surface morphology is adapted for bio-film growth there upon, and wherein each cell of said internal reticulated matrix of cells has a predetermined second aspect ratio, and further wherein said bio-film has alternating thick and thin regions in close proximity, and wherein said thick regions preferentially contain anoxic sites for de-nitrification and said thin regions contain aerobic sites for nitrification thereby promoting the efficient transfer of nitrites between said anoxic and said aerobic sites.
  • 2. The biomass carrier as claimed in claim 1 wherein said predetermined first aspect ratio is between a value of 1.3:1 and 3:1.
  • 3. The biomass carrier as claimed in claim 1 wherein said predetermined second aspect ration is between a value of 2.5:1 and 4.0:1.
  • 4. The biomass carrier as claimed in claim 1 having a specific gravity between 0.975 and 0.995.
  • 5. The biomass carrier as claimed in claim 1 wherein the predetermined inside surface morphology comprises a plurality of spaced integral projections depending inwards, wherein each projection of said plurality of spaced projections has a predetermined length and is separated from an adjacent projection by a predetermined distance.
  • 6. The biomass carrier as claimed in claim 5 wherein each projection of said plurality of spaced projections has a rounded tip, and wherein the bio-film is thinner over said rounded tip and thicker between said projections so that anoxic regions form between said projections and aerobic regions form over the rounded tip thereby forming alternating anoxic regions and aerobic regions in close proximity for simultaneous nitrification-de-nitrification and further wherein the bio-film thickness near the midway point between projections will be thinner than in the areas closer to the projections such that a second set of aerobic—anoxic interfaces is active.
  • 7. A biomass carrier optimized for simultaneous nitrification-de-nitrification comprising: a hollow rectangular body having rounded corners, said body comprising a length, a width and a thickness, wherein the body has a top wall, a bottom wall, a left wall and a right wall; and, a plurality of vertical and parallel structural members within the hollow rectangular body and between the top wall and the bottom wall, wherein said plurality of vertical and parallel structural members is adapted to provide rigidity to the hollow rectangular body; and, at least one horizontal member disposed between the left wall and the right wall and midway between the top wall and the bottom wall; and, a plurality of rectangular cells resulting from the intersection of the plurality of vertical and parallel structural members and said at least one horizontal member.
  • 8. The biomass carrier as claimed in claim 7 wherein each cell of said plurality of rectangular cells comprises an inside surface having a predetermined morphology.
  • 9. The biomass carrier as claimed in claim 8 wherein said morphology comprises a plurality of spaced integral projections depending inwardly.
  • 10. The biomass carrier as claimed in claim 9 wherein each projection of said plurality of spaced integral projections has a rounded tip.
  • 11. The biomass carrier as claimed in claim 10 wherein each projection of the plurality of spaced integral projections has a predetermined length and is spaced by a predetermined distance thereby forming a separation between a first and a second spaced integral projection.
  • 12. The biomass carrier as claimed in claim 11 wherein the morphology promotes thick bio-film growth within said separation and thin bio-film growth over said first and said second spaced integral projection.
  • 13. The biomass carrier as claimed in claim 12 wherein the morphology covers no less than 70 percent of the inside surface area of the biomass carrier.
  • 14. The biomass carrier as claimed in claim 13 wherein said thick bio-film growth promotes the formation of anoxic sites and said thin bio-film growth promotes the formation of aerobic sites thereby creating alternating anoxic and aerobic sites in close proximity for simultaneous nitrification-de-nitrification.
  • 15. The biomass carrier as claimed in claim 14 wherein each projection of the plurality of spaced integral projections has a height between 0.5 mm and 2.0 mm.
  • 16. The biomass carrier as claimed in claim 15 wherein the separation has a width between 3 and 6 mm.
  • 17. The biomass carrier as claimed in claim 16 wherein the ratio of separation width to projection height is between 1.2 and 3.
  • 18. The biomass carrier as claimed in claim 17 wherein the body has an aspect ratio between 1.3:1 and 3:1.
  • 19. The biomass carrier as claimed in claim 18 wherein each cell of the plurality of cells has an aspect ratio between 2.5:1 and 4.0:1.
  • 20. The biomass carrier as claimed in claim 19 wherein the body is manufactured from extruded high density polyethylene having a specific gravity between 0.975 and 0.995.
Priority Claims (1)
Number Date Country Kind
2,550,121 Jun 2006 CA national